CN114999952A - Method for confirming M surface in gallium nitride substrate and method for cutting gallium nitride substrate - Google Patents
Method for confirming M surface in gallium nitride substrate and method for cutting gallium nitride substrate Download PDFInfo
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Abstract
本申请提供一种氮化镓衬底中M面的确认方法及氮化镓衬底的切割方法,包括:提供氮化镓衬底;于所述氮化镓衬底的上表面选择扫描点;基于所述扫描点对所述氮化镓衬底的预设晶面进行多次摇摆曲线扫描,以得到多个Omega曲线及与多个Omega曲线的峰值对应的多个扫描角度;对所述氮化镓衬底的W面进行360°Phi扫描,以得到多个与M面对应的Phi值;基于多个所述扫描角度中的最大扫描角度、最小扫描角度及多个所述Phi值,确定所述氮化镓衬底中与所述斜切角最近的M面及与所述斜切角最远的M面。上述氮化镓衬底中M面的确认方法中,可以准确确认氮化镓衬底中与斜切角最近的M面及与斜切角最远的M面。
The present application provides a method for confirming an M-plane in a gallium nitride substrate and a method for cutting the gallium nitride substrate, including: providing a gallium nitride substrate; selecting a scanning point on the upper surface of the gallium nitride substrate; Perform multiple rocking curve scans on the preset crystal plane of the gallium nitride substrate based on the scanning points to obtain multiple Omega curves and multiple scanning angles corresponding to the peaks of the multiple Omega curves; The W surface of the gallium nitride substrate is scanned at 360° Phi to obtain a plurality of Phi values corresponding to the M surface; The M-plane closest to the chamfered corner and the M-plane farthest from the chamfered corner in the gallium nitride substrate are determined. In the above method for confirming the M-plane in the gallium nitride substrate, the M-plane closest to the chamfer angle and the M-plane farthest from the chamfer angle can be accurately confirmed in the gallium nitride substrate.
Description
技术领域technical field
本申请涉及半导体技术领域,特别是涉及一种氮化镓衬底中M面的确认方法及氮化镓衬底的切割方法。The present application relates to the field of semiconductor technology, and in particular, to a method for confirming an M-plane in a gallium nitride substrate and a method for cutting the gallium nitride substrate.
背景技术Background technique
在生长氮化镓衬底时,氮化镓衬底的物理平面(譬如上表面)和氮化镓晶胞的方向经常存在一定的角度(即斜切角),在这样的前提下,会导致氮化镓晶胞朝所述氮化镓衬底的某个方向倾斜。现有技术中,在得到氮化镓衬底后,对于具有斜切角的氮化镓衬底,需要寻找氮化镓衬底与斜切角最近的M面及与斜切角最远的M面,以便于将氮化镓衬底按所需的面进行切割等后续处理。然而,目前并没有有效的方法可以准确确认氮化镓衬底与斜切角最近的M面及与斜切角最远的M面。When growing a gallium nitride substrate, the physical plane (such as the upper surface) of the gallium nitride substrate and the direction of the gallium nitride unit cell often have a certain angle (that is, a chamfered angle). The gallium nitride unit cell is inclined towards a certain direction of the gallium nitride substrate. In the prior art, after a gallium nitride substrate is obtained, for a gallium nitride substrate with a chamfered angle, it is necessary to find the M surface of the gallium nitride substrate closest to the chamfered angle and the M plane farthest from the chamfered angle. face, so that the gallium nitride substrate can be cut according to the required face and other subsequent processing. However, at present, there is no effective method to accurately identify the M-plane closest to the chamfer angle and the M-plane farthest from the chamfer angle of the gallium nitride substrate.
发明内容SUMMARY OF THE INVENTION
基于现有技术存在的无法准确确认氮化镓衬底与斜切角最近的M面及与斜切角最远的M面的问题,提供一种氮化镓衬底中M面的确认方法及氮化镓衬底的切割方法。Based on the problem in the prior art that the M-plane closest to the chamfer angle and the M-plane farthest from the chamfer angle of the gallium nitride substrate cannot be accurately confirmed, a method for confirming the M-plane in a gallium nitride substrate and the method are provided. Cutting method of gallium nitride substrate.
本申请提供一种氮化镓衬底中M面的确认方法,包括:The present application provides a method for confirming the M-plane in a gallium nitride substrate, including:
提供氮化镓衬底;Provide gallium nitride substrate;
于所述氮化镓衬底的上表面选择扫描点;selecting scanning points on the upper surface of the gallium nitride substrate;
基于所述扫描点对所述氮化镓衬底的预设晶面进行多次摇摆曲线扫描,以得到多个Omega曲线及与多个Omega曲线的峰值对应的多个扫描角度;Perform multiple rocking curve scans on the preset crystal plane of the gallium nitride substrate based on the scanning points to obtain multiple Omega curves and multiple scanning angles corresponding to the peaks of the multiple Omega curves;
对所述氮化镓衬底的W面进行360°Phi扫描,以得到多个与M面对应的Phi值;360°Phi scanning is performed on the W surface of the gallium nitride substrate to obtain a plurality of Phi values corresponding to the M surface;
基于多个所述扫描角度中的最大扫描角度、最小扫描角度及多个所述Phi值,确定所述氮化镓衬底中与所述斜切角最近的M面及与所述斜切角最远的M面。Based on a maximum scanning angle, a minimum scanning angle and a plurality of the Phi values among the plurality of scanning angles, the M-plane closest to the bevel angle and the bevel angle in the gallium nitride substrate are determined The farthest M face.
在生长氮化镓衬底时,氮化镓衬底的物理平面(譬如上表面)和氮化镓晶胞的方向经常存在一定的角度(即斜切角),在这样的前提下,会导致氮化镓晶胞朝所述氮化镓衬底的某个方向倾斜;上述氮化镓衬底中M面的确认方法中,利用这种倾斜,通过对氮化镓衬底进行预设晶面的多次摇摆曲线扫描,多个Omega曲线及与多个Omega曲线的峰值对应的多个扫描角度,然后对氮化镓衬底的W面进行多次Phi扫描,以得到多个与M面对应的Phi值,最后基于多个扫描角度中的最大扫描角度、最小扫描角度及多个Phi值,即可准确确认氮化镓衬底中与斜切角最近的M面及与斜切角最远的M面。When growing a gallium nitride substrate, the physical plane (such as the upper surface) of the gallium nitride substrate and the direction of the gallium nitride unit cell often have a certain angle (that is, a chamfered angle). The gallium nitride unit cell is inclined in a certain direction of the gallium nitride substrate; in the above-mentioned method for confirming the M plane in the gallium nitride substrate, this inclination is used to preset the crystal plane on the gallium nitride substrate. Multiple rocking curve scans, multiple Omega curves and multiple scan angles corresponding to the peaks of the multiple Omega curves, and then perform multiple Phi scans on the W surface of the gallium nitride substrate to obtain multiple and M surfaces. The corresponding Phi value, and finally based on the maximum scanning angle, the minimum scanning angle and the multiple Phi values among the multiple scanning angles, the M-plane closest to the chamfering angle and the M-plane closest to the chamfering angle in the gallium nitride substrate can be accurately confirmed. far M face.
在其中一个实施例中,所述基于所述扫描点对所述氮化镓衬底的预设晶面进行多次摇摆曲线扫描,以得到多个Omega曲线及与多个Omega曲线的峰值对应的多个扫描角度,包括:In one embodiment, the predetermined crystal plane of the gallium nitride substrate is scanned multiple times on the rocking curve based on the scanning points, so as to obtain multiple Omega curves and peaks corresponding to the multiple Omega curves Multiple scan angles, including:
基于所述扫描点对所述氮化镓衬底进行所述预设晶面的摇摆曲线扫描,以得到该步骤的Omega曲线,并记录该步骤得到的Omega曲线的峰值对应的扫描角度;Perform rocking curve scanning of the preset crystal plane on the gallium nitride substrate based on the scanning points to obtain the Omega curve of this step, and record the scanning angle corresponding to the peak of the Omega curve obtained in this step;
将所述氮化镓衬底在XY平面内转动预设角度,再次对所述扫描点进行所述预设晶面的摇摆曲线扫描,以得到该步骤的Omega曲线,并记录该步骤得到的Omega曲线的峰值对应的扫描角度;Rotate the gallium nitride substrate by a preset angle in the XY plane, and perform rocking curve scanning of the preset crystal plane on the scanning point again to obtain the Omega curve of this step, and record the Omega obtained in this step. The scan angle corresponding to the peak of the curve;
重复上一步骤若干次,直至所述氮化镓衬底旋转360°,以得到多个Omega曲线及与多个Omega曲线的峰值对应的多个扫描角度。The previous step is repeated several times until the gallium nitride substrate is rotated by 360°, so as to obtain a plurality of Omega curves and a plurality of scanning angles corresponding to the peaks of the plurality of Omega curves.
在其中一个实施例中,所述基于所述扫描点对所述氮化镓衬底进行所述预设晶面的摇摆曲线扫描之前,包括:In one embodiment, before performing the rocking curve scanning of the preset crystal plane on the gallium nitride substrate based on the scanning points, the method includes:
选择XY平面内任一点作为扫描起始角度点。Select any point in the XY plane as the scan start angle point.
在其中一个实施例中,所述预设晶面为(002)面。In one embodiment, the predetermined crystal plane is a (002) plane.
在其中一个实施例中,所述预设角度为0.1°~30°。In one embodiment, the preset angle is 0.1°˜30°.
在其中一个实施例中,所述预设角度为1°~10°。In one embodiment, the preset angle is 1°˜10°.
在其中一个实施例中,所述氮化镓衬底的W面为与所述氮化镓衬底的M面及所述氮化镓衬底的C面的交线相平行的面。In one embodiment, the W plane of the gallium nitride substrate is a plane parallel to the intersection of the M plane of the gallium nitride substrate and the C plane of the gallium nitride substrate.
在其中一个实施例中,所述氮化镓衬底的W面为(114)面或者(102)面。In one embodiment, the W plane of the gallium nitride substrate is a (114) plane or a (102) plane.
在其中一个实施例中,所述最大扫描角度所对应的所述氮化镓衬底在XY平面内的旋转角度记为第一角度,所述最小扫描角度所对应的所述氮化镓衬底在XY平面内的旋转角度记为第二角度;基于多个所述扫描角度中的最大扫描角度、最小扫描角度及多个所述Phi值,确定所述氮化镓衬底中与所述斜切角最近的M面及与所述斜切角最远的M面,包括:In one embodiment, the rotation angle of the gallium nitride substrate in the XY plane corresponding to the maximum scanning angle is denoted as a first angle, and the gallium nitride substrate corresponding to the minimum scanning angle The rotation angle in the XY plane is denoted as the second angle; based on the maximum scanning angle, the minimum scanning angle and the plurality of the Phi values among the plurality of scanning angles, it is determined that the slope of the The M-face closest to the chamfered angle and the M-face farthest from the chamfered angle, including:
将所述第一角度与多个所述Phi值进行比较,与所述第一角度的差值的绝对值小于或等于预设值的Phi值所对应的M面,即为氮化镓衬底上离斜切角最远的M面;Comparing the first angle with a plurality of the Phi values, the M plane corresponding to the Phi value whose absolute value of the difference with the first angle is less than or equal to the preset value is the gallium nitride substrate The upper M face farthest from the chamfered corner;
将所述第二角度与多个所述Phi值进行比较,与所述第二角度的差值的绝对值小于或等于所述预设值的Phi值所对应的M面,即为氮化镓衬底上离斜切角最近的M面。Comparing the second angle with a plurality of the Phi values, the absolute value of the difference between the second angle and the second angle is less than or equal to the M-plane corresponding to the Phi value of the preset value, that is, the gallium nitride The M-plane closest to the chamfered corner on the substrate.
在其中一个示例中,所述预设值小于或等于31°。In one example, the preset value is less than or equal to 31°.
本申请还提供一种氮化镓衬底的切割方法,包括:The present application also provides a method for cutting a gallium nitride substrate, comprising:
采用如上述任一方案中所述的氮化镓衬底中M面的确认方法确定所述氮化镓衬底中与所述斜切角最近的M面及与所述斜切角最远的M面;Determine the M-plane closest to the chamfered angle and the M-plane farthest from the chamfered angle in the gallium nitride substrate by using the method for confirming the M-plane in the gallium nitride substrate as described in any of the above solutions M face;
自所述氮化镓衬底中与所述斜切角最近的M面或自所述氮化镓衬底中与所述斜切角最远的M面对所述氮化镓衬底进行切割。The gallium nitride substrate is cut from the M-plane of the gallium nitride substrate closest to the bevel angle or from the M-plane of the gallium nitride substrate farthest from the bevel angle .
在生长氮化镓衬底时,氮化镓衬底的物理平面(譬如上表面)和氮化镓晶胞的方向经常存在一定的角度(即斜切角),在这样的前提下,会导致氮化镓晶胞朝所述氮化镓衬底的某个方向倾斜;由于上述氮化镓衬底中M面的确认方法中,利用这种倾斜,通过对氮化镓衬底进行预设晶面的多次摇摆曲线扫描,多个Omega曲线及与多个Omega曲线的峰值对应的多个扫描角度,然后对氮化镓衬底的W面进行多次Phi扫描,以得到多个与M面对应的Phi值,最后基于多个扫描角度中的最大扫描角度、最小扫描角度及多个Phi值,即可准确确认氮化镓衬底中与斜切角最近的M面及与斜切角最远的M面;进而可以确保对氮化镓衬底10进行切割时,可以精确沿着氮化镓衬底中与斜切角最近的M面或氮化镓衬底中与斜切角最远的M面进行切割,从而确保切割的良率。When growing a gallium nitride substrate, the physical plane (such as the upper surface) of the gallium nitride substrate and the direction of the gallium nitride unit cell often have a certain angle (that is, a chamfered angle). The gallium nitride unit cell is inclined towards a certain direction of the gallium nitride substrate; because in the above-mentioned method for confirming the M plane in the gallium nitride substrate, this inclination is used to pre-crystallize the gallium nitride substrate Multiple rocking curve scans of the surface, multiple Omega curves and multiple scan angles corresponding to the peaks of the multiple Omega curves, and then multiple Phi scans are performed on the W surface of the gallium nitride substrate to obtain multiple and M surfaces. The corresponding Phi value, and finally based on the maximum scanning angle, the minimum scanning angle and the multiple Phi values among the multiple scanning angles, the M-plane closest to the chamfering angle in the gallium nitride substrate and the chamfering angle can be accurately confirmed. The farthest M-plane; thus, it can be ensured that when the
附图说明Description of drawings
为了更清楚地说明本申请实施例或传统技术中的技术方案,下面将对实施例或传统技术描述中所需要使用的附图作简单地介绍,显而易见地,下面描述中的附图仅仅是本申请的一些实施例,对于本领域普通技术人员来讲,在不付出创造性劳动的前提下,还可以根据这些附图获得其他的附图。In order to more clearly illustrate the technical solutions in the embodiments of the present application or in the traditional technology, the following briefly introduces the accompanying drawings that are used in the description of the embodiments or the traditional technology. Obviously, the drawings in the following description are only the For some embodiments of the application, for those of ordinary skill in the art, other drawings can also be obtained according to these drawings without any creative effort.
图1为本申请一实施例中提供的氮化镓衬底中M面的确认方法的流程图;FIG. 1 is a flowchart of a method for confirming an M-plane in a gallium nitride substrate provided in an embodiment of the application;
图2为本申请一实施例中提供的氮化镓衬底中M面的确认方法中的氮化镓衬底的俯视结构示意图;2 is a schematic top-view structural diagram of a gallium nitride substrate in a method for confirming an M-plane in a gallium nitride substrate provided in an embodiment of the present application;
图3为本申请一实施例中提供的氮化镓衬底中M面的确认方法中的氮化镓衬底中的氮化镓晶胞的立体结构示意图;3 is a schematic three-dimensional structure diagram of a gallium nitride unit cell in a gallium nitride substrate in a method for confirming an M-plane in a gallium nitride substrate provided in an embodiment of the application;
图4为本申请一实施例中提供的氮化镓衬底中M面的确认方法中的氮化镓衬底的截面结构示意图;4 is a schematic cross-sectional structure diagram of a gallium nitride substrate in a method for confirming an M-plane in a gallium nitride substrate provided in an embodiment of the application;
图5为本申请另一实施例中提供的氮化镓衬底的切割方法的流程图。FIG. 5 is a flowchart of a method for cutting a gallium nitride substrate provided in another embodiment of the present application.
附图标记说明:10、氮化镓衬底;101、氮化镓晶胞。Description of reference numerals: 10. Gallium nitride substrate; 101. Gallium nitride unit cell.
具体实施方式Detailed ways
为了便于理解本申请,下面将参照相关附图对本申请进行更全面的描述。附图中给出了本申请的实施例。但是,本申请可以以许多不同的形式来实现,并不限于本文所描述的实施例。相反地,提供这些实施例的目的是使本申请的公开内容更加透彻全面。In order to facilitate understanding of the present application, the present application will be described more fully below with reference to the related drawings. Embodiments of the present application are presented in the accompanying drawings. However, the application may be implemented in many different forms and is not limited to the embodiments described herein. Rather, these embodiments are provided so that this disclosure will be thorough and complete.
除非另有定义,本文所使用的所有的技术和科学术语与属于本申请的技术领域的技术人员通常理解的含义相同。本文中在本申请的说明书中所使用的术语只是为了描述具体的实施例的目的,不是旨在于限制本申请。Unless otherwise defined, all technical and scientific terms used herein have the same meaning as commonly understood by one of ordinary skill in the technical field to which this application belongs. The terms used herein in the specification of the application are for the purpose of describing specific embodiments only, and are not intended to limit the application.
可以理解,本申请所使用的术语“第一”、“第二”等可在本文中用于描述各种元件,但这些元件不受这些术语限制。这些术语仅用于将第一个元件与另一个元件区分。It will be understood that the terms "first", "second", etc. used in this application may be used herein to describe various elements, but these elements are not limited by these terms. These terms are only used to distinguish a first element from another element.
可以理解,以下实施例中的“连接”,如果被连接的电路、模块、单元等相互之间具有电信号或数据的传递,则应理解为“电连接”、“通信连接”等。It can be understood that the "connection" in the following embodiments should be understood as "electrical connection", "communication connection", etc. if the connected circuits, modules, units, etc. have electrical signals or data transmission between them.
在此使用时,单数形式的“一”、“一个”和“所述/该”也可以包括复数形式,除非上下文清楚指出另外的方式。还应当理解的是,术语“包括/包含”或“具有”等指定所陈述的特征、整体、步骤、操作、组件、部分或它们的组合的存在,但是不排除存在或添加一个或更多个其他特征、整体、步骤、操作、组件、部分或它们的组合的可能性。As used herein, the singular forms "a," "an," and "the/the" can include the plural forms as well, unless the context clearly dictates otherwise. It should also be understood that the terms "comprising/comprising" or "having" etc. designate the presence of stated features, integers, steps, operations, components, parts or combinations thereof, but do not preclude the presence or addition of one or more Possibilities of other features, integers, steps, operations, components, parts or combinations thereof.
请参阅图1,本申请提供一种氮化镓衬底中M面的确认方法,氮化镓衬底中M面的确认方法可以包括如下步骤:Referring to FIG. 1, the present application provides a method for confirming an M-plane in a gallium nitride substrate, and the method for confirming an M-plane in a gallium nitride substrate may include the following steps:
S10:提供氮化镓衬底;S10: Provide gallium nitride substrate;
S11:于所述氮化镓衬底的上表面选择扫描点;S11: selecting a scanning point on the upper surface of the gallium nitride substrate;
S12:基于所述扫描点对所述氮化镓衬底的预设晶面进行多次摇摆曲线扫描,以得到多个Omega曲线及与多个Omega曲线的峰值对应的多个扫描角度;S12: Perform multiple rocking curve scans on the preset crystal plane of the gallium nitride substrate based on the scanning points to obtain multiple Omega curves and multiple scanning angles corresponding to the peaks of the multiple Omega curves;
S13:对所述氮化镓衬底的W面进行360°Phi扫描,以得到多个与M面对应的Phi值;S13: Perform 360° Phi scanning on the W surface of the gallium nitride substrate to obtain a plurality of Phi values corresponding to the M surface;
S14:基于多个所述扫描角度中的最大扫描角度、最小扫描角度及多个所述Phi值,确定所述氮化镓衬底中与所述斜切角最近的M面及与所述斜切角最远的M面。S14: Based on the maximum scanning angle, the minimum scanning angle and the plurality of the Phi values among the plurality of scanning angles, determine the M-plane closest to the chamfering angle in the gallium nitride substrate and the surface closest to the chamfering angle and the slanting angle. Chamfer the farthest M face.
在生长氮化镓衬底时,氮化镓衬底的物理平面(譬如上表面)和氮化镓晶胞的方向经常存在一定的角度(即斜切角),在这样的前提下,会导致氮化镓晶胞朝所述氮化镓衬底的某个方向倾斜;上述氮化镓衬底中M面的确认方法中,利用这种倾斜,通过对氮化镓衬底进行预设晶面的多次摇摆曲线扫描,多个Omega曲线及与多个Omega曲线的峰值对应的多个扫描角度,然后对氮化镓衬底的W面进行多次Phi扫描,以得到多个与M面对应的Phi值,最后基于多个扫描角度中的最大扫描角度、最小扫描角度所对应的在XY平面内的旋转角度及多个Phi值,即可准确确认氮化镓衬底中与斜切角最近的M面及与斜切角最远的M面。When growing a gallium nitride substrate, the physical plane (such as the upper surface) of the gallium nitride substrate and the direction of the gallium nitride unit cell often have a certain angle (that is, a chamfered angle). The gallium nitride unit cell is inclined in a certain direction of the gallium nitride substrate; in the above-mentioned method for confirming the M plane in the gallium nitride substrate, this inclination is used to preset the crystal plane on the gallium nitride substrate. Multiple rocking curve scans, multiple Omega curves and multiple scan angles corresponding to the peaks of the multiple Omega curves, and then perform multiple Phi scans on the W surface of the gallium nitride substrate to obtain multiple and M surfaces. The corresponding Phi value, and finally based on the maximum scanning angle among the multiple scanning angles, the rotation angle in the XY plane corresponding to the minimum scanning angle, and the multiple Phi values, the chamfer angle in the gallium nitride substrate can be accurately confirmed. The nearest M-face and the M-face farthest from the chamfered angle.
在步骤S10中,请参阅图1中的S10步骤及图2至图4,提供氮化镓衬底10。In step S10 , referring to step S10 in FIG. 1 and FIGS. 2 to 4 , a
具体的,氮化镓衬底10可以具有晶体法线及物理面法线,物理面法线可以为氮化镓衬底10上表面的法线。Specifically, the
更为具体的,氮化镓衬底10具有斜切角,氮化镓衬底10的斜切角即为晶体法线与物理面法线之间的夹角α,如图4所示。More specifically, the
在步骤S11中,请参阅图1中的S11步骤,于氮化镓衬底10的上表面选择扫描点。In step S11 , referring to step S11 in FIG. 1 , scanning points are selected on the upper surface of the
具体的,在一个示例中,可以于氮化镓衬底10的表面选择任一点作为扫描点;譬如,可以选择氮化镓衬底10上表面的中心点作为扫描点;当然,在其他示例中,扫描点也可以为氮化镓衬底10上表面上任意一点,此处不做限定。Specifically, in one example, any point on the surface of the
更为具体的,在一个示例中,可以将扫描点记为A点。More specifically, in one example, the scan point can be recorded as point A.
在步骤S12中,请参阅图1中的S11及图2至图4,基于扫描点对氮化镓衬底10的预设晶面进行多次摇摆曲线(Rocking Cure)扫描,以得到多个Omega曲线及与多个Omega曲线的峰值对应的多个扫描角度。In step S12 , referring to S11 in FIG. 1 and FIGS. 2 to 4 , the preset crystal plane of the
在一个示例中,步骤S12中,于氮化镓衬底10的上表面选择扫描点,基于扫描点对氮化镓衬底10的预设晶面进行多次摇摆曲线扫描,以得到多个Omega曲线及与多个Omega曲线的峰值对应的多个扫描角度,可以包括如下步骤:In one example, in step S12, scanning points are selected on the upper surface of the
S121:基于扫描点对氮化镓衬底10进行所述预设晶面的摇摆曲线扫描,以得到该步骤的Omega曲线,并记录该步骤得到的Omega曲线的峰值对应的扫描角度;该步骤中得到的Omega曲线的峰值对应的扫描角度记为θ1’;S121: Scan the rocking curve of the preset crystal plane on the
S122:将氮化镓衬底10在XY平面内转动预设角度(预设角度可以记为B),晶体XY平面内转动用Phi表示,再次对扫描点进行所述预设晶面的摇摆曲线扫描,以得到该步骤的Omega曲线,并记录该步骤得到的Omega曲线的峰值对应的扫描角度;该步骤中得到的Omega曲线的峰值对应的扫描角度记为θ2’;XY平面与氮化镓衬底10的上表面相平行,即如图1中X轴与Y轴所在的平面即为XY平面,XY平面即与如图4中的氮化镓衬底10的物理面(即上表面)相平行;S122: Rotate the
S123:重复上一步骤若干次,直至氮化镓衬底10旋转360°,以得到多个Omega曲线及与多个Omega曲线的峰值对应的多个扫描角度。S123 : Repeat the previous step several times until the
具体的,步骤S121之前,还可以包括:选择XY平面内任一点作为扫描起始角度点,并将扫描起始角度点作为0°开始点。Specifically, before step S121, it may further include: selecting any point in the XY plane as the scanning starting angle point, and using the scanning starting angle point as the 0° starting point.
具体的,步骤S121中,可以将氮化镓衬底10置于XRD单晶衍射仪上对扫描点进行预选晶面的摇摆曲线扫描。Specifically, in step S121 , the
在步骤S122及步骤S123中,可以继续将氮化镓衬底10置于XRD单晶衍射仪上对扫描点进行预选晶面的摇摆曲线扫描,相较于步骤S121,可以调整XRD单晶衍射仪上的参数,使得氮化镓衬底10于XY平面内旋转预设角度。In step S122 and step S123, the
在一个示例中,预设角度可以为0.1°~30°,具体的,预设角度可以为0.1°、1°、5°、10°、15°、20°、25°或30°等等。预设角度越小精确度越高,但预设角度越小,需要旋转扫描的次数越多,判断效率会越多;在保证可以得到准确的判定结果的基础上,要选择一个合理的数值范围作为预设角度,才能在保证判断结果准确的基础上又保证判断效率。优选地,预设角度可以为1°~10°,本实施例中,预设角度可以为1°、5°或10°等等。In one example, the preset angle may be 0.1°˜30°, and specifically, the preset angle may be 0.1°, 1°, 5°, 10°, 15°, 20°, 25° or 30°, and so on. The smaller the preset angle is, the higher the accuracy is, but the smaller the preset angle is, the more times it needs to rotate and scan, and the more the judgment efficiency will be; on the basis of ensuring that accurate judgment results can be obtained, a reasonable value range should be selected As a preset angle, the judgment efficiency can be ensured on the basis of ensuring the accuracy of the judgment result. Preferably, the preset angle may be 1°˜10°, and in this embodiment, the preset angle may be 1°, 5°, 10°, and so on.
在步骤S121~步骤S123中,如何对扫描点进行预设晶面的摇摆曲线扫描为本领域技术人员所知晓,此处不再累述。In steps S121 to S123 , how to perform the rocking curve scanning of the preset crystal plane on the scanning point is known to those skilled in the art, and will not be described here.
在步骤S123中,重复步骤S122若干次,重复步骤S122的次数与预设角度的大小有关,预设角度越小,重复步骤S122的次数越多。In step S123, step S122 is repeated several times. The number of times step S122 is repeated is related to the size of the preset angle. The smaller the preset angle is, the more times step S122 is repeated.
具体的,氮化镓衬底10每旋转一次,均会得到一个Omega曲线及Omega曲线的峰值对应的扫描角度;以预设角度记为B为例完成360°旋转为例,扫描结束后,一共可以得到360/B个扫描角度,可以分别记为θ1’、θ2’、θ3’、θ4’…θn’;其中,n=360/B。Specifically, every time the
需要说明的是,由于每旋转一侧得到一个Omega曲线及Omega曲线的峰值对应的扫描角度,故每个Omega曲线及Omega曲线的峰值对应的扫描角度也对应一个氮化镓衬底10在XY平面的旋转角度,譬如,以预设角度记为B为例,首次得到的Omega曲线及Omega曲线的峰值对应的扫描角度二者所对应的氮化镓衬底10在XY平面的旋转角度为0°,旋转一次后得到的Omega曲线及Omega曲线的峰值对应的扫描角度二者所对应的氮化镓衬底10在XY平面的旋转角度为B,旋转两次后得到的Omega曲线及Omega曲线的峰值对应的扫描角度二者所对应的氮化镓衬底10在XY平面的旋转角度为2B,依次类推。It should be noted that, since each rotating side obtains an Omega curve and a scan angle corresponding to the peak of the Omega curve, the scan angle corresponding to each Omega curve and the peak of the Omega curve also corresponds to a
作为示例,在得到多个扫描角度后,将多个扫描角度进行比较,可以从多个扫描角度中选取多个扫描角度中的最大扫描角度θmax和最小扫描角度θmin所对应的样品在XY平面内的旋转角度;最大扫描角度θmax所对应的样品在XY平面内的旋转角度可以记为第一角度Phimax,最小扫描角度θmin所对应的样品在XY平面内的旋转的角度可以记为第二角度Phimin。步骤S121~步骤S123中,每次扫描均可以得到一个Omega曲线,每个Omega曲线会有一个峰值,每一个Omega曲线的峰值对应有一个XRD单晶衍射仪扫描过程中的扫描角度,同时,每个扫描角度对应一个氮化镓衬底10在XY平面内的旋转角度。As an example, after obtaining multiple scanning angles, the multiple scanning angles are compared, and the samples corresponding to the maximum scanning angle θmax and the minimum scanning angle θmin of the multiple scanning angles can be selected from the multiple scanning angles in the XY plane The rotation angle of the sample in the XY plane corresponding to the maximum scanning angle θmax can be recorded as the first angle Phimax, and the rotation angle of the sample corresponding to the minimum scanning angle θmin in the XY plane can be recorded as the second angle Phimin . In steps S121 to S123, an Omega curve can be obtained for each scan, each Omega curve has a peak, and each peak of the Omega curve corresponds to a scanning angle during the scanning process of the XRD single crystal diffractometer. Each scan angle corresponds to a rotation angle of the
在步骤S13中,请参阅图1中的S12及图2至图4,对氮化镓衬底10的W面进行360°Phi扫描,以得到多个与M面对应的Phi值。In step S13 , referring to S12 in FIG. 1 and FIGS. 2 to 4 , a 360° Phi scan is performed on the W surface of the
在一个示例中,如图3所示,氮化镓晶胞101为六面柱体结构,氮化镓衬底10的W面为氮化镓衬底10的M面及氮化镓衬底10的C面(即0001晶面)的交线相平行的面,如图3中与线段AB与C’D’所在的平面,线段A’B’与线段CD所在的平面等等;氮化镓衬底10中的(102)晶面和(114)晶面等均为氮化镓衬底10的W面。In one example, as shown in FIG. 3 , the gallium
由图3可知,氮化镓晶胞101为六面柱体结构,其侧面即为氮化镓衬底10的M面,共有6个M面;对氮化镓衬底10的W面进行多次Phi扫描,可以得到与6个M面一一对应的6个Phi值,即每个M面对应一个Phi扫描的Phi值。6个Phi值可以分别记为Phi1、Phi2、Phi3、Phi4、Phi5和Phi6。需要说明的是,这里的Phi值为Phi扫描过程中对应每个M面的峰值。It can be seen from FIG. 3 that the gallium
需要说明的是,如何对氮化镓衬底10的W面进行360°Phi扫描为本领域技术人员所知晓,此处不再累述。It should be noted that, how to perform 360°Phi scanning on the W surface of the
在步骤S14中,请参阅图1中的S13步骤及图2至图4,基于多个扫描角度中的最大扫描角度、最小扫描角度及多个Phi值,确定氮化镓衬底10中与斜切角最近的M面及与所述斜切角最远的M面。In step S14 , referring to step S13 in FIG. 1 and FIGS. 2 to 4 , based on the maximum scanning angle, the minimum scanning angle and the plurality of Phi values among the plurality of scanning angles, the slope of the
在一个示例中,步骤S14中,基于多个扫描角度中的最大扫描角度所对应的氮化镓衬底10在XY平面内的旋转的第一角度Phimax、多个扫描角度中的最小扫描角度所对应的氮化镓衬底10在XY平面内的旋转的第二角度Phimin及多个Phi值,确定氮化镓衬底10中与斜切角最近的M面及与所述斜切角最远的M面,可以包括:In one example, in step S14, based on the first angle Phimax of the rotation of the
S141:将第一角度Phimax与多个Phi值进行比较,与第一角度Phimax的差值的绝对值小于或等于预设值的Phi值所对应的M面,即为氮化镓衬底10上离斜切角最远的M面;S141 : Compare the first angle Phimax with a plurality of Phi values, and the absolute value of the difference with the first angle Phimax is less than or equal to the preset value of the M surface corresponding to the Phi value, that is, the surface on the
S142:将第二角度Phimin与多个Phi值进行比较,与第二角度Phimin的差值的绝对值小于或等于预设值的Phi值所对应的M面,即为氮化镓衬底10上离斜切角最近的M面。S142 : Compare the second angle Phimin with a plurality of Phi values, and the absolute value of the difference between the second angle Phimin and the second angle Phimin is less than or equal to the preset value of the M surface corresponding to the Phi value, that is, the surface on the
在一个示例中,预设值小于或等于31°;具体的,预设值可以为31°、30°、25°、20°、15°、10°或5°等等;优选地,本实施例中,预设值可以为31°。In one example, the preset value is less than or equal to 31°; specifically, the preset value may be 31°, 30°, 25°, 20°, 15°, 10°, or 5°, etc.; preferably, this implementation For example, the preset value may be 31°.
需要说明的是,多个Phi值中,与第一角度Phimax的差值的绝对值小于或等于预设值的Phi值仅有一个,与第二角度Phimin的差值的绝对值小于或等于预设值的Phi值也仅有一个,而每个Phi值对应一个M面,通过上述氮化镓衬底中M面的确认方法,可以准确确定出氮化镓衬底10中与斜切角最近的M面及氮化镓衬底10中与斜切角最远的M面。It should be noted that, among the multiple Phi values, there is only one Phi value whose absolute value of the difference with the first angle Phimax is less than or equal to the preset value, and the absolute value of the difference with the second angle Phimin is less than or equal to the preset value. There is only one Phi value for the set value, and each Phi value corresponds to an M-plane. Through the confirmation method of the M-plane in the gallium nitride substrate above, it can be accurately determined that the
请结合图1至图4,参阅图5,本申请还提供一种氮化镓衬底的切割方法,氮化镓衬底的切割方法可以包括如下步骤:Please refer to FIG. 5 in conjunction with FIGS. 1 to 4 . The present application further provides a method for cutting a gallium nitride substrate. The method for cutting a gallium nitride substrate may include the following steps:
S20:确定氮化镓衬底10中与斜切角最近的M面及氮化镓衬底10中与斜切角最远的M面;S20: Determine the M-plane closest to the chamfer angle in the
S21:自氮化镓衬底10中与斜切角最近的M面或自氮化镓衬底10中与斜切角最远的M面对氮化镓衬底10进行切割。S21 : The
在生长氮化镓衬底时,氮化镓衬底的物理平面(譬如上表面)和氮化镓晶胞的方向经常存在一定的角度(即斜切角),在这样的前提下,会导致氮化镓晶胞朝所述氮化镓衬底的某个方向倾斜;由于上述氮化镓衬底中M面的确认方法中,利用这种倾斜,通过对氮化镓衬底进行预设晶面的多次摇摆曲线扫描,多个Omega曲线及与多个Omega曲线的峰值对应的多个扫描角度,然后对氮化镓衬底的W面进行多次Phi扫描,以得到多个与M面对应的Phi值,最后基于多个扫描角度中的最大扫描角度、最小扫描角度及多个Phi值,即可准确确认氮化镓衬底中与斜切角最近的M面及与斜切角最远的M面;进而可以确保对氮化镓衬底10进行切割时,可以精确沿着氮化镓衬底10中与斜切角最近的M面或氮化镓衬底中与斜切角最远的M面进行切割,从而确保切割的良率。When growing a gallium nitride substrate, the physical plane (such as the upper surface) of the gallium nitride substrate and the direction of the gallium nitride unit cell often have a certain angle (that is, a chamfered angle). The gallium nitride unit cell is inclined towards a certain direction of the gallium nitride substrate; because in the above-mentioned method for confirming the M plane in the gallium nitride substrate, this inclination is used to pre-crystallize the gallium nitride substrate Multiple rocking curve scans of the surface, multiple Omega curves and multiple scan angles corresponding to the peaks of the multiple Omega curves, and then multiple Phi scans are performed on the W surface of the gallium nitride substrate to obtain multiple and M surfaces. The corresponding Phi value, and finally based on the maximum scanning angle, the minimum scanning angle and the multiple Phi values among the multiple scanning angles, the M-plane closest to the chamfering angle in the gallium nitride substrate and the chamfering angle can be accurately confirmed. The farthest M-plane; thus, it can be ensured that when the
在一个示例中,步骤S20中,可以采用如上述实施例中所述的氮化镓衬底中M面的确认方法确定氮化镓衬底10中与斜切角最近的M面及氮化镓衬底10中与斜切角最远的M面,具体请参阅图1至图4及相关实施例描述,此处不再累述。。In one example, in step S20, the M-plane in the
在步骤S21中,可以采用现有任意一种氮化镓衬底切割方式对氮化镓衬底10进行切割,譬如,线切割或激光切割等等,此处对切割的具体工艺不做限定。In step S21, the
在本说明书的描述中,参考术语“其中一个实施例”、“其他实施例”等的描述意指结合该实施例或示例描述的具体特征、结构、材料或者特征包含于本发明的至少一个实施例或示例中。在本说明书中,对上述术语的示意性描述不一定指的是相同的实施例或示例。In the description of this specification, description with reference to the terms "one of the embodiments", "the other embodiment", etc. means that a particular feature, structure, material or feature described in connection with that embodiment or example is included in at least one implementation of the invention example or example. In this specification, schematic descriptions of the above terms do not necessarily refer to the same embodiment or example.
以上所述实施例的各技术特征可以进行任意的组合,为使描述简洁,未对上述实施例中的各个技术特征所有可能的组合都进行描述。然而,只要这些技术特征的组合不存在矛盾,都应当认为是本说明书记载的范围。The technical features of the above-described embodiments can be combined arbitrarily. To simplify the description, all possible combinations of the technical features of the above-described embodiments are not described. However, as long as there is no contradiction in the combination of these technical features, they should be considered to be within the scope of the description in this specification.
以上所述实施例仅表达了本发明的几种实施方式,其描述较为具体和详细,但并不能因此而理解为对发明专利范围的限制。应当指出的是,对于本领域的普通技术人员来说,在不脱离本发明构思的前提下,还可以做出若干变形和改进,这些都属于本发明的保护范围。因此,本发明专利的保护范围应以所附权利要求为准。The above-mentioned embodiments only represent several embodiments of the present invention, and the descriptions thereof are specific and detailed, but should not be construed as a limitation on the scope of the invention patent. It should be pointed out that for those of ordinary skill in the art, without departing from the concept of the present invention, several modifications and improvements can also be made, which all belong to the protection scope of the present invention. Therefore, the protection scope of the patent of the present invention should be subject to the appended claims.
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