CN115304958B

CN115304958B - Hui ink with full color and luster and aromatic flavor and preparation method thereof

Info

Publication number: CN115304958B
Application number: CN202211121851.2A
Authority: CN
Inventors: 胡海涌
Original assignee: Anhui Jixi Xulong Mountain Villa Four Treasures Culture Co ltd
Current assignee: Anhui Jixi Xulong Mountain Villa Four Treasures Culture Co ltd
Priority date: 2022-09-15
Filing date: 2022-09-15
Publication date: 2023-05-26
Anticipated expiration: 2042-09-15
Also published as: CN115304958A

Abstract

The invention discloses a hui ink with full color and luster and aromatic flavor and a preparation method thereof, and relates to the technical field of ink, and the hui ink is prepared from the following components: modified compound pine smoke, castor oil, bone glue, peach gum, musk and tree peony bark mixed extract, pearl powder, sodium hydroxymethyl cellulose, rosin derivatives, surfactant, tourmaline powder and deionized water; the ink prepared by the invention has full color and luster and aromatic flavor, the fragrance of the prepared ink can be greatly improved by introducing the mixed extract of musk and tree peony bark, especially the mixed extract of musk and tree peony bark, the obtained active ingredients are mixed, and the formed fragrant rubber has more aromatic and durable fragrance with the introduced single raw material.

Description

Hui ink with full color and luster and aromatic flavor and preparation method thereof

Technical Field

The invention belongs to the technical field of ink, and particularly relates to a hui ink with full color and luster and aromatic flavor and a preparation method thereof.

Background

Ink, anhui province Huang Shanshi, xuan City specialty, national geographic marking products. The Hui ink has the characteristics of falling paper such as paint, black and moist color, no fading after a long time, no glue of paper and pen, aromatic flavor, rich and smooth skin, and the like, and has the characteristics of light weight, bright color, beautiful appearance, silence color, paint like color, and good reputation.

The invention provides a prior art application number 2022100530619, and relates to a pine smoke logo ink and a preparation method thereof. The application introduces a nano preparation process into the preparation of the Hui ink for the first time, prepares a nano pine smoke mixture by adding sodium cholate in a specific proportion into pine smoke and adopting a high-pressure homogenization process, and further prepares the pine smoke Hui ink. The pine emblem ink prepared by this technique can ignore to some extent the effect of the proportion of gum added. I.e. the writing is equally smooth with a larger proportion of glue and the adhesion is not reduced with a lower proportion of glue. The technology is suitable for industrialized production, however, the fading resistance is poor, and the painting and calligraphy works are extremely easy to fade after a long time, so that the painting and calligraphy works cannot be stored for a long time.

Accordingly, there is a need for further improvements in the art.

Disclosure of Invention

Aiming at the existing problems, the invention provides the hui ink with full color and luster and aromatic flavor and the preparation method thereof.

The invention is realized by the following technical scheme:

the technical scheme adopted by the invention is as follows:

the Hui ink with full color and luster and aromatic flavor is prepared from the following components in parts by weight:

40-50 parts of modified composite pine smoke, 4-6 parts of castor oil, 28-35 parts of bone glue, 4-5 parts of peach gum, 0.1-0.3 part of musk and tree peony bark mixed extract, 1-2 parts of pearl powder, 1.2-1.6 parts of sodium hydroxymethyl cellulose, 3-5 parts of rosin derivative, 1-3 parts of surfactant, 0.1-0.3 part of tourmaline powder and 10-15 parts of deionized water.

As a further technical scheme: the preparation method of the modified composite pine smoke comprises the following steps:

(1) Mixing pine and camphor tree together, burning, collecting to obtain compound pine smoke;

(2) Uniformly dispersing the prepared compound pine smoke into an isopropanol solution, and stirring for 30min at a rotating speed of 500r/min to obtain a mixed solution;

(3) Adding sodium maleate and caprylic/capric triglyceride into the mixed solution, adjusting the temperature to 80 ℃, keeping the temperature and stirring for 2 hours, standing for 40 minutes, then performing ultrasonic treatment for 10 minutes, adjusting the temperature to 45 ℃, and keeping the temperature for 30 minutes to obtain a reaction solution;

(4) Carrying out suction filtration on the obtained reaction liquid to obtain a solid reaction material;

(5) Drying the prepared solid reaction material, and grinding to obtain modified composite pine smoke;

the drying temperature is 55 ℃, and the drying mode adopts a vacuum drying mode.

As a further technical scheme: the mixing mass ratio of the pine to the camphor tree is 15:1;

trunk combustion is carried out on pine and camphor tree.

As a further technical scheme: the mixing mass ratio of the compound pine smoke to the isopropanol solution is 1:8;

the mass fraction of the isopropanol solution is 30%.

As a further technical scheme: the mixing mass ratio of the mixed solution to the sodium maleate to the caprylic/capric triglyceride is 100:3:6;

the ultrasonic frequency is 40kHz.

As a further technical scheme: the preparation method of the musk and tree peony bark mixed extract comprises the following steps:

pulverizing Moschus to obtain Moschus powder;

pulverizing cortex moutan to obtain cortex moutan powder;

fumigating Moschus powder with steam for 20min, adding into ethanol solution, adding cortex moutan powder into ethanol solution, mixing, stirring at 2000r/min for 2 hr, then for 1 hr, and filtering to obtain filtrate;

spray drying the filtrate to obtain the mixed extract of musk and tree peony bark.

As a further technical scheme: the temperature of the water vapor is 100 ℃;

the mixing mass ratio of musk powder to tree peony bark powder is 5:1;

the mixing mass ratio of musk powder to ethanol is 1:15;

the mass fraction of the ethanol solution is 75%.

As a further technical scheme: the rosin derivative is calcified rosin.

As a further technical scheme: the surfactant is sodium fatty alcohol polyoxyethylene ether sulfate.

A preparation method of a hui ink with full color and luster and aromatic flavor comprises the following steps:

(1) Weighing the following components in parts by weight: modified compound pine smoke, castor oil, bone glue, peach gum, musk and tree peony bark mixed extract, pearl powder, sodium hydroxymethyl cellulose, rosin derivatives, surfactant, tourmaline powder and deionized water;

(2) Sequentially adding modified compound pine smoke, castor oil, bone glue and deionized water into a stirrer, stirring, adjusting the stirring temperature to 55 ℃, and stirring for 40min to obtain a first mixture;

(3) Sequentially adding peach gum, musk and tree peony bark mixed extract, pearl powder, hydroxymethyl cellulose sodium, rosin derivative, surfactant and tourmaline powder into a stirrer, stirring at normal temperature for 1 hour to obtain a second mixture;

(4) Mixing the first mixture and the second mixture, continuing stirring for 1 hour, then performing pestle and ramming, forming, shaping and drying ink.

According to the invention, the adhesive force of bone glue to the conventional pine smoke can be improved by modifying the conventional pine smoke, so that the prepared Hui ink has better adhesive force, writing is convenient, and the ink color level and fragrance of the ink can be enhanced by adopting the musk and tree peony bark mixed extract. By introducing the pearl powder and tourmaline powder, the compactness of the ink block can be increased.

Through the introduction of tourmaline powder, the written ink can also generate negative ions; tourmaline powder has the functions of generating anions and far infrared emissivity, is a borosilicate mineral, and is a silicate mineral with a ring structure of aluminum, iron, sodium, magnesium and lithium, which is characterized by boron; as the tourmaline powder is a polar crystal with a special structure, can generate electric ions for a long time, permanently releases air anions and far infrared rays, and has higher anion generation amount and far infrared emissivity after being processed and purified, and the generated anions have the following characteristics: dust removal: the small particle size of the negative oxygen ions can interact with, complex with, diffuse to affect the conversion of contaminants in the air or act as a catalyst to alter the toxicity of trace gases during chemical processes. The fine particle fly ash which is as small as 0.01 micron and is difficult to remove industrially has obvious sedimentation removal effect. The negative oxygen ion has higher activity and strong oxidation-reduction effect, and can destroy the activity of cell membranes or cell protoplasm active enzymes of bacteria, thereby achieving the aim of antibiosis and sterilization. In the high-concentration negative oxygen ion environment, the number of moulds and bacteria in the air can be reduced by more than 90 percent through measurement. Deodorization effect: the negative air ions can play an oxidation role with organic matters in the air to remove peculiar smell generated by the negative air ions, so that the negative air ions have an effect of cleaning the air, and therefore, the ink prepared by the invention has better corrosion resistance.

According to the invention, by introducing a certain amount of castor oil, the color fullness of the prepared ink can be increased, the color is brighter, and the stability is high.

Through introducing peach gum and bone gum to combine, can obviously improve the adhesive force of badge's china ink, increase badge's friction nature when grinding for the china ink grinds more evenly, does not still influence the blackness of china ink simultaneously.

Compared with the prior art, the invention has the following advantages:

the ink prepared by the invention has full color and luster and aromatic flavor, the fragrance of the prepared ink can be greatly improved by introducing the mixed extract of musk and tree peony bark, especially the mixed extract of musk and tree peony bark, the obtained active ingredients are mixed, and the formed fragrant rubber has more aromatic and durable fragrance with the introduced single raw material.

The invention can improve the color of the prepared ink by adopting the modified composite pine smoke, so that the written color is bright and full, and the ornamental value of the painting and calligraphy works is greatly increased.

Detailed Description

The following description of the embodiments of the present invention will be made clearly and completely, and it is apparent that the described embodiments are only some embodiments of the present invention, but not all embodiments. All other embodiments, which can be made by those skilled in the art based on the embodiments of the invention without making any inventive effort, are intended to be within the scope of the invention.

Example 1

40 parts of modified composite pine smoke, 4 parts of castor oil, 28 parts of bone glue, 4 parts of peach gum, 0.1 part of musk and tree peony bark mixed extract, 1 part of pearl powder, 1.2 parts of hydroxymethyl cellulose sodium, 3 parts of rosin derivative, 1 part of surfactant, 0.1 part of tourmaline powder and 10 parts of deionized water.

The preparation method of the modified composite pine smoke comprises the following steps:

The mixing mass ratio of the pine to the camphor tree is 15:1;

trunk combustion is carried out on pine and camphor tree.

The mixing mass ratio of the compound pine smoke to the isopropanol solution is 1:8;

the mass fraction of the isopropanol solution is 30%.

The mixing mass ratio of the mixed solution to the sodium maleate to the caprylic/capric triglyceride is 100:3:6;

the ultrasonic frequency is 40kHz.

The preparation method of the musk and tree peony bark mixed extract comprises the following steps:

pulverizing Moschus to obtain Moschus powder;

pulverizing cortex moutan to obtain cortex moutan powder;

The temperature of the water vapor is 100 ℃;

the mixing mass ratio of musk powder to tree peony bark powder is 5:1;

the mixing mass ratio of musk powder to ethanol is 1:15;

the mass fraction of the ethanol solution is 75%.

The rosin derivative is calcified rosin.

The surfactant is sodium fatty alcohol polyoxyethylene ether sulfate.

Example 2

45 parts of modified composite pine smoke, 5 parts of castor oil, 32 parts of bone glue, 4.5 parts of peach gum, 0.2 part of musk and tree peony bark mixed extract, 1.5 parts of pearl powder, 1.3 parts of hydroxymethyl cellulose sodium, 4 parts of rosin derivative, 2 parts of surfactant, 0.2 part of tourmaline powder and 13 parts of deionized water.

The mixing mass ratio of the pine to the camphor tree is 15:1;

trunk combustion is carried out on pine and camphor tree.

the mass fraction of the isopropanol solution is 30%.

the ultrasonic frequency is 40kHz.

pulverizing Moschus to obtain Moschus powder;

pulverizing cortex moutan to obtain cortex moutan powder;

The temperature of the water vapor is 100 ℃;

the mixing mass ratio of musk powder to tree peony bark powder is 5:1;

the mixing mass ratio of musk powder to ethanol is 1:15;

the mass fraction of the ethanol solution is 75%.

The rosin derivative is calcified rosin.

The surfactant is sodium fatty alcohol polyoxyethylene ether sulfate.

Example 3

50 parts of modified composite pine smoke, 6 parts of castor oil, 35 parts of bone glue, 5 parts of peach gum, 0.3 part of musk and tree peony bark mixed extract, 2 parts of pearl powder, 1.6 parts of hydroxymethyl cellulose sodium, 3 parts of rosin derivatives, 3 parts of surfactants, 0.3 part of tourmaline powder and 15 parts of deionized water.

The mixing mass ratio of the pine to the camphor tree is 15:1;

trunk combustion is carried out on pine and camphor tree.

the mass fraction of the isopropanol solution is 30%.

the ultrasonic frequency is 40kHz.

pulverizing Moschus to obtain Moschus powder;

pulverizing cortex moutan to obtain cortex moutan powder;

The temperature of the water vapor is 100 ℃;

the mixing mass ratio of musk powder to tree peony bark powder is 5:1;

the mixing mass ratio of musk powder to ethanol is 1:15;

the mass fraction of the ethanol solution is 75%.

The rosin derivative is calcified rosin.

The surfactant is sodium fatty alcohol polyoxyethylene ether sulfate.

Comparative example 1: the difference from example 1 is that no modification treatment was performed on the pine smoke;

comparative example 2: the difference from example 1 is that camphor tree is not added in the preparation process of the modified composite pine smoke;

test

And (3) detecting the inking degree:

the test samples of the examples and the comparative examples are weighed, the ink stick is fixed on an ink grinder (the rotating speed of the ink grinder is 36 revolutions per minute, the weight loading mass is 2 kg, the rotating diameter is 200 mm), the bottom surface of the ink stick is enabled to be fully contacted with an inkstone table board (the inkstone is a painting and calligraphy inkstone), 100mL of clear water is added, the ink stick is ground for 60 minutes and taken down, and after the ink stick is placed for 10 minutes, the ink stick is weighed again.

The results are calculated as follows. The test is continuously carried out for 5 times, and the test result takes the average value of the 5 times of tests;

blackening degree (g/min) = (P-P1)/60;

wherein, the mass g of the P-ink stick before grinding;

p1-the mass g of the ink stick after grinding;

TABLE 1

	Degree of ink emission g/min
		Example 1	0.22
Example 2	0.25
		Example 3	0.21
Comparative example 1	0.14
		Comparative example 2	0.17

As can be seen from table 1, the ink prepared according to the present invention has excellent ink-emitting degree, and writing smoothness can be improved by improving the ink-emitting degree.

Writing the sample of the embodiment, and detecting the appearance;

TABLE 2

	Appearance of
		Example 1	Bright color and luster
Example 2	Bright color and luster
		Example 3	Bright color and luster

As can be seen from Table 2, the ink prepared by the invention has bright color and good appearance condition.

And (3) drying time detection: writing under the same conditions, room temperature was 22 ℃, and air relative humidity was 50%:

TABLE 3 Table 3

	Drying time(s)
		Example 1	28
Example 2	23
		Example 3	25
Comparative example 1	49
		Comparative example 2	35

It can be seen from table 3 that the ink prepared by the present invention has a short drying time, and the ink of the present invention can be dried rapidly after writing.

The foregoing description of the preferred embodiments of the invention should not be taken as limiting the scope of the invention, which is defined by the appended claims, but rather by the description of the preferred embodiments, all changes and modifications that come within the meaning and range of equivalency of the claims are intended to be embraced therein.

Claims

1. An ink with full color and luster and aromatic flavor is characterized in that: the coating is prepared from the following components in parts by weight:

40-50 parts of modified composite pine smoke, 4-6 parts of castor oil, 28-35 parts of bone glue, 4-5 parts of peach gum, 0.1-0.3 part of musk and tree peony bark mixed extract, 1-2 parts of pearl powder, 1.2-1.6 parts of sodium hydroxymethyl cellulose, 3-5 parts of rosin derivative, 1-3 parts of surfactant, 0.1-0.3 part of tourmaline powder and 10-15 parts of deionized water;

(1) Mixing pine and camphor tree together, burning, and collecting to obtain compound pine smoke, wherein the mixing mass ratio of pine to camphor tree is 15:1; trunk burning is carried out on pine and camphor tree;

(2) Uniformly dispersing the prepared compound pine smoke into an isopropanol solution, and stirring for 30min at a rotating speed of 500r/min to obtain a mixed solution; the mixing mass ratio of the compound pine smoke to the isopropanol solution is 1:8; the mass fraction of the isopropanol solution is 30%;

(3) Adding sodium maleate and caprylic/capric triglyceride into the mixed solution, adjusting the temperature to 80 ℃, keeping the temperature and stirring for 2 hours, standing for 40 minutes, then performing ultrasonic treatment for 10 minutes, adjusting the temperature to 45 ℃, and keeping the temperature for 30 minutes to obtain a reaction solution; the mixing mass ratio of the mixed solution to the sodium maleate to the caprylic/capric triglyceride is 100:3:6; the ultrasonic frequency is 40kHz;

(5) Drying the prepared solid reaction material, and grinding to obtain modified composite pine smoke; the drying temperature is 55 ℃, and the drying mode adopts a vacuum drying mode.

2. The full-color, aromatic ink according to claim 1, wherein: the preparation method of the musk and tree peony bark mixed extract comprises the following steps:

pulverizing Moschus to obtain Moschus powder;

pulverizing cortex moutan to obtain cortex moutan powder; fumigating Moschus powder with steam for 20min, adding into ethanol solution, adding cortex moutan powder into ethanol solution, mixing, stirring at 2000r/min for 2 hr, then for 1 hr, and filtering to obtain filtrate;

3. The full-color, aromatic ink according to claim 2, wherein: the temperature of the water vapor is 100 ℃;

the mixing mass ratio of musk powder to tree peony bark powder is 5:1;

the mixing mass ratio of musk powder to ethanol is 1:15;

the mass fraction of the ethanol solution is 75%.

4. The full-color, aromatic ink according to claim 1, wherein: the rosin derivative is calcified rosin.

5. The full-color, aromatic ink according to claim 1, wherein: the surfactant is sodium fatty alcohol polyoxyethylene ether sulfate.

6. The method for preparing the full-color and aromatic-flavor ink according to claim 1, which is characterized in that: the method comprises the following steps: