CN115216164A - Fire-resistant, corrosion-resistant and aging-resistant industrial paint for oil stations - Google Patents

Fire-resistant, corrosion-resistant and aging-resistant industrial paint for oil stations Download PDF

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Publication number
CN115216164A
CN115216164A CN202210846860.1A CN202210846860A CN115216164A CN 115216164 A CN115216164 A CN 115216164A CN 202210846860 A CN202210846860 A CN 202210846860A CN 115216164 A CN115216164 A CN 115216164A
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parts
inorganic
resistant
agent
solution
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CN202210846860.1A
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陈海平
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Harbin Xueying Engineering Materials Co ltd
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Harbin Xueying Engineering Materials Co ltd
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Priority to CN202210846860.1A priority Critical patent/CN115216164A/en
Publication of CN115216164A publication Critical patent/CN115216164A/en
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    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D1/00Coating compositions, e.g. paints, varnishes or lacquers, based on inorganic substances
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/08Anti-corrosive paints
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/18Fireproof paints including high temperature resistant paints

Abstract

The invention relates to the technical field of industrial paints, and discloses a fire-resistant, corrosion-resistant and aging-resistant industrial paint for an oil station, which comprises the following raw materials in parts by weight: 1-3 parts of wetting agent, 145-155 parts of deionized water, 95-105 parts of nano inorganic resin, 3-7 parts of inorganic dispersing agent, 4-6 parts of stabilizer, 2-4 parts of defoaming agent, 45-55 parts of flame retardant powder, 95-105 parts of titanium dioxide, 290-310 parts of inorganic composite filler, 4-6 parts of 250 cellulose, 70-80 parts of inorganic emulsion, 2-4 parts of inorganic film forming assistant and 190-210 parts of inorganic bonding material. The oil station fire-resistant corrosion-resistant aging-resistant industrial paint is suitable for painting or spraying the surface of a cement-based outer wall, has strong binding power to the cement-based outer wall, is not easy to crack, chap or fall off, and simultaneously has the advantages of aging resistance, acid and alkali corrosion resistance, fire resistance, good waterproof performance and the like.

Description

Fire-resistant, corrosion-resistant and aging-resistant industrial paint for oil stations
Technical Field
The invention relates to the technical field of industrial paints, in particular to a fire-resistant, corrosion-resistant and aging-resistant industrial paint for an oil station.
Background
The industrial paint is applied to the protection and decoration of equipment, ships, containers, bridges, gas tanks, port machinery, chemical equipment, railway tank cars, electric machinery, storage tanks, inner walls of pipelines, various steel structures, concrete and the like produced by industrial enterprises, and comprises asphalt paint, alkyd paint, amino paint, epoxy paint, polyurethane paint, acrylic paint, organic silicon paint, fluorocarbon paint, rubber paint and the like.
In the construction of oil stations, the building surface is necessarily coated with industrial paint for fire prevention, but the existing industrial paint has single component, so that the performance of the industrial paint is not comprehensive enough, and the industrial paint is mainly focused on one aspect.
Disclosure of Invention
Technical problem to be solved
Aiming at the defects of the prior art, the invention provides the fire-resistant, corrosion-resistant and aging-resistant industrial paint for the oil station, which has the advantages of comprehensive performance and the like.
(II) technical scheme
In order to achieve the purpose of comprehensive performance, the invention provides the following technical scheme: the oil station fire-resistant corrosion-resistant aging-resistant industrial paint comprises the following raw materials in parts by weight: 1-3 parts of wetting agent, 145-155 parts of deionized water, 95-105 parts of nano inorganic resin, 3-7 parts of inorganic dispersing agent, 4-6 parts of stabilizing agent, 2-4 parts of defoaming agent, 45-55 parts of flame retardant powder, 95-105 parts of titanium dioxide, 290-310 parts of inorganic composite filler, 4-6 parts of 250 cellulose, 70-80 parts of inorganic emulsion, 2-4 parts of inorganic film forming aid, 190-210 parts of inorganic bonding material, 60-70 parts of quartz powder, 5-7 parts of expanded perlite, 5-8 parts of waterproof agent, 3-5 parts of sodium bentonite, 7-10 parts of organic aid, 1-3 parts of active agent, 1.5-3 parts of silica sol and 0.5-1.8 parts of magnesium zinc ferrite.
Further, the active agent is lignosulfonic acid, and the wetting agent is hydroxypropyl methylcellulose.
Further, the feed comprises the following raw materials in parts by weight: 1-3 parts of wetting agent, 145-155 parts of deionized water, 95-105 parts of nano inorganic resin, 3-7 parts of inorganic dispersant, 4-6 parts of stabilizer, 2-4 parts of defoaming agent, 45-55 parts of flame retardant powder, 300-310 parts of inorganic composite filler, 6-8 parts of 250 cellulose, 70-80 parts of inorganic emulsion, 2-4 parts of inorganic film forming aid, 200-210 parts of inorganic bonding material, 60-70 parts of quartz powder, 5-7 parts of expanded perlite, 5-8 parts of waterproof agent, 7-10 parts of organic aid, 1-3 parts of active agent, 1.5-3 parts of silica sol and 0.5-1.8 parts of magnesium zinc ferrite
Further, the feed comprises the following raw materials in parts by weight: 1-3 parts of wetting agent, 120-135 parts of deionized water, 95-105 parts of nano inorganic resin, 3-7 parts of inorganic dispersant, 4-6 parts of stabilizer, 2-4 parts of defoamer, 45-55 parts of flame retardant powder, 90-100 parts of titanium dioxide, 250-260 parts of inorganic composite filler, 4-6 parts of 250 cellulose, 70-80 parts of inorganic emulsion, 2-4 parts of inorganic film forming aid, 190-210 parts of inorganic bonding material, 60-70 parts of quartz powder, 5-7 parts of expanded perlite, 5-8 parts of waterproof agent, 3-5 parts of sodium bentonite, 7-10 parts of organic aid, 1-3 parts of active agent, 1.5-3 parts of silica sol, 0.5-1.8 parts of magnesium zinc ferrite
The invention aims to solve another technical problem of providing a preparation method of the fire-resistant, corrosion-resistant and aging-resistant industrial paint for the oil station), which comprises the following steps:
1) Soaking quartz powder in sulfuric acid solution for 6-8 hours, washing with deionized water, soaking in sodium hydroxide solution for 3-4 hours, and washing with deionized water to neutrality to obtain neutral quartz powder;
2) Putting neutral quartz powder into a calcining furnace for calcining, wherein the calcining dimension is 600-700 ℃, the calcining time is 2-3 hours, and then adding expanded perlite, sodium bentonite and a proper amount of water for mixing, granulating and crushing to obtain modified quartz particles;
3) Weighing inorganic composite filler, inorganic emulsion and deionized water according to a proportion, mixing and stirring at a stirring speed of 40-60 r/min for 45-55 min, and uniformly mixing to obtain a solution A;
4) Weighing the flame retardant powder, the titanium dioxide, the stabilizer, the defoaming agent, the inorganic wetting agent and the inorganic dispersing agent according to the proportion, mixing and stirring at the stirring speed of 120-150 revolutions per minute for 40-50 minutes, and uniformly mixing to obtain a solution B;
5) Standing the solution A for 20-40 minutes, adding the nano inorganic resin, the 250 cellulose and the inorganic film-forming auxiliary agent, stirring for 30-60 minutes at the stirring speed of 30-40 revolutions per minute, and uniformly stirring and mixing to obtain a solution C;
6) Weighing the inorganic binder and the solution B according to the proportion, adding the inorganic binder and the solution B into the solution C, stirring and mixing at the stirring speed of 80-90 revolutions per minute for 40-50 minutes, and uniformly mixing to obtain a solution D;
7) Mixing the modified quartz particle D solution obtained in the step, stirring at the speed of 100-120 r/min for 10-20 min, heating to 220-260 ℃, and then preserving heat for 1-2 hours;
8) And (3) after the furnace body is cooled to 50 ℃, keeping the temperature for 2 hours, heating to 100-120 ℃, keeping the temperature for 1 hour, and cooling to the normal temperature at the speed of 20 ℃/hour to obtain the finished product of the industrial paint.
(III) advantageous effects
Compared with the prior art, the invention provides the fire-resistant, corrosion-resistant and aging-resistant industrial paint for the oil station, which has the following beneficial effects:
the oil station fire-resistant corrosion-resistant aging-resistant industrial paint is suitable for painting or spraying the surface of a cement-based outer wall, has strong binding power to the cement-based outer wall, is not easy to crack, chap or fall off, and simultaneously has the advantages of aging resistance, acid and alkali corrosion resistance, fire resistance, good waterproof performance and the like.
Detailed Description
The technical solutions in the embodiments of the present invention will be clearly and completely described below with reference to the embodiments of the present invention, and it is obvious that the described embodiments are only a part of the embodiments of the present invention, and not all of the embodiments. All other embodiments, which can be obtained by a person skilled in the art without making any creative effort based on the embodiments in the present invention, belong to the protection scope of the present invention.
The first embodiment is as follows: the oil station fire-resistant, corrosion-resistant and aging-resistant industrial paint comprises the following raw materials in parts by weight: 2 parts of wetting agent, 145 parts of deionized water, 95 parts of nano inorganic resin, 3 parts of inorganic dispersant, 4 parts of stabilizer, 2 parts of defoamer, 45 parts of flame retardant powder, 95 parts of titanium dioxide, 290 parts of inorganic composite filler, 4 parts of 250 cellulose, 70 parts of inorganic emulsion, 2 parts of inorganic film forming aid, 190 parts of inorganic bonding material, 60 parts of quartz powder, 5 parts of expanded perlite, 5 parts of waterproof agent, 3 parts of sodium bentonite, 7 parts of organic aid, 1 part of active agent, 1.5 parts of silica sol and 0.5 part of magnesium zinc ferrite.
Wherein, the active agent adopts lignosulfonic acid, and the wetting agent is hydroxypropyl methylcellulose.
The invention aims to solve another technical problem of providing a preparation method of the fire-resistant, corrosion-resistant and aging-resistant industrial paint for the oil station), which comprises the following steps:
1) Soaking quartz powder in sulfuric acid solution for 6.5 hours, washing with deionized water, soaking in sodium hydroxide solution for 3.5 hours, and washing with deionized water to neutrality to obtain neutral quartz powder;
2) Putting neutral quartz powder into a calcining furnace for calcining, wherein the calcining dimensionality is 680 ℃, the calcining time is 4 hours, and then adding expanded perlite, sodium bentonite and a proper amount of water, mixing, granulating and crushing to obtain modified quartz particles;
3) Weighing the inorganic composite filler, the inorganic emulsion and the deionized water according to the proportion, then mixing and stirring at the stirring speed of 55 revolutions per minute for 47 minutes to obtain a solution A after uniform mixing;
4) Weighing the flame retardant powder, the titanium dioxide, the stabilizer, the defoaming agent, the inorganic wetting agent and the inorganic dispersing agent according to the proportion, mixing and stirring at the stirring speed of 150 revolutions per minute for 55 minutes, and uniformly mixing to obtain a solution B;
5) Standing the solution A for 20-40 minutes, adding the nano inorganic resin, the 250 cellulose and the inorganic film-forming assistant, stirring for 55 minutes at the stirring speed of 35 revolutions per minute, and uniformly stirring and mixing to obtain a solution C;
6) Weighing the inorganic bonding material and the solution B according to the proportion, adding the inorganic bonding material and the solution B into the solution C, stirring and mixing at the stirring speed of 80-90 revolutions per minute for 40-50 minutes, and uniformly mixing to obtain a solution D;
7) Mixing the modified quartz particle D solution obtained in the step (A), stirring at the speed of 1120 rpm for 20 minutes, heating to 280 ℃, and then preserving heat for 2 hours;
8) And (3) after the furnace body is cooled to 50 ℃, keeping the temperature for 2 hours, heating to 110 ℃, keeping the temperature for 1 hour, and cooling to the normal temperature at the speed of 20 ℃/hour to obtain the finished product of the industrial paint.
Example two: the oil station fire-resistant, corrosion-resistant and aging-resistant industrial paint comprises the following raw materials in parts by weight: 2 parts of wetting agent, 150 parts of deionized water, 99 parts of nano inorganic resin, 5 parts of inorganic dispersant, 5 parts of stabilizer, 3 parts of defoaming agent, 48 parts of flame retardant powder, 300 parts of inorganic composite filler, 8 parts of 250 cellulose, 78 parts of inorganic emulsion, 3 parts of inorganic film-forming aid, 210 parts of inorganic bonding material, 67 parts of quartz powder, 7 parts of expanded perlite, 8 parts of waterproof agent, 9 parts of organic aid, 1.3 parts of active agent, 1.8 parts of silica sol and 0.8 part of magnesium-zinc ferrite.
The active agent is lignosulfonic acid, and the wetting agent is hydroxypropyl methylcellulose.
The invention aims to solve another technical problem of providing a preparation method of the fire-resistant, corrosion-resistant and aging-resistant industrial paint for the oil station), which comprises the following steps:
1) Soaking quartz powder in a sulfuric acid solution for 8 hours, washing with deionized water, soaking in a sodium hydroxide solution for 3 hours, and washing with deionized water to be neutral to obtain neutral quartz powder;
2) Putting neutral quartz powder into a calcining furnace for calcining, wherein the calcining dimension is 650 ℃, the calcining time is 3-4 hours, and then adding expanded perlite, sodium bentonite and a proper amount of water, mixing, granulating and crushing to obtain modified quartz particles;
3) Weighing inorganic composite filler, inorganic emulsion and deionized water according to a proportion, mixing and stirring at the stirring speed of 70 r/min for 45 min, and uniformly mixing to obtain a solution A;
4) Weighing the flame retardant powder, the titanium dioxide, the stabilizer, the defoaming agent, the inorganic wetting agent and the inorganic dispersing agent according to the proportion, mixing and stirring at the stirring speed of 120 revolutions per minute for 45 minutes to obtain a solution B after uniform mixing;
5) Standing the solution A for 30 minutes, adding the nano inorganic resin, 250 cellulose and the inorganic film-forming aid, stirring for 40 minutes at the stirring speed of 55 revolutions per minute, and uniformly stirring and mixing to obtain a solution C;
6) Weighing the inorganic binder and the solution B according to the proportion, adding the inorganic binder and the solution B into the solution C, stirring and mixing at the stirring speed of 90 revolutions per minute for 50 minutes, and uniformly mixing to obtain a solution D;
7) Mixing the modified quartz particle D solution obtained in the step (A), stirring at the speed of 120 revolutions per minute for 15 minutes, heating to 240 ℃, and then preserving heat for 1-2 hours;
8) And (3) after the furnace body is cooled to 50 ℃, keeping the temperature for 2 hours, heating to 110 ℃, keeping the temperature for 1 hour, and cooling to the normal temperature at the speed of 20 ℃/hour to obtain the finished product of the industrial paint.
The beneficial effects of the invention are: the industrial paint is particularly suitable for painting or spraying the surface of a cement-based outer wall, has strong binding power for the cement-based outer wall, is not easy to crack, chap or fall off, and simultaneously has the advantages of aging resistance, acid and alkali corrosion resistance, fire resistance, good waterproof performance and the like.
Although embodiments of the present invention have been shown and described, it will be appreciated by those skilled in the art that changes, modifications, substitutions and alterations can be made in these embodiments without departing from the principles and spirit of the invention, the scope of which is defined in the appended claims and their equivalents.

Claims (5)

1. The oil station fire-resistant, corrosion-resistant and aging-resistant industrial paint is characterized by comprising the following raw materials in parts by weight: 1-3 parts of wetting agent, 145-155 parts of deionized water, 95-105 parts of nano inorganic resin, 3-7 parts of inorganic dispersing agent, 4-6 parts of stabilizing agent, 2-4 parts of defoaming agent, 45-55 parts of flame retardant powder, 95-105 parts of titanium dioxide, 290-310 parts of inorganic composite filler, 4-6 parts of 250 cellulose, 70-80 parts of inorganic emulsion, 2-4 parts of inorganic film forming aid, 190-210 parts of inorganic bonding material, 60-70 parts of quartz powder, 5-7 parts of expanded perlite, 5-8 parts of waterproofing agent, 3-5 parts of sodium bentonite, 7-10 parts of organic aid, 1-3 parts of active agent, 1.5-3 parts of silica sol and 0.5-1.8 parts of magnesium zinc ferrite.
2. The industrial paint of claim 1, wherein the active agent is lignosulfonic acid and the wetting agent is hydroxypropyl methylcellulose.
3. The oil station fire-resistant corrosion-resistant aging-resistant industrial paint according to claim 1 is characterized by comprising the following raw materials in parts by weight: 1-3 parts of wetting agent, 145-155 parts of deionized water, 95-105 parts of nano inorganic resin, 3-7 parts of inorganic dispersant, 4-6 parts of stabilizer, 2-4 parts of defoaming agent, 45-55 parts of flame retardant powder, 300-310 parts of inorganic composite filler, 6-8 parts of 250 cellulose, 70-80 parts of inorganic emulsion, 2-4 parts of inorganic film forming aid, 200-210 parts of inorganic bonding material, 60-70 parts of quartz powder, 5-7 parts of expanded perlite, 5-8 parts of waterproof agent, 7-10 parts of organic aid, 1-3 parts of active agent, 1.5-3 parts of silica sol and 0.5-1.8 parts of magnesium zinc ferrite.
4. The oil station fire-resistant corrosion-resistant aging-resistant industrial paint according to claim 1 is characterized by comprising the following raw materials in parts by weight: 1-3 parts of wetting agent, 120-135 parts of deionized water, 95-105 parts of nano inorganic resin, 3-7 parts of inorganic dispersant, 4-6 parts of stabilizer, 2-4 parts of defoamer, 45-55 parts of flame retardant powder, 90-100 parts of titanium dioxide, 250-260 parts of inorganic composite filler, 4-6 parts of 250 cellulose, 70-80 parts of inorganic emulsion, 2-4 parts of inorganic film forming aid, 190-210 parts of inorganic bonding material, 60-70 parts of quartz powder, 5-7 parts of expanded perlite, 5-8 parts of waterproof agent, 3-5 parts of sodium bentonite, 7-10 parts of organic aid, 1-3 parts of active agent, 1.5-3 parts of silica sol and 0.5-1.8 parts of magnesium zinc ferrite.
5. The preparation method of the oil station fire-resistant, corrosion-resistant and aging-resistant industrial paint is characterized by comprising the following steps:
1) Soaking quartz powder in sulfuric acid solution for 6-8 hours, washing with deionized water, soaking in sodium hydroxide solution for 3-4 hours, and washing with deionized water to neutrality to obtain neutral quartz powder;
2) Putting neutral quartz powder into a calcining furnace for calcining, wherein the calcining dimensionality is between 600 and 700 ℃, the calcining time is 2 to 3 hours, and then adding expanded perlite, sodium bentonite and a proper amount of water, mixing, granulating and crushing to obtain modified quartz particles;
3) Weighing inorganic composite filler, inorganic emulsion and deionized water according to a proportion, mixing and stirring at a stirring speed of 40-60 r/min for 45-55 min, and uniformly mixing to obtain a solution A;
4) Weighing the flame retardant powder, the titanium dioxide, the stabilizer, the defoaming agent, the inorganic wetting agent and the inorganic dispersing agent according to the proportion, mixing and stirring at the stirring speed of 120-150 revolutions per minute for 40-50 minutes, and uniformly mixing to obtain a solution B;
5) Standing the solution A for 20-40 minutes, adding the nano inorganic resin, the 250 cellulose and the inorganic film-forming auxiliary agent, stirring for 30-60 minutes at the stirring speed of 30-40 revolutions per minute, and uniformly stirring and mixing to obtain a solution C;
6) Weighing the inorganic binder and the solution B according to the proportion, adding the inorganic binder and the solution B into the solution C, stirring and mixing at the stirring speed of 80-90 revolutions per minute for 40-50 minutes, and uniformly mixing to obtain a solution D;
7) Mixing the modified quartz particle D solution obtained in the step (A), stirring at the speed of 100-120 r/min for 10-20 min, heating to 220-260 ℃, and then preserving heat for 1-2 hours;
8) And (3) after the furnace body is cooled to 50 ℃, keeping the temperature for 2 hours, heating to 100-120 ℃, keeping the temperature for 1 hour, and cooling to the normal temperature at the speed of 20 ℃/hour to obtain the finished product of the industrial paint.
CN202210846860.1A 2022-07-19 2022-07-19 Fire-resistant, corrosion-resistant and aging-resistant industrial paint for oil stations Pending CN115216164A (en)

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CN202210846860.1A CN115216164A (en) 2022-07-19 2022-07-19 Fire-resistant, corrosion-resistant and aging-resistant industrial paint for oil stations

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CN202210846860.1A CN115216164A (en) 2022-07-19 2022-07-19 Fire-resistant, corrosion-resistant and aging-resistant industrial paint for oil stations

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Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2007016112A (en) * 2005-07-07 2007-01-25 Sugimura Kagaku Kogyo Kk Aqueous composition for use in formation of heat-resistant/corrosion-resistant coating film, and heat-resistant/corrosion-resistant coating film
CN104355589A (en) * 2014-10-08 2015-02-18 合肥向荣环保科技有限公司 Corrosion-resistant external wall coating
CN111019416A (en) * 2019-11-12 2020-04-17 立邦涂料(四川)有限公司 Fireproof reflective heat-insulation inorganic coating for exterior wall and preparation method thereof
CN111534133A (en) * 2020-06-24 2020-08-14 思贝克汀(厦门)新型建材有限公司 Negative oxygen ion inorganic coating and preparation method thereof
CN113308133A (en) * 2021-06-22 2021-08-27 山东智力佳建筑装饰材料有限责任公司 Inorganic antibacterial purifying fireproof coating
CN113528004A (en) * 2021-08-26 2021-10-22 黄鑫 Water-based nano inorganic finish paint

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2007016112A (en) * 2005-07-07 2007-01-25 Sugimura Kagaku Kogyo Kk Aqueous composition for use in formation of heat-resistant/corrosion-resistant coating film, and heat-resistant/corrosion-resistant coating film
CN104355589A (en) * 2014-10-08 2015-02-18 合肥向荣环保科技有限公司 Corrosion-resistant external wall coating
CN111019416A (en) * 2019-11-12 2020-04-17 立邦涂料(四川)有限公司 Fireproof reflective heat-insulation inorganic coating for exterior wall and preparation method thereof
CN111534133A (en) * 2020-06-24 2020-08-14 思贝克汀(厦门)新型建材有限公司 Negative oxygen ion inorganic coating and preparation method thereof
CN113308133A (en) * 2021-06-22 2021-08-27 山东智力佳建筑装饰材料有限责任公司 Inorganic antibacterial purifying fireproof coating
CN113528004A (en) * 2021-08-26 2021-10-22 黄鑫 Water-based nano inorganic finish paint

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Application publication date: 20221021