CN109680514A - A kind of dyeing for washing ammonia four sides elasticity fabric - Google Patents
A kind of dyeing for washing ammonia four sides elasticity fabric Download PDFInfo
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- CN109680514A CN109680514A CN201811435392.9A CN201811435392A CN109680514A CN 109680514 A CN109680514 A CN 109680514A CN 201811435392 A CN201811435392 A CN 201811435392A CN 109680514 A CN109680514 A CN 109680514A
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/16—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using dispersed, e.g. acetate, dyestuffs
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- D—TEXTILES; PAPER
- D03—WEAVING
- D03D—WOVEN FABRICS; METHODS OF WEAVING; LOOMS
- D03D15/00—Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used
- D03D15/40—Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used characterised by the structure of the yarns or threads
- D03D15/47—Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used characterised by the structure of the yarns or threads multicomponent, e.g. blended yarns or threads
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- D—TEXTILES; PAPER
- D03—WEAVING
- D03D—WOVEN FABRICS; METHODS OF WEAVING; LOOMS
- D03D15/00—Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used
- D03D15/50—Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used characterised by the properties of the yarns or threads
- D03D15/56—Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used characterised by the properties of the yarns or threads elastic
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06B—TREATING TEXTILE MATERIALS USING LIQUIDS, GASES OR VAPOURS
- D06B9/00—Solvent-treatment of textile materials
- D06B9/02—Solvent-treatment of textile materials solvent-dyeing
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/39—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using acid dyes
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
- D06P1/445—Use of auxiliary substances before, during or after dyeing or printing
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P3/00—Special processes of dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form, classified according to the material treated
- D06P3/82—Textiles which contain different kinds of fibres
- D06P3/8204—Textiles which contain different kinds of fibres fibres of different chemical nature
- D06P3/8214—Textiles which contain different kinds of fibres fibres of different chemical nature mixtures of fibres containing ester and amide groups
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P5/00—Other features in dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form
- D06P5/02—After-treatment
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P5/00—Other features in dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form
- D06P5/02—After-treatment
- D06P5/04—After-treatment with organic compounds
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P5/00—Other features in dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form
- D06P5/02—After-treatment
- D06P5/10—After-treatment with compounds containing metal
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- D—TEXTILES; PAPER
- D10—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B2331/00—Fibres made from polymers obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. polycondensation products
- D10B2331/04—Fibres made from polymers obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. polycondensation products polyesters, e.g. polyethylene terephthalate [PET]
-
- D—TEXTILES; PAPER
- D10—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B2331/00—Fibres made from polymers obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. polycondensation products
- D10B2331/10—Fibres made from polymers obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. polycondensation products polyurethanes
-
- D—TEXTILES; PAPER
- D10—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B2401/00—Physical properties
- D10B2401/14—Dyeability
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- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Chemical & Material Sciences (AREA)
- Dispersion Chemistry (AREA)
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Abstract
The invention discloses a kind of dyeings for washing ammonia four sides elasticity fabric, and include the following steps: step S1, dyeing pre-treatment: ammonia spandex fabric woven fabric is washed in selection, and the content of spandex carries out dyeing pre-treatment in 15%-25%, and to fabric;Step S2, it dyes: soft water being added in dye vat according to the bath raio of 1:20 at room temperature, and bleeding agent, color fixing agent, levelling agent, pH adjusting agent, spandex promotor, acid dyes, disperse dyes, fiber protection agent, diffusant are added in clear water;Step S3, reduction cleaning: contain caustic soda, sodium hydrosulfite, cleaning agent, hydroxymethanesulfinate in cleaning solution;Step S4, lather styling.One kind according to the present invention washs ammonia four sides elasticity fabric, it may make the higher spandex content polyester/polyurethane fabric uniformity that terylene and spandex dye in dyeing compared with common process, dye level having the same, and it is more preferable compared with traditional handicraft to the dyeing effect of spandex, it is preferable to wash the rear non-discolouring color fastness that do not fade.
Description
Technical field
The present invention relates to textile fabric staining technique field, especially a kind of dyeing for washing ammonia four sides elasticity fabric.
Background technique
Spandex fabric is got consumer reception again due to its excellent elasticity, and spandex is often mixed into twisting with other fibers
Silk or covering yarn, for various warp knits, weft-knitted fabric and woven fabric etc.;But then, spandex does not have due to its unique structure
There is dedicated dye that can dye.In traditional dyeing process, wash ammonia, the spandex in bright and beautiful ammonia is not painted substantially, i.e., it is enabled to catch face
Color, fastness is also very poor, not washable, and especially when spandex content is higher, the color fastness of fabric cannot be met the requirements.
Summary of the invention
The object of the present invention is to provide a kind of dyeings for washing ammonia four sides elasticity fabric, and polyester/polyurethane fabric is enabled to have
Preferable dyeing uniformity and color fastness.
In order to solve the above technical problems, the object of the present invention is achieved like this:
A kind of dyeing for washing ammonia four sides elasticity fabric involved in the present invention, includes the following steps:
Step S1, dye pre-treatment: ammonia spandex fabric woven fabric is washed in selection, and the content of spandex is in 15%-25%, warp and weft
It is Polyester Polyurethane Core-spun Yarn;By the bath raio injected clear water of selected fabric 1:15-25, be added ULTRAVON TC,
INVATEX CRA, INVADINE LUN, INVATEX KR HC, RUCOGEN WBL, caustic soda;The ULTRAVON TC being added is
1-3g/L, INVATEX CS are 1-2g/L, and INVADINE LUN3-8g/L, INVATEX KR HC is 5-8g/L, RUCOGEN
FWK is 2-4g/L, caustic soda 20-60g/L;It is warming up to 70-80 DEG C, and keeps 15-20min;Washing 2-3 is carried out to fabric again
It is secondary;
Step S2, it dyes: soft water being added in dye vat according to the bath raio of 1:20 at room temperature, and bleeding agent is added in clear water
ALBAFLOW FFA-01, color fixing agent ALBAFIX ECO, levelling agent ALBEGALA, pH adjusting agent ALBATEX PS-35, spandex
Promotor ERIO NAL EIA, acid dyes, disperse dyes, fiber protection agent RUCO-LUB KSA, diffusant DFM, are added
Bleeding agent ALBAFLOW FFA-01 be 0.1-1g/L, color fixing agent ALBAFIX ECO be 10-20g/L, levelling agent ALBEGALA
For 1-2g/L, pH adjusting agent ALBATEX PS-35 adjusting pH value to 4-5, spandex promotor ERIO NAL EIA is 3-5g/L,
Fiber protection agent RUCO-LUB KSA is 20-60g/L, and diffusant DFM is 2-4g/L;According to the heating rate of 0.7-1 DEG C/min
85-90 DEG C of heating keeps 30-50min;It heats up 120-125 DEG C according still further to the heating rate of 0.7-1 DEG C/min, keeps 30-
40min;According still further to the speed 80-85 DEG C of holding 10-20min of cooling of 1-2 DEG C/min, cool down according still further to the speed of 1-2 DEG C/min
To 60 DEG C, sample to color;
Step S3, reduction cleaning: being at room temperature in the cleaning solution of 1:10 by the fabric merging bath raio after dyeing, described is clear
Contain caustic soda, sodium hydrosulfite, cleaning agent ERIOPON OLS, hydroxymethanesulfinate in washing lotion, the content of caustic soda is 4-6g/L, is protected
The content of dangerous powder is 2-5g/L, and cleaning agent ERIOPON OLS is 0.5-1g/L, and hydroxymethanesulfinate 2-5g/L is heated to 70-
80 DEG C, and keep 10-15min;
Step S4, lather styling: the fabric after reduction cleaning is immersed in foaming machine and is formed by foam, is contained in foam
There are setting agent and softening agent, setting temperature is 160-170 DEG C, setting time 1.5-2min, speed 20-25m/min;It is added
The softening agent entered is ULTRATEX FMI.
It washs warp and weft used in ammonia four sides elasticity fabric as a further illustration of the above scheme, selected and is
150D+40D。
The beneficial effects of the present invention are: one kind according to the present invention washs ammonia four sides elasticity fabric, high spandex may make to contain
Measuring polyester/polyurethane fabric, terylene and the uniformity of spandex dyeing are compared with common process in dyeing, dye level having the same, and
And it is more preferable compared with traditional handicraft to the dyeing effect of spandex, it is preferable to wash the rear non-discolouring color fastness that do not fade.
Specific embodiment
The present invention is further described combined with specific embodiments below.
Embodiment one
A kind of dyeing for washing ammonia four sides elasticity fabric involved in the present embodiment includes the following steps: to washing ammonia four
The dyeing pre-treatment of face elastic fabric, to wash the dyeing of ammonia four sides elasticity fabric, to the reduction cleaning of dyed shell fabrics, to dyeing face
The lather styling of material.
Before step S1 is dyed in processing, ammonia spandex fabric woven fabric is washed in selection, and the content of spandex is in 15%-25%, warp
Weft yarn is Polyester Polyurethane Core-spun Yarn.It is selected that wash warp and weft used in ammonia four sides elasticity fabric be 150D+40D.
By the bath raio injected clear water of selected fabric 1:15, ULTRAVON TC, INVATEX CRA, INVADINE is added
LUN, INVATEX KR HC, RUCOGEN WBL, caustic soda.
ULTRAVON TC is the efficient of Huntsman Corporation, multipurpose detergent, dispersing agent and detergent, and there is strength to moisten
Wet efficiency.There is low foam high dirt to disperse suspending power.INVATEX CRA and INVATEX KR HC is institute, Huntsman Corporation
A kind of complexing agent out is especially suitable in desizing liquid (enzyme desizing or surfactant) with peptizaiton, and resistive connection crystalline substance is low
Limit effect.Have increase-volume and promotes scourability.INVADINE LUN be Huntsman Corporation a kind of surfactant, for it is weak yin from
Son has brilliant wetability.The strength refining agent that RUCOGEN WBL is gone out by Rudoiph company, for a variety of neutral phosphate esters
Nonionic emulsifier composition, applied to the high effective scouring penetrant of all fibres type, be particularly adapted to the pre-treatment of fabric,
The obstinate grease stain on fabric can be effectively removed.
The ULTRAVON TC being added is 3g/L, and INVATEX CS is 2g/L, INVADINE LUN8g/L, INVATEX
KR HC is 8g/L, and RUCOGEN FWK is 4g/L, caustic soda 60g/L;80 DEG C are warming up to, and keeps 20min;Fabric is carried out again
Washing 3 times.And the fabric after pre-treatment is dried.
Step S2 in the dyeing for washing ammonia four sides elasticity fabric, be at room temperature according to the bath raio of 1:20 in dye vat plus
Enter soft water, the hardness for the soft water being added is 5.And bleeding agent ALBAFLOW FFA-01, color fixing agent are added in clear water
ALBAFIX ECO, levelling agent ALBEGALA, pH adjusting agent ALBATEX PS-35, spandex promotor ERIO NAL EIA, acid
Property dyestuff, fiber protection agent RUCO-LUB KSA, diffusant DFM.
Bleeding agent ALBAFLOW FFA-01 is a kind of bleeding agent that Huntsman Corporation goes out, can remove all fabrics it is wet plus
Air in work bath, especially suitable for liquid circulation overflow dyeing machine, release is trapped within liquid internal and is tightly adhered to hydrophobicity
Micro-dispersion air bubbles on fiber prevent it from accumulating in without air pocket phenomenon on fiber, and can be with all dye class and textile auxiliary
There is good compatibility, odorlessness remains on fabric after dyeing.One kind that color fixing agent ALBAFIX ECO is gone out by Huntsman Corporation
Color fixing agent has outstanding water logging, sweat stain and resistance to hot pressing (ironing) fastness, and can significantly improve soaping fastness, and drying
Prevent dye migration and good reproducibility in the process, and do not influence the feel of fabric, when can protect dyeing not by
Hydrolysis or thermal cracking.Levelling agent ALBEGALA be Huntsman Corporation pick a kind of multi-functional levelling agent, for premetallized dye,
Acid dyes, and prevent from precipitating when one-bath dyeing, color fastness, especially colorfastness to rubbing can be improved.PH adjusting agent
ALBATEX PS-35 is suitable for the boiling point under all kinds of dyeing installations of almost all of dyestuff or each processing rank under hot conditions
Section can be used for any pH and need to slide onto acid dyeing system from neutrality, can prevent dyestuff is too fast to reach exhaustion, and can be really
Protect reproducibility.Fiber protection agent RUCO-LUB KSA is gone out by Rudoiph company, and finishing fluid can be prevented unstable and run
It is unsmooth, the strength of fabric after dyeing can be improved, assign soft fabric and smooth characteristic.Spandex promotor ERIO NAL EIA is
A kind of spandex colouring promotor, makes spandex polyamide fibre obtain immediate color.
Acid dyes be added is acid black FRIOFAST M, Indian yellow ERIOFAST R in the present embodiment.And in addition to
Disperse dyes are also added into outside acid dyes, the disperse dyes being added are to disperse black W-EU, disperse blue W-EI.The acid being added
Property black FRIOFAST M be 1.5% (o.m.f), Indian yellow ERIOFAST R is 0.5% (o.m.f), the black W- of the dispersion being added
EU is 5.5% (o.m.f), disperse blue W-EI1.5% (o.m.f).The contaminated color of the present embodiment is black.
In this step, the bleeding agent ALBAFLOW FFA-01 being added is 0.1-1g/L, color fixing agent ALBAFIX ECO
It is 2g/L, pH adjusting agent ALBATEX PS-35 adjusting pH value to 4, spandex promotor for 20g/L, levelling agent ALBEGALA
ERIO NAL EIA is 5g/L, and fiber protection agent RUCO-LUB KSA is 60g/L, and diffusant DFM is g/L;According to 0.7 DEG C/min
Heating rate heat up 90 DEG C, keep 50min;It heats up 125 DEG C according still further to the heating rate of 0.7 DEG C/min, keeps 40min;Again
According to speed 85 DEG C of holding 20min of cooling of 1 DEG C/min, 60 DEG C are cooled to according still further to the speed of 1 DEG C/min, is sampled to color.
It is at room temperature institute in the cleaning solution of 1:10 by the fabric merging bath raio after dyeing in step S3 reduction cleaning
Contain caustic soda, sodium hydrosulfite, cleaning agent ERIOPON OLS, hydroxymethanesulfinate in the cleaning solution stated, the content of caustic soda is 6g/
L, the content of sodium hydrosulfite are 5g/L, and cleaning agent ERIOPON OLS is 1g/L, hydroxymethanesulfinate 5g/L, are heated to 80 DEG C, and
Keep 15min.
A kind of rear cleaning agent that cleaning agent ERIOPON OLS is gone out by Huntsman Corporation, main component is ethoxylated fatty
Acid derivative can improve the wet fastness and crock fastness of dyed fabric, recycle suitable for jet dyeing apparatus and high-speed liquid
Dyeing or cleaning equipment.Hydroxymethanesulfinate can increase the efficiency of loose colour cleaning.
In step S4 lather styling, the fabric after reduction cleaning is immersed in foaming machine and is formed by foam, foam
In contain setting agent and softening agent, setting temperature be 170 DEG C, setting time 2min, speed 20m/min;What is be added is soft
Soft dose is ULTRATEX FMI.
Embodiment two
A kind of dyeing for washing ammonia four sides elasticity fabric involved in the present embodiment includes the following steps: to washing ammonia four
The dyeing pre-treatment of face elastic fabric, to wash the dyeing of ammonia four sides elasticity fabric, to the reduction cleaning of dyed shell fabrics, to dyeing face
The lather styling of material.
Before step S1 is dyed in processing, ammonia spandex fabric woven fabric is washed in selection, and the content of spandex is in 15%-25%, warp
Weft yarn is Polyester Polyurethane Core-spun Yarn.It is selected that wash warp and weft used in ammonia four sides elasticity fabric be 150D+40D.
By the bath raio injected clear water of selected fabric 1:25, ULTRAVON TC, INVATEX CRA, INVADINE is added
LUN, INVATEX KR HC, RUCOGEN WBL, caustic soda.
The ULTRAVON TC being added is 1g/L, and INVATEX CS is 1g/L, INVADINE LUN3g/L, INVATEX
KR HC is 5g/L, and RUCOGEN FWK is 2g/L, caustic soda 20g/L;70 DEG C are warming up to, and keeps 15min;Fabric is carried out again
Washing 2 times.And the fabric after pre-treatment is dried.
Step S2 in the dyeing for washing ammonia four sides elasticity fabric, be at room temperature according to the bath raio of 1:20 in dye vat plus
Enter soft water, the hardness for the soft water being added is 7.And bleeding agent ALBAFLOW FFA-01, color fixing agent are added in clear water
ALBAFIX ECO, levelling agent ALBEGALA, pH adjusting agent ALBATEX PS-35, spandex promotor ERIO NAL EIA, acid
Property dyestuff, fiber protection agent RUCO-LUB KSA, diffusant DFM.
Acid dyes be added is acid orange ERIOFAST 4R, acid red ERIOFAST B in the present embodiment.And in addition to
Disperse dyes are also added into outside acid dyes, the disperse dyes being added are to disperse golden yellow W-3R, disperse red W-EL, disperse blue W-
EU.The acid orange ERIOFAST 4R being added is 1.0% (o.m.f), and acid red ERIOFAST B is 0.35% (o.m.f), institute
The golden yellow W-3R of the dispersion of addition is 0.7% (o.m.f), and disperse red W-EL is 2.1% (o.m.f), and disperse blue W-EU is 0.6%
(o.m.f).The color that the present embodiment is contaminated is deep claret.
In this step, the bleeding agent ALBAFLOW FFA-01 being added is 0.1g/L, and color fixing agent ALBAFIX ECO is
10g/L, levelling agent ALBEGALA are 1g/L, pH adjusting agent ALBATEX PS-35 adjusting pH value to 5, spandex promotor ERIO
NAL EIA is 5g/L, and fiber protection agent RUCO-LUB KSA is 20g/L, and diffusant DFM is 2g/L;According to the heating of 1 DEG C/min
Speed heats up 85 DEG C, keeps 30min;It heats up 120 DEG C according still further to the heating rate of 1 DEG C/min, keeps 30min;According still further to 2 DEG C/
Speed 80 DEG C of holding 10min of cooling of min, are cooled to 60 DEG C according still further to the speed of 2 DEG C/min, sample to color.
It is at room temperature institute in the cleaning solution of 1:10 by the fabric merging bath raio after dyeing in step S3 reduction cleaning
Contain caustic soda, sodium hydrosulfite, cleaning agent ERIOPON OLS, hydroxymethanesulfinate in the cleaning solution stated, the content of caustic soda is 4g/
L, the content of sodium hydrosulfite are 2g/L, and cleaning agent ERIOPON OLS is 0.5g/L, and hydroxymethanesulfinate 2g/L is heated to 70 DEG C,
And keep 10min.
In step S4 lather styling, the fabric after reduction cleaning is immersed in foaming machine and is formed by foam, foam
In contain setting agent and softening agent, setting temperature be 160 DEG C, setting time 1.5min, speed 25m/min;It is added
Softening agent is ULTRATEX FMI.
Comparative example one
A kind of process flow of dyeing that washing ammonia four sides elasticity fabric involved in the present embodiment are as follows: polyester/polyurethane fabric →
Pre-treatment → 180 DEG C preboarding → dyeing → reduction cleaning → setting (160 DEG C, 45s).
In pre-treating technology, used bath raio is 1:20, and treatment temperature is 75 DEG C, and the processing time is 15min.Preceding place
Manage the sodium carbonate of ULTRAVON SIR containing 2g/L, INVATEX CS of 1g/L, 1.5g/L in liquid.
In dyeing, used bath raio is 1:20, and pH value 4 is warming up to most according to the heating rate of 1 DEG C/min
130 DEG C of high dyeing temperature, and keep 60min.The levelling agent of bleeding agent ALBAFLOW UINI, 1g/L in dye liquor containing 1g/L
Spandex promotor ERIO NAL EIA, the 2g/L of acid buffer agent ALBATEXAB-45,3g/L of UNIVADINE DPU, 3g/L
Diffusant UNIVADINE DFM, the black W-EU of dispersion of 5.5% (o.m.f), 1.5% (o.m.f) disperse blue W-EU.
It is that 15min is handled in reduction cleaning liquid in reduction clearing step, treatment temperature is 76 DEG C, in reduction cleaning liquid
The cleaning agent ERIOPON OLS of the sodium hydrosulfite of caustic soda, 2g/L containing 4g/L, 1g/L.After reduction cleaning, then fabric is carried out
Dehydration, then carried out shaping using conventional setting process.
Comparative example two
A kind of process flow of dyeing that washing ammonia four sides elasticity fabric involved in the present embodiment are as follows: polyester/polyurethane fabric →
Pre-treatment → 180 DEG C preboarding → dyeing → dehydration → setting (160 DEG C, 45s).
In pre-treating technology, used bath raio is 1:20, and treatment temperature is 75 DEG C, and the processing time is 15min.Preceding place
Manage the sodium carbonate of ULTRAVON SIR containing 2g/L, INVATEX CS of 1g/L, 1.5g/L in liquid.
In dyeing, used bath raio is 1:20, and pH value 4 is warming up to most according to the heating rate of 1 DEG C/min
130 DEG C of high dyeing temperature, and keep 60min.The levelling agent of bleeding agent ALBAFLOW UINI, 1g/L in dye liquor containing 1g/L
Spandex promotor ERIO NAL EIA, the 2g/L of acid buffer agent ALBATEXAB-45,3g/L of UNIVADINE DPU, 3g/L
Diffusant UNIVADINE DFM, the golden yellow W-3RL of dispersion of 0.7% (o.m.f), 2.1% (o.m.f) disperse red W-FL,
The disperse red W-FL of 0.6% (o.m.f).
It is that 15min is handled in reduction cleaning liquid in reduction clearing step, treatment temperature is 76 DEG C, in reduction cleaning liquid
The cleaning agent ERIOPON OLS of the sodium hydrosulfite of caustic soda, 2g/L containing 4g/L, 1g/L.After reduction cleaning, then fabric is carried out
Dehydration, then carried out shaping using conventional setting process.
To embodiment one, embodiment two, comparative example one, comparative example two carry out dyeing concentration and level-dyeing property, elastic recovery rate,
Dyefastness is tested.Using Datacolor color measurement and color match instrument, in D65, the K/S value of dyed fabric is measured under 10 ° of light sources.With
K/S value characterizes the dyeability of dyed fabric, level-dyeing property, is evaluated with measuring the standard deviation of average value of 8 K/S values.Mark
Quasi- deviation is smaller, and level-dyeing property is better.It is measured according to " textile woven fabric tensile elasticity test method ".Colour fasteness to dry cleaning: it presses
According to " textile color stability tests resistance to tetrachloro-ethylene and dry-cleans color fastness " measurement.Colour fastness to rubbing: according to " textile color stability tries
Test colour fastness to rubbing " measurement.Resistance to colour fastness to water: it is measured according to " textile color stability test color fastness to water ".Perspiration resistance
Color fastness: it is measured according to " textile color stability test colour fastness to perspiration ".
Each 3 pieces of the dyeing sample of comparative example and embodiment are taken, the dyeing K/S value and standard deviation S of fabric is measured, the results are shown in Table
l。
The K/S value and S value of 1 dyed fabric of table
As shown in Table 1, in embodiment the K/S value and traditional handicraft of stained specimens it is close, show the dyer of embodiment
Skill can contaminate to obtain same depth with the technique of comparative example, and have good level-dyeing property.This shows that diffusant DFM and spandex promote
Addition into agent ELA and other auxiliary agents will not influence dye level and dyeing uniformity.
Each 3 pieces of dye skill tinctorial pattern of dark contrast's example and embodiment are taken, measure its elastic recovery rate, dyeing is to fabric bullet
The influence of property is shown in Table 2.
Influence of 2 dyeing of table to fabric elastic force
As can be seen from Table 2, the elastic recovery for the fabric that the dyeing of embodiment one and two is dyed is than comparative example
It is good.This is because the dyeing temperature of embodiment one and two, reduces the elastic loss of spandex, although elasticity is dropped after setting
It is low, but remain to reach good wearability.This explanation reduces dyeing temperature, to change by addition auxiliary agent DFM and ELA
It has been apt to the resilience that ammonia fabric is washed in dyeing.
The spandex washed in ammonia blended fabric that embodiment one, embodiment two, comparative example one, comparative example two are dyed is split
Out, reduction cleaning compares the color change of the clear first front and back of reduction respectively.Before reduction cleaning, work in comparative example one and two
The spandex of skill dyeing is consistent with the spandex color depth of dyeing is improved, but after reduction cleaning, the technique of comparative example one and two dye
The spandex of color fades seriously;And the spandex for using embodiment one and two to dye does not fade substantially after washing.This illustrates one He of comparative example
The white spandex of two dyeings is not really upper to be contaminated, and surface is only built-up in, not washable;And the ammonia of the dyeing of embodiment one and two
Synthetic fibre washes rear non-discolouring do not fade.
Every fastness test is done to the dyeing cloth specimen of comparative example one, comparative example two, embodiment one, embodiment two, is as a result seen
Table 3.As can be seen from Table 3, embodiment one, two technique of embodiment contaminate the discoloration of black and deep claret all at 4-5 grades, and comparative example
One, two technique of comparative example only has 3-4 grades, the dyeing of embodiment one, embodiment two, and staining fastness is and right all at 4 grades or more
Ratio one, two technique of comparative example only have 2-3 grades;Fastness to wet rubbing is also at 3 grades or more.Embodiment one, embodiment two are due to improving
The dyeing of spandex improves fastness obvious, and the finished product after dye is able to satisfy production requirement.
Following acid dyes: acid orange ERIOFAST 4R, acid red ERIOFAST B is used in dyeing, it is acid
Black ERIOFAS M, acid red ERIOFAST R, and diffusant DFM is added, spandex promotor ELA can be fine at 125 DEG C
Upper dye spandex and keep good confused color fastness, wash it is rear it is non-discolouring do not fade, to ensure that polyester/polyurethane fabric is red in dye black, wine
Fastness when color etc. is dark.
The preferred embodiment of the present invention has been described in detail above.It should be appreciated that those skilled in the art without
It needs creative work according to the present invention can conceive and makes many modifications and variations.Therefore, all technologies in the art
Personnel are available by logical analysis, reasoning, or a limited experiment on the basis of existing technology under this invention's idea
Technical solution, all should be within the scope of protection determined by the claims.
Claims (2)
1. a kind of dyeing for washing ammonia four sides elasticity fabric, which comprises the steps of:
Step S1, dye pre-treatment: ammonia spandex fabric woven fabric is washed in selection, and in 15%-25%, warp and weft is the content of spandex
Polyester Polyurethane Core-spun Yarn;By the bath raio injected clear water of selected fabric 1:15-25, ULTRAVON TC, INVATEX is added
CRA, INVADINE LUN, INVATEX KR HC, RUCOGEN WBL, caustic soda;The ULTRAVON TC being added is 1-3g/L,
INVATEX CS is 1-2g/L, and INVADINE LUN3-8g/L, INVATEX KR HC is 5-8g/L, and RUCOGEN FWK is 2-
4g/L, caustic soda 20-60g/L;It is warming up to 70-80 DEG C, and keeps 15-20min;Washing 2-3 times is carried out to fabric again;
Step S2, it dyes: soft water being added in dye vat according to the bath raio of 1:20 at room temperature, and bleeding agent is added in clear water
ALBAFLOW FFA-01, color fixing agent ALBAFIX ECO, levelling agent ALBEGALA, pH adjusting agent ALBATEX PS-35, spandex
Promotor ERIO NAL EIA, acid dyes, disperse dyes, fiber protection agent RUCO-LUB KSA, diffusant DFM, are added
Bleeding agent ALBAFLOW FFA-01 be 0.1-1g/L, color fixing agent ALBAFIX ECO be 10-20g/L, levelling agent ALBEGAL A
For 1-2g/L, pH adjusting agent ALBATEX PS-35 adjusting pH value to 4-5, spandex promotor ERIO NAL EIA is 3-5g/L,
Fiber protection agent RUCO-LUB KSA is 20-60g/L, and diffusant DFM is 2-4g/L;According to the heating rate of 0.7-1 DEG C/min
85-90 DEG C of heating keeps 30-50min;It heats up 120-125 DEG C according still further to the heating rate of 0.7-1 DEG C/min, keeps 30-
40min;According still further to the speed 80-85 DEG C of holding 10-20min of cooling of 1-2 DEG C/min, cool down according still further to the speed of 1-2 DEG C/min
To 60 DEG C, sample to color;
Step S3, reduction cleaning: being at room temperature the cleaning solution in the cleaning solution of 1:10 by the fabric merging bath raio after dyeing
In contain caustic soda, sodium hydrosulfite, cleaning agent ERIOPON OLS, hydroxymethanesulfinate, the content of caustic soda is 4-6g/L, sodium hydrosulfite
Content be 2-5g/L, cleaning agent ERIOPON OLS is 0.5-1g/L, and hydroxymethanesulfinate 2-5g/L is heated to 70-80
DEG C, and keep 10-15in;
Step S4, lather styling: being immersed in foaming machine for the fabric after reduction cleaning and be formed by foam, containing fixed in foam
Type agent and softening agent, setting temperature are 160-170 DEG C, setting time 1.5-2min, speed 20-25m/min;It is added
Softening agent is ULTRATEX FMI.
2. washing the dyeing of ammonia four sides elasticity fabric as described in claim 1, which is characterized in that selected to wash ammonia four sides
Warp and weft used in elastic fabric is 150D+40D.
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