CN115028773A - Instant film forming material and preparation method and application thereof - Google Patents

Abstract

The invention discloses an instant film-forming material and a preparation method and application thereof.A component A of a prefabricated acrylate solution containing an oxidant, a component B of the acrylate solution containing a reducing agent and a component C of the alginate solution are uniformly mixed to obtain a mixed solution, namely the instant film-forming material, and the obtained mixed solution is directly coated on the surface of a human hand to prepare a real-time curing formed glove; the acrylate in the mixed solution is polymerized in real time under the action of a redox initiation system, and the alginate is subjected to lateral crosslinking real-time polymerization when meeting acrylate high-valence metal ions, so that the high-strength and high-toughness acrylate-alginate hybrid hydrogel glove is solidified on the surface of the hand within seconds. The invention can be customized, prepared for use on site, the real-time preparation, molding and wearing are synchronously completed, and the raw materials and the finished product are nontoxic, harmless and naturally degradable, thereby having strong practical value and wide application prospect.

Description

Instant film forming material and preparation method and application thereof

Technical Field

The invention relates to an instant film-forming material, a preparation method and application thereof, in particular to a real-time curing molding glove material, a preparation method and a use method thereof, belonging to the technical field of high molecular compound material technology and wearing technology.

Background

Gloves used by people in life and production activities are mainly gloves which are manufactured in advance and have relatively normalized structure sizes, and the invention and the application of the gloves which are directly cured and formed on hands are rare.

In the prior art, a large number of glove materials with standardized structure and size and preparation technical patents are disclosed, for example, CN105639777B discloses a preparation process of wear-resistant flannelette butyronitrile gloves, which sequentially comprises the following steps: preparing materials, preparing a coagulant, mixing glue, dipping, airing and drying. For another example, CN1631645A discloses a method for manufacturing nitrile rubber medical gloves, which comprises the following steps: A. preparing a sizing material: mixing two nitrile rubber latexes, wherein the mixing volume ratio is 30: 70-70: 30, and the content difference of acrylonitrile in the two nitrile rubber latexes is 3% -10%; B. pre-vulcanizing the rubber material, wherein the mixture ratio of the pre-vulcanizing agent is as follows: 1-5% of KOH, 0.5-2.0% of sulfur, 0.6-3.0% of ZnO, 0-1.5% of ZDC, 0-1.0% of BZ and 0.6-2.5% of titanium dioxide; C. molding; D. vulcanizing; E. and (6) surface treatment.

In the prior art, some liquid forming glove materials and preparation patents are disclosed in recent years, for example, CN 101481561B discloses a liquid glove and a production method thereof, wherein raw materials comprise 10 to 50 parts of chitosan solution, 10 to 50 parts of polyvinyl alcohol solution, 1 to 10 parts of glycerol and 0.5 to 15 parts of ethanol; wherein: the chitosan solution is prepared by adding 0.5 to 10 g of chitosan into per 100 to 200 ml of acetic acid solution with the weight percentage concentration of 3 to 5 percent and dissolving, and the polyvinyl alcohol solution is prepared by adding 10 to 50 g of polyvinyl alcohol into per 50 to 400 ml of acetic acid solution with the weight percentage concentration of 3 to 5 percent and dissolving. For another example, CN 105647303a discloses a method for preparing a ternary blended liquid glove, which is a ternary blended liquid glove prepared by blending gelatin, chitosan and polyvinyl alcohol.

The preparation and use method of the current glove material have a plurality of defects: (1) a large number of gloves with standardized and shaped structure sizes are manufactured in advance, the process is complex, the production period is long, the gloves are not only difficult to adapt to hand appearance characteristics of different people in reality, but also can cause social burden of a large number of glove finished products in the aspects of production, transportation, storage and recovery; (2) in order to be easy to wear, the gloves manufactured in advance usually need to be provided with larger openings and even splicing seams, so that the tight fit and sealing between the gloves and hands are difficult to ensure; (3) the existing gloves made of fiber fabrics, rubber, plastics and other materials have poor environment-friendly and generally degradable components, and are not beneficial to protecting the natural environment and human health; (4) the disclosed hand-cured gloves and methods for making the same leave much room for improvement in materials, processes, functions, performance, etc.

Therefore, there is a need to develop a method for preparing and using real-time curing molded glove materials that can overcome the above-mentioned deficiencies.

Disclosure of Invention

The purpose of the invention is as follows: in order to solve the problems of the prior art, the first object of the present invention is to provide a material capable of forming a film instantly, the second object of the present invention is to provide a method for preparing a material capable of forming a film instantly, and the third object of the present invention is to provide the use of the material capable of forming a film instantly for preparing a real-time cured and formed glove.

The technical scheme is as follows: the instant film forming material is prepared by mixing a component A containing an oxidant and an acrylate solution, a component B containing a reducing agent and the acrylate solution and a component C containing an alginate solution.

Further, the component A comprises the following components in parts by weight: 100 parts of acrylate solution and 0.1-15 parts of oxidant solution (0.05-1.5 parts of oxidant).

The component C comprises the following components in parts by weight: 20-50 parts of alginate solution.

Further, the component B comprises the following components in parts by weight: 100 parts of acrylate solution and 0.1-15 parts of reducing agent solution (0.01-0.35 part of reduced reducing agent).

Further, the component C comprises the following components in parts by weight: 20-50 parts of alginate solution.

Furthermore, the concentration of the acrylate solution in the component A and the concentration of the acrylate solution in the component B are both 18-40 wt%.

Further, the concentration of the oxidant solution is 1-30 wt%.

Furthermore, the concentration of the reducing agent solution is 1-30 wt%.

Further, the concentration of the alginate solution in the component C is 1-10 wt%.

Further, the acrylate is a divalent acrylate or a higher acrylate.

Further, the higher valent acrylate may be a more divalent acrylate, such as a trivalent acrylate.

Furthermore, the acrylate is one or more of magnesium acrylate, calcium acrylate, barium acrylate, iron acrylate, zinc acrylate and aluminum acrylate.

Further, the oxidant is one or more of hydrogen peroxide, ammonium persulfate, sodium persulfate and potassium persulfate.

Further, the oxidizing agent is preferably hydrogen peroxide.

Further, the reducing agent is one or more of ferrous sulfate, sodium bisulfite, sodium sulfite and sodium thiosulfate.

Further, the reducing agent is preferably sodium hydrogen sulfite.

Further, the alginate is monovalent alginate.

Furthermore, the monovalent alginate is one or more of sodium alginate, potassium alginate and ammonium alginate.

The preparation method of the instant film-forming material comprises the following steps:

(1) adding oxidant solution into acrylate solution, and stirring uniformly to prepare mixed solution A, namely component A;

(2) adding a reducing agent solution into the acrylate solution, and uniformly stirring to prepare a mixed solution B, namely a component B;

(3) adding alginate into deionized water, stirring until uniform and transparent, and making into alginate solution C to obtain component C;

(4) the component A, the component B and the component C are quickly and uniformly mixed to form a mixed solution, namely the instant film-forming material.

The instant film-forming material is applied to the preparation of real-time curing and forming gloves.

The application method of the instant film-forming material in the preparation of the real-time curing molding gloves comprises the following steps:

(1) adding oxidant solution into acrylate solution, and stirring uniformly to prepare mixed solution A, namely component A;

(2) adding a reducing agent solution into the acrylate solution, and uniformly stirring to prepare a mixed solution B, namely a component B;

(3) adding alginate into deionized water, stirring until uniform and transparent, and making into alginate solution C to obtain component C;

(4) cleaning the surface of a hand, quickly and uniformly mixing the component A, the component B and the component C to form a mixed solution, coating the mixed solution on the surface of the hand to a required length, and stretching fingers in the coating process so as to prevent the fingers from approaching each other and bonding together when the mixed solution is cured;

(5) baking the hand coated with the mixed solution at the temperature of 30-45 ℃ for 5-30 s, keeping the fingers open and turning the wrist during baking, drying the whole hand surface, and finishing the glove manufacturing;

(6) after the gloves are used, the gloves are uncovered from the edges of the gloves and taken off.

The principle of the technical scheme of the invention is as follows: preparing an acrylate solution A component containing an oxidant, an acrylate solution B component containing a reducing agent and an alginate solution C component in advance, and directly coating a mixed solution obtained by uniformly mixing the component A, the component B and the component C on the surface of the hand of a human body; the acrylate in the mixed solution is polymerized in real time under the action of a redox initiation system, and the alginate is subjected to lateral crosslinking real-time polymerization when meeting high-valence metal ions of the acrylate, and is solidified into the high-strength and high-toughness acrylate-alginate hybrid hydrogel glove on the surface of the hand within seconds.

Has the advantages that: compared with the prior art, the invention has the following remarkable advantages:

the invention preferably adopts environment-friendly nontoxic harmless and easily degradable materials, is directly adhered to the surface of a human body at normal temperature and is cured in real time to form a seamless jointed high-strength and high-toughness film layer, and is particularly suitable for being used on hands or the surfaces of the skin of arms, shoulders, legs and feet or other parts of the body.

The invention can provide a novel aseptic and pollution-free protection means for certain occasions with higher sanitary requirements. Meanwhile, the invention can be directly used for surface protection or decoration of some articles under appropriate conditions, and can also be used as a lining, an outer protective layer, a buffer layer, a reinforcing cushion layer and the like of other protection or packaging objects.

The invention is different from the manufacturing process and the using mode of the traditional gloves, the invention is different from people, customized, prepared and used at the present, the manufacturing and the wearing are finished at one time, the raw materials and the finished products are nontoxic and harmless, can be naturally degraded, and has strong practical value and wide application prospect.

Drawings

FIG. 1 is a schematic process flow diagram of a technical scheme;

FIG. 2 is a side view of a glove after manufacture;

FIG. 3 is a dorsal picture of a glove after it has been formed;

FIG. 4 is a side view of the palm of the hand with the glove removed;

fig. 5 is a dorsal picture of a glove when removed.

Detailed Description

The technical scheme of the invention is further explained by combining the attached drawings.

Example 1

In the embodiment, the component A, the component B and the component C comprise the following raw materials in parts by weight: 100 parts of a 20 wt% magnesium acrylate solution and 5 parts of a 10 wt% hydrogen peroxide solution (equivalent to 0.5 part of hydrogen peroxide); the component B comprises the following raw materials: 100 parts of a 20 wt% magnesium acrylate solution and 5 parts of a 3 wt% sodium hydrogen sulfite solution (equivalent to 0.15 parts of sodium hydrogen sulfite); the component C comprises the following raw materials: and 30 parts of 5 wt% sodium alginate solution.

The specific process flow is shown in figure 1:

(1) adding 5 parts of 10 wt% hydrogen peroxide solution into 100 parts of 20 wt% magnesium acrylate solution, and uniformly stirring to prepare a mixed solution A, namely a component A;

(2) adding 5 parts of 3 wt% sodium bisulfite solution into 100 parts of 20 wt% magnesium acrylate solution, and stirring uniformly to obtain mixed solution B to obtain component B;

(3) adding 30 parts of 5 wt% sodium alginate solution into deionized water, and stirring until the solution is uniform and transparent to prepare alginate solution C, namely component C;

(4) the hand surface is cleaned, then the mixed solution formed by quickly and uniformly mixing the component A, the component B and the component C is coated on the hand surface of a human body, and fingers are spread as far as possible in the coating process so as to prevent the fingers from approaching each other and being bonded together when the mixed solution is cured.

(5) Baking the hand coated with the mixed solution at the temperature of 40 ℃ for 15s, keeping the fingers open and turning the wrist during baking, and drying the surface of the whole glove to finish the manufacturing of the glove;

(6) after the gloves are used, the gloves are uncovered and taken off from the glove edges.

Example 2

In the embodiment, the component A, the component B and the component C comprise the following raw materials in parts by weight: 100 parts of a 30 wt% magnesium acrylate solution and 9 parts of a 10 wt% hydrogen peroxide solution (reduced to 0.9 part of hydrogen peroxide); the component B comprises the following raw materials: 100 parts of a 30 wt% magnesium acrylate solution and 10 parts of a 2.2 wt% sodium hydrogen sulfite solution (0.22 parts in terms of sodium hydrogen sulfite); the component C comprises the following raw materials: 30 parts of 5 wt% sodium alginate solution; the specific process flow is the same as that in example 1:

(1) adding 9 parts of 10 wt% hydrogen peroxide solution into 100 parts of 30 wt% magnesium acrylate solution, and uniformly stirring to prepare a mixed solution A, namely a component A;

(2) adding 10 parts of 2.2 wt% sodium bisulfite solution into 100 parts of 30 wt% magnesium acrylate solution, and stirring to obtain mixed solution B to obtain component B;

(3) adding 30 parts of 5 wt% sodium alginate solution into deionized water, and stirring until the solution is uniform and transparent to obtain alginate solution C, namely component C;

(4) the surface of the hand is cleaned, then the mixed solution formed by quickly and uniformly mixing the component A, the component B and the component C is coated on the surface of the hand of a human body, and fingers are spread as far as possible in the coating process so as to prevent the fingers from being close to each other and being bonded together when the mixed solution is cured.

(5) Baking the hand coated with the mixed solution at 40 ℃ for 15s, keeping fingers open and turning the wrist while baking, and drying the surface of the whole glove, thereby finishing the manufacturing of the glove;

(6) after the gloves are used, the gloves are uncovered and taken off from the glove edges.

Example 3

In the embodiment, the component A, the component B and the component C comprise the following raw materials in parts by weight: 100 parts of 38 wt% magnesium acrylate solution and 10 parts of 12 wt% hydrogen peroxide solution (1.2 parts in terms of hydrogen peroxide); the component B comprises the following raw materials: 100 parts of 38 wt% magnesium acrylate solution and 10 parts of 3 wt% sodium hydrogen sulfite solution (0.3 part in terms of sodium hydrogen sulfite); the component C comprises the following raw materials: 30 parts of 5 wt% sodium alginate solution; the specific process flow is the same as that in example 1:

(1) adding 10 parts of 12 wt% hydrogen peroxide solution into 100 parts of 38 wt% magnesium acrylate solution, and uniformly stirring to prepare a mixed solution A, namely a component A;

(2) adding 0.3 part of sodium bisulfite (10 parts of 3 wt% sodium bisulfite solution) into 100 parts of 38 wt% magnesium acrylate solution, and stirring to obtain mixed solution B to obtain component B;

(3) adding 30 parts of 5 wt% sodium alginate solution into deionized water, and stirring until the solution is uniform and transparent to prepare alginate solution C, namely component C;

(4) the surface of the hand is cleaned, then the mixed solution formed by quickly and uniformly mixing the component A, the component B and the component C is coated on the surface of the hand of a human body, and fingers are spread as far as possible in the coating process so as to prevent the fingers from being close to each other and being bonded together when the mixed solution is cured.

(5) Baking the hand coated with the mixed solution at the temperature of 40 ℃ for 15s, keeping the fingers open and turning the wrist during baking, and drying the surface of the whole glove to finish the manufacturing of the glove;

(6) after the gloves are used, the gloves are uncovered and taken off from the glove edges.

Example 4

In the embodiment, the component A, the component B and the component C comprise the following raw materials in parts by weight: 100 parts of a 20 wt% magnesium acrylate solution and 5 parts of a 10 wt% hydrogen peroxide solution (0.5 part as hydrogen peroxide); the component B comprises the following raw materials: 100 parts of a 20 wt% magnesium acrylate solution and 5 parts of a 3 wt% sodium hydrogen sulfite solution (0.15 parts in terms of sodium hydrogen sulfite); the component C comprises the following raw materials: 30 parts of 10 wt% sodium alginate solution; the specific process flow is the same as that in example 1:

(1) adding 10 wt% hydrogen peroxide solution into 100 parts of 20 wt% magnesium acrylate solution, and stirring uniformly to prepare a mixed solution A, namely a component A;

(2) adding 5 parts of 3 wt% sodium bisulfite solution into 100 parts of 20 wt% magnesium acrylate solution, and stirring to obtain mixed solution B to obtain component B;

(3) adding 30 parts of 10 wt% sodium alginate solution into deionized water, and stirring until the solution is uniform and transparent to prepare alginate solution C, namely component C;

(4) the surface of the hand is cleaned, then the mixed solution formed by quickly and uniformly mixing the component A, the component B and the component C is coated on the surface of the hand of a human body, and fingers are spread as far as possible in the coating process so as to prevent the fingers from being close to each other and being bonded together when the mixed solution is cured.

(5) Baking the hand coated with the mixed solution at 40 ℃ for 15s, keeping fingers open and turning the wrist while baking, and drying the surface of the whole glove, thereby finishing the manufacturing of the glove;

(6) after the gloves are used, the gloves are uncovered and taken off from the glove edges.

Example 5

In the embodiment, the component A, the component B and the component C comprise the following raw materials in parts by weight: 100 parts of a 30 wt% magnesium acrylate solution and 9 parts of a 10 wt% hydrogen peroxide solution (0.9 part as hydrogen peroxide); the component B comprises the following raw materials: 100 parts of a 30 wt% magnesium acrylate solution and 10 parts of a 2.2 wt% sodium hydrogen sulfite solution (0.22 parts in terms of sodium hydrogen sulfite); the component C comprises the following raw materials: 30 parts of 10 wt% sodium alginate solution; the specific process flow is the same as that in example 1:

(1) adding 9 parts of 10 wt% hydrogen peroxide solution into 100 parts of 30 wt% magnesium acrylate solution, and uniformly stirring to prepare a mixed solution A, namely a component A;

(2) adding 10 parts of 2.2 wt% sodium bisulfite solution into 100 parts of 30 wt% magnesium acrylate solution, and stirring to obtain mixed solution B to obtain component B;

(3) adding 30 parts of 10 wt% sodium alginate solution into deionized water, and stirring until the solution is uniform and transparent to prepare alginate solution C, namely component C;

(4) the hand surface is cleaned, then the mixed solution formed by quickly and uniformly mixing the component A, the component B and the component C is coated on the hand surface of a human body, and fingers are spread as far as possible in the coating process so as to prevent the fingers from approaching each other and being bonded together when the mixed solution is cured.

(5) Baking the hand coated with the mixed solution at 40 ℃ for 15s, keeping fingers open and turning the wrist while baking, and drying the surface of the whole glove, thereby finishing the manufacturing of the glove;

(6) after the gloves are used, the gloves are uncovered and taken off from the glove edges.

Example 6

In the embodiment, the component A, the component B and the component C comprise the following raw materials in parts by weight: 100 parts of 38 wt% magnesium acrylate solution and 10 parts of 12 wt% hydrogen peroxide solution (1.2 parts in terms of hydrogen peroxide); the component B comprises the following raw materials: 100 parts of 38 wt% magnesium acrylate solution and 10 parts of 3 wt% sodium hydrogen sulfite solution (0.3 part in terms of sodium hydrogen sulfite); the component C comprises the following raw materials: 30 parts of 10 wt% sodium alginate solution; the specific process flow is the same as that in example 1:

(1) adding 10 parts of 12 wt% hydrogen peroxide solution into 100 parts of 38 wt% magnesium acrylate solution, and uniformly stirring to prepare a mixed solution A, namely a component A;

(2) adding 10 parts of 3 wt% sodium bisulfite solution into 100 parts of 38 wt% magnesium acrylate solution, and stirring to obtain mixed solution B to obtain component B;

(3) adding 30 parts of 10 wt% sodium alginate solution into deionized water, and stirring until the solution is uniform and transparent to prepare alginate solution C, namely component C;

(4) the hand surface is cleaned, then the mixed solution formed by quickly and uniformly mixing the component A, the component B and the component C is coated on the hand surface of a human body, and fingers are spread as far as possible in the coating process so as to prevent the fingers from approaching each other and being bonded together when the mixed solution is cured.

(5) Baking the hand coated with the mixed solution at the temperature of 40 ℃ for 15s, keeping the fingers open and turning the wrist during baking, and drying the surface of the whole glove to finish the manufacturing of the glove;

(6) after the gloves are used, the gloves are uncovered and taken off from the glove edges.

Example 7

In the embodiment, the component A, the component B and the component C comprise the following raw materials in parts by weight: 100 parts of a 30 wt% magnesium acrylate solution and 9 parts of a 10 wt% hydrogen peroxide solution (0.9 part as hydrogen peroxide); the component B comprises the following raw materials: 100 parts of a 30 wt% magnesium acrylate solution, 10 parts of a 2.2 wt% sodium hydrogen sulfite solution (0.22 parts in terms of sodium hydrogen sulfite); the component C comprises the following raw materials: 20 parts of 5 wt% sodium alginate solution; the specific process flow is the same as that in example 1:

(1) adding 9 parts of 10 wt% hydrogen peroxide solution into 100 parts of 30 wt% magnesium acrylate solution, and uniformly stirring to prepare a mixed solution A, namely a component A;

(2) adding 10 parts of 2.2 wt% sodium bisulfite solution into 100 parts of 30 wt% magnesium acrylate solution, and stirring to obtain mixed solution B to obtain component B;

(3) adding 20 parts of 10 wt% sodium alginate solution into deionized water, and stirring until the solution is uniform and transparent to prepare alginate solution C, namely component C;

(4) the surface of the hand is cleaned, then the mixed solution formed by quickly and uniformly mixing the component A, the component B and the component C is coated on the surface of the hand of a human body, and fingers are spread as far as possible in the coating process so as to prevent the fingers from being close to each other and being bonded together when the mixed solution is cured.

(5) Baking the hand coated with the mixed solution at the temperature of 40 ℃ for 15s, keeping the fingers open and turning the wrist during baking, and drying the surface of the whole glove to finish the manufacturing of the glove;

(6) after the gloves are used, the gloves are uncovered and taken off from the glove edges.

Example 8

In the embodiment, the component A, the component B and the component C comprise the following raw materials in parts by weight: 100 parts of a 30 wt% magnesium acrylate solution and 9 parts of a 10 wt% hydrogen peroxide solution (reduced to 0.9 part of hydrogen peroxide); the component B comprises the following raw materials: 100 parts of a 30 wt% magnesium acrylate solution and 10 parts of a 2.2 wt% sodium hydrogen sulfite solution (0.22 parts in terms of sodium hydrogen sulfite); the component C comprises the following raw materials: 50 parts of 5 wt% sodium alginate solution; the specific process flow is the same as that in example 1:

(1) adding 9 parts of 10 wt% hydrogen peroxide solution into 100 parts of 30 wt% magnesium acrylate solution, and uniformly stirring to prepare a mixed solution A, namely a component A;

(2) adding 10 parts of 2.2 wt% sodium bisulfite solution into 100 parts of 30 wt% magnesium acrylate solution, and stirring to obtain mixed solution B to obtain component B;

(3) adding 50 parts of 5 wt% sodium alginate solution into deionized water, and stirring until the solution is uniform and transparent to prepare alginate solution C, namely component C;

(4) the surface of the hand is cleaned, then the mixed solution formed by quickly and uniformly mixing the component A, the component B and the component C is coated on the surface of the hand of a human body, and fingers are spread as far as possible in the coating process so as to prevent the fingers from being close to each other and being bonded together when the mixed solution is cured.

(5) Baking the hand coated with the mixed solution at the temperature of 40 ℃ for 15s, keeping the fingers open and turning the wrist during baking, and drying the surface of the whole glove to finish the manufacturing of the glove;

(6) after the gloves are used, the gloves are uncovered and taken off from the glove edges.

Example 9

The real-time curing molding glove material comprises a component A, a component B and a component C, wherein the component A comprises the following raw materials in parts by weight: 100 parts of a 30 wt% magnesium acrylate solution and 1 part of a 10 wt% hydrogen peroxide solution (0.1 part as hydrogen peroxide); the component B comprises the following raw materials: 100 parts of a 30 wt% magnesium acrylate solution and 1 part of a 3 wt% sodium hydrogen sulfite solution (0.03 parts in terms of sodium hydrogen sulfite); the component C comprises the following raw materials: 30 parts of 5 wt% sodium alginate solution; the specific process flow is the same as that in example 1:

(1) adding 1 part of 10 wt% hydrogen peroxide solution into 100 parts of 30 wt% magnesium acrylate solution, and uniformly stirring to prepare a mixed solution A, namely a component A;

(2) adding 1 part of 3 wt% sodium bisulfite solution into 100 parts of 30 wt% magnesium acrylate solution, and stirring to obtain mixed solution B to obtain component B;

(3) adding 30 parts of 5 wt% sodium alginate solution into deionized water, and stirring until the solution is uniform and transparent to prepare alginate solution C, namely component C;

(4) the hand surface is cleaned, then the mixed solution formed by quickly and uniformly mixing the component A, the component B and the component C is coated on the hand surface of a human body, and fingers are spread as far as possible in the coating process so as to prevent the fingers from approaching each other and being bonded together when the mixed solution is cured.

(5) Baking the hand coated with the mixed solution at the temperature of 30 ℃ for 30s, keeping the fingers open and turning the wrist during baking, and drying the surface of the whole glove to finish the manufacturing of the glove;

(6) after the gloves are used, the gloves are uncovered and taken off from the glove edges.

Example 10

The real-time curing molding glove material comprises a component A, a component B and a component C, wherein the component A comprises the following raw materials in parts by weight: 100 parts of a 30 wt% magnesium acrylate solution and 10 parts of a 13 wt% hydrogen peroxide solution (1.3 parts as hydrogen peroxide); the component B comprises the following raw materials: 100 parts of a 30 wt% magnesium acrylate solution and 10 parts of a 2.5 wt% sodium hydrogen sulfite solution (reduced to 0.25 part of sodium hydrogen sulfite); the component C comprises the following raw materials: 30 parts of 5 wt% sodium alginate solution; the specific process flow is the same as that in example 1:

(1) adding 10 parts of 13 wt% hydrogen peroxide solution into 100 parts of 30 wt% magnesium acrylate solution), and uniformly stirring to prepare a mixed solution A, namely a component A;

(2) adding 10 parts of 2.5 wt% sodium bisulfite solution into 100 parts of 30 wt% magnesium acrylate solution, and stirring to obtain mixed solution B to obtain component B;

(3) adding 30 parts of 5 wt% sodium alginate solution into deionized water, and stirring until the solution is uniform and transparent to prepare alginate solution C, namely component C;

(4) the surface of the hand is cleaned, then the mixed solution formed by quickly and uniformly mixing the component A, the component B and the component C is coated on the surface of the hand of a human body, and fingers are spread as far as possible in the coating process so as to prevent the fingers from being close to each other and being bonded together when the mixed solution is cured.

(5) Baking the hand coated with the mixed solution at 45 ℃ for 5s, keeping the fingers open and turning the wrist during baking, and drying the surface of the whole glove to finish the manufacturing of the glove;

(6) after the gloves are used, the gloves are uncovered and taken off from the glove edges.

Comparative example 1

In the embodiment, the component A, the component B and the component C comprise the following raw materials in parts by weight: 100 parts of a 20 wt% magnesium acrylate solution and 5 parts of a 10 wt% hydrogen peroxide solution (0.5 part as hydrogen peroxide); the component B comprises the following raw materials: 100 parts of a 20 wt% magnesium acrylate solution and 5 parts of a 3 wt% sodium hydrogen sulfite solution (0.15 parts in terms of sodium hydrogen sulfite); the component C comprises the following raw materials: 0 part of sodium alginate solution; the specific process flow is the same as that in example 1:

(1) adding 5 parts of 10 wt% hydrogen peroxide solution into 100 parts of 20 wt% magnesium acrylate solution, and uniformly stirring to prepare a mixed solution A, namely a component A;

(2) adding 5 parts of 3 wt% sodium bisulfite solution into 100 parts of 20 wt% magnesium acrylate solution, and stirring to obtain mixed solution B to obtain component B;

(3) the hand surface is cleaned, then the mixed solution formed by quickly and uniformly mixing the component A and the component B is coated on the hand surface of a human body, and fingers are spread as far as possible in the coating process so as to prevent the fingers from approaching each other and being bonded together when the mixed solution is cured.

(4) Baking the hand coated with the mixed solution at the temperature of 40 ℃ for 15s, keeping the fingers open and turning the wrist during baking, and drying the surface of the whole glove to finish the manufacturing of the glove;

(5) after the gloves are used, the gloves are uncovered and taken off from the glove edges.

Comparative example 2

In the embodiment, the component A, the component B and the component C comprise the following raw materials in parts by weight: 100 parts of a 30 wt% magnesium acrylate solution and 10 parts of a 9 wt% hydrogen peroxide solution (0.9 part as hydrogen peroxide); the component B comprises the following raw materials: 100 parts of a 30 wt% magnesium acrylate solution, 10 parts of a 2.2 wt% sodium hydrogen sulfite solution (0.22 parts in terms of sodium hydrogen sulfite); the component C comprises the following raw materials: 0 part of sodium alginate solution; the specific process flow is the same as that in example 1:

(1) adding 10 parts of 9 wt% hydrogen peroxide solution into 100 parts of 30 wt% magnesium acrylate solution, and uniformly stirring to prepare a mixed solution A, namely a component A;

(2) adding 10 parts of 2.2 wt% sodium bisulfite solution into 100 parts of 30 wt% magnesium acrylate solution, and stirring to obtain mixed solution B to obtain component B;

(3) the hand surface is cleaned, then the mixed solution formed by quickly and uniformly mixing the component A and the component B is coated on the hand surface of a human body, and fingers are spread as far as possible in the coating process so as to prevent the fingers from approaching each other and being bonded together when the mixed solution is cured.

(4) Baking the hand coated with the mixed solution at 40 ℃ for 15s, keeping fingers open and turning the wrist while baking, and drying the surface of the whole glove, thereby finishing the manufacturing of the glove;

(5) after the gloves are used, the gloves are uncovered and taken off from the glove edges.

Comparative example 3

In the embodiment, the component A, the component B and the component C comprise the following raw materials in parts by weight: 100 parts of 38 wt% magnesium acrylate solution and 10 parts of 12 wt% hydrogen peroxide solution (1.2 parts in terms of hydrogen peroxide); the component B comprises the following raw materials: 100 parts of 38 wt% magnesium acrylate solution and 10 parts of 3 wt% sodium hydrogen sulfite solution (0.3 part in terms of sodium hydrogen sulfite); the component C comprises the following raw materials: 0 part of sodium alginate solution; the specific process flow is the same as that in example 1:

(1) adding 10 parts of 12 wt% hydrogen peroxide solution into 100 parts of 38 wt% magnesium acrylate solution, and uniformly stirring to prepare a mixed solution A, namely a component A;

(2) adding 10 parts of 3 wt% sodium bisulfite solution into 100 parts of 38 wt% magnesium acrylate solution, and stirring to obtain mixed solution B to obtain component B;

(3) the hand surface is cleaned, then the mixed solution formed by quickly and uniformly mixing the component A and the component B is coated on the hand surface of a human body, and fingers are spread as far as possible in the coating process so as to prevent the fingers from approaching each other and being bonded together when the mixed solution is cured.

(4) Baking the hand coated with the mixed solution at the temperature of 40 ℃ for 15s, keeping the fingers open and turning the wrist during baking, and drying the surface of the whole glove to finish the manufacturing of the glove;

(5) after the gloves are used, the gloves are uncovered and taken off from the glove edges.

Example 11

In the embodiment, the component A, the component B and the component C comprise the following raw materials in parts by weight: 100 parts of a 30 wt% calcium acrylate solution and 9 parts of a 10 wt% hydrogen peroxide solution (0.9 part as hydrogen peroxide); the component B comprises the following raw materials: 100 parts of a 30 wt% calcium acrylate solution and 10 parts of a 2.2 wt% sodium hydrogen sulfite solution (0.22 parts in terms of sodium hydrogen sulfite); the component C comprises the following raw materials: 30 parts of 5 wt% sodium alginate solution; the specific process flow is the same as that in example 1:

(1) adding 9 parts of 10 wt% hydrogen peroxide solution into 100 parts of 30 wt% calcium acrylate solution, and uniformly stirring to prepare a mixed solution A, namely a component A;

(2) adding 10 parts of 2.2 wt% sodium bisulfite solution into 100 parts of 30 wt% calcium acrylate solution, and stirring uniformly to obtain a mixed solution B, namely a component B;

(3) adding 30 parts of 5 wt% sodium alginate solution into deionized water, and stirring until the solution is uniform and transparent to prepare alginate solution C, namely component C;

(4) the surface of the hand is cleaned, then the mixed solution formed by quickly and uniformly mixing the component A, the component B and the component C is coated on the surface of the hand of a human body, and fingers are spread as far as possible in the coating process so as to prevent the fingers from being close to each other and being bonded together when the mixed solution is cured.

(5) Baking the hand coated with the mixed solution at the temperature of 40 ℃ for 15s, keeping the fingers open and turning the wrist during baking, and drying the surface of the whole glove to finish the manufacturing of the glove;

(6) after the gloves are used, the gloves are uncovered and taken off from the glove edges.

Example 12

In the embodiment, the component A, the component B and the component C comprise the following raw materials in parts by weight: 100 parts of a 30 wt% barium acrylate solution and 9 parts of a 10 wt% hydrogen peroxide solution (0.9 part in terms of hydrogen peroxide); the component B comprises the following raw materials: 100 parts of a 30 wt% barium acrylate solution and 10 parts of a 2.2 wt% sodium hydrogen sulfite solution (0.22 parts in terms of sodium hydrogen sulfite); the component C comprises the following raw materials: 30 parts of 5 wt% sodium alginate solution; the specific process flow is the same as that in example 1:

(1) uniformly stirring 9 parts of 10 wt% hydrogen peroxide solution in 100 parts of 30 wt% barium acrylate solution to prepare a mixed solution A, thus obtaining a component A;

(2) adding 10 parts of 2.2 wt% sodium bisulfite solution into 100 parts of 30 wt% barium acrylate solution, and uniformly stirring to prepare a mixed solution B, namely a component B;

(3) adding 30 parts of 5 wt% sodium alginate solution into deionized water, and stirring until the solution is uniform and transparent to prepare alginate solution C, namely component C;

(4) the surface of the hand is cleaned, then the mixed solution formed by quickly and uniformly mixing the component A, the component B and the component C is coated on the surface of the hand of a human body, and fingers are spread as far as possible in the coating process so as to prevent the fingers from being close to each other and being bonded together when the mixed solution is cured.

(5) Baking the hand coated with the mixed solution at 40 ℃ for 15s, keeping fingers open and turning the wrist while baking, and drying the surface of the whole glove, thereby finishing the manufacturing of the glove;

(6) after the gloves are used, the gloves are uncovered and taken off from the glove edges.

Example 13

In the embodiment, the component A, the component B and the component C comprise the following raw materials in parts by weight: 100 parts of a 30 wt% iron acrylate solution and 9 parts of a 10 wt% hydrogen peroxide solution (0.9 part in terms of hydrogen peroxide); the component B comprises the following raw materials: 100 parts of a 30 wt% iron acrylate solution, 10 parts of a 2.2 wt% sodium hydrogen sulfite solution (0.22 part in terms of sodium hydrogen sulfite); the component C comprises the following raw materials: 30 parts of 5 wt% sodium alginate solution; the specific process flow is the same as that in example 1:

(1) adding 9 parts of 10 wt% hydrogen peroxide solution into 100 parts of 30 wt% ferric acrylate solution, and uniformly stirring to prepare a mixed solution A, namely a component A;

(2) adding 10 parts of 2.2 wt% sodium bisulfite solution into 100 parts of 30 wt% ferric acrylate solution, and stirring to obtain mixed solution B to obtain component B;

(3) adding 30 parts of 5 wt% sodium alginate solution into deionized water, and stirring until the solution is uniform and transparent to obtain alginate solution C, namely component C;

(4) the surface of the hand is cleaned, then the mixed solution formed by quickly and uniformly mixing the component A, the component B and the component C is coated on the surface of the hand of a human body, and fingers are spread as far as possible in the coating process so as to prevent the fingers from being close to each other and being bonded together when the mixed solution is cured.

(5) Baking the hand coated with the mixed solution at the temperature of 40 ℃ for 15s, keeping the fingers open and turning the wrist during baking, and drying the surface of the whole glove to finish the manufacturing of the glove;

(6) after the gloves are used, the gloves are uncovered and taken off from the glove edges.

Example 14

In the embodiment, the component A, the component B and the component C comprise the following raw materials in parts by weight: 100 parts of a 30 wt% zinc acrylate solution and 9 parts of a 10 wt% hydrogen peroxide solution (0.9 part as hydrogen peroxide); the component B comprises the following raw materials: 100 parts of a 30 wt% zinc acrylate solution and 10 parts of a 2.2 wt% sodium hydrogen sulfite solution (0.22 parts in terms of sodium hydrogen sulfite); the component C comprises the following raw materials: 30 parts of 5 wt% sodium alginate solution; the specific process flow is the same as that in example 1:

(1) adding 9 parts of 10 wt% hydrogen peroxide solution into 100 parts of 30 wt% zinc acrylate solution, and uniformly stirring to prepare a mixed solution A, namely a component A;

(2) adding 10 parts of 2.2 wt% sodium bisulfite solution into 100 parts of 30 wt% zinc acrylate solution, and stirring uniformly to obtain mixed solution B to obtain component B;

(3) adding 30 parts of 5 wt% sodium alginate solution into deionized water, and stirring until the solution is uniform and transparent to prepare alginate solution C, namely component C;

(4) the surface of the hand is cleaned, then the mixed solution formed by quickly and uniformly mixing the component A, the component B and the component C is coated on the surface of the hand of a human body, and fingers are spread as far as possible in the coating process so as to prevent the fingers from being close to each other and being bonded together when the mixed solution is cured.

(5) Baking the hand coated with the mixed solution at the temperature of 40 ℃ for 15s, keeping the fingers open and turning the wrist during baking, and drying the surface of the whole glove to finish the manufacturing of the glove;

(6) after the gloves are used, the gloves are uncovered and taken off from the glove edges.

Example 15

In the embodiment, the component A, the component B and the component C comprise the following raw materials in parts by weight: 100 parts of a 30 wt% aluminum acrylate solution and 9 parts of a 10 wt% hydrogen peroxide solution (0.9 part in terms of hydrogen peroxide); the component B comprises the following raw materials: 100 parts of a 30 wt% aluminum acrylate solution and 10 parts of a 2.2 wt% sodium hydrogen sulfite solution (0.22 parts in terms of sodium hydrogen sulfite); the component C comprises the following raw materials: 30 parts of 5 wt% sodium alginate solution; the specific process flow is the same as that in example 1:

(1) adding 9 parts of 10 wt% hydrogen peroxide solution into 100 parts of 30 wt% aluminum acrylate solution, and uniformly stirring to prepare a mixed solution A, namely a component A;

(2) adding 10 parts of 2.2 wt% sodium bisulfite solution into 100 parts of 30 wt% aluminum acrylate solution, and stirring uniformly to obtain a mixed solution B, namely a component B;

(3) adding 30 parts of 5 wt% sodium alginate solution into deionized water, and stirring until the solution is uniform and transparent to prepare alginate solution C, namely component C;

(4) the surface of the hand is cleaned, then the mixed solution formed by quickly and uniformly mixing the component A, the component B and the component C is coated on the surface of the hand of a human body, and fingers are spread as far as possible in the coating process so as to prevent the fingers from being close to each other and being bonded together when the mixed solution is cured.

(5) Baking the hand coated with the mixed solution at 40 ℃ for 15s, keeping fingers open and turning the wrist while baking, and drying the surface of the whole glove, thereby finishing the manufacturing of the glove;

(6) after the gloves are used, the gloves are uncovered and taken off from the glove edges.

Example 16

In the embodiment, the component A, the component B and the component C comprise the following raw materials in parts by weight: 100 parts of a 30 wt% magnesium acrylate solution, 9 parts of a 10 wt% ammonium persulfate solution (equivalent to 0.9 part of ammonium persulfate); the component B comprises the following raw materials: 100 parts of a 30 wt% magnesium acrylate solution, 10 parts of a 2.2 wt% sodium hydrogen sulfite solution (0.22 parts in terms of sodium hydrogen sulfite); the component C comprises the following raw materials: 30 parts of 5 wt% sodium alginate solution; the specific process flow is the same as that in example 1:

(1) adding 9 parts of 10 wt% ammonium persulfate solution into 100 parts of 30 wt% magnesium acrylate solution, and uniformly stirring to prepare a mixed solution A, namely a component A;

(2) adding 10 parts of 2.2 wt% sodium bisulfite solution into 100 parts of 30 wt% magnesium acrylate solution, and stirring to obtain mixed solution B to obtain component B;

(3) adding 30 parts of 5 wt% sodium alginate solution into deionized water, and stirring until the solution is uniform and transparent to obtain alginate solution C, namely component C;

(4) the hand surface is cleaned, then the mixed solution formed by quickly and uniformly mixing the component A, the component B and the component C is coated on the hand surface of a human body, and fingers are spread as far as possible in the coating process so as to prevent the fingers from approaching each other and being bonded together when the mixed solution is cured.

(5) Baking the hand coated with the mixed solution at 40 ℃ for 15s, keeping fingers open and turning the wrist while baking, and drying the surface of the whole glove, thereby finishing the manufacturing of the glove;

(6) after the gloves are used, the gloves are uncovered and taken off from the glove edges.

Example 17

In the embodiment, the component A, the component B and the component C comprise the following raw materials in parts by weight: 100 parts of a 30 wt% magnesium acrylate solution and 9 parts of a 10 wt% sodium persulfate solution (equivalent to 0.9 parts of sodium persulfate); the component B comprises the following raw materials: 100 parts of a 30 wt% magnesium acrylate solution and 10 parts of a 2.2 wt% sodium hydrogen sulfite solution (0.22 parts in terms of sodium hydrogen sulfite); the component C comprises the following raw materials: 30 parts of 5 wt% sodium alginate solution; the specific process flow is the same as that in example 1:

(1) adding 9 parts of 10 wt% sodium persulfate solution into 100 parts of 30 wt% magnesium acrylate solution, and uniformly stirring to prepare a mixed solution A, namely a component A;

(2) adding 10 parts of 2.2 wt% sodium bisulfite solution into 100 parts of 30 wt% magnesium acrylate solution, and stirring to obtain mixed solution B to obtain component B;

(3) adding 30 parts of 5 wt% sodium alginate solution into deionized water, and stirring until the solution is uniform and transparent to prepare alginate solution C, namely component C;

(4) the surface of the hand is cleaned, then the mixed solution formed by quickly and uniformly mixing the component A, the component B and the component C is coated on the surface of the hand of a human body, and fingers are spread as far as possible in the coating process so as to prevent the fingers from being close to each other and being bonded together when the mixed solution is cured.

(5) Baking the hand coated with the mixed solution at the temperature of 40 ℃ for 15s, keeping the fingers open and turning the wrist during baking, and drying the surface of the whole glove to finish the manufacturing of the glove;

(6) after the gloves are used, the gloves are uncovered and taken off from the glove edges.

Example 18

In the embodiment, the component A, the component B and the component C comprise the following raw materials in parts by weight: 100 parts of 30 wt% magnesium acrylate solution and 9 parts of 10 wt% potassium persulfate solution (equivalent to 0.9 part of potassium persulfate); the component B comprises the following raw materials: 100 parts of a 30 wt% magnesium acrylate solution and 10 parts of a 2.2 wt% sodium hydrogen sulfite solution (0.22 parts in terms of sodium hydrogen sulfite); the component C comprises the following raw materials: 30 parts of 5 wt% sodium alginate solution; the specific process flow is the same as that in example 1:

(1) adding 9 parts of 10 wt% potassium persulfate solution into 100 parts of 30 wt% magnesium acrylate solution, and uniformly stirring to prepare a mixed solution A, namely a component A;

(2) adding 10 parts of 2.2 wt% sodium bisulfite solution into 100 parts of 30 wt% magnesium acrylate solution, and stirring to obtain mixed solution B to obtain component B;

(3) adding 30 parts of 5 wt% sodium alginate solution into deionized water, and stirring until the solution is uniform and transparent to prepare alginate solution C, namely component C;

(4) the surface of the hand is cleaned, then the mixed solution formed by quickly and uniformly mixing the component A, the component B and the component C is coated on the surface of the hand of a human body, and fingers are spread as far as possible in the coating process so as to prevent the fingers from being close to each other and being bonded together when the mixed solution is cured.

(5) Baking the hand coated with the mixed solution at 40 ℃ for 15s, keeping fingers open and turning the wrist while baking, and drying the surface of the whole glove, thereby finishing the manufacturing of the glove;

(6) after the gloves are used, the gloves are uncovered and taken off from the glove edges.

Example 19

In the embodiment, the component A, the component B and the component C comprise the following raw materials in parts by weight: 100 parts of a 30 wt% magnesium acrylate solution and 9 parts of a 10 wt% hydrogen peroxide solution (0.9 part as hydrogen peroxide); the component B comprises the following raw materials: 100 parts of 30 wt% magnesium acrylate solution and 10 parts of 2.2 wt% ferrous sulfate solution (0.22 parts in terms of ferrous sulfate); the component C comprises the following raw materials: 30 parts of 5 wt% sodium alginate solution; the specific process flow is the same as that in example 1:

(1) adding 9 parts of 10 wt% hydrogen peroxide solution into 100 parts of 30 wt% magnesium acrylate solution, and uniformly stirring to prepare a mixed solution A, namely a component A;

(2) adding 10 parts of 2.2 wt% ferrous sulfate solution into 100 parts of 30 wt% magnesium acrylate solution, and uniformly stirring to prepare a mixed solution B, namely a component B;

(3) adding 30 parts of 5 wt% sodium alginate solution into deionized water, and stirring until the solution is uniform and transparent to obtain alginate solution C, namely component C;

(4) the surface of the hand is cleaned, then the mixed solution formed by quickly and uniformly mixing the component A, the component B and the component C is coated on the surface of the hand of a human body, and fingers are spread as far as possible in the coating process so as to prevent the fingers from being close to each other and being bonded together when the mixed solution is cured.

(5) Baking the hand coated with the mixed solution at the temperature of 40 ℃ for 15s, keeping the fingers open and turning the wrist during baking, and drying the surface of the whole glove to finish the manufacturing of the glove;

(6) after the gloves are used, the gloves are uncovered and taken off from the glove edges.

Example 20

In the embodiment, the component A, the component B and the component C comprise the following raw materials in parts by weight: 100 parts of a 30 wt% magnesium acrylate solution and 9 parts of a 10 wt% hydrogen peroxide solution (0.9 part as hydrogen peroxide); the component B comprises the following raw materials: 100 parts of a 30 wt% magnesium acrylate solution and 10 parts of a 2.2 wt% ammonium bisulfite solution (0.22 parts in terms of ammonium bisulfite); the component C comprises the following raw materials: 30 parts of 5 wt% sodium alginate solution; the specific process flow is the same as that in example 1:

(1) adding 9 parts of 10 wt% hydrogen peroxide solution into 100 parts of 30 wt% magnesium acrylate solution, and uniformly stirring to prepare a mixed solution A, namely a component A;

(2) adding 10 parts of 2.2 wt% ammonium bisulfite solution into 100 parts of 30 wt% magnesium acrylate solution, and stirring to obtain mixed solution B to obtain component B;

(3) adding 30 parts of 5 wt% sodium alginate solution into deionized water, and stirring until the solution is uniform and transparent to obtain alginate solution C, namely component C;

(4) the surface of the hand is cleaned, then the mixed solution formed by quickly and uniformly mixing the component A, the component B and the component C is coated on the surface of the hand of a human body, and fingers are spread as far as possible in the coating process so as to prevent the fingers from being close to each other and being bonded together when the mixed solution is cured.

(5) Baking the hand coated with the mixed solution at the temperature of 40 ℃ for 15s, keeping the fingers open and turning the wrist during baking, and drying the surface of the whole glove to finish the manufacturing of the glove;

(6) after the gloves are used, the gloves are uncovered and taken off from the glove edges.

Example 21

In the embodiment, the component A, the component B and the component C comprise the following raw materials in parts by weight: 100 parts of a 30 wt% magnesium acrylate solution and 9 parts of a 10 wt% hydrogen peroxide solution (0.9 part as hydrogen peroxide); the component B comprises the following raw materials: 100 parts of a 30 wt% magnesium acrylate solution, 10 parts of a 2.2 wt% sodium sulfite solution (0.22 parts as sodium sulfite); the component C comprises the following raw materials: 30 parts of 5 wt% sodium alginate solution; the specific process flow is the same as that in example 1:

(1) adding 9 parts of 10 wt% hydrogen peroxide solution into 100 parts of 30 wt% magnesium acrylate solution, and uniformly stirring to prepare a mixed solution A, namely a component A;

(2) adding 10 parts of 2.2 wt% sodium sulfite solution into 100 parts of 30 wt% magnesium acrylate solution, and uniformly stirring to prepare a mixed solution B, namely a component B;

(3) adding 30 parts of 5 wt% sodium alginate solution into deionized water, and stirring until the solution is uniform and transparent to prepare alginate solution C, namely component C;

(4) the surface of the hand is cleaned, then the mixed solution formed by quickly and uniformly mixing the component A, the component B and the component C is coated on the surface of the hand of a human body, and fingers are spread as far as possible in the coating process so as to prevent the fingers from being close to each other and being bonded together when the mixed solution is cured.

(5) Baking the hand coated with the mixed solution at the temperature of 40 ℃ for 15s, keeping the fingers open and turning the wrist during baking, and drying the surface of the whole glove to finish the manufacturing of the glove;

(6) after the gloves are used, the gloves are uncovered and taken off from the glove edges.

Example 22

In the embodiment, the component A, the component B and the component C comprise the following raw materials in parts by weight: 100 parts of a 30 wt% magnesium acrylate solution and 9 parts of a 10 wt% hydrogen peroxide solution (0.9 part as hydrogen peroxide); the component B comprises the following raw materials: 100 parts of a 30 wt% magnesium acrylate solution and 10 parts of a 2.2 wt% sodium thiosulfate solution (0.22 parts in terms of sodium thiosulfate); the component C comprises the following raw materials: 30 parts of 5 wt% sodium alginate solution; the specific process flow is the same as that in example 1:

(1) adding 9 parts of 10 wt% hydrogen peroxide solution into 100 parts of 30 wt% magnesium acrylate solution, and uniformly stirring to prepare a mixed solution A, namely a component A;

(2) adding 10 parts of 2.2 wt% sodium thiosulfate solution into 100 parts of 30 wt% magnesium acrylate solution, and uniformly stirring to prepare a mixed solution B, namely a component B;

(3) adding 30 parts of 5 wt% sodium alginate solution into deionized water, and stirring until the solution is uniform and transparent to obtain alginate solution C, namely component C;

(4) the surface of the hand is cleaned, then the mixed solution formed by quickly and uniformly mixing the component A, the component B and the component C is coated on the surface of the hand of a human body, and fingers are spread as far as possible in the coating process so as to prevent the fingers from being close to each other and being bonded together when the mixed solution is cured.

(5) Baking the hand coated with the mixed solution at the temperature of 40 ℃ for 15s, keeping the fingers open and turning the wrist during baking, and drying the surface of the whole glove to finish the manufacturing of the glove;

(6) after the gloves are used, the gloves are uncovered and taken off from the glove edges.

Example 23

In the embodiment, the component A, the component B and the component C comprise the following raw materials in parts by weight: 50 parts of a 30 wt% magnesium acrylate solution, 50 parts of a 30 wt% calcium acrylate solution, 3 parts of a 10 wt% hydrogen peroxide solution (0.3 part in terms of hydrogen peroxide), and 6 parts of a 10 wt% potassium persulfate solution (0.6 part in terms of potassium persulfate); the component B comprises the following raw materials: 70 parts of a 30 wt% barium acrylate solution, 30 parts of a 30 wt% zinc acrylate solution, 1 part of a 10 wt% sodium thiosulfate solution (0.10 parts in terms of sodium hydrogen sulfite), and 1 part of a 12 wt% sodium thiosulfate solution (0.12 parts in terms of sodium thiosulfate); the component C comprises the following raw materials: 30 parts of 5 wt% sodium alginate solution; the specific process flow is the same as that in example 1:

(1) uniformly mixing 50 parts of 30 wt% magnesium acrylate solution and 50 parts of 30 wt% calcium acrylate solution, adding 3 parts of 10 wt% hydrogen peroxide solution and 6 parts of 10 wt% potassium persulfate solution, and uniformly stirring to prepare a mixed solution A, thus obtaining a component A;

(2) uniformly mixing 70 parts of 30 wt% barium acrylate solution and 30 parts of 30 wt% zinc acrylate solution, adding 1 part of 10 wt% sodium thiosulfate solution and 1 part of 12 wt% sodium thiosulfate solution, and uniformly stirring to prepare a mixed solution B, thus obtaining a component B;

(3) adding 30 parts of 5 wt% sodium alginate solution into deionized water, and stirring until the solution is uniform and transparent to prepare alginate solution C, namely component C;

(4) the surface of the hand is cleaned, then the mixed solution formed by quickly and uniformly mixing the component A, the component B and the component C is coated on the surface of the hand of a human body, and fingers are spread as far as possible in the coating process so as to prevent the fingers from being close to each other and being bonded together when the mixed solution is cured.

(5) Baking the hand coated with the mixed solution at 40 ℃ for 15s, keeping fingers open and turning the wrist while baking, and drying the surface of the whole glove, thereby finishing the manufacturing of the glove;

(6) after the gloves are used, the gloves are uncovered and taken off from the glove edges.

The formulations of the components A, B and C of examples 1-23 and comparative examples 1-3 are shown in Table 1, and the performance test results of the instant curing gloves of examples 1-23 and comparative examples 1-3 are shown in Table 2.

TABLE 1 ingredient tables for component A, component B and component C in examples 1-23 and comparative examples 1-3

Note: in Table 1, the acrylate solutions of the component A and the component B are 100 parts.

TABLE 2 glove Properties obtained in examples 1-23 and comparative examples 1-3

From examples 1 to 10 it can be seen that: with the increase of the contents of the acrylate monomer and the alginate, the invention is beneficial to improving the tensile strength and the tearing strength of the glove material, and the higher content of the acrylate monomer is beneficial to shortening the curing time of the glove material;

as can be seen from the comparison between examples 1-3 and comparative examples 1-3, the alginate-free acrylate polymer material in comparative examples 1-3 has strong viscosity, is easy to adhere to the contacted object, has different parts adhered and fused with each other on the surface, has longer curing time, and obviously reduces the tensile strength, the elongation at break and the tearing strength. The surface of the glove formed by synchronously polymerizing the alginate and the acrylate is not adhered to the contacted object, and different parts on the surface are not adhered and fused with each other, so that unnecessary adhesion between different parts of the glove body or between the glove body and the contacted object can be prevented. And the curing time can be effectively reduced, and the tensile strength, the elongation at break and the tearing strength of the glove are enhanced.

As can be seen from example 2 and examples 11 to 23, one or more divalent or higher acrylates are polymerizable under different kinds of oxidizing and reducing agents, and have a small fluctuation in the influence on the material properties.

Claims (10)

1. An instant film-forming material is characterized in that the instant film-forming material is obtained by mixing a component A containing an oxidant and an acrylate solution, a component B containing a reducing agent and the acrylate solution and a component C containing an alginate solution.

2. The instant film-forming material according to claim 1, wherein the component A comprises the following components in parts by weight: 100 parts of acrylate solution and 0.1-15 parts of oxidant solution, wherein the component B comprises the following components in parts by weight: 100 parts of acrylate solution and 0.1-15 parts of reducing agent solution, wherein the component C comprises the following components in parts by weight: 20-50 parts of alginate solution.

3. The instant film-forming material according to claim 1, wherein the concentration of the acrylate solution in both the component A and the component B is 18-40 wt%; the concentration of the oxidant solution is 1-30 wt%, the concentration of the reducing agent solution is 1-30 wt%, and the concentration of the alginate solution in the component C is 1-10 wt%.

4. The instant film-forming material of claim 1, wherein the acrylate is a divalent acrylate or a higher acrylate.

5. The instant film-forming material according to claim 4, wherein the acrylate is one or more of magnesium acrylate, calcium acrylate, barium acrylate, iron acrylate, zinc acrylate, and aluminum acrylate.

6. The instant film-forming material according to claim 1, wherein the oxidant is one or more of hydrogen peroxide, ammonium persulfate, sodium persulfate and potassium persulfate, and the reducing agent is one or more of ferrous sulfate, sodium bisulfite, sodium sulfite and sodium thiosulfate.

7. The instant film-forming material of claim 1, wherein the alginate is a monovalent alginate.

8. A process for preparing an instant film-forming material according to any one of claims 1 to 7, comprising the steps of:

(1) adding an oxidant solution into the acrylate solution, and uniformly stirring to prepare a mixed solution A, namely a component A;

(2) adding a reducing agent solution into the acrylate solution, and uniformly stirring to prepare a mixed solution B, namely a component B;

(3) adding alginate into deionized water, stirring until uniform and transparent, and making into alginate solution C to obtain component C;

(4) the component A, the component B and the component C are quickly and uniformly mixed to form a mixed solution, namely the instant film-forming material.

9. Use of the instant film-forming material of any one of claims 1 to 7 in the preparation of a real-time cured shaped glove.

10. A method of using the instant film-forming material of claim 9 in the preparation of a real-time cured, shaped glove, comprising the steps of:

(1) adding oxidant solution into acrylate solution, and stirring uniformly to prepare mixed solution A, namely component A;

(2) adding a reducing agent solution into the acrylate solution, and uniformly stirring to prepare a mixed solution B, namely a component B;

(3) adding alginate into deionized water, stirring until uniform and transparent, and making into alginate solution C to obtain component C;

(4) cleaning the surface of a hand, quickly and uniformly mixing the component A, the component B and the component C to form a mixed solution, coating the mixed solution on the surface of the hand to a required length, and stretching fingers in the coating process so as to prevent the fingers from approaching each other and bonding together when the mixed solution is cured;

(5) baking the hand coated with the mixed solution at the temperature of 30-45 ℃ for 5-30 s, keeping the fingers open and turning the wrist during baking, drying the whole hand surface, and finishing the glove manufacturing;

(6) after the gloves are used, the gloves are uncovered from the edges of the gloves and taken off.

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