CN115142257A - Preparation method and application of MXene flexible fabric - Google Patents
Preparation method and application of MXene flexible fabric Download PDFInfo
- Publication number
- CN115142257A CN115142257A CN202110337343.7A CN202110337343A CN115142257A CN 115142257 A CN115142257 A CN 115142257A CN 202110337343 A CN202110337343 A CN 202110337343A CN 115142257 A CN115142257 A CN 115142257A
- Authority
- CN
- China
- Prior art keywords
- mxene
- fibers
- fabrics
- spinning
- cloth
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000004744 fabric Substances 0.000 title claims abstract description 55
- 238000002360 preparation method Methods 0.000 title claims abstract description 13
- 239000000835 fiber Substances 0.000 claims abstract description 28
- 238000000034 method Methods 0.000 claims abstract description 21
- 238000004519 manufacturing process Methods 0.000 claims abstract description 9
- 238000009987 spinning Methods 0.000 claims abstract description 8
- 239000000463 material Substances 0.000 claims abstract description 5
- 238000002074 melt spinning Methods 0.000 claims abstract description 4
- 238000002166 wet spinning Methods 0.000 claims abstract description 4
- 239000002131 composite material Substances 0.000 claims abstract description 3
- 238000001523 electrospinning Methods 0.000 claims abstract description 3
- 238000000576 coating method Methods 0.000 claims description 8
- 239000000758 substrate Substances 0.000 claims description 8
- 229920000742 Cotton Polymers 0.000 claims description 7
- 239000011248 coating agent Substances 0.000 claims description 7
- 239000006185 dispersion Substances 0.000 claims description 7
- 239000004677 Nylon Substances 0.000 claims description 6
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 claims description 6
- 238000001035 drying Methods 0.000 claims description 6
- 229920001778 nylon Polymers 0.000 claims description 6
- 239000002356 single layer Substances 0.000 claims description 5
- 239000010410 layer Substances 0.000 claims description 4
- 238000001291 vacuum drying Methods 0.000 claims description 4
- 239000002759 woven fabric Substances 0.000 claims description 4
- 235000017166 Bambusa arundinacea Nutrition 0.000 claims description 3
- 235000017491 Bambusa tulda Nutrition 0.000 claims description 3
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 3
- 235000015334 Phyllostachys viridis Nutrition 0.000 claims description 3
- 239000011425 bamboo Substances 0.000 claims description 3
- 229910052799 carbon Inorganic materials 0.000 claims description 3
- 238000005266 casting Methods 0.000 claims description 3
- 238000003618 dip coating Methods 0.000 claims description 3
- 229920000728 polyester Polymers 0.000 claims description 3
- 239000002096 quantum dot Substances 0.000 claims description 3
- 229910052709 silver Inorganic materials 0.000 claims description 3
- 239000004332 silver Substances 0.000 claims description 3
- 238000005507 spraying Methods 0.000 claims description 3
- 229920002994 synthetic fiber Polymers 0.000 claims description 3
- 239000012209 synthetic fiber Substances 0.000 claims description 3
- 238000002788 crimping Methods 0.000 claims description 2
- 230000001590 oxidative effect Effects 0.000 claims description 2
- 239000002904 solvent Substances 0.000 claims description 2
- 241000219146 Gossypium Species 0.000 claims 1
- 235000004431 Linum usitatissimum Nutrition 0.000 claims 1
- 240000006240 Linum usitatissimum Species 0.000 claims 1
- 244000082204 Phyllostachys viridis Species 0.000 claims 1
- 230000000694 effects Effects 0.000 abstract description 8
- 239000004753 textile Substances 0.000 abstract description 4
- 230000001954 sterilising effect Effects 0.000 abstract description 2
- 239000011149 active material Substances 0.000 abstract 1
- 238000004659 sterilization and disinfection Methods 0.000 abstract 1
- 230000000844 anti-bacterial effect Effects 0.000 description 8
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 7
- 239000007864 aqueous solution Substances 0.000 description 6
- PQXKHYXIUOZZFA-UHFFFAOYSA-M lithium fluoride Chemical compound [Li+].[F-] PQXKHYXIUOZZFA-UHFFFAOYSA-M 0.000 description 6
- 239000000243 solution Substances 0.000 description 6
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 4
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 4
- 238000005406 washing Methods 0.000 description 4
- 238000005516 engineering process Methods 0.000 description 3
- 239000000843 powder Substances 0.000 description 3
- 238000002791 soaking Methods 0.000 description 3
- 238000003756 stirring Methods 0.000 description 3
- 241001330002 Bambuseae Species 0.000 description 2
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 2
- 238000005520 cutting process Methods 0.000 description 2
- 239000008367 deionised water Substances 0.000 description 2
- 229910021641 deionized water Inorganic materials 0.000 description 2
- 238000005530 etching Methods 0.000 description 2
- 239000011259 mixed solution Substances 0.000 description 2
- 239000002245 particle Substances 0.000 description 2
- 239000002994 raw material Substances 0.000 description 2
- VDZOOKBUILJEDG-UHFFFAOYSA-M tetrabutylammonium hydroxide Chemical compound [OH-].CCCC[N+](CCCC)(CCCC)CCCC VDZOOKBUILJEDG-UHFFFAOYSA-M 0.000 description 2
- 241000894006 Bacteria Species 0.000 description 1
- NIPNSKYNPDTRPC-UHFFFAOYSA-N N-[2-oxo-2-(2,4,6,7-tetrahydrotriazolo[4,5-c]pyridin-5-yl)ethyl]-2-[[3-(trifluoromethoxy)phenyl]methylamino]pyrimidine-5-carboxamide Chemical compound O=C(CNC(=O)C=1C=NC(=NC=1)NCC1=CC(=CC=C1)OC(F)(F)F)N1CC2=C(CC1)NN=N2 NIPNSKYNPDTRPC-UHFFFAOYSA-N 0.000 description 1
- 239000003242 anti bacterial agent Substances 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 230000003115 biocidal effect Effects 0.000 description 1
- 238000004140 cleaning Methods 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 239000002270 dispersing agent Substances 0.000 description 1
- 238000010041 electrostatic spinning Methods 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 231100000252 nontoxic Toxicity 0.000 description 1
- 230000003000 nontoxic effect Effects 0.000 description 1
- 238000000643 oven drying Methods 0.000 description 1
- 238000004321 preservation Methods 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 238000004506 ultrasonic cleaning Methods 0.000 description 1
Images
Classifications
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
- D06M11/73—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with carbon or compounds thereof
- D06M11/74—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with carbon or compounds thereof with carbon or graphite; with carbides; with graphitic acids or their salts
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M16/00—Biochemical treatment of fibres, threads, yarns, fabrics, or fibrous goods made from such materials, e.g. enzymatic
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M2101/00—Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
- D06M2101/02—Natural fibres, other than mineral fibres
- D06M2101/04—Vegetal fibres
- D06M2101/06—Vegetal fibres cellulosic
Landscapes
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Life Sciences & Earth Sciences (AREA)
- Chemical & Material Sciences (AREA)
- Biochemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Microbiology (AREA)
- Chemical Or Physical Treatment Of Fibers (AREA)
Abstract
The invention discloses a preparation method and application of MXene flexible cloth, which comprises fibers, yarns and fabrics based on MXene. MXene active materials were incorporated into textile-based architectures using two methods to make MXene-based fibers, yarns and fabrics. One method is to coat the fiber or yarn with an MXene material, which can penetrate into the yarn, coat individual fibers, or form a sheath around the surface of the yarn. Another method is to incorporate MXene into a spinning recipe to produce a custom composite fiber by melt spinning, wet spinning, electrospinning or other methods. The MXene flexible cloth prepared by the method can be used for manufacturing clothes, bedding, cloth crafts, masks, bandages and the like. The MXene flexible fabric prepared by the method has good photo-thermal effect and sterilization effect, is simple in manufacturing method and low in cost, and can be prepared in a large scale.
Description
Technical Field
The invention belongs to the technical field of textiles, and particularly relates to a preparation method and application of MXene flexible cloth.
Background
The textile industry improves the cloth raw materials and the processing technology to produce the cloth with great practical value such as water resistance, heat preservation, antibiosis and the like. The demand of people for cloth with special performance also greatly promotes the updating and development of the textile industry. In the prior art, the antibacterial cloth is mainly prepared by modifying fiber raw materials through nano silver and other materials, but in the using process, the nano silver particles cannot be tightly combined with fibers, so that the nano silver particles can gradually fall off along with the increase of washing times, the antibacterial effect of the antibacterial cloth is reduced rapidly and obviously, and the production cost is high. In addition, the research on the functions of the cloth tends to be diversified at present, the warm-keeping performance is better in cold winter, and the comfortable warm-keeping effect can be provided for wearers. Therefore, the MXene is used for improving the fibers, and the fabric added with the MXene and having good antibacterial and warm-keeping effects is provided.
Disclosure of Invention
In order to solve the problems that in the prior art, bacteria are easy to breed in clothes, and the antibacterial effect and the heat retention are poor, the invention provides the MXene flexible fabric with good antibacterial and heat retention effects.
In order to solve the problems, the technical scheme adopted by the invention is as follows:
the MXene flexible cloth is characterized by comprising fibers, yarns and fabrics based on MXene, wherein the MXene comprises Ti 3 C 2 、Ti 2 C、Nb 2 C、V 2 C. The method for manufacturing the MXene-based fiber, yarn and fabric comprises the following steps of (1) one or any combination of more than two of TiVC multilayer, few layers, single layer and quantum dot, wherein the methods for manufacturing the MXene-based fiber, yarn and fabric comprise coating a substrate with MXene materials and introducing MXene into a spinning formula, and the coating method comprises dip coating, spray coating and drop casting; the substrate comprises natural fibers (cotton, linen, bamboo), individual fibers (twisted yarns and knitted and woven fabrics), synthetic fibers (nylon, polyester, silver-coated nylon, carbon-based fabrics); the spinning technology comprises melt spinning, wet spinning, electrostatic spinning or double-curling technology; the MXene flexible cloth can be used for manufacturing clothes, bedding, cloth art, masks, gauzes and the like.
The preparation method of the MXene flexible cloth comprises the following steps:
(1) Preparing a homogeneous MXene dispersion;
(2) Preparing MXene-based fibers, yarns and fabrics by using the dispersion obtained in the step (1);
(3) Carrying out vacuum drying on the MXene fibers, yarns and fabrics obtained in the step (2) to obtain MXene flexible cloth;
further, in the step (1) of the above technical scheme, the MXene comprises Ti 3 C 2 、Ti 2 C、Nb 2 C、V 2 C. One or more arbitrary combinations of TiVC multilayer, few layers, single layer and quantum dot.
Further, the method for manufacturing the MXene-based fiber, yarn and fabric in the step (2) of the technical scheme has two methods, and the steps are as follows:
i, MXene material coating fiber or yarn
First a homogeneous aqueous MXene dispersion is prepared, natural fibers (cotton, linen, bamboo), individual fibers (twisted yarn and knitted and woven fabrics), synthetic fibers (nylon, polyester, silver coated nylon, carbon based fabrics) are coated by dip coating, spray coating, drop casting, the coated substrate is dried in air or in an oven at low temperature (< 80 ℃) to evaporate the solvent quickly without oxidizing MXene or burning the fibrous substrate. In practice, this process may be repeated until the desired MXene coated substrate is achieved.
II, introducing MXene into a spinning formula
MXene is first added to a spinning dope and the MXene-based composite fiber is produced by melt spinning, wet spinning, electrospinning or double crimping techniques.
Further, the MXene flexible cloth in the step (3) of the technical scheme can be used for manufacturing clothes, bedding, cloth art, masks, gauze and the like.
Compared with the prior art, the technical scheme of the invention can obtain the following beneficial effects:
(1) Compared with the traditional preparation process, the MXene flexible fabric is simpler, can adopt a dipping-drying method, is nontoxic, pollution-free, environment-friendly and strong in operability, and does not fade;
(2) Due to the good hydrophilicity of MXene, when preparing an MXene dispersion liquid coating, soaking a woven fabric and introducing the MXene into a spinning formula, no other dispersing agent needs to be added;
(3) The MXene flexible fabric has a good photo-thermal effect, so that the MXene flexible fabric has a good heat-producing and warm-keeping effect, and the fabric has good antibacterial performance without adding an additional antibacterial agent;
(4) The preparation method of the MXene flexible fabric has universality, is simple in preparation method and low in cost, and can be used for large-scale preparation.
Drawings
Fig. 1 is a flow chart of the preparation of the MXene flexible cloth of the present invention;
FIG. 2 shows Ti in example 1 3 C 2 The photo-thermal effect of the fabric;
fig. 3 shows the antibacterial effect of the TiVC fabric in example 2.
Detailed Description
In order to facilitate the understanding of the present invention, the technical solutions of the present patent will be described in further detail with reference to the following embodiments.
Example 1
(1) Preparation of Ti 3 C 2 Aqueous solution
Dissolving 1 g lithium fluoride in 20 mL hydrochloric acid solution with concentration of 6 mol/L to obtain LiF/HCl mixed solution, and dissolving 1 g Ti at room temperature 3 AlC 2 Adding the powder into LiF/HCl mixed solution, stirring and etching 24 h, washing with water and drying to obtain Ti 3 C 2 (ii) a Mixing Ti 3 C 2 Adding the mixture into an aqueous solution, and uniformly dispersing by ultrasonic to obtain Ti with the concentration of 2 mg/mL 3 C 2 An aqueous solution;
（2）Ti 3 C 2 coated fabric
Ultrasonically cleaning commercially available cotton cloth in acetone, alcohol and deionized water solution for 30 min, drying, cutting into 2 × 2 cm square, and soaking the cloth in the Ti 3 C 2 And (5) dissolving in water for 5 min. Vacuum drying the above Ti at 60 deg.C 3 C 2 And coating flexible cloth.
Example 2
(1) Preparation of aqueous TiVC solution
Adding 1 g of TiVAlC powder into 10 mL of 55% HF solution, stirring and etching 24 h, washing with water, and drying to obtain TiVC; adding 1 g of TiVAlC powder into 10 mL tetrabutyl ammonium hydroxide, stirring for 30 min, washing with water, and drying to obtain single-layer TiVC; adding the single-layer TiVC into the aqueous solution, and uniformly dispersing by ultrasonic to obtain a TiVC aqueous solution with the concentration of 0.05 mg/mL;
(2) TiVC coating fabric
Cutting commercially available cotton thread into small segments, ultrasonic cleaning in acetone, alcohol, and deionized water solution for 30 min, oven drying, and soaking in the above TiVC aqueous solution for 5 min. Vacuum drying the TiVC cotton thread at 60 deg.C, wherein the cotton thread can be woven into sterilizing layer of mask or medical gauze and bandage.
The foregoing illustrates and describes the principles, general features, and advantages of the present invention. It will be understood by those skilled in the art that the present invention is not limited to the embodiments described above, which are described in the specification and illustrated only to illustrate the principle of the present invention, but that various changes and modifications may be made therein without departing from the spirit and scope of the present invention, which fall within the scope of the invention as claimed. The scope of the invention is defined by the appended claims and equivalents thereof.
Claims (4)
1. A preparation method of MXene flexible cloth is characterized by comprising the following steps: the method comprises the following steps:
(1) Preparing a homogeneous MXene dispersion;
(2) Preparing MXene-based fibers, yarns and fabrics by using the dispersion obtained in the step (1);
(3) And (3) carrying out vacuum drying on the MXene fibers, yarns and fabrics obtained in the step (2) to obtain the MXene flexible cloth.
2. The method for preparing MXene flexible cloth according to claim 1, characterized by: the MXene in the step 1 comprises Ti 3 C 2 、Ti 2 C、Nb 2 C、V 2 C. One or more arbitrary combinations of TiVC multilayer, few layers, single layer and quantum dot.
3. The method of claim 1, wherein the step of forming the MXene flexible cloth comprises: there are two methods for making MXene-based fibers, yarns and fabrics described in step 2, the steps being as follows:
i, MXene material coating fiber or yarn
Firstly, preparing homogeneous MXene aqueous dispersion, coating natural fibers (cotton, flax and bamboo), single fibers (twisted yarn and knitted and woven fabrics), synthetic fibers (nylon, polyester, silver-coated nylon and carbon-based fabrics) by adopting a dip coating, spray coating and drop casting method, drying the coated substrate in air or in an oven at low temperature (80 ℃) so as to quickly evaporate solvent without oxidizing MXene or burning the fiber substrate, and repeating the process in the actual operation process until the required MXene coated substrate is reached;
II, introducing MXene into a spinning formula
MXene is first added to a spinning dope by melt spinning, wet spinning, electrospinning or double crimping techniques to produce MXene-based composite fibers.
4. An article of apparel, bedding, cloth art, mask, gauze, etc. made by the method of making an MXene flexible cloth of any one of claims 1-3.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN202110337343.7A CN115142257A (en) | 2021-03-30 | 2021-03-30 | Preparation method and application of MXene flexible fabric |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN202110337343.7A CN115142257A (en) | 2021-03-30 | 2021-03-30 | Preparation method and application of MXene flexible fabric |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN115142257A true CN115142257A (en) | 2022-10-04 |
Family
ID=83404701
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN202110337343.7A Pending CN115142257A (en) | 2021-03-30 | 2021-03-30 | Preparation method and application of MXene flexible fabric |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN115142257A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN116289180A (en) * | 2023-02-08 | 2023-06-23 | 江苏大同宝富纺织科技有限公司 | Forming, dyeing and finishing processing method for synthetic fiber fabric with conductive function |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110714273A (en) * | 2019-10-17 | 2020-01-21 | 宁波甬烯光电科技有限公司 | Mxene/polylactic acid non-woven fabric and preparation method thereof |
| CN111304777A (en) * | 2020-04-15 | 2020-06-19 | 西安工业大学 | Electrostatic spinning preparation method of degradable and high-conductivity MXene composite film |
| CN111501326A (en) * | 2020-05-13 | 2020-08-07 | 郑州大学 | Multifunctional wearable polymer/MXene composite fabric heater and preparation method thereof |
| CN112458553A (en) * | 2020-10-29 | 2021-03-09 | 烟台泰和新材料股份有限公司 | High-performance carbon nano/MXene composite fiber and preparation method thereof |
-
2021
- 2021-03-30 CN CN202110337343.7A patent/CN115142257A/en active Pending
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110714273A (en) * | 2019-10-17 | 2020-01-21 | 宁波甬烯光电科技有限公司 | Mxene/polylactic acid non-woven fabric and preparation method thereof |
| CN111304777A (en) * | 2020-04-15 | 2020-06-19 | 西安工业大学 | Electrostatic spinning preparation method of degradable and high-conductivity MXene composite film |
| CN111501326A (en) * | 2020-05-13 | 2020-08-07 | 郑州大学 | Multifunctional wearable polymer/MXene composite fabric heater and preparation method thereof |
| CN112458553A (en) * | 2020-10-29 | 2021-03-09 | 烟台泰和新材料股份有限公司 | High-performance carbon nano/MXene composite fiber and preparation method thereof |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN116289180A (en) * | 2023-02-08 | 2023-06-23 | 江苏大同宝富纺织科技有限公司 | Forming, dyeing and finishing processing method for synthetic fiber fabric with conductive function |
| CN116289180B (en) * | 2023-02-08 | 2024-01-02 | 江苏大同宝富纺织科技有限公司 | Forming, dyeing and finishing processing method for synthetic fiber fabric with conductive function |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN106978721A (en) | A kind of preparation method of long-acting antibiotic textile | |
| KR20090110004A (en) | Functional Soft Union cloth Used Natural Materials Finished | |
| CN109518458A (en) | It is a kind of using silk as the metal nanometer line of substrate/graphene conductive material and preparation method thereof | |
| CN101307526A (en) | Bamboo charcoal fibre face fabric manufacturing technique | |
| CN102493014B (en) | A kind of epsilon-polylysine polyvinyl alcohol compound bio anti-bacterial fibre and preparation method thereof | |
| WO2019014968A1 (en) | In-situ-based preparation method for antibacterial ribbon | |
| CN114108309A (en) | Graphene multifunctional fabric and preparation method and application thereof | |
| CN115142257A (en) | Preparation method and application of MXene flexible fabric | |
| CN106079761B (en) | A kind of nanofiber high magnification hydrophilic nonwoven material and preparation method | |
| CN109576990A (en) | A kind of silk electrode material and preparation method thereof based on silver nanowires conductive network | |
| CN206501534U (en) | A kind of antibacterial flame-retardant looped fabric | |
| CN109972279A (en) | A kind of preparation method of the nice and cool blended yarn weaved fabric of wide cut | |
| CN109594174A (en) | A kind of graphene function of driving mosquitoes fabric and preparation method thereof | |
| KR20120064736A (en) | Weaving method of both different color pattern fabric used chitosan finishing fiber | |
| CN112359453A (en) | Composite yarn and preparation method thereof | |
| CN105113218B (en) | A kind of manufacturing process of antibacterial vamp | |
| KR101125253B1 (en) | Skin-core fiber comprising anionic polymer salt and cellulose, and method for manufacturing the same | |
| CN206244979U (en) | A kind of antibacterial thermal insulating looped fabric | |
| CN106555267A (en) | A kind of antibacterial thermal insulating looped fabric and its production technology | |
| CN107653533A (en) | A kind of preparation method of antibacterial, deodorization summer shirt fabric | |
| CN214782379U (en) | Graphene fiber composite yarn | |
| CN206359819U (en) | A kind of antibiotic radiation proof looped fabric | |
| CN107700020A (en) | A kind of manufacture method of Nano Silver weaving face fabric | |
| CN112853563A (en) | Graphene fiber composite yarn and spinning process thereof | |
| CN108103670A (en) | A kind of manufacturing method of Breathable nonwoven |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| WD01 | Invention patent application deemed withdrawn after publication |
Application publication date: 20221004 |
|
| WD01 | Invention patent application deemed withdrawn after publication |