CN112359453A - Composite yarn and preparation method thereof - Google Patents
Composite yarn and preparation method thereof Download PDFInfo
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- CN112359453A CN112359453A CN202011230852.1A CN202011230852A CN112359453A CN 112359453 A CN112359453 A CN 112359453A CN 202011230852 A CN202011230852 A CN 202011230852A CN 112359453 A CN112359453 A CN 112359453A
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- 239000002131 composite material Substances 0.000 title claims abstract description 20
- 238000002360 preparation method Methods 0.000 title claims description 8
- 239000000835 fiber Substances 0.000 claims abstract description 39
- 238000004321 preservation Methods 0.000 claims abstract description 32
- 229920000742 Cotton Polymers 0.000 claims abstract description 31
- 235000017166 Bambusa arundinacea Nutrition 0.000 claims abstract description 20
- 235000017491 Bambusa tulda Nutrition 0.000 claims abstract description 20
- 235000015334 Phyllostachys viridis Nutrition 0.000 claims abstract description 20
- 239000011425 bamboo Substances 0.000 claims abstract description 20
- 239000003610 charcoal Substances 0.000 claims abstract description 20
- 210000004209 hair Anatomy 0.000 claims abstract description 14
- 244000132059 Carica parviflora Species 0.000 claims abstract description 13
- 235000014653 Carica parviflora Nutrition 0.000 claims abstract description 13
- 241000272525 Anas platyrhynchos Species 0.000 claims abstract description 12
- 241000272814 Anser sp. Species 0.000 claims abstract description 12
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 claims abstract description 12
- 241000283973 Oryctolagus cuniculus Species 0.000 claims abstract description 12
- 210000002268 wool Anatomy 0.000 claims abstract description 12
- 239000002105 nanoparticle Substances 0.000 claims description 33
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims description 20
- 241001330002 Bambuseae Species 0.000 claims description 19
- 238000004804 winding Methods 0.000 claims description 12
- 239000000919 ceramic Substances 0.000 claims description 10
- 239000004408 titanium dioxide Substances 0.000 claims description 10
- 239000004964 aerogel Substances 0.000 claims description 8
- 239000010949 copper Substances 0.000 claims description 8
- 229910052802 copper Inorganic materials 0.000 claims description 8
- 238000001035 drying Methods 0.000 claims description 7
- 239000002245 particle Substances 0.000 claims description 7
- 239000004816 latex Substances 0.000 claims description 6
- 229920000126 latex Polymers 0.000 claims description 6
- 238000002791 soaking Methods 0.000 claims description 6
- 238000005507 spraying Methods 0.000 claims description 6
- 238000002156 mixing Methods 0.000 claims description 4
- 238000000034 method Methods 0.000 claims 2
- 238000003860 storage Methods 0.000 abstract description 2
- 244000082204 Phyllostachys viridis Species 0.000 abstract 1
- 238000009413 insulation Methods 0.000 description 4
- 239000002086 nanomaterial Substances 0.000 description 4
- 241000894006 Bacteria Species 0.000 description 3
- 239000011248 coating agent Substances 0.000 description 3
- 238000000576 coating method Methods 0.000 description 3
- 238000009941 weaving Methods 0.000 description 3
- 239000004744 fabric Substances 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 239000002120 nanofilm Substances 0.000 description 2
- 239000002994 raw material Substances 0.000 description 2
- 239000004753 textile Substances 0.000 description 2
- 241000238876 Acari Species 0.000 description 1
- 244000025254 Cannabis sativa Species 0.000 description 1
- 235000012766 Cannabis sativa ssp. sativa var. sativa Nutrition 0.000 description 1
- 235000012765 Cannabis sativa ssp. sativa var. spontanea Nutrition 0.000 description 1
- 230000000172 allergic effect Effects 0.000 description 1
- 208000010668 atopic eczema Diseases 0.000 description 1
- 238000009395 breeding Methods 0.000 description 1
- 230000001488 breeding effect Effects 0.000 description 1
- 235000009120 camo Nutrition 0.000 description 1
- 235000005607 chanvre indien Nutrition 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 230000005611 electricity Effects 0.000 description 1
- 238000005338 heat storage Methods 0.000 description 1
- 239000011487 hemp Substances 0.000 description 1
- 238000009940 knitting Methods 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 230000008092 positive effect Effects 0.000 description 1
- 102000004169 proteins and genes Human genes 0.000 description 1
- 108090000623 proteins and genes Proteins 0.000 description 1
- 238000011084 recovery Methods 0.000 description 1
- 230000003068 static effect Effects 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 210000004243 sweat Anatomy 0.000 description 1
- 230000002195 synergetic effect Effects 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
Images
Classifications
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- D—TEXTILES; PAPER
- D02—YARNS; MECHANICAL FINISHING OF YARNS OR ROPES; WARPING OR BEAMING
- D02G—CRIMPING OR CURLING FIBRES, FILAMENTS, THREADS, OR YARNS; YARNS OR THREADS
- D02G3/00—Yarns or threads, e.g. fancy yarns; Processes or apparatus for the production thereof, not otherwise provided for
- D02G3/02—Yarns or threads characterised by the material or by the materials from which they are made
- D02G3/04—Blended or other yarns or threads containing components made from different materials
-
- D—TEXTILES; PAPER
- D02—YARNS; MECHANICAL FINISHING OF YARNS OR ROPES; WARPING OR BEAMING
- D02G—CRIMPING OR CURLING FIBRES, FILAMENTS, THREADS, OR YARNS; YARNS OR THREADS
- D02G3/00—Yarns or threads, e.g. fancy yarns; Processes or apparatus for the production thereof, not otherwise provided for
- D02G3/02—Yarns or threads characterised by the material or by the materials from which they are made
- D02G3/12—Threads containing metallic filaments or strips
-
- D—TEXTILES; PAPER
- D02—YARNS; MECHANICAL FINISHING OF YARNS OR ROPES; WARPING OR BEAMING
- D02G—CRIMPING OR CURLING FIBRES, FILAMENTS, THREADS, OR YARNS; YARNS OR THREADS
- D02G3/00—Yarns or threads, e.g. fancy yarns; Processes or apparatus for the production thereof, not otherwise provided for
- D02G3/22—Yarns or threads characterised by constructional features, e.g. blending, filament/fibre
- D02G3/38—Threads in which fibres, filaments, or yarns are wound with other yarns or filaments, e.g. wrap yarns, i.e. strands of filaments or staple fibres are wrapped by a helically wound binder yarn
-
- D—TEXTILES; PAPER
- D10—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B2201/00—Cellulose-based fibres, e.g. vegetable fibres
- D10B2201/01—Natural vegetable fibres
- D10B2201/02—Cotton
-
- D—TEXTILES; PAPER
- D10—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B2201/00—Cellulose-based fibres, e.g. vegetable fibres
- D10B2201/20—Cellulose-derived artificial fibres
-
- D—TEXTILES; PAPER
- D10—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B2211/00—Protein-based fibres, e.g. animal fibres
- D10B2211/01—Natural animal fibres, e.g. keratin fibres
-
- D—TEXTILES; PAPER
- D10—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B2211/00—Protein-based fibres, e.g. animal fibres
- D10B2211/01—Natural animal fibres, e.g. keratin fibres
- D10B2211/02—Wool
-
- D—TEXTILES; PAPER
- D10—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B2211/00—Protein-based fibres, e.g. animal fibres
- D10B2211/01—Natural animal fibres, e.g. keratin fibres
- D10B2211/04—Silk
Landscapes
- Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- Textile Engineering (AREA)
- Yarns And Mechanical Finishing Of Yarns Or Ropes (AREA)
Abstract
The invention discloses a composite yarn which comprises a yarn body, wherein the yarn body comprises a first heat-insulating layer, a second heat-insulating layer and a third heat-insulating layer, the first heat-insulating layer comprises modal, wool, rabbit hair, duck down, goose down and space cotton, the second heat-insulating layer comprises a coral down layer, a polar fleece layer, a bamboo charcoal fiber layer and a cotton fiber layer, the second heat-insulating layer is connected with the third heat-insulating layer through a copper wire, and the third heat-insulating layer comprises a silk fiber layer. The invention has good heat preservation and storage performance and can resist severe cold.
Description
Technical Field
The invention relates to the technical field of yarns, in particular to a composite yarn and a preparation method thereof.
Background
With the development of economy, the living conditions are greatly improved, and people often use cotton, hemp, silk and other natural raw materials to weave clothes in the past, so that the structure is single, and the heat retention is poor; at present, people weave various raw materials into yarn for clothing, the yarn is a textile, various textile fibers are processed into products with certain fineness, the products are used for weaving, rope making, thread making, knitting, embroidery and the like, and the products are divided into staple fiber yarn, continuous filament yarn and the like, and are generally used for weaving woolen sweaters, woolen pants, woolen vests, scarves, caps and gloves and weaving various articles for clothing in spring and autumn.
For example, the invention patent of china patent No. 200910099350.7 discloses a nano yarn and a preparation system and a preparation method thereof, which comprises a yarn, wherein a layer of nano film is arranged on the surface of the yarn, the yarn in a yarn roll enters a nano material coating pressurizing bin through a bin-entering negative pressure recovery bin, the nano material with pressure is diffused in the nano material coating pressurizing bin, when the yarn passes through the nano material coating pressurizing bin, the surface of the yarn is coated with a layer of nano film, and the yarn is dried and wound through a drying channel to obtain the nano yarn, and the nano yarn is wound into a nano yarn roll.
Although the strength and toughness of the yarn are improved, the yarn is not sticky to water and sweat, but the yarn has poor heat preservation and storage performance and cannot resist severe cold.
Disclosure of Invention
The invention aims to provide the yarn which has good heat preservation and heat storage performance and can resist severe cold.
In order to solve the technical problems, the technical scheme adopted by the invention is as follows: the composite yarn comprises a yarn body, wherein the yarn body comprises a first heat-insulating layer, a second heat-insulating layer and a third heat-insulating layer, the first heat-insulating layer comprises modal, wool, rabbit hair, duck down, goose down and space cotton, the second heat-insulating layer comprises a coral down layer, a polar fleece layer, a bamboo charcoal fiber layer and a cotton fiber layer, the second heat-insulating layer is connected with the third heat-insulating layer through copper wires, and the third heat-insulating layer comprises a silk fiber layer.
As a further scheme of the invention, the proportion of modal, wool, rabbit hair, duck down, goose down and space cotton is (12-18): (14-20): (18-24): (14-18): (17-20): (10-15).
As a further aspect of the invention, the ratio of modal, wool, rabbit hair, duck down, goose down, and space cotton is 15:17: 20: 17: 19:12.
As a further scheme of the invention, the coral fleece layer, the polar fleece layer, the bamboo charcoal fiber layer and the cotton fiber layer are respectively wound on the first heat preservation layer in the clockwise direction.
According to a further scheme of the bamboo charcoal fiber layer, the bamboo charcoal fiber layer contains titanium dioxide nanoparticles, and the cotton fiber layer contains ceramic nanoparticles.
As a further scheme of the invention, the particle size of the titanium dioxide nanoparticles is 40-60 nm, and the particle size of the ceramic nanoparticles is 20-50 nm.
According to a further scheme of the silk fabric, aerogel nanoparticles are contained in the silk fiber layer, and latex is arranged on the outer surface of the silk fiber layer.
As a further scheme of the invention, the particle size of the aerogel nanoparticles is 20-50 nm.
A preparation method of composite yarn comprises the following specific steps:
the first step is as follows: the first heat preservation layer is formed by mixing modal, wool, rabbit hair, duck down, goose down and space cotton in proportion into a long roll shape;
the second step is that: adding nanoparticles once, and respectively injecting titanium dioxide nanoparticles and ceramic nanoparticles into the bamboo charcoal fiber layer and the cotton fiber layer;
the third step: winding a first heat preservation layer, and winding the coral fleece layer, the polar fleece layer, the bamboo charcoal fiber layer and the cotton fiber layer on the first heat preservation layer respectively in a clockwise direction;
fourthly, winding copper wires, namely winding the copper wires at the adjacent spaces of the coral fleece layer, the polar fleece layer, the bamboo charcoal fiber layer and the cotton fiber layer;
the fifth step: adding nanoparticles for the second time, soaking, spraying and drying in the air, injecting aerogel nanoparticles into the silk fiber layer, and soaking, spraying and drying the silk fiber layer by using a latex sprayer;
and a sixth step: wrapping the second heat-insulating layer, and wrapping the dried silk fiber layer with the second heat-insulating layer to obtain the yarn body.
According to a further scheme of the invention, the diameter of the first heat-preservation layer is 0.5-1 mm, and the diameter of the yarn body is 2-3 mm.
The invention has the advantages and positive effects that: due to the adoption of the technical scheme, the heat-insulation cloth can effectively keep warm through the combined action of the first heat-insulation layer, the second heat-insulation layer and the third heat-insulation layer, is light in texture and low in heat conductivity, and can meet the requirement of resisting severe cold through clothes woven by the yarn body.
Drawings
FIG. 1 is a cross-sectional view of a composite yarn of the present invention.
FIG. 2 is a schematic structural view of the second insulating layer.
FIG. 3 is a flow chart of a method of making a composite yarn of the present invention.
In the figure: 1 is the yarn body, 2 is first heat preservation, 3 is the second heat preservation, 4 is the third heat preservation, 5 is the coral fine hair layer, 6 is the shake grain fine hair layer, 7 is the bamboo charcoal fiber layer, 8 is the cotton fiber layer, and 9 is the copper wire.
Detailed Description
The present invention will be described in further detail with reference to the accompanying drawings and specific embodiments.
As shown in fig. 1 to 3, the composite yarn provided by the invention comprises a yarn body 1, wherein the yarn body 1 comprises a first heat-insulating layer 2, a second heat-insulating layer 3 and a third heat-insulating layer 4, the first heat-insulating layer 2 comprises modal, wool, rabbit hair, duck down, goose down and space cotton, the second heat-insulating layer 3 comprises a coral down layer 5, a polar fleece layer 6, a bamboo charcoal fiber layer 7 and a cotton fiber layer 8, the second heat-insulating layer 3 is connected with the third heat-insulating layer 4 through a copper wire 9, and the third heat-insulating layer 4 comprises a silk fiber layer.
The invention provides a preparation method of composite yarn, which comprises the following steps:
the first step is as follows: the first heat preservation layer 2 is formed by mixing, by mass, 15:17: 20: 17: 19:12, mixing the modal, the wool, the rabbit hair, the duck down, the goose down and the space cotton to prepare a first heat preservation layer 2 in a long roll shape;
the second step is that: adding nanoparticles once, and respectively injecting titanium dioxide nanoparticles of 40-60 nm and ceramic nanoparticles of 20-50 nm into the bamboo charcoal fiber layer 7 and the cotton fiber layer 8;
the third step: winding a first heat preservation layer 2, and winding a coral fleece layer 5, a polar fleece layer 6, a bamboo charcoal fiber layer 7 and a cotton fiber layer 8 on the first heat preservation layer 2 in a clockwise direction respectively;
fourthly, winding copper wires 9, namely winding the copper wires 9 at the adjacent spaces of the coral fleece layer 5, the polar fleece layer 6, the bamboo charcoal fiber layer 7 and the cotton fiber layer 8;
the fifth step: adding nanoparticles for the second time, soaking, spraying and drying, injecting aerogel nanoparticles with the particle size of 20-50 nm into the silk fiber layer, and soaking, spraying and drying the silk fiber layer through a latex sprayer;
and a sixth step: wrapping the second heat-insulating layer 3, and wrapping the dried silk fiber layer with the second heat-insulating layer 3 to obtain the yarn body 1.
As shown in figure 2, the diameter of the first heat-preservation layer 2 is 0.5-1 mm, and the diameter of the yarn body 1 is 2-3 mm. The mixture of modal, wool, rabbit hair, duck down, goose down and space cotton in the first heat-preservation layer 2 has heat preservation performance, and can prevent heat from diffusing; the titanium dioxide nanoparticle material can reflect heat emitted by a human body, the ceramic nanoparticle material has a heat preservation effect, and heat can be better preserved through the synergistic effect of the titanium dioxide nanoparticles with holes and the ceramic nanoparticles, so that heat overflow is prevented; the copper wire 9 can prevent substances such as titanium dioxide nanoparticles, ceramic nanoparticles, silk and the like from generating static electricity, so that electric shock of a human body is avoided; the bamboo charcoal fiber layer 7 can inhibit bacteria and resist bacteria, so that bacteria are prevented from breeding; the aerogel has the functions of lightness and low heat conductivity, can effectively prevent heat conduction, and the oak protein in the latex cross can inhibit the growth and reproduction of mites, thereby effectively reducing the allergic probability of people.
Although specific embodiments of the present invention have been described above, it will be appreciated by those skilled in the art that these are merely examples and that many variations or modifications may be made to the embodiments without departing from the principles and spirit of the invention, the scope of which is defined in the appended claims.
Claims (10)
1. A composite yarn, comprising a yarn body (1), characterized in that: the yarn body (1) comprises a first heat preservation layer (2), a second heat preservation layer (3) and a third heat preservation layer (4), the first heat preservation layer (2) comprises modal, wool, rabbit hair, duck down, goose down and space cotton, the second heat preservation layer (3) comprises a coral down layer (5), a polar fleece layer (6), a bamboo charcoal fiber layer (7) and a cotton fiber layer (8), the second heat preservation layer (3) is connected with the third heat preservation layer (4) through copper wires (9), and the third heat preservation layer (4) comprises a silk fiber layer.
2. A composite yarn according to claim 1, wherein: the proportion of the modal, the wool, the rabbit hair, the duck down, the goose down and the space cotton is (12-18): (14-20): (18-24): (14-18): (17-20): (10-15).
3. A composite yarn according to claim 2, wherein: the proportion of modal, wool, rabbit hair, duck down, goose down and space cotton is 15:17: 20: 17: 19:12.
4. A composite yarn according to claim 1, wherein: the coral fleece layer (5), the polar fleece layer (6), the bamboo charcoal fiber layer (7) and the cotton fiber layer (8) are respectively wound on the first heat preservation layer (2) in the clockwise direction.
5. A composite yarn according to claim 1, wherein: the bamboo charcoal fiber layer (7) contains titanium dioxide nanoparticles, and the cotton fiber layer (8) contains ceramic nanoparticles.
6. A composite yarn according to claim 5, wherein: the particle size of the titanium dioxide nanoparticles is 40-60 nm, and the particle size of the ceramic nanoparticles is 20-50 nm.
7. A composite yarn according to claim 1, wherein: the silk fiber layer contains aerogel nano particles, and the outer surface of the silk fiber layer is provided with latex.
8. A composite yarn according to claim 7, wherein: the particle size of the aerogel nanoparticles is 20-50 nm.
9. A preparation method of composite yarn is characterized by comprising the following steps: the method comprises the following specific steps:
the first step is as follows: the first heat-preservation layer (2) is prepared by mixing modal, wool, rabbit hair, duck down, goose down and space cotton in proportion into a long-roll shape;
the second step is that: nano particles are added at one time, and titanium dioxide nano particles and ceramic nano particles are respectively injected into the bamboo charcoal fiber layer (7) and the cotton fiber layer (8);
the third step: winding a first heat preservation layer (2), and respectively winding a coral fleece layer (5), a polar fleece layer (6), a bamboo charcoal fiber layer (7) and a cotton fiber layer (8) on the first heat preservation layer (2) in a clockwise direction;
fourthly, winding copper wires (9), namely winding the copper wires (9) at the adjacent spaces of the coral fleece layer (5), the polar fleece layer (6), the bamboo charcoal fiber layer (7) and the cotton fiber layer (8);
the fifth step: adding nanoparticles for the second time, soaking, spraying and drying in the air, injecting aerogel nanoparticles into the silk fiber layer, and soaking, spraying and drying the silk fiber layer by using a latex sprayer;
and a sixth step: wrapping the second heat-insulating layer (3), and wrapping the dried silk fiber layer with the second heat-insulating layer (3) to obtain the yarn body (1).
10. The method of claim 9, wherein the step of preparing the composite yarn comprises: the diameter of the first heat preservation layer (2) is 0.5-1 mm, and the diameter of the yarn body (1) is 2-3 mm.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN202011230852.1A CN112359453B (en) | 2020-11-06 | 2020-11-06 | Composite yarn and preparation method thereof |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN202011230852.1A CN112359453B (en) | 2020-11-06 | 2020-11-06 | Composite yarn and preparation method thereof |
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| Publication Number | Publication Date |
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| CN112359453A true CN112359453A (en) | 2021-02-12 |
| CN112359453B CN112359453B (en) | 2024-01-30 |
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Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN113668111A (en) * | 2021-09-13 | 2021-11-19 | 四川润厚特种纤维有限公司 | Composite yarn and preparation method thereof |
| CN115506157A (en) * | 2022-10-19 | 2022-12-23 | 卡尔美体育用品有限公司 | Antibacterial warm-keeping down jacket fabric and preparation method thereof |
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| CN211227516U (en) * | 2019-12-17 | 2020-08-11 | 苏州晶丝奇新材料科技有限公司 | Light-absorbing heat-accumulating thermal-insulation antibacterial composite fiber |
| CN211730522U (en) * | 2019-12-26 | 2020-10-23 | 绍兴山淼贸易有限公司 | Polar fleece composite fabric |
| CN111645378A (en) * | 2020-07-09 | 2020-09-11 | 江西服装学院 | Breathable and easy-to-clean down jacket shell fabric and production process thereof |
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| CN113668111A (en) * | 2021-09-13 | 2021-11-19 | 四川润厚特种纤维有限公司 | Composite yarn and preparation method thereof |
| CN115506157A (en) * | 2022-10-19 | 2022-12-23 | 卡尔美体育用品有限公司 | Antibacterial warm-keeping down jacket fabric and preparation method thereof |
| CN115506157B (en) * | 2022-10-19 | 2024-02-13 | 卡尔美体育用品有限公司 | Antibacterial warm down jacket fabric and preparation method thereof |
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Effective date of registration: 20240104 Address after: No.68 Yangqu Road, Dongjia Village, Nanniu Township, Zhengding County, Shijiazhuang City, Hebei Province, 050899 Applicant after: Hebei Yirong Textile Co.,Ltd. Address before: 224500 second floor to sixth floor (North Building), No.100 Renmin Road, Binhai County, Yancheng City, Jiangsu Province Applicant before: Binhai Jinheng Textile Co.,Ltd. |
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