CN115028877A - Solid waste based stone crystal floor base material and preparation method thereof - Google Patents
Solid waste based stone crystal floor base material and preparation method thereof Download PDFInfo
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- 239000004575 stone Substances 0.000 title claims abstract description 59
- 239000002910 solid waste Substances 0.000 title claims abstract description 55
- 239000013078 crystal Substances 0.000 title claims abstract description 41
- 239000000463 material Substances 0.000 title claims abstract description 39
- 238000002360 preparation method Methods 0.000 title abstract description 5
- 239000000843 powder Substances 0.000 claims abstract description 92
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- 239000010935 stainless steel Substances 0.000 claims abstract description 37
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- 239000000203 mixture Substances 0.000 claims description 44
- 238000002156 mixing Methods 0.000 claims description 33
- 239000000758 substrate Substances 0.000 claims description 24
- 239000000126 substance Substances 0.000 claims description 23
- NXQMCAOPTPLPRL-UHFFFAOYSA-N 2-(2-benzoyloxyethoxy)ethyl benzoate Chemical group C=1C=CC=CC=1C(=O)OCCOCCOC(=O)C1=CC=CC=C1 NXQMCAOPTPLPRL-UHFFFAOYSA-N 0.000 claims description 22
- 239000004156 Azodicarbonamide Substances 0.000 claims description 22
- UIIMBOGNXHQVGW-UHFFFAOYSA-M Sodium bicarbonate Chemical compound [Na+].OC([O-])=O UIIMBOGNXHQVGW-UHFFFAOYSA-M 0.000 claims description 22
- XOZUGNYVDXMRKW-AATRIKPKSA-N azodicarbonamide Chemical compound NC(=O)\N=N\C(N)=O XOZUGNYVDXMRKW-AATRIKPKSA-N 0.000 claims description 22
- 235000019399 azodicarbonamide Nutrition 0.000 claims description 22
- 239000002243 precursor Substances 0.000 claims description 22
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- UIIMBOGNXHQVGW-DEQYMQKBSA-M Sodium bicarbonate-14C Chemical compound [Na+].O[14C]([O-])=O UIIMBOGNXHQVGW-DEQYMQKBSA-M 0.000 claims description 11
- NIXOWILDQLNWCW-UHFFFAOYSA-M acrylate group Chemical group C(C=C)(=O)[O-] NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 claims description 11
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- 238000000034 method Methods 0.000 claims description 5
- 238000009408 flooring Methods 0.000 claims description 4
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- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 abstract description 30
- 229910000019 calcium carbonate Inorganic materials 0.000 abstract description 15
- FPAFDBFIGPHWGO-UHFFFAOYSA-N dioxosilane;oxomagnesium;hydrate Chemical compound O.[Mg]=O.[Mg]=O.[Mg]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O FPAFDBFIGPHWGO-UHFFFAOYSA-N 0.000 abstract description 10
- 241001264730 Callistemon salignus Species 0.000 abstract description 4
- BPQQTUXANYXVAA-UHFFFAOYSA-N Orthosilicate Chemical compound [O-][Si]([O-])([O-])[O-] BPQQTUXANYXVAA-UHFFFAOYSA-N 0.000 abstract description 4
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- 150000001875 compounds Chemical class 0.000 abstract 1
- 229910004298 SiO 2 Inorganic materials 0.000 description 18
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- 230000000052 comparative effect Effects 0.000 description 4
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- RNFJDJUURJAICM-UHFFFAOYSA-N 2,2,4,4,6,6-hexaphenoxy-1,3,5-triaza-2$l^{5},4$l^{5},6$l^{5}-triphosphacyclohexa-1,3,5-triene Chemical compound N=1P(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP=1(OC=1C=CC=CC=1)OC1=CC=CC=C1 RNFJDJUURJAICM-UHFFFAOYSA-N 0.000 description 1
- BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 description 1
- 229920001875 Ebonite Polymers 0.000 description 1
- 239000004743 Polypropylene Substances 0.000 description 1
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 1
- 239000004566 building material Substances 0.000 description 1
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- C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
- C08J9/04—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent
- C08J9/06—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent by a chemical blowing agent
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- C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
- C08J9/0014—Use of organic additives
- C08J9/0023—Use of organic additives containing oxygen
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- C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
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- C08J9/06—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent by a chemical blowing agent
- C08J9/10—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent by a chemical blowing agent developing nitrogen, the blowing agent being a compound containing a nitrogen-to-nitrogen bond
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Abstract
The invention provides a solid waste base stone crystal floor base material and a preparation method thereof, belonging to the field of stone wood polymer composite floors. The invention utilizes stainless steel slag ultrafine powder and solidified fly ash ultrafine powder, and then compounds the stainless steel slag ultrafine powder, the solidified fly ash ultrafine powder, resin powder, a heat stabilizer, a plasticizer, a lubricant, a mixed foaming agent and a foaming regulator to prepare the solid waste base stone floor base material. The stone crystal floor base material prepared by the invention not only has waterproofness and moisture resistance, but also greatly improves the wear resistance and weather resistance. The invention solves the problem that the traditional stone crystal floor base material needs to consume primary resources such as light calcium carbonate powder, talcum powder and the like; the light calcium carbonate powder belongs to silicate, so that the wear resistance is to be improved; the solidified fly ash is difficult to utilize, and particularly has high added value utilization, thereby meeting the current industrial development requirements of energy conservation, environmental protection and circular economy.
Description
Technical Field
The invention belongs to the field of stone-wood polymer composite floors, and particularly relates to a solid waste base stone crystal floor base material and a preparation method thereof.
Background
The stone crystal floor is a composite floor which is prepared by using a composite material prepared from high polymer materials such as calcium carbonate powder, polyvinyl chloride (or polypropylene) and other materials as raw materials as a base material and performing surface decoration and processing, wherein the stone crystal floor base material is a main component. T/CNFPIA 3004-2019 Stone Wood Plastic flooring is formally released in 2019, 3 and 20 months, and after the group standard is implemented, in order to promote the application of the stone crystalline flooring in engineering, the China Association for forestry industry and the China society for urban science and research jointly compile and release the technical standards for the application of the Stone Wood Plastic flooring in 2020, 4 months. With the increasing expansion of the market of the stone floor in recent years, the demand of raw materials for the stone floor base material is increased, and especially the consumption of primary resources such as light calcium carbonate and talcum powder is obviously increased.
The stainless steel slag is industrial solid waste which is alkaline, and the main components of the stainless steel slag are CaO and Fe 2 O 3 、SiO 2 And small amount of ZnO, CuO and Cr 2 O 3 Heavy metal oxides such as PbO; the fly ash is different from common fly ash or fly ash, is not a chemical inert substance, contains various harmful heavy metal substances such as Cd, Pb, Zn, Cr and the like and salts which can be leached by water, belongs to dangerous solid waste, and can be used after being treated by a curing technology. The solidified fly ash solves the problem that various harmful heavy metal substances and salts such as Cd, Pb, Zn, Cr and the like can be leached by water, and the main chemical component of the solidified fly ash is SiO 2 、Al 2 O 3 And CaO. At present, the stainless steel slag and the solidified fly ash have low utilization rate and are piled in open air in large quantity, thereby not only occupying valuable land, but also polluting the surrounding environment and underground water. If the stainless steel slag and the solidified fly ash can be used for replacing expensive primary resources of light calcium carbonate and talcum powder, the utilization additional values of the stainless steel slag and the solidified fly ash can be improved, and the production cost of the stone crystal floor base material can be reduced.
Disclosure of Invention
The problem that the conventional stone-crystal floor base material needs to consume primary resources such as light calcium carbonate powder, talcum powder and the like is solved; the light calcium carbonate powder belongs to silicate, so that the wear resistance is to be improved; the solidified fly ash is difficult to utilize, and particularly has high added value utilization. The invention provides a solid waste base stone crystal floor base material prepared by utilizing stainless steel slag ultrafine powder and solidified fly ash ultrafine powder, which aims to solve the problems and meets the current industrial development requirements of energy conservation, environmental protection and circular economy.
In order to solve the above technical problems, the present invention is realized by the following technical solutions.
The invention provides a solid waste-based stone crystal floor base material which comprises the following raw materials in percentage by weight:
the fineness of the stainless steel slag ultrafine powder is 500-700 meshes, and the main chemical components are CaO (52.35 percent) and SiO 2 (23.68%)、Al 2 O 3 (8.31%)、MgO(7.56%)、Fe 2 O 3 (1.96%)、Cr 2 O 3 (1.12%)、PbO(0.83%)、P 2 O5 (0.41%), CuO (0.37%), MnO (0.32%) and others (3.09%).
The fineness of the solidified fly ash ultrafine powder is 500-700 meshes, and the main chemical components are CaO (35.15 percent) and SiO 2 (28.59%)、Al 2 O 3 (13.35%)、Fe 2 O 3 (6.11%)、MgO(2.22%)、SO 3 (4.12%), Cl (0.86%) and others (9.60%).
The resin powder is polyvinyl chloride.
The heat stabilizer is polyethylene wax.
The plasticizer is diethylene glycol dibenzoate.
The lubricant is liquid chlorinated paraffin.
The mixed foaming agent is a mixture of azodicarbonamide and sodium bicarbonate, and the mass ratio of the azodicarbonamide to the sodium bicarbonate is 1: 2-2: 1.
The foaming regulator is acrylate.
The total weight percentage of the heat stabilizer, the plasticizer, the lubricant, the mixed foaming agent and the foaming regulator is 7-10%.
The invention also provides a preparation method of the solid waste based stone floor base material, which comprises the following steps:
firstly, mixing stainless steel slag ultrafine powder, solidified fly ash ultrafine powder and resin powder by using a high-speed mixer at the temperature of 110-130 ℃ for 90-120 min, and then adding a heat stabilizer, a plasticizer, a lubricant, a mixed foaming agent and a foaming regulator for mixing for 45-60 min to obtain a high-temperature mixture.
And secondly, cooling the high-temperature mixture for 60-90 min by using a cold mixer at the temperature of 50-60 ℃ to obtain the solid waste base stone floor base material precursor.
And finally, mixing the solid waste base stone crystal floor base material precursor for 45-60 min by using a screw extruder with the temperature of 170-200 ℃, then feeding the mixture into a sheet T die head for extrusion molding, and obtaining the solid waste base stone crystal floor base material by passing the molded sheet through a three/four-roller calender.
The innovation points of the invention are as follows:
(1) the stainless steel slag superfine powder and the solidified fly ash superfine powder have the characteristics of spherical shape (ball milling process) and gravel shape (vertical milling process), are used for replacing light calcium carbonate powder and talcum powder, and achieve the effects of particle filling and framework supporting in the stone-crystal floor base material.
(2) The light calcium carbonate powder belongs to carbonate, and has good water resistance, but the wear resistance and the weather resistance are insufficient. By utilizing the characteristic that stainless steel slag ultrafine powder belongs to silicate and polyvinyl chloride belongs to a high polymer material and has good hydrophobicity, the prepared stone-crystal floor base material not only has waterproofness and moisture resistance, but also has greatly improved wear resistance and weather resistance.
(3) The fineness of the stainless steel slag ultrafine powder is 500-700 meshes, the fineness of the solidified fly ash ultrafine powder is 500-700 meshes, and the ultrafine powder can be uniformly dispersed in the polyvinyl chloride by utilizing the characteristics of large specific surface area and good dispersibility, so that good workability is achieved.
(4) The stainless steel slag has alkalinity, is beneficial to foaming of the stone crystal floor base material, and improves the bending strength performance; the solidified fly ash has high alumina content and improved flame retardant performance. And meanwhile, the polyvinyl chloride has good wrapping property, so that heavy metal in the stainless steel slag can be effectively wrapped, leaching of heavy metal elements is limited, and safety is ensured.
Compared with the prior art, the invention has the following beneficial effects:
1. the invention solves the problem that the traditional stone crystal floor base material needs to consume primary resources such as light calcium carbonate powder, talcum powder and the like; the light calcium carbonate powder belongs to silicate, so that the wear resistance is to be improved; the solidified fly ash is difficult to utilize, and particularly has high added value utilization.
2. The invention prepares the solid waste based stone crystal floor base material by utilizing the industrial solid waste stainless steel slag superfine powder and the solidified fly ash superfine powder, and compounding the solid waste stainless steel slag superfine powder with resin powder, a heat stabilizer, a plasticizer, a lubricant, a mixed foaming agent and a foaming regulator, so as to solve the problems and meet the current industrial development requirements of energy conservation, environmental protection and circular economy.
Drawings
FIG. 1 is an SEM image of stainless steel slag ultrafine powder produced by the ball milling process of the present invention.
FIG. 2 is SEM image of solidified fly ash micropowder obtained by the vertical milling process of the present invention.
Detailed Description
The present invention will be described in detail with reference to specific examples, but the present invention is not limited to the examples.
Example 1
The components used for preparing 100g of the product of the invention and the mass ratio thereof are as follows:
the fineness of the stainless steel slag ultrafine powder is 550 meshes, and the main chemical components are CaO (52.35 percent) and SiO 2 (23.68%)、Al 2 O 3 (8.31%)、MgO(7.56%)、Fe 2 O 3 (1.96%)、Cr 2 O 3 (1.12%)、PbO(0.83%)、P 2 O5 (0.41%), CuO (0.37%), MnO (0.32%) and others (3.09%).
The fineness of the solidified fly ash ultrafine powder is 700 meshes, and the main chemical components are CaO (35.15 percent) and SiO 2 (28.59%)、Al 2 O 3 (13.35%)、Fe 2 O 3 (6.11%)、MgO(2.22%)、SO 3 (4.12%), Cl (0.86%) and others (9.60%).
The resin powder is polyvinyl chloride.
The heat stabilizer is polyethylene wax.
The plasticizer is diethylene glycol dibenzoate.
The lubricant is liquid chlorinated paraffin.
The mixed foaming agent is a mixture of azodicarbonamide and sodium bicarbonate, and the mass ratio of the azodicarbonamide to the sodium bicarbonate is 1: 2.
The foaming regulator is acrylate.
The total weight percentage of the heat stabilizer, the plasticizer, the lubricant, the mixed foaming agent and the foaming regulator is 9.1%.
Firstly, mixing stainless steel slag ultrafine powder, solidified fly ash ultrafine powder and resin powder for 90min by using a high-speed mixer at the temperature of 125 ℃, adding a heat stabilizer, a plasticizer, a lubricant, a mixed foaming agent and a foaming regulator, and mixing for 45min to obtain a high-temperature mixture.
And secondly, cooling the high-temperature mixture for 70min by using a cold mixer at the temperature of 60 ℃ to obtain the solid waste base stone floor substrate precursor.
And finally, mixing the solid waste base stone crystal floor substrate precursor for 55min by using a screw extruder with the temperature of 190 ℃, then feeding the mixture into a sheet T die head for extrusion molding, and performing three/four-roller calender on the molded sheet to obtain the solid waste base stone crystal floor substrate.
Example 2
The components used for preparing 100g of the product of the invention and the mass ratio thereof are as follows:
the fineness of the stainless steel slag ultrafine powder is 700 meshes, and the main chemical components are CaO (52.35 percent) and SiO 2 (23.68%)、Al 2 O 3 (8.31%)、MgO(7.56%)、Fe 2 O 3 (1.96%)、Cr 2 O 3 (1.12%)、PbO(0.83%)、P 2 O5 (0.41%), CuO (0.37%), MnO (0.32%) and the likeHe (3.09%).
The fineness of the solidified fly ash ultrafine powder is 600 meshes, and the main chemical components are CaO (35.15 percent) and SiO 2 (28.59%)、Al 2 O 3 (13.35%)、Fe 2 O 3 (6.11%)、MgO(2.22%)、SO 3 (4.12%), Cl (0.86%) and others (9.60%).
The resin powder is polyvinyl chloride.
The heat stabilizer is polyethylene wax.
The plasticizer is diethylene glycol dibenzoate.
The lubricant is liquid chlorinated paraffin.
The mixed foaming agent is a mixture of azodicarbonamide and sodium bicarbonate, and the mass ratio of the azodicarbonamide to the sodium bicarbonate is 2: 1.
The foaming regulator is acrylate.
The total weight percentage of the heat stabilizer, the plasticizer, the lubricant, the mixed foaming agent and the foaming regulator is 8.7%.
Firstly, mixing stainless steel slag ultrafine powder, solidified fly ash ultrafine powder and resin powder for 105min by using a high-speed mixer at the temperature of 110 ℃, adding a heat stabilizer, a plasticizer, a lubricant, a mixed foaming agent and a foaming regulator, and mixing for 60min to obtain a high-temperature mixture.
And secondly, cooling the high-temperature mixture for 80min by using a cold mixer at the temperature of 55 ℃ to obtain the solid waste base stone floor substrate precursor.
And finally, mixing the solid waste base stone crystal floor base material precursor for 60min by using a screw extruder with the temperature of 170 ℃, then feeding the mixture into a sheet T die head for extrusion molding, and obtaining the solid waste base stone crystal floor base material by passing the molded sheet through a three/four-roller calender.
Example 3
The components used for preparing 100g of the product of the invention and the mass ratio thereof are as follows:
the fineness of the stainless steel slag ultrafine powder is 650 meshes, and the main chemical components are CaO (52.35 percent) and SiO 2 (23.68%)、Al 2 O 3 (8.31%)、MgO(7.56%)、Fe 2 O 3 (1.96%)、Cr 2 O 3 (1.12%)、PbO(0.83%)、P 2 O5 (0.41%), CuO (0.37%), MnO (0.32%) and others (3.09%).
The fineness of the solidified fly ash ultrafine powder is 500 meshes, and the main chemical components are CaO (35.15 percent) and SiO 2 (28.59%)、Al 2 O 3 (13.35%)、Fe 2 O 3 (6.11%)、MgO(2.22%)、SO 3 (4.12%), Cl (0.86%) and others (9.60%).
The resin powder is polyvinyl chloride.
The heat stabilizer is polyethylene wax.
The plasticizer is diethylene glycol dibenzoate.
The lubricant is liquid chlorinated paraffin.
The mixed foaming agent is a mixture of azodicarbonamide and sodium bicarbonate, and the mass ratio of the azodicarbonamide to the sodium bicarbonate is 1: 1.
The foaming regulator is acrylate.
The total weight percentage of the heat stabilizer, the plasticizer, the lubricant, the mixed foaming agent and the foaming regulator is 9.2%.
Firstly, mixing stainless steel slag ultrafine powder, solidified fly ash ultrafine powder and resin powder by using a high-speed mixer at the temperature of 130 ℃ for 95min, and then adding a heat stabilizer, a plasticizer, a lubricant, a mixed foaming agent and a foaming regulator for mixing for 55min to obtain a high-temperature mixture.
And secondly, cooling the high-temperature mixture for 90min by using a cold mixer at the temperature of 50 ℃ to obtain the solid waste base stone floor substrate precursor.
And finally, mixing the solid waste base stone crystal floor substrate precursor for 45min by using a screw extruder with the temperature of 200 ℃, then feeding the mixture into a sheet T die head for extrusion molding, and performing three/four-roller calender on the molded sheet to obtain the solid waste base stone crystal floor substrate.
Example 4
The components used for preparing 100g of the product of the invention and the mass ratio thereof are as follows:
the fineness of the stainless steel slag ultrafine powder is 500-700 meshes, and the main chemical components are CaO (52.35 percent) and SiO 2 (23.68%)、Al 2 O 3 (8.31%)、MgO(7.56%)、Fe 2 O 3 (1.96%)、Cr 2 O 3 (1.12%)、PbO(0.83%)、P 2 O5 (0.41%), CuO (0.37%), MnO (0.32%) and others (3.09%).
The fineness of the solidified fly ash ultrafine powder is 500-700 meshes, and the main chemical components are CaO (35.15%), SiO 2 (28.59%)、Al 2 O 3 (13.35%)、Fe 2 O 3 (6.11%)、MgO(2.22%)、SO 3 (4.12%), Cl (0.86%) and others (9.60%).
The resin powder is polyvinyl chloride.
The heat stabilizer is polyethylene wax.
The plasticizer is diethylene glycol dibenzoate.
The lubricant is liquid chlorinated paraffin.
The mixed foaming agent is a mixture of azodicarbonamide and sodium bicarbonate, and the mass ratio of the azodicarbonamide to the sodium bicarbonate is 2: 1.
The foaming regulator is acrylate.
The total weight percentage of the heat stabilizer, the plasticizer, the lubricant, the mixed foaming agent and the foaming regulator is 9.9%.
Firstly, mixing stainless steel slag ultrafine powder, solidified fly ash ultrafine powder and resin powder by using a high-speed mixer at the temperature of 120 ℃ for 120min, and then adding a heat stabilizer, a plasticizer, a lubricant, a mixed foaming agent and a foaming regulator for mixing for 50min to obtain a high-temperature mixture.
And secondly, cooling the high-temperature mixture for 60min by using a cold mixer at the temperature of 50 ℃ to obtain a solid waste base stone floor substrate precursor.
And finally, mixing the solid waste base stone crystal floor substrate precursor for 50min by using a screw extruder with the temperature of 180 ℃, then feeding the mixture into a sheet T die head for extrusion molding, and performing three/four-roller calender on the molded sheet to obtain the solid waste base stone crystal floor substrate.
Example 5
The components used for preparing 100g of the product of the invention and the mass ratio thereof are as follows:
the fineness of the stainless steel slag ultrafine powder is 500 meshes, and the main chemical components comprise CaO (52.35 percent) and SiO 2 (23.68%)、Al 2 O 3 (8.31%)、MgO(7.56%)、Fe 2 O 3 (1.96%)、Cr 2 O 3 (1.12%)、PbO(0.83%)、P 2 O5 (0.41%), CuO (0.37%), MnO (0.32%) and others (3.09%).
The fineness of the solidified fly ash ultrafine powder is 650 meshes, and the main chemical components are CaO (35.15 percent) and SiO 2 (28.59%)、Al 2 O 3 (13.35%)、Fe 2 O 3 (6.11%)、MgO(2.22%)、SO 3 (4.12%), Cl (0.86%) and others (9.60%).
The resin powder is polyvinyl chloride.
The heat stabilizer is polyethylene wax.
The plasticizer is diethylene glycol dibenzoate.
The lubricant is liquid chlorinated paraffin.
The mixed foaming agent is a mixture of azodicarbonamide and sodium bicarbonate, and the mass ratio of the azodicarbonamide to the sodium bicarbonate is 1: 2.
The foaming regulator is acrylate.
The total weight percentage of the heat stabilizer, the plasticizer, the lubricant, the mixed foaming agent and the foaming regulator is 8.1 percent.
Firstly, mixing stainless steel slag ultrafine powder, solidified fly ash ultrafine powder and resin powder for 115min by using a high-speed mixer at the temperature of 115 ℃, adding a heat stabilizer, a plasticizer, a lubricant, a mixed foaming agent and a foaming regulator, and mixing for 60min to obtain a high-temperature mixture.
And secondly, cooling the high-temperature mixture for 70min by using a cold mixer at the temperature of 60 ℃ to obtain the solid waste base stone floor substrate precursor.
And finally, mixing the solid waste base stone crystal floor substrate precursor for 45min by using a screw extruder with the temperature of 200 ℃, then feeding the mixture into a sheet T die head for extrusion molding, and performing three/four-roller calender on the molded sheet to obtain the solid waste base stone crystal floor substrate.
Example 6
The components used for preparing 100g of the product of the invention and the mass ratio thereof are as follows:
the fineness of the stainless steel slag ultrafine powder is 600 meshes, and the main chemical components of the stainless steel slag ultrafine powder are CaO (52.35 percent) and SiO 2 (23.68%)、Al 2 O 3 (8.31%)、MgO(7.56%)、Fe 2 O 3 (1.96%)、Cr 2 O 3 (1.12%)、PbO(0.83%)、P 2 O5 (0.41%), CuO (0.37%), MnO (0.32%) and others (3.09%).
The fineness of the solidified fly ash ultrafine powder is 550 meshes, and the main chemical components are CaO (35.15 percent) and SiO 2 (28.59%)、Al 2 O 3 (13.35%)、Fe 2 O 3 (6.11%)、MgO(2.22%)、SO 3 (4.12%), Cl (0.86%) and others (9.60%).
The resin powder is polyvinyl chloride.
The heat stabilizer is polyethylene wax.
The plasticizer is diethylene glycol dibenzoate.
The lubricant is liquid chlorinated paraffin.
The mixed foaming agent is a mixture of azodicarbonamide and sodium bicarbonate, and the mass ratio of the azodicarbonamide to the sodium bicarbonate is 1: 1.
The foaming regulator is acrylate.
The total weight percentage of the heat stabilizer, the plasticizer, the lubricant, the mixed foaming agent and the foaming regulator is 9 percent.
Firstly, mixing stainless steel slag ultrafine powder, solidified fly ash ultrafine powder and resin powder for 110min by using a high-speed mixer at the temperature of 125 ℃, adding a heat stabilizer, a plasticizer, a lubricant, a mixed foaming agent and a foaming regulator, and mixing for 55min to obtain a high-temperature mixture.
And secondly, cooling the high-temperature mixture for 80min by using a cold mixer at the temperature of 55 ℃ to obtain a solid waste base stone floor substrate precursor.
And finally, mixing the solid waste base stone crystal floor base material precursor for 55min by using a screw extruder with the temperature of 190 ℃, then feeding the mixture into a sheet T die head for extrusion molding, and processing the molded sheet by a three/four-roller calender to obtain the solid waste base stone crystal floor base material.
Comparative example 1
The components used for preparing 100g of the product of the invention and the mass ratio thereof are as follows:
the fineness of the light calcium carbonate is 325 meshes.
The fineness of the solidified fly ash ultrafine powder is 550 meshes, and the main chemical components are CaO (35.15 percent) and SiO 2 (28.59%)、Al 2 O 3 (13.35%)、Fe 2 O 3 (6.11%)、MgO(2.22%)、SO 3 (4.12%), Cl (0.86%) and others (9.60%).
The resin powder is polyvinyl chloride.
The heat stabilizer is polyethylene wax.
The plasticizer is diethylene glycol dibenzoate.
The lubricant is liquid chlorinated paraffin.
The mixed foaming agent is a mixture of azodicarbonamide and sodium bicarbonate, and the mass ratio of the azodicarbonamide to the sodium bicarbonate is 1: 1.
The foaming regulator is acrylate.
The total weight percentage of the heat stabilizer, the plasticizer, the lubricant, the mixed foaming agent and the foaming regulator is 9 percent.
Firstly, mixing light calcium carbonate powder, solidified fly ash ultrafine powder and resin powder for 110min by using a high-speed mixer at the temperature of 125 ℃, adding a heat stabilizer, a plasticizer, a lubricant, a mixed foaming agent and a foaming regulator, and mixing for 55min to obtain a high-temperature mixture.
And secondly, cooling the high-temperature mixture for 80min by using a cold mixer at the temperature of 55 ℃ to obtain the solid waste base stone floor substrate precursor.
And finally, mixing the solid waste base stone crystal floor substrate precursor for 55min by using a screw extruder with the temperature of 190 ℃, then feeding the mixture into a sheet T die head for extrusion molding, and performing three/four-roller calender on the molded sheet to obtain the solid waste base stone crystal floor substrate.
Comparative example 2
The components used for preparing 100g of the product of the invention and the mass ratio thereof are as follows:
the fineness of the stainless steel slag ultrafine powder is 600 meshes, and the main chemical components of the stainless steel slag ultrafine powder are CaO (52.35 percent) and SiO 2 (23.68%)、Al 2 O 3 (8.31%)、MgO(7.56%)、Fe 2 O 3 (1.96%)、Cr 2 O 3 (1.12%)、PbO(0.83%)、P 2 O5(0.41%)、CuO(0.37%)、MnO(0.32%) and others (3.09%).
The fineness of the talcum powder is 400 meshes.
The resin powder is polyvinyl chloride.
The heat stabilizer is polyethylene wax.
The plasticizer is diethylene glycol dibenzoate.
The lubricant is liquid chlorinated paraffin.
The mixed foaming agent is a mixture of azodicarbonamide and sodium bicarbonate, and the mass ratio of the azodicarbonamide to the sodium bicarbonate is 1: 1.
The foaming regulator is acrylate.
The total weight percentage of the heat stabilizer, the plasticizer, the lubricant, the mixed foaming agent and the foaming regulator is 9 percent.
Firstly, mixing stainless steel slag ultrafine powder, talcum powder and resin powder for 110min by using a high-speed mixer at the temperature of 125 ℃, adding a heat stabilizer, a plasticizer, a lubricant, a mixed foaming agent and a foaming regulator, and mixing for 55min to obtain a high-temperature mixture.
And secondly, cooling the high-temperature mixture for 80min by using a cold mixer at the temperature of 55 ℃ to obtain a solid waste base stone floor substrate precursor.
And finally, mixing the solid waste base stone crystal floor base material precursor for 55min by using a screw extruder with the temperature of 190 ℃, then feeding the mixture into a sheet T die head for extrusion molding, and processing the molded sheet by a three/four-roller calender to obtain the solid waste base stone crystal floor base material.
Comparative example 3
The components used for preparing 100g of the product of the invention and the mass ratio thereof are as follows:
the fineness of the light calcium carbonate powder is 325 meshes.
The fineness of the talcum powder is 400 meshes.
The resin powder is polyvinyl chloride.
The heat stabilizer is polyethylene wax.
The plasticizer is diethylene glycol dibenzoate.
The lubricant is liquid chlorinated paraffin.
The mixed foaming agent is a mixture of azodicarbonamide and sodium bicarbonate, and the mass ratio of the azodicarbonamide to the sodium bicarbonate is 1: 1.
The foaming regulator is acrylate.
The total weight percentage of the heat stabilizer, the plasticizer, the lubricant, the mixed foaming agent and the foaming regulator is 9 percent.
Firstly, mixing light calcium carbonate powder, talcum powder and resin powder for 110min by using a high-speed mixer at the temperature of 125 ℃, adding a heat stabilizer, a plasticizer, a lubricant, a mixed foaming agent and a foaming regulator, and mixing for 55min to obtain a high-temperature mixture.
And secondly, cooling the high-temperature mixture for 80min by using a cold mixer at the temperature of 55 ℃ to obtain the solid waste base stone floor substrate precursor.
And finally, mixing the solid waste base stone crystal floor base material precursor for 55min by using a screw extruder with the temperature of 190 ℃, then feeding the mixture into a sheet T die head for extrusion molding, and processing the molded sheet by a three/four-roller calender to obtain the solid waste base stone crystal floor base material.
The performance test process of the solid waste base stone crystal floor base materials prepared in the embodiments 1-6 and the comparative examples 1-3 is as follows:
performance tests were carried out according to "hardness of indentation (Shore hardness) measured by a durometer for plastics and hard rubber" (GB/T2411-2008), "flammability test method for building materials" (GB/T8626-2007), "bending Performance test method for plastics" (GB/T9341-2000).
TABLE 1 Properties of solid waste-based floor base materials
Claims (7)
1. The solid waste-based stone crystal floor base material is characterized by comprising the following raw materials in percentage by weight:
the fineness of the stainless steel slag ultrafine powder is 500-700 meshes;
the fineness of the solidified fly ash ultrafine powder is 500-700 meshes;
the heat stabilizer is polyethylene wax;
the plasticizer is diethylene glycol dibenzoate;
the mixed foaming agent is a mixture of azodicarbonamide and sodium bicarbonate, and the mass ratio of the azodicarbonamide to the sodium bicarbonate is 1: 2-2: 1;
the foaming regulator is acrylate.
4. the solid waste based crystalline stone floor substrate of claim 1, wherein the resin powder is polyvinyl chloride.
5. The solid waste based crystalline flooring substrate of claim 1, wherein said lubricant is liquid chlorinated paraffin.
6. The solid waste based stone floor substrate of claim 1, wherein the total weight percentage of the heat stabilizer, the plasticizer, the lubricant, the mixed foaming agent and the foaming regulator is 7-10%.
7. The method for preparing the solid waste based stone floor substrate as claimed in claim 1, characterized by comprising the steps of:
firstly, mixing stainless steel slag ultrafine powder, solidified fly ash ultrafine powder and resin powder for 90-120 min by using a high-speed mixer at the temperature of 110-130 ℃, adding a heat stabilizer, a plasticizer, a lubricant, a mixed foaming agent and a foaming regulator, and mixing for 45-60 min to obtain a high-temperature mixture;
secondly, cooling the high-temperature mixture for 60-90 min by using a cold mixer at the temperature of 50-60 ℃ to obtain a solid waste base stone floor base material precursor;
and finally, mixing the solid waste base stone crystal floor base material precursor for 45-60 min by using a screw extruder with the temperature of 170-200 ℃, then feeding the mixture into a sheet T die head for extrusion molding, and obtaining the solid waste base stone crystal floor base material by passing the molded sheet through a three/four-roller calender.
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CN112644043A (en) * | 2020-09-10 | 2021-04-13 | 贺州隆源新材料有限公司 | Method for preparing spc floor from artificial granite waste residues |
CN112793268A (en) * | 2020-12-31 | 2021-05-14 | 浙江永裕家居股份有限公司 | Composite stone crystal floor and manufacturing method thereof |
CN113667238A (en) * | 2021-08-16 | 2021-11-19 | 浙江亚厦装饰股份有限公司 | Stone-plastic section bar and preparation method thereof |
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CN101168610A (en) * | 2007-10-12 | 2008-04-30 | 遵化市钟馗门业有限公司 | Special-purpose board for building and producing method thereof |
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CN111395686A (en) * | 2020-03-24 | 2020-07-10 | 福建龙净脱硫脱硝工程有限公司 | Stone-plastic floor and preparation method thereof |
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