CN115040972A - Multidimensional normal-pressure purification equipment for carbon dioxide - Google Patents

Multidimensional normal-pressure purification equipment for carbon dioxide Download PDF

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Publication number
CN115040972A
CN115040972A CN202210437248.9A CN202210437248A CN115040972A CN 115040972 A CN115040972 A CN 115040972A CN 202210437248 A CN202210437248 A CN 202210437248A CN 115040972 A CN115040972 A CN 115040972A
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China
Prior art keywords
carbon dioxide
butterfly valve
tank
adsorption
fan
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Pending
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CN202210437248.9A
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Chinese (zh)
Inventor
师圆生
杨林鲜
易友元
余月勇
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Shandong Baolan Ep Co ltd
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Shandong Baolan Ep Co ltd
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Priority to CN202210437248.9A priority Critical patent/CN115040972A/en
Publication of CN115040972A publication Critical patent/CN115040972A/en
Pending legal-status Critical Current

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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D53/00Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/02Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2257/00Components to be removed
    • B01D2257/50Carbon oxides
    • B01D2257/504Carbon dioxide
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2259/00Type of treatment
    • B01D2259/40Further details for adsorption processes and devices
    • B01D2259/40083Regeneration of adsorbents in processes other than pressure or temperature swing adsorption
    • B01D2259/40088Regeneration of adsorbents in processes other than pressure or temperature swing adsorption by heating
    • B01D2259/4009Regeneration of adsorbents in processes other than pressure or temperature swing adsorption by heating using hot gas

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Analytical Chemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Treating Waste Gases (AREA)

Abstract

The invention discloses a multidimensional normal-pressure purification device for carbon dioxide, which comprises a draught fan, a carbon dioxide adsorption box, a first screw conveyor, a first material lifting machine, a regeneration tank, an air heater, a fresh air fan, a first butterfly valve, a second butterfly valve and a third butterfly valve. Wherein, the air outlet of draught fan with the air inlet of carbon dioxide adsorption tank is connected, the carbon dioxide adsorption tank intussuseption is filled with adsorption material, first screw conveyer install in the lower part of carbon dioxide adsorption tank, first material lifting machine install in first screw conveyer's lower part, the regeneration tank with first material lifting machine is connected, the new trend fan passes through air heater with the regeneration tank is connected, first butterfly valve, second butterfly valve and third butterfly valve respectively with the regeneration tank is connected. The invention adopts normal pressure adsorption and off-line temperature swing desorption, can effectively reduce energy consumption, improve adsorption efficiency and reduce the emission of carbon dioxide.

Description

Carbon dioxide multidimensional normal-pressure purification equipment
Technical Field
The invention relates to the technical field of carbon dioxide gas treatment, in particular to multidimensional normal-pressure purification equipment for carbon dioxide.
Background
The carbon dioxide emission in China strives to reach a peak value 2030 years ago, and strives to achieve carbon neutralization 2060 years ago. Carbon peak reaching means that the emission of carbon dioxide does not increase until 2030 years of commitment in China, and the emission of carbon dioxide gradually decreases after the carbon peak reaching. Carbon neutralization means that enterprises, groups or individuals measure and calculate the total amount of greenhouse gas emission generated directly or indirectly within a certain time, and then the emission of carbon dioxide generated by the enterprises, the groups or the individuals is counteracted through the forms of afforestation, energy conservation, emission reduction and the like, so that zero emission of the carbon dioxide is realized.
The carbon dioxide in the atmosphere mainly comes from six aspects of power generation, transportation, industry, building industry and animal and plant respiration. Among them, the main sources of anthropogenic carbon dioxide emissions are fossil fuel combustion in energy production and transportation, and many hundreds of plants and power stations and motor vehicles powered by fossil fuels worldwide, and their exhaust gases are the main sources of atmospheric carbon dioxide. The harm of carbon dioxide to human beings is mainly reflected in the following two aspects. Most typically the greenhouse effect, which causes the glaciers to melt and the sea level to rise. Greenhouse effect can also affect the circulation of the atmosphere, change the water circulation of the earth and further change the global precipitation distribution. The greenhouse effect seriously influences the production, life and social and economic development of people, and causes huge economic loss. Carbon dioxide, on the other hand, is a carbon resource. The high-concentration carbon dioxide can be applied to the fields of medical treatment, food, welding and the like. Due to its wide application, carbon dioxide recovery technology has become one of the focuses of research concerns in countries around the world.
At present, the mainstream carbon dioxide recovery process at home and abroad is an MEA process and a pressure swing adsorption process.
Wherein the MEA process is a chemical absorption method and means utilizing CO 2 Reacting with absorbent to form a weakly bonded intermediate compound, and changing the conditions to enrich CO 2 Absorbing liquid of (2) CO 2 The absorbent can be regenerated by desorption. A typical chemical absorbent is Monoethanolamine (MEA). The method has some defects, so that the popularization and the application are limited, for example, the solvent needs to be heated during regeneration, the energy consumption is high, the operation cost is high when the method is used in the power industry, and the problems of air pollution, easy oxidative degradation, serious corrosion to equipment and the like exist.
The pressure swing adsorption method mainly utilizes the characteristic that the adsorption capacity of an adsorbent to gas changes along with the pressure change, the adsorbent is used for pressurizing and adsorbing carbon dioxide components in the gas under the condition of selective adsorption, and the components are decompressed and desorbed to regenerate the adsorbent, so that the separation of the carbon dioxide components and impurity components is realized, and meanwhile, the adsorbent is regenerated. Each adsorber must go through two stages of adsorption and regeneration in a practical process. It follows that the adsorption process is intermittent for each adsorber and multiple adsorber cycles must be employed.
Disclosure of Invention
The embodiment of the invention aims to provide carbon dioxide multidimensional normal-pressure purification equipment which adopts normal-pressure adsorption and offline temperature swing desorption, can effectively reduce energy consumption, improve adsorption efficiency and reduce the emission of carbon dioxide.
In order to achieve the purpose, the invention adopts the following technical scheme:
the utility model provides a carbon dioxide multidimension ordinary pressure purification equipment, includes draught fan, carbon dioxide adsorption tank, first screw conveyer, first lifting machine, regeneration tank, air heater, new trend fan, first butterfly valve, second butterfly valve and third butterfly valve, wherein, the air outlet of draught fan with the air inlet of carbon dioxide adsorption tank is connected, the carbon dioxide adsorption tank intussuseption is filled with adsorption material, first screw conveyer install in the lower part of carbon dioxide adsorption tank, first lifting machine install in first screw conveyer's lower part, the regeneration tank with first lifting machine connects, new trend fan passes through air heater with the regeneration tank is connected, first butterfly valve, second butterfly valve and third butterfly valve respectively with the regeneration tank is connected.
Further, the multidimensional normal-pressure purification equipment for carbon dioxide further comprises a conveying fan and an adsorbent storage tank, wherein an air outlet of the conveying fan is close to the first butterfly valve, and an air outlet of the conveying fan is connected with the adsorbent storage tank.
Further, a second spiral conveyor is arranged at the lower part of the adsorbent storage tank, a second material lifting machine is arranged at the lower part of the second spiral conveyor, and the second material lifting machine is connected with the carbon dioxide adsorption tank.
Furthermore, the top inlet of the regeneration tank is connected with the first material lifting machine, the bottom outlet of the regeneration tank is connected with the first butterfly valve, the upper outlet of the regeneration tank is respectively connected with the second butterfly valve and the third butterfly valve, and the lower inlet of the regeneration tank is connected with the air heater.
Further, the heating temperature of the air heater is 200-300 ℃.
Further, the adsorbent material is a multi-dimensional zeolite adsorbent.
Further, the air inlet of the carbon dioxide adsorption tank is located at a position on the side surface of the carbon dioxide adsorption tank close to the bottom, and the adsorption material is filled in the lower portion of the carbon dioxide adsorption tank.
The invention has the following beneficial effects:
according to the invention, carbon dioxide is adsorbed at normal pressure by an adsorbing material filled in the carbon dioxide adsorption box, the adsorbing material enters the regeneration tank through the first screw conveyor and the first material lifting machine after being adsorbed and saturated, then the air fed by the fresh air fan is heated by the air heater and then is fed into the regeneration tank, the saturated adsorbing material is desorbed at high temperature, the carbon dioxide is desorbed and then is respectively subjected to subsequent storage treatment through the third butterfly valve and is discharged through the second butterfly valve, and the desorbed adsorbing material is recycled through the first butterfly valve. Because normal pressure adsorption and off-line temperature swing desorption are adopted, the energy consumption can be effectively reduced, the adsorption efficiency can be improved, and the emission of carbon dioxide can be reduced.
Drawings
Fig. 1 is a schematic structural diagram of a multidimensional normal pressure purification apparatus for carbon dioxide according to an embodiment of the present invention.
Reference numerals:
an induced draft fan 1; a carbon dioxide adsorption tank 2; a first screw conveyor 3; a first material lifting machine 4;
a regeneration tank 5; an air heater 6; a fresh air fan 7; a conveying fan 8;
an adsorbent storage tank 9; a second screw conveyor 10; a second material elevator 11; a first butterfly valve 12;
a second butterfly valve 13; a third butterfly valve 14.
Detailed Description
The technical solutions in the embodiments of the present invention will be clearly and completely described below with reference to the drawings in the embodiments of the present invention, and it is obvious that the described embodiments are only a part of the embodiments of the present invention, and not all of the embodiments. All other embodiments, which can be derived by a person skilled in the art from the embodiments given herein without making any creative effort, shall fall within the protection scope of the present invention.
In the description of the present invention, it should be noted that the terms "center", "upper", "lower", "left", "right", "vertical", "horizontal", "inner", "outer", etc., indicate orientations or positional relationships based on the orientations or positional relationships shown in the drawings, and are only for convenience of description and simplicity of description, but do not indicate or imply that the device or element being referred to must have a particular orientation, be constructed and operated in a particular orientation, and thus, should not be construed as limiting the present invention; the terms "first," "second," and "third" are used for descriptive purposes only and are not to be construed as indicating or implying relative importance, and furthermore, unless otherwise explicitly stated or limited, the terms "mounted," "connected," and "connected" are to be construed broadly and may be, for example, fixedly connected, detachably connected, or integrally connected; can be mechanically or electrically connected; they may be connected directly or indirectly through intervening media, or they may be interconnected between two elements. The specific meanings of the above terms in the present invention can be understood in a specific case to those of ordinary skill in the art.
As shown in fig. 1, the multidimensional normal-pressure purification equipment for carbon dioxide provided by the embodiment of the invention may include an induced draft fan 1, a carbon dioxide adsorption tank 2, a first screw conveyor 3, a first material lifting machine 4, a regeneration tank 5, an air heater 6, a fresh air fan 7, a first butterfly valve 12, a second butterfly valve 13, a third butterfly valve 14, and the like.
Specifically, draught fan 1 set up in the front end of carbon dioxide adsorption box 2, draught fan 1's air outlet with the air inlet of carbon dioxide adsorption box 2 is connected, and draught fan 1's air intake is used for inhaling outside flue gas, contain the carbon dioxide in the flue gas.
And the carbon dioxide adsorption box 2 is filled with an adsorption material, and the adsorption material is used for adsorbing carbon dioxide. The adsorbent material is preferably a multi-dimensional zeolite adsorbent.
In this embodiment, the first screw conveyor 3 is attached to the lower portion of the carbon dioxide adsorption tank 2, and enters the first screw conveyor 3 when the adsorption material is saturated. The first lifter 4 is installed at a lower portion of the first screw conveyor 3, and is configured to feed the saturated adsorbent in the first screw conveyor 3 into the regeneration tank 5.
The regeneration tank 5 is connected with the first material lifting machine 4. The fresh air fan 7 is connected with the air heater 6, and the fresh air fan 7 is connected with the regeneration tank 5 through the air heater 6. The first butterfly valve 12, the second butterfly valve 13, and the third butterfly valve 14 are connected to the regeneration tank 5, respectively.
Preferably, the heating temperature of the air heater 6 is 200-300 ℃, and the air entering the air heater 6 can be heated to 200-300 ℃ and then discharged.
In implementation, the fresh air fan 7 firstly introduces air into the air heater 6 for heating. Then, the heated high-temperature air enters the regeneration tank 5, and the saturated adsorption material is subjected to high-temperature desorption, and carbon dioxide is desorbed. The third butterfly valve 14 is then opened and the second butterfly valve 13 closed, allowing the carbon dioxide to exit into a subsequent storage and disposal system. After the desorption of the carbon dioxide in the regeneration tank 5 is completed, the third butterfly valve 14 is closed, the second butterfly valve 13 is opened, the air heater 6 is closed, so that cold air enters the regeneration tank 5, the adsorption material is cooled, and the cooled air is discharged into the atmosphere. Finally, the desorbed adsorbent material is recycled through the first butterfly valve 12.
Because normal pressure adsorption and off-line temperature swing desorption are adopted, the energy consumption can be effectively reduced, the adsorption efficiency can be improved, and the emission of carbon dioxide can be reduced.
As an embodiment of the present invention, the top inlet of the regeneration tank 5 is connected to the first lifter 4, so that the adsorbing material in the first lifter 4 can smoothly enter into the regeneration tank 5. The outlet at the bottom of the regeneration tank 5 is connected with the first butterfly valve 12, so that the adsorbing material desorbed from the regeneration tank 5 is recycled through the first butterfly valve 12. The upper outlet of the regeneration tank 5 is connected with the second butterfly valve 13 and the third butterfly valve 14 respectively, so that the carbon dioxide desorbed from the regeneration tank 5 is discharged and enters a subsequent storage and treatment system or is discharged into the atmosphere. The lower inlet of the regeneration tank 5 is connected with the air heater 6, so that high-temperature air heated by the air heater 6 can enter the regeneration tank 5 to complete off-line temperature-variable desorption.
In order to make the entering flue gas among the carbon dioxide adsorption tank 2 flows from bottom to top, realizes the abundant absorption to carbon dioxide, the air inlet of carbon dioxide adsorption tank 2 set up in the position that the carbon dioxide adsorption tank 2 side is close to the bottom, will the adsorption material fill in the lower part of carbon dioxide adsorption tank 2.
In this embodiment, when the adsorption material after desorption is recycled through the first butterfly valve 12, the multidimensional normal pressure purification equipment for carbon dioxide may further include a delivery fan 8 and an adsorbent storage tank 9. Wherein, the air outlet of the conveying fan 8 is close to the first butterfly valve 12, and the air outlet of the conveying fan 8 is connected with the adsorbent storage tank 9. During operation, the first butterfly valve 12 is opened, the conveying fan 8 is started, and the desorbed adsorbing material is blown into the adsorbent storage tank 9, so that recycling is facilitated.
Further, a second screw conveyor 10 is arranged at the lower part of the adsorbent storage tank 9, and the second screw conveyor 10 is used for feeding the adsorbing material in the adsorbent storage tank 9 into the second material lifting machine 11. The second lifter 11 is disposed at a lower portion of the second screw conveyor 10, and the second lifter 11 is connected to the carbon dioxide adsorption tank 2. The second material lifting machine 11 is used for conveying the adsorbing material into the carbon dioxide adsorbing tank 2, so as to realize the recycling of the adsorbing material.
It should be noted that the induced draft fan 1, the carbon dioxide adsorption tank 2, the first screw conveyor 3, the first material lifting machine 4, the regeneration tank 5, the air heater 6, the fresh air fan 7, the conveying fan 8, the adsorbent storage tank 9, the second screw conveyor 10 and the second material lifting machine 11 are connected through pipelines, and the connection mode is flange connection.
In summary, according to the present invention, the carbon dioxide is adsorbed at normal pressure by the adsorbing material filled in the carbon dioxide adsorbing box 2, the adsorbing material is saturated and then enters the regeneration tank 5 through the first screw conveyor 3 and the first material lifting machine 4, the air heater 6 heats the air fed by the fresh air fan 7 and then enters the regeneration tank 5, the saturated adsorbing material is desorbed at high temperature, the carbon dioxide is desorbed and then is subjected to subsequent storage treatment through the third butterfly valve 14 and is discharged to the atmosphere through the second butterfly valve 13, and the desorbed adsorbing material is recycled through the first butterfly valve 12. Because normal pressure adsorption and off-line temperature swing desorption are adopted, the energy consumption can be effectively reduced, the adsorption efficiency can be improved, and the emission of carbon dioxide can be reduced.
Finally, it should be noted that: although the present invention has been described in detail with reference to the foregoing embodiments, it will be apparent to those skilled in the art that modifications may be made to the embodiments or portions thereof without departing from the spirit and scope of the invention.

Claims (7)

1. The utility model provides a carbon dioxide multidimension ordinary pressure purification equipment, its characterized in that, includes draught fan, carbon dioxide adsorption box, first screw conveyer, first lifting machine, regeneration tank, air heater, new trend fan, first butterfly valve, second butterfly valve and third butterfly valve, wherein, the air outlet of draught fan with the air inlet of carbon dioxide adsorption box is connected, the carbon dioxide adsorption box intussuseption is filled with adsorption material, first screw conveyer install in the lower part of carbon dioxide adsorption box, first lifting machine install in first screw conveyer's lower part, the regeneration tank with first lifting machine connects, the new trend fan passes through air heater with the regeneration tank is connected, first butterfly valve, second butterfly valve and third butterfly valve respectively with the regeneration tank is connected.
2. The multidimensional normal-pressure purification equipment for carbon dioxide as claimed in claim 1, further comprising a conveying fan and an adsorbent storage tank, wherein an air outlet of the conveying fan is arranged close to the first butterfly valve, and an air outlet of the conveying fan is connected with the adsorbent storage tank.
3. The multidimensional atmospheric-pressure purification equipment for carbon dioxide as recited in claim 2, wherein a second screw conveyor is arranged at the lower part of the adsorbent storage tank, and a second material lifting machine is arranged at the lower part of the second screw conveyor and connected with the carbon dioxide adsorption tank.
4. The multi-dimensional atmospheric purification apparatus for carbon dioxide as recited in claim 1, wherein the regeneration tank has a top inlet connected to the first elevator, a bottom outlet connected to the first butterfly valve, an upper outlet connected to the second butterfly valve and the third butterfly valve, respectively, and a lower inlet connected to the air heater.
5. The multidimensional atmospheric purification equipment of carbon dioxide as recited in claim 1, wherein the heating temperature of the air heater is 200-300 ℃.
6. The multi-dimensional atmospheric purification plant of carbon dioxide as recited in claim 1, wherein the adsorbent material is a multi-dimensional zeolite adsorbent.
7. The multidimensional atmospheric-pressure purification apparatus for carbon dioxide as recited in claim 1, wherein the gas inlet of the carbon dioxide adsorption tank is located at a position on a side surface of the carbon dioxide adsorption tank near a bottom thereof, and the adsorption material is filled in a lower portion of the carbon dioxide adsorption tank.
CN202210437248.9A 2022-04-21 2022-04-21 Multidimensional normal-pressure purification equipment for carbon dioxide Pending CN115040972A (en)

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN115970441A (en) * 2022-11-02 2023-04-18 原初科技(北京)有限公司 Carbon dioxide absorption furnace and using method thereof

Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN114307535A (en) * 2022-02-09 2022-04-12 西安热工研究院有限公司 System and method for directly capturing carbon dioxide by continuous air

Patent Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN114307535A (en) * 2022-02-09 2022-04-12 西安热工研究院有限公司 System and method for directly capturing carbon dioxide by continuous air

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN115970441A (en) * 2022-11-02 2023-04-18 原初科技(北京)有限公司 Carbon dioxide absorption furnace and using method thereof

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Application publication date: 20220913