CN115305730A - Production process of antifouling, color migration prevention, scraping prevention and environment-friendly technical cloth - Google Patents

Production process of antifouling, color migration prevention, scraping prevention and environment-friendly technical cloth Download PDF

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Publication number
CN115305730A
CN115305730A CN202210771062.7A CN202210771062A CN115305730A CN 115305730 A CN115305730 A CN 115305730A CN 202210771062 A CN202210771062 A CN 202210771062A CN 115305730 A CN115305730 A CN 115305730A
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China
Prior art keywords
fabric
disperse
antifouling
production process
prevention
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Pending
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CN202210771062.7A
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Chinese (zh)
Inventor
程家瑛
程婷
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Haining Singa Textile Co ltd
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Haining Singa Textile Co ltd
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Application filed by Haining Singa Textile Co ltd filed Critical Haining Singa Textile Co ltd
Priority to CN202210771062.7A priority Critical patent/CN115305730A/en
Publication of CN115305730A publication Critical patent/CN115305730A/en
Pending legal-status Critical Current

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    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
    • D06P1/16—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using dispersed, e.g. acetate, dyestuffs
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B37/00—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B38/00—Ancillary operations in connection with laminating processes
    • B32B38/0012—Mechanical treatment, e.g. roughening, deforming, stretching
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B38/00—Ancillary operations in connection with laminating processes
    • B32B38/0036—Heat treatment
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B38/00—Ancillary operations in connection with laminating processes
    • B32B38/08—Impregnating
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B38/00—Ancillary operations in connection with laminating processes
    • B32B38/14—Printing or colouring
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B38/00—Ancillary operations in connection with laminating processes
    • B32B38/14—Printing or colouring
    • B32B38/145—Printing
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B38/00—Ancillary operations in connection with laminating processes
    • B32B38/16—Drying; Softening; Cleaning
    • B32B38/164—Drying
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B5/00—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts
    • B32B5/02—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by structural features of a fibrous or filamentary layer
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B5/00—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts
    • B32B5/02—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by structural features of a fibrous or filamentary layer
    • B32B5/026—Knitted fabric
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B5/00—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts
    • B32B5/22—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by the presence of two or more layers which are next to each other and are fibrous, filamentary, formed of particles or foamed
    • B32B5/24—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by the presence of two or more layers which are next to each other and are fibrous, filamentary, formed of particles or foamed one layer being a fibrous or filamentary layer
    • B32B5/26—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by the presence of two or more layers which are next to each other and are fibrous, filamentary, formed of particles or foamed one layer being a fibrous or filamentary layer another layer next to it also being fibrous or filamentary
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
    • C09J11/08—Macromolecular additives
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J133/00—Adhesives based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Adhesives based on derivatives of such polymers
    • C09J133/04—Homopolymers or copolymers of esters
    • C09J133/14—Homopolymers or copolymers of esters of esters containing halogen, nitrogen, sulfur or oxygen atoms in addition to the carboxy oxygen
    • D—TEXTILES; PAPER
    • D02—YARNS; MECHANICAL FINISHING OF YARNS OR ROPES; WARPING OR BEAMING
    • D02G—CRIMPING OR CURLING FIBRES, FILAMENTS, THREADS, OR YARNS; YARNS OR THREADS
    • D02G3/00—Yarns or threads, e.g. fancy yarns; Processes or apparatus for the production thereof, not otherwise provided for
    • D02G3/02—Yarns or threads characterised by the material or by the materials from which they are made
    • D—TEXTILES; PAPER
    • D02—YARNS; MECHANICAL FINISHING OF YARNS OR ROPES; WARPING OR BEAMING
    • D02J—FINISHING OR DRESSING OF FILAMENTS, YARNS, THREADS, CORDS, ROPES OR THE LIKE
    • D02J1/00—Modifying the structure or properties resulting from a particular structure; Modifying, retaining, or restoring the physical form or cross-sectional shape, e.g. by use of dies or squeeze rollers
    • D02J1/08—Interlacing constituent filaments without breakage thereof, e.g. by use of turbulent air streams
    • D—TEXTILES; PAPER
    • D04—BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
    • D04B—KNITTING
    • D04B21/00—Warp knitting processes for the production of fabrics or articles not dependent on the use of particular machines; Fabrics or articles defined by such processes
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/322—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing nitrogen
    • D06M13/395—Isocyanates
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
    • D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
    • D06P1/52—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders using compositions containing synthetic macromolecular substances
    • D06P1/5207—Macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds
    • D06P1/525—Polymers of unsaturated carboxylic acids or functional derivatives thereof
    • D06P1/5257—(Meth)acrylic acid
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
    • D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
    • D06P1/52—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders using compositions containing synthetic macromolecular substances
    • D06P1/5264—Macromolecular compounds obtained otherwise than by reactions involving only unsaturated carbon-to-carbon bonds
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
    • D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
    • D06P1/60—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders using compositions containing polyethers
    • D06P1/613—Polyethers without nitrogen
    • D06P1/6131—Addition products of hydroxyl groups-containing compounds with oxiranes
    • D06P1/6133—Addition products of hydroxyl groups-containing compounds with oxiranes from araliphatic or aliphatic alcohols
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
    • D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
    • D06P1/64—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders using compositions containing low-molecular-weight organic compounds without sulfate or sulfonate groups
    • D06P1/642—Compounds containing nitrogen
    • D06P1/6429—Compounds containing nitrogen bound to a six-membered aromatic carbocyclic ring
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
    • D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
    • D06P1/64—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders using compositions containing low-molecular-weight organic compounds without sulfate or sulfonate groups
    • D06P1/651—Compounds without nitrogen
    • D06P1/65106—Oxygen-containing compounds
    • D06P1/65125—Compounds containing ester groups
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
    • D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
    • D06P1/673—Inorganic compounds
    • D06P1/67333—Salts or hydroxides
    • D06P1/6735—Salts or hydroxides of alkaline or alkaline-earth metals with anions different from those provided for in D06P1/67341
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P3/00—Special processes of dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form, classified according to the material treated
    • D06P3/34—Material containing ester groups
    • D06P3/52—Polyesters
    • D06P3/54—Polyesters using dispersed dyestuffs
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2260/00—Layered product comprising an impregnated, embedded, or bonded layer wherein the layer comprises an impregnation, embedding, or binder material
    • B32B2260/02—Composition of the impregnated, bonded or embedded layer
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    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2262/00—Composition or structural features of fibres which form a fibrous or filamentary layer or are present as additives
    • B32B2262/02—Synthetic macromolecular fibres
    • B32B2262/0276—Polyester fibres
    • B32B2262/0284—Polyethylene terephthalate [PET] or polybutylene terephthalate [PBT]
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00—Properties of the layers or laminate
    • B32B2307/50—Properties of the layers or laminate having particular mechanical properties
    • B32B2307/584—Scratch resistance
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M2101/00—Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
    • D06M2101/16—Synthetic fibres, other than mineral fibres
    • D06M2101/30—Synthetic polymers consisting of macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M2101/32—Polyesters
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M2200/00—Functionality of the treatment composition and/or properties imparted to the textile material
    • D06M2200/01—Stain or soil resistance
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M2200/00—Functionality of the treatment composition and/or properties imparted to the textile material
    • D06M2200/10—Repellency against liquids
    • D06M2200/11—Oleophobic properties
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M2200/00—Functionality of the treatment composition and/or properties imparted to the textile material
    • D06M2200/10—Repellency against liquids
    • D06M2200/12—Hydrophobic properties

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  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Chemical & Material Sciences (AREA)
  • Mechanical Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Physics & Mathematics (AREA)
  • Organic Chemistry (AREA)
  • Dispersion Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Thermal Sciences (AREA)
  • Fluid Mechanics (AREA)
  • Coloring (AREA)

Abstract

The embodiment discloses a production process of antifouling, color migration prevention, scraping prevention and environment-friendly technical cloth, which comprises the steps of base cloth preparation, napping treatment, dyeing, sanding, heat setting, transfer printing, gold stamping, composite thickening fabric, three-proofing finishing and drying. The dispersed printing ink comprises dispersed dye color paste, dopamine hydrochloride, anhydrous copper sulfate and polycarbodiimide crosslinking agent; the glue used for gold stamping comprises hydroxyl polyacrylate, six-functional-group polyurethane acrylic resin, polyisocyanate crosslinking agent, adhesion promoter and polycarbodiimide crosslinking agent. The adoption of the superfine terylene interlaced yarn can ensure that the technical cloth has soft hand feeling, and the adoption of the auxiliary agents such as dopamine hydrochloride and the like in the used dispersing printing ink enables the combining ability of the dispersing dye and the terylene fiber to be difficult to generate the phenomenon of color migration. The glue used in the gold stamping process uses at least two crosslinking agents, so that the composite fabric has a good scratch-resistant effect, and the composite fabric is subjected to three-proofing finishing.

Description

Production process of antifouling, color migration prevention, scraping prevention and environment-friendly technical cloth
Technical Field
The invention relates to the technical field of textile fabric production, in particular to a production process of antifouling, color migration prevention, scratch prevention and environment-friendly technical cloth.
Background
In recent years, when a soft package such as a sofa or a soft bed is purchased, there is a product called a "breathable fabric" which has a soft touch of genuine leather and a soft touch of cloth art, and is called a technical cloth. Technical cloth, the english name is Leathair, also called super fine cloth of science and technology, nanometer science and technology cloth is one kind of sofa fabric commonly used, and the main material is dacron, adopts warp knitting cloth usually, and the bionical design decorative pattern of application 3D to through the dyeing, draw line, stamp, gilt, thickening complex, the novel surface fabric that the process preparation such as stoving can understand an synthetic leather.
However, although the existing technical cloth has good hand feeling and air permeability, the existing technical cloth which is subjected to gold stamping has defects in the aspects of color migration prevention and scratch prevention.
Disclosure of Invention
The invention aims to provide a production process of antifouling, color migration prevention and scratch prevention environment-friendly technical cloth, so that the prepared technical cloth fabric has good antifouling, three-prevention and anti-fouling performances on the premise of good color migration prevention and scratch prevention performances.
In order to solve the technical problems, the invention aims to realize that:
the invention relates to a production process of an antifouling, color migration preventing, scraping preventing and environment-friendly technical cloth, which comprises the following steps:
s1, preparing base cloth: in the weaving process of the base cloth, a first comb section adopts 50D/24F terylene FDY, a second comb section adopts 75D/288F full terylene composite interlaced yarn, and a Germany KARL-MAYER warp knitting machine is adopted for weaving; the gram weight range of the base cloth is 180-240 grams per square meter;
s2, napping treatment: napping 75D/288F polyester composite interlaced yarn in the base fabric by using a napping machine, wherein the napping length is 0.5-2mm;
s3, dyeing: pretreating the fabric prepared in the previous step, and dyeing by adopting a high-temperature high-pressure overflow dyeing machine;
s4, sanding: sanding the fabric prepared in the previous step by adopting a four-roller sanding machine, wherein the length of sanded fluff is 0.5-1mm;
s5, heat setting: performing heat setting on the fabric prepared in the last step by using a tentering setting machine, wherein the setting temperature is 160-165 ℃;
s6, transfer printing: firstly, pretreating the shaped fabric, and then printing the shaped fabric by adopting transfer printing equipment and dispersed printing ink, wherein the transfer printing temperature is 200-210 ℃;
s7, gold stamping: forming patterns matched with the printing patterns on the surface of the release film by using glue through a laser engraving gravure pattern roller and a glue trough, and bonding the printed fabric with the upper glue surface of the release film through a hot roller at 105-110 ℃ so that the glue is transferred to the printed fabric to form a leather-like effect;
s8, compounding thickened fabric;
s9, three-proofing finishing: dipping the composite fabric prepared in the last step into a three-proofing finishing liquid;
s10, drying;
in the step S6, the pre-treatment of the shaped fabric is to perform ultrasonic treatment on the fabric in alkali liquor for 30min and then use deionized water for leaching;
the disperse ink comprises 25-30% of disperse dye color paste, 3-5% of dopamine hydrochloride, 20-25% of thickening agent, 5-8% of humectant, 0.5-1% of surface tension regulator, 0.2-0.4% of defoaming agent, 0.05-0.1% of anticoagulant, 2-3% of anhydrous copper sulfate, 1-3% of polycarbodiimide crosslinking agent, 1-2% of penetrating agent and the balance of deionized water;
in the step S7, the glue used comprises 10-20% of hydroxyl polyacrylate, 5-10% of hexa-functional group polyurethane acrylic resin, 5-10% of alcohol ethoxylate carboxylate, 3-5% of polyether modified polysiloxane, 2-3% of oleamido sodium, 3-5% of polyisocyanate crosslinking agent, 3-5% of silicon tetrafluoride hydrophobic agent, 1-3% of adhesion promoter, 2-4% of polycarbodiimide crosslinking agent and the balance of deionized water.
On the basis of the above scheme and as a preferable scheme of the scheme: the thickening agent is butylene diacrylate or diallyl phthalate.
On the basis of the above scheme and as a preferable scheme of the scheme: the surface activity regulator is as follows: one or more of linear alkyl benzene sodium sulfonate, fatty alcohol-polyoxyethylene ether sodium sulfate, fatty alcohol-polyoxyethylene ether ammonium sulfate, lauryl alcohol sodium sulfate, nonylphenol polyoxyethylene ether, diethanol amide, stearic acid monoglyceride, lignosulfonate, heavy alkylbenzene sulfonate, alkyl polyether and fatty alcohol-polyoxyethylene ether.
On the basis of the above scheme and as a preferable scheme of the scheme: the three-proofing finishing liquid comprises 8-10% of closed oxime isocyanate dispersion liquid, 3-5% of penetrating agent OT and the balance of deionized water.
On the basis of the above scheme and as a preferable scheme of the scheme: the disperse dye color paste comprises 30-40% of disperse dye, 10-15% of fatty alcohol polyoxypropylene, 5-8% of sodium polyacrylate and the balance of deionized water.
The invention has the beneficial effects that: according to the production process of the antifouling, color migration prevention, scraping prevention and environment-friendly technical cloth, the technical cloth can be guaranteed to have soft hand feeling by adopting the superfine polyester mesh yarns, and the disperse dye and polyester fibers are not easy to generate color migration due to the binding capacity of the disperse dye and the polyester fibers by adopting the auxiliary agents such as dopamine hydrochloride and the like in the used disperse ink. The at least two crosslinking agents are used in the glue used in the gold stamping process, so that the film forming performance of the glue can be effectively improved, a good scratch-resistant effect is achieved, and three-proofing finishing is performed on the compounded fabric, so that the technical cloth has a good three-proofing effect.
Detailed Description
The present invention is further illustrated by the following specific examples.
Example one
The production process of the antifouling, color migration preventing, scraping preventing and environment-friendly technical cloth comprises the following steps: s1, preparing base cloth, S2 napping, S3 dyeing, S4 sanding, S5 heat setting, S6 transfer printing, S7 gold stamping, S8 composite thickening fabric, S9 three-proofing finishing and S10 drying.
In the step S1, in the process of weaving the base cloth, a first comb section adopts 50D/24F terylene FDY, a second comb section adopts 75D/288F polyester composite interlaced yarn, and a Germany KARL-MAYER warp knitting machine is adopted for weaving; the grammage of the base fabric ranges from 240 grams per square meter. The 75D/288F polyester composite interlaced yarn can improve the leather-like effect of the base fabric, so that the base fabric has good hand feeling.
In the step S2 of napping treatment, a napping machine is adopted to nappe 75D/288F polyester composite interlaced yarn in the base fabric, and the napping length is 2mm. Napping may form a pile on one side of the base fabric.
In the step S3 of dyeing, the fabric prepared in the previous step is pretreated, and then a high-temperature high-pressure overflow dyeing machine is adopted for dyeing. Dyeing of polyester fabrics is the prior art and is not described herein.
In the step S4, a four-roller sanding machine is adopted to sande the fabric prepared in the last step, and the length of the sanded fluff is 1mm. The surfaces of the first sanding roller and the second sanding roller adopt 200-mesh carborundum, and the surfaces of the third sanding roller and the fourth sanding roller adopt 300-mesh carborundum.
In the step S5 of heat setting, the fabric prepared in the last step is subjected to heat setting by a tenter setting machine, wherein the setting temperature is 160-165 ℃.
In the step S6 of transfer printing, the shaped fabric is pretreated, and then the shaped fabric is printed by adopting transfer printing equipment and dispersed ink, wherein the transfer printing temperature is 200-210 ℃. Pretreating the shaped fabric, namely performing ultrasonic treatment on the fabric in alkali liquor for 30min, and then leaching with deionized water;
in this step, the dispersion ink comprises 30% of a disperse dye color paste, 3% of dopamine hydrochloride, 25% of a thickening agent, 5% of a humectant, 1% of a surface tension regulator, 0.2-0.4% of a defoaming agent, 0.1% of an anticoagulant, 3% of anhydrous copper sulfate, 1% of a polycarbodiimide crosslinking agent, 2% of a penetrating agent and the balance of deionized water.
Further, the thickening agent is butylene diacrylate or diallyl phthalate. In this example, butylene diacrylate was used.
Further, the surface activity regulator is: one or more of linear alkyl benzene sodium sulfonate, fatty alcohol-polyoxyethylene ether sodium sulfate, fatty alcohol-polyoxyethylene ether ammonium sulfate, lauryl alcohol sodium sulfate, nonylphenol polyoxyethylene ether, diethanol amide, stearic acid monoglyceride, lignosulfonate, heavy alkylbenzene sulfonate, alkyl polyether and fatty alcohol-polyoxyethylene ether. Sodium lauryl sulfate was chosen in this example.
Further, the disperse dye color paste comprises 30% of disperse dye, 15% of fatty alcohol polyoxypropylene, 5% of sodium polyacrylate and the balance of deionized water.
Further, the disperse dye is one of disperse red 19, disperse red 53, disperse red 54, disperse red 60, disperse red 86, disperse red 118, disperse red 179, disperse yellow 54, disperse yellow 64, disperse yellow 79, disperse yellow 104, disperse yellow 163, disperse yellow 232, disperse blue 7, disperse blue 14, disperse blue 26, disperse blue 72, disperse blue 79, disperse blue 124, disperse blue 359, disperse orange 11, disperse orange 13, disperse orange 29, disperse orange 31, disperse orange 73, disperse orange 149, disperse violet 17, disperse violet 26, disperse violet 28, and disperse violet 63. Disperse red 19 is chosen in this example.
The copper sulfate can catalyze the polymerized dopamine formed by polymerizing the dopamine hydrochloride, and can be well combined with the polyester fiber, so that the combination fastness of the polyester fiber and the disperse dye is improved, and the color fastness of dyeing can be effectively improved. And the thickening agent, the surface tension regulator and the polycarbodiimide crosslinking agent are used in the dispersed ink, so that the crosslinking effect between the dispersed inks after drying can be increased, and the dyed fabric is not easy to have a color migration phenomenon.
Gold stamping in step S7: the surface of the release film is provided with patterns matched with the printing patterns by laser engraving of a gravure pattern roller and passing through a glue groove, and the printed fabric is bonded with the upper gluing surface of the release film by a hot roller at 105-110 ℃, so that the glue is transferred to the printed fabric, and the leather-like effect is formed.
In step S7, the glue used includes 10% of hydroxyl polyacrylate, 10% of hexa-functional group polyurethane acrylic resin, 5-% of alcohol ethoxylate carboxylate, 5% of polyether modified polysiloxane, 3% of sodium oleamidoate, 3% of polyisocyanate crosslinking agent, 5% of silicon tetrafluoride hydrophobing agent, 2% of polycarbodiimide crosslinking agent, and the balance of deionized water. The crosslinking strength of the surface of the glue is improved by adopting the polyisocyanate crosslinking agent and the polycarbodiimide crosslinking agent, so that the glue has good scratch resistance.
And step S8, compounding thickened fabric. The composite fabric can be napping fabric or other fabrics.
In the step S9 of three-proofing finishing, the composite fabric prepared in the last step is soaked in three-proofing finishing liquid. The three-proofing finishing liquid comprises 10% of closed oxime isocyanate dispersion liquid, 5% of penetrating agent OT and the balance of deionized water.
And step S10, drying, namely drying the fabric impregnated in the previous step.
Example two
The production process of the antifouling, color migration preventing, scraping preventing and environment-friendly technical cloth comprises the following steps: s1, preparing base cloth, S2 napping, S3 dyeing, S4 sanding, S5 heat setting, S6 transfer printing, S7 gold stamping, S8 composite thickening fabric, S9 three-proofing finishing and S10 drying.
In the step S1, in the process of weaving the base cloth, a first comb section adopts 50D/24F terylene FDY, a second comb section adopts 75D/288F polyester composite interlaced yarn, and a Germany KARL-MAYER warp knitting machine is adopted for weaving; the grammage of the base fabric is in the range of 180 grams per square meter. The 75D/288F polyester composite interlaced yarn can improve the imitation leather effect of the base fabric, so that the base fabric has good hand feeling.
In the step S2 of napping treatment, a napping machine is adopted to nappe 75D/288F polyester composite interlaced yarn in the woven fabric, and the napping length is 0.5mm. Napping may form a pile on one side of the base fabric.
In the step S3 of dyeing, the fabric prepared in the previous step is pretreated, and then a high-temperature high-pressure overflow dyeing machine is adopted for dyeing. Dyeing of polyester fabrics is the prior art and is not described herein.
In the sanding in the step S4, the fabric prepared in the previous step is sanded by a four-roller sanding machine, and the length of the sanded fluff is 0.3. The surfaces of the first sanding roller and the second sanding roller adopt 200-mesh carborundum, and the surfaces of the third sanding roller and the fourth sanding roller adopt 300-mesh carborundum.
In the step S5 of heat setting, the fabric prepared in the previous step is heat-set by a tenter setting machine, and the setting temperature is 160 ℃.
In the step S6 of transfer printing, the shaped fabric is pretreated, and then the shaped fabric is printed by adopting transfer printing equipment and dispersed ink, wherein the transfer printing temperature is 200-210 ℃. Pretreating the shaped fabric, namely performing ultrasonic treatment on the fabric in alkali liquor for 30min, and then leaching with deionized water;
in this step, the dispersion ink comprises 25% of a disperse dye paste, 5% of dopamine hydrochloride, 20% of a thickening agent, 8% of a humectant, 0.5% of a surface tension regulator, 0.4% of an antifoaming agent, 0.05% of an anticoagulant, 2% of anhydrous copper sulfate, 3% of a polycarbodiimide crosslinking agent, 1% of a penetrating agent and the balance of deionized water.
Further, the thickening agent is butylene diacrylate or diallyl phthalate. In this example, diallyl phthalate was chosen.
Further, the surface activity regulator is: one or more of linear alkyl benzene sodium sulfonate, fatty alcohol-polyoxyethylene ether sodium sulfate, fatty alcohol-polyoxyethylene ether ammonium sulfate, lauryl alcohol sodium sulfate, nonylphenol polyoxyethylene ether, diethanol amide, stearic acid monoglyceride, lignosulfonate, heavy alkylbenzene sulfonate, alkyl polyether and fatty alcohol-polyoxyethylene ether. In this example, the fatty alcohol polyoxyethylene ether ammonium sulfate, lignosulfonate and alkylsulfonate are selected according to a ratio of 1:1:1, and mixing.
Further, the disperse dye color paste comprises 40% of disperse dye, 10% of fatty alcohol polyoxypropylene, 8% of sodium polyacrylate and the balance of deionized water.
Further, the disperse dye is one of disperse red 19, disperse red 53, disperse red 54, disperse red 60, disperse red 86, disperse red 118, disperse red 179, disperse yellow 54, disperse yellow 64, disperse yellow 79, disperse yellow 104, disperse yellow 163, disperse yellow 232, disperse blue 7, disperse blue 14, disperse blue 26, disperse blue 72, disperse blue 79, disperse blue 124, disperse blue 359, disperse orange 11, disperse orange 13, disperse orange 29, disperse orange 31, disperse orange 73, disperse orange 149, disperse violet 17, disperse violet 26, disperse violet 28, and disperse violet 63. In this embodiment disperse blue 14 is selected.
The copper sulfate can catalyze the polymerized dopamine formed by the polymerization of the dopamine hydrochloride, and can be well combined with the polyester fiber, so that the combination fastness of the polyester fiber and the disperse dye is improved, and the dyeing color fastness can be effectively improved. And the thickening agent, the surface tension regulator and the polycarbodiimide crosslinking agent are used in the dispersed ink, so that the crosslinking effect between the dispersed inks after drying can be improved, and the dyed fabric is not easy to have a color migration phenomenon.
Gold stamping in step S7: the laser engraving gravure pattern roller passes through the glue groove, so that glue forms patterns matched with the printing patterns on the surface of the release film, the printed fabric is bonded with the upper glue surface of the release film through a hot roller at 105-110 ℃, and the glue is transferred to the printed fabric to form the leather-like effect.
In the step S7, the glue used comprises 20% of hydroxyl polyacrylate, 5% of hexa-functional group polyurethane acrylic resin, 10% of alcohol ethoxylate carboxylate, 3% of polyether modified polysiloxane, 2% of sodium oleamidoate, 5% of polyisocyanate crosslinking agent, 3% of silicon tetrafluoride hydrophobic agent, 4% of polycarbodiimide crosslinking agent and the balance of deionized water. The crosslinking strength of the surface of the glue is improved by adopting the polyisocyanate crosslinking agent and the polycarbodiimide crosslinking agent, so that the glue has good scratch resistance.
And step S8, compounding thickened fabric. The composite fabric can be napping cloth or other fabrics.
In the step S9 of three-proofing finishing, the composite fabric prepared in the last step is soaked in three-proofing finishing liquid. The three-proofing finishing liquid comprises 8% of closed oxime isocyanate dispersion liquid, 3% of penetrating agent OT and the balance of deionized water.
And step S10, drying, namely drying the fabric impregnated in the previous step.
The technical fabrics prepared in the first embodiment, the second embodiment and the comparative embodiment are subjected to color migration prevention tests, including sublimation fastness and storage color fastness. The comparative example is technical cloth purchased in the market.
When the temperature reaches a certain temperature, the dye in the fiber is directly changed into gas from a powdery solid to escape, and the escaped dye is condensed into a solid after being cooled and is stained on the surface of a fabric or other fabrics, usually expressed as disperse dye, which is a heat migration phenomenon and is also commonly called sublimation fastness, and the color fastness of dry heat (except hot pressing) is generally adopted for testing. The test standards for sublimation fastness were: GB/T5718-1997 color fastness to dry heat (excluding hot pressing) in the textile color fastness test.
When the temperature is lower than the sublimation temperature of the dye and the dye is not capable of sublimating, the dye in the fabric composed of different colors migrates from one place to another in storage or use, usually the dark color part transfers to the light color part, and this phenomenon is generally called dye migration (color migration), and the dye transfer performance or the storage fastness test can be used. The storage color fastness test standard is GB/T32008-2015 color fastness to storage of textile color fastness test. The method comprises the following steps: combining a sample to be tested with a pre-wetted multi-fiber lining or a designated fabric, clamping the combined sample into a test stand of a sweat stain resistance color fastness instrument, fixing the test stand, putting the test stand into a constant temperature and humidity device under specified test conditions, and evaluating the color change of the sample and the staining of the multi-fiber lining or the designated fabric by using a gray sample card. The test conditions were 24. + -. 2 ℃ and relative humidity 80. + -. 5% for 48 hours.
The test results were as follows:
examplesA Example two Comparative example
Colour fastness to sublimation 4-5 4-5 3
Color fastness to storage 4-5 4 3
Therefore, the technical cloth prepared in the first embodiment and the second embodiment has good color migration prevention effect.
The scratch resistance test, namely the scratch resistance test, is carried out on the first embodiment, the second embodiment and the comparative example, the three technical cloths are tested by a scratch resistance testing mechanism, after 100 scratch tests, the surface of the comparative example has obvious scratches and has fluffy phenomena, and the surface of the technical cloth related to the first embodiment and the second embodiment has only slight scratches.
The foregoing detailed description of the preferred embodiments of the invention has been presented. It should be understood that numerous modifications and variations can be devised by those skilled in the art in light of the above teachings. Therefore, the technical solutions available to those skilled in the art through logic analysis, reasoning and limited experiments based on the prior art according to the concept of the present invention should be within the scope of protection defined by the claims.

Claims (5)

1. The production process of the antifouling, color migration prevention, scraping prevention and environment-friendly technical cloth is characterized by comprising the following steps of: the method comprises the following steps:
s1, preparing base cloth: in the weaving process of the base cloth, a first comb section adopts 50D/24F terylene FDY, a second comb section adopts 75D/288F terylene composite interlaced yarn, and a Germany KARL-MAYER warp knitting machine is adopted for weaving; the gram weight range of the base cloth is 180-240 grams per square meter;
s2, napping: a napping machine is adopted to nappe the 75D/288F polyester composite interlaced yarn in the base fabric, and the napping length is 0.5-2mm;
s3, dyeing: pretreating the fabric prepared in the previous step, and dyeing by adopting a high-temperature high-pressure overflow dyeing machine;
s4, sanding: sanding the fabric prepared in the last step by using a four-roller sanding machine, wherein the length of the sanded fluff is 0.3-1mm;
s5, heat setting: performing heat setting on the fabric prepared in the last step by using a tentering setting machine, wherein the setting temperature is 160-165 ℃;
s6, transfer printing: firstly, pretreating the shaped fabric, and then printing the shaped fabric by adopting transfer printing equipment and dispersed ink, wherein the transfer printing temperature is 200-210 ℃;
s7, gold stamping: forming patterns matched with the printing patterns on the surface of the release film by using glue through a laser engraving gravure pattern roller and a glue trough, and bonding the printed fabric with the upper glue surface of the release film through a hot roller at 105-110 ℃ so that the glue is transferred to the printed fabric to form a leather-like effect;
s8, compounding thickened fabric;
s9, three-proofing finishing: dipping the composite fabric prepared in the last step into three-proofing finishing liquid;
s10, drying;
in the step S6, the pre-treatment of the shaped fabric is to perform ultrasonic treatment on the fabric in alkali liquor for 30min and then use deionized water for leaching;
the disperse ink comprises 25-30% of disperse dye color paste, 3-5% of dopamine hydrochloride, 20-25% of thickening agent, 5-8% of humectant, 0.5-1% of surface tension regulator, 0.2-0.4% of defoaming agent, 0.05-0.1% of anticoagulant, 2-3% of anhydrous copper sulfate, 1-3% of polycarbodiimide crosslinking agent, 1-2% of penetrating agent OT and the balance of deionized water;
in the step S7, the glue used comprises 10-20% of hydroxyl polyacrylate, 5-10% of hexa-functional group polyurethane acrylic resin, 5-10% of alcohol ethoxylate carboxylate, 3-5% of polyether modified polysiloxane, 2-3% of oleamido sodium, 3-5% of polyisocyanate crosslinking agent, 3-5% of silicon tetrafluoride hydrophobic agent, 1-3% of adhesion promoter, 2-4% of polycarbodiimide crosslinking agent and the balance of deionized water.
2. The production process of the antifouling, color migration and scratch preventing environment-friendly technical cloth according to claim 1, characterized by comprising the following steps: the thickening agent is butylene diacrylate or diallyl phthalate.
3. The production process of the antifouling, color migration and scratch preventing environment-friendly technical cloth according to claim 1, characterized by comprising the following steps: the surface activity regulator is as follows: one or more of linear alkyl benzene sodium sulfonate, fatty alcohol-polyoxyethylene ether sodium sulfate, fatty alcohol-polyoxyethylene ether ammonium sulfate, lauryl alcohol sodium sulfate, nonylphenol polyoxyethylene ether, diethanol amide, stearic acid monoglyceride, lignosulfonate, heavy alkylbenzene sulfonate, alkyl polyether and fatty alcohol-polyoxyethylene ether.
4. The production process of the antifouling, color migration and scratch preventing environment-friendly technical cloth according to claim 1, characterized by comprising the following steps: the three-proofing finishing liquid comprises 8-10% of closed oxime isocyanate dispersion liquid, 3-5% of penetrating agent OT and the balance of deionized water.
5. The production process of the antifouling, color migration and scratch preventing environment-friendly technical cloth according to claim 1, characterized by comprising the following steps: the disperse dye color paste comprises 30-40% of disperse dye, 10-15% of fatty alcohol polyoxypropylene, 5-8% of sodium polyacrylate and the balance of deionized water.
CN202210771062.7A 2022-06-30 2022-06-30 Production process of antifouling, color migration prevention, scraping prevention and environment-friendly technical cloth Pending CN115305730A (en)

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