CN115292770B - Optimization method and system for fuel cell stack channel structure - Google Patents
Optimization method and system for fuel cell stack channel structure Download PDFInfo
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Abstract
The invention relates to the technical field of fuel cells, and particularly discloses an optimization method and an optimization system for a fuel cell stack channel structure, wherein the optimization method comprises the following steps: constructing a single cell-electric pile CFD porous medium numerical calculation model, and distributing a variation coefficient CV by the flow of the fuel cell electric pile, and the total pressure drop of the inlet and the outlet of the fuel cell electric pileCoefficient of cell flow excessUnevenness ofAnd cell voltage dropAnd as an optimization condition, realizing efficient optimization of the inlet and outlet common channel structure of the fuel cell stack and the variable flow area structure of the single cell and the common channel of the fuel cell stack based on the simulation calculation result of the single cell-single stack CFD porous medium numerical calculation model.
Description
Technical Field
The invention relates to the technical field of fuel cell simulation optimization, in particular to an optimization method and system for a fuel cell stack channel structure.
Background
During the operation of the fuel cell stack, not only the fluid distribution uniformity of each flow channel inside a single cell is related to the cell performance, but also the fluid distribution uniformity flowing into each single cell from a common channel of the stack has a great influence on the operation performance of the stack. The distribution uniformity of the air and hydrogen flow among the single cells is poor, which may cause great difference in performance uniformity among the single cells, and the phenomena of serious water blockage, single low and the like of partial single cells affect the stable operation and the overall performance of the electric pile. The poor uniformity of coolant flow distribution between the monocells may cause that heat generated by part of the cells cannot be taken away in time, so that the temperature is too high, a membrane electrode and even a bipolar plate are burnt out, and the galvanic pile is seriously damaged. Therefore, the optimization work of the common channel structure of the electric pile is very important.
Because the cost of the whole pile of the electric pile is high, and a plurality of rounds of structural changes are possible, if the structure is optimized by adopting an experimental method, the processing time and the cost are very large, and therefore a simulation method is generally adopted in the design stage. The whole pile has complex geometric structure, the number of single cells is hundreds or even more than 400, if the original three-dimensional geometric model is used for simulation calculation, the current hardware calculation resources and capability are difficult to realize, and in addition, the time and cost required by the optimization of multiple rounds are not less than that of the test; if the simplified one-dimensional model is adopted for simulation, the precision of the calculation structure is difficult to ensure.
The prior Chinese patent with application number 2021111572038 and publication number CN114065567A discloses a fuel cell stack common manifold structure optimization method, which utilizes a cuboid structure to simulate and construct a monocell simulation structure according to the size of a flow field runner of a monocell in a stack structure, simplifies the grid amount of the monocell simulation structure when a finite element grid is divided, and reduces the simulation calculation amount. However, the practical application research of the present application finds that the existing patent only uses the flow distribution unevenness of the single cell simulation structure and the total pressure loss of the inlet and outlet areas of the common manifold simulation structure as optimization conditions, and cannot perform efficient simulation optimization on the common channel structure of the fuel cell stack.
Therefore, the prior art is still in need of further improvement and development.
Disclosure of Invention
In view of the defects of the prior art, the invention aims to provide an optimization method and an optimization system for a fuel cell stack common manifold structure, and aims to solve the problem that the conventional optimization method for the fuel cell stack common manifold structure cannot perform efficient simulation optimization on the fuel cell stack common manifold structure.
The technical scheme of the invention is as follows:
a method for optimizing a channel structure of a fuel cell stack, comprising the steps of:
constructing a single cell CFD numerical calculation model according to a single cell geometric structure of the fuel cell stack;
constructing a single cell CFD porous medium numerical calculation model based on the single cell CFD numerical calculation model according to the variable flow area structure of the single cell and the public channel;
constructing a CFD numerical calculation model of a common channel of the fuel cell stack according to the geometric structure of the common channel of the fuel cell stack;
establishing a single cell-electric pile CFD porous medium numerical calculation model according to the single cell CFD porous medium numerical calculation model and the electric pile common channel CFD numerical calculation model;
optimizing the inlet and outlet common channel structure of the fuel cell stack according to the simulation calculation result of the single cell-stack CFD porous medium numerical calculation model, so that the flow distribution variation coefficient CV of the fuel cell stack meets a first target design value, and the total pressure drop of the inlet and outlet of the fuel cell stack meets a first target design valueSatisfying a second target design value, a cell flow excess coefficient in the fuel cell stackUnevenness ofSatisfy a third target design valueSingle cell voltage drop in the fuel cell stackSatisfying a fourth target design value;
after the inlet and outlet common channel structure of the fuel cell stack is optimized and determined, the variable flow area structure of a single cell and a common channel in the fuel cell stack is optimized according to the simulation calculation result of the CFD numerical computation model of the single cell-stack, so that the flow distribution variation coefficient CV of the fuel cell stack meets a fifth target design value, and the total pressure drop of the inlet and outlet of the fuel cell stackA sixth target design value is satisfied, and a single cell flow excess coefficient in the fuel cell stackUnevenness ofA single cell voltage drop in the fuel cell stack satisfying a seventh target design valueThe eighth target design value is satisfied.
The optimization method of the fuel cell stack channel structure comprises the following steps of calculating a flow distribution variation coefficient CV of the fuel cell stack according to the following formula:wherein, in the process,the flow rate of the ith single cell of the fuel cell stack is measured; n is the total number of single cells of the fuel cell stack,is that theAverage flow rate of each unit cell of the fuel cell stack.
The optimization method of the channel structure of the fuel cell stack is characterized in that the total pressure drop of the inlet and the outlet of the fuel cell stackCalculated according to the following formula:
wherein, in the process,calculating an inlet average static pressure value of a model for the single cell CFD porous medium numerical value;and calculating the outlet average static pressure value of the model for the single cell CFD porous medium numerical value.
The optimization method of the fuel cell stack channel structure is characterized in that each single cell flow excess coefficient in the fuel cell stackUnevenness ofCalculated according to the following formula:wherein, in the step (A),the flow excess coefficient of the ith single cell is obtained; and n is the total number of single cells of the fuel cell stack.
The optimization method of the fuel cell stack channel structure is characterized in that the pressure drop of a single cell in the fuel cell stackAccording to the followingThe following formula is calculated:wherein, in the step (A),the inlet static pressure value of the ith single cell,the outlet static pressure value of the ith single cell is shown.
The optimization method of the fuel cell stack channel structure comprises the following steps of constructing a single cell CFD porous medium numerical calculation model based on the single cell CFD numerical calculation model according to the variable flow area structure of a single cell and a common channel, wherein the step comprises the following steps:
the single cell CFD numerical calculation model comprises a bipolar plate with a flow field flow channel structure, a gas diffusion layer, a microporous layer, a catalytic layer and a proton exchange membrane;
setting the cross section size of the single cell CFD porous medium numerical calculation model as the cross section size of a bipolar plate flow field flow channel structure in the single cell CFD numerical calculation model; and setting the height direction size of the single cell CFD porous medium numerical calculation model as the depth direction size of a bipolar plate flow field flow channel structure in the single cell CFD numerical calculation model.
The optimization method of the fuel cell stack channel structure further comprises the following steps:
giving corresponding inlet flow to different working conditions of the single cell CFD numerical calculation model to obtain corresponding single cell flow field pressure drop, performing data analysis on a calculated flow resistance curve of the single cell, and fitting a function relation of speed and pressure drop;
obtaining the inertial resistance coefficient of the single cell CFD porous medium numerical calculation model according to the function relation of the speed and the pressure drop of the single cell CFD numerical calculation modelAnd coefficient of viscous drag。
The optimization method of the fuel cell stack channel structure comprises the following steps of establishing a single cell-stack CFD porous medium numerical calculation model according to a single cell CFD porous medium numerical calculation model and a stack common channel CFD numerical calculation model:
and setting the single cell CFD porous medium numerical calculation model as a porous medium area, setting the pile common channel CFD numerical calculation model as a fluid area, and establishing a single cell-single pile CFD porous medium numerical model of the fuel cell pile.
A storage medium having one or more programs stored thereon that are executable by one or more processors to implement the steps in the fuel cell stack channel structure optimization method of the present invention.
An optimization system for a channel structure of a fuel cell stack, comprising: a processor, a memory, and a communication bus; the memory has stored thereon a computer readable program executable by the processor;
the communication bus realizes connection communication between the processor and the memory;
the processor, when executing the computer readable program, implements the steps in the fuel cell stack channel structure optimization method of the present invention.
Has the beneficial effects that: the invention provides an optimization method of a fuel cell stack channel structure, which comprises the steps of firstly, respectively establishing a single cell CFD numerical calculation model and a single cell CFD porous medium numerical calculation model based on a single cell geometric structure of a real proton exchange membrane fuel cell and a variable flow area structure of the real proton exchange membrane fuel cell and a public channel; then establishing a CFD numerical calculation model of the common channel of the fuel cell stack based on the geometric structure of the common channel of the fuel cell stack, and further establishing a single cell-single stack CFD porous medium numerical calculation model of the fuel cell stack; finally, the flow distribution variation coefficient CV of the fuel cell galvanic pile is used, and the total pressure drop of the inlet and the outlet of the fuel cell galvanic pileCoefficient of cell flow excessUnevenness ofAnd cell voltage dropAnd as an optimization condition, realizing efficient optimization of the inlet and outlet common channel structure of the fuel cell stack and the variable flow area structure of the single cell and the common channel of the fuel cell stack based on the simulation calculation result of the single cell-single stack CFD porous medium numerical calculation model.
Drawings
FIG. 1 is a flow diagram of the connection hole between the common channel and the single cell of the fuel cell stack according to the present invention.
Fig. 2 is a schematic structural diagram of the present invention, in which a bidirectional extension baffle or a unidirectional extension baffle (collectively arranged in a left extension manner or collectively arranged in a right extension manner) is arranged at an air flow inlet of a single cell, so as to reduce the aperture area of the single cell.
Fig. 3 is a schematic structural diagram of a single cell-single pile CFD porous medium numerical calculation model.
Fig. 4 is a schematic view of a variable flow area structure of a single cell and a common channel.
FIG. 5 is a graph illustrating a single cell excess coefficient distribution in a fuel cell stack.
Fig. 6 is a graph illustrating a cell pressure drop profile in a fuel cell stack.
Fig. 7 is a schematic diagram of an optimization system of a channel structure of a fuel cell stack according to the present invention.
Detailed Description
The present invention provides a method and a system for optimizing a fuel cell stack channel structure, and the present invention is further described in detail below in order to make the purpose, technical solution and effect of the present invention clearer and clearer. It should be understood that the specific embodiments described herein are merely illustrative of the invention and are not intended to limit the invention.
Computational Fluid Dynamics (CFD) is an analysis of a system containing related physical phenomena such as Fluid flow and heat conduction by computer numerical calculation and image display, which can be regarded as numerical simulation of flow under the control of a basic equation of flow. Through the numerical simulation and the combination of a graphic processing tool, the structure optimization design can be carried out.
Based on this, the invention provides a method for optimizing a channel structure of a fuel cell stack, which comprises the following steps:
s100, constructing a single cell CFD numerical calculation model according to a single cell geometric structure of the fuel cell stack;
s200, constructing a single cell CFD porous medium numerical calculation model based on the single cell CFD numerical calculation model according to a variable flow area structure of the single cell and the public channel;
s300, constructing a CFD numerical calculation model of the common channel of the fuel cell stack according to the geometric structure of the common channel of the fuel cell stack;
s400, establishing a single cell-electric pile CFD porous medium numerical calculation model according to the single cell CFD porous medium numerical calculation model and the electric pile common channel CFD numerical calculation model;
s500, optimizing a common inlet and outlet channel structure of the fuel cell stack according to a simulation calculation result of the CFD numerical calculation model of the single cell-stack to ensure that the flow distribution variation coefficient CV of the fuel cell stack meets a first target design value and the total inlet and outlet pressure drop of the fuel cell stack meets a first target design valueSatisfying a second target design value, a cell flow excess coefficient in the fuel cell stackUnevenness ofSatisfying a third target design value, a cell voltage drop in the fuel cell stackSatisfying a fourth target design value;
s600, after the inlet and outlet common channel structure of the fuel cell stack is optimized and determined, optimizing the variable flow area structure of a single cell and a common channel in the fuel cell stack according to the simulation calculation result of the CFD (computational fluid dynamics) numerical calculation model of the single cell-stack to ensure that the flow distribution variation coefficient CV of the fuel cell stack meets a fifth target design value, and the total pressure drop of the inlet and outlet of the fuel cell stackA sixth target design value is satisfied, and a single cell flow excess coefficient in the fuel cell stackUnevenness ofSatisfying a seventh target design value, a cell voltage drop in the fuel cell stackThe eighth target design value is satisfied.
After a single cell-single stack CFD porous medium numerical calculation model of the fuel cell stack is established, the flow distribution variation coefficient CV of the fuel cell stack and the total pressure drop of the inlet and the outlet of the fuel cell stack are usedCell flow excess factorUnevenness ofAnd cell voltage dropAs an optimization condition, the high-efficiency optimization of the inlet and outlet common channel structure of the fuel cell stack and the variable flow area structure of a single cell and a common channel of the fuel cell stack is realized based on the simulation calculation result of a single cell-single stack CFD porous medium numerical calculation model.
In the present invention, the first target design value, the second target design value, the third target design value and the fourth target design value are designed for optimally adjusting the inlet and outlet common channel structures of the fuel cell stack, the fifth target design value, the sixth target design value, the seventh target design value and the eighth target design value are designed based on further optimizing and adjusting the variable flow area structures of the single cells and the common channels (i.e. the U-shaped necking manner at the connection between the common channels and the single cells) after the inlet and outlet common channel structures are optimally adjusted, and the fifth to eighth target design values are further optimization targets of the same design variable compared with the first to fourth target design values, which are more stringent requirements and can achieve better performance after conditions are satisfied.
The invention uses the flow distribution coefficient of variation CV and total pressure drop of the inlet and outlet of the galvanic pileAs a global evaluation index of the fuel cell stack level, a single cell flow excess coefficient is usedUnevenness ofAnd single cell voltage dropAs a single cell layerThe evaluation indexes of the key parameter distribution uniformity of the surface optimize the fuel cell stack channel structure from two layer indexes.
In some embodiments, a cell CFD numerical calculation model is constructed from the cell geometry of the fuel cell stack. In this embodiment, the single cell CFD numerical calculation model includes a bipolar plate having a flow field channel structure, a gas diffusion layer, a microporous layer, a catalytic layer, and a proton exchange membrane. The bipolar plate of the single cell CFD numerical calculation model takes the real flow field flow channel structure into consideration, establishes a numerical calculation model taking the actual single cell flow field flow channel structure as a physical model, and can realize the analysis of the influence of the cell structure design on the cell performance. The single cell CFD numerical calculation model considers conservation models of flow, heat transfer, mass transfer, electrochemical reaction, current transmission and the like.
In some embodiments, corresponding flow field pressure drop of the monocell can be accurately obtained by giving corresponding inlet flow to different working conditions of the CFD numerical calculation model of the monocell, data analysis is carried out on a calculated flow resistance curve of the monocell, and a function relation of speed and pressure drop is fitted; calculating and simulating a speed-pressure drop curve of the single cell CFD numerical calculation model to obtain an inertial resistance coefficient of the single cell CFD porous medium numerical modelAnd coefficient of viscous dragAnd conditions are provided for further uniform distribution calculation of the galvanic pile fluid.
Specifically, different excess coefficients are given to the fluid channels (hydrogen, air, water) of the single-cell CFD numerical calculation modelLower inlet flowAnd simulating to obtain the voltage drop of the corresponding single cell CFD numerical calculation model(non-actual measurement flow resistance), converting the flow into a speed value v under the corresponding inlet structure size, acquiring speed values of different flows, calculating the speed value v of the model according to the single cell CFD numerical value, simulating to obtain the pressure drop of the single cell CFD numerical value calculation model corresponding to the different speed values v, and calculating the functional relation formula of the speed and the pressure drop of the model according to the single cell CFD numerical value。
In some embodiments, the velocity as a function of pressure drop for the model is calculated from the single cell CFD valuesObtaining the inertial resistance coefficient of the single cell CFD porous medium numerical calculation modelAnd coefficient of viscous drag。
Specifically, in fluid calculations, the porous medium region is reduced to a fluid region where the source of resistance is increased, in a manner that provides a velocity-dependent momentum sink in the porous region, expressed as:in the formula (I), wherein,a source term of the momentum equation in the ith (x, y, z) direction;is a speed value; d and C are designated matrixes, and the first term on the right side in the formula is a viscous loss term and the second term is an inertial loss term.
For a homogeneous porous medium, then the rewritables are:in the formula (I), wherein,in order to be able to determine the permeability,in order to be the coefficient of inertial resistance,is the coefficient of viscous drag. At this time, the matrix D is. The momentum sink acts on the fluid to create a pressure gradient,that is to say haveTo do soIs the thickness of the porous media domain. The fluid flows through the single cell CFD numerical calculation model in a function of the speed and the pressure drop,wherein。
In some embodiments, the cross-sectional dimension of the single cell CFD porous medium numerical calculation model is set as the cross-sectional dimension of a bipolar plate flow field flow channel structure in the single cell CFD numerical calculation model; and setting the height direction dimension of the single cell CFD porous medium numerical calculation model as the depth direction dimension of a bipolar plate flow field flow channel structure in the single cell CFD numerical calculation model.
In some embodiments, the single cell-single stack CFD porous medium numerical model of the fuel cell stack is established by setting the single cell CFD porous medium numerical calculation model as a porous medium region, setting the stack common channel CFD numerical calculation model as a fluid region; carrying out grid division on a single cell-stack CFD porous medium numerical calculation model of the fuel cell stack; in the single cell-stack CFD porous medium numerical calculation model of the fuel cell stack, resistance pressure drop of each single cell is equivalently replaced by the single cell CFD porous medium numerical model, the single cell CFD numerical calculation model is obtained by an actual single cell real geometric structure (comprising a plurality of flow channels, bridges and other structures), but if the single cell CFD numerical calculation model is directly applied to single cell-stack simulation, the model is complex, so that equivalent replacement and simplification need to be carried out on the single cell CFD numerical calculation model in calculation, and the single cell CFD porous medium numerical model is obtained as a result of replacement and simplification. The connection between the single cell CFD numerical calculation model and the single cell CFD porous medium numerical model is equivalent to a black box, and the same pressure drop can be fed back given the same inlet flow.
Specifically, the invention sets the flow area of the fuel battery single cells and the common channel as 100 percent, optimizes and adjusts the inlet and outlet common channel structure of the fuel battery electric pile so that the flow distribution variation coefficient CV of the fuel battery electric pile meets a first target design value, and the total pressure drop of the inlet and outlet of the fuel battery electric pile meets a first target design valueSatisfying a second target design value, a cell flow excess coefficient in the fuel cell stackUnevenness ofSatisfying a third target design value, a cell voltage drop in the fuel cell stackThe fourth target design value is satisfied.
And taking the inlet and outlet common channel structures of the fuel cell electric stacks meeting the conditions as the inlet and outlet common channel structures of the target fuel cell electric stacks.
Specifically, the static pressure of the fluid flowing in the common channel is perpendicular to the side walls. And static pressure difference exists between the common channel and the two sides of the single cell connecting hole, and fluid can flow out of the hole in the direction perpendicular to the side wall. According to the theory of hydrodynamics, the flow velocity resulting from the effect of the static pressure difference is:
(1) (ii) a The flow rate of the fluid in the common channel is as follows:(2) In the formula:static pressure in the public channel;is the dynamic pressure in the common channel.
Thus, the actual flow rate and the direction of outflow of the fluid from the orifice are influenced by the flow rate in the utility channel in addition to the flow rate and direction resulting from the static pressure. As shown in fig. 1, the outflow direction in the hole is deflected under the influence of the flow velocity in the common channel, and the actual outlet flow direction from the orifice makes an angle α with the axis of the common channel. Defining the area of the orificeProjected area of orifice perpendicular to direction of fluid flowThe actual orifice flow rate v, has:(3) (ii) a The orifice outflow is:(4) In the formulaIs the orifice flow coefficient. It can be seen from the analysis of equation (4) that to achieve uniform distribution of fluid among the cells, a reduction in orifice area can be adoptedThe method (1) is carried out.
The invention only changes the shape and size of the common channel when improving the structure of the common channel of the fuel cell stack, but actually changes the orifice area at the joint of the single cells and the common channel by adopting a U-shaped necking mode, as shown in figure 2, the orifice area is reduced by adopting the U-shaped necking mode to realize the uniform distribution of fluid among the single cells. Specifically, at the connection between the common channel and each single cell airflow inlet, a bidirectional extension baffle or a unidirectional extension baffle (collectively extending leftwards or rightwards) is arranged at the single cell airflow inlet, so that the orifice area of the single cells is reduced, and the fluid entering from the common channel is uniformly distributed among the single cells.
Further, a variable flow area structure of a single cell and a common channel in the fuel cell stack is optimized according to a simulation calculation result of the single cell-stack CFD porous medium numerical calculation model, so that a flow distribution variation coefficient CV of the fuel cell stack meets a fifth target design value, and total pressure drops at an inlet and an outlet of the fuel cell stack meet a fifth target design valueSatisfying a sixth target design value, a cell flow excess coefficient in the fuel cell stackUnevenness ofSatisfying a seventh target design value, a cell voltage drop in the fuel cell stackThe eighth target design value is satisfied.
Specifically, a structural schematic diagram of the single cell CFD porous medium numerical calculation model is shown in fig. 3, wherein fig. 4 is a structural schematic diagram of a variable flow area of a single cell and a common channel. In the present embodiment, the single cell and common channel variable flow area structure of the fuel cell stack satisfying the above conditions is used as a target single cell and common channel variable flow area structure of the fuel cell stack.
In some embodiments, the flow distribution coefficient of variation CV of the fuel cell stack is calculated as follows:wherein, in the step (A),the flow rate of the ith single cell of the fuel cell stack is measured; n is the total number of single cells of the fuel cell stack,the average flow rate of each single cell of the fuel cell stack.
In some embodiments, the total pressure drop of the inlet and the outlet of the fuel cell stackCalculated according to the following formula:wherein, in the process,calculating an inlet average static pressure value of a model for the single cell CFD porous medium numerical value;and calculating the outlet average static pressure value of the model for the single cell CFD porous medium numerical value.
In some embodiments, each cell flow excess factor in the fuel cell stackUnevenness ofCalculated according to the following formula:wherein, in the step (A),the flow excess coefficient of the ith single cell is obtained; and n is the total number of single cells of the fuel cell stack.
In some embodiments, the cell voltage drop in the fuel cell stackCalculated according to the following formula:wherein, in the step (A),the inlet static pressure value of the ith single cell,the outlet static pressure value of the ith single cell is shown.
The following further explains the optimization method of the fuel cell stack channel structure according to the present invention by specific embodiments:
example 1 (A: 100% + 100%)
The optimization method is applied to a cell stack consisting of 600 single cells, and the channel structure of the cell stack is subjected to simulation calculation, analysis and evaluation:
s1, constructing a single cell CFD numerical calculation model by using three-dimensional modeling software according to a single cell geometric structure of a fuel cell stack, wherein the three-dimensional modeling software can be CATIA software, but is not limited to the CATIA software;
s2, importing the single cell CFD numerical calculation model constructed in the step S1 into grid division software for grid division to obtain a grid model and ensure grid quality, wherein the grid division software can be ICEM software, but is not limited to ICEM software;
s3, introducing the grid model into fluid calculation software to select a relevant model, determine boundary conditions and set solving parameters, wherein the inlet boundary conditions are set as follows: for different working conditions of the single cell CFD numerical calculation model, corresponding single cell inlet flow under different excess coefficients is given, and single cell inlet flow velocity is obtained through conversion according to the flow area of a common channel and a single cell, wherein the fluid calculation software can be fluent software, but is not limited to the fluent software;
s4, simulating and calculating the corresponding CFD numerical calculation model flow field pressure drop delta P of the single cell, wherein the pressure drop delta P is shown in a table 1:
TABLE 1
S5, performing data analysis on the calculated flow resistance curve of the single cell, and fitting a function relation of the inlet flow velocity and the pressure drop of the CFD numerical calculation model of the single cell;;
s6, calculating the inlet flow rate and the inlet flow rate of the model according to the single cell CFD numerical value obtained in the step S5Pressure drop function, density of 1.225kg/m for air working operating conditions, kinematic viscosity of 1.79E-05kg/m/s for working operating conditions, effective length of single cell CFD porous medium numerical modelCalculating the inertial resistance coefficient of the single cell CFD porous medium numerical calculation modelAnd coefficient of viscous dragThe results are shown in Table 2, in which,,;
TABLE 2
S7, constructing a single cell CFD porous medium numerical calculation model by using three-dimensional modeling software based on the single cell CFD numerical calculation model constructed in the step S1, and setting the cross section size of the single cell CFD porous medium numerical calculation model as the cross section size of a bipolar plate flow field flow channel structure in the single cell CFD numerical calculation model; setting the height direction size of the single cell CFD porous medium numerical calculation model as the depth direction size of a bipolar plate flow field flow channel structure in the single cell CFD numerical calculation model;
s8, constructing a geometric model of a flow field of an air channel of the fuel cell by using three-dimensional modeling software according to the structure of the fuel cell stack, wherein the geometric model is a structural schematic diagram of a numerical calculation model of a single cell-single stack CFD porous medium shown in FIG 3;
s9, 1 in figure 3 is a common inlet channel of the fuel cell stack, which is arranged as a fluidA domain; FIG. 3 shows a fuel cell stack outlet common channel at 3, arranged in the fluid domain; in fig. 3, 2 is a stack of 600 single-cell CFD porous medium numerical calculation models, the geometric structure of which is obtained in step S7 and is set as a porous medium domain, and the parameter viscosity resistance coefficient of the porous medium model of which is set as the porous medium domainAnd coefficient of inertial resistanceThe obtaining by step S6;
s10, importing the single cell-single pile CFD porous medium numerical calculation model into grid division software for grid division to obtain a single cell-single pile CFD porous medium numerical calculation grid model and ensure grid quality;
s11, introducing the single cell-single pile CFD porous medium numerical calculation grid model into fluid calculation software to select related models, determine boundary conditions and set solving parameters. Wherein the entry boundary conditions are set as follows: for the numerical calculation model of the single cell-single pile CFD porous medium, giving corresponding cell pile inlet flow under the condition that an excess coefficient is 1.7 (or other excess coefficients); the exit boundary conditions were set as follows: a pressure outlet boundary; the operating pressure was set to 101325Pa;
s12, simulating and calculating a corresponding single cell-single pile CFD porous medium numerical calculation model, and performing post-processing on the calculation result to obtain the average flow of 600 single cells:
and then calculating to obtain a flow distribution variation coefficient CV of the fuel cell stack:
through the post-processing analysis of the calculation result, the CV value of the numerical calculation model of the single cell-single pile CFD porous medium before optimization can be obtained to be 5.815%.
Analyzing the result, selecting the inlet boundary surface of the inlet common channel to obtain the average static pressure value of the inlet(ii) a Selecting the outlet boundary surface of the common channel of the outlet to obtain the average static pressure value of the outletTotal pressure drop of inlet and outlet of the fuel cell stackCalculated according to the following formula:
Post-processing the calculation results to obtain the flow excess coefficient of each single battery of 600 single batteriesThe minimum excess factor is not 1.602, and the maximum excess factor is 1.920;
fig. 5 is a schematic diagram of a cell excess coefficient distribution curve.
Post-processing and analyzing the calculation result, and respectively selecting the interfaces of the common channel at the inlet of the cell stack and 600 single cells to obtain the inlet static pressure value of each single cell(ii) a Respectively selecting the interfaces of the common channel at the outlet of the electric pile and 600 single cells to obtain the outlet static pressure value of each single cell;
The voltage drop of each single cell in the fuel cell stackCalculated according to the following formula:;
fig. 6 is a schematic diagram of the pressure drop distribution curve of each unit cell of the fuel cell stack.
Table 3 is the static pressure distribution of the single cell-stack porous medium model of example 1, which includes the inlet average static pressure value of the inlet common channel and the outlet average static pressure value of the outlet common channel; for convenience of calculation, the inlet static pressure value of each 20 single cells, the outlet static pressure value of each 20 single cells and the pressure drop of each 20 single cells are respectively selected for statistical analysis.
TABLE 3
Example 2 (B: 50% + 100%)
And after the inlet and outlet common channel structure of the fuel cell stack is optimized and determined, optimizing the variable flow area structure of the single cell and the common channel in the fuel cell stack according to the simulation calculation result of the CFD (computational fluid dynamics) porous medium numerical calculation model of the single cell-stack.
In the embodiment 2, the orifice area (50% of the maximum orifice area) at the gas inlet is reduced in a necking mode by changing the interface flow area of the common inlet channel of the fuel cell stack and each single cell, so that the uniform distribution of the fluid among the single cells is realized.
Fig. 4 is a schematic view of a variable flow area structure of a single cell and a common channel.
The simulation calculation procedure was the same as S1 to S11 in example 1.
S12, simulating and calculating a corresponding single cell-single pile CFD porous medium numerical calculation model, and performing post-processing on the calculation result to obtain the average flow of 600 single cells:
and further calculating and obtaining a flow distribution variation coefficient CV of the fuel cell stack:
through the post-processing analysis of the calculation result, the CV value of the numerical calculation model of the single cell-single pile CFD porous medium before optimization is 3.350 percent, and the CV calculation value is reduced compared with that of the example 1.
Analyzing the result, selecting the inlet boundary surface of the inlet common channel to obtain the average static pressure value of the inlet(ii) a Selecting the outlet boundary surface of the common channel of the outlet to obtain the average static pressure value of the outletThen the total pressure drop of the inlet and outlet of the fuel cell stack is reducedCalculated according to the following formula:
The calculation results are post-processed to obtain the flow excess coefficient of each single battery of 600 single batteriesMinimum excess factor of not 1.650The maximum excess factor was 1.837.
Fig. 5 is a schematic view of a cell excess coefficient distribution curve.
Post-processing and analyzing the calculation result, and respectively selecting the interfaces of the common channel at the inlet of the cell stack and 600 single cells to obtain the inlet static pressure value of each single cell(ii) a Respectively selecting the interfaces of the common channel at the outlet of the electric pile and 600 single cells to obtain the outlet static pressure value of each single cell;
The voltage drop of each single cell in the fuel cell stackCalculated according to the following formula:;
fig. 6 is a schematic diagram of the pressure drop distribution curve of each unit cell of the fuel cell stack.
Table 4 shows the model static pressure distribution of the single cell-stack porous medium in example 2, including the inlet average static pressure value of the inlet common channel and the outlet average static pressure value of the outlet common channel; for the convenience of calculation, the inlet static pressure value of every 20 single cells, the outlet static pressure value of every 20 single cells and the pressure drop of every 20 single cells are respectively selected for statistical analysis.
TABLE 4
Through comparative analysis, the flow distribution variation coefficient CV, the excess coefficient distribution of each single cell and the pressure drop of each single cell of the fuel cell stack in the embodiment 2 are optimized by optimizing the variable flow area structure of the single cell and the common channel in the fuel cell stackComparative example 1 was optimized.
Example 3 (C: 100% + 50%)
And after the inlet and outlet common channel structures of the fuel cell stack are optimized and determined, optimizing the variable flow area structure of the single cell and the common channel in the fuel cell stack according to the simulation calculation result of the single cell-stack CFD porous medium numerical calculation model.
In the embodiment 2, the orifice area (50% of the maximum orifice area) at the gas outlet is reduced in a necking mode by changing the interface flow area of the common inlet channel of the fuel cell stack and each single cell, so that the uniform distribution of the fluid among the single cells is realized.
The simulation calculation procedure was the same as S1 to S11 in example 1.
S12, simulating and calculating a corresponding single cell-single pile CFD porous medium numerical calculation model, and performing post-processing on the calculation result to obtain the average flow of 600 single cells:
and then calculating to obtain a flow distribution variation coefficient CV of the fuel cell stack:
through the post-processing analysis of the calculation result, the CV value of the numerical calculation model of the single cell-single pile CFD porous medium before optimization is 5.521%, and the CV calculation value is not much different from that of the example 1.
Analyzing the result, selecting inlet boundary surface of inlet common channel to obtain average static pressure value(ii) a Selecting the outlet boundary surface of the common channel of the outlet to obtain the average static pressure value of the outletTotal pressure drop of inlet and outlet of the fuel cell stackCalculated according to the following formula:
The calculation results are post-processed to obtain the flow excess coefficient of each single battery of 600 single batteriesThe minimum excess factor is not 1.609 and the maximum excess factor is 1.908.
Fig. 5 is a schematic diagram of a cell excess coefficient distribution curve.
Post-processing and analyzing the calculation result, and respectively selecting interfaces of a common channel of the cell stack inlet and 600 single cells to obtain the inlet static pressure value of each single cell(ii) a Respectively selecting the interfaces of the common channel at the outlet of the electric pile and 600 single cells to obtain the outlet static pressure value of each single cell;
The voltage drop of each single cell in the fuel cell stackCalculated according to the following formula:;
fig. 6 is a schematic diagram of the pressure drop distribution curve of each single cell of the fuel cell stack.
Through comparative analysis, the purpose of optimizing the variable flow area structure of the single cell and the common channel in the fuel cell stack cannot be achieved by reducing the orifice area at the gas outlet in a necking mode, and the flow distribution variation coefficient CV, the excess coefficient distribution of each single cell and the pressure drop of each single cell of the stack in the embodiment 2Comparative example 1 was not much changed.
Example 4 (D: 40% + 100%)
And after the inlet and outlet common channel structure of the fuel cell stack is optimized and determined, optimizing the variable flow area structure of the single cell and the common channel in the fuel cell stack according to the simulation calculation result of the CFD (computational fluid dynamics) porous medium numerical calculation model of the single cell-stack.
In the embodiment 4, the orifice area (40% of the maximum orifice area) at the gas inlet is reduced in a necking mode by changing the interface flow area of the common inlet channel of the fuel cell stack and each single cell, so as to realize uniform distribution of fluid among the single cells.
Fig. 4 is a schematic view of the variable flow area structure of the single cell and the common channel.
The simulation calculation procedure was the same as S1 to S11 in example 1.
S12, simulating and calculating a corresponding single cell-single pile CFD porous medium numerical calculation model, and performing post-processing on the calculation result to obtain the average flow of 600 single cells:
and further calculating and obtaining a flow distribution variation coefficient CV of the fuel cell stack:
through the post-processing analysis of the calculation result, the CV value of the numerical calculation model of the single cell-single pile CFD porous medium before optimization is 2.356 percent, and the calculated CV value is obviously reduced compared with the calculated CV value in example 1.
Analyzing the result, selecting the inlet boundary surface of the inlet common channel to obtain the average static pressure value of the inlet(ii) a Selecting the outlet boundary surface of the common channel of the outlet to obtain the average static pressure value of the outletThen the total pressure drop of the inlet and outlet of the fuel cell stack is reducedCalculated according to the following formula:
The calculation results are post-processed to obtain the flow excess coefficient of each single battery of 600 single batteriesThe minimum excess factor is not 1.662 and the maximum excess factor is 1.805.
Fig. 5 is a schematic diagram of a cell excess coefficient distribution curve.
Post-processing and analyzing the calculation result, and respectively selecting the interfaces of the common channel at the inlet of the cell stack and 600 single cells to obtain the inlet static pressure value of each single cell(ii) a Respectively selecting the interfaces of the common channel at the outlet of the electric pile and 600 single batteries,obtaining the outlet static pressure value of each single cell;
The voltage drop of each single cell in the fuel cell stackCalculated according to the following formula:;
fig. 6 is a schematic diagram of the pressure drop distribution curve of each unit cell of the fuel cell stack.
Through comparative analysis, the flow distribution coefficient of variation CV, the excess coefficient distribution of each single cell and the pressure drop of each single cell of the fuel cell stack of example 4 were obtained by optimizing the variable flow area structure of the single cell and the common channel in the fuel cell stackCompared with the embodiment 1, the method has larger optimization.
Example 5 (E: 33.3% + 100%)
And after the inlet and outlet common channel structure of the fuel cell stack is optimized and determined, optimizing the variable flow area structure of the single cell and the common channel in the fuel cell stack according to the simulation calculation result of the CFD (computational fluid dynamics) porous medium numerical calculation model of the single cell-stack.
In the embodiment 5, the orifice area at the gas inlet (which is 33.3 percent of the maximum orifice area) is reduced in a necking mode by changing the interface flow area of the common inlet channel of the fuel cell stack and each single cell so as to realize uniform distribution of the fluid among the single cells.
Fig. 4 is a schematic view of the variable flow area structure of the single cell and the common channel.
The simulation calculation procedure was the same as S1 to S11 in example 1.
S12, simulating and calculating a corresponding single cell-single pile CFD porous medium numerical calculation model, and performing post-processing on the calculation result to obtain the average flow of 600 single cells:
and further calculating and obtaining a flow distribution variation coefficient CV of the fuel cell stack:
through the post-processing analysis of the calculation result, the CV value of the numerical calculation model of the single cell-single pile CFD porous medium before optimization is 1.579%, and the CV calculation value is obviously reduced compared with that of the example 1.
Analyzing the result, selecting the inlet boundary surface of the inlet common channel to obtain the average static pressure value of the inlet(ii) a Selecting the outlet boundary surface of the common channel of the outlet to obtain the average static pressure value of the outletTotal pressure drop of inlet and outlet of the fuel cell stackCalculated according to the following formula:
The calculation results are post-processed to obtain the flow excess coefficient of each single battery of 600 single batteriesThe minimum excess factor is not 1.669 and the maximum excess factor is 1.754.
Fig. 5 is a schematic diagram of a cell excess coefficient distribution curve.
Post-processing and analyzing the calculation result, and respectively selecting the interfaces of the common channel at the inlet of the cell stack and 600 single cells to obtain the inlet static pressure value of each single cell(ii) a Respectively selecting the interfaces of the common channel at the outlet of the electric pile and 600 single cells to obtain the outlet static pressure value of each single cell;
The voltage drop of each single cell in the fuel cell stackCalculated according to the following formula:;
fig. 6 is a schematic diagram of the pressure drop distribution curve of each unit cell of the fuel cell stack.
Through comparative analysis, the flow distribution variation coefficient CV, the excess coefficient distribution of each single cell and the pressure drop of each single cell of the fuel cell stack in example 5 were obtained by optimizing the variable flow area structure of the single cell and the common channel in the fuel cell stackComparative example 1 was optimized.
In some embodiments, there is also provided a storage medium storing one or more programs executable by one or more processors to implement the steps in the optimization method of a fuel cell stack channel structure of the present invention.
In some embodiments, there is also provided a fuel cell stack channel structure optimization system, as shown in fig. 7, which includes at least one processor (processor) 20; a display screen 21; and a memory (memory) 22, and may further include a communication Interface (Communications Interface) 23 and a bus 24. The processor 20, the display 21, the memory 22 and the communication interface 23 can communicate with each other through the bus 24. The display screen 21 is configured to display a user guidance interface preset in the initial setting mode. The communication interface 23 may transmit information. Processor 20 may call logic instructions in memory 22 to perform the methods in the embodiments described above.
Furthermore, the logic instructions in the memory 22 may be implemented in software functional units and stored in a computer readable storage medium when sold or used as a stand-alone product.
The memory 22, which is a computer-readable storage medium, may be configured to store a software program, a computer-executable program, such as program instructions or modules corresponding to the methods in the embodiments of the present disclosure. The processor 20 executes the functional applications and data processing, i.e. implements the methods in the above embodiments, by running software programs, instructions or modules stored in the memory 22.
The memory 22 may include a storage program area and a storage data area, wherein the storage program area may store an operating system, an application program required for at least one function; the storage data area may store data created according to the use of the terminal device, and the like. Further, the memory 22 may include a high speed random access memory and may also include a non-volatile memory. For example, a variety of media that can store program codes, such as a usb disk, a removable hard disk, a Read-Only Memory (ROM), a Random Access Memory (RAM), a magnetic disk, or an optical disk, may also be transient storage media.
In addition, the specific processes loaded and executed by the storage medium and the instruction processors in the terminal device are described in detail in the above method, and are not stated herein.
It is to be understood that the invention is not limited to the examples described above, but that modifications and variations may be effected thereto by those of ordinary skill in the art in light of the foregoing description, and that all such modifications and variations are intended to be within the scope of the invention as defined by the appended claims.
Claims (6)
1. A method for optimizing a channel structure of a fuel cell stack, comprising the steps of:
constructing a single cell CFD numerical calculation model according to a single cell geometric structure of the fuel cell stack;
constructing a single cell CFD porous medium numerical calculation model based on the single cell CFD numerical calculation model according to the variable flow area structure of the single cell and the common channel;
constructing a CFD numerical calculation model of the common channel of the fuel cell stack according to the geometric structure of the common channel of the fuel cell stack;
establishing a single cell-electric pile CFD porous medium numerical calculation model according to the single cell CFD porous medium numerical calculation model and the electric pile common channel CFD numerical calculation model;
optimizing the inlet and outlet common channel structure of the fuel cell stack according to the simulation calculation result of the single cell-stack CFD porous medium numerical calculation model, so that the flow distribution variation coefficient CV of the fuel cell stack meets a first target design value, and the total pressure drop of the inlet and outlet of the fuel cell stack meets a first target design valueSatisfying a second target design value, and calculating the flow excess coefficient of each single cell in the fuel cell stackUnevenness ofSatisfying a third target design value, and reducing the voltage drop of each single cell in the fuel cell stackSatisfy the followingFour target design values, wherein the flow distribution Coefficient of Variation (CV) of the fuel cell stack is calculated according to the following formula:wherein, in the process,the flow rate of the ith single cell of the fuel cell stack is shown, n is the total number of single cells of the fuel cell stack,the average flow rate of each single cell of the fuel cell stack; the total pressure drop of the inlet and the outlet of the fuel cell stackCalculated according to the following formula:wherein, in the process,calculating an inlet average static pressure value of a model for the single cell CFD porous medium numerical value;calculating an outlet average static pressure value of a model for the single cell CFD porous medium numerical value; flow excess coefficient of each single cell in the fuel cell stackUnevenness ofCalculated according to the following formula:wherein, in the step (A),the flow excess coefficient of the ith single cell is set; n is the total number of single cells of the fuel cell stack; single cell pressure drop in the fuel cell stackCalculated according to the following formula:wherein, in the step (A),the inlet static pressure value of the ith single cell,the outlet static pressure value of the ith single cell is obtained;
after the inlet and outlet common channel structure of the fuel cell stack is optimized and determined, the variable flow area structure of a single cell and a common channel in the fuel cell stack is optimized according to the simulation calculation result of the CFD numerical computation model of the single cell-stack, so that the flow distribution variation coefficient CV of the fuel cell stack meets a fifth target design value, and the total pressure drop of the inlet and outlet of the fuel cell stackA sixth target design value is satisfied, and a single cell flow excess coefficient in the fuel cell stackUnevenness ofSatisfying a seventh target design value, the fuelCell voltage drop in a battery stackThe eighth target design value is met, the variable flow area structure of the single cells and the common channel in the fuel cell stack is improved by changing the orifice area at the joint of the single cells and the common channel in a U-shaped necking mode, and the orifice area of the single cells is reduced by arranging a bidirectional extension baffle or a unidirectional extension baffle at the airflow inlet of the single cells, so that the fluid entering from the common channel is uniformly distributed among the single cells.
2. The method for optimizing the channel structure of the fuel cell stack according to claim 1, wherein the step of constructing the CFD numerical calculation model of the single cell based on the CFD numerical calculation model of the single cell according to the variable flow area structure of the single cell and the common channel comprises the following steps:
the single cell CFD numerical calculation model comprises a bipolar plate with a flow field flow channel structure, a gas diffusion layer, a microporous layer, a catalytic layer and a proton exchange membrane;
setting the cross section size of the single cell CFD porous medium numerical calculation model as the cross section size of a bipolar plate flow field flow channel structure in the single cell CFD numerical calculation model; and setting the height direction dimension of the single cell CFD porous medium numerical calculation model as the depth direction dimension of a bipolar plate flow field flow channel structure in the single cell CFD numerical calculation model.
3. The method for optimizing the channel structure of the fuel cell stack according to claim 2, further comprising the steps of:
giving corresponding inlet flow to different working conditions of the single cell CFD numerical calculation model to obtain corresponding single cell flow field pressure drop, performing data analysis on a calculated flow resistance curve of the single cell, and fitting a function relation of speed and pressure drop;
4. The method for optimizing the channel structure of the fuel cell stack according to claim 2, wherein the step of establishing the numerical calculation model of the CFD porous medium of the single cell-stack according to the numerical calculation model of the CFD porous medium of the single cell and the numerical calculation model of the CFD porous medium of the common channel of the stack comprises the steps of:
and setting the CFD numerical calculation model of the single cell as a porous medium area, setting the CFD numerical calculation model of the common channel of the fuel cell stack as a fluid area, and establishing a single cell-single stack CFD numerical model of the fuel cell stack.
5. A storage medium storing one or more programs, the one or more programs being executable by one or more processors to perform the steps of the method for optimizing a channel structure of a fuel cell stack according to any one of claims 1 to 4.
6. A system for optimizing a channel structure of a fuel cell stack, comprising: a processor, a memory, and a communication bus; the memory has stored thereon a computer readable program executable by the processor;
the communication bus realizes the connection communication between the processor and the memory;
the processor, when executing the computer readable program, implements the steps in the method for optimizing a channel structure of a fuel cell stack according to any one of claims 1 to 4.
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