CN115028371A - Method for producing small-size Low-E coated glass and application thereof - Google Patents

Method for producing small-size Low-E coated glass and application thereof Download PDF

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Publication number
CN115028371A
CN115028371A CN202210496655.7A CN202210496655A CN115028371A CN 115028371 A CN115028371 A CN 115028371A CN 202210496655 A CN202210496655 A CN 202210496655A CN 115028371 A CN115028371 A CN 115028371A
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glass
small
coated
pieces
low
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CN202210496655.7A
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CN115028371B (en
Inventor
任怀学
黄颖
熊云
李连发
阮军琪
崔平生
余光辉
彭立群
王勇
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CSG Holding Co Ltd
Dongguan CSG Architectural Glass Co Ltd
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CSG Holding Co Ltd
Dongguan CSG Architectural Glass Co Ltd
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Priority to CN202210496655.7A priority Critical patent/CN115028371B/en
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    • CCHEMISTRY; METALLURGY
    • C03GLASS; MINERAL OR SLAG WOOL
    • C03CCHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C17/00Surface treatment of glass, not in the form of fibres or filaments, by coating
    • C03C17/001General methods for coating; Devices therefor
    • C03C17/002General methods for coating; Devices therefor for flat glass, e.g. float glass
    • CCHEMISTRY; METALLURGY
    • C03GLASS; MINERAL OR SLAG WOOL
    • C03CCHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C27/00Joining pieces of glass to pieces of other inorganic material; Joining glass to glass other than by fusing
    • C03C27/06Joining glass to glass by processes other than fusing
    • CCHEMISTRY; METALLURGY
    • C03GLASS; MINERAL OR SLAG WOOL
    • C03CCHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C2218/00Methods for coating glass
    • C03C2218/10Deposition methods
    • C03C2218/15Deposition methods from the vapour phase
    • C03C2218/154Deposition methods from the vapour phase by sputtering
    • C03C2218/156Deposition methods from the vapour phase by sputtering by magnetron sputtering
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02BCLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO BUILDINGS, e.g. HOUSING, HOUSE APPLIANCES OR RELATED END-USER APPLICATIONS
    • Y02B80/00Architectural or constructional elements improving the thermal performance of buildings
    • Y02B80/22Glazing, e.g. vaccum glazing

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Geochemistry & Mineralogy (AREA)
  • Materials Engineering (AREA)
  • Organic Chemistry (AREA)
  • Ceramic Engineering (AREA)
  • Joining Of Glass To Other Materials (AREA)

Abstract

The invention discloses a method for producing small-size Low-E coated glass and application thereof. The method for producing the small-size Low-E coated glass comprises the following steps: two pieces of glass with the same size and specification are pasted and spliced into a whole side by side, and then film coating is carried out; wherein, the diagonal line of each glass is respectively parallel to the conveying roller for conveying the glass; the small specification means that the length of the diagonal of each part of glass is less than 800 mm; the thickness of the glass is less than or equal to 18 mm. The method can improve the production efficiency of the coated glass with the diagonal line less than 800mm and realize the production of small-specification glass with the thickness more than 12 mm.

Description

Method for producing small-size Low-E coated glass and application thereof
Technical Field
The invention belongs to the technical field of coated glass, and particularly relates to a method for producing small-size Low-E coated glass and application thereof.
Background
The driving rollers of the magnetron sputtering coating equipment are horizontal, and the distance between the centers of two adjacent driving rollers is 300 mm. The diagonal line of the glass is required to be larger than 800mm in order to be transmitted on the transmission table and not to fall off on the transmission table or jolt during transmission because the length and the width of the glass are too small, and the diagonal line of the Low-E coated glass is required to be smaller than 800mm when the Low-E coated glass (Low-emissivity coated glass) is applied to residential doors and windows and the like in a large scale.
At present, the Low-E coated glass with the diagonal line smaller than 800mm is produced by adopting a tray paster mode. The specific scheme is as follows: and (3) using 6mm glass as a tray, placing the tray glass on a clean room conveying table, and sticking double-sided adhesive tapes at the proper positions of the tray. When glass passes through the air knife position, a specially-assigned person is required to monitor the state of the glass, and the glass is prevented from being blown to be broken or overlapped to be collided at the air knife position. When glass is conveyed to the outlet of the cleaning machine, the glass needs to be quickly taken down and pasted on the tray, otherwise, the glass drops below the driving roller because of being too small, and therefore the glass needs to be timely and quickly taken away from the outlet of the cleaning machine and placed on the tray. And finally, the glass enters a coating chamber for coating, and the glass is taken down from the tray one by one after the glass is coated.
The above method of tray pasting has several disadvantages: 1. the production efficiency is extremely low, when the small glass is cleaned independently, the small glass is easy to be blown down or overlapped and broken at the air knife position due to light weight, and special personnel are required to see the glass at the air knife position of the cleaning machine, in addition, the air knife can see the glass for 1 person, the glass placing for 1 person, the glass receiving for 1 person in the clean room, the glass pasting for 1 person, the main control room technician and the glass unloading personnel are required to go up to assist other people; 2. the color control difficulty is high, because the thickness of the coated substrate is increased when the glass is adhered to the tray, the parameters read out by the detection equipment are different from the parameters of the actual product, and the parameters need to be independently debugged; because the surface of the glass is uneven, a gap exists between the glass and the tray when the glass is stuck on the tray, and the residual air in the gap can influence the film coating effect during film coating; 3. the glass is attached to the tray, so that the thickness of the coated substrate is increased, small-sized glass with the thickness of more than 12mm cannot enter the coating chamber, and the actual thickness of the coated glass is reduced.
Disclosure of Invention
The technical problem to be solved by the invention is as follows:
provides a method for producing small-size Low-E coated glass. The method can improve the production efficiency of the coated glass with the diagonal line less than 800mm and realize the production of small-specification glass with the thickness more than 12 mm.
The invention also provides application of the method for producing the small-size Low-E coated glass in a coating process.
The invention also provides application of the method for producing the small-size Low-E coated glass in glass production.
In order to solve the technical problem, the technical scheme adopted by the invention is as follows:
a method for producing small-size Low-E coated glass comprises the following steps:
two pieces of glass with the same size and specification are stuck side by side and spliced into a whole, and then film coating is carried out;
wherein, the diagonal line of each glass is respectively parallel to the conveying roller for conveying the glass;
the small specification means that the length of the diagonal of each part of glass is less than 800 mm;
the thickness of the glass is less than or equal to 18 mm.
The small specification means that the length of the diagonal of each piece of glass is less than 800mm, but not the length of the whole diagonal formed by two pieces of glass after being arranged side by side is less than 800 mm. Before the adhesive sticker is adhered, two small-sized glass pieces are tightly abutted, and no gap can be left.
Low-E glass is also called Low-emissivity glass, and is a film product formed by plating a plurality of layers of metal or other compounds on the surface of the glass. The coating layer has the characteristics of high visible light transmission and high mid-far infrared ray reflection, so that the coating layer has excellent heat insulation effect and good light transmission compared with common glass and traditional coating glass for buildings.
After the two small glass pieces are spliced into a whole, the diagonal line of each small glass piece is ensured to be parallel to the transmission roller during sheet arrangement, but not the diagonal line after the small glass pieces are spliced into a whole is parallel to the transmission roller. The problem that the glass is damaged due to the fact that the sharp corner collides with the cavity door when the glass senses the photoelectric switch before entering the vacuum magnetron sputtering coating device is avoided.
The invention relates to a method for producing small-size Low-E coated glass, which is used for realizing mass production of the coated glass with the diagonal line less than 800 mm.
In the method, the time for sticking the two pieces of glass with the same size and specification side by side is preferably adjusted to be the gap, and the small-size glass is stuck together by the coated adhesive sticker, so that the production time is not delayed.
In the method, two pieces of glass with the same size and specification are pasted side by side, the color of the spliced product does not need to be specially debugged, and the color is easy to control.
In the method, two pieces of glass with the same size and specification are pasted side by side, so that the method for pasting the sheet on the tray in the prior art is overcome, the thickness of the glass capable of being coated can be further increased, and the maximum thickness of the glass capable of being coated is increased to 18 mm.
The method can reduce operators for coating the small pieces of glass, save coating time and improve coating efficiency.
Two pieces of glass with the same size and specification are pasted side by side to form a whole body, so that the whole body reaches the minimum specification (including 300 x 800mm) that the vacuum coating equipment can be placed, and then coating is carried out in the vacuum chamber. Thereby meeting the requirement of coating the small-size glass.
According to one embodiment of the invention, the glass thickness is greater than 12 mm.
According to one embodiment of the invention, the method comprises the steps of adhering two pieces of glass side by side, placing the two pieces of glass on a conveying roller, and gradually conveying the glass to washing and air drying, buffering and vacuum coating.
According to one embodiment of the invention, when the cleaning and air-drying device performs air-drying operation, the air pressure is less than or equal to 1kg/cm 2 . After the glass is cleaned, the glass is dried by an air knife, the air pressure is less than that of the large glass, and the air pressure is set to be less than or equal to 1kg/cm 2 Thereby preventing blowing of the glass bond.
The inlet chamber functions as: during the process of transferring the substrate into the sputtering chamber, air is prevented from entering the sputtering chamber, and the vacuum degree of the inlet chamber can reach 10 -2 mbar。
The inlet buffer chamber has the functions of: the vacuum degree of the substrate before entering the sputtering chamber can reach 10 - 4 mbar。
A hydraulic or compressed air controlled chamber door is provided between the inlet chamber and the inlet buffer chamber to prevent air cross-talk between the chambers.
The vacuum magnetron sputtering chamber is a vacuum chamber for carrying out magnetron sputtering on a glass substrate, namely a coating working area, and has high-precision air tightness and a function of strictly controlling air flow. The vacuum chamber contains a plurality of cathodes (mounting sputtering targets) which, in addition to the function of stably sputtering various layers, need to have insulating and cooling sealing properties for other parts of the apparatus. The vacuum chamber also comprises a conveying roller way mechanism, and the chamber wall is also provided with various orifices which are respectively connected with the pipelines and various lines of the vacuum system, the gas distribution system and the water cooling system, and is also provided with an observation hole. The vacuum chamber has higher vacuum degree requirement, and is obtained by rotary vane pump, Roots pump, and molecular pump, and the background vacuum degree can reach 10 -6 -10 -7 mbar。
According to one embodiment of the present invention, after the two glass sheets are pasted side by side, the total transverse width of the two glass sheets is not more than 85% of the length of the conveying roller, and preferably, for a coating production line with a width of 3.3 meters, the total transverse width of the two glass sheets is not more than 2.8 meters.
According to one embodiment of the invention, the two glass sheets are glued side by side, the total longitudinal length of which does not exceed 5.5 m.
If the total transverse width (the total transverse width is 3.3 meters) and the total longitudinal length of the two pieces of glass after being pasted side by side are not limited, the transverse uniformity of a coating film and the specification limitation of a glass substrate result in low probability of putting glass on two sides, the linear speed of conveying rollers on two sides is larger than that of the middle, the displacement of the glass on the side part is larger than that of the middle glass, the small-specification spliced patch glass moves obliquely in a vacuum chamber, the longitudinal length of the two pieces of spliced glass is less than 800mm, the glass is conveyed immovably and can be broken, and the glass breaking accident of the vacuum chamber is caused. The total longitudinal length is limited within 5.5 meters, and the production safety is improved.
According to one embodiment of the invention, the two panes of glass are adhered side by side with a non-setting adhesive or sealant. The selection principle of the self-adhesive sticker or the sealant is as follows: 1. after the adhesive tape is adhered, the adhesive tape is not easy to deform when pulled; 2. the adhesive tape can prevent water, and the adhesive tape can not be degummed when the adhesive tape passes through a cleaning machine; 3. the adhesive tape can not leave adhesive on the surface of the glass, and secondary cleaning is not needed after the adhesive tape is torn.
According to one embodiment of the invention, the side-by-side application sites are located on the uncoated side of the glass. The position of the upper surface of the glass, which needs to be coated, is prevented from being covered by the adhesive tape.
In still another aspect of the invention, the invention also provides an application of the method for producing the small-size Low-E coated glass in a coating process.
In still another aspect of the invention, the invention also provides application of the method for producing the small-size Low-E coated glass in glass production.
One of the technical solutions has at least one of the following advantages or beneficial effects:
according to the method, two pieces of glass with the same size and specification are pasted side by side, the problem that the thickness of the platable film is low due to the fact that a tray is required to be used in a tray pasting method in the prior art is solved, the tray is not required to be used in the scheme, the thickness of the platable film of the glass can be further increased, the maximum thickness of the platable film is increased to 18mm, and the mass production of the plated glass with the diagonal line smaller than 800mm can be realized.
Drawings
The accompanying drawings, which are incorporated in and constitute a part of this specification, are included to provide a further understanding of the invention, and are incorporated in and constitute a part of this specification, illustrate exemplary embodiments of the invention and together with the description serve to explain the invention and not to limit the invention.
FIG. 1 is a flow chart of a method for producing small-gauge Low-E coated glass in an example.
FIG. 2 is a schematic diagram of the arrangement of the small-sized Low-E coated glass in the example.
FIG. 3 is a schematic diagram of the splicing result of the small-sized Low-E coated glass in the embodiment.
Detailed Description
The technical solutions in the embodiments of the present invention will be clearly and completely described below with reference to the embodiments of the present invention, and it is obvious that the described embodiments are only a part of the embodiments of the present invention, and not all of the embodiments. All other embodiments, which can be derived by a person skilled in the art from the embodiments given herein without making any creative effort, shall fall within the scope of the present invention.
Examples
A method for producing small-size Low-E coated glass is shown in a flow chart 1 and specifically comprises the following steps: and (3) placing two pieces of glass with the same size and specification side by side, aligning the two pieces of glass to the left and right, sticking the two pieces of glass together by using the non-setting adhesive, sticking the adhesive tape tightly, and avoiding bubbles in the middle to obtain the spliced small-specification glass to be coated. The schematic diagram of the arrangement of the small-sized glass to be coated is shown in FIG. 2, and the gray part represents adhesive sticker; the result of the small-sized glass to be coated is schematically shown in fig. 3.
The diagonal length of the glass used in example 1 was 676 mm; the glass thickness was 6 mm.
Cleaning glass: after the small-size glass is spliced according to the method, the small-size glass can be loaded, cleaned and air-dried. When the glass is laminated, the surface with the adhesive tape faces downwards, so that the position of the upper surface of the glass, which needs to be coated, is prevented from being covered by the adhesive tape. When the piece is loaded, attention is paid to: after the two small glass pieces are spliced into a whole, the diagonal line of each small glass piece is ensured to be parallel to the transmission roller during sheet arrangement, but not the diagonal line after the small glass pieces are spliced into a whole is parallel to the transmission roller. And cleaning by using a coating cleaning machine. First to two pots at first, need to be in clearAnd checking the cleaning quality in an observation room behind the cleaning machine, checking the adhesive tape sticking quality, and performing mass production after the adhesive tape sticking quality is confirmed to be correct. After the glass is cleaned, the glass is dried by an air knife, and the air pressure is controlled to be 80 percent (1 kg/cm) of that in the production of large glass 2 Left and right) to prevent the glass bond from being blown apart.
Inlet chamber, inlet buffer chamber: 1) after the small-size glass is spliced, cleaned and inspected according to the method, the small-size glass can enter a vacuum magnetron sputtering chamber through an inlet chamber and an inlet buffer chamber to be coated.
2) And the coating production line controls the transmission and the stop of each conveying table by a photoelectric switch, and the glass substrate is required to correctly sense the photoelectric switch. The glass substrate is stopped before the cavity doors of the inlet chamber and the inlet buffer chamber, and the vacuum degree is pumped to the set door opening condition by the air pumping system. The spliced small-specification glass to be coated is placed diagonally, the diagonal lines of two pieces of glass in the small-specification glass to be coated are parallel to the transmission roller, the glass can sense a photoelectric switch, and the glass on the whole conveying table is controlled to safely enter a vacuum sputtering chamber for magnetron sputtering coating.
Vacuum magnetron sputtering coating: the small-size glass can enter a vacuum magnetron sputtering chamber for coating after being spliced, cleaned, checked and passed through a buffer chamber according to the method, and the coating parameters are consistent with those of products with different thicknesses and without splicing.
Unloading the sheet: and (4) unloading the spliced and coated qualified products to a specified iron stand according to the sheet number and size requirements of the order. The coated glass can not be touched by bare hands or dirty gloves to prevent oxidation. To take a clean glove lower piece wrapped with dust-free cloth, a piece of glass is pressed by one hand, the glove lower piece is separated and put well, then the adhesive tape is taken down, and then the other glove lower piece is taken down. This action is repeated until all the tiles to be spliced are completely disassembled. The color of the film is kept consistent after the film is coated, the color stability is good, the color difference is avoided, and the appearance rejection rate is kept at 0%.
The above description is only an example of the present invention and is not intended to limit the scope of the present invention, and all equivalent modifications made by the present invention as described in the specification of the present invention or directly or indirectly applied to the related technical fields are included in the scope of the present invention.

Claims (9)

1. A method for producing small-size Low-E coated glass is characterized by comprising the following steps: the method comprises the following steps:
two pieces of glass with the same size and specification are pasted and spliced into a whole side by side, and then film coating is carried out;
wherein, the diagonal line of each glass is respectively parallel to the conveying roller for conveying the glass;
the small specification means that the length of the diagonal of each part of glass is less than 800 mm;
the thickness of the glass is less than or equal to 18 mm.
2. The method for producing small-format Low-E coated glass according to claim 1, wherein: the thickness of the glass is more than 12 mm.
3. The method for producing small-format Low-E coated glass according to claim 1, wherein: the method comprises the steps of sticking two pieces of glass side by side, placing the glass on a transmission roller, and gradually conveying the glass to cleaning and air drying, buffering treatment and vacuum coating.
4. The method for producing small-format Low-E coated glass according to claim 3, wherein: when the air drying operation is executed, the air pressure is less than or equal to 1kg/cm 2
5. The method for producing small-format Low-E coated glass according to claim 3, wherein: after the two pieces of glass are stuck side by side, the total longitudinal length of the two pieces of glass is not more than 5.5 meters.
6. The method for producing small-format Low-E coated glass according to claim 3, wherein: and adhering the two pieces of glass side by using adhesive sticker or sealant.
7. The method for producing small-format Low-E coated glass according to claim 6, wherein: the pasted part is positioned on the non-film-coated surface of the glass.
8. Use of a method according to any one of claims 1 to 7 for the production of small format Low-E coated glass in a coating process.
9. Use of a method according to any one of claims 1 to 7 for the production of small format Low-E coated glass in the production of glass.
CN202210496655.7A 2022-05-09 2022-05-09 Method for producing small-sized Low-E coated glass and application thereof Active CN115028371B (en)

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Citations (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1610651A (en) * 2001-12-27 2005-04-27 小贯英雄 Method for adhering transparent articles and quartz glass plate prepared through adhesion and device using the same
CN101578548A (en) * 2006-12-06 2009-11-11 康宁股份有限公司 Modular glass reference plate assembly
CN203960051U (en) * 2014-06-24 2014-11-26 咸宁南玻节能玻璃有限公司 Big or small slice glass assembly and doubling coated glass print preparation system
CN106467365A (en) * 2015-08-22 2017-03-01 江苏北玻节能玻璃科技有限公司 A kind of production method of Low-E coated glass
CN108072922A (en) * 2016-11-17 2018-05-25 上海域申光电科技有限公司 The profusely footpath coating process of optical mirror slip
CN109975895A (en) * 2019-03-26 2019-07-05 上海域申光电科技有限公司 A kind of glasses lens plated preceding pretreating process of high reflection
CN111675491A (en) * 2020-06-09 2020-09-18 杭州美迪凯光电科技股份有限公司 Processing method of infrared narrow-band coated filter with extremely small size
CN215628260U (en) * 2021-06-03 2022-01-25 天津南玻节能玻璃有限公司 Tool for coating small-size glass

Patent Citations (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1610651A (en) * 2001-12-27 2005-04-27 小贯英雄 Method for adhering transparent articles and quartz glass plate prepared through adhesion and device using the same
CN101578548A (en) * 2006-12-06 2009-11-11 康宁股份有限公司 Modular glass reference plate assembly
CN203960051U (en) * 2014-06-24 2014-11-26 咸宁南玻节能玻璃有限公司 Big or small slice glass assembly and doubling coated glass print preparation system
CN106467365A (en) * 2015-08-22 2017-03-01 江苏北玻节能玻璃科技有限公司 A kind of production method of Low-E coated glass
CN108072922A (en) * 2016-11-17 2018-05-25 上海域申光电科技有限公司 The profusely footpath coating process of optical mirror slip
CN109975895A (en) * 2019-03-26 2019-07-05 上海域申光电科技有限公司 A kind of glasses lens plated preceding pretreating process of high reflection
CN111675491A (en) * 2020-06-09 2020-09-18 杭州美迪凯光电科技股份有限公司 Processing method of infrared narrow-band coated filter with extremely small size
CN215628260U (en) * 2021-06-03 2022-01-25 天津南玻节能玻璃有限公司 Tool for coating small-size glass

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