CN115235196A - Positive pressure curing negative pressure drying system for storage battery - Google Patents

Positive pressure curing negative pressure drying system for storage battery Download PDF

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Publication number
CN115235196A
CN115235196A CN202210783330.7A CN202210783330A CN115235196A CN 115235196 A CN115235196 A CN 115235196A CN 202210783330 A CN202210783330 A CN 202210783330A CN 115235196 A CN115235196 A CN 115235196A
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CN
China
Prior art keywords
pressure
valve
box
temperature
humidity
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Withdrawn
Application number
CN202210783330.7A
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Chinese (zh)
Inventor
朱新华
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Jiangsu Jinfan Xincheng Equipment Co ltd
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Jiangsu Jinfan Xincheng Equipment Co ltd
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Application filed by Jiangsu Jinfan Xincheng Equipment Co ltd filed Critical Jiangsu Jinfan Xincheng Equipment Co ltd
Priority to CN202210783330.7A priority Critical patent/CN115235196A/en
Publication of CN115235196A publication Critical patent/CN115235196A/en
Withdrawn legal-status Critical Current

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    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F26DRYING
    • F26BDRYING SOLID MATERIALS OR OBJECTS BY REMOVING LIQUID THEREFROM
    • F26B9/00Machines or apparatus for drying solid materials or objects at rest or with only local agitation; Domestic airing cupboards
    • F26B9/06Machines or apparatus for drying solid materials or objects at rest or with only local agitation; Domestic airing cupboards in stationary drums or chambers
    • F26B9/066Machines or apparatus for drying solid materials or objects at rest or with only local agitation; Domestic airing cupboards in stationary drums or chambers the products to be dried being disposed on one or more containers, which may have at least partly gas-previous walls, e.g. trays or shelves in a stack
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F26DRYING
    • F26BDRYING SOLID MATERIALS OR OBJECTS BY REMOVING LIQUID THEREFROM
    • F26B21/00Arrangements or duct systems, e.g. in combination with pallet boxes, for supplying and controlling air or gases for drying solid materials or objects
    • F26B21/02Circulating air or gases in closed cycles, e.g. wholly within the drying enclosure
    • F26B21/04Circulating air or gases in closed cycles, e.g. wholly within the drying enclosure partly outside the drying enclosure
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F26DRYING
    • F26BDRYING SOLID MATERIALS OR OBJECTS BY REMOVING LIQUID THEREFROM
    • F26B21/00Arrangements or duct systems, e.g. in combination with pallet boxes, for supplying and controlling air or gases for drying solid materials or objects
    • F26B21/06Controlling, e.g. regulating, parameters of gas supply
    • F26B21/08Humidity
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F26DRYING
    • F26BDRYING SOLID MATERIALS OR OBJECTS BY REMOVING LIQUID THEREFROM
    • F26B21/00Arrangements or duct systems, e.g. in combination with pallet boxes, for supplying and controlling air or gases for drying solid materials or objects
    • F26B21/06Controlling, e.g. regulating, parameters of gas supply
    • F26B21/10Temperature; Pressure
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F26DRYING
    • F26BDRYING SOLID MATERIALS OR OBJECTS BY REMOVING LIQUID THEREFROM
    • F26B25/00Details of general application not covered by group F26B21/00 or F26B23/00
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F26DRYING
    • F26BDRYING SOLID MATERIALS OR OBJECTS BY REMOVING LIQUID THEREFROM
    • F26B5/00Drying solid materials or objects by processes not involving the application of heat
    • F26B5/04Drying solid materials or objects by processes not involving the application of heat by evaporation or sublimation of moisture under reduced pressure, e.g. in a vacuum
    • F26B5/044Drying solid materials or objects by processes not involving the application of heat by evaporation or sublimation of moisture under reduced pressure, e.g. in a vacuum for drying materials in a batch operation in an enclosure having a plurality of shelves which may be heated
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00Electrodes
    • H01M4/02Electrodes composed of, or comprising, active material
    • H01M4/14Electrodes for lead-acid accumulators
    • H01M4/16Processes of manufacture
    • H01M4/20Processes of manufacture of pasted electrodes
    • H01M4/21Drying of pasted electrodes
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/10Energy storage using batteries

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  • Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • General Engineering & Computer Science (AREA)
  • Health & Medical Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Molecular Biology (AREA)
  • Manufacturing & Machinery (AREA)
  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Electrochemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Drying Of Solid Materials (AREA)

Abstract

The application discloses malleation solidification negative pressure drying system for battery, including the box that bears the battery, one side of box is provided with the door body of switching, one side of box is provided with the drive the circulating fan of the inside gas flow of box, the inside heater that is provided with of box, the bottom both sides of box are provided with steam humidification valve and blowoff valve respectively, the top of box has set gradually hydrofuge valve, relief valve, booster valve, humidification valve. The invention has the advantages that the internal pressure is increased during curing, the internal pressure is greater than the standard atmospheric pressure, the reaction of free lead is accelerated, and meanwhile, steam molecules become very active under the positive pressure state, so that the temperature and humidity uniformity of different indoor areas is improved; when drying, the interior is decompressed to be in a negative pressure state, thereby accelerating the separation of water in the polar plate and shortening the drying time.

Description

Positive pressure curing negative pressure drying system for storage battery
Technical Field
The application relates to the field of storage batteries, in particular to a positive-pressure curing negative-pressure drying system for a storage battery.
Background
In the production process of the storage battery pole plate, one procedure is to solidify and dry the just-coated pole plate, firstly, the pole plate is solidified under certain temperature and humidity, and then dried after solidification, so that the water content in the pole plate is reduced.
The purpose of curing is as follows: enabling the pole plate lead paste to form a crystal structure; corroding the grid and strengthening the bonding rate of the grid and lead paste; free lead in the conversion lead paste, and the like.
The usual curing methods are: setting the temperature and humidity of the curing environment, stirring air by using a circulating fan to ensure that the internal temperature and humidity are relatively uniform, and reacting under normal pressure.
And (3) drying purpose: and removing the water in the polar plate.
The usual drying methods are: indoor high humid air passes through the hydrofuge fan and arranges to the open air, inside the drying chamber is inhaled to the air of outside, inside and outside replacement step by step, raises the temperature simultaneously, lets the inside moisture evaporation of polar plate come out.
The disadvantages of this are:
1. although the inside is stirred by the circulating fan, the uniformity of the temperature and the humidity inside has great relation with the internal volume of the equipment, the air quantity of the fan, the direction of the polar plate, the density degree, the placing position of the polar plate and the like, so that the curing time of the polar plates in different areas is different, and the total curing time is finally prolonged. And the final plate quality of different areas also differs.
2. The conversion of free lead requires oxygen and moisture because of atmospheric curing, and oxygen needs a certain time to enter the gaps between the lead paste molecules, which is another reason for prolonging the total curing time.
3. When drying, the inside of the polar plate needs to be dried completely, the water inside needs to permeate outwards gradually, and the polar plate is evaporated by depending on the temperature, so that higher temperature and larger air volume are needed. For the arrangement mode without gaps between the polar plates, longer drying time is needed, and the production and operation cost is increased due to high temperature, strong wind and long time.
All the curing and drying are carried out under normal pressure, the curing and drying can be completed only by prolonging the time, and the air speed flowing through the polar plates placed in different areas is different, so that the physical and chemical indexes of the final polar plates are different.
Disclosure of Invention
The invention aims to provide a positive-pressure curing and negative-pressure drying system for a storage battery, which reduces curing and drying time in a curing positive-pressure and drying negative-pressure mode; the consistency of the pole plate quality in different areas is improved.
In order to achieve the above purpose, the present invention provides the following technical solutions.
The embodiment of the application discloses malleation solidification negative pressure drying system for battery, including the box that bears the battery, one side of box is provided with the door body of switching, one side of box is provided with the drive the circulating fan of the inside gas flow of box, the inside heater that is provided with of box, the bottom both sides of box are provided with steam humidifying valve and blowoff valve respectively, the top of box has set gradually hydrofuge valve, relief valve, booster valve, humidification valve.
Preferably, in the positive pressure curing and negative pressure drying system for the storage battery, fan protection valves are arranged on two sides of the circulating fan.
Preferably, in the positive pressure curing and negative pressure drying system for a secondary battery, a PSV safety valve is provided at a top of the case.
Preferably, in foretell positive pressure solidification negative pressure drying system for battery, the hydrofuge valve deviates from one side of box connects gradually in cooling trough, comdenstion water collecting vessel and hydrofuge fan, the bottom of comdenstion water collecting vessel is provided with the condensate water blow-off valve.
Preferably, in the positive pressure curing and negative pressure drying system for a storage battery, the door body is opened and closed in a lifting and sealing manner.
Correspondingly, also discloses a use method of the positive pressure curing and negative pressure drying system for the storage battery,
during curing: when the temperature, the humidity and the pressure do not reach the set values, the steam humidifying valve is opened to spray steam to the inside so as to synchronously raise the temperature, the humidity and the pressure; when the temperature reaches and the pressure and the humidity do not reach, the humidifying valve is opened to increase the internal humidity and the pressure; when the temperature and the humidity reach and the pressure does not reach, the pressure increasing valve is opened to convey compressed air inwards to increase the pressure,
and (3) during drying: circulating fan operation, heater work simultaneously, make the temperature rise, close heater and circulating fan after reaching the settlement temperature, open the outside hydrofuge of hydrofuge valve, after reaching the negative pressure value of settlement, close the hydrofuge valve, discharge the comdenstion water, a period of time stews afterwards, let the inside moisture of battery polar plate separate out the polar plate surface fast under the effect of negative pressure, open the relief valve again, let internal pressure resume the ordinary pressure, reopen heater, circulating fan, blowoff valve, rapid evaporation polar plate surface moisture, the circulation is several times, accomplish the drying.
Compared with the prior art, the invention has the advantages that: during curing, the internal pressure is increased, so that the internal pressure is greater than the standard atmospheric pressure, the reaction of free lead is accelerated, and meanwhile, steam molecules become very active in a positive pressure state, so that the temperature and humidity uniformity of different indoor areas is improved; when drying, the interior is decompressed to be in a negative pressure state, thereby accelerating the separation of water in the polar plate and shortening the drying time.
Drawings
In order to more clearly illustrate the embodiments of the present application or the technical solutions in the prior art, the drawings needed to be used in the description of the embodiments or the prior art will be briefly described below, it is obvious that the drawings in the following description are only some embodiments described in the present application, and other drawings can be obtained by those skilled in the art without creative efforts.
Fig. 1 is a schematic diagram of a positive pressure curing negative pressure drying system for a storage battery according to an embodiment of the invention.
Detailed Description
The technical solutions in the embodiments of the present invention will be described in detail below with reference to the drawings in the embodiments of the present invention, and it is obvious that the described embodiments are only a part of the embodiments of the present invention, and not all embodiments. All other embodiments, which can be obtained by a person skilled in the art without making any creative effort based on the embodiments in the present invention, belong to the protection scope of the present invention.
Referring to fig. 1, the positive pressure curing negative pressure drying system 100 for the storage battery includes a box 101 for carrying the storage battery, a door 102 for opening and closing is disposed on one side of the box 101, a circulating fan 103 for driving gas inside the box 101 to flow is disposed on one side of the box 101, a heater 104 is disposed inside the box 101, a steam humidifying valve 105 and a blow-down valve 106 are disposed on two sides of the bottom of the box 101, and a humidity discharging valve 107, a pressure relief valve 108, a pressure increasing valve 109, and a humidifying valve 110 are sequentially disposed on the top of the box 101. Fan protection valves 111 are provided on both sides of the circulation fan 103. The top of the tank 101 is provided with a PSV relief valve 112. One side of the moisture exhaust valve 107 departing from the box 101 is sequentially connected to a cooling water tank 113, a condensed water collecting bucket 114 and a moisture exhaust fan 115, and a condensed water discharge valve 116 is arranged at the bottom of the condensed water collecting bucket 114. The door 102 is opened and closed in a lifting and sealing manner.
When in specific use:
during curing: when the temperature, the humidity and the pressure do not reach the set values, the steam humidifying valve 105 is opened to spray steam to the inside, so that the temperature, the humidity and the pressure are synchronously increased; when the temperature reaches and the pressure and the humidity do not reach, the humidifying valve 110 is opened to increase the internal humidity and the pressure; when the temperature and the humidity reach and the pressure does not reach, the pressure increasing valve 109 is opened to convey the compressed air inwards to increase the pressure,
and (3) during drying: the circulating fan 103 operates, meanwhile, the heater 104 works to enable the temperature to rise, the heater 104 and the circulating fan 103 are closed after the set temperature is reached, the dehumidifying valve 107 is opened to discharge moisture outwards, the dehumidifying valve 107 is closed after the set negative pressure value is reached, condensed water is discharged, standing is carried out for a period of time, moisture in the storage battery pole plate is rapidly separated out to the surface of the pole plate under the action of negative pressure, the pressure release valve 108 is opened again to enable the internal pressure to be recovered to the normal pressure, the heater 104, the circulating fan 103 and the blow-down valve 106 are opened again to rapidly evaporate moisture on the surface of the pole plate, and drying is completed for a plurality of times.
In this embodiment of the present invention,
functional description of each component:
lifting the door body: the access plate is opened and closed during normal operation.
A circulating fan: circularly stirring the air inside to improve the uniformity inside;
a fan protection valve: the fan inlet and the fan outlet are arranged to protect the fan from deformation under negative pressure, and the fan inlet and the fan outlet are synchronously opened with the circulating fan.
A moisture removal fan: when the pressure relief valve is closed, the indoor air can reach negative pressure.
A moisture exhaust valve: and the same moisture exhaust fan is synchronously started.
A cooling water tank: the high-humidity air discharged from the inside of the cooling chamber to the outside does not enter the dehumidifying fan to cause faults.
A condensed water collecting barrel: and separating the moisture to prevent the moisture from entering the moisture exhaust fan.
Condensed water discharge valve: discharging the water in the collecting barrel.
A pressure release valve: the indoor temperature can be recovered to normal pressure by opening; the internal air and the external air can be partially replaced by opening the same humidity exhaust fan at the same time.
PSV: and the safety valve automatically releases pressure when exceeding the pressure.
A pressure increasing valve: the pressure in the room can be increased by delivering compressed air inwards.
A humidifying valve: the interior is humidified to increase the humidity and at the same time increase the pressure.
A heater: the internal temperature is increased.
A steam humidifying valve: the steam is sprayed to the inside, and the temperature, the humidity and the pressure are improved.
A blowdown valve: and discharging accumulated water in the tank.
And (3) curing: the temperature, the humidity, the time, the pressure and the fan operation percentage are set on a control interface, and the equipment is automatically adjusted according to the set temperature, humidity and pressure. When the temperature, the humidity and the pressure do not reach set values, the steam humidifying valve is opened to spray steam to the inside, so that the temperature, the humidity and the pressure are synchronously increased; when the temperature is reached; if the pressure and the humidity do not reach, the humidifying valve is opened to increase the internal humidity and the pressure. When the temperature and the humidity reach and the pressure does not reach, the pressure increasing valve is opened, and compressed air is conveyed inwards to increase the pressure.
And (3) a drying stage: and setting temperature, humidity, time, pressure, cycle times and fan operation percentage on a control interface, and automatically adjusting the equipment according to the set temperature, humidity and pressure.
The flow of each cycle is as follows: and (3) operating the circulating fan, simultaneously, operating the heater to raise the temperature, closing the heater and the circulating fan after the temperature reaches the set temperature, opening the moisture exhausting fan to exhaust moisture outwards, and closing the moisture exhausting fan to discharge condensed water after the set negative pressure value is reached. Standing for a period of time to enable the moisture in the polar plate to be quickly separated out to the surface of the polar plate under the action of negative pressure, opening the pressure release valve again to enable the internal pressure to be recovered to normal pressure, opening the heater, the circulating fan and the blow-down valve again to quickly evaporate the moisture on the surface of the polar plate, and repeating the steps to set times to complete the drying process.
Compared with the traditional method, the method has the following advantages that the positive pressure curing and the negative pressure drying are adopted: the process time is saved; the consistency of physical and chemical indexes of the polar plate is improved.
When the positive pressure curing is adopted, on one hand, the steam molecules in the high pressure become abnormal activity, and the same temperature and humidity can be obtained in different areas in the same space, on the other hand, the reaction of the free lead can be accelerated under the high pressure, and the curing process can be completed in a short time.
When adopting the negative pressure solidification, can separate out the inside moisture of polar plate fast under the effect of negative pressure on the one hand, on the other hand, the negative pressure can the reduce temperature, and after the temperature reduced, the water content in the air reduces because of the dissolution rate, and unnecessary moisture can the condensation accumulation in the bottom, and it is outdoor to discharge when indoor recovery ordinary pressure. The drying of the polar plate is accelerated.
It is noted that, herein, relational terms such as first and second, and the like may be used solely to distinguish one entity or action from another entity or action without necessarily requiring or implying any actual such relationship or order between such entities or actions. Also, the terms "comprises," "comprising," or any other variation thereof, are intended to cover a non-exclusive inclusion, such that a process, method, article, or apparatus that comprises a list of elements does not include only those elements but may include other elements not expressly listed or inherent to such process, method, article, or apparatus. Without further limitation, an element defined by the phrases "comprising a," "8230," "8230," or "comprising" does not exclude the presence of additional like elements in a process, method, article, or apparatus that comprises the element.
The foregoing is directed to embodiments of the present application and it is noted that numerous modifications and adaptations may be made by those skilled in the art without departing from the principles of the present application and are intended to be within the scope of the present application.

Claims (6)

1. The utility model provides a malleation solidification negative pressure drying system for battery, its characterized in that, is including the box that bears the battery, one side of box is provided with the door body of switching, one side of box is provided with the drive the circulating fan of the inside gas flow of box, the inside heater that is provided with of box, the bottom both sides of box are provided with steam humidification valve and blowoff valve respectively, the top of box has set gradually hydrofuge valve, relief valve, booster valve, humidification valve.
2. The positive-pressure curing and negative-pressure drying system for the storage battery of claim 1, wherein fan protection valves are arranged on two sides of the circulating fan.
3. The positive pressure curing negative pressure drying system for the storage battery as claimed in claim 1, wherein a PSV safety valve is provided at the top of the case.
4. The positive-pressure curing negative-pressure drying system for the storage battery as claimed in claim 1, wherein one side of the moisture exhaust valve, which is away from the box body, is sequentially connected with a cooling water tank, a condensed water collecting barrel and a moisture exhaust fan, and a condensed water discharge valve is arranged at the bottom of the condensed water collecting barrel.
5. The positive-pressure curing and negative-pressure drying system for the storage battery according to claim 1, wherein the door body is opened and closed in a lifting and sealing manner.
6. The method of using a positive pressure curing negative pressure drying system for storage batteries according to claim 1,
during curing: when the temperature, the humidity and the pressure do not reach set values, the steam humidifying valve is opened to spray steam to the inside, so that the temperature, the humidity and the pressure are synchronously increased; when the temperature reaches and the pressure and the humidity do not reach, opening a humidifying valve to increase the internal humidity and the pressure; when the temperature and the humidity reach and the pressure does not reach, the pressure increasing valve is opened to convey the compressed air inwards to increase the pressure,
and (3) during drying: circulating fan operation, heater work simultaneously, make the temperature rise, close heater and circulating fan after reaching the settlement temperature, open the outside hydrofuge of hydrofuge valve, after reaching the negative pressure value of settlement, close the hydrofuge valve, discharge the comdenstion water, a period of time stews afterwards, let the inside moisture of battery polar plate separate out the polar plate surface fast under the effect of negative pressure, open the relief valve again, let internal pressure resume the ordinary pressure, reopen heater, circulating fan, blowoff valve, rapid evaporation polar plate surface moisture, the circulation is several times, accomplish the drying.
CN202210783330.7A 2022-07-05 2022-07-05 Positive pressure curing negative pressure drying system for storage battery Withdrawn CN115235196A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN202210783330.7A CN115235196A (en) 2022-07-05 2022-07-05 Positive pressure curing negative pressure drying system for storage battery

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Application Number Priority Date Filing Date Title
CN202210783330.7A CN115235196A (en) 2022-07-05 2022-07-05 Positive pressure curing negative pressure drying system for storage battery

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Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH07153452A (en) * 1993-11-26 1995-06-16 Yuasa Corp Manufacture of negative electrode plate for lead-acid battery
CN2499983Y (en) * 2001-06-06 2002-07-10 江苏三环实业股份有限公司 Solidifying and drying device for accumulator polar plate
CN102856536A (en) * 2012-09-20 2013-01-02 江苏先特能源装备有限公司 Pressure container curing chamber and curing method thereof
CN105185950A (en) * 2015-07-22 2015-12-23 江苏苏中电池科技发展有限公司 High-temperature curing chamber and curing technology for battery pole plates
CN208336375U (en) * 2018-06-01 2019-01-04 骆驼集团襄阳蓄电池有限公司 A kind of lead-acid accumulator humidogene plate high temperature and pressure curing and drying device
CN109411708A (en) * 2018-10-08 2019-03-01 蔡锦良 A kind of polar plate of lead acid storage battery pressure-cure storehouse

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH07153452A (en) * 1993-11-26 1995-06-16 Yuasa Corp Manufacture of negative electrode plate for lead-acid battery
CN2499983Y (en) * 2001-06-06 2002-07-10 江苏三环实业股份有限公司 Solidifying and drying device for accumulator polar plate
CN102856536A (en) * 2012-09-20 2013-01-02 江苏先特能源装备有限公司 Pressure container curing chamber and curing method thereof
CN105185950A (en) * 2015-07-22 2015-12-23 江苏苏中电池科技发展有限公司 High-temperature curing chamber and curing technology for battery pole plates
CN208336375U (en) * 2018-06-01 2019-01-04 骆驼集团襄阳蓄电池有限公司 A kind of lead-acid accumulator humidogene plate high temperature and pressure curing and drying device
CN109411708A (en) * 2018-10-08 2019-03-01 蔡锦良 A kind of polar plate of lead acid storage battery pressure-cure storehouse

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Application publication date: 20221025

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