CN115341963A - Ammonia-hydrogen-methane multi-substance mixed heat supply and electricity generation system and use method thereof - Google Patents
Ammonia-hydrogen-methane multi-substance mixed heat supply and electricity generation system and use method thereof Download PDFInfo
- Publication number
- CN115341963A CN115341963A CN202210839686.8A CN202210839686A CN115341963A CN 115341963 A CN115341963 A CN 115341963A CN 202210839686 A CN202210839686 A CN 202210839686A CN 115341963 A CN115341963 A CN 115341963A
- Authority
- CN
- China
- Prior art keywords
- valve
- ammonia
- combustion chamber
- turbine
- storage tank
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000000126 substance Substances 0.000 title claims abstract description 49
- 230000005611 electricity Effects 0.000 title claims abstract description 12
- 238000000034 method Methods 0.000 title claims abstract description 9
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 claims abstract description 82
- 238000002485 combustion reaction Methods 0.000 claims abstract description 64
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 claims abstract description 46
- 229910021529 ammonia Inorganic materials 0.000 claims abstract description 30
- 238000001704 evaporation Methods 0.000 claims abstract description 22
- 238000003860 storage Methods 0.000 claims abstract description 22
- 230000008020 evaporation Effects 0.000 claims abstract description 18
- 239000003345 natural gas Substances 0.000 claims abstract description 18
- 239000007789 gas Substances 0.000 claims description 31
- 239000000446 fuel Substances 0.000 claims description 30
- 238000010531 catalytic reduction reaction Methods 0.000 claims description 17
- MWUXSHHQAYIFBG-UHFFFAOYSA-N Nitric oxide Chemical compound O=[N] MWUXSHHQAYIFBG-UHFFFAOYSA-N 0.000 claims description 15
- 230000003197 catalytic effect Effects 0.000 claims description 13
- 230000003647 oxidation Effects 0.000 claims description 13
- 238000007254 oxidation reaction Methods 0.000 claims description 13
- 239000001257 hydrogen Substances 0.000 claims description 9
- 229910052739 hydrogen Inorganic materials 0.000 claims description 9
- IJGRMHOSHXDMSA-UHFFFAOYSA-N nitrogen Substances N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 claims description 9
- 238000010248 power generation Methods 0.000 claims description 8
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims description 7
- 238000010438 heat treatment Methods 0.000 claims description 7
- 239000000203 mixture Substances 0.000 claims description 6
- 229910052757 nitrogen Inorganic materials 0.000 claims description 6
- 238000000354 decomposition reaction Methods 0.000 claims description 4
- 238000006722 reduction reaction Methods 0.000 claims description 4
- 239000002918 waste heat Substances 0.000 claims description 4
- 239000003054 catalyst Substances 0.000 claims description 3
- 238000002407 reforming Methods 0.000 claims description 3
- 238000006057 reforming reaction Methods 0.000 claims description 3
- 238000004227 thermal cracking Methods 0.000 claims description 3
- 239000002912 waste gas Substances 0.000 claims description 3
- 239000007795 chemical reaction product Substances 0.000 claims description 2
- 150000002431 hydrogen Chemical class 0.000 claims description 2
- 239000000047 product Substances 0.000 claims description 2
- 230000008676 import Effects 0.000 abstract 1
- 239000000463 material Substances 0.000 abstract 1
- 229910052799 carbon Inorganic materials 0.000 description 4
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 3
- AWAUBADRMJIRAK-UHFFFAOYSA-N azane;methane Chemical compound C.N AWAUBADRMJIRAK-UHFFFAOYSA-N 0.000 description 2
- 238000006243 chemical reaction Methods 0.000 description 2
- 238000005086 pumping Methods 0.000 description 2
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 239000006227 byproduct Substances 0.000 description 1
- 229910002091 carbon monoxide Inorganic materials 0.000 description 1
- 238000005336 cracking Methods 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- 238000007599 discharging Methods 0.000 description 1
- 239000003623 enhancer Substances 0.000 description 1
- 239000003344 environmental pollutant Substances 0.000 description 1
- 239000002803 fossil fuel Substances 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 231100000719 pollutant Toxicity 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
Images
Classifications
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F01—MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
- F01D—NON-POSITIVE DISPLACEMENT MACHINES OR ENGINES, e.g. STEAM TURBINES
- F01D15/00—Adaptations of machines or engines for special use; Combinations of engines with devices driven thereby
- F01D15/10—Adaptations for driving, or combinations with, electric generators
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/34—Chemical or biological purification of waste gases
- B01D53/74—General processes for purification of waste gases; Apparatus or devices specially adapted therefor
- B01D53/86—Catalytic processes
- B01D53/8643—Removing mixtures of carbon monoxide or hydrocarbons and nitrogen oxides
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F17—STORING OR DISTRIBUTING GASES OR LIQUIDS
- F17C—VESSELS FOR CONTAINING OR STORING COMPRESSED, LIQUEFIED OR SOLIDIFIED GASES; FIXED-CAPACITY GAS-HOLDERS; FILLING VESSELS WITH, OR DISCHARGING FROM VESSELS, COMPRESSED, LIQUEFIED, OR SOLIDIFIED GASES
- F17C13/00—Details of vessels or of the filling or discharging of vessels
- F17C13/04—Arrangement or mounting of valves
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F17—STORING OR DISTRIBUTING GASES OR LIQUIDS
- F17C—VESSELS FOR CONTAINING OR STORING COMPRESSED, LIQUEFIED OR SOLIDIFIED GASES; FIXED-CAPACITY GAS-HOLDERS; FILLING VESSELS WITH, OR DISCHARGING FROM VESSELS, COMPRESSED, LIQUEFIED, OR SOLIDIFIED GASES
- F17C9/00—Methods or apparatus for discharging liquefied or solidified gases from vessels not under pressure
- F17C9/02—Methods or apparatus for discharging liquefied or solidified gases from vessels not under pressure with change of state, e.g. vaporisation
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F23—COMBUSTION APPARATUS; COMBUSTION PROCESSES
- F23C—METHODS OR APPARATUS FOR COMBUSTION USING FLUID FUEL OR SOLID FUEL SUSPENDED IN A CARRIER GAS OR AIR
- F23C7/00—Combustion apparatus characterised by arrangements for air supply
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2257/00—Components to be removed
- B01D2257/50—Carbon oxides
- B01D2257/502—Carbon monoxide
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F17—STORING OR DISTRIBUTING GASES OR LIQUIDS
- F17C—VESSELS FOR CONTAINING OR STORING COMPRESSED, LIQUEFIED OR SOLIDIFIED GASES; FIXED-CAPACITY GAS-HOLDERS; FILLING VESSELS WITH, OR DISCHARGING FROM VESSELS, COMPRESSED, LIQUEFIED, OR SOLIDIFIED GASES
- F17C2221/00—Handled fluid, in particular type of fluid
- F17C2221/01—Pure fluids
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F17—STORING OR DISTRIBUTING GASES OR LIQUIDS
- F17C—VESSELS FOR CONTAINING OR STORING COMPRESSED, LIQUEFIED OR SOLIDIFIED GASES; FIXED-CAPACITY GAS-HOLDERS; FILLING VESSELS WITH, OR DISCHARGING FROM VESSELS, COMPRESSED, LIQUEFIED, OR SOLIDIFIED GASES
- F17C2221/00—Handled fluid, in particular type of fluid
- F17C2221/03—Mixtures
- F17C2221/032—Hydrocarbons
- F17C2221/033—Methane, e.g. natural gas, CNG, LNG, GNL, GNC, PLNG
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F17—STORING OR DISTRIBUTING GASES OR LIQUIDS
- F17C—VESSELS FOR CONTAINING OR STORING COMPRESSED, LIQUEFIED OR SOLIDIFIED GASES; FIXED-CAPACITY GAS-HOLDERS; FILLING VESSELS WITH, OR DISCHARGING FROM VESSELS, COMPRESSED, LIQUEFIED, OR SOLIDIFIED GASES
- F17C2227/00—Transfer of fluids, i.e. method or means for transferring the fluid; Heat exchange with the fluid
- F17C2227/01—Propulsion of the fluid
- F17C2227/0128—Propulsion of the fluid with pumps or compressors
- F17C2227/0135—Pumps
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F17—STORING OR DISTRIBUTING GASES OR LIQUIDS
- F17C—VESSELS FOR CONTAINING OR STORING COMPRESSED, LIQUEFIED OR SOLIDIFIED GASES; FIXED-CAPACITY GAS-HOLDERS; FILLING VESSELS WITH, OR DISCHARGING FROM VESSELS, COMPRESSED, LIQUEFIED, OR SOLIDIFIED GASES
- F17C2227/00—Transfer of fluids, i.e. method or means for transferring the fluid; Heat exchange with the fluid
- F17C2227/03—Heat exchange with the fluid
- F17C2227/0302—Heat exchange with the fluid by heating
Landscapes
- Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- General Engineering & Computer Science (AREA)
- Chemical & Material Sciences (AREA)
- Environmental & Geological Engineering (AREA)
- Biomedical Technology (AREA)
- Health & Medical Sciences (AREA)
- Analytical Chemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Combustion & Propulsion (AREA)
- Exhaust Gas After Treatment (AREA)
Abstract
The invention provides an ammonia-hydrogen-methane multi-substance mixed heat and electricity supply system and a using method thereof, belonging to the field of cogeneration. The problem of poor ammonia ignition performance is solved. The utility model provides an ammonia-hydrogen-methane multi-material mixes heat supply and produces electric system includes the compressor, the combustion chamber, the turbine, the generator, the liquid ammonia storage tank, the natural gas storage tank, the stop valve, the pump, the evaporation chamber, the admission valve, the flow divider, chemical regenerator and valve controller, the exit end of compressor and the inlet end intercommunication of combustion chamber, the rotation output of turbine links to each other with the power input end of generator, the exit end of pump and the entrance point intercommunication of evaporation chamber, the exit end of evaporation chamber and the entrance point intercommunication of flow divider, the exit end of natural gas storage tank communicates with the entrance point of combustion chamber through the admission valve, the hot junction export of combustion chamber and the hot junction import of evaporation chamber communicate, stop valve, admission valve and flow divider all are connected with the valve controller electricity. It is mainly used for generating electricity by using ammonia-hydrogen-methane.
Description
Technical Field
The invention belongs to the field of cogeneration, and particularly relates to an ammonia-hydrogen-methane multi-substance mixed heat and electricity supply system and a using method thereof.
Background
With the background of increasing energy demand and carbon emission pressure, the search for clean carbon-free fuels is the current research focus; ammonia is used as a hydrogen-rich substance and is an ideal carrier of hydrogen energy, and zero carbon emission can be realized by combustion; on the other hand, ammonia can be produced from renewable energy sources, and is more convenient to store and transport compared with hydrogen; therefore, ammonia can be used as a promising renewable fuel in the field of cogeneration;
however, because ammonia is less reactive and ignition energy is higher than fossil fuels, the combustion rate is much lower than the corresponding value of conventional hydrogen-carbon fuels; the direct use of pure ammonia as fuel also causes the problems of difficult ignition, unstable combustion, insufficient combustion and the like, and simultaneously needs to control the emission of nitrogen oxides, so that fuels such as hydrogen, methane and the like are needed to be used as fuel enhancers to realize the continuous and stable combustion of ammonia, especially methane, which is used for power generation of a gas turbine for a long time;
the ammonia-methane mixture can be used from a green ammonia source and can also be used from a byproduct ammonia obtained in an industrial process, so that the ammonia/methane mixed fuel can be used for a gas turbine mixing system, and the design of an electricity generating system which can utilize the ammonia-methane mixture as a raw material and can improve the combustion efficiency and the electricity generating efficiency is a problem to be solved urgently.
Disclosure of Invention
In view of this, the present invention is directed to an ammonia-hydrogen-methane multi-substance hybrid heating power generation system and a method for using the same to solve the problem of poor ignition performance of ammonia.
In order to achieve the above object, according to an aspect of the present invention, an ammonia-hydrogen-methane multi-substance mixed heat and electricity supply system is provided, which includes a gas compressor, a combustion chamber, a turbine, an electric generator, a liquid ammonia storage tank, a natural gas storage tank, a stop valve, a pump, an evaporation chamber, an air inlet valve, a flow divider, a chemical heat regenerator and a valve controller, wherein an outlet of the gas compressor is communicated with an inlet of the combustion chamber, a gas outlet of the combustion chamber is communicated with an inlet of the turbine, a rotation output end of the turbine is connected with a power input end of the electric generator, an output end of the liquid ammonia storage tank is communicated with an inlet of the pump through the stop valve, an outlet of the pump is communicated with an inlet of the evaporation chamber, an outlet of the evaporation chamber is communicated with an inlet of the flow divider, two outlet of the flow divider are respectively communicated with an inlet of the chemical heat regenerator and a fuel inlet of the combustion chamber, a discharge end of the chemical heat regenerator is communicated with another fuel inlet of the combustion chamber, a tail gas of the turbine is communicated with an inlet of the chemical heat regenerator through the air inlet of the combustion chamber, a hot end of the combustion chamber is communicated with an outlet of the evaporation chamber, and the flow divider, the stop valve and the inlet of the chemical heat regenerator are electrically connected with the inlet of the chemical heat exchanger.
Furthermore, the power generation system further comprises a metering valve, a catalytic reduction device and a catalytic oxidation device, wherein the gas outlet end of the chemical regenerator is communicated with the inlet end of the catalytic reduction device through the metering valve, and the output end of the catalytic reduction device is communicated with the inlet end of the catalytic oxidation device.
Furthermore, the valve controller is electrically connected with the metering valve.
Furthermore, the opening degrees of the stop valve, the air inlet valve, the flow dividing valve and the metering valve can be adjusted.
Furthermore, a reforming chamber capable of performing ammonia decomposition reforming reaction is arranged in the chemical regenerator.
Furthermore, the reaction product of the chemical regenerator is an ammonia-hydrogen-nitrogen mixture.
Furthermore, a nitrogen oxide selective reduction catalyst is arranged in the catalytic reduction device.
Further, the output product of the catalytic oxidation device is N 2 And CO 2 。
Further, the compressor is coaxially connected with the turbine.
According to another aspect of the invention, a method for supplying heat and generating electricity by using the ammonia-hydrogen-methane multi-substance mixture comprises the steps of introducing natural gas stored in a natural gas storage tank into a combustion chamber, premixing the natural gas with air compressed by an air compressor, igniting and combusting the natural gas, opening a stop valve after the combustion is stable, introducing liquid ammonia in a pumping liquid ammonia storage tank into an evaporation chamber by using heat generated by the combustion chamber, heating and evaporating the liquid ammonia to obtain ammonia, dividing the ammonia into two paths by using a flow dividing valve, directly inputting one path of the ammonia into a fuel inlet end of the combustion chamber to be mixed with the air for combustion, inputting the other path of the ammonia into a chemical heat regenerator, carrying out thermal cracking by using waste heat recovered from turbine tail gas by the chemical heat regenerator, enabling the generated mixed gas of the ammonia, the hydrogen and the nitrogen to flow out from a discharge end of the chemical heat regenerator as supplementary fuel to be introduced into the combustion chamber to be mixed with the air for combustion, generating a large amount of tail gas after the fuel is combusted to drive a power generator to generate power by using a turbine, and sequentially introducing waste gas of the chemical heat regenerator into a catalytic reduction device and a catalytic oxidation device by using a metering valve to be treated and then discharged.
Compared with the prior art, the invention has the beneficial effects that:
1. the ammonia fuel and the hydrogen fuel mixed into the combustion chamber can replace part of the original methane fuel, so that the carbon emission of the system is effectively reduced;
2. the opening degrees of the stop valve, the air inlet valve and the flow dividing valve are controlled by the valve controller, and the gas component ratio entering the combustion chamber can be adjusted, so that the optimal combustion efficiency is achieved, and the power generation efficiency is improved;
3. the waste heat of the tail gas is collected by the chemical heat regenerator to carry out thermal cracking on part of the ammonia fuel, and the generated ammonia-hydrogen-nitrogen mixed gas is introduced into the combustion chamber for combustion, so that the heat required by the reaction is reduced compared with the original direct combustion of the part of the ammonia fuel;
4. the catalytic reduction device and the catalytic oxidation device are used for respectively treating pollutants such as nitrogen oxides, carbon monoxide and the like in the tail gas, so that the pollution to the environment is greatly reduced.
Drawings
The accompanying drawings, which are incorporated in and constitute a part of this specification, illustrate an embodiment of the invention and, together with the description, serve to explain the invention and not to limit the invention. In the drawings:
FIG. 1 is a schematic structural diagram of an AMH multi-substance hybrid heating and power generation system according to the present invention.
A compressor 1; a combustion chamber 2; a turbine 3; a generator 4; a liquid ammonia storage tank 5; a natural gas storage tank 6; a stop valve 7; a pump 8; an evaporation chamber 9; an intake valve 10; a flow divider valve 11; a chemical regenerator 12; a valve controller 13; a metering valve 14; a catalytic reduction device 15; a catalytic oxidation unit 16.
Detailed Description
The technical solutions in the embodiments of the present invention will be clearly and completely explained below with reference to the drawings in the embodiments of the present invention. It should be noted that, in the present invention, the embodiments and features of the embodiments may be combined with each other without conflict, and the described embodiments are only a part of the embodiments of the present invention, not all of the embodiments.
Referring to the drawings for illustrating the present embodiment, according to one aspect of the present invention, there is provided an ammonia-hydrogen-methane multi-substance hybrid heating and power generation system, comprising a compressor 1, a combustion chamber 2, a turbine 3, a generator 4, a liquid ammonia storage tank 5, a natural gas storage tank 6, a stop valve 7, a pump 8, an evaporation chamber 9, an air intake valve 10, a flow divider valve 11, a chemical regenerator 12, a valve controller 13, a metering valve 14, a catalytic reduction device 15 and a catalytic oxidation device 16, the outlet end of the compressor 1 is communicated with the air inlet end of the combustion chamber 2, the gas outlet end of the combustion chamber 2 is communicated with the inlet end of the turbine 3, the rotating output end of the turbine 3 is connected with the power input end of the generator 4, the output end of the liquid ammonia storage tank 5 is communicated with the inlet end of the pump 8 through a stop valve 7, the outlet end of the pump 8 is communicated with the inlet end of an evaporation chamber 9, the outlet end of the evaporation chamber 9 is communicated with the inlet end of a flow dividing valve 11, two outlet ends of the flow dividing valve 11 are respectively communicated with a feeding end of the chemical heat regenerator 12 and a fuel inlet end of the combustion chamber 2, the discharge end of the chemical regenerator 12 is communicated with the other fuel inlet end of the combustion chamber 2, the tail gas discharge outlet of the turbine 3 is communicated with the gas inlet end of the chemical regenerator 12, the outlet end of the natural gas storage tank 6 is communicated with the inlet end of the combustion chamber 2 through an air inlet valve 10, the hot end outlet of the combustion chamber 2 is communicated with the hot end inlet of the evaporation chamber 9, the gas outlet end of the chemical regenerator 12 is communicated with the inlet end of a catalytic reduction device 15 through a metering valve 14, the output end of the catalytic reduction device 15 is communicated with the inlet end of the catalytic oxidation device 16, and the stop valve 7, the air inlet valve 10, the flow divider valve 11 and the metering valve 14 are all electrically connected with the valve controller 13.
In this embodiment, the opening degrees of the stop valve 7, the intake valve 10, the flow dividing valve 11 and the metering valve 14 can be adjusted, so as to facilitate the adjustment of the gas component ratios in the combustion chamber 2, thereby improving the combustion efficiency in the combustion chamber 2, improving the output efficiency of the fuel due to high combustion efficiency, and thus enabling the fuel entering the turbine 3 to generate more mechanical energy after reaction, thereby driving the generator 4 to generate more electric energy in unit time.
In this embodiment, the chemical regenerator 12 is provided with a reforming chamber capable of performing ammonia decomposition reforming reaction, so as to facilitate ammonia decomposition.
In this embodiment, the catalytic reduction device 15 is provided with a nitrogen oxide selective reduction catalyst to facilitate the reduction reaction.
In this embodiment, the compressor 1 and the turbine 3 are coaxially connected to each other, so as to perform a power utilization function, thereby improving the energy utilization rate.
According to another aspect of the invention, a method for supplying heat and power by using the ammonia-hydrogen-methane multi-substance mixture is provided, which comprises introducing natural gas stored in a natural gas storage tank 6 into a combustion chamber 2, premixing the natural gas with air compressed by an air compressor 1, igniting and combusting the natural gas, opening a stop valve 7 after the combustion is stable, pumping liquid ammonia in a liquid ammonia storage tank 5 by using a pump 8, introducing the liquid ammonia into an evaporation chamber 9, heating and evaporating the liquid ammonia by heat generated by the combustion chamber 2 to obtain ammonia gas, dividing the ammonia gas into two paths by a flow dividing valve 11, directly inputting one path of the ammonia gas into a fuel inlet end of the combustion chamber 2 to be mixed with the air for combustion, inputting the other path of the ammonia gas into a chemical regenerator 12, thermally cracking the ammonia gas by using waste heat recovered from turbine 3 by the chemical regenerator 12, allowing the generated mixed gas of the ammonia, the hydrogen and the nitrogen to flow out from a discharge end of the chemical regenerator 12 as supplementary fuel, introducing the supplementary fuel into the combustion chamber 2 to be mixed with the air for combustion, generating a large amount of tail gas generated after the fuel is combusted, driving a generator 4 to generate power by the turbine 3 to generate power, and discharging the waste gas of the chemical regenerator 12 after being sequentially treated by a catalytic reduction device 15 and a catalytic oxidation device 16 through a metering valve 14.
The embodiments of the invention disclosed above are intended merely to aid in the explanation of the invention. The examples are not intended to be exhaustive or to limit the invention to the precise forms disclosed. Many modifications and variations are possible in light of the above teaching. The embodiments were chosen and described in order to best explain the principles of the invention and the practical application, to thereby enable others skilled in the art to best utilize the invention.
Claims (10)
1. The utility model provides an electricity system is produced in many material mixture heating of ammonia hydrogen methane which characterized in that: comprises a gas compressor (1), a combustion chamber (2), a turbine (3), a generator (4), a liquid ammonia storage tank (5), a natural gas storage tank (6), a stop valve (7), a pump (8), an evaporation chamber (9), an air inlet valve (10), a flow divider valve (11), a chemical heat regenerator (12) and a valve controller (13), wherein the outlet end of the gas compressor (1) is communicated with the air inlet end of the combustion chamber (2), the gas outlet end of the combustion chamber (2) is communicated with the inlet end of the turbine (3), the rotation output end of the turbine (3) is connected with the power input end of the generator (4), the output end of the liquid ammonia storage tank (5) is communicated with the inlet end of the pump (8) through the stop valve (7), the exit end of pump (8) and the entrance point intercommunication of evaporating chamber (9), the exit end of evaporating chamber (9) and the entrance point intercommunication of flow divider valve (11), two exit ends of flow divider valve (11) communicate with the pan feeding end of chemical regenerator (12) and a fuel entry end of combustion chamber (2) respectively, the discharge end of chemical regenerator (12) and another fuel entry end intercommunication of combustion chamber (2), the tail gas discharge mouth of turbine (3) and the inlet end intercommunication of chemical regenerator (12), the exit end of natural gas storage tank (6) is through admission valve (10) and the entrance end intercommunication of combustion chamber (2) The inlet end is communicated, the hot end outlet of the combustion chamber (2) is communicated with the hot end inlet of the evaporation chamber (9), and the stop valve (7), the air inlet valve (10) and the flow dividing valve (11) are electrically connected with the valve controller (13).
2. The system according to claim 1, wherein the system comprises: the power generation system further comprises a metering valve (14), a catalytic reduction device (15) and a catalytic oxidation device (16), the gas outlet end of the chemical heat regenerator (12) is communicated with the inlet end of the catalytic reduction device (15) through the metering valve (14), and the output end of the catalytic reduction device (15) is communicated with the inlet end of the catalytic oxidation device (16).
3. The system according to claim 2, wherein the system comprises: the valve controller (13) is electrically connected with the metering valve (14).
4. The system according to claim 3, wherein the system comprises: the opening degrees of the stop valve (7), the air inlet valve (10), the flow dividing valve (11) and the metering valve (14) can be adjusted.
5. The system according to claim 2, wherein the system comprises: the chemical regenerator (12) is provided with a reforming chamber capable of carrying out ammonia decomposition reforming reaction.
6. The system according to claim 5, wherein the system comprises: the reaction product of the chemical heat regenerator (12) is ammonia-hydrogen-nitrogen mixed gas.
7. The system according to claim 2, wherein the system comprises: and a nitrogen oxide selective reduction catalyst is arranged in the catalytic reduction device (15).
8. The system according to claim 1, wherein the system comprises: the output product of the catalytic oxidation device (16) is N 2 And CO 2 。
9. The system according to claim 1, wherein the system comprises: the compressor (1) is coaxially connected with the turbine (3).
10. A method of using the amhydromethane multi-substance hybrid heating power generation system according to any one of claims 1 to 9, characterized in that: the method comprises the steps that natural gas stored in a natural gas storage tank (6) is introduced into a combustion chamber (2) to be premixed with air compressed by a compressor (1) and ignited for combustion, after combustion is stable, a stop valve (7) is opened, liquid ammonia in a liquid ammonia storage tank (5) is extracted by a pump (8) and introduced into an evaporation chamber (9) to be heated and evaporated by heat generated by the combustion chamber (2) to obtain ammonia, the ammonia is divided into two paths by a flow divider valve (11), one path of ammonia is directly input into a fuel inlet end of the combustion chamber (2) to be mixed with the air for combustion, the other path of ammonia enters a chemical heat regenerator (12), waste heat recovered from tail gas of a turbine (3) by the chemical heat regenerator (12) is used for thermal cracking, a generated mixed gas of ammonia, hydrogen and nitrogen flows out of a discharge end of the chemical heat regenerator (12) to serve as supplementary fuel to be introduced into the combustion chamber (2) to be mixed with the air for combustion, a large amount of the tail gas generated after the fuel is combusted, the tail gas is used for acting through the turbine (3) to drive a generator (4) to generate electricity, and the waste gas of the chemical heat regenerator (12) sequentially enters a catalytic reduction device (15) and a catalytic oxidation device (16) to be treated by a metering valve (16), and then is discharged.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN202210839686.8A CN115341963A (en) | 2022-07-18 | 2022-07-18 | Ammonia-hydrogen-methane multi-substance mixed heat supply and electricity generation system and use method thereof |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN202210839686.8A CN115341963A (en) | 2022-07-18 | 2022-07-18 | Ammonia-hydrogen-methane multi-substance mixed heat supply and electricity generation system and use method thereof |
Publications (1)
Publication Number | Publication Date |
---|---|
CN115341963A true CN115341963A (en) | 2022-11-15 |
Family
ID=83950804
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CN202210839686.8A Pending CN115341963A (en) | 2022-07-18 | 2022-07-18 | Ammonia-hydrogen-methane multi-substance mixed heat supply and electricity generation system and use method thereof |
Country Status (1)
Country | Link |
---|---|
CN (1) | CN115341963A (en) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US20220275759A1 (en) * | 2019-08-26 | 2022-09-01 | 8 Rivers Capital, Llc | Flame control in an oxyfuel combustion process |
Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
RU2015148800A (en) * | 2015-11-13 | 2017-05-23 | Федеральное государственное бюджетное учреждение "Национальный исследовательский центр "Курчатовский институт" | ENERGY CONVERSION METHOD |
CN107100736A (en) * | 2017-06-09 | 2017-08-29 | 厦门大学 | Combustion turbine combined system |
US20190084831A1 (en) * | 2016-03-14 | 2019-03-21 | Equinor Energy As | Ammonia cracking |
CN110300840A (en) * | 2017-03-27 | 2019-10-01 | 株式会社Ihi | Burner and gas turbine engine system |
CN113389699A (en) * | 2020-03-11 | 2021-09-14 | 张建城 | Solar energy and wind energy and ammonia oxygen gas complementary circulation thermal power generation device |
-
2022
- 2022-07-18 CN CN202210839686.8A patent/CN115341963A/en active Pending
Patent Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
RU2015148800A (en) * | 2015-11-13 | 2017-05-23 | Федеральное государственное бюджетное учреждение "Национальный исследовательский центр "Курчатовский институт" | ENERGY CONVERSION METHOD |
US20190084831A1 (en) * | 2016-03-14 | 2019-03-21 | Equinor Energy As | Ammonia cracking |
CN110300840A (en) * | 2017-03-27 | 2019-10-01 | 株式会社Ihi | Burner and gas turbine engine system |
CN107100736A (en) * | 2017-06-09 | 2017-08-29 | 厦门大学 | Combustion turbine combined system |
CN113389699A (en) * | 2020-03-11 | 2021-09-14 | 张建城 | Solar energy and wind energy and ammonia oxygen gas complementary circulation thermal power generation device |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US20220275759A1 (en) * | 2019-08-26 | 2022-09-01 | 8 Rivers Capital, Llc | Flame control in an oxyfuel combustion process |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
CN109193009B (en) | Solid oxide fuel cell composite system and method of use | |
CN102456898B (en) | Fuel battery combustion turbine co-generation unit | |
CN103311560B (en) | Solid oxide fuel cell power generating system and battery pile thereof | |
EP1231183B1 (en) | Fuel reformer system | |
AU3311499A (en) | Integrated power module | |
CN110544785A (en) | natural gas self-heating reforming proton exchange membrane fuel cell distributed cogeneration system and method | |
CN108400358A (en) | Solid oxide fuel cell oven gas electrification technique and device | |
WO2017000626A1 (en) | Self-contained hydrogen fuel cell system and operation method thereof | |
CN115199442A (en) | Engine system based on plasma-assisted ammonia combustion and ammonia catalytic cracking | |
CN115341963A (en) | Ammonia-hydrogen-methane multi-substance mixed heat supply and electricity generation system and use method thereof | |
JPH02226666A (en) | Automatic temperature/ power control of high temperature fuel cell | |
CN115234905A (en) | Combustion system and method for ammonia decomposition hydrogen production blended combustion of ammonia gas | |
CN210103450U (en) | Efficient hydrogen production device and methanol water instant hydrogen production system using same | |
CN114471401A (en) | Brayton cycle system and method based on chemical regenerative ammonia source partial cracking | |
Wang et al. | Comparison of the exergy efficiency of four power generation systems from methane using fuel cells | |
CN114843551B (en) | Fuel processor and hydrogen production method | |
CN112864432B (en) | System and method for generating power by using synthesis gas high-temperature fuel cell | |
CN114665120B (en) | SOFC-GT hybrid power generation system based on multi-type fuel | |
CN220796812U (en) | Fuel cell cogeneration system for oilfield exploitation | |
Azegami | MCFC/MGT hybrid generation system | |
CN218241898U (en) | Fuel cell power generation system | |
CN215220773U (en) | Alcohol-hydrogen fuel power system and power generation device | |
CN115234370B (en) | System and method for small vehicle-mounted methanol reforming hydrogen production combined internal combustion engine | |
CN113607841B (en) | Reformer testing device and method of solid oxide fuel cell system | |
CN220745386U (en) | Natural gas hydrogen production equipment |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
PB01 | Publication | ||
PB01 | Publication | ||
SE01 | Entry into force of request for substantive examination | ||
SE01 | Entry into force of request for substantive examination |