CN114959694A - Stomach wall cutting machinery hand - Google Patents

Stomach wall cutting machinery hand Download PDF

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Publication number
CN114959694A
CN114959694A CN202210737445.2A CN202210737445A CN114959694A CN 114959694 A CN114959694 A CN 114959694A CN 202210737445 A CN202210737445 A CN 202210737445A CN 114959694 A CN114959694 A CN 114959694A
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weight
parts
substrate material
surface modification
cladding process
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CN114959694B (en
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欧阳锡武
姚磊
白宁
宁彩虹
王志明
欧阳辉
李新营
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Xiangya Hospital of Central South University
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Xiangya Hospital of Central South University
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    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23CCOATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C24/00Coating starting from inorganic powder
    • C23C24/08Coating starting from inorganic powder by application of heat or pressure and heat
    • C23C24/10Coating starting from inorganic powder by application of heat or pressure and heat with intermediate formation of a liquid phase in the layer
    • C23C24/103Coating with metallic material, i.e. metals or metal alloys, optionally comprising hard particles, e.g. oxides, carbides or nitrides
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61BDIAGNOSIS; SURGERY; IDENTIFICATION
    • A61B34/00Computer-aided surgery; Manipulators or robots specially adapted for use in surgery
    • A61B34/70Manipulators specially adapted for use in surgery
    • CCHEMISTRY; METALLURGY
    • C21METALLURGY OF IRON
    • C21DMODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D6/00Heat treatment of ferrous alloys
    • C21D6/04Hardening by cooling below 0 degrees Celsius
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C29/00Alloys based on carbides, oxides, nitrides, borides, or silicides, e.g. cermets, or other metal compounds, e.g. oxynitrides, sulfides
    • C22C29/02Alloys based on carbides, oxides, nitrides, borides, or silicides, e.g. cermets, or other metal compounds, e.g. oxynitrides, sulfides based on carbides or carbonitrides
    • C22C29/06Alloys based on carbides, oxides, nitrides, borides, or silicides, e.g. cermets, or other metal compounds, e.g. oxynitrides, sulfides based on carbides or carbonitrides based on carbides, but not containing other metal compounds
    • C22C29/067Alloys based on carbides, oxides, nitrides, borides, or silicides, e.g. cermets, or other metal compounds, e.g. oxynitrides, sulfides based on carbides or carbonitrides based on carbides, but not containing other metal compounds comprising a particular metallic binder
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C30/00Alloys containing less than 50% by weight of each constituent
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C38/00Ferrous alloys, e.g. steel alloys
    • C22C38/002Ferrous alloys, e.g. steel alloys containing In, Mg, or other elements not provided for in one single group C22C38/001 - C22C38/60
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C38/00Ferrous alloys, e.g. steel alloys
    • C22C38/06Ferrous alloys, e.g. steel alloys containing aluminium
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C38/00Ferrous alloys, e.g. steel alloys
    • C22C38/14Ferrous alloys, e.g. steel alloys containing titanium or zirconium
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P10/00Technologies related to metal processing
    • Y02P10/25Process efficiency

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • Materials Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Surgery (AREA)
  • Robotics (AREA)
  • Heart & Thoracic Surgery (AREA)
  • Nuclear Medicine, Radiotherapy & Molecular Imaging (AREA)
  • Physics & Mathematics (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Thermal Sciences (AREA)
  • Biomedical Technology (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medical Informatics (AREA)
  • Molecular Biology (AREA)
  • Animal Behavior & Ethology (AREA)
  • General Health & Medical Sciences (AREA)
  • Public Health (AREA)
  • Veterinary Medicine (AREA)
  • Cleaning And De-Greasing Of Metallic Materials By Chemical Methods (AREA)

Abstract

The invention relates to an abdominal wall cutting manipulator. The method comprises the steps of carrying out surface modification on a substrate material of the abdominal wall cutting manipulator by selecting a laser cladding process and liquid nitrogen cryogenic treatment, wherein the laser cladding process selects mixed powder consisting of 40-50 parts by weight of ZrC, 10-15 parts by weight of Al, 10-29 parts by weight of B and 40-50 parts by weight of Fe, and prepares a composite cladding layer on the surface of the substrate by a synchronous powder feeding method, and then the composite cladding layer is subjected to cryogenic treatment for 120-150min under the condition of liquid nitrogen so as to further improve the wear resistance of the manipulator.

Description

Stomach wall cutting machinery hand
Technical Field
The invention relates to the field of medical instruments, in particular to an abdominal wall cutting manipulator.
Background
With the research and progress of the automation technology in the clinical medical field, the medical manipulator is gradually used in the operation process, and the manipulator can perform the operation which can be completed only by skilled doctors, so that the manipulator has huge application prospect in the medical field. However, since the fine medical manipulator is expensive to manufacture and the corrosion resistance and wear resistance directly determine the lifespan of the manipulator, it is necessary to research a medical manipulator having excellent corrosion resistance and wear resistance.
Disclosure of Invention
Aiming at the problems in the prior art, the invention aims to provide the abdominal wall cutting manipulator which has excellent corrosion resistance and wear resistance.
The invention provides an abdominal wall cutting manipulator which is obtained by performing surface modification treatment on a stainless steel substrate material by using mixed powder, wherein the mixed powder comprises 40-50 parts by weight of ZrC, 10-15 parts by weight of Al, 10-29 parts by weight of B and 40-50 parts by weight of Fe.
Preferably, the surface modification treatment comprises liquid nitrogen cryogenic treatment.
Preferably, the surface modification treatment comprises:
sequentially carrying out oil removal, acid cleaning, polishing, cleaning and drying on a substrate material for later use;
selecting a laser cladding process to carry out surface modification on the substrate material, wherein the laser power in the cladding process is 1000-1200W, the scanning speed is 300-320mm/min, the powder feeding speed is 10-12g/min, the argon flow is 8-10L/min, and the spot diameter is 2-2.5mm, and the cladding process adopts a synchronous powder feeding method;
and soaking the substrate material subjected to surface modification in liquid nitrogen for cryogenic treatment, and taking out after the treatment for 120-150 minutes.
Preferably, the degreasing is performed by using 15% sodium hydroxide solution, the pickling is performed by using 20% hydrochloric acid solution, the polishing is performed in polishing solution containing alumina particles, the cleaning is performed by using ethanol solution and matching ultrasonic waves, and the drying is performed under the nitrogen condition.
Preferably, the laser power in the cladding process is 1000W, the scanning speed is 300mm/min, the powder feeding speed is 10g/min, the argon flow is 10L/min, and the spot diameter is 2 mm.
The method comprises the steps of carrying out surface modification on a substrate material of the abdominal wall cutting manipulator by selecting a laser cladding process and liquid nitrogen cryogenic treatment, wherein the laser cladding process selects mixed powder consisting of 40-50 parts by weight of ZrC, 10-15 parts by weight of Al, 10-29 parts by weight of B and 40-50 parts by weight of Fe, and prepares a composite cladding layer on the surface of the substrate by a synchronous powder feeding method, and then the composite cladding layer is subjected to cryogenic treatment for 120-150min under the condition of liquid nitrogen so as to further improve the wear resistance of the manipulator.
Detailed Description
The technical effects of the present invention are demonstrated below by specific examples, but the embodiments of the present invention are not limited thereto.
Example 1
Cutting stainless steel as substrate material into proper size by machining;
sequentially carrying out oil removal, acid cleaning, polishing, cleaning and drying on a substrate material for later use, wherein 15% of sodium hydroxide solution is selected for oil removal, 20% of hydrochloric acid solution is selected for acid cleaning, polishing is carried out in polishing solution containing alumina particles, ethanol solution is selected for cleaning and matched with ultrasonic waves, and drying is carried out under the condition of nitrogen;
carrying out surface modification on a substrate material by selecting a laser cladding process, wherein the laser power in the cladding process is 1000W, the scanning speed is 300mm/min, the powder feeding speed is 10g/min, the argon flow is 10L/min, the spot diameter is 2mm, the cladding process adopts a synchronous powder feeding method, and the cladding powder raw materials comprise 40 parts by weight of ZrC, 10 parts by weight of Al, 10 parts by weight of B and 40 parts by weight of Fe;
and soaking the substrate material subjected to surface modification in liquid nitrogen at the temperature of-196 ℃ for cryogenic treatment, and taking out the substrate material after 120 minutes of treatment.
Example 2
Cutting stainless steel as substrate material into proper size by machining;
sequentially carrying out oil removal, acid cleaning, polishing, cleaning and drying on a substrate material for later use, wherein 15% of sodium hydroxide solution is selected for oil removal, 20% of hydrochloric acid solution is selected for acid cleaning, polishing is carried out in polishing solution containing alumina particles, ethanol solution is selected for cleaning and matched with ultrasonic waves, and drying is carried out under the condition of nitrogen;
carrying out surface modification on a substrate material by selecting a laser cladding process, wherein the laser power in the cladding process is 1000W, the scanning speed is 300mm/min, the powder feeding speed is 10g/min, the argon flow is 10L/min, the spot diameter is 2mm, the cladding process adopts a synchronous powder feeding method, and the cladding powder raw materials comprise 40 parts by weight of ZrC, 10 parts by weight of Al, 13 parts by weight of B and 40 parts by weight of Fe;
and soaking the substrate material subjected to surface modification in liquid nitrogen at the temperature of-196 ℃ for cryogenic treatment, and taking out the substrate material after 120 minutes of treatment.
Example 3
Cutting stainless steel as substrate material into proper size by machining;
sequentially carrying out oil removal, acid cleaning, polishing, cleaning and drying on a substrate material for later use, wherein 15% of sodium hydroxide solution is selected for oil removal, 20% of hydrochloric acid solution is selected for acid cleaning, polishing is carried out in polishing solution containing alumina particles, ethanol solution is selected for cleaning and matched with ultrasonic waves, and drying is carried out under the condition of nitrogen;
carrying out surface modification on a substrate material by selecting a laser cladding process, wherein the laser power in the cladding process is 1000W, the scanning speed is 300mm/min, the powder feeding speed is 10g/min, the argon flow is 10L/min, the spot diameter is 2mm, the cladding process adopts a synchronous powder feeding method, and the cladding powder raw materials comprise 40 parts by weight of ZrC, 10 parts by weight of Al, 17 parts by weight of B and 40 parts by weight of Fe;
and soaking the substrate material subjected to surface modification in liquid nitrogen at the temperature of-196 ℃ for cryogenic treatment, and taking out the substrate material after 120 minutes of treatment.
Example 4
Cutting stainless steel as substrate material into proper size by machining;
sequentially carrying out oil removal, acid cleaning, polishing, cleaning and drying on a substrate material for later use, wherein 15% of sodium hydroxide solution is selected for oil removal, 20% of hydrochloric acid solution is selected for acid cleaning, polishing is carried out in polishing solution containing alumina particles, ethanol solution is selected for cleaning and matched with ultrasonic waves, and drying is carried out under the condition of nitrogen;
carrying out surface modification on a substrate material by selecting a laser cladding process, wherein the laser power in the cladding process is 1000W, the scanning speed is 300mm/min, the powder feeding speed is 10g/min, the argon flow is 10L/min, the spot diameter is 2mm, the cladding process adopts a synchronous powder feeding method, and the cladding powder raw materials comprise 40 parts by weight of ZrC, 10 parts by weight of Al, 25 parts by weight of B and 40 parts by weight of Fe;
and soaking the substrate material subjected to surface modification in liquid nitrogen at the temperature of-196 ℃ for cryogenic treatment, and taking out the substrate material after 120 minutes of treatment.
Example 5
Cutting stainless steel as substrate material into proper size by machining;
sequentially carrying out oil removal, acid cleaning, polishing, cleaning and drying on a substrate material for later use, wherein 15% of sodium hydroxide solution is selected for oil removal, 20% of hydrochloric acid solution is selected for acid cleaning, polishing is carried out in polishing solution containing alumina particles, ethanol solution is selected for cleaning and matched with ultrasonic waves, and drying is carried out under the condition of nitrogen;
carrying out surface modification on a substrate material by selecting a laser cladding process, wherein the laser power in the cladding process is 1000W, the scanning speed is 300mm/min, the powder feeding speed is 10g/min, the argon flow is 10L/min, the spot diameter is 2mm, the cladding process adopts a synchronous powder feeding method, and the cladding powder raw materials comprise 40 parts by weight of ZrC, 10 parts by weight of Al, 29 parts by weight of B and 40 parts by weight of Fe;
and soaking the substrate material subjected to surface modification in liquid nitrogen at the temperature of-196 ℃ for cryogenic treatment, and taking out the substrate material after 120 minutes of treatment.
Comparative example 1
Cutting stainless steel as substrate material into proper size by machining;
sequentially carrying out oil removal, acid cleaning, polishing, cleaning and drying on a substrate material for later use, wherein 15% sodium hydroxide solution is selected for oil removal, 20% hydrochloric acid solution is selected for acid cleaning, polishing is carried out in polishing solution containing alumina particles, ethanol solution is selected for cleaning and matched with ultrasonic waves, and drying is carried out under the condition of nitrogen;
carrying out surface modification on a substrate material by selecting a laser cladding process, wherein the laser power in the cladding process is 1000W, the scanning speed is 300mm/min, the powder feeding speed is 10g/min, the argon flow is 10L/min, the spot diameter is 2mm, the cladding process adopts a synchronous powder feeding method, and the cladding powder raw materials comprise 40 parts by weight of ZrC, 10 parts by weight of Al, 3 parts by weight of B and 40 parts by weight of Fe;
and soaking the substrate material subjected to surface modification in liquid nitrogen at the temperature of-196 ℃ for cryogenic treatment, and taking out the substrate material after 120 minutes of treatment.
Comparative example 2
Cutting stainless steel as substrate material into proper size by machining;
sequentially carrying out oil removal, acid cleaning, polishing, cleaning and drying on a substrate material for later use, wherein 15% of sodium hydroxide solution is selected for oil removal, 20% of hydrochloric acid solution is selected for acid cleaning, polishing is carried out in polishing solution containing alumina particles, ethanol solution is selected for cleaning and matched with ultrasonic waves, and drying is carried out under the condition of nitrogen;
carrying out surface modification on a substrate material by selecting a laser cladding process, wherein the laser power in the cladding process is 1000W, the scanning speed is 300mm/min, the powder feeding speed is 10g/min, the argon flow is 10L/min, the spot diameter is 2mm, the cladding process adopts a synchronous powder feeding method, and the cladding powder raw materials comprise 40 parts by weight of ZrC, 10 parts by weight of Al, 50 parts by weight of B and 40 parts by weight of Fe;
and soaking the substrate material subjected to surface modification in liquid nitrogen at the temperature of-196 ℃ for cryogenic treatment, and taking out the substrate material after 120 minutes of treatment.
Comparative example 3
Cutting stainless steel as substrate material into proper size by machining;
sequentially carrying out oil removal, acid cleaning, polishing, cleaning and drying on a substrate material for later use, wherein 15% of sodium hydroxide solution is selected for oil removal, 20% of hydrochloric acid solution is selected for acid cleaning, polishing is carried out in polishing solution containing alumina particles, ethanol solution is selected for cleaning and matched with ultrasonic waves, and drying is carried out under the condition of nitrogen;
carrying out surface modification on a substrate material by selecting a laser cladding process, wherein the laser power in the cladding process is 1000W, the scanning speed is 300mm/min, the powder feeding speed is 10g/min, the argon flow is 10L/min, the spot diameter is 2mm, the cladding process adopts a synchronous powder feeding method, and the cladding powder raw materials comprise 40 parts by weight of ZrC, 10 parts by weight of Al, 17 parts by weight of B and 40 parts by weight of Fe;
the inventors tested the corrosion resistance and wear resistance of the samples of examples 1 to 5 and comparative examples 1 to 3 as follows:
and (3) corrosion resistance testing: performing electrochemical test on each sample in simulated body fluid by adopting an electrochemical workstation, sealing a non-working surface by using nail polish, and performing test in a room temperature environment;
and (3) wear resistance test: the wear resistance of each sample is evaluated by adopting a CETR-3 type friction wear testing machine, the load is 5N, the friction pair is a GCr15 steel ball with the diameter of 5mm, the friction frequency is 8Hz, the friction stroke is 3mm, the friction time is 90min, and the mass before and after the wear is weighed by an electronic balance to calculate the wear loss.
The test results of each sample are shown in table 1, in which "√" indicates excellent, "√" indicates acceptable, and "×" indicates unacceptable. Wherein the self-corrosion current density is less than 2.0 x 10 -7 A·cm -2 The rating is excellent, and the self-corrosion current density is between 2.0 x 10 -7 A·cm -2 -5.0*10 -7 A·cm -2 Rated as pass between, the self-corrosion current density was greater than 5.0 x 10 -7 A·cm -2 Grade as unqualified; the grade of the abrasion loss is excellent when the abrasion loss is less than 0.5mg, the grade of the abrasion loss is qualified when the abrasion loss is between 0.5 and 1.0mg, and the grade of the abrasion loss is unqualified when the abrasion loss is more than 1.0 mg.
Table 1 experimental data for each sample
Number of Corrosion resistance Amount of wear
Example 1
Example 2
Example 3
Example 4
Example 5
Comparative example 1 ×
Comparative example 2 ×
Comparative example 3
The above description is only a preferred embodiment of the present invention, and it should be noted that, for those skilled in the art, several modifications and variations can be made without departing from the technical principle of the present invention, and these modifications and variations should also be regarded as the protection scope of the present invention.

Claims (5)

1. The abdominal wall cutting manipulator is characterized by being obtained by carrying out surface modification treatment on a stainless steel substrate material by using mixed powder, wherein the mixed powder comprises 40-50 parts by weight of ZrC, 10-15 parts by weight of Al, 10-29 parts by weight of B and 40-50 parts by weight of Fe.
2. The abdominal wall cutting manipulator according to claim 1, wherein the surface modification treatment comprises a liquid nitrogen cryogenic treatment.
3. An abdominal wall cutting manipulator according to claim 1 or 2, wherein the surface modification treatment comprises:
sequentially carrying out oil removal, acid cleaning, polishing, cleaning and drying on the substrate material for later use;
selecting a laser cladding process to carry out surface modification on the substrate material, wherein the laser power in the cladding process is 1000-1200W, the scanning speed is 300-320mm/min, the powder feeding speed is 10-12g/min, the argon flow is 8-10L/min, and the spot diameter is 2-2.5mm, and the cladding process adopts a synchronous powder feeding method;
and soaking the substrate material subjected to surface modification in liquid nitrogen for cryogenic treatment, and taking out after the treatment for 120-150 minutes.
4. The abdominal wall cutting manipulator according to claim 3, wherein the degreasing is performed by using 15% sodium hydroxide solution, the pickling is performed by using 20% hydrochloric acid solution, the polishing is performed in polishing solution containing alumina particles, the cleaning is performed by using ethanol solution and matching ultrasonic waves, and the drying is performed under nitrogen.
5. The abdominal wall cutting manipulator as claimed in claim 3, wherein the laser power of the cladding process is 1000W, the scanning speed is 300mm/min, the powder feeding speed is 10g/min, the argon flow is 10L/min, and the spot diameter is 2 mm.
CN202210737445.2A 2022-06-27 2022-06-27 Abdominal wall cutting manipulator Active CN114959694B (en)

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Citations (17)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102618866A (en) * 2012-02-23 2012-08-01 山东大学 Method for reinforcing laser cladding layer on surface of titanium alloy
CN102776463A (en) * 2012-08-10 2012-11-14 昆山乔锐金属制品有限公司 Method for using novel iron-aluminum thermal-spraying powder core wire
CN103667798A (en) * 2013-11-20 2014-03-26 柳岸敏 Special nickel-based metal ceramic alloy powder for continuous-wave optical fiber laser fusion covering
CN103938207A (en) * 2013-01-20 2014-07-23 江苏兆龙电气有限公司 Method for laser cladding of metal ceramic powder on surface of austenitic stainless steel
CN104164668A (en) * 2014-08-15 2014-11-26 北京工业大学 Preparation method of high-temperature anti-wear Fe-Cr-B-Al alloy
CN104195362A (en) * 2014-08-15 2014-12-10 北京工业大学 Preparation method of high-boron and wear-resistant alloy
CN104250812A (en) * 2013-06-28 2014-12-31 丹阳宏图激光科技有限公司 Laser cladding process of aluminum alloy surface
CN106811663A (en) * 2015-11-29 2017-06-09 印杰 A kind of mould laser reinforcing powder
CN107988595A (en) * 2017-11-30 2018-05-04 钢铁研究总院 Laser melting coating prepares Fe3Al/Cr3C2The method of composite coating
CN109536949A (en) * 2018-12-12 2019-03-29 江苏大学 A kind of process improving aluminum alloy materials thermal fatigue property
CN109972134A (en) * 2019-03-08 2019-07-05 广东工业大学 A method of FeCoNiCrMn high entropy alloy coating is prepared on potassium steel surface
CN110512205A (en) * 2019-09-06 2019-11-29 中北大学 A kind of preparation method of iron-based amorphous coating
CN110846651A (en) * 2019-10-18 2020-02-28 山东农业工程学院 Ceramic-reinforced cobalt-based cladding material, coating and preparation method thereof
CN112442646A (en) * 2020-11-30 2021-03-05 宁波大学 Hot spraying wear-resistant coating
CN113667974A (en) * 2021-09-01 2021-11-19 燕山大学 Preparation method of wear-resistant metal-multi-element ceramic composite modified coating on surface of titanium alloy
WO2022111739A1 (en) * 2020-11-30 2022-06-02 湖南金天铝业高科技股份有限公司 Iron-aluminum alloy composite reinforced aluminum-based material, preparation method therefor and application thereof
CN114574857A (en) * 2022-04-28 2022-06-03 中南大学湘雅医院 Coating material and application thereof in field of surgical knife

Patent Citations (18)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102618866A (en) * 2012-02-23 2012-08-01 山东大学 Method for reinforcing laser cladding layer on surface of titanium alloy
CN102776463A (en) * 2012-08-10 2012-11-14 昆山乔锐金属制品有限公司 Method for using novel iron-aluminum thermal-spraying powder core wire
CN103938207A (en) * 2013-01-20 2014-07-23 江苏兆龙电气有限公司 Method for laser cladding of metal ceramic powder on surface of austenitic stainless steel
CN104250812A (en) * 2013-06-28 2014-12-31 丹阳宏图激光科技有限公司 Laser cladding process of aluminum alloy surface
CN106048601A (en) * 2013-06-28 2016-10-26 丹阳宏图激光科技有限公司 Aluminum alloy surface laser-cladding technology for improving wear resistance and corrosion resistance
CN103667798A (en) * 2013-11-20 2014-03-26 柳岸敏 Special nickel-based metal ceramic alloy powder for continuous-wave optical fiber laser fusion covering
CN104164668A (en) * 2014-08-15 2014-11-26 北京工业大学 Preparation method of high-temperature anti-wear Fe-Cr-B-Al alloy
CN104195362A (en) * 2014-08-15 2014-12-10 北京工业大学 Preparation method of high-boron and wear-resistant alloy
CN106811663A (en) * 2015-11-29 2017-06-09 印杰 A kind of mould laser reinforcing powder
CN107988595A (en) * 2017-11-30 2018-05-04 钢铁研究总院 Laser melting coating prepares Fe3Al/Cr3C2The method of composite coating
CN109536949A (en) * 2018-12-12 2019-03-29 江苏大学 A kind of process improving aluminum alloy materials thermal fatigue property
CN109972134A (en) * 2019-03-08 2019-07-05 广东工业大学 A method of FeCoNiCrMn high entropy alloy coating is prepared on potassium steel surface
CN110512205A (en) * 2019-09-06 2019-11-29 中北大学 A kind of preparation method of iron-based amorphous coating
CN110846651A (en) * 2019-10-18 2020-02-28 山东农业工程学院 Ceramic-reinforced cobalt-based cladding material, coating and preparation method thereof
CN112442646A (en) * 2020-11-30 2021-03-05 宁波大学 Hot spraying wear-resistant coating
WO2022111739A1 (en) * 2020-11-30 2022-06-02 湖南金天铝业高科技股份有限公司 Iron-aluminum alloy composite reinforced aluminum-based material, preparation method therefor and application thereof
CN113667974A (en) * 2021-09-01 2021-11-19 燕山大学 Preparation method of wear-resistant metal-multi-element ceramic composite modified coating on surface of titanium alloy
CN114574857A (en) * 2022-04-28 2022-06-03 中南大学湘雅医院 Coating material and application thereof in field of surgical knife

Non-Patent Citations (2)

* Cited by examiner, † Cited by third party
Title
I. MANNA等: "Laser surface cladding of Fe–B–C, Fe–B–Si and Fe–BC–Si–Al–C on plain carbon steel", 《SURFACE & COATINGS TECHNOLOGY》, vol. 201, pages 434 - 440 *
王振廷等: "氩弧熔覆原位合成ZrC-TiB_2/Fe基复合涂层组织与耐磨性", 《黑龙江科技学院学报》, vol. 21, no. 3, pages 219 - 222 *

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