CN115180833A - Pearl dry particles, pearl glaze, preparation methods of pearl dry particles and pearl glaze and ceramic tile - Google Patents
Pearl dry particles, pearl glaze, preparation methods of pearl dry particles and pearl glaze and ceramic tile Download PDFInfo
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- CN115180833A CN115180833A CN202210808305.XA CN202210808305A CN115180833A CN 115180833 A CN115180833 A CN 115180833A CN 202210808305 A CN202210808305 A CN 202210808305A CN 115180833 A CN115180833 A CN 115180833A
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- dry particles
- pearlescent
- glaze
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- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C8/00—Enamels; Glazes; Fusion seal compositions being frit compositions having non-frit additions
- C03C8/14—Glass frit mixtures having non-frit additions, e.g. opacifiers, colorants, mill-additions
- C03C8/16—Glass frit mixtures having non-frit additions, e.g. opacifiers, colorants, mill-additions with vehicle or suspending agents, e.g. slip
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C8/00—Enamels; Glazes; Fusion seal compositions being frit compositions having non-frit additions
- C03C8/02—Frit compositions, i.e. in a powdered or comminuted form
- C03C8/04—Frit compositions, i.e. in a powdered or comminuted form containing zinc
Abstract
The invention discloses pearlescent dry particles, pearlescent glaze, preparation methods of the pearlescent dry particles and the pearlescent glaze and ceramic tiles. The pearly-luster dry particles comprise, by weight, 2-3 parts of high-temperature mica dry particles and 7-8 parts of matte transparent dry particles; the matte transparent dry particles comprise the following components in parts by weight: siO 2 2 50 to 55 portions of Al 2 O 3 15 to 18 portions of K 2 O2.5-3.5 parts, na 2 1-2 parts of O, 5-6 parts of BaO, 1-1.5 parts of MgO, 6-8 parts of CaO and 5-6 parts of ZnO. The high-temperature mica dry particles and the matte transparent dry particles with high aluminum, zinc and barium contents are matched, so that the sintering temperature of the pearlescent glaze is increased, and the pearlescent glaze can be applied to a high-temperature one-time rapid sintering process.
Description
Technical Field
The invention relates to the field of ceramics, in particular to pearlescent dry particles, pearlescent glaze, a preparation method of the pearlescent dry particles and the pearlescent glaze, and ceramics.
Background
The pearlescent ceramic is a product with pearl light sensation on the surface, and the product can show different pearlescent effects under different light angles.
At present, the pearl ceramic is generally fired in China by a secondary firing mode, the difficulty of the firing mode is low, however, biscuit firing is needed firstly, then glaze spraying printing is conducted, and then firing is conducted in a kiln, the consumed energy is large, and the steps are complicated. Therefore, one-time firing is a technology pursued by many enterprises in the industry, which can greatly save energy consumption, but the difficulty is high, and a ceramic blank which is not subjected to biscuit firing is easy to absorb moisture in glaze and becomes fragile.
In addition, the current pearl dry particles have low firing temperature, relatively long firing temperature, low production efficiency and difficult improvement of one-time firing due to the limitation of the firing temperature.
It is seen that improvements and enhancements in the prior art are needed.
Disclosure of Invention
In view of the defects of the prior art, the invention aims to provide the pearl dry particles, the pearl glaze, the preparation method of the pearl glaze and the ceramic tile, and aims to solve the technical problems that the sintering temperature of the pearl dry particles is low and the pearl ceramic product is difficult to sinter at one time in the prior art.
In order to achieve the purpose, the invention adopts the following technical scheme:
the pearlescent dry particles comprise the following components in parts by weight: 2-3 parts of high-temperature mica dry particles and 7-8 parts of matte transparent dry particles; the matte transparent dry particle comprises the following components in parts by weight: siO 2 2 50 to 55 portions of Al 2 O 3 15 to 18 portions of K 2 2.5 to 3.5 portions of O and Na 2 1 to 2 portions of O, 5 to 6 portions of BaO, 1 to 1.5 portions of MgO, 6 to 8 portions of CaO and 5 to 6 portions of ZnO.
The melting point of the high-temperature mica dry particles is 1150-1180 ℃.
The particle size of the high-temperature mica dry particle is 20-100 mu m.
The particle size of the pearlescent dry particles is 20-100 μm.
The high-temperature mica dry particle is white or yellow.
The pearlescent glaze comprises, by weight, 9-11 parts of the pearlescent dry particles and 50 parts of an aqueous suspending agent.
The pearl glaze has a specific gravity of 1.2-1.3.
The sintering temperature of the pearl glaze is 1180-1230 ℃.
A preparation method of pearlescent glaze is used for preparing the pearlescent glaze and comprises the following steps:
s001, processing the high-temperature mica blocks and the matte transparent frit into high-temperature mica dry particles and matte transparent dry particles through an airflow mill respectively; mixing the high-temperature mica dry particles and the matte transparent dry particles according to a ratio to prepare pearlescent dry particles;
and S002, mixing the pearlescent dry particles with the aqueous suspending agent according to the proportion to obtain the pearlescent glaze.
A ceramic tile, which comprises the pearlescent dry particles.
Has the advantages that:
the invention provides a pearlescent dry particle, which improves the firing temperature by matching high-temperature mica dry particles with matte transparent dry particles. The content of aluminum, zinc and barium in the formula of the matt transparent dry particle is higher, so that the pearlescent glaze has good color development when being sintered at high temperature, and the glaze surface can present a relatively pure pearlescent effect under natural light.
The invention also provides the pearlescent glaze, which is prepared by dispersing the pearlescent dry particles by using the aqueous suspending agent, can be used for firing the pearlescent ceramic at one time, and has high yield, and the fired pearlescent glaze has good stain resistance and friction resistance.
The invention also provides a preparation method of the pearlescent glaze, the method adopts an air flow mill to process the high-temperature mica blocks and the matte transparent frits into powder particles, the obtained high-temperature mica dry particles and the matte transparent dry particles have small particle size and are integrally uniform, uniform fluid is formed after the high-temperature mica dry particles and the matte transparent dry particles are mixed with the aqueous suspending agent, the preparation process is simple and convenient, and the efficiency is high.
The invention also provides a ceramic tile, which is prepared by adopting the pearlescent dry particles, and the surface of the ceramic tile can show pure pearlescent effect.
Drawings
FIG. 1 shows the brick surface coated with the staining agent of example 1.
FIG. 2 shows the brick surface after the cleaning with a wet cloth in example 1.
Detailed Description
The invention provides pearlescent dry particles, pearlescent glaze, a preparation method thereof and a ceramic tile, and the invention is further detailed by the following embodiments in order to make the purpose, technical scheme and effect of the invention clearer and more clear. It should be understood that the specific embodiments described herein are merely illustrative of the invention and do not limit the invention.
The invention provides a pearly-lustre dry particle which comprises the following components in parts by weight: 2-3 parts of high-temperature mica dry particles and 7-8 parts of matte transparent dry particles; the matte transparent dry particles comprise the following components in parts by weight: siO 2 2 50 to 55 portions of Al 2 O 3 15 to 18 portions of K 2 O2.5-3.5 parts, na 2 1 to 2 portions of O, 5 to 6 portions of BaO, 1 to 1.5 portions of MgO, 6 to 8 portions of CaO and 5 to 6 portions of ZnO. In order to improve the sintering temperature of the pearl dry particles, the high-temperature mica dry particles are adopted, so that the fusion or decomposition cannot occur at 1000 ℃, and the pearl effect can be formed at high temperature. In the matte transparent dry particles, siO 2 The product can be used for producing glass substance with alkali metal and alkaline earth metal oxide at high temperature, and can improve transparency, hardness, whiteness and chemical stability of glaze. Al (aluminum) 2 O 3 Can increase the sintering temperature and sintering temperature range, and can be mixed with SiO 2 Mullite is generated to form a framework. K 2 O and Na 2 O energy melting part of SiO 2 And Al 2 O 3 The surface generates a glass phase and is filled in the gap of the carcass framework, so that the density, the transparency and the mechanical strength of the finished product are improved. BaO is used to increase the gloss of the glaze and to reduce the melt viscosity. MgO can reduce the high-temperature viscosity, reduce the expansion coefficient of the glaze, improve the elasticity of the glaze and form a good intermediate layer between the blank glazes, thereby improving the thermal stability of the product, but the use of MgO is not excessive, otherwise the glossiness is reduced. CaO can also be reacted with SiO 2 And a glass phase is generated, the high-temperature viscosity of the glaze is reduced, the high-temperature fluidity of the glaze is increased, and the glaze surface is smooth and transparent. ZnO can increase the mechanical strength, elasticity, heat-resistant stability and luster of the glaze, but the using amount is not excessive, otherwise, crystals are easy to precipitate. In the inventionThe matt transparent dry particles are matched with high-aluminum, high-zinc and high-barium, so that the luster of the glaze surface can be obviously improved, and the firing temperature is increased.
The melting point of the high-temperature mica dry particles is 1150-1180 ℃, compared with the existing pearl powder (the melting point is 970-1000 ℃), the melting point of the high-temperature mica dry particles is improved by 180 ℃, and accordingly, the sintering temperature of the prepared pearl dry particles is improved, and the high-temperature mica dry particles can be used for high-temperature quick sintering.
Preferably, the particle size of the high-temperature mica dry particles is 20-100 μm. The smaller the particle size of the high-temperature mica dry particles is, the better the dispersibility is, but the particle size is not too small, otherwise, the surface gloss is influenced, and the pearly luster effect is poor.
Preferably, the particle size of the matt transparent dry particles is 20 to 100 μm. The smaller the particle size of the matte transparent dry particles is, the better the dispersibility is, the faster the high-temperature reaction speed is, the firing time can be reduced, but the particle size is not too small, otherwise, the surface is not smooth and the pattern cannot be controlled due to too large fluidity.
Preferably, the color of the high-temperature mica dry particles is white or yellow. The color of the pearl is white or yellow, and the glaze fired by the white or yellow high-temperature mica dry particles has a glaze effect more similar to the pearl color.
The pearly luster glaze comprises, by weight, 9-11 parts of the pearly luster dry particles and 50 parts of an aqueous suspending agent. The aqueous suspending agent is used for dispersing each component in the pearlescent dry particles to form fluid, so that the pearlescent glaze can be uniformly sprayed or sprinkled on the green body.
The specific gravity of the pearlescent glaze is 1.2-1.3. The glaze material has the most suitable consistency and fluidity under the specific gravity, and the glaze pouring effect is the best.
The sintering temperature of the pearl glaze is 1180-1230 ℃. The pearlescent glaze has the best color development and bright color at the temperature, and can show silvery white or silvery yellow pearlescent effect under natural light.
A preparation method of pearlescent glaze is used for preparing the pearlescent glaze and comprises the following steps:
s001, processing the high-temperature mica blocks and the matte transparent frit into high-temperature mica dry particles and matte transparent dry particles through an airflow mill respectively; mixing the high-temperature mica dry particles and the matte transparent dry particles according to a ratio to prepare pearlescent dry particles;
and S002, mixing the pearlescent dry particles with the aqueous suspending agent according to the proportion to obtain the pearlescent glaze.
Specifically, the matt transparent frit is prepared by the following steps: will respectively contain SiO 2 、Al 2 O 3 、K 2 O、Na 2 The raw materials of O, baO, mgO, caO and ZnO are prepared into powder, mixed according to the formula and melted, and the obtained bulk product can form a frit with smaller volume through water quenching, so that the grinding time of the jet mill can be shortened.
A ceramic tile, which comprises the pearlescent dry particles.
Example 1
The pearl dry particles comprise the following components in parts by weight: 3 parts of high-temperature mica dry particles and 7 parts of matte transparent dry particles; the matte transparent dry particle comprises the following components in parts by weight: siO 2 2 50 parts of Al 2 O 3 16 parts of K 2 3.5 portions of O and Na 2 1 part of O, 5 parts of BaO, 1.5 parts of MgO, 8 parts of CaO and 6 parts of ZnO.
The melting point of the high-temperature mica dry particles is 1150-1180 ℃.
The color of the high-temperature mica dry particles is white.
The pearlescent glaze comprises the following components in parts by weight: 10 parts of the pearl dry particles and 50 parts of aqueous suspending agent. The specific gravity of the pearlescent glaze is 1.2.
The preparation method of the pearlescent glaze comprises the following steps:
s001, processing the high-temperature mica blocks and the matte transparent frit into high-temperature mica dry particles and matte transparent dry particles through an airflow mill respectively; the particle size of the high-temperature mica dry particles is 20-100 mu m; the particle size of the matte transparent dry particles is 20-100 mu m; mixing the high-temperature mica dry particles and the matte transparent dry particles according to a ratio to prepare the pearlescent dry particles;
and S002, mixing 10 parts of pearlescent dry particles and 50 parts of aqueous suspending agent to obtain the pearlescent glaze.
A ceramic tile, the method of making comprising the steps of:
and (3) applying the prepared pearlescent glaze on the surface of the ceramic overglaze through glaze spraying or glaze pouring process, drying, then sending into a roller kiln, and firing at a high temperature in a kiln at 1210 ℃ to obtain the ceramic tile.
Example 2
The pearl dry particles comprise the following components in parts by weight: 2 parts of high-temperature mica dry particles and 8 parts of matt transparent dry particles; the matte transparent dry particles comprise the following components in parts by weight: siO 2 2 54 parts of Al 2 O 3 15 parts of, K 2 O3 parts, na 2 1.5 parts of O, 6 parts of BaO, 1.2 parts of MgO, 6 parts of CaO and 5.5 parts of ZnO.
The melting point of the high-temperature mica dry particles is 1150-1180 ℃.
The color of the high-temperature mica dry particles is white.
The pearlescent glaze comprises the following components in parts by weight: 11 parts of the pearl dry particles and 50 parts of aqueous suspending agent. The specific gravity of the pearlescent glaze is 1.3.
The preparation method of the pearlescent glaze comprises the following steps:
s001, processing the high-temperature mica blocks and the matte transparent frit into high-temperature mica dry particles and matte transparent dry particles through an airflow mill respectively; the particle size of the high-temperature mica dry particles is 20-100 mu m; the particle size of the matte transparent dry particles is 20-100 mu m; mixing the high-temperature mica dry particles and the matte transparent dry particles according to a ratio to prepare pearlescent dry particles;
and S002, mixing 11 parts of pearl dry particles and 50 parts of aqueous suspending agent to obtain the pearl glaze.
A ceramic tile, the method of making comprising the steps of:
and (3) applying the prepared pearlescent glaze on the surface of the ceramic overglaze through glaze spraying or glaze pouring process, drying, then sending into a roller kiln, and firing at high temperature in the kiln at 1200 ℃ to obtain the ceramic tile.
Example 3
A kind ofThe pearl dry particles comprise the following components in parts by weight: 3 parts of high-temperature mica dry particles and 8 parts of matte transparent dry particles; the matte transparent dry particles comprise the following components in parts by weight: siO 2 2 52 parts of Al 2 O 3 15 parts of, K 2 O2.5 parts, na 2 O2, baO5, mgO 1.5, caO 7 and ZnO 6.
The melting point of the high-temperature mica dry particles is 1150-1180 ℃.
The color of the high-temperature mica dry particles is yellow.
The pearlescent glaze comprises, by weight, 9 parts of the pearlescent dry particles and 50 parts of an aqueous suspending agent. The specific gravity of the pearlescent glaze is 1.3.
The preparation method of the pearlescent glaze comprises the following steps:
s001, processing the high-temperature mica blocks and the matte transparent frit into high-temperature mica dry particles and matte transparent dry particles through an airflow mill respectively; the particle size of the high-temperature mica dry particles is 20-100 mu m; the particle size of the matt transparent dry particles is 20-100 mu m; mixing the high-temperature mica dry particles and the matte transparent dry particles according to a ratio to prepare the pearlescent dry particles;
and S002, mixing 10 parts of pearlescent dry particles and 50 parts of aqueous suspending agent to obtain the pearlescent glaze.
A ceramic tile, the preparation method of which comprises the following steps:
and (3) applying the prepared pearlescent glaze on the surface of the ceramic overglaze through glaze spraying or glaze pouring process, drying, then sending into a roller kiln, and firing at high temperature in the kiln at 1200 ℃ to obtain the ceramic tile.
Example 4
The pearl dry particles comprise the following components in parts by weight: 2 parts of high-temperature mica dry particles and 7 parts of matte transparent dry particles; the matte transparent dry particle comprises the following components in parts by weight: siO 2 2 55 parts of Al 2 O 3 18 parts of, K 2 O3 parts, na 2 O2, baO5, mgO 1, caO 8 and ZnO 6.
The melting point of the high-temperature mica dry particles is 1150-1180 ℃.
The color of the high-temperature mica dry particles is white.
The pearly luster glaze comprises, by weight, 9 parts of the pearly luster dry particles and 50 parts of an aqueous suspending agent. The specific gravity of the pearlescent glaze is 1.2.
The preparation method of the pearlescent glaze comprises the following steps:
s001, processing the high-temperature mica blocks and the matte transparent frit into high-temperature mica dry particles and matte transparent dry particles through an airflow mill respectively; the particle size of the high-temperature mica dry particles is 20-100 mu m; the particle size of the matt transparent dry particles is 20-100 mu m; mixing the high-temperature mica dry particles and the matte transparent dry particles according to a ratio to prepare the pearlescent dry particles;
and S002, mixing 11 parts of pearl dry particles and 50 parts of aqueous suspending agent to obtain the pearl glaze.
A ceramic tile, the method of making comprising the steps of:
and (3) applying the prepared pearlescent glaze on the surface of the ceramic overglaze through glaze spraying or glaze pouring, drying, then sending into a roller kiln, and firing at a high temperature in a 1180 ℃ kiln to obtain the ceramic tile.
The ceramic tiles prepared in examples 1-4 were tested for gloss and stain resistance.
Wherein, the glossiness is measured by adopting a glossiness meter; the stain resistance is determined according to GB/T3810.14-2006 ceramic tile test method part 14: measurement of stain resistance "".
The results of the correlation measurements are as follows:
| degree of gloss | Stain resistance | |
| Example 1 | 42 | Class A |
| Example 2 | 50 | Class A |
| Example 3 | 35 | Class A |
| Example 4 | 47 | Class A |
From the above results, it can be seen that the pearly luster glaze surface prepared by the invention has the glossiness of 35-50, can present the pearly luster effect similar to pearls, and has excellent pollution resistance, and the pollution resistance of the ceramic tiles prepared by the examples 1-4 reaches the A level. Fig. 1 and 2 show the contamination resistance of the brick surface after the smearing and the scrubbing of the contamination-resistant agent in example 1, respectively, and it can be seen from fig. 2 that the smearing agent can be easily scrubbed only by using a wet cloth, and the scrubbed brick surface has no trace.
It should be understood that equivalents and modifications to the invention as described herein may occur to those skilled in the art, and all such modifications and alterations are intended to fall within the scope of the appended claims.
Claims (10)
1. The pearlescent dry particle is characterized by comprising the following components in parts by weight: 2-3 parts of high-temperature mica dry particles and 7-8 parts of matt transparent dry particles; the matte transparent dry particle comprises the following components in parts by weight:SiO 2 50 to 55 portions of Al 2 O 3 15 to 18 portions of K 2 O2.5-3.5 parts, na 2 1 to 2 portions of O, 5 to 6 portions of BaO, 1 to 1.5 portions of MgO, 6 to 8 portions of CaO and 5 to 6 portions of ZnO.
2. The pearlescent dry particle of claim 1, wherein the melting point of the high temperature mica dry particle is 1150-1180 ℃.
3. A pearlescent dried particle according to claim 1 wherein the particle size of the high temperature mica dried particle is 20 to 100 μm.
4. A pearlescent dried particle according to claim 1 wherein the particle diameter of the semi-opaque transparent dried particle is 20 to 100 μm.
5. The pearlescent dry particles of claim 1, wherein the color of the high temperature mica dry particles is white or yellow.
6. A pearlescent glaze, which is characterized by comprising the following components, by weight, 9 to 11 parts of pearlescent dry particles according to any one of claims 1 to 5 and 50 parts of aqueous suspending agent.
7. The pearlescent glaze according to claim 6, wherein the specific gravity is 1.2 to 1.3.
8. The pearlescent glaze according to claim 6, wherein the firing temperature is 1180 ℃ to 1230 ℃.
9. A method for preparing a pearlescent glaze, which is used for preparing the pearlescent glaze of any one of claims 6 to 8, and comprises the following steps:
s001, respectively processing the high-temperature mica blocks and the matt transparent frit into high-temperature mica dry particles and matt transparent dry particles through an air flow mill; mixing the high-temperature mica dry particles and the matte transparent dry particles according to a ratio to prepare the pearlescent dry particles;
and S002, mixing the pearl dry particles and the aqueous suspending agent according to the proportion to obtain the pearl glaze.
10. Ceramic tile comprising the pearlescent dry particles of any one of claims 1-5.
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN202210808305.XA CN115180833A (en) | 2022-07-11 | 2022-07-11 | Pearl dry particles, pearl glaze, preparation methods of pearl dry particles and pearl glaze and ceramic tile |
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| CN202210808305.XA CN115180833A (en) | 2022-07-11 | 2022-07-11 | Pearl dry particles, pearl glaze, preparation methods of pearl dry particles and pearl glaze and ceramic tile |
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN116217271A (en) * | 2023-01-09 | 2023-06-06 | 黄宝达 | Pearlescent dry particle ceramic tile and preparation method thereof |
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| CN116217271A (en) * | 2023-01-09 | 2023-06-06 | 黄宝达 | Pearlescent dry particle ceramic tile and preparation method thereof |
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