CN115287001A - Water-based polyurea color sand crack beautifying agent - Google Patents

Water-based polyurea color sand crack beautifying agent Download PDF

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Publication number
CN115287001A
CN115287001A CN202210929883.9A CN202210929883A CN115287001A CN 115287001 A CN115287001 A CN 115287001A CN 202210929883 A CN202210929883 A CN 202210929883A CN 115287001 A CN115287001 A CN 115287001A
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CN
China
Prior art keywords
parts
agent
color sand
isocyanate
water
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Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN202210929883.9A
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Chinese (zh)
Inventor
涂青
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Meizhou Jincheng Waterproof Material Co ltd
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Meizhou Jincheng Waterproof Material Co ltd
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Priority to CN202210929883.9A priority Critical patent/CN115287001A/en
Publication of CN115287001A publication Critical patent/CN115287001A/en
Pending legal-status Critical Current

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    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09JADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J4/00Adhesives based on organic non-macromolecular compounds having at least one polymerisable carbon-to-carbon unsaturated bond ; adhesives, based on monomers of macromolecular compounds of groups C09J183/00 - C09J183/16
    • C09J4/06Organic non-macromolecular compounds having at least one polymerisable carbon-to-carbon unsaturated bond in combination with a macromolecular compound other than an unsaturated polymer of groups C09J159/00 - C09J187/00
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09JADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J11/00Features of adhesives not provided for in group C09J9/00, e.g. additives
    • C09J11/02Non-macromolecular additives
    • C09J11/06Non-macromolecular additives organic
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09JADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J11/00Features of adhesives not provided for in group C09J9/00, e.g. additives
    • C09J11/08Macromolecular additives

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Paints Or Removers (AREA)
  • Compositions Of Macromolecular Compounds (AREA)

Abstract

The invention discloses a water-based polyurea color sand crack beautifying agent, which comprises the following components in part by weight: the paint comprises polyaspartic acid resin, isocyanate, methacrylic acid, a toughening agent, an organic silicon defoaming agent, a thickening agent and a pigment, wherein the polyaspartic acid resin comprises the following components in parts by weight: 50-60 parts of polyaspartic acid resin, 32-38 parts of isocyanate, 2-4 parts of methacrylic acid, 6-10 parts of toughening agent, 1-4 parts of organic silicon defoaming agent, 2-4 parts of thickening agent and 1-3 parts of pigment; the water-based polyurea color sand synthesized by polyaspartic acid resin and isocyanate is used as a main material, replaces the traditional epoxy crack sealer, has strong heat resistance and weather resistance, is not yellowed after long-time sunlight irradiation, is durable and yellow-resistant, ensures the attractiveness of brick joints, improves the toughness of the crack sealer by adding the flexibilizer, has high tensile strength, is not easy to crack in the using process, avoids the invasion problem of dirt, and has good user experience.

Description

Water-based polyurea color sand crack beautifying agent
Technical Field
The invention relates to the technical field of crack beautifying agents, and particularly relates to a water-based polyurea color sand crack beautifying agent.
Background
The crack beautifying agent is used for beautifying the crack between wall and floor tile, is suitable for decorating the crack between ceramic tile, mosaic tile, stone material, wood board, glass, plastic-aluminum board and other material, and is used for covering ceramic tile in toilet, kitchen and floor. However, most of the traditional crack sealer is made of epoxy resin materials, so that the heat resistance and the weather resistance are poor, the yellowing problem easily occurs after the sunlight is irradiated for a long time, the attractiveness of brick joints is influenced, the toughness is poor, the tensile strength is low, the cracking problem easily occurs in the use process, dirt enters cracks, the user experience is poor, in addition, more residual gas and water exist, the bonding strength of the crack sealer is inevitably influenced, the crack sealer is easy to fall off after crack filling and curing, and the working reliability is poor.
Disclosure of Invention
The invention aims to provide a water-based polyurea color sand crack beautifying agent to solve the problems in the background technology.
In order to achieve the purpose, the invention provides the following technical scheme: the water-based polyurea color sand crack beautifying agent comprises the following components in percentage by weight: the paint comprises polyaspartic acid resin, isocyanate, methacrylic acid, a toughening agent, an organic silicon defoaming agent, a thickening agent and a pigment, wherein the polyaspartic acid resin comprises the following components in parts by weight: 50-60 parts of polyaspartic acid resin, 32-38 parts of isocyanate, 2-4 parts of methacrylic acid, 6-10 parts of toughening agent, 1-4 parts of organic silicon defoaming agent, 2-4 parts of thickening agent and 1-3 parts of pigment.
Preferably, the isocyanate is any one of methylene diisocyanate and isophorone isocyanate.
Preferably, the toughening agent is formed by mixing polystyrene, polysulfide rubber and ABS resin, and the weight ratio of the polystyrene to the polysulfide rubber to the ABS resin is 5: 1: 2.
Preferably, the silicone defoaming agent is formed by mixing fluorosilicone, ethylene glycol siloxane and polydimethylsiloxane, and the weight ratio of the fluorosilicone to the ethylene glycol siloxane to the polydimethylsiloxane is 1: 2.
Preferably, the thickening agent is formed by mixing pectin, agar, seaweed gel and carrageenan, and the weight ratio of the pectin to the agar to the seaweed gel to the carrageenan is 3: 1: 2: 1.
Preferably, the pigment is any one or two of cochineal red, chrome yellow, cobalt blue, iron oxide black and titanium dioxide.
Compared with the prior art, the invention has the beneficial effects that: the water-based polyurea color sand crack beautifying agent adopts water-based polyurea color sand synthesized by polyaspartic acid resin and isocyanate as a main material, replaces the traditional epoxy crack beautifying agent, has strong heat resistance and weather resistance, is not yellowed by long-time sunlight irradiation, is durable and yellow, and ensures the attractiveness of brick joints; the toughening agent formed by mixing the polystyrene, the polysulfide rubber and the ABS resin is added, so that the toughness of the seam beautifying agent is improved, the tensile strength is high, the seam beautifying agent is not easy to crack in the using process, the problem of dirt invasion is avoided, and the user experience is good; by adding the organic silicon defoaming agent and the thickening agent, residual gas and moisture of the seam beautifying agent are effectively removed, the bonding strength of the seam beautifying agent is improved, the seam beautifying agent is not easy to fall off after filling and curing, and the work is more reliable.
Detailed Description
The technical solutions in the embodiments of the present invention will be described clearly and completely below, and it is obvious that the described embodiments are only a part of the embodiments of the present invention, and not all of the embodiments. All other embodiments, which can be derived by a person skilled in the art from the embodiments given herein without making any creative effort, shall fall within the protection scope of the present invention.
The invention provides a technical scheme that:
example 1:
the water-based polyurea color sand crack beautifying agent comprises the following components in percentage by weight: the paint comprises polyaspartic acid ester resin, isocyanate, methacrylic acid, a flexibilizer, an organic silicon defoamer, a thickening agent and a pigment, wherein the polyaspartic acid ester resin comprises the following components in parts by weight: 50 parts of polyaspartic acid resin, 32 parts of isocyanate, 2 parts of methacrylic acid, 6 parts of a toughening agent, 1 part of an organic silicon defoaming agent, 2 parts of a thickening agent and 1 part of pigment, wherein the isocyanate selects any one of methylene diisocyanate and isophorone isocyanate, the toughening agent is formed by mixing polystyrene, polysulfide rubber and ABS resin in a weight ratio of 5: 1: 2, the organic silicon defoaming agent is formed by mixing fluorosilicone, ethylene glycol siloxane and polydimethylsiloxane in a weight ratio of 1: 2, the thickening agent is formed by mixing pectin, agar, seaweed and carrageenan in a weight ratio of 3: 1: 2: 1, and the pigment selects any one or two of cochineal, chrome yellow, cobalt blue, iron oxide black and titanium white.
Example 2:
a water-based polyurea color sand crack beautifying agent is disclosed, and the formula comprises: the paint comprises polyaspartic acid resin, isocyanate, methacrylic acid, a toughening agent, an organic silicon defoaming agent, a thickening agent and a pigment, wherein the polyaspartic acid resin comprises the following components in parts by weight: 55 parts of polyaspartic acid ester resin, 35 parts of isocyanate, 3 parts of methacrylic acid, 8 parts of flexibilizer, 3 parts of organic silicon defoamer, 3 parts of thickener and 2 parts of pigment, wherein the isocyanate is selected from any one of methylene diisocyanate and isophorone isocyanate, the flexibilizer is formed by mixing polystyrene, polysulfide rubber and ABS resin according to the weight ratio of 5: 1: 2, the organic silicon defoamer is formed by mixing fluorosilicone, ethylene glycol siloxane and polydimethylsiloxane according to the weight ratio of 1: 2, the thickener is formed by mixing pectin, agar, seaweed and carrageenan according to the weight ratio of 3: 1: 2: 1, and the pigment is selected from any one or two of cochineal carmine, chrome yellow, cobalt blue, iron oxide black and titanium white.
Example 3:
a water-based polyurea color sand crack beautifying agent, a water-based polyurea color sand crack beautifying agent, comprises the following components by weight: the paint comprises polyaspartic acid ester resin, isocyanate, methacrylic acid, a flexibilizer, an organic silicon defoamer, a thickening agent and a pigment, wherein the polyaspartic acid ester resin comprises the following components in parts by weight: 60 parts of polyaspartic acid resin, 38 parts of isocyanate, 4 parts of methacrylic acid, 10 parts of flexibilizer, 4 parts of organic silicon defoamer, 4 parts of thickener and 3 parts of pigment, wherein the isocyanate is any one of methylene diisocyanate and isophorone isocyanate, the flexibilizer is formed by mixing polystyrene, polysulfide rubber and ABS resin according to the weight ratio of 5: 1: 2, the organic silicon defoamer is formed by mixing fluorosilicone, ethylene glycol siloxane and polydimethylsiloxane according to the weight ratio of 1: 2, the thickener is formed by mixing pectin, agar, seaweed and carrageenan according to the weight ratio of 3: 1: 2: 1, and the pigment is any one or two of cochineal red, chrome yellow, cobalt blue, iron oxide black and titanium white.
The physical properties of the aqueous polyurea color sand crack beautifying agent obtained in the above embodiment are respectively detected, and compared with the common epoxy crack beautifying agent on the market, the obtained results are as follows:
water content ratio
Example 1 15.23%
Example 2 16.15%
Example 3 16.81%
Comparative example 35.16%
Based on the above, the invention has the advantages that the waterborne polyurea color sand synthesized by polyaspartic acid ester resin and isocyanate is used as a main material, the traditional epoxy crack sealer is replaced, the heat resistance and weather resistance are strong, the polyurea color sand is not yellowed after long-time sunlight irradiation and is durable and yellow-resistant, the attractiveness of brick joints is ensured, the toughening agent formed by mixing polystyrene, polysulfide rubber and ABS resin is added, the toughness of the crack sealer is improved, the tensile strength is high, the crack is not easy to crack in the using process, the invasion problem of dirt is avoided, the user experience is good, in addition, the organic silicon defoaming agent and the thickening agent are added, the residual gas and water of the crack sealer are effectively removed, the bonding strength of the crack sealer is improved, the crack sealer is not easy to fall off after being filled and cured, and the work is more reliable.
It will be evident to those skilled in the art that the invention is not limited to the details of the foregoing illustrative embodiments, and that the present invention may be embodied in other specific forms without departing from the spirit or essential attributes thereof. The present embodiments are therefore to be considered in all respects as illustrative and not restrictive, the scope of the invention being indicated by the appended claims rather than by the foregoing description, and all changes which come within the meaning and range of equivalency of the claims are therefore intended to be embraced therein. Any reference sign in a claim should not be construed as limiting the claim concerned.

Claims (6)

1. The water-based polyurea color sand crack beautifying agent comprises the following components in percentage by weight: polyaspartic acid resin, isocyanate, methacrylic acid, a flexibilizer, an organic silicon defoamer, a thickening agent and a pigment, and is characterized in that: the weight parts of the components are respectively as follows: 50-60 parts of polyaspartic acid resin, 32-38 parts of isocyanate, 2-4 parts of methacrylic acid, 6-10 parts of toughening agent, 1-4 parts of organic silicon defoaming agent, 2-4 parts of thickening agent and 1-3 parts of pigment.
2. The water-based polyurea color sand crack sealer according to claim 1, characterized in that: the isocyanate is any one of methylene diisocyanate and isophorone isocyanate.
3. The aqueous polyurea color sand crack sealer according to claim 1, which is characterized in that: the toughening agent is formed by mixing polystyrene, polysulfide rubber and ABS resin, and the weight ratio of the polystyrene to the polysulfide rubber to the ABS resin is 5: 1: 2.
4. The aqueous polyurea color sand crack sealer according to claim 1, which is characterized in that: the organic silicon defoaming agent is formed by mixing fluorosilicone, ethylene glycol siloxane and polydimethylsiloxane, and the weight ratio of the fluorosilicone to the ethylene glycol siloxane to the polydimethylsiloxane is 1: 2.
5. The water-based polyurea color sand crack sealer according to claim 1, characterized in that: the thickening agent is formed by mixing pectin, agar, seaweed gel and carrageenan, and the weight ratio of the pectin to the agar to the seaweed gel to the carrageenan is 3: 1: 2: 1.
6. The water-based polyurea color sand crack sealer according to claim 1, characterized in that: the pigment is any one or two of cochineal red, chrome yellow, cobalt blue, iron oxide black and titanium dioxide.
CN202210929883.9A 2022-08-02 2022-08-02 Water-based polyurea color sand crack beautifying agent Pending CN115287001A (en)

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN117965123A (en) * 2024-02-01 2024-05-03 潮州市猛犸象建材科技有限公司 Strong-hydrophobicity two-component joint beautifying agent and preparation method thereof

Citations (9)

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Publication number Priority date Publication date Assignee Title
CN101010397A (en) * 2004-09-02 2007-08-01 Ppg工业俄亥俄公司 Multi-component coatings that include polyurea coating layers
CN104945978A (en) * 2015-06-18 2015-09-30 成都纳硕科技有限公司 Water-based high-impact UV-curing fluorine-containing paint for polycarbonate sheets
KR20170012701A (en) * 2015-07-22 2017-02-03 석승국 Tile grout composition using non-yellowing polyamic Spa ticks urea
CN109251643A (en) * 2018-08-16 2019-01-22 游代华 A kind of Polyaspartic Polyurea coating and its application
CN110317528A (en) * 2019-08-01 2019-10-11 深圳飞扬骏研新材料股份有限公司 A kind of joint trimming agent
CN112063338A (en) * 2020-09-27 2020-12-11 广东粤固建材科技有限公司 Anticorrosive joint filling material for ceramic tiles and preparation method thereof
CN112250817A (en) * 2020-09-27 2021-01-22 深圳飞扬兴业科技有限公司 Synthesis method of water-based asparagus polyurea and application of water-based asparagus polyurea in seam beautifying agent
CN112266754A (en) * 2020-11-03 2021-01-26 上海牛元工贸有限公司 Seam beautifying agent not prone to foaming and preparation method thereof
CN114045141A (en) * 2021-12-06 2022-02-15 北京吉时吉兴贸易有限公司 Two-component polyurea seam beautifying agent

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CN101010397A (en) * 2004-09-02 2007-08-01 Ppg工业俄亥俄公司 Multi-component coatings that include polyurea coating layers
CN104945978A (en) * 2015-06-18 2015-09-30 成都纳硕科技有限公司 Water-based high-impact UV-curing fluorine-containing paint for polycarbonate sheets
KR20170012701A (en) * 2015-07-22 2017-02-03 석승국 Tile grout composition using non-yellowing polyamic Spa ticks urea
CN109251643A (en) * 2018-08-16 2019-01-22 游代华 A kind of Polyaspartic Polyurea coating and its application
CN110317528A (en) * 2019-08-01 2019-10-11 深圳飞扬骏研新材料股份有限公司 A kind of joint trimming agent
CN112063338A (en) * 2020-09-27 2020-12-11 广东粤固建材科技有限公司 Anticorrosive joint filling material for ceramic tiles and preparation method thereof
CN112250817A (en) * 2020-09-27 2021-01-22 深圳飞扬兴业科技有限公司 Synthesis method of water-based asparagus polyurea and application of water-based asparagus polyurea in seam beautifying agent
CN112266754A (en) * 2020-11-03 2021-01-26 上海牛元工贸有限公司 Seam beautifying agent not prone to foaming and preparation method thereof
CN114045141A (en) * 2021-12-06 2022-02-15 北京吉时吉兴贸易有限公司 Two-component polyurea seam beautifying agent

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN117965123A (en) * 2024-02-01 2024-05-03 潮州市猛犸象建材科技有限公司 Strong-hydrophobicity two-component joint beautifying agent and preparation method thereof

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Application publication date: 20221104