CN115300406A - Hair-dyeing mild color-protecting composition and application thereof - Google Patents

Hair-dyeing mild color-protecting composition and application thereof Download PDF

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CN115300406A
CN115300406A CN202210955822.XA CN202210955822A CN115300406A CN 115300406 A CN115300406 A CN 115300406A CN 202210955822 A CN202210955822 A CN 202210955822A CN 115300406 A CN115300406 A CN 115300406A
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hair
sodium
post
conditioner
care composition
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CN115300406B (en
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陈殿松
张伟雄
梁菁
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Guangzhou Gude Personal Nursing Products Co ltd
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    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/18Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/49Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing heterocyclic compounds
    • A61K8/4906Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing heterocyclic compounds with one nitrogen as the only hetero atom
    • A61K8/4913Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing heterocyclic compounds with one nitrogen as the only hetero atom having five membered rings, e.g. pyrrolidone carboxylic acid
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/18Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/40Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing nitrogen
    • A61K8/44Aminocarboxylic acids or derivatives thereof, e.g. aminocarboxylic acids containing sulfur; Salts; Esters or N-acylated derivatives thereof
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/18Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/64Proteins; Peptides; Derivatives or degradation products thereof
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61QSPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q5/00Preparations for care of the hair
    • A61Q5/004Preparations used to protect coloured hair
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61QSPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q5/00Preparations for care of the hair
    • A61Q5/02Preparations for cleaning the hair
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61QSPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q5/00Preparations for care of the hair
    • A61Q5/12Preparations containing hair conditioners

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  • Life Sciences & Earth Sciences (AREA)
  • Animal Behavior & Ethology (AREA)
  • General Health & Medical Sciences (AREA)
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Abstract

The invention discloses a hair-dyed mild color-protecting composition and application thereof, wherein the composition comprises the following components: sodium pyrrolidone carboxylate, sodium lauroyl hydrolyzed silk and arginine. The hair-dyed mild color protection composition has excellent hair color protection effect after dyeing and fading slowing, can improve the experience feeling of scalp, the flushing effect and the conditioning performance of dry hair, and has obvious repairing effect on hair scales after dyeing.

Description

Hair-dyeing mild color-protecting composition and application thereof
Technical Field
The invention belongs to the technical field of cosmetics, and particularly relates to a hair-dyed mild color-protecting composition and application thereof.
Background
The beauty brought by hair dyeing is increasingly popular with people of all ages. The most common in domestic market is oxidation type permanent hair dye cream which is permeated into the cortex of hair through dye intermediate and coupling agent, and then reacts to form larger dye molecules which are enclosed in hair cellulose. However, the formed macromolecules are not easy to pass through the pore size of the hair fiber and can be washed away during cleaning. At present, the market also uses non-oxidation type semi-permanent dye paste, does not need hydrogen peroxide as a coloring oxidant, and the fading speed is relatively higher. However, the cost of hair dyeing is not low, much time is spent, satisfactory hair is dyed, and obvious color difference appears due to fading after each cleaning, which is very painful for consumers. Meanwhile, hydrogen peroxide in the hair dye cream can damage hair to a certain degree, so that hair scales are opened to cause irreversible damage, and common shampoo conditioning is easy to knot in the stages of wet hair and dry hair.
At present, a plurality of shampoos claiming color protection appear in the market, but the general effects are not satisfactory, the fading speed is still too high, the color protection function is not greatly different from that of the conventional shampoo, and the appeal of hair dyeing groups is difficult to solve.
Disclosure of Invention
This section is for the purpose of summarizing some aspects of embodiments of the invention and to briefly introduce some preferred embodiments. In this section, as well as in the abstract and the title of the invention of this application, simplifications or omissions may be made to avoid obscuring the purpose of the section, the abstract and the title, and such simplifications or omissions are not intended to limit the scope of the invention.
As one aspect of the present invention, the present invention provides a post-hair dyeing mild color care composition, which consists of the following components: sodium pyrrolidone carboxylate, sodium lauroyl hydrolyzed silk and arginine; wherein the sodium pyrrolidone carboxylate: lauroyl hydrolyzed silk sodium: the mass ratio of arginine is (0.1-2): (0.05 to 4): (0.05-0.2).
As a preferable embodiment of the post-hair dyeing mild color protection composition of the present invention: the sodium pyrrolidone carboxylate: lauroyl hydrolyzed silk sodium: the mass ratio of arginine is (0.2-1): (0.3-3): (0.05-0.2)
As a preferable embodiment of the post-hair dyeing mild color protection composition of the present invention: the mass concentration of the sodium pyrrolidone carboxylate is 0.1-2%; the mass concentration of the lauroyl hydrolyzed silk sodium is 0.05-4%; the mass concentration of the arginine is 0.05-0.2%.
As a preferred embodiment of the post-hair dye mild color care composition of the present invention: the mass concentration of the sodium pyrrolidone carboxylate is 0.2-1%; the mass concentration of the lauroyl hydrolyzed silk sodium is 0.3-3%.
As another aspect of the invention, the invention provides a shampoo composition containing the after-hair-dyeing mild color-protecting composition, which comprises a surfactant, a hair conditioner, a humectant, a preservative, an essence, the after-hair-dyeing mild color-protecting composition and a solvent; wherein the surfactant comprises one or more of an anionic surfactant, a nonionic surfactant and an amphoteric surfactant;
comprises the following components in percentage by mass,
10 to 50 percent of surfactant;
0.1 to 5 percent of hair conditioner;
0.1 to 5 percent of humectant;
0.01 to 2 percent of preservative;
0 to 2 percent of essence;
0.2 to 6.2 percent of mild color protection composition after hair dyeing;
the balance of solvent to 100%.
As a preferable scheme of the shampoo composition containing the post-hair-dyeing mild color-protecting composition, the anionic surfactant comprises one or more of ammonium laureth sulfate, sodium laureth sulfate, disodium lauroyl glutamate, sodium trideceth sulfate, sodium laureth sulfate, ammonium laureth sulfate and disodium laureth sulfosuccinate;
the nonionic surfactant comprises one or more of cocamide methyl MEA, cocamide DEA, PEG-150 distearate, PEG-120 methyl glucose dioleate, butanediol laurate and glycerol laurate;
the amphoteric surfactant comprises one or more of cocamidopropyl betaine, lauramidopropyl betaine and cocamidopropyl hydroxysulfobetaine.
As a preferable scheme of the shampoo composition containing the mild color protection composition after hair dyeing, the hair conditioner comprises one or more of a polyquaternium conditioner, a guar gum hydroxypropyl trimethyl ammonium chloride conditioner, a silicone oil conditioner and a protein conditioner; the humectant comprises one or more of glycerol, propylene glycol, butanediol and dipropylene glycol; the solvent is water.
As another aspect of the invention, the invention provides the use of the post-dyeing mild color care composition in a hair color care product.
Wherein the hair color protecting product comprises shampoo, hair conditioner, hair mask and no-clean hair care product.
The invention has the beneficial effects that: the hair-dyed mild color protection composition has excellent hair color protection effect after dyeing and fading slowing, can improve the experience feeling of scalp, the flushing effect and the conditioning performance of dry hair, and has obvious repairing effect on hair scales after dyeing.
Drawings
In order to more clearly illustrate the technical solutions of the embodiments of the present invention, the drawings needed to be used in the description of the embodiments will be briefly introduced below, and it is obvious that the drawings in the following description are only some embodiments of the present invention, and it is obvious for those skilled in the art to obtain other drawings based on these drawings without inventive exercise. Wherein:
FIG. 1 is an electron micrograph of dyed hair after shampooing using the shampoo formulations of example 1 and comparative example 4.
Detailed Description
In order to make the aforementioned objects, features and advantages of the present invention comprehensible, embodiments accompanied with examples are described in detail below.
In the following description, numerous specific details are set forth in order to provide a thorough understanding of the present invention, however, the present invention may be practiced otherwise than as specifically described herein, and it will be appreciated by those skilled in the art that the present invention may be practiced without departing from the spirit and scope of the present invention and that the present invention is not limited by the specific embodiments disclosed below.
Furthermore, reference herein to "one embodiment" or "an embodiment" means that a particular feature, structure, or characteristic described in connection with the embodiment is included in at least one implementation of the invention. The appearances of the phrase "in one embodiment" in various places in the specification are not necessarily all referring to the same embodiment, nor are separate or alternative embodiments mutually exclusive of other embodiments.
The formulation of the shampoo containing the color care composition according to the examples of the present invention is shown in the following table:
TABLE 1 shampoo formulations containing color care compositions
Figure BDA0003791308790000031
Figure BDA0003791308790000041
The preparation method of the shampoo comprises the following steps:
1) Mixing deionized water and a conditioner, and stirring for 15 minutes;
2) Adding an amphoteric surfactant, and stirring for 5 minutes;
3) Adding an anionic surfactant, and stirring for 15 minutes until the anionic surfactant is completely dissolved;
4) Adding the nonionic surfactant, and stirring for 5 minutes;
5) And finally, adding the rest other components, and uniformly stirring to obtain the shampoo composition.
The color protection effect test method comprises the following steps: the bleached real human hair bundles were uniformly dyed red (semi-permanent cream of unicorn sea king red), left to stand for 2 days after dyeing, the test data before shampooing was recorded with a hair color tester MAMBO, the hair bundles were washed with shampoo of the same standard, the test data after shampooing was recorded again with the apparatus after air-drying, the experiment was repeated three times, the average value was taken, and the data after washing were measured several times, and the color difference of the hair bundles before shampooing and after shampooing was calculated and designated as Δ E (after washing) as compared with the initial state. The delta E can comprehensively reflect the change of hair chromaticity, the more the delta E value is, the more obvious the fading of the shampoo is, and the less the delta E value is, the better the color protection effect of the shampoo is. Calculating the color protection capability through delta E, wherein the calculation formula is as follows:
ΔE=SQRT(ΔL 2 +Δa 2 +Δb 2 )
wherein Δ L = post-shampoo L value-pre-shampoo L value; Δ a = post-shampoo a-pre-shampoo a value; Δ b = post-shampoo b-pre-shampoo b-value.
Since the colour loss is usually most pronounced after the first rinsing of the hair tresses after dyeing, the Δ E values after 1 shampooing were tested and the results are shown in table 2.
TABLE 2
Corresponding sample Delta E after 1 shampoo
Example 1 8.04±0.22
Comparative example 1 11.22±0.45***
Comparative example 2 12.61±0.28***
Comparative example 3 11.53±0.42***
Comparative example 4 12.00±0.51***
In the table, denotes p <0.001.
The inventor unexpectedly finds that the shampoo added with the three components of arginine, sodium PCA (sodium pyrrolidone carboxylate) and sodium lauroyl hydrolyzed silk is obviously less prone to fading after washing and dyeing. However, the effect is not good when the three components are added separately, which shows that the three components generate synergistic effect after being combined and have synergistic color protection effect.
Sensory evaluation:
sensory evaluation test method: samples example 1 and comparative example 4 were each issued to 30 freshly dyed hair testers for a half-test. The samples were used by washing the hair in the same procedure, each sample being used for 2 weeks. The testers make scores according to the experience of the testers. The experimental results were averaged. The full rate is 10 parts, the best is 10 parts, the worst is 1 part, the higher the full rate is, the better the effect is, and the evaluation results of the two samples are shown in the following table. An electron micrograph of hair after shampooing using the shampoo formulations of example 1 and comparative example 4 is shown in fig. 1.
TABLE 3
Figure BDA0003791308790000051
As can be seen from the above table, the composition of the present invention can improve the scalp experience, the water-flushing effect, the hair-drying conditioning effect, and has an obvious color-protecting effect.
Meanwhile, as can be seen from fig. 1, the product using the composition of the present invention has an obvious repairing effect on hair scales.
The formulation of the shampoo containing the color care composition of each example is shown in the following table:
TABLE 4
Figure BDA0003791308790000061
TABLE 5
Figure BDA0003791308790000062
Figure BDA0003791308790000071
As can be seen from the above table, the color protection composition of the invention still exerts an obvious color protection effect after different surfactants are replaced by the shampoo formula.
It should be noted that the above-mentioned embodiments are only for illustrating the technical solutions of the present invention and not for limiting, and although the present invention has been described in detail with reference to the preferred embodiments, it should be understood by those skilled in the art that modifications or equivalent substitutions may be made on the technical solutions of the present invention without departing from the spirit and scope of the technical solutions of the present invention, which should be covered by the claims of the present invention.

Claims (10)

1. A post-hair dye mild color care composition, characterized by: the composition consists of the following components: sodium pyrrolidone carboxylate, sodium lauroyl hydrolyzed silk and arginine; wherein the sodium pyrrolidone carboxylate: lauroyl hydrolyzed silk sodium: the mass ratio of arginine is (0.1-2): (0.05 to 4): (0.05-0.2).
2. The post-hair dye mild color care composition according to claim 1, characterized in that: the sodium pyrrolidone carboxylate: the mass ratio of the lauroyl hydrolyzed silk sodium is (0.2-1): (0.3-3).
3. The post-hair dye mild color care composition according to claim 1, characterized in that: the mass concentration of the sodium pyrrolidone carboxylate is 0.1-2%; the mass concentration of the lauroyl hydrolyzed silk sodium is 0.05-4%.
4. The post-hair dye mild color care composition according to claim 3, characterized in that: the mass concentration of the sodium pyrrolidone carboxylate is 0.2-1%; the mass concentration of the lauroyl hydrolyzed silk sodium is 0.3-3%.
5. The post-hair dye mild color care composition according to any one of claims 1 to 4, characterized in that: also comprises a surfactant, a hair conditioner, a humectant, a preservative, essence and a solvent; wherein the surfactant comprises one or more of an anionic surfactant, a nonionic surfactant and an amphoteric surfactant;
the weight percentage of each component is as follows:
10 to 50 percent of surfactant;
0.1 to 5 percent of hair conditioner;
0.1 to 5 percent of humectant;
0.01 to 2 percent of preservative;
0 to 2 percent of essence;
the balance being solvent.
6. The post-hair dyeing mild color care composition according to claim 5, characterized in that: the anionic surfactant comprises one or more of lauryl polyether ammonium sulfate, lauryl polyoxyethylene ether sodium sulfate, lauroyl disodium glutamate, tridecyl polyether sodium sulfate, lauryl sulfate sodium, lauryl sulfate ammonium, and lauryl polyether disodium sulfosuccinate.
7. The post-hair dye mild color care composition according to claim 6, characterized in that: the nonionic surfactant comprises one or more of cocamide methyl MEA, cocamide DEA, PEG-150 distearate, PEG-120 methyl glucose dioleate, butanediol laurate and glycerol laurate;
the amphoteric surfactant comprises one or more of cocamidopropyl betaine, lauramidopropyl betaine and cocamidopropyl hydroxysulfobetaine.
8. The shampoo composition containing the post-hair dye mild color care composition according to claim 5, wherein: the hair conditioner comprises one or more of polyquaternary ammonium salt conditioner, guar gum hydroxypropyl trimethyl ammonium chloride conditioner, silicone oil conditioner and protein conditioner; the humectant comprises one or more of glycerol, propylene glycol, butanediol and dipropylene glycol; the solvent is water.
9. Use of the post-hair dyeing mild color care composition according to claim 1 in a hair color care product.
10. Use according to claim 9, characterized in that: the hair color protecting product comprises shampoo, hair conditioner, hair mask and no-clean hair care product.
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Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104921989A (en) * 2015-06-12 2015-09-23 广州环亚化妆品科技有限公司 Liquid shampoo without silicon oil and with hair caring effect and preparation method thereof
CN107438425A (en) * 2016-09-12 2017-12-05 拉芳家化股份有限公司 A kind of hair care and nourishing composition of the complexing agent containing moisturizing
US20220117881A1 (en) * 2018-09-14 2022-04-21 Symrise Ag A hair care composition

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104921989A (en) * 2015-06-12 2015-09-23 广州环亚化妆品科技有限公司 Liquid shampoo without silicon oil and with hair caring effect and preparation method thereof
CN107438425A (en) * 2016-09-12 2017-12-05 拉芳家化股份有限公司 A kind of hair care and nourishing composition of the complexing agent containing moisturizing
US20220117881A1 (en) * 2018-09-14 2022-04-21 Symrise Ag A hair care composition

Non-Patent Citations (2)

* Cited by examiner, † Cited by third party
Title
卡卡烘焙日记: "超市货都扔掉了!口碑之作,回购10+次", pages 2, Retrieved from the Internet <URL:https://mp.weixin.qq.com/s?src=11&timestamp=1685605582&ver=4563&signature=45LotiN9rqy8G-O5txeW39n67YEIflYQkGNNmekqBwET4rrjbg5o7WdN2x1Ck9As7aQB4*-L007wrfgnob4xvZw6Fpc9UwGSbiy6PPKggVaIbuU5uTZlRojfSVlDFKqn&new=1> *
广东芭薇生物科技股份有限公司: "人仁和匠心氨基酸修护固色洗发水", pages 1, Retrieved from the Internet <URL:https://hzpba.nmpa.gov.cn/gccx/chakanHis.html?prodId=67ae134aab314680b9a0d3c85f28a898&gb=G> *

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