CN114989767A - Special glue for repairing Taini and repairing method of billiard tablecloth - Google Patents
Special glue for repairing Taini and repairing method of billiard tablecloth Download PDFInfo
- Publication number
- CN114989767A CN114989767A CN202210683319.3A CN202210683319A CN114989767A CN 114989767 A CN114989767 A CN 114989767A CN 202210683319 A CN202210683319 A CN 202210683319A CN 114989767 A CN114989767 A CN 114989767A
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- CN
- China
- Prior art keywords
- parts
- repairing
- taini
- special
- glue
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- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000003292 glue Substances 0.000 title claims abstract description 33
- 238000000034 method Methods 0.000 title claims abstract description 13
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 claims abstract description 20
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims abstract description 10
- 229910000019 calcium carbonate Inorganic materials 0.000 claims abstract description 10
- 239000004432 silane-modified polyurethane Substances 0.000 claims abstract description 9
- 239000003054 catalyst Substances 0.000 claims abstract description 8
- 229910021485 fumed silica Inorganic materials 0.000 claims abstract description 8
- FZHAPNGMFPVSLP-UHFFFAOYSA-N silanamine Chemical compound [SiH3]N FZHAPNGMFPVSLP-UHFFFAOYSA-N 0.000 claims abstract description 8
- 239000006087 Silane Coupling Agent Substances 0.000 claims abstract description 7
- 239000000843 powder Substances 0.000 claims description 11
- 238000010438 heat treatment Methods 0.000 claims description 6
- 239000000853 adhesive Substances 0.000 claims description 5
- 230000001070 adhesive effect Effects 0.000 claims description 5
- NKSJNEHGWDZZQF-UHFFFAOYSA-N ethenyl(trimethoxy)silane Chemical group CO[Si](OC)(OC)C=C NKSJNEHGWDZZQF-UHFFFAOYSA-N 0.000 claims description 5
- KSBAEPSJVUENNK-UHFFFAOYSA-L tin(ii) 2-ethylhexanoate Chemical compound [Sn+2].CCCCC(CC)C([O-])=O.CCCCC(CC)C([O-])=O KSBAEPSJVUENNK-UHFFFAOYSA-L 0.000 claims description 3
- FERIUCNNQQJTOY-UHFFFAOYSA-M Butyrate Chemical compound CCCC([O-])=O FERIUCNNQQJTOY-UHFFFAOYSA-M 0.000 claims description 2
- FERIUCNNQQJTOY-UHFFFAOYSA-N Butyric acid Natural products CCCC(O)=O FERIUCNNQQJTOY-UHFFFAOYSA-N 0.000 claims description 2
- NBJODVYWAQLZOC-UHFFFAOYSA-L [dibutyl(octanoyloxy)stannyl] octanoate Chemical compound CCCCCCCC(=O)O[Sn](CCCC)(CCCC)OC(=O)CCCCCCC NBJODVYWAQLZOC-UHFFFAOYSA-L 0.000 claims description 2
- 238000004140 cleaning Methods 0.000 claims description 2
- 239000002245 particle Substances 0.000 claims 1
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 abstract description 3
- 229910052710 silicon Inorganic materials 0.000 abstract description 3
- 239000010703 silicon Substances 0.000 abstract description 3
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 16
- 239000004744 fabric Substances 0.000 description 12
- 229910052742 iron Inorganic materials 0.000 description 8
- 238000010409 ironing Methods 0.000 description 3
- 229910002027 silica gel Inorganic materials 0.000 description 2
- 239000000741 silica gel Substances 0.000 description 2
- 238000003860 storage Methods 0.000 description 2
- 239000002318 adhesion promoter Substances 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 239000011230 binding agent Substances 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 239000003431 cross linking reagent Substances 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 239000000945 filler Substances 0.000 description 1
- 239000001046 green dye Substances 0.000 description 1
- 230000007774 longterm Effects 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 239000003607 modifier Substances 0.000 description 1
- 230000036632 reaction speed Effects 0.000 description 1
- 239000012763 reinforcing filler Substances 0.000 description 1
- 238000005507 spraying Methods 0.000 description 1
- 239000000758 substrate Substances 0.000 description 1
- LSZKGNJKKQYFLR-UHFFFAOYSA-J tri(butanoyloxy)stannyl butanoate Chemical compound [Sn+4].CCCC([O-])=O.CCCC([O-])=O.CCCC([O-])=O.CCCC([O-])=O LSZKGNJKKQYFLR-UHFFFAOYSA-J 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
Images
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J175/00—Adhesives based on polyureas or polyurethanes; Adhesives based on derivatives of such polymers
- C09J175/04—Polyurethanes
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
- C09J11/02—Non-macromolecular additives
- C09J11/04—Non-macromolecular additives inorganic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
- C09J11/02—Non-macromolecular additives
- C09J11/06—Non-macromolecular additives organic
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/24—Acids; Salts thereof
- C08K3/26—Carbonates; Bicarbonates
- C08K2003/265—Calcium, strontium or barium carbonate
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/011—Nanostructured additives
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Adhesives Or Adhesive Processes (AREA)
Abstract
The invention belongs to the technical field of billiard table repair, and particularly relates to special glue for repairing a billiard table and a billiard table surface repairing method. The special glue for repairing the Taini comprises the following components in parts by weight: 40-50 parts of silane modified polyurethane, 0-15 parts of silane coupling agent, 5-40 parts of fumed silica, 1-10 parts of aminosilane, 30-40 parts of nano calcium carbonate, 0.1-5 parts of catalyst and 1-5 parts of color paste. The glue special for repairing the Taini is a silicon-based glue, is soft after being cured, is not hardened and hardened, keeps the softness similar to that of the Taini and can keep the flat table surface.
Description
Technical Field
The invention belongs to the technical field of billiard table repair, and particularly relates to special glue for repairing a billiard table and a billiard table surface repairing method.
Background
Billiards, also called table tennis and billiards, are indoor entertainment sports which use a ball rod to strike balls on a table and determine the success or failure of a game by calculating scores. Billiards are introduced into China at the end of the 19 th century, and are increasingly popular with people with the development of the times, so that the billiards become popular entertainment projects.
In the process of playing billiards, the tablecloth is very easy to damage, and only one piece of tablecloth is damaged, a new piece of tablecloth needs to be replaced, so that the cost is very high.
Disclosure of Invention
Aiming at the problems, the invention provides the special glue for repairing the billiard table cloth and the method for repairing the billiard table cloth, which solve the problems, can repair the damaged table cloth in time and prolong the service life of the table cloth.
In order to achieve the purpose, the technical scheme of the invention is as follows: the special glue for repairing the Taini comprises the following components in parts by weight: 40-50 parts of silane modified polyurethane, 0-15 parts of silane coupling agent, 5-40 parts of fumed silica, 1-10 parts of aminosilane, 30-40 parts of nano calcium carbonate, 0.1-5 parts of catalyst and 1-5 parts of color paste.
The special glue for repairing the Taini comprises the following components in parts by weight: 45 parts of silane modified polyurethane, 8 parts of silane coupling agent, 5 parts of fumed silica, 5 parts of aminosilane, 30 parts of nano calcium carbonate, 4 parts of catalyst and 3 parts of color paste.
In the above special glue for repairing the tinib, the silane coupling agent is vinyl trimethoxy silane.
The catalyst is one or more than two of stannous octoate, stannic butyrate and dibutyltin dioctoate.
The size of the nano calcium carbonate is 0.01-0.1 μm.
A billiard table surface repairing method comprises the following steps:
1) cleaning up the damaged part of the billiard table surface, and coating a proper amount of the special glue for repairing the Taini;
2) strickling the surface of the glue special for repairing the Taini and uniformly spraying the Taini fine powder;
3) heating the green fine powder part at high temperature.
In the repairing method of the billiard table surface, the high-temperature heating is carried out for 8-10min at the temperature of 70-80 ℃.
In the invention, the silane modified polyurethane is a main substrate, and compared with common silica gel, the silane modified polyurethane can well bond materials which are difficult to bond. The vinyl trimethoxy silane is an adhesion promoter, a surface modifier and a system water removing agent, and the long-term storage performance of the product is improved. The fumed silica is used as a reinforcing filler to improve the strength of the silica gel. Aminosilane is a binder. The nano calcium carbonate can improve the overall physical and mechanical properties and improve the bonding strength. The catalyst can accelerate the reaction speed of the system. The color paste is used to match the billiard color with the special glue for repairing the billiards.
The invention has the beneficial effects that:
1. the technology of the invention adopts a process of matching the high-temperature crosslinking agent and the Taiwan mud fine powder.
2. The glue special for repairing the Taini is a silicon-based glue, is soft after being cured, is not hardened and hardened, keeps the softness similar to that of the Taini and can keep the flat table surface.
3. The special glue for repairing the Taini resists high temperature of 180 ℃ for more than 5 seconds, does not soften or deform when ironing the Taini by using a high-temperature iron, and also has good bonding force.
4. The adhesive special for repairing the Taini is blended with a silicon-based green dye, so that the color of a repaired part is consistent with that of the Taini.
5. The special adhesive for repairing the Taini is moderate in viscosity, can be adhered and can be torn off when the Taini is replaced. So as not to damage the table top or leave hard residues.
6. The glue special for repairing the Tsuny is matched with 120-mesh Tsuny fine powder for use together. The powder acts as a break-up filler. I.e. maintaining the flatness of the mesa. The surface friction force of the repaired part is kept consistent with that of the Taini, and in addition, the color of the repaired part is kept consistent with that of the original Taini. So-called "triple agreement". The flatness is consistent, the friction force is consistent, and the surface color is consistent.
7. The special adhesive for repairing the teny also has the advantages of low manufacturing cost, suitability for civil use, normal-temperature storage and the like. .
Drawings
FIG. 1 shows a billiard table cloth before repair.
FIG. 2 shows the billiard table cloth repaired by the special glue for repairing the billiard table cloth.
FIG. 3 shows the billiard table cloth before repair.
FIG. 4 is a billiard table cloth repaired by the special glue for repairing the billiard table cloth.
Detailed Description
Example 1
The special glue for repairing the Taini comprises the following components in parts by weight:
45 parts of silane modified polyurethane, 8 parts of vinyl trimethoxy silane, 5 parts of fumed silica, 5 parts of amino silane, 30 parts of 0.01-0.1 mu m nano calcium carbonate, 4 parts of catalyst stannous octoate and 3 parts of color paste with the same color as the Taini, and the components are uniformly mixed to obtain the Taini repairing special glue.
The above components are all commercially available.
A repairing method of a billiard table surface comprises the following steps:
1) as shown in fig. 1, the damaged part of the billiard table surface is cleaned up, and a proper amount of special adhesive for repairing the billiard table cloth is coated according to the damaged area of the billiard table cloth;
2) the surface of the glue special for repairing the Taini is scraped off and evenly sprinkled with the Taini fine powder;
3) flattening the fine powder with an electric iron, heating to 70-80 deg.C, and maintaining for 8-10 min.
4) And (4) turning off the power supply of the electric iron, and continuously ironing the wound surface for 1-3min by using the residual temperature of the electric iron.
The repaired tablecloth is flat as before, as shown in figure 2. No trace of damage was visible at all.
Example 2
The special glue for repairing the Taini comprises the following components in parts by weight: 50 parts of silane modified polyurethane, 10 parts of vinyl trimethoxy silane, 10 parts of fumed silica, 8 parts of amino silane, 40 parts of nano calcium carbonate, 5 parts of tin butyrate and 4 parts of color paste with the same color as the Taini are uniformly mixed to obtain the special glue for repairing the Taini.
The above components are all commercially available.
A billiard table surface repairing method comprises the following steps:
1) as shown in fig. 3, the damaged part of the billiard table surface is cleaned up, and a proper amount of special glue for repairing the taini is coated according to the damaged area of the tablecloth;
2) the surface of the glue special for repairing the Taini is scraped off and evenly sprinkled with the Taini fine powder;
3) flattening the fine powder with an electric iron, heating the electric iron to 70-80 deg.C, and maintaining for 8-10 min.
4) And (4) turning off the power supply of the electric iron, and continuously ironing the wound surface for 1-3min by using the residual temperature of the electric iron.
The repaired tablecloth is flat as before. As shown in fig. 4, no trace of damage was recognized at all.
Claims (7)
1. The special glue for repairing the Taini is characterized by comprising the following components in parts by weight: 40-50 parts of silane modified polyurethane, 0-15 parts of silane coupling agent, 5-40 parts of fumed silica, 1-10 parts of aminosilane, 30-40 parts of nano calcium carbonate, 0.1-5 parts of catalyst and 1-5 parts of color paste.
2. The special glue for repairing the Taney as claimed in claim 1, which is characterized by comprising the following components in parts by weight: 45 parts of silane modified polyurethane, 8 parts of silane coupling agent, 5 parts of fumed silica, 5 parts of aminosilane, 30 parts of nano calcium carbonate, 4 parts of catalyst and 3 parts of color paste.
3. The special glue for repairing Tainy according to claim 1 or 2, wherein the silane coupling agent is vinyltrimethoxysilane.
4. The special glue for repairing tinia according to claim 1 or 2, characterized in that the catalyst is one or more than two of stannous octoate, stannic butyrate and dibutyltin dioctoate.
5. The special glue for repairing Taney as claimed in claim 1 or 2, wherein the particle size of the nano calcium carbonate is 0.01-0.1 μm.
6. A billiard table surface repairing method is characterized by comprising the following steps:
1) cleaning up the damaged part of the billiard table surface, and smearing a proper amount of the special adhesive for repairing the Taini according to claim 1;
2) the surface of the glue special for repairing the Taini is scraped off and evenly sprinkled with the Taini fine powder;
3) heating the green fine powder part at high temperature.
7. A method for repairing a billiard table surface as claimed in claim 6, wherein said high temperature heating is performed at 70-80 deg.C for 8-10 min.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN202210683319.3A CN114989767B (en) | 2022-06-17 | 2022-06-17 | Special adhesive for Taini repair and repairing method of billiard table cloth |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN202210683319.3A CN114989767B (en) | 2022-06-17 | 2022-06-17 | Special adhesive for Taini repair and repairing method of billiard table cloth |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN114989767A true CN114989767A (en) | 2022-09-02 |
| CN114989767B CN114989767B (en) | 2024-01-02 |
Family
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Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN202210683319.3A Active CN114989767B (en) | 2022-06-17 | 2022-06-17 | Special adhesive for Taini repair and repairing method of billiard table cloth |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN114989767B (en) |
Citations (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR20000021199A (en) * | 1998-09-28 | 2000-04-25 | 김종길 | Repairing adhesives of covering cloth for billiard table |
| KR20110024499A (en) * | 2009-09-02 | 2011-03-09 | (주)삼중 | Siloxane modified isocyanate alkoxy silane compound, preparation method thereof, and the use thereof |
| CN102181257A (en) * | 2011-01-31 | 2011-09-14 | 北京东方雨虹防水技术股份有限公司 | Single-component silane modified polyurethane sealant and preparation method |
| CN105038681A (en) * | 2015-08-28 | 2015-11-11 | 上海蒂姆新材料科技有限公司 | Silane modified resin sealing gum and preparing method thereof |
| CN106318307A (en) * | 2016-08-31 | 2017-01-11 | 江苏创景科技有限公司 | Special adhesive used for ceramic tile and realizing high hardness, high brightness and mould prevention |
| CN208287460U (en) * | 2018-02-09 | 2018-12-28 | 曹侃 | Shield Buddhist nun for billiard table Buddhist nun pastes |
| CN113463406A (en) * | 2021-07-16 | 2021-10-01 | 李妮头 | Soft wear-resistant non-woven fabric and preparation method thereof |
-
2022
- 2022-06-17 CN CN202210683319.3A patent/CN114989767B/en active Active
Patent Citations (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR20000021199A (en) * | 1998-09-28 | 2000-04-25 | 김종길 | Repairing adhesives of covering cloth for billiard table |
| KR20110024499A (en) * | 2009-09-02 | 2011-03-09 | (주)삼중 | Siloxane modified isocyanate alkoxy silane compound, preparation method thereof, and the use thereof |
| CN102181257A (en) * | 2011-01-31 | 2011-09-14 | 北京东方雨虹防水技术股份有限公司 | Single-component silane modified polyurethane sealant and preparation method |
| CN105038681A (en) * | 2015-08-28 | 2015-11-11 | 上海蒂姆新材料科技有限公司 | Silane modified resin sealing gum and preparing method thereof |
| CN106318307A (en) * | 2016-08-31 | 2017-01-11 | 江苏创景科技有限公司 | Special adhesive used for ceramic tile and realizing high hardness, high brightness and mould prevention |
| CN208287460U (en) * | 2018-02-09 | 2018-12-28 | 曹侃 | Shield Buddhist nun for billiard table Buddhist nun pastes |
| CN113463406A (en) * | 2021-07-16 | 2021-10-01 | 李妮头 | Soft wear-resistant non-woven fabric and preparation method thereof |
Non-Patent Citations (2)
| Title |
|---|
| 张剑;黄活阳;王奉平;: "快速硫化有机硅改性聚氨酯密封胶的研制", 有机硅材料, no. 02, pages 120 - 123 * |
| 赵喜桢;张继承;: "钢轨绝缘修补密封胶的研究", 功能材料, no. 06, pages 6108 - 6113 * |
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| Publication number | Publication date |
|---|---|
| CN114989767B (en) | 2024-01-02 |
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