CN115110319A - Milk-flavored polyvinyl chloride artificial leather and preparation method thereof - Google Patents
Milk-flavored polyvinyl chloride artificial leather and preparation method thereof Download PDFInfo
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- CN115110319A CN115110319A CN202210677051.2A CN202210677051A CN115110319A CN 115110319 A CN115110319 A CN 115110319A CN 202210677051 A CN202210677051 A CN 202210677051A CN 115110319 A CN115110319 A CN 115110319A
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
- D06N3/00—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
- D06N3/04—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof with macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- D06N3/06—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof with macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds with polyvinylchloride or its copolymerisation products
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
- D06N3/00—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
- D06N3/0043—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof characterised by their foraminous structure; Characteristics of the foamed layer or of cellular layers
- D06N3/0047—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof characterised by their foraminous structure; Characteristics of the foamed layer or of cellular layers obtained by incorporating air, i.e. froth
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
- D06N3/00—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
- D06N3/0056—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof characterised by the compounding ingredients of the macro-molecular coating
- D06N3/0059—Organic ingredients with special effects, e.g. oil- or water-repellent, antimicrobial, flame-resistant, magnetic, bactericidal, odour-influencing agents; perfumes
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
- D06N3/00—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
- D06N3/0056—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof characterised by the compounding ingredients of the macro-molecular coating
- D06N3/0061—Organic fillers or organic fibrous fillers, e.g. ground leather waste, wood bark, cork powder, vegetable flour; Other organic compounding ingredients; Post-treatment with organic compounds
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- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
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- D06N3/00—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
- D06N3/0056—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof characterised by the compounding ingredients of the macro-molecular coating
- D06N3/0063—Inorganic compounding ingredients, e.g. metals, carbon fibres, Na2CO3, metal layers; Post-treatment with inorganic compounds
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- D06N3/00—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
- D06N3/007—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof characterised by mechanical or physical treatments
- D06N3/0077—Embossing; Pressing of the surface; Tumbling and crumbling; Cracking; Cooling; Heating, e.g. mirror finish
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- D06N2209/00—Properties of the materials
- D06N2209/16—Properties of the materials having other properties
- D06N2209/165—Odour absorbing, deodorizing ability
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- D06N2211/00—Specially adapted uses
- D06N2211/12—Decorative or sun protection articles
- D06N2211/28—Artificial leather
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- D06N2213/00—Others characteristics
- D06N2213/02—All layers being of the same kind of material, e.g. all layers being of polyolefins, all layers being of polyesters
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Abstract
The invention relates to milk-flavor polyvinyl chloride artificial leather and a preparation method thereof, belonging to the technical field of polyvinyl chloride artificial leather. Coating a pasty adhesive on the pasting surface of a base fabric to form a pasting fabric on a pasting machine, sequentially adhering a surface layer and a foaming layer above the pasting fabric, entering a surface coating treatment station for coating and scraping according to the requirements of customers on the wear resistance and hand feeling of the surface, cooling, rolling into a roll, after foaming in an oven, cooling and shaping, sending to the oven, drying to remove small-molecule volatile substances, and cutting into small rolls for storage and transportation after the inspection is qualified. The polyvinyl chloride artificial leather material produced by the method has the advantages that the formula of the material is improved, the material emits milk fragrance from inside to outside, the plastic taste and burnt taste are greatly improved, no adverse effect is caused on the performances of the upper layer material such as durability, color and the like, the pleasure degree of the polyvinyl chloride interior decoration can be improved, and the polyvinyl chloride artificial leather material is accepted by consumers.
Description
Technical Field
The invention belongs to the technical field of polyvinyl chloride artificial leather, and particularly relates to milk-flavor polyvinyl chloride artificial leather and a preparation method thereof.
Background
With the development of society, people's life is becoming more and more compact with the passenger vehicle, and the higher requirement of user to vehicle interior has not been satisfied to simple plastics interior trim product, and soft interior trim surface more obtains user's favor. Generally, such soft interior surface materials are mostly made of polyvinyl chloride (PVC) artificial leather. Influenced by the physical properties and processing method of the materials, the current mainstream polyvinyl chloride artificial leather has obvious plastic taste and burnt taste, especially when the temperature in summer is higher, the smell intensity is higher, and the materials can make users feel uncomfortable obviously in the using process. The Chinese automobile users have great complaints about the smell in the automobile, and the feedback of the smell in the automobile is the most in the annual survey evaluation. In order to satisfy consumer demand, it is very necessary to improve the plastic odor and burnt odor of polyvinyl chloride materials for interior decoration of vehicles.
Therefore, the patent of the preparation method of the milk-flavor polyvinyl chloride artificial leather is developed, aiming at solving the odor problem of the polyvinyl chloride artificial leather.
Disclosure of Invention
The invention provides a milk-flavor polyvinyl chloride artificial leather and a preparation method thereof, and aims to solve the problems that the existing artificial leather interior decoration made of a polyvinyl chloride material has plastic flavor and burnt flavor which are easily uncomfortable, and especially the odor intensity is higher when the temperature is higher in summer, so that consumers complain about the odor.
The technical scheme adopted by the invention is as follows: sequentially adhering a surface layer and a foaming layer above the pasting cloth, wherein:
the surface layer is prepared from the following raw materials in parts by weight:
90-110 parts of polyvinyl chloride resin powder with the polymerization degree of 1800-;
60-85 parts of nonyl undecyl phthalate;
15-25 parts of polyester polymer plasticizer;
1.0-2.5 parts of barium stearate or zinc stearate;
5-20 parts of calcium carbonate;
2.0-2.4 parts of epoxidized soybean oil;
2.0-10 parts of a pigment;
the foaming layer is prepared from the following raw materials in parts by weight:
polyvinyl chloride resin powder with polymerization degree of 1250 +/-50 of 90-110 parts;
60-85 parts of nonyl undecyl phthalate;
15-25 parts of polyester polymer plasticizer;
0.5-2.0 parts of azodicarbonamide;
8-15 parts of antimony trioxide;
5-20 parts of calcium carbonate;
0.1-0.5 part of calcium stearate or zinc stearate;
0.2-0.5 parts of barium stearate;
0.1-0.4 parts of milk flavor modifier;
1.0-5 parts of a coloring material.
The milk flavor modifier provided by the invention adopts OBS 1200.
The surface of the surface layer is coated with a water-based treatment layer.
A preparation method of milk-flavor polyvinyl chloride artificial leather comprises the following steps:
(one) pasting
Coating the pasty adhesive on the pasting surface of the base cloth in a pasting machine, drying in a 15-meter-long drying oven at 160 ℃, and rolling into a roll to form the pasting cloth;
(II) bonding
(1) When the foaming layer is prepared, putting polyvinyl chloride resin powder, stearic acid substances, calcium carbonate and a milk flavor modifier into a mixing barrel according to a formula proportion, stirring at a low speed of 160-200 r/min, after the powder is put, continuously stirring at a high speed of 1300-1500 r/min for 60s, putting nonyl undecyl phthalate and a polyester polymer plasticizer into the mixing barrel, stirring to 125 ℃, discharging, simultaneously adding the rest raw materials and a pigment, and mixing in a mixer; and (2) mixing the materials by an internal mixer until the materials are plasticized, wherein the temperature reaches 165 +/-3 ℃, conveying the materials to an open mill for heat preservation and continuous plasticization, the temperature of the open mill is 160 ℃, and the temperature of a four-roll calender is as follows: adjusting the thickness of the foaming layer to be 0.15-0.30 mm at the upper front temperature of 170 ℃ and the lower middle temperature of 164 ℃;
(2) when the surface layer is prepared, putting polyvinyl chloride resin powder, stearic acid substances, calcium carbonate and epoxidized soybean oil into a mixing barrel according to a formula proportion, stirring at a low speed of 160-200 r/min, after the powder is put in, continuously stirring at a high speed of 1300-1500 r/min for 60s, putting nonyl undecyl phthalate and polyester polymer plasticizer into the mixing barrel, stirring to 125 ℃, discharging, simultaneously adding pigments, and mixing together in a sealing machine; and (2) mixing the materials by an internal mixer until the materials are plasticized, wherein the temperature reaches 165 +/-3 ℃, conveying the materials to an open mill for heat preservation and continuous plasticization, wherein the temperature of the open mill is 165 ℃, and the temperature of a four-roll calender is: adjusting the thickness of the surface layer to be 0.20-0.30 mm at the front upper part of 175 ℃ and the middle lower part of 168 ℃;
(3) the pasted cloth is delivered to a guide wheel of a calender in a unreeling way, the surface layer and the foaming layer with the adjusted thickness are attached to the pasted cloth, and are pressed by a plain weave embossing wheel, cooled and shaped, and then coiled into a roll to be sent to the next section for production;
(III) coating and scraping
Selecting a water-based treating agent according to the requirements of customers on the wear resistance and hand feeling of the surface, and using a 120-180-mesh treating wheel, wherein the water-based treating agent is divided into a primary coating and a surface coating, the primary coating treating agent is dried by using a 6-meter drying oven at 110 ℃ after being coated and scraped, enters a surface coating treatment station for coating and scraping, is conveyed to a 20-meter drying oven for drying and bridging, is firmly connected with a polyvinyl chloride material, and is then cooled by a cooling wheel and is rolled into a package;
(IV) foaming and baking smell
Dividing a 25-meter-long oven into 5 regions, setting the temperature to be 220 ℃, 225 ℃, 215 ℃ and 180 ℃, setting the allowable range to be +/-5 ℃, after foaming in the oven, heating to 160 ℃ by medium wave infrared, manufacturing required textures by using an embossing wheel, cooling and shaping, sending to a 20-meter oven, drying small-molecule volatile substances at 95-110 ℃, sampling and inspecting during coiling, and cutting into small coils for storage and transportation after physical properties tested by a person to be tested are qualified.
In the step (III) of the present invention, the primer uses Starter WF-71486.
In the step (III), BF-8039 of Boschoff is used for surface coating.
The invention has the advantages that the formula of the material is improved, the polyvinyl chloride artificial leather material produced by the method emits milk fragrance from inside to outside, the plastic taste and burnt taste are greatly improved, the milk fragrance modifier does not generate chemical reaction with polyvinyl chloride resin, the tiny addition amount of the milk fragrance modifier does not change various properties of the original foaming layer material, no adverse effect is generated on the properties of the upper layer material such as durability, color and the like, and the pleasure of the interior decoration of polyvinyl chloride can be improved, so that the polyvinyl chloride artificial leather material is accepted by consumer groups.
Drawings
Fig. 1 is a schematic structural view of the present invention.
Detailed Description
Example 1
The surface layer 2 and the foaming layer 3 are sequentially stuck above the paste cloth 4, wherein:
the surface layer is prepared from the following raw materials in parts by weight:
polyvinyl chloride resin powder with the polymerization degree of 1800 in 90 parts;
60 parts of nonyl undecyl phthalate;
15 parts of polyester polymer plasticizer;
1.0 part of zinc stearate;
5 parts of calcium carbonate;
2.0 parts of epoxidized soybean oil;
2.0 parts of pigment;
the foaming layer is prepared from the following raw materials in parts by weight:
polyvinyl chloride resin powder with the polymerization degree of 1200 and 90 parts;
60 parts of nonyl undecyl phthalate;
15 parts of polyester polymer plasticizer;
0.5 part of azodicarbonamide;
8 parts of antimony trioxide;
5 parts of calcium carbonate;
0.1 part of zinc stearate;
0.2-0.5 parts of barium stearate;
0.1 part of milk flavor modifier OBS 1200;
1.0 part of pigment;
coating a water-based treatment layer 1 on the surface of the surface layer;
the preparation method of the milk-flavor polyvinyl chloride artificial leather comprises the following steps:
(one) pasting
Coating the pasty adhesive on the pasting surface of the base cloth in a pasting machine, drying in a 15-meter-long drying oven at 160 ℃, and rolling into a roll to form the pasting cloth;
(II) bonding
(1) When preparing the foaming layer, putting polyvinyl chloride resin powder, stearic acid substances, calcium carbonate and a milk flavor modifier into a mixing barrel according to a formula proportion, stirring at a low speed of 160r/min, after the powder is put, continuously stirring at a high speed of 1300r/min for 60s, putting nonyl undecyl phthalate and a polyester polymer plasticizer into the mixing barrel, stirring to 125 ℃, discharging, simultaneously adding the rest raw materials and a pigment, and mixing in a mixer; and (3) mixing the materials by an internal mixer until the materials are plasticized, keeping the temperature of the materials at 162 ℃, conveying the materials to an open mill for heat preservation and continuously plasticizing, wherein the temperature of the open mill is 160 ℃, and the temperature of a four-roll calender is as follows: adjusting the thickness of the foaming layer to be 0.15mm at the front upper temperature of 170 ℃ and the middle lower temperature of 164 ℃;
(2) when the surface layer is prepared, putting polyvinyl chloride resin powder, stearic acid substances, calcium carbonate and epoxidized soybean oil into a mixing barrel according to a formula proportion, stirring at a low speed of 160r/min, after the powder is put in, continuously stirring at a high speed of 1300r/min for 60s, putting nonylundecyl phthalate and polyester high-molecular plasticizer into the mixing barrel, stirring to 125 ℃, discharging, simultaneously adding pigments, and mixing together in a sealing machine; and (3) mixing the materials by an internal mixer until the materials are plasticized, keeping the temperature of the materials at 162 ℃, conveying the materials to an open mill for heat preservation and continuously plasticizing, wherein the temperature of the open mill is 165 ℃, and the temperature of a four-roll calender is: the front upper part is 175 ℃, the middle lower part is 168 ℃, and the thickness of the surface layer is adjusted to be 0.20 mm;
(3) the pasted cloth is delivered to a guide wheel of a calender in a unreeling way, the surface layer and the foaming layer with the adjusted thickness are attached to the pasted cloth, and are pressed by a plain weave embossing wheel, cooled and shaped, and then coiled into a roll to be sent to the next section for production;
(III) coating and scraping
Selecting a water-based treating agent according to the requirements of a client on the wear resistance and the hand feeling of the surface, and utilizing a 120-mesh treating wheel, wherein the water-based treating agent is divided into a base coat and a top coat, the base coat uses WF-71486 of Stahl, the top coat uses BF-8039 of Bossv, the base coat treating agent is dried by a 6-meter drying oven at 110 ℃ after being scraped, enters a top coat treating station for coating and scraping, is conveyed to a 20-meter drying oven for drying and bridging, is firmly connected with a polyvinyl chloride material, is cooled by a cooling wheel and is rolled into a package;
(IV) foaming and baking smell
The method comprises the steps of dividing a 25-meter-long oven into 5 regions, setting the temperature to be 220 ℃, 225 ℃, 215 ℃ and 180 ℃, setting the allowable range to be +/-5 ℃, setting the higher temperature to be favorable for decomposing gas from azodicarbonamide in a foaming layer, forming foam pores in the material, heating the material to 160 ℃ by medium wave infrared after foaming in the oven, manufacturing required textures by using an embossing wheel, cooling and shaping the material, sending the material to a 20-meter oven, drying small-molecule volatile substances at 95-110 ℃, sampling and inspecting the material during coiling, and cutting the material into small coils for storage and transportation after testing physical properties of an inspector.
Example 2
Sequentially adhering a surface layer and a foaming layer above the pasting cloth, wherein:
the surface layer is prepared from the following raw materials in parts by weight:
polyvinyl chloride resin powder with polymerization degree of 2000, 100 parts;
nonyl undecyl phthalate, 75 parts;
20 parts of polyester polymer plasticizer;
1.8 parts of barium stearate;
12 parts of calcium carbonate;
2.2 parts of epoxidized soybean oil;
6 parts of pigment;
the foaming layer is prepared from the following raw materials in parts by weight:
polyvinyl chloride resin powder, polymerization degree 1250, 100 portions;
75 parts of nonyl undecyl phthalate;
20 parts of polyester polymer plasticizer;
1.2 parts of azodicarbonamide;
12 parts of antimony trioxide;
12 parts of calcium carbonate;
0.3 part of calcium stearate;
0.3 part of barium stearate;
0.3 part of milk flavor modifier OBS 1200;
3.0 parts of pigment.
Coating a water-based treatment layer on the surface of the surface layer;
the preparation method of the milk-flavor polyvinyl chloride artificial leather comprises the following steps:
first, pasting
Coating the pasty adhesive on the pasting surface of the base cloth in a pasting machine, drying in a 15-meter-long drying oven at 160 ℃, and rolling into a roll to form the pasting cloth;
(II) bonding
(1) When preparing the foaming layer, putting the polyvinyl chloride resin powder, the stearic acid substances, the calcium carbonate and the milk flavor modifier into a mixing barrel according to the formula proportion, stirring at a low speed of 200r/min, after the powder is put in, continuously stirring at a high speed of 1500r/min for 60s, putting the nonyl undecyl phthalate and the polyester polymer plasticizer into the mixing barrel, stirring to 125 ℃, discharging, simultaneously adding the rest raw materials and the pigment, and mixing in a mixer; and (3) mixing the materials by an internal mixer until the materials are plasticized, keeping the temperature of the materials at 165 ℃, conveying the materials to an open mill for heat preservation and continuously plasticizing, wherein the temperature of the open mill is 160 ℃, and the temperature of a four-roll calender is as follows: adjusting the thickness of the foaming layer to be 0.22mm at the front upper temperature of 170 ℃ and the middle lower temperature of 164 ℃;
(2) when the surface layer is prepared, putting polyvinyl chloride resin powder, stearic acid substances, calcium carbonate and epoxidized soybean oil into a mixing barrel according to a formula proportion, stirring at a low speed of 200r/min, after the powder is put in, continuously stirring at a high speed of 1500r/min for 60s, putting nonylundecyl phthalate and polyester high-molecular plasticizer into the mixing barrel, stirring to 125 ℃, discharging, simultaneously adding pigments, and mixing together in a sealing machine; and (2) mixing the materials by an internal mixer until the materials are plasticized, keeping the temperature of the materials at 165 ℃, conveying the materials to an open mill for heat preservation and continuously plasticizing, wherein the temperature of the open mill is 165 ℃, and the temperature of a four-roll calender is: the front upper part is 175 ℃, the middle lower part is 168 ℃, and the thickness of the surface layer is adjusted to be 0.25 mm;
(3) the pasted cloth is delivered to a guide wheel of a calender, the surface layer and the foaming layer with the adjusted thickness are pasted on the pasted cloth, and are pressed by a plain weave embossing wheel, and the pasted cloth is cooled, shaped, rolled into a roll and sent to the next section for production;
(III) coating and scraping
Selecting a water-based treating agent according to the requirements of a client on the wear resistance and hand feeling of the surface, and utilizing a 120-180-mesh treating wheel, wherein the water-based treating agent is divided into a bottom coating and a top coating, the bottom coating uses WF-71486 of Stahl, the top coating uses BF-8039 of Bosfer, the bottom coating treating agent is dried by a 6-meter drying oven at 110 ℃ after being scraped, enters a top coating treating station for coating and scraping, is conveyed to a 20-meter drying oven for drying and bridging, is firmly connected with a polyvinyl chloride material, is cooled by a cooling wheel and is rolled into a package;
(IV) foaming and baking smell
The method comprises the steps of dividing a drying oven with the length of 25 meters into 5 zones, setting the temperature to be 220 ℃, 225 ℃, 215 ℃ and 180 ℃, setting the allowable range to be +/-5 ℃, setting the higher temperature to be favorable for decomposing gas from azodicarbonamide in a foaming layer, forming foam holes in the material, heating the material to 160 ℃ through medium wave infrared after foaming in the drying oven, manufacturing required textures by using an embossing wheel, cooling and shaping the material, sending the material to a 20-meter drying oven, drying small-molecule volatile substances at 110 ℃, sampling and inspecting the material during coiling, and cutting the material into small coils for storage and transportation after testing the physical properties of a person to be tested.
Example 3
Sequentially adhering a surface layer and a foaming layer above the pasting cloth, wherein:
the surface layer is prepared from the following raw materials in parts by weight:
polyvinyl chloride resin powder with polymerization degree of 2100, 110 parts;
nonyl undecyl phthalate, 85 parts;
25 parts of polyester polymer plasticizer;
2.5 parts of barium stearate;
20 parts of calcium carbonate;
2.4 parts of epoxidized soybean oil;
10 parts of pigment;
the foaming layer is prepared from the following raw materials in parts by weight:
polyvinyl chloride resin powder with the polymerization degree of 1300, 110 parts;
85 parts of nonyl undecyl phthalate;
25 parts of polyester polymer plasticizer;
2.0 parts of azodicarbonamide;
15 parts of antimony trioxide;
20 parts of calcium carbonate;
0.5 part of calcium stearate;
0.5 part of barium stearate;
0.4 part of milk flavor modifier OBS 1200;
5 parts of a pigment;
and coating a water-based treatment layer on the surface of the surface layer.
A preparation method of milk-flavor polyvinyl chloride artificial leather comprises the following steps:
first, pasting
Coating the pasty adhesive on the pasting surface of the base cloth in a pasting machine, drying in a 15-meter-long drying oven at 160 ℃, and rolling into a roll to form the pasting cloth;
(II) bonding
(1) When preparing the foaming layer, putting the polyvinyl chloride resin powder, the stearic acid substances, the calcium carbonate and the milk flavor modifier into a mixing barrel according to the formula proportion, stirring at a low speed of 180r/min, after the powder is put in, continuously stirring at a high speed of 1400r/min for 60s, putting the nonylundecyl phthalate and the polyester polymer plasticizer into the mixing barrel, stirring to 125 ℃, discharging, simultaneously adding the rest raw materials and the pigment, and mixing in a mixer; and (3) mixing the materials by an internal mixer until the materials are plasticized, keeping the temperature of the materials at 168 ℃, conveying the materials to an open mill for heat preservation and continuously plasticizing, wherein the temperature of the open mill is 160 ℃, and the temperature of a four-roll calender is as follows: adjusting the thickness of the foaming layer to be 0.30mm at the front upper temperature of 170 ℃ and the middle lower temperature of 164 ℃;
(2) when the surface layer is prepared, putting polyvinyl chloride resin powder, stearic acid substances, calcium carbonate and epoxidized soybean oil into a mixing barrel according to a formula proportion, stirring at a low speed of 180r/min, after the powder is put, continuously stirring at a high speed of 1400r/min for 60s, putting nonyl undecyl phthalate and polyester high-molecular plasticizer into the mixing barrel, stirring to 125 ℃, discharging, simultaneously adding pigments, and mixing together in a mixer; and (3) mixing the materials by an internal mixer until the materials are plasticized, keeping the temperature of the materials at 168 ℃, conveying the materials to an open mill for heat preservation and continuously plasticizing, wherein the temperature of the open mill is 165 ℃, and the temperature of a four-roll calender is: regulating the thickness of the surface layer to be 0.30mm at the front upper part of 175 ℃ and the middle lower part of 168 ℃;
(3) the pasted cloth is delivered to a guide wheel of a calender in a unreeling way, the surface layer and the foaming layer with the adjusted thickness are attached to the pasted cloth, and are pressed by a plain weave embossing wheel, cooled and shaped, and then coiled into a roll to be sent to the next section for production;
(III) coating and scraping
Selecting a water-based treating agent according to the requirements of a client on the wear resistance and hand feeling of the surface, and utilizing a 120-180-mesh treating wheel, wherein the water-based treating agent is divided into a bottom coating and a top coating, the bottom coating uses WF-71486 of Stahl, the top coating uses BF-8039 of Bosfer, the bottom coating treating agent is dried by a 6-meter drying oven at 110 ℃ after being scraped, enters a top coating treating station for coating and scraping, is conveyed to a 20-meter drying oven for drying and bridging, is firmly connected with a polyvinyl chloride material, is cooled by a cooling wheel and is rolled into a package;
(IV) foaming and baking smell
The method comprises the steps of dividing a drying oven with the length of 25 meters into 5 zones, setting the temperature to be 220 ℃, 225 ℃, 215 ℃ and 180 ℃, setting the allowable range to be +/-5 ℃, setting the higher temperature to be favorable for decomposing gas from azodicarbonamide in a foaming layer, forming foam holes in the material, heating the material to 160 ℃ through medium wave infrared after foaming in the drying oven, manufacturing required textures by using an embossing wheel, cooling and shaping the material, sending the material to a 20-meter drying oven, drying small-molecule volatile substances at 100 ℃, sampling and inspecting the material during coiling, and cutting the material into small coils for storage and transportation after testing the physical properties of a person to be tested.
The invention is further illustrated below by means of experimental examples.
The polyvinyl chloride artificial leather production is carried out by respectively using the embodiment 2 and the conventional method of the invention to obtain two groups of polyvinyl chloride artificial leather products, and the artificial odor evaluation is used for judging the effect. The specific evaluation method comprises cutting two groups of artificial leather products into sample blocks with the thickness of 100 multiplied by the product thickness, placing the sample blocks into a 4L standard odor test bottle, placing the sample blocks into a clean oven, baking the sample blocks for 1 hour at the temperature of 100 ℃, taking the sample blocks out, placing the sample blocks in a constant temperature and humidity environment (23 +/-2 ℃, 50 +/-5% RH) for cooling, and then carrying out olfaction judgment by a professional olfactor. Under the same conditions, the polyvinyl chloride artificial leather product prepared in the method example 2 has the odor intensity of 2.4 grade, presents obvious milk fragrance, and 5 of 6 sniffers participating in judgment like the odor; the polypropylene plastic prepared without the method has the odor intensity of 2.6 grades (the lower the odor intensity grade is, the better the odor property is), the plastic odor and the burnt odor are presented, and no one of 6 smellers participating in the judgment likes the odor.
Since polyvinyl chloride is gradually decomposed at a temperature of 80 ℃ or higher, more substances which are not favorable for human body feeling, such as hydrogen chloride with sour taste, are generated. The main components of the milk flavor modifier OBS1200 are uracil, thermoplastic phenolic resin, organic activator and the like, and the reaction mechanism is as follows:
(1) the unstable chlorine atoms on the PVC chain are replaced or substituted to generate more stable ester, thereby inhibiting dehydrochlorination reaction, protecting the stability of the structure of the polyvinyl chloride material and preventing sourness;
(2) after the artificial leather is compounded with the sponge, the modifier can also generate certain combination reaction with amine substances in the sponge, so that the ammonia smell emitted by the sponge is weakened.
Prevent destroying the specific micromolecular substance similar to chloroethylene of polyvinyl chloride structure through snatching, fix it inside the foaming layer, avoid polyvinyl chloride macromolecular structure to suffer destruction, decomposition to form stable polyvinyl chloride foaming layer, and then reduce the smell material that polyvinyl chloride synthetic leather product volatilizes, improve product smell nature.
Claims (6)
1. The utility model provides a milk fragrance polyvinyl chloride synthetic leather which characterized in that glues surface course and foaming layer in proper order in the burnt cloth top, wherein:
the surface layer is prepared from the following raw materials in parts by weight:
90-110 parts of polyvinyl chloride resin powder with the polymerization degree of 1800-;
60-85 parts of nonyl undecyl phthalate;
15-25 parts of polyester polymer plasticizer;
1.0-2.5 parts of barium stearate or zinc stearate;
5-20 parts of calcium carbonate;
2.0-2.4 parts of epoxidized soybean oil;
2.0-10 parts of a pigment;
the foaming layer is prepared from the following raw materials in parts by weight:
polyvinyl chloride resin powder with polymerization degree of 1250 +/-50 of 90-110 parts;
60-85 parts of nonyl undecyl phthalate;
15-25 parts of polyester polymer plasticizer;
0.5-2.0 parts of azodicarbonamide;
8-15 parts of antimony trioxide;
5-20 parts of calcium carbonate;
0.1-0.5 part of calcium stearate or zinc stearate;
0.2-0.5 parts of barium stearate;
0.1-0.4 parts of milk flavor modifier OBS 1200;
1.0-5 parts of a coloring material.
2. The milk-flavored polyvinyl chloride artificial leather according to claim 1, wherein: the milk flavor modifier adopts OBS 1200.
3. The milk-flavored polyvinyl chloride artificial leather according to claim 1 or 2, wherein the surface of the top layer is coated with a scratch-off water-based treatment layer.
4. The method for preparing milk-flavored polyvinyl chloride artificial leather according to claim 3, comprising the steps of:
first, pasting
Coating the pasty adhesive on the pasting surface of the base cloth in a pasting machine, drying in a 15-meter-long drying oven at 160 ℃, and rolling into a roll to form the pasting cloth;
(II) bonding
(1) When the foaming layer is prepared, putting polyvinyl chloride resin powder, stearic acid substances, calcium carbonate and a milk flavor modifier into a mixing barrel according to a formula proportion, stirring at a low speed of 160-200 r/min, after the powder is put in, continuously stirring at a high speed of 1300-1500 r/min for 60s, putting nonyl undecyl phthalate and a polyester polymer plasticizer into the mixing barrel, stirring to 125 ℃, discharging, simultaneously adding the rest raw materials and a pigment, and mixing in a material mixer; and (2) mixing the materials by an internal mixer until the materials are plasticized, wherein the temperature reaches 165 +/-3 ℃, conveying the materials to an open mill for heat preservation and continuous plasticization, the temperature of the open mill is 160 ℃, and the temperature of a four-roll calender is as follows: adjusting the thickness of the foaming layer to be 0.15-0.30 mm at the upper front temperature of 170 ℃ and the lower middle temperature of 164 ℃;
(2) when the surface layer is prepared, putting polyvinyl chloride resin powder, stearic acid substances, calcium carbonate and epoxidized soybean oil into a mixing barrel according to a formula proportion, stirring at a low speed of 160-200 r/min, after the powder is put in, continuously stirring at a high speed of 1300-1500 r/min for 60s, putting nonyl undecyl phthalate and polyester polymer plasticizer into the mixing barrel, stirring to 125 ℃, discharging, simultaneously adding pigments, and mixing together in a sealing machine; and (2) mixing the materials by an internal mixer until the materials are plasticized, wherein the temperature reaches 165 +/-3 ℃, conveying the materials to an open mill for heat preservation and continuous plasticization, wherein the temperature of the open mill is 165 ℃, and the temperature of a four-roll calender is: the front upper part is 175 ℃, the middle lower part is 168 ℃, and the thickness of the surface layer is adjusted to be 0.20-0.30 mm;
(3) the pasted cloth is delivered to a guide wheel of a calender in a unreeling way, the surface layer and the foaming layer with the adjusted thickness are attached to the pasted cloth, and are pressed by a plain weave embossing wheel, cooled and shaped, and then coiled into a roll to be sent to the next section for production;
(III) coating and scraping
Selecting a water-based treating agent according to the requirements of customers on the wear resistance and hand feeling of the surface, and using a 120-180-mesh treating wheel, wherein the water-based treating agent is divided into a primary coating and a surface coating, the primary coating treating agent is dried by using a 6-meter drying oven at 110 ℃ after being coated and scraped, enters a surface coating treatment station for coating and scraping, is conveyed to a 20-meter drying oven for drying and bridging, is firmly connected with a polyvinyl chloride material, and is then cooled by a cooling wheel and is rolled into a package;
(IV) foaming and baking smell
The drying oven with the length of 25 meters is divided into 5 zones, the temperature is set to be 220 ℃, 225 ℃, 215 ℃ and 180 ℃, the allowable range is set to be +/-5 ℃, after foaming in the drying oven is finished, the temperature is heated to 160 ℃ by medium wave infrared, required textures are manufactured by using an embossing wheel, after cooling and shaping, the textures are sent to the drying oven with the length of 20 meters, small-molecule volatile substances are dried at the temperature of 95-110 ℃, samples are taken for inspection when coils are formed, and after physical properties tested by an inspector are qualified, the coils are cut into small coils so as to be convenient for storage and transportation.
5. The method for preparing milk-flavored polyvinyl chloride artificial leather according to claim 4, wherein WF-71486 of Starter is used for the undercoat in the step (III).
6. The method of preparing milk-flavored polyvinyl chloride artificial leather according to claim 4, wherein BF-8039 of bosch is used for the top coating in the step (three).
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Citations (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102417680A (en) * | 2011-11-30 | 2012-04-18 | 广东联塑科技实业有限公司 | Lead-free PVC-U (Poly Vinyl Chloride-Unplasticized) pipe for drainage and manufacturing method thereof |
| CN102898741A (en) * | 2012-10-08 | 2013-01-30 | 太原市塑料研究所 | Polyvinyl chloride heat stabilizer and preparation method thereof |
| CA2968585A1 (en) * | 2014-11-24 | 2016-06-02 | Lubrizol Advanced Materials, Inc. | Novel coupled uracil compound for vinyl chloride polymer resins |
| CN107418105A (en) * | 2017-09-20 | 2017-12-01 | 广东顺德江顺磁材有限公司 | A kind of PVC gaskets with resistance to shift function and preparation method thereof |
| CN108035160A (en) * | 2017-12-01 | 2018-05-15 | 南亚塑胶工业（南通）有限公司 | A kind of low smell PVC artificial leather and preparation method thereof |
| CN110408166A (en) * | 2019-07-31 | 2019-11-05 | 河北雄发新材料科技发展有限公司 | A kind of OBS organic stabilizer and preparation method thereof |
| CN112080948A (en) * | 2020-09-10 | 2020-12-15 | 北京汽车集团越野车有限公司 | Polyvinyl chloride artificial leather, preparation method and vehicle |
-
2022
- 2022-06-15 CN CN202210677051.2A patent/CN115110319A/en active Pending
Patent Citations (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102417680A (en) * | 2011-11-30 | 2012-04-18 | 广东联塑科技实业有限公司 | Lead-free PVC-U (Poly Vinyl Chloride-Unplasticized) pipe for drainage and manufacturing method thereof |
| CN102898741A (en) * | 2012-10-08 | 2013-01-30 | 太原市塑料研究所 | Polyvinyl chloride heat stabilizer and preparation method thereof |
| CA2968585A1 (en) * | 2014-11-24 | 2016-06-02 | Lubrizol Advanced Materials, Inc. | Novel coupled uracil compound for vinyl chloride polymer resins |
| CN107418105A (en) * | 2017-09-20 | 2017-12-01 | 广东顺德江顺磁材有限公司 | A kind of PVC gaskets with resistance to shift function and preparation method thereof |
| CN108035160A (en) * | 2017-12-01 | 2018-05-15 | 南亚塑胶工业（南通）有限公司 | A kind of low smell PVC artificial leather and preparation method thereof |
| CN110408166A (en) * | 2019-07-31 | 2019-11-05 | 河北雄发新材料科技发展有限公司 | A kind of OBS organic stabilizer and preparation method thereof |
| CN112080948A (en) * | 2020-09-10 | 2020-12-15 | 北京汽车集团越野车有限公司 | Polyvinyl chloride artificial leather, preparation method and vehicle |
Non-Patent Citations (1)
| Title |
|---|
| 黄泽雄;: "PVC加工用有机基热稳定剂", 国外塑料, no. 05, pages 75 * |
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