CN115317387B - Cleansing cream and preparation method thereof - Google Patents

Cleansing cream and preparation method thereof Download PDF

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Publication number
CN115317387B
CN115317387B CN202211168353.3A CN202211168353A CN115317387B CN 115317387 B CN115317387 B CN 115317387B CN 202211168353 A CN202211168353 A CN 202211168353A CN 115317387 B CN115317387 B CN 115317387B
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cleansing cream
grease
cleansing
nonionic emulsifier
cream
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CN115317387A (en
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钟玉容
徐小建
潘美红
严二平
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Guangzhou Natural State Biotechnology Co ltd
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Guangzhou Natural State Biotechnology Co ltd
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    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/18Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/33Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
    • A61K8/37Esters of carboxylic acids
    • A61K8/375Esters of carboxylic acids the alcohol moiety containing more than one hydroxy group
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/18Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/31Hydrocarbons
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/18Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/33Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
    • A61K8/37Esters of carboxylic acids
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/18Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/33Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
    • A61K8/39Derivatives containing from 2 to 10 oxyalkylene groups
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/18Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/49Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing heterocyclic compounds
    • A61K8/4973Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing heterocyclic compounds with oxygen as the only hetero atom
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/18Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/72Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/84Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions otherwise than those involving only carbon-carbon unsaturated bonds
    • A61K8/86Polyethers
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61QSPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q1/00Make-up preparations; Body powders; Preparations for removing make-up
    • A61Q1/14Preparations for removing make-up
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K2800/00Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
    • A61K2800/40Chemical, physico-chemical or functional or structural properties of particular ingredients
    • A61K2800/48Thickener, Thickening system
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K2800/00Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
    • A61K2800/40Chemical, physico-chemical or functional or structural properties of particular ingredients
    • A61K2800/59Mixtures
    • A61K2800/592Mixtures of compounds complementing their respective functions

Abstract

The invention belongs to the technical field of daily chemicals, and discloses a makeup removing cream which comprises grease, a nonionic emulsifier, an oil phase thickener and water; the grease consists of the following components: isononanoate and/or isononyl isononanoate, neopentyl glycol dioctanoate/dicaprate, cetyl ethyl hexanoate, glycerol tri (ethyl hexanoate) and propyl heptanoate; the grease accounts for 65-75wt% of the total weight of the cleansing cream; the nonionic emulsifier consists of the following components: sorbitol polyether-30 tetraisostearate, PEG-10 isostearate, sorbitan sesquioleate; the nonionic emulsifier accounts for 18-23 wt% of the total weight of the cleansing cream. The cleansing cream meets four requirements of fresh use, high-efficiency cleansing, mildness, no stimulation and high-temperature stability, and is suitable for all skin types of all ages, particularly pregnant women.

Description

Cleansing cream and preparation method thereof
Technical Field
The invention relates to the field of daily chemical materials, in particular to a cleansing cream and a preparation method thereof.
Background
With the temperature rise of the color make-up market, the potential of the make-up removal product is also released rapidly. It is expected that with the increasing health consciousness of residents and the increasing living standard, more and more female consumers will use makeup removing products, and the importance of the makeup removing products in cosmetics is increasingly prominent, and the market demand of the makeup removing products is also increasing. According to the different makeup removing principles, the makeup removing product can be further divided into makeup removing water/liquid, makeup removing oil, makeup removing cream, makeup removing emulsion, makeup removing gel, makeup removing wet tissues and the like. The research report of the authorities shows that the market share of the online makeup remover is being transferred to the types of makeup remover, makeup remover wet tissues and the like. The cleansing cream is popular among all brands as cleansing cream which is convenient to carry, combines washing and cleansing and can remove concentrated makeup rapidly. In the face of new consumer complaints and new consumption scenes, on the basis of urban high-rhythm life pressure background, new products of the makeup removal cream need to be continuously optimized and innovated in terms of factors such as using freshness, makeup removal capability, emulsification cleaning effect or external packing design, for example, the product is declared to be clean without intentional emulsification by the primary explosion type single-product bilberry moringa seed makeup removal cream; the cream can be emulsified for 3 seconds when in use, can be cleaned for one time and achieves the subtle balance of cleaning force and temperature; for example, the Mikania micrantha grease cleansing cream is declared to be body-feel cleansing cream, and small molecular grease penetrates into pores to wrap cleansing residues, so that the cleansing residues are emulsified for one second and secondary cleaning is not needed.
Make-up removal products can be broadly divided into make-up removal oils/creams and make-up removal ointments;
make-up removal oil/cream can be referred to the following comparison document:
d1: CN201811065987 discloses a cleansing emulsion containing PEG-12 monolaurate and a preparation method thereof. The cleansing emulsion consists of the following components: 13 to 17 percent of PEG-12 monolaurate, 4 to 6 percent of isononyl isononanoate, 2 to 4 percent of cetyl ethyl hexanoate, 1 to 3 percent of polyglycerol-2 triisostearate, 0.2 to 0.4 percent of thickening agent, 10 to 12 percent of humectant, 2 to 3 percent of emulsifying agent, 0.1 to 0.4 percent of pH regulator, 0.5 to 1.5 percent of oat kernel extract, 0.5 to 1.5 percent of bradykinin Calmin, 0 to proper amount of preservative, 0 to proper amount of essence, 0 to proper amount of pigment, the balance of water and pH of 6.5 to 7.0.
The emulsifying agent is as follows: one or two of C20-22 alcohol phosphate ester/C20-22 alcohol and polyacrylamide/C13-14 isoparaffin/laureth-7.
D2: CN202010094991 discloses a bicontinuous phase type eye lip cleansing lotion and a preparation method thereof, wherein the cleansing lotion comprises the following components in percentage by mass: 15-35% of PEG-20 triisostearate, 5-15% of sorbitol polyether-30 tetraisostearate, 10-25% of emollient and 10-35% of deionized water; wherein the mass ratio of deionized water to the emollient is 0.5-2;
the description is as follows: the cleansing liquid comprises the following emollients in percentage by mass: 5 to 20 percent of ethylhexyl palmitate, 1 to 10 percent of isotridecyl isononanoate and 1 to 10 percent of cyclopentadimethicone;
the emulsifying agent is as follows: PEG-20 Triisostearate, sorbitol polyether-30 Tetraisostearate.
D3: CN202010991015 discloses a foam cleansing liquid and a preparation method thereof. The foam cleansing liquid comprises the following components in percentage by mass: 3-8% of lauroyl oat amino acid sodium, 1-4% of sophorolipid, 3-5% of 1-carboxyl-N, N, N-trimethyl-1-pentadecyl ammonium inner salt, 8-16% of tridecyl alcohol stearate, 6-12% of neopentyl glycol dicaprylate/dicaprate, 4-9% of theophylline methyl silanol mannuronate, 10-15% of dipropylene glycol, 20-30% of Asian white birch juice and the balance of water.
D4: CN202110988140 discloses a cleansing oil for relieving inflammation and a preparation method thereof. The raw materials of the cleansing oil comprise 2-10wt% of active ingredients and 90-98wt% of main ingredients, wherein the active ingredients comprise an aqueous emulsifier and water-soluble active matters, and the specification records: the main components comprise vegetable oil and synthetic oil; the weight ratio of the vegetable oil to the synthetic oil is 1: (0.8-3); the synthetic oil is at least one selected from propylene glycol dicaprylate/dicaprate, triglyceride, caprylic/capric triglyceride, pentaerythritol tetra (ethylhexanoate), isopropyl myristate, tridecyl trimellitate, diisopropyl sebacate, tricitrate, triisostearate of glycerol, oleyl erucate, isononyl isononanoate, octapalmitate, tocopheryl acetate, decyl cocoate, cocoyl-caprylate/caprate, isopropyl isostearate, propyl heptyl caprylate, C15-19 alkane, tri (ethylhexanoate) glycerol, and dioctyl butylene glycol dicaprylate/dicaprate carbonate.
D5: CN202111528231 discloses a cleansing oil of polyglycerol emulsifier, comprising: ethylhexyl palmitate, polyglycerol-6-dicaprate, glycerol tri (ethylhexanoate), polyglycerol-10-dioleate, caprylic/capric triglyceride, bilberry seed oil, white pool seed oil, sweet orange peel oil, squalane, pentaerythritol tetraester, nanocellulose.
D6: CN202210292272 discloses a bicontinuous cleansing oil, which comprises the following raw materials in percentage by mass: c9-12 alkane, cetyl alcohol ethyl hexanoate, neopentyl glycol di (ethyl hexanoate), caprylic/capric triglyceride, C13-16 isoparaffin, sorbitol poly (riddle-30 tetraoleate), PEG-7 glycerol cocoate, PEG-8 diisostearate, sorbitan sesquioleate, butylene glycol dicaprylate/dicaprate, and the like.
The emulsifying agent is as follows: sorbitol poly (riddle-30) tetraoleate, PEG-7 glycerol cocoate, PEG-8 diisostearate, sorbitan sesquioleate.
D7: CN202210378249 discloses a cleansing cream, which comprises the following components in percentage by mass: 8-35% of nonionic surfactant, 20-75% of grease, 5-25% of humectant and the balance of water; the nonionic surfactant has an overall HLB value of from 8 to 13.
The description is as follows: the ester oil is selected from one or more of isononyl isononanoate, ethylhexyl palmitate, cetyl ethyl hexanoate, neopentyl glycol di (ethyl hexanoate), neopentyl glycol di (decanoate), glycerol tri (ethyl hexanoate), caprylic/capric triglyceride, triisostearin, pentaerythritol tetra (ethyl hexanoate), pentaerythritol tetraisostearate, octyl dodecanoate, cetyl stearyl ethyl hexanoate, cetostearyl isononanoate, diethyl hexyl adipate, cetyl stearyl isononanoate, diethyl hexyl adipate, diisodecyl adipate, diisopropyl sebacate, ethylhexyl cocoate, ethylhexyl stearate, isopropyl isostearate, isopropyl myristate, isopropyl palmitate, neopentyl glycol dicaprylate/dicaprate, propylene glycol dicaprylate/dicaprate, triisononin, ethylhexyl isononanoate, ethylhexyl nonanoate.
The nonionic surfactant is selected from two or more of polyethylene glycol glyceride, hydrogenated castor oil, and polyglycerol fatty acid esters. The nonionic surfactant HLB interval is expected to be 8-13, wherein the chemical structure and physicochemical properties of the polyglycerin fatty acid ester are related to the polymerization degree, fatty acid type and esterification degree of the polyglycerin, meanwhile, the emulsifying property of the polyglycerin fatty acid ester is related to the hydrophilic-lipophilic balance value (hydrophile lipophilic balance, HLB value), and the HLB value can be 2-16 according to the polymerization degree, fatty acid carbon chain length and esterification degree of the polyglycerin, namely the polyglycerin fatty acid ester can be used as a hydrophilic emulsifier or a lipophilic emulsifier. The polyglycerin-3 polyricinoleate mentioned in the patent document has a longer fatty acid carbon chain parent end and a smaller glycerin polymerization degree hydrophilic end, the actual HLB value is generally about 3, and the actual HLB value does not accord with the target value of the interval 8-13.
The make-up remover has relatively few comparative documents, and reference is made to the following documents:
d8: CN201510266286 discloses a mild no-clean cleansing cream, which is characterized by comprising the following components in percentage by weight: 2 to 10 percent of polyethylene, 2 to 20 percent of cetyl alcohol ethyl caproate, 2 to 20 percent of PEG-10 isostearate, 2 to 20 percent of PEG-20 glycerol triisostearate, 0.2 to 1 percent of tocopheryl acetate, 2 to 10 percent of phenyl trimethicone, 0.2 to 3.0 percent of dextrin palmitate and the balance of caprylic acid/capric acid triglyceride.
The nonionic emulsifier is used, and is specifically PEG-20 glycerol triisostearate and PEG-10 isostearate. Both HLB values are about 11, the dissolution strength of polar synthetic oil is high, but the dissolution performance of the p-phenyl siloxane and the cyclic siloxane is poor, so that the residual oil film feeling after makeup removal is enhanced, and the freshness after makeup removal is reduced.
D9: 103191027a discloses a solid make-up remover with warm feel in use, wherein more than 15% of polyol is added in the formula to enable the make-up remover to generate warm feel when contacting skin through hydration, and a polyol thickener of polyglycerol-10 behenate/eicosanedioate is added to thicken the polyol, so that the polyol with high addition amount can be mixed with other oil components to be solidified and stabilized. Thus, the formula finally presents a thicker appearance and has a much more sticky feel than conventional cleansing cream. On the other hand, the melting point range of the formula of the cleansing cream is 38-48 ℃, which cannot meet the domestic daily transportation and storage requirements, and has high sealing performance requirement on matched packaging materials, thus being not beneficial to expanding production.
D10: 105581939A discloses a massage makeup removing cream, which utilizes two hydrophilic emulsifiers of PEG-20 triisostearate and polysorbate-85 to mix various oils so as to dissolve makeup residues and achieve the use effect of emulsification and flushing. The HLB value of the hydrophilic-lipophilic balance value of the two hydrophilic emulsifiers is 11, and the low-polarity grease such as mineral oil or cyclomethicone with a small content is added in the patent formula, so that the compatibility of the matched emulsifiers and grease is poor according to the similar compatibility principle, the actual emulsification cleaning effect is poor after the makeup is melted, and the oil film feel heavy on the face and feel not fresh.
In summary, D1-D10, the oils and fats that are widely used in make-up removal oils/creams/pastes include, but are not limited to:
PEG-12 monolaurate, isononyl isononanoate, cetyl ethyl hexanoate, polyglycerol-2 triisostearate, ethylhexyl palmitate, isotridecyl isononanoate, propylene glycol dicaprylate/dicaprate, triglycerides, caprylic/capric triglycerides, pentaerythritol tetra (ethylhexanoate), isopropyl myristate, tridecyl trimellitate, diisopropyl sebacate, tricitrate, triisostearate, oleyl erucate, isononyl isononanoate, octapalmitate, tocopheryl acetate, decyl cocoate, cocoyl-caprylate/caprate, isopropyl isostearate, propyl heptyl octoate, C15-19 alkyl, tri (ethylhexanoate), butylene glycol dicaprylate/dicaprate dioctyl carbonate ethylhexyl palmitate, polyglycerol-6-dicaprate, glycerol triethylhexanoate, polyglycerol-10-dioleate, caprylic/capric triglyceride, C9-12 alkane, neopentyl glycol di (ethylhexanoate), caprylic/capric triglyceride, C13-16 isoparaffin, sorbitol poly (riddle-30 tetraoleate), PEG-7 glycerol cocoate, PEG-8 diisostearate, sorbitan sesquioleate, butanediol dicaprylate/dicaprate, isononyl isononanoate, isotridecyl isononanoate, ethylhexyl palmitate, neopentyl glycol dicaprate, caprylic/capric triglyceride, triisostearin, pentaerythritol tetra (ethylhexanoate), pentaerythritol tetraisostearate, octyl dodecanol lactate, cetyl stearyl ethyl hexanoate, cetylstearyl isononanoate, diethylhexyl adipate, diisodecyl adipate, diisopropyl sebacate, ethylhexyl cocoate, ethylhexyl stearate, isopropyl isostearate, isopropyl myristate, isopropyl palmitate, neopentyl glycol dicaprylate/dicaprate, propylene glycol dicaprylate/dicaprate, triisononin, ethylhexyl isononanoate, ethylhexyl pelargonate, PEG-10 isostearate, PEG-20 glycerol triisostearate.
Optional emulsifiers include, but are not limited to: c20-22 alcohol phosphate, C20-22 alcohol and polyacrylamide, C13-14 isoparaffin, laureth-7, PEG-20 glyceryl triisostearate, sorbitol polyether-30 tetraisostearate, sorbitol poly-riddle-30 tetraoleate, PEG-7 glyceryl cocoate, PEG-8 diisostearate, sorbitan sesquioleate, polyethylene glycol glyceryl fatty acid esters, polyethylene glycol hydrogenated castor oil, polyglycerol fatty acid esters, PEG-10 isostearate.
The oil and the emulsifier in the cleansing cream are more carefully selected, and the cleansing cream is easy to leak oil at 45 ℃ and 50 ℃, and meanwhile, the cleansing cream has the problems of poor skin feel, poor emulsification cleaning force, poor mildness and the like during cleansing.
Disclosure of Invention
The invention aims to provide a cleansing cream which meets four requirements of fresh use, high-efficiency cleansing, mildness, no stimulation and high-temperature stability, and is suitable for all skin types of all ages, particularly pregnant women.
Meanwhile, the invention also provides a preparation method of the cleansing cream.
Unless otherwise specified, M represents mol/liter; % and wt% both represent weight percentages and parts represent parts by weight.
In order to achieve the above purpose, the present invention provides the following technical solutions: a cleansing cream comprises oil, nonionic emulsifier, oil phase thickener, and water;
the grease comprises the following components in percentage by weight of the total weight of the cleansing cream:
isononanoate of isotridecyl alcohol and/or isononyl isononanoate 24-32wt%
16 to 24 weight percent of neopentyl glycol dicaprylate/dicaprate
8 to 12 weight percent of cetyl ethyl hexanoate
7 to 10 weight percent of glycerin tri (ethyl caproic acid) ester
3-5wt% of propyl heptyl octanoate;
the grease accounts for 65-75wt% of the total weight of the cleansing cream;
the nonionic emulsifier consists of the following components:
13-18 wt% of sorbitol polyether-30 tetraisostearate;
3-5 wt% of PEG-10 isostearate;
sorbitan sesquioleate 0.8-1.2 wt%;
the nonionic emulsifier accounts for 18-23 wt% of the total weight of the cleansing cream.
The functions of each component in the invention are as follows:
grease and oil
Selecting synthetic oil with low odor, small acid value and fresh skin feel, wherein the synthetic oil comprises isotridecyl isononanoate, cetyl alcohol ethyl caproate, propyl heptyl octoate, glycerol tri (ethyl caproate), neopentyl glycol di (ethyl caproate) and neopentyl glycol dicaprylate/dicaprate; and the grease with different polarities and spreading capacity is utilized to match to remove the oily residue of the makeup.
Isononanoate is a monoester composed of odd-numbered medium-carbon branched alcohol and odd-numbered medium-carbon branched fatty acid, is colorless and odorless, has good high-temperature stability, and belongs to synthetic oil with lower polarity. The use of the multi-branched fatty acid multi-branched alcohol has excellent solubility to silicone oils in make-up and sunscreens, and at the same time has a high spreading value, and a smooth feel to the skin.
Cetyl ethyl hexanoate is commonly called as sea bird feather oil, is an efficient waterproof emollient with excellent performance, has higher polarity, and can be almost mutually dissolved with all grease for cosmetics; and has the advantages of good air permeability, spreadability, dispersibility, moistening property and the like. After the application, the skin can be moistened and soft, and the pleasant skin feeling is not greasy.
Propyl heptyl octoate is a medium-polarity and extremely high-spreadability emollient with multidimensional soft feel, and can greatly reduce the greasy feel of the cleansing cream.
The triglyceride (ethyl caproate) is composed of glycerol and medium carbon branched fatty acid, has medium polarity, low freezing point (-30 ℃ below), is colorless and odorless, has good oxidation stability and hydrolysis stability, and has good compatibility with most of oils. The addition of the makeup removing cream formula is beneficial to improving the change of the freezing hardness and the service performance in a low-temperature environment.
The neopentyl glycol di (ethyl caproate) and the neopentyl glycol dicaprylate/dicaprate are both diester composed of neopentyl glycol and medium-chain branched fatty acid, have lower polarity, and have better compatibility with high-viscosity silicone oil due to a multi-branched structure, so that the application of the silicone oil to a makeup removing product is more beneficial to removing the residual sun-screening foundation.
Emulsifying agent
According to the similar principle of compatibility, the hydrophilic and lipophilic nonionic emulsifiers are matched, and different emulsifiers with thin skin feel, strong self-emulsifying capability, good flushing property and low color and smell are preferred, so that various hydrophilic or lipophilic components in the foundation make-up residue can be removed efficiently, the particle size of emulsion during flushing and self-emulsifying is reduced through reasonable matching, and the oil film feel after flushing is reduced. Particularly preferably, the sorbitol polyether-30 tetraisostearate and PEG-10 isostearate with HLB values of about 11 are selected, and the sorbitan sesquioleate with HLB values of about 5 is selected at the same time, so that the sorbitan sesquioleate can be optimally matched with the grease of the invention, the sufficient dispersion and emulsification of the grease can be realized, and the cleaning strength and affinity of the grease can be synergistically improved.
The cleansing cream comprises the following components:
grease;
a nonionic emulsifier;
3.0 to 4.0 weight percent of oil phase thickener;
the balance of water.
The cleansing cream also contains a proper amount of auxiliary preservative components.
In the cleansing cream, the auxiliary preservative component is any one of glycerol caprylate, ethylhexyl glycerol, sorbitan caprylate and octylglycol; the content of the auxiliary anti-corrosion component in the cleansing cream is 0.1-1 wt%.
In the cleansing cream, the oil phase thickener is Fischer-Tropsch wax with a number average molecular weight of 500-1000.
In the cleansing cream, the dropping point of the Fischer-Tropsch wax is 86-91 ℃, the solidifying point is 78-83 ℃ and the penetration degree is 3-7.
In the present invention, fischer-Tropsch wax with molecular weight of 500-1000, i.e. synthetic wax, is selected, and Fischer-Tropsch wax with dropping point 86-91 deg.c, solidifying point 78-83 deg.c and penetration 3-7 is especially preferred. The saturated high-carbon alkane composition imparts the properties of fine crystal structure, high melting point, narrow melting point range, low oil content, low penetration, low mobility, low melt viscosity, hardness, abrasion resistance and high stability to such chemicals. Can be dissolved with various oils in the formula of the cleansing cream, and effectively improves the heat stability and the breaking temperature of the cleansing cream. The low melt viscosity of the Fischer-Tropsch synthetic wax also simultaneously endows the cleansing use feel of melting once when the cleansing cream is used, and improves the using pleasure of the cleansing cream.
Meanwhile, the invention also discloses a preparation method of the cleansing cream, which comprises the following steps:
stirring and heating the grease, the nonionic emulsifier and the oil phase thickener to 90-95 ℃, and then preserving heat and dissolving for 10-20 minutes;
cooling to 60-68deg.C, adding water, stirring to dissolve uniformly;
and then filtering, discharging, hot-pouring into corresponding packing materials, and uniformly cooling to form paste.
Compared with the prior art, the invention has the beneficial effects that:
the cleansing cream disclosed by the invention is prepared from the synthetic grease with different polarities and fresh skin feel, and is matched with three emulsifiers with different HLB values to realize the balance of using freshness and emulsifying cleaning force, so that the mild cleansing cream with better experience is provided;
the cleansing cream also solves the hidden trouble of easy oil seepage at high temperature of the commercial hot-market cleansing cream, can realize no oil seepage at high temperature of 50 ℃ by carefully selecting Fischer-Tropsch synthetic wax types and matching the grease and the emulsifying agent, is convenient for transportation and storage of finished products after marketing, and simultaneously gives consideration to the fresh use feeling of the cleansing cream.
Drawings
FIG. 1 shows the oil bleeding performance at 50℃for the related products of examples and comparative examples.
Detailed Description
The following description of the embodiments of the present invention will be made clearly and completely with reference to the accompanying drawings, in which it is apparent that the embodiments described are only some embodiments of the present invention, but not all embodiments. All other embodiments, which can be made by those skilled in the art based on the embodiments of the invention without making any inventive effort, are intended to be within the scope of the invention.
Examples 1 to 4 and comparative examples 1 to 7
The preparation method of the cleansing cream is briefly described as follows:
stirring and heating the phase A raw material to 92 ℃, and then preserving heat and dissolving for 15 minutes;
cooling to 65 ℃, sequentially adding the phase B raw materials, and stirring to dissolve uniformly;
and then filtering, discharging, hot-pouring into corresponding packing materials, and uniformly cooling to form paste.
The formulation is referred to in table 1 below:
table 1 formulation table
The formula is as follows:
examples 1 to 4: four gradient concentration emulsifying agents, grease and oil phase thickening agents are matched;
comparative example 1: compared with the example 3, the total amount of the emulsifying agent is more, the relative oil amount is reduced, and the emulsifying and flushing speed is reduced;
comparative example 2: compared with the example 3, the total amount of the emulsifying agent is less, the relative oil amount is reduced, and the emulsifying and flushing speed is also reduced;
comparative example 3: as compared with example 3, the lipophilic emulsifier sorbitan sesquioleate with low HLB value is reduced in the emulsifier, and the emulsifying and flushing speed is also reduced;
comparative example 4: in comparison with example 3, the polar grease "iso-tridecanol isononanoate" was changed into the nonpolar grease "hydrogenated polyisobutene", and the emulsification flushing speed was slowed;
comparative example 5: in comparison with example 3, the main emulsifier "sorbitol polyether-30 tetraisostearate" was changed to "PEG-20 glycerol triisostearate", and the emulsion flushing speed was slowed;
comparative example 6 and comparative example 7: is a commercial hot-market cleansing cream product.
Performance testing
1. Stability test
The samples of the examples and the comparative examples are uniformly placed in a high-low temperature oven for 90 days to observe the change of appearance state; the melting point of each sample was measured using a capillary melting point apparatus. The test results are shown in Table 2.
TABLE 2 stability test results
FIG. 1 shows the oil bleeding performance at 50℃for the related products of examples and comparative examples.
2. Crowd actual use test
20 girls with full face cosmetic habits are selected, the ages are between 20 and 35, each product is used for three days, a questionnaire is submitted immediately after each sample is used, and the questionnaire is scored from five dimensions of touch preference, face refreshing degree, makeup removal force, emulsification cleaning force and use mildness (including whether hot eyes are included), the average score is calculated comprehensively, and specific results can be seen in Table 3.
Scoring criteria: 1-5 min, the best 5 min and the worst 1 min
Table 3 volunteer test results
Sample of Touch preference degree Upper face refreshing degree Make-up removal force Emulsion cleaning force Use mildness
Example 1 3.89 4.23 3.56 4.05 4.23
Example 2 3.78 4.05 3.42 3.89 4.23
Example 3 3.56 4.05 3.42 4.05 4.23
Example 4 3.78 4.23 3.78 4.23 4.23
Comparative example 1 3.56 3.56 3.32 2.56 3.89
Comparative example 2 3.56 3.78 3.42 2.89 3.89
Comparative example 3 3.56 3.87 3.32 3.05 4.23
Comparative example 4 3.56 3.32 3.32 3.05 3.89
Comparative example 5 3.56 3.87 3.42 3.45 3.89
Comparative example 6 3.42 3.87 3.42 3.89 4.42
Comparative example 7 3.56 3.37 3.42 3.42 3.89
The test results are described below:
comparative examples 1-5 were significantly lower than the other samples in the emulsion cleaning strength score;
the market product of comparative example 6 performed well in all dimensions, but was slightly lower in touch preference than the other samples;
the market product of comparative example 7 performed well in terms of touch preference, with other dimensions performing generally, especially with the lowest score on the face freshness;
the formulations of examples 1-4 have good performance in each dimension by carefully matching the addition proportion of the grease, the emulsifier and the oil phase thickener, well balance the cleaning strength and the use comfort, and have higher trial satisfaction of people than the market heat marketing products.

Claims (4)

1. The cleansing cream is characterized by comprising the following components:
grease;
a nonionic emulsifier;
3.0-4.0wt% of oil phase thickener;
the balance of water;
the grease comprises the following components in percentage by weight of the total weight of the cleansing cream:
isononanoate of isotridecyl alcohol and/or isononyl isononanoate 24-32wt%
16-24wt% of neopentyl glycol dicaprylate/dicaprate
8-12 wt% of cetyl ethyl hexanoate
7-10wt% of glycerol tri (ethylhexanoate)
3-5wt% of propyl heptyl octanoate;
the grease accounts for 65-75wt% of the total weight of the cleansing cream;
the nonionic emulsifier consists of the following components:
13-18wt% of sorbitol polyether-30 tetraisostearate;
3-5wt% of PEG-10 isostearate;
sorbitan sesquioleate 0.8-1.2wt%;
the nonionic emulsifier accounts for 18-23wt% of the total weight of the cleansing cream;
the oil phase thickener is Fischer-Tropsch wax with a number average molecular weight of 500-1000; the drop point of the Fischer-Tropsch wax is 86-91 ℃, the solidifying point is 78-83 ℃ and the penetration degree is 3-7.
2. The cleansing cream of claim 1 wherein an amount of a co-preservative ingredient is also added.
3. The cleansing cream according to claim 2, wherein the auxiliary preservative component is any one of glycerol caprylate, ethylhexyl glycerol, sorbitan caprylate, and octylglycol; the content of the auxiliary anti-corrosion component in the cleansing cream is 0.1-1wt%.
4. A method for preparing the cleansing cream according to claim 1, wherein the method comprises the steps of:
stirring and heating the grease, the nonionic emulsifier and the oil phase thickener to 90-95 ℃, and then preserving heat and dissolving for 10-20 minutes;
cooling to 60-68deg.C, adding water, stirring to dissolve uniformly;
and then filtering, discharging, hot-pouring into corresponding packing materials, and uniformly cooling to form paste.
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Citations (2)

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Publication number Priority date Publication date Assignee Title
CN114795978A (en) * 2022-04-12 2022-07-29 上海佰太生物科技有限公司 Makeup remover
CN114869814A (en) * 2022-03-24 2022-08-09 北京茂思商贸有限公司 Water-oil dual-cleansing-moistening cleansing oil and preparation process thereof

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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN114869814A (en) * 2022-03-24 2022-08-09 北京茂思商贸有限公司 Water-oil dual-cleansing-moistening cleansing oil and preparation process thereof
CN114795978A (en) * 2022-04-12 2022-07-29 上海佰太生物科技有限公司 Makeup remover

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