CN114989767B - Special adhesive for Taini repair and repairing method of billiard table cloth - Google Patents
Special adhesive for Taini repair and repairing method of billiard table cloth Download PDFInfo
- Publication number
- CN114989767B CN114989767B CN202210683319.3A CN202210683319A CN114989767B CN 114989767 B CN114989767 B CN 114989767B CN 202210683319 A CN202210683319 A CN 202210683319A CN 114989767 B CN114989767 B CN 114989767B
- Authority
- CN
- China
- Prior art keywords
- parts
- taini
- repair
- special adhesive
- billiard table
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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- 239000000853 adhesive Substances 0.000 title claims abstract description 34
- 230000001070 adhesive effect Effects 0.000 title claims abstract description 34
- 238000000034 method Methods 0.000 title claims abstract description 12
- 239000004744 fabric Substances 0.000 title description 8
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 claims abstract description 18
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims abstract description 9
- 229910000019 calcium carbonate Inorganic materials 0.000 claims abstract description 9
- 239000003054 catalyst Substances 0.000 claims abstract description 8
- 229910021485 fumed silica Inorganic materials 0.000 claims abstract description 7
- FZHAPNGMFPVSLP-UHFFFAOYSA-N silanamine Chemical compound [SiH3]N FZHAPNGMFPVSLP-UHFFFAOYSA-N 0.000 claims abstract description 7
- 239000004432 silane-modified polyurethane Substances 0.000 claims abstract description 7
- 239000000843 powder Substances 0.000 claims description 11
- NKSJNEHGWDZZQF-UHFFFAOYSA-N ethenyl(trimethoxy)silane Chemical compound CO[Si](OC)(OC)C=C NKSJNEHGWDZZQF-UHFFFAOYSA-N 0.000 claims description 5
- 238000004140 cleaning Methods 0.000 claims description 4
- 238000007790 scraping Methods 0.000 claims description 4
- KSBAEPSJVUENNK-UHFFFAOYSA-L tin(ii) 2-ethylhexanoate Chemical compound [Sn+2].CCCCC(CC)C([O-])=O.CCCCC(CC)C([O-])=O KSBAEPSJVUENNK-UHFFFAOYSA-L 0.000 claims description 3
- LSZKGNJKKQYFLR-UHFFFAOYSA-J tri(butanoyloxy)stannyl butanoate Chemical compound [Sn+4].CCCC([O-])=O.CCCC([O-])=O.CCCC([O-])=O.CCCC([O-])=O LSZKGNJKKQYFLR-UHFFFAOYSA-J 0.000 claims description 3
- NBJODVYWAQLZOC-UHFFFAOYSA-L [dibutyl(octanoyloxy)stannyl] octanoate Chemical compound CCCCCCCC(=O)O[Sn](CCCC)(CCCC)OC(=O)CCCCCCC NBJODVYWAQLZOC-UHFFFAOYSA-L 0.000 claims 1
- 239000006087 Silane Coupling Agent Substances 0.000 abstract description 4
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical group [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 abstract description 3
- 239000003292 glue Substances 0.000 abstract description 3
- 229910052710 silicon Inorganic materials 0.000 abstract description 3
- 239000010703 silicon Substances 0.000 abstract description 3
- 238000007711 solidification Methods 0.000 abstract description 2
- 230000008023 solidification Effects 0.000 abstract description 2
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 14
- 229910052742 iron Inorganic materials 0.000 description 7
- 238000010438 heat treatment Methods 0.000 description 4
- 229920000433 Lyocell Polymers 0.000 description 2
- 238000010409 ironing Methods 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 229910002027 silica gel Inorganic materials 0.000 description 2
- 239000000741 silica gel Substances 0.000 description 2
- 239000002318 adhesion promoter Substances 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- AYOHIQLKSOJJQH-UHFFFAOYSA-N dibutyltin Chemical compound CCCC[Sn]CCCC AYOHIQLKSOJJQH-UHFFFAOYSA-N 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 239000000945 filler Substances 0.000 description 1
- 239000001046 green dye Substances 0.000 description 1
- 230000007774 longterm Effects 0.000 description 1
- 239000003607 modifier Substances 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 230000036632 reaction speed Effects 0.000 description 1
- 239000012763 reinforcing filler Substances 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J175/00—Adhesives based on polyureas or polyurethanes; Adhesives based on derivatives of such polymers
- C09J175/04—Polyurethanes
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
- C09J11/02—Non-macromolecular additives
- C09J11/04—Non-macromolecular additives inorganic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
- C09J11/02—Non-macromolecular additives
- C09J11/06—Non-macromolecular additives organic
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/24—Acids; Salts thereof
- C08K3/26—Carbonates; Bicarbonates
- C08K2003/265—Calcium, strontium or barium carbonate
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/011—Nanostructured additives
Abstract
The invention belongs to the technical field of billiard table repair, and particularly relates to special glue for billiard table repair and a billiard table surface repair method. The special adhesive for the Taini repair comprises the following components in parts by weight: 40-50 parts of silane modified polyurethane, 0-15 parts of silane coupling agent, 5-40 parts of fumed silica, 1-10 parts of aminosilane, 30-40 parts of nano calcium carbonate, 0.1-5 parts of catalyst and 1-5 parts of color paste. The special adhesive for the Taini repair is a silicon-based adhesive, becomes soft after solidification, does not harden or harden, keeps the softness similar to the Taini and can keep the table top flat.
Description
Technical Field
The invention belongs to the technical field of billiard table repair, and particularly relates to special glue for billiard table repair and a billiard table surface repair method.
Background
Billiards, which are indoor sports, are also called billiards and billiards, are indoor entertainment sports items which are hit by a billiard rod on a table and determine the success or failure of a match by calculating scores. Billiards are transmitted into China at the end of the 19 th century, and are increasingly popular with people along with the development of the age, so that the billiards become public entertainment projects.
In the billiard playing process, the tablecloth is easy to damage, and only one piece of tablecloth is damaged, so that a new tablecloth needs to be replaced, and the cost is very high.
Disclosure of Invention
Aiming at the problems, the invention provides the special adhesive for repairing the billiard table cloth and the billiard table cloth repairing method, which solve the problems, and can repair damaged table cloth in time, thereby prolonging the service life of the table cloth.
In order to achieve the above purpose, the technical scheme of the invention is as follows: the special adhesive for the Taini repair comprises the following components in parts by weight: 40-50 parts of silane modified polyurethane, 0-15 parts of silane coupling agent, 5-40 parts of fumed silica, 1-10 parts of aminosilane, 30-40 parts of nano calcium carbonate, 0.1-5 parts of catalyst and 1-5 parts of color paste.
The special adhesive for the Taini repair comprises the following components in parts by weight: 45 parts of silane modified polyurethane, 8 parts of silane coupling agent, 5 parts of fumed silica, 5 parts of aminosilane, 30 parts of nano calcium carbonate, 4 parts of catalyst and 3 parts of color paste.
The special adhesive for the Taini repair is characterized in that the silane coupling agent is vinyl trimethoxy silane.
The catalyst is one or more of stannous octoate, tin butyrate and dibutyl tin dioctate.
The particle size of the nano calcium carbonate is 0.01-0.1 mu m.
A repairing method of billiard table top comprises the following steps:
1) Cleaning the damaged part of the billiard table surface, and smearing a proper amount of the special adhesive for repairing the billiard table surface;
2) Scraping the surface of the special adhesive for repairing the Taini, and uniformly sprinkling the Taini fine powder;
3) And heating the green fine powder part at high temperature.
The repairing method of the billiard table top comprises the step of heating at a high temperature of 70-80 ℃ for 8-10min.
In the invention, the silane modified polyurethane is a main base material, and can be well adhered to materials difficult to adhere compared with common silica gel. Vinyl trimethoxy silane is an adhesion promoter and a surface modifier, and is also used as a system water removing agent, so that the long-term storage performance of the product is improved. Fumed silica is used as a reinforcing filler to improve the strength of the silica gel. Aminosilane is the adhesive. The nano calcium carbonate can improve the physical and mechanical properties of the whole body and improve the bonding strength. The catalyst can accelerate the reaction speed of the system. The color paste is used for matching the special glue for the Taini repair with the color of the billiard ball.
The invention has the beneficial effects that:
1. the technology of the invention adopts a process of combining the high-temperature adhesive and the table mud fine powder.
2. The special adhesive for the Taini repair is a silicon-based adhesive, becomes soft after solidification, does not harden or harden, keeps the softness similar to the Taini and can keep the table top flat.
3. The special adhesive for repairing the tencel has the advantages of high temperature resistance of 180 ℃, heat resistance time of more than 5 seconds, no softening and deformation when the tencel is ironed by using a high-temperature iron, and good adhesive force.
4. The special adhesive for the Taini repair is doped with the silicon-based green dye, so that the color of the repaired part is consistent with that of the Taini.
5. The special adhesive for the Taini repair is moderate in adhesiveness, and can be adhered and removed when the Taini is replaced. Without damaging the mesa or leaving a hard residue.
6. The special adhesive for the Taini repair is matched with 120-mesh Taini fine powder for use. The powder acts as a breakage filler. I.e. to maintain mesa flatness. The friction force between the repair part and the surface of the Taini is kept consistent, and in addition, the color of the repair part and the original Taini is kept consistent. So-called "tri-coincidence". The flatness is consistent, the friction force is consistent, and the surface color is consistent.
7. The special adhesive for Taini repair has the advantages of low cost, suitability for civil use, normal-temperature storage and the like. .
Drawings
FIG. 1 is a billiard cue before repair.
FIG. 2 shows a billiard cue after being repaired by a Taini repair adhesive.
FIG. 3 is a billiard cue before repair.
FIG. 4 shows a billiard cue after being repaired by a Taini repair adhesive.
Detailed Description
Example 1
The special adhesive for the Taini repair comprises the following components in parts by weight:
45 parts of silane modified polyurethane, 8 parts of vinyl trimethoxysilane, 5 parts of fumed silica, 5 parts of aminosilane, 30 parts of nano calcium carbonate with the diameter of 0.01-0.1 mu m, 4 parts of stannous octoate serving as a catalyst and 3 parts of color paste with the same color as that of Taini, and uniformly mixing the components to obtain the adhesive special for Taini repair.
All the above components are commercially available.
A repairing method of billiard table top comprises the following steps:
1) As shown in fig. 1, cleaning the damaged part of the billiard table surface, and smearing proper amount of special adhesive for repairing the billiard according to the damaged area of the billiard cloth;
2) Scraping the surface of the special adhesive for repairing the Taini, and uniformly sprinkling the Taini fine powder;
3) Flattening the fine powder with an electric iron, heating to 70-80deg.C, and maintaining for 8-10min.
4) And (5) turning off the power supply of the electric iron, and continuously ironing the wound surface for 1-3min by utilizing the residual temperature of the electric iron.
The repaired tablecloth was flattened as shown in fig. 2. No trace of damage was seen at all.
Example 2
The special adhesive for the Taini repair comprises the following components in parts by weight: 50 parts of silane modified polyurethane, 10 parts of vinyl trimethoxysilane, 10 parts of fumed silica, 8 parts of aminosilane, 40 parts of nano calcium carbonate, 5 parts of tin butyrate, 4 parts of color paste with the same color as that of tenny, and uniformly mixing the above components to obtain the tenny repair special adhesive.
All the above components are commercially available.
A repairing method of billiard table top comprises the following steps:
1) As shown in fig. 3, cleaning the damaged part of the billiard table surface, and smearing proper amount of special adhesive for repairing the billiard according to the damaged area of the billiard cloth;
2) Scraping the surface of the special adhesive for repairing the Taini, and uniformly sprinkling the Taini fine powder;
3) Flattening the fine powder with an electric iron, heating to 70-80deg.C, and maintaining for 8-10min.
4) And (5) turning off the power supply of the electric iron, and continuously ironing the wound surface for 1-3min by utilizing the residual temperature of the electric iron.
The repaired tablecloth is flat as before. As shown in fig. 4, no trace of damage is seen at all.
Claims (1)
1. A repairing method of a billiard table surface is characterized by comprising the following steps:
1) Cleaning damaged parts of billiard table tops, and smearing proper amount of special adhesive for repairing billiard;
2) Scraping the surface of the special adhesive for repairing the Taini, and uniformly sprinkling the Taini fine powder;
3) Preserving the temperature of the green fine powder part at 70-80deg.C for 8-10min;
the special adhesive for the Taini repair comprises the following components in parts by weight: 45 parts of silane modified polyurethane, 8 parts of vinyl trimethoxy silane, 5 parts of fumed silica, 5 parts of aminosilane, 30 parts of nano calcium carbonate, 4 parts of a catalyst and 3 parts of color paste;
the catalyst is one or more than two of stannous octoate, tin butyrate and dibutyl tin dioctanoate;
the grain diameter of the nano calcium carbonate is 0.01-0.1 mu m.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN202210683319.3A CN114989767B (en) | 2022-06-17 | 2022-06-17 | Special adhesive for Taini repair and repairing method of billiard table cloth |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN202210683319.3A CN114989767B (en) | 2022-06-17 | 2022-06-17 | Special adhesive for Taini repair and repairing method of billiard table cloth |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN114989767A CN114989767A (en) | 2022-09-02 |
| CN114989767B true CN114989767B (en) | 2024-01-02 |
Family
ID=83034639
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN202210683319.3A Active CN114989767B (en) | 2022-06-17 | 2022-06-17 | Special adhesive for Taini repair and repairing method of billiard table cloth |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN114989767B (en) |
Citations (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR20000021199A (en) * | 1998-09-28 | 2000-04-25 | 김종길 | Repairing adhesives of covering cloth for billiard table |
| KR20110024499A (en) * | 2009-09-02 | 2011-03-09 | (주)삼중 | Siloxane modified isocyanate alkoxy silane compound, preparation method thereof, and the use thereof |
| CN102181257A (en) * | 2011-01-31 | 2011-09-14 | 北京东方雨虹防水技术股份有限公司 | Single-component silane modified polyurethane sealant and preparation method |
| CN105038681A (en) * | 2015-08-28 | 2015-11-11 | 上海蒂姆新材料科技有限公司 | Silane modified resin sealing gum and preparing method thereof |
| CN106318307A (en) * | 2016-08-31 | 2017-01-11 | 江苏创景科技有限公司 | Special adhesive used for ceramic tile and realizing high hardness, high brightness and mould prevention |
| CN208287460U (en) * | 2018-02-09 | 2018-12-28 | 曹侃 | Shield Buddhist nun for billiard table Buddhist nun pastes |
| CN113463406A (en) * | 2021-07-16 | 2021-10-01 | 李妮头 | Soft wear-resistant non-woven fabric and preparation method thereof |
-
2022
- 2022-06-17 CN CN202210683319.3A patent/CN114989767B/en active Active
Patent Citations (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR20000021199A (en) * | 1998-09-28 | 2000-04-25 | 김종길 | Repairing adhesives of covering cloth for billiard table |
| KR20110024499A (en) * | 2009-09-02 | 2011-03-09 | (주)삼중 | Siloxane modified isocyanate alkoxy silane compound, preparation method thereof, and the use thereof |
| CN102181257A (en) * | 2011-01-31 | 2011-09-14 | 北京东方雨虹防水技术股份有限公司 | Single-component silane modified polyurethane sealant and preparation method |
| CN105038681A (en) * | 2015-08-28 | 2015-11-11 | 上海蒂姆新材料科技有限公司 | Silane modified resin sealing gum and preparing method thereof |
| CN106318307A (en) * | 2016-08-31 | 2017-01-11 | 江苏创景科技有限公司 | Special adhesive used for ceramic tile and realizing high hardness, high brightness and mould prevention |
| CN208287460U (en) * | 2018-02-09 | 2018-12-28 | 曹侃 | Shield Buddhist nun for billiard table Buddhist nun pastes |
| CN113463406A (en) * | 2021-07-16 | 2021-10-01 | 李妮头 | Soft wear-resistant non-woven fabric and preparation method thereof |
Non-Patent Citations (3)
| Title |
|---|
| 快速硫化有机硅改性聚氨酯密封胶的研制;张剑;黄活阳;王奉平;;有机硅材料(02);第120-123页 * |
| 赵喜桢 ; 张继承 ; .钢轨绝缘修补密封胶的研究.功能材料.2020,(06),第6108-6113页. * |
| 钢轨绝缘修补密封胶的研究;赵喜桢;张继承;;功能材料(06);第6108-6113页 * |
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| CN114989767A (en) | 2022-09-02 |
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