CN115287001A - Water-based polyurea color sand crack beautifying agent - Google Patents
Water-based polyurea color sand crack beautifying agent Download PDFInfo
- Publication number
- CN115287001A CN115287001A CN202210929883.9A CN202210929883A CN115287001A CN 115287001 A CN115287001 A CN 115287001A CN 202210929883 A CN202210929883 A CN 202210929883A CN 115287001 A CN115287001 A CN 115287001A
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- color sand
- isocyanate
- water
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- 229920002396 Polyurea Polymers 0.000 title claims abstract description 22
- 239000003795 chemical substances by application Substances 0.000 title claims abstract description 22
- 239000004576 sand Substances 0.000 title claims abstract description 22
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 title claims abstract description 20
- 229920000805 Polyaspartic acid Polymers 0.000 claims abstract description 20
- 239000012948 isocyanate Substances 0.000 claims abstract description 20
- 150000002513 isocyanates Chemical class 0.000 claims abstract description 20
- 108010064470 polyaspartate Proteins 0.000 claims abstract description 20
- 229920005989 resin Polymers 0.000 claims abstract description 20
- 239000011347 resin Substances 0.000 claims abstract description 20
- 239000002562 thickening agent Substances 0.000 claims abstract description 19
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 claims abstract description 18
- 229910052710 silicon Inorganic materials 0.000 claims abstract description 18
- 239000010703 silicon Substances 0.000 claims abstract description 18
- 239000000049 pigment Substances 0.000 claims abstract description 17
- CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 claims abstract description 12
- 239000002518 antifoaming agent Substances 0.000 claims abstract description 12
- 239000012745 toughening agent Substances 0.000 claims abstract description 12
- LYCAIKOWRPUZTN-UHFFFAOYSA-N ethylene glycol Natural products OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 claims description 14
- -1 ethylene glycol siloxane Chemical class 0.000 claims description 14
- 239000004793 Polystyrene Substances 0.000 claims description 9
- 229920000122 acrylonitrile butadiene styrene Polymers 0.000 claims description 9
- 229920001971 elastomer Polymers 0.000 claims description 9
- 229920002223 polystyrene Polymers 0.000 claims description 9
- 229920001021 polysulfide Polymers 0.000 claims description 9
- 239000005077 polysulfide Substances 0.000 claims description 9
- 150000008117 polysulfides Polymers 0.000 claims description 9
- 229920001817 Agar Polymers 0.000 claims description 7
- 241001474374 Blennius Species 0.000 claims description 7
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims description 7
- 239000008272 agar Substances 0.000 claims description 7
- 239000000679 carrageenan Substances 0.000 claims description 7
- 235000010418 carrageenan Nutrition 0.000 claims description 7
- 229920001525 carrageenan Polymers 0.000 claims description 7
- 229940113118 carrageenan Drugs 0.000 claims description 7
- 239000013530 defoamer Substances 0.000 claims description 7
- 239000004205 dimethyl polysiloxane Substances 0.000 claims description 7
- 239000001814 pectin Substances 0.000 claims description 7
- 235000010987 pectin Nutrition 0.000 claims description 7
- 229920001277 pectin Polymers 0.000 claims description 7
- 229920000435 poly(dimethylsiloxane) Polymers 0.000 claims description 7
- UHVMMEOXYDMDKI-JKYCWFKZSA-L zinc;1-(5-cyanopyridin-2-yl)-3-[(1s,2s)-2-(6-fluoro-2-hydroxy-3-propanoylphenyl)cyclopropyl]urea;diacetate Chemical compound [Zn+2].CC([O-])=O.CC([O-])=O.CCC(=O)C1=CC=C(F)C([C@H]2[C@H](C2)NC(=O)NC=2N=CC(=CC=2)C#N)=C1O UHVMMEOXYDMDKI-JKYCWFKZSA-L 0.000 claims description 7
- XBXFGOSIPGWNLZ-UHFFFAOYSA-N O=C1C=C(CC(C)(C)C1)C.N=C=O Chemical compound O=C1C=C(CC(C)(C)C1)C.N=C=O XBXFGOSIPGWNLZ-UHFFFAOYSA-N 0.000 claims description 5
- 239000010941 cobalt Substances 0.000 claims description 5
- 229910017052 cobalt Inorganic materials 0.000 claims description 5
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 claims description 5
- KIQKWYUGPPFMBV-UHFFFAOYSA-N diisocyanatomethane Chemical compound O=C=NCN=C=O KIQKWYUGPPFMBV-UHFFFAOYSA-N 0.000 claims description 5
- SZVJSHCCFOBDDC-UHFFFAOYSA-N ferrosoferric oxide Chemical compound O=[Fe]O[Fe]O[Fe]=O SZVJSHCCFOBDDC-UHFFFAOYSA-N 0.000 claims description 5
- MOUPNEIJQCETIW-UHFFFAOYSA-N lead chromate Chemical compound [Pb+2].[O-][Cr]([O-])(=O)=O MOUPNEIJQCETIW-UHFFFAOYSA-N 0.000 claims description 5
- 235000012730 carminic acid Nutrition 0.000 claims description 4
- 239000004106 carminic acid Substances 0.000 claims description 4
- 229940080423 cochineal Drugs 0.000 claims description 4
- 239000000499 gel Substances 0.000 claims description 4
- 239000004408 titanium dioxide Substances 0.000 claims description 2
- 239000000463 material Substances 0.000 abstract description 6
- 239000003973 paint Substances 0.000 abstract description 5
- 239000004593 Epoxy Substances 0.000 abstract description 4
- 239000011449 brick Substances 0.000 abstract description 4
- 238000000034 method Methods 0.000 abstract description 4
- 230000009545 invasion Effects 0.000 abstract description 3
- 150000002148 esters Chemical class 0.000 description 6
- 235000010215 titanium dioxide Nutrition 0.000 description 4
- 239000000919 ceramic Substances 0.000 description 2
- 229910052782 aluminium Inorganic materials 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- DGQLVPJVXFOQEV-JNVSTXMASA-N carminic acid Chemical compound OC1=C2C(=O)C=3C(C)=C(C(O)=O)C(O)=CC=3C(=O)C2=C(O)C(O)=C1[C@@H]1O[C@H](CO)[C@@H](O)[C@H](O)[C@H]1O DGQLVPJVXFOQEV-JNVSTXMASA-N 0.000 description 1
- 230000000052 comparative effect Effects 0.000 description 1
- 238000005336 cracking Methods 0.000 description 1
- 239000003822 epoxy resin Substances 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 230000000704 physical effect Effects 0.000 description 1
- 229920000647 polyepoxide Polymers 0.000 description 1
- 229920001296 polysiloxane Polymers 0.000 description 1
- 239000004575 stone Substances 0.000 description 1
- 239000002023 wood Substances 0.000 description 1
- 238000004383 yellowing Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J4/00—Adhesives based on organic non-macromolecular compounds having at least one polymerisable carbon-to-carbon unsaturated bond ; adhesives, based on monomers of macromolecular compounds of groups C09J183/00 - C09J183/16
- C09J4/06—Organic non-macromolecular compounds having at least one polymerisable carbon-to-carbon unsaturated bond in combination with a macromolecular compound other than an unsaturated polymer of groups C09J159/00 - C09J187/00
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
- C09J11/02—Non-macromolecular additives
- C09J11/06—Non-macromolecular additives organic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
- C09J11/08—Macromolecular additives
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Paints Or Removers (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
The invention discloses a water-based polyurea color sand crack beautifying agent, which comprises the following components in part by weight: the paint comprises polyaspartic acid resin, isocyanate, methacrylic acid, a toughening agent, an organic silicon defoaming agent, a thickening agent and a pigment, wherein the polyaspartic acid resin comprises the following components in parts by weight: 50-60 parts of polyaspartic acid resin, 32-38 parts of isocyanate, 2-4 parts of methacrylic acid, 6-10 parts of toughening agent, 1-4 parts of organic silicon defoaming agent, 2-4 parts of thickening agent and 1-3 parts of pigment; the water-based polyurea color sand synthesized by polyaspartic acid resin and isocyanate is used as a main material, replaces the traditional epoxy crack sealer, has strong heat resistance and weather resistance, is not yellowed after long-time sunlight irradiation, is durable and yellow-resistant, ensures the attractiveness of brick joints, improves the toughness of the crack sealer by adding the flexibilizer, has high tensile strength, is not easy to crack in the using process, avoids the invasion problem of dirt, and has good user experience.
Description
Technical Field
The invention relates to the technical field of crack beautifying agents, and particularly relates to a water-based polyurea color sand crack beautifying agent.
Background
The crack beautifying agent is used for beautifying the crack between wall and floor tile, is suitable for decorating the crack between ceramic tile, mosaic tile, stone material, wood board, glass, plastic-aluminum board and other material, and is used for covering ceramic tile in toilet, kitchen and floor. However, most of the traditional crack sealer is made of epoxy resin materials, so that the heat resistance and the weather resistance are poor, the yellowing problem easily occurs after the sunlight is irradiated for a long time, the attractiveness of brick joints is influenced, the toughness is poor, the tensile strength is low, the cracking problem easily occurs in the use process, dirt enters cracks, the user experience is poor, in addition, more residual gas and water exist, the bonding strength of the crack sealer is inevitably influenced, the crack sealer is easy to fall off after crack filling and curing, and the working reliability is poor.
Disclosure of Invention
The invention aims to provide a water-based polyurea color sand crack beautifying agent to solve the problems in the background technology.
In order to achieve the purpose, the invention provides the following technical scheme: the water-based polyurea color sand crack beautifying agent comprises the following components in percentage by weight: the paint comprises polyaspartic acid resin, isocyanate, methacrylic acid, a toughening agent, an organic silicon defoaming agent, a thickening agent and a pigment, wherein the polyaspartic acid resin comprises the following components in parts by weight: 50-60 parts of polyaspartic acid resin, 32-38 parts of isocyanate, 2-4 parts of methacrylic acid, 6-10 parts of toughening agent, 1-4 parts of organic silicon defoaming agent, 2-4 parts of thickening agent and 1-3 parts of pigment.
Preferably, the isocyanate is any one of methylene diisocyanate and isophorone isocyanate.
Preferably, the toughening agent is formed by mixing polystyrene, polysulfide rubber and ABS resin, and the weight ratio of the polystyrene to the polysulfide rubber to the ABS resin is 5: 1: 2.
Preferably, the silicone defoaming agent is formed by mixing fluorosilicone, ethylene glycol siloxane and polydimethylsiloxane, and the weight ratio of the fluorosilicone to the ethylene glycol siloxane to the polydimethylsiloxane is 1: 2.
Preferably, the thickening agent is formed by mixing pectin, agar, seaweed gel and carrageenan, and the weight ratio of the pectin to the agar to the seaweed gel to the carrageenan is 3: 1: 2: 1.
Preferably, the pigment is any one or two of cochineal red, chrome yellow, cobalt blue, iron oxide black and titanium dioxide.
Compared with the prior art, the invention has the beneficial effects that: the water-based polyurea color sand crack beautifying agent adopts water-based polyurea color sand synthesized by polyaspartic acid resin and isocyanate as a main material, replaces the traditional epoxy crack beautifying agent, has strong heat resistance and weather resistance, is not yellowed by long-time sunlight irradiation, is durable and yellow, and ensures the attractiveness of brick joints; the toughening agent formed by mixing the polystyrene, the polysulfide rubber and the ABS resin is added, so that the toughness of the seam beautifying agent is improved, the tensile strength is high, the seam beautifying agent is not easy to crack in the using process, the problem of dirt invasion is avoided, and the user experience is good; by adding the organic silicon defoaming agent and the thickening agent, residual gas and moisture of the seam beautifying agent are effectively removed, the bonding strength of the seam beautifying agent is improved, the seam beautifying agent is not easy to fall off after filling and curing, and the work is more reliable.
Detailed Description
The technical solutions in the embodiments of the present invention will be described clearly and completely below, and it is obvious that the described embodiments are only a part of the embodiments of the present invention, and not all of the embodiments. All other embodiments, which can be derived by a person skilled in the art from the embodiments given herein without making any creative effort, shall fall within the protection scope of the present invention.
The invention provides a technical scheme that:
example 1:
the water-based polyurea color sand crack beautifying agent comprises the following components in percentage by weight: the paint comprises polyaspartic acid ester resin, isocyanate, methacrylic acid, a flexibilizer, an organic silicon defoamer, a thickening agent and a pigment, wherein the polyaspartic acid ester resin comprises the following components in parts by weight: 50 parts of polyaspartic acid resin, 32 parts of isocyanate, 2 parts of methacrylic acid, 6 parts of a toughening agent, 1 part of an organic silicon defoaming agent, 2 parts of a thickening agent and 1 part of pigment, wherein the isocyanate selects any one of methylene diisocyanate and isophorone isocyanate, the toughening agent is formed by mixing polystyrene, polysulfide rubber and ABS resin in a weight ratio of 5: 1: 2, the organic silicon defoaming agent is formed by mixing fluorosilicone, ethylene glycol siloxane and polydimethylsiloxane in a weight ratio of 1: 2, the thickening agent is formed by mixing pectin, agar, seaweed and carrageenan in a weight ratio of 3: 1: 2: 1, and the pigment selects any one or two of cochineal, chrome yellow, cobalt blue, iron oxide black and titanium white.
Example 2:
a water-based polyurea color sand crack beautifying agent is disclosed, and the formula comprises: the paint comprises polyaspartic acid resin, isocyanate, methacrylic acid, a toughening agent, an organic silicon defoaming agent, a thickening agent and a pigment, wherein the polyaspartic acid resin comprises the following components in parts by weight: 55 parts of polyaspartic acid ester resin, 35 parts of isocyanate, 3 parts of methacrylic acid, 8 parts of flexibilizer, 3 parts of organic silicon defoamer, 3 parts of thickener and 2 parts of pigment, wherein the isocyanate is selected from any one of methylene diisocyanate and isophorone isocyanate, the flexibilizer is formed by mixing polystyrene, polysulfide rubber and ABS resin according to the weight ratio of 5: 1: 2, the organic silicon defoamer is formed by mixing fluorosilicone, ethylene glycol siloxane and polydimethylsiloxane according to the weight ratio of 1: 2, the thickener is formed by mixing pectin, agar, seaweed and carrageenan according to the weight ratio of 3: 1: 2: 1, and the pigment is selected from any one or two of cochineal carmine, chrome yellow, cobalt blue, iron oxide black and titanium white.
Example 3:
a water-based polyurea color sand crack beautifying agent, a water-based polyurea color sand crack beautifying agent, comprises the following components by weight: the paint comprises polyaspartic acid ester resin, isocyanate, methacrylic acid, a flexibilizer, an organic silicon defoamer, a thickening agent and a pigment, wherein the polyaspartic acid ester resin comprises the following components in parts by weight: 60 parts of polyaspartic acid resin, 38 parts of isocyanate, 4 parts of methacrylic acid, 10 parts of flexibilizer, 4 parts of organic silicon defoamer, 4 parts of thickener and 3 parts of pigment, wherein the isocyanate is any one of methylene diisocyanate and isophorone isocyanate, the flexibilizer is formed by mixing polystyrene, polysulfide rubber and ABS resin according to the weight ratio of 5: 1: 2, the organic silicon defoamer is formed by mixing fluorosilicone, ethylene glycol siloxane and polydimethylsiloxane according to the weight ratio of 1: 2, the thickener is formed by mixing pectin, agar, seaweed and carrageenan according to the weight ratio of 3: 1: 2: 1, and the pigment is any one or two of cochineal red, chrome yellow, cobalt blue, iron oxide black and titanium white.
The physical properties of the aqueous polyurea color sand crack beautifying agent obtained in the above embodiment are respectively detected, and compared with the common epoxy crack beautifying agent on the market, the obtained results are as follows:
water content ratio | |
Example 1 | 15.23% |
Example 2 | 16.15% |
Example 3 | 16.81% |
Comparative example | 35.16% |
Based on the above, the invention has the advantages that the waterborne polyurea color sand synthesized by polyaspartic acid ester resin and isocyanate is used as a main material, the traditional epoxy crack sealer is replaced, the heat resistance and weather resistance are strong, the polyurea color sand is not yellowed after long-time sunlight irradiation and is durable and yellow-resistant, the attractiveness of brick joints is ensured, the toughening agent formed by mixing polystyrene, polysulfide rubber and ABS resin is added, the toughness of the crack sealer is improved, the tensile strength is high, the crack is not easy to crack in the using process, the invasion problem of dirt is avoided, the user experience is good, in addition, the organic silicon defoaming agent and the thickening agent are added, the residual gas and water of the crack sealer are effectively removed, the bonding strength of the crack sealer is improved, the crack sealer is not easy to fall off after being filled and cured, and the work is more reliable.
It will be evident to those skilled in the art that the invention is not limited to the details of the foregoing illustrative embodiments, and that the present invention may be embodied in other specific forms without departing from the spirit or essential attributes thereof. The present embodiments are therefore to be considered in all respects as illustrative and not restrictive, the scope of the invention being indicated by the appended claims rather than by the foregoing description, and all changes which come within the meaning and range of equivalency of the claims are therefore intended to be embraced therein. Any reference sign in a claim should not be construed as limiting the claim concerned.
Claims (6)
1. The water-based polyurea color sand crack beautifying agent comprises the following components in percentage by weight: polyaspartic acid resin, isocyanate, methacrylic acid, a flexibilizer, an organic silicon defoamer, a thickening agent and a pigment, and is characterized in that: the weight parts of the components are respectively as follows: 50-60 parts of polyaspartic acid resin, 32-38 parts of isocyanate, 2-4 parts of methacrylic acid, 6-10 parts of toughening agent, 1-4 parts of organic silicon defoaming agent, 2-4 parts of thickening agent and 1-3 parts of pigment.
2. The water-based polyurea color sand crack sealer according to claim 1, characterized in that: the isocyanate is any one of methylene diisocyanate and isophorone isocyanate.
3. The aqueous polyurea color sand crack sealer according to claim 1, which is characterized in that: the toughening agent is formed by mixing polystyrene, polysulfide rubber and ABS resin, and the weight ratio of the polystyrene to the polysulfide rubber to the ABS resin is 5: 1: 2.
4. The aqueous polyurea color sand crack sealer according to claim 1, which is characterized in that: the organic silicon defoaming agent is formed by mixing fluorosilicone, ethylene glycol siloxane and polydimethylsiloxane, and the weight ratio of the fluorosilicone to the ethylene glycol siloxane to the polydimethylsiloxane is 1: 2.
5. The water-based polyurea color sand crack sealer according to claim 1, characterized in that: the thickening agent is formed by mixing pectin, agar, seaweed gel and carrageenan, and the weight ratio of the pectin to the agar to the seaweed gel to the carrageenan is 3: 1: 2: 1.
6. The water-based polyurea color sand crack sealer according to claim 1, characterized in that: the pigment is any one or two of cochineal red, chrome yellow, cobalt blue, iron oxide black and titanium dioxide.
Priority Applications (1)
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CN202210929883.9A CN115287001A (en) | 2022-08-02 | 2022-08-02 | Water-based polyurea color sand crack beautifying agent |
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CN202210929883.9A CN115287001A (en) | 2022-08-02 | 2022-08-02 | Water-based polyurea color sand crack beautifying agent |
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CN202210929883.9A Pending CN115287001A (en) | 2022-08-02 | 2022-08-02 | Water-based polyurea color sand crack beautifying agent |
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Cited By (1)
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CN117965123A (en) * | 2024-02-01 | 2024-05-03 | 潮州市猛犸象建材科技有限公司 | Strong-hydrophobicity two-component joint beautifying agent and preparation method thereof |
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Application publication date: 20221104 |