CN114953691A - Antibacterial wear-resistant fabric and preparation method thereof - Google Patents

Antibacterial wear-resistant fabric and preparation method thereof Download PDF

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Publication number
CN114953691A
CN114953691A CN202210705683.5A CN202210705683A CN114953691A CN 114953691 A CN114953691 A CN 114953691A CN 202210705683 A CN202210705683 A CN 202210705683A CN 114953691 A CN114953691 A CN 114953691A
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China
Prior art keywords
parts
layer
wear
antibacterial
fiber
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Granted
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CN202210705683.5A
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Chinese (zh)
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CN114953691B (en
Inventor
李海霞
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Puning Yaxiufen Garment Co ltd
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Individual
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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B5/00Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts
    • B32B5/02Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by structural features of a fibrous or filamentary layer
    • B32B5/022Non-woven fabric
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B5/00Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts
    • B32B5/02Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by structural features of a fibrous or filamentary layer
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B5/00Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts
    • B32B5/02Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by structural features of a fibrous or filamentary layer
    • B32B5/08Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by structural features of a fibrous or filamentary layer the fibres or filaments of a layer being of different substances, e.g. conjugate fibres, mixture of different fibres
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B5/00Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts
    • B32B5/22Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by the presence of two or more layers which are next to each other and are fibrous, filamentary, formed of particles or foamed
    • B32B5/24Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by the presence of two or more layers which are next to each other and are fibrous, filamentary, formed of particles or foamed one layer being a fibrous or filamentary layer
    • B32B5/26Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by the presence of two or more layers which are next to each other and are fibrous, filamentary, formed of particles or foamed one layer being a fibrous or filamentary layer another layer next to it also being fibrous or filamentary
    • B32B5/265Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by the presence of two or more layers which are next to each other and are fibrous, filamentary, formed of particles or foamed one layer being a fibrous or filamentary layer another layer next to it also being fibrous or filamentary characterised by one fibrous or filamentary layer being a non-woven fabric layer
    • B32B5/266Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by the presence of two or more layers which are next to each other and are fibrous, filamentary, formed of particles or foamed one layer being a fibrous or filamentary layer another layer next to it also being fibrous or filamentary characterised by one fibrous or filamentary layer being a non-woven fabric layer next to one or more non-woven fabric layers
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    • B32B5/22Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by the presence of two or more layers which are next to each other and are fibrous, filamentary, formed of particles or foamed
    • B32B5/24Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by the presence of two or more layers which are next to each other and are fibrous, filamentary, formed of particles or foamed one layer being a fibrous or filamentary layer
    • B32B5/26Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by the presence of two or more layers which are next to each other and are fibrous, filamentary, formed of particles or foamed one layer being a fibrous or filamentary layer another layer next to it also being fibrous or filamentary
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    • DTEXTILES; PAPER
    • D01NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01FCHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
    • D01F1/00General methods for the manufacture of artificial filaments or the like
    • D01F1/02Addition of substances to the spinning solution or to the melt
    • D01F1/10Other agents for modifying properties
    • DTEXTILES; PAPER
    • D01NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01FCHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
    • D01F1/00General methods for the manufacture of artificial filaments or the like
    • D01F1/02Addition of substances to the spinning solution or to the melt
    • D01F1/10Other agents for modifying properties
    • D01F1/103Agents inhibiting growth of microorganisms
    • DTEXTILES; PAPER
    • D01NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01FCHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
    • D01F8/00Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof
    • D01F8/02Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof from cellulose, cellulose derivatives, or proteins
    • DTEXTILES; PAPER
    • D01NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01FCHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
    • D01F8/00Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof
    • D01F8/04Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof from synthetic polymers
    • D01F8/12Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof from synthetic polymers with at least one polyamide as constituent
    • DTEXTILES; PAPER
    • D01NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01FCHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
    • D01F8/00Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof
    • D01F8/04Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof from synthetic polymers
    • D01F8/14Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof from synthetic polymers with at least one polyester as constituent
    • DTEXTILES; PAPER
    • D03WEAVING
    • D03DWOVEN FABRICS; METHODS OF WEAVING; LOOMS
    • D03D11/00Double or multi-ply fabrics not otherwise provided for
    • DTEXTILES; PAPER
    • D03WEAVING
    • D03DWOVEN FABRICS; METHODS OF WEAVING; LOOMS
    • D03D15/00Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used
    • D03D15/20Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used characterised by the material of the fibres or filaments constituting the yarns or threads
    • D03D15/208Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used characterised by the material of the fibres or filaments constituting the yarns or threads cellulose-based
    • D03D15/225Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used characterised by the material of the fibres or filaments constituting the yarns or threads cellulose-based artificial, e.g. viscose
    • DTEXTILES; PAPER
    • D03WEAVING
    • D03DWOVEN FABRICS; METHODS OF WEAVING; LOOMS
    • D03D15/00Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used
    • D03D15/20Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used characterised by the material of the fibres or filaments constituting the yarns or threads
    • D03D15/283Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used characterised by the material of the fibres or filaments constituting the yarns or threads synthetic polymer-based, e.g. polyamide or polyester fibres
    • DTEXTILES; PAPER
    • D03WEAVING
    • D03DWOVEN FABRICS; METHODS OF WEAVING; LOOMS
    • D03D15/00Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used
    • D03D15/20Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used characterised by the material of the fibres or filaments constituting the yarns or threads
    • D03D15/292Conjugate, i.e. bi- or multicomponent, fibres or filaments
    • DTEXTILES; PAPER
    • D03WEAVING
    • D03DWOVEN FABRICS; METHODS OF WEAVING; LOOMS
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    • D03D15/30Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used characterised by the structure of the fibres or filaments
    • D03D15/37Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used characterised by the structure of the fibres or filaments with specific cross-section or surface shape
    • DTEXTILES; PAPER
    • D03WEAVING
    • D03DWOVEN FABRICS; METHODS OF WEAVING; LOOMS
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    • D03D15/40Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used characterised by the structure of the yarns or threads
    • D03D15/47Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used characterised by the structure of the yarns or threads multicomponent, e.g. blended yarns or threads
    • DTEXTILES; PAPER
    • D03WEAVING
    • D03DWOVEN FABRICS; METHODS OF WEAVING; LOOMS
    • D03D15/00Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used
    • D03D15/50Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used characterised by the properties of the yarns or threads
    • D03D15/58Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used characterised by the properties of the yarns or threads characterised by the coefficients of friction
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M17/00Producing multi-layer textile fabrics
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    • B32B2307/00Properties of the layers or laminate
    • B32B2307/50Properties of the layers or laminate having particular mechanical properties
    • B32B2307/554Wear resistance
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    • B32B2307/00Properties of the layers or laminate
    • B32B2307/70Other properties
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    • B32B2307/7145Rot proof, resistant to bacteria, mildew, mould, fungi
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    • B32B2437/00Clothing

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  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Manufacturing & Machinery (AREA)
  • Chemical Or Physical Treatment Of Fibers (AREA)
  • Agricultural Chemicals And Associated Chemicals (AREA)

Abstract

The invention discloses an antibacterial wear-resistant fabric which comprises a wear-resistant layer on a surface layer, an antibacterial layer on a middle layer and a moisture-absorbing breathable layer on an inner layer; the wear-resistant layer, the antibacterial layer and the moisture absorption breathable layer are connected through binding; the wear-resistant layer is formed by interweaving wear-resistant fibers; the wear-resistant fiber comprises the following components in parts by weight: 5-25 parts of nano silica gel, 60-80 parts of polyester solution and 80-100 parts of aramid resin polymer solution; the antibacterial layer consists of the following components in parts by weight: 1-10 parts of nano silver-alginate-sericin compound, 1-10 parts of modified chitosan, 1-10 parts of nano modified bamboo charcoal, 70-90 parts of bamboo pulp and 40-60 parts of polyester solution. The invention has good biocompatibility and skin-friendly property, inhibits the production of various harmful bacteria and mites, and improves the antibacterial and bacteriostatic properties and the anti-allergic properties.

Description

Antibacterial wear-resistant fabric and preparation method thereof
Technical Field
The invention relates to the technical field of textile fabrics, in particular to an antibacterial wear-resistant fabric and a preparation method thereof.
Background
Fabric is the material used to make clothing. As one of the three elements of the garment, the fabric not only can explain the style and the characteristics of the garment, but also directly controls the expression effects of the color and the shape of the garment. In outdoor applications, in addition to the appearance and comfort properties of textiles, the wear resistance and antimicrobial effect of textiles should also be considered. The existing fabric with antibacterial performance is generally provided with some antibacterial compositions attached to the fabric, the compositions are usually inorganic compounds or some naturally extracted antibacterial substances, and when the compounds are used in the textile, the fabric rubs against external objects, so that the antibacterial effect of the textile is obviously reduced, and the antibacterial performance of the textile is influenced.
Disclosure of Invention
The invention aims to provide an antibacterial wear-resistant fabric which is good in biocompatibility and skin affinity, inhibits the production of various harmful bacteria and mites, and improves antibacterial and bacteriostatic properties and anti-allergy properties.
In order to solve the technical problems, the invention adopts the following technical scheme: an antibacterial wear-resistant fabric comprises a wear-resistant layer on a surface layer, an antibacterial layer on a middle layer and a moisture-absorbing breathable layer on an inner layer; the wear-resistant layer, the antibacterial layer and the moisture absorption breathable layer are connected through binding;
the wear-resistant layer is formed by interweaving wear-resistant fibers; the wear-resistant fiber comprises the following components in parts by weight: 5-25 parts of nano silica gel, 60-80 parts of polyester solution and 80-100 parts of aramid resin polymer solution;
the antibacterial layer consists of the following components in parts by weight: 1-10 parts of nano silver-alginate-sericin compound, 1-10 parts of modified chitosan, 1-10 parts of nano modified bamboo charcoal, 70-90 parts of bamboo pulp and 40-60 parts of polyester solution.
Furthermore, the wear-resistant layer is formed by interweaving wear-resistant fibers; the wear-resistant fiber comprises the following components in parts by weight: 12-15 parts of nano silica gel, 66-72 parts of polyester solution and 89-95 parts of aramid resin polymerization solution.
Further, the antibacterial layer consists of the following components in parts by weight: 1-5 parts of nano silver-alginate-sericin compound, 1-5 parts of modified chitosan, 1-5 parts of nano modified bamboo charcoal, 70-80 parts of bamboo pulp and 50-60 parts of polyester solution.
Furthermore, warp yarns and weft yarns of the moisture-absorbing and air-permeable layer are interwoven by the first core-spun yarns and the second core-spun yarns according to the arrangement ratio of 5: 2; the first core-spun yarn adopts superfine profiled acrylic fibers and alginate fibers as core yarns, the center of the core yarn is the alginate fibers, and 3-5 superfine profiled acrylic fibers surround the periphery of the core yarn; the outer wrapping fiber is Tai Chi viscose fiber; the core yarn of the second core-spun yarn is modal fiber, and the outer wrapping fiber is composite fiber consisting of hydrophilic antibacterial fiber, heating fiber and spectrum fiber.
Further, the preparation method of the hydrophilic antibacterial fiber comprises the following steps: adding the copper nonyl phenolsulfonate and the silver-carrying antibacterial agent into a hydrophilic polymer, and carrying out melt spinning to obtain the antibacterial agent.
Further, the preparation method of the nano silver-alginate-sericin compound comprises the following steps:
1) extracting sericin: cleaning silkworm cocoon, placing into degumming solution, degumming at 80-100 deg.C, and filtering to obtain degumming solution;
2) mixing and dissolving sericin and alginate; adding nano silver into the degumming solution, heating to 42 ℃ at the speed of 1-3 ℃/min, and then cooling;
3) preparing a nano silver-alginate-sericin compound: adding the nano silver dispersion liquid into the solution obtained in the step 2), mixing and stirring.
The invention also discloses a preparation method of the antibacterial wear-resistant fabric, which is characterized by comprising the following steps: the method comprises the following steps:
1) preparing a wear-resistant layer: simultaneously spraying a polyester solution and an aramid polymer from spinneret orifices, wherein the spinneret orifices comprise a polyester solution spray orifice in the middle and four aramid resin polymer liquid spinneret orifices surrounding the polyester solution spray orifice; the spinning holes of the aramid fiber resin polymerization liquid are regulated to rotate by a regulating assembly, the rotating angle is 1 degree, and a wavy aramid fiber resin fiber layer is covered outside the polyester fiber; spraying nano silica gel on the outer layer of the fiber sprayed from the spinneret orifice;
2) preparation of the antibacterial layer: mixing the starch-alginate-sericin compound, the modified chitosan, the nano modified bamboo charcoal, the bamboo pulp and the polyester solution to prepare spinning fibers, and interweaving the prepared spinning fibers to form an antibacterial layer;
3) preparing a moisture absorption breathable layer: the warp yarns and the weft yarns are interwoven by the covering yarns I and the covering yarns II according to the arrangement ratio of 5:2 to prepare the moisture-absorbing and breathable layer.
Further, a nano silica gel nozzle is arranged at the spinning outlet in the step 1) and is used for spraying nano silica gel on the spun fiber.
The invention has the beneficial effects that:
1) the fabric disclosed by the invention is good in biocompatibility and skin-friendly property, can inhibit the production of various harmful bacteria and mites, and can improve antibacterial and bacteriostatic properties and antiallergic properties.
2) The wear-resistant fiber structure and the wear-resistant fiber layer are improved, so that the wear resistance of the fabric can be effectively improved, the prepared fabric is not easy to wear, and the service life is longer.
3) The fabric disclosed by the invention has good air permeability and moisture absorption, is environment-friendly, sanitary, green and economical, and has a good protection effect on the skin surface layer.
Detailed Description
The technical solution of the present invention will be clearly and completely described by the following detailed description.
Example 1
The antibacterial wear-resistant fabric comprises a wear-resistant layer on the surface layer, an antibacterial layer in the middle layer and a moisture-absorbing breathable layer in the inner layer; the wear-resistant layer, the antibacterial layer and the moisture absorption breathable layer are connected through binding; the wear-resistant layer is formed by interweaving wear-resistant fibers; the wear-resistant fiber comprises the following components in parts by weight: 5 parts of nano-silica gel, 60 parts of polyester solution and 80 parts of aramid resin polymerization solution; the antibacterial layer consists of the following components in parts by weight: 1 part of nano silver-alginate-sericin compound, 1 part of modified chitosan, 1 part of nano modified bamboo charcoal, 70 parts of bamboo pulp and 60 parts of polyester solution.
Warp yarns and weft yarns of the moisture-absorbing and air-permeable layer are interwoven by the first core-spun yarns and the second core-spun yarns according to the arrangement ratio of 5: 2; the first core-spun yarn adopts superfine profiled acrylic fibers and alginate fibers as core yarns, the center of the core yarn is the alginate fibers, and 3 superfine profiled acrylic fibers surround the periphery of the core yarn; the outer wrapping fiber is Tai Chi viscose fiber; the core yarn of the second core-spun yarn is modal fiber, and the outer wrapping fiber is composite fiber consisting of hydrophilic antibacterial fiber, heating fiber and spectrum fiber.
The preparation method of the hydrophilic antibacterial fiber comprises the following steps: adding the copper nonyl phenolsulfonate and the silver-carrying antibacterial agent into a hydrophilic polymer, and carrying out melt spinning to obtain the antibacterial agent.
The preparation method of the nano silver-alginate-sericin compound comprises the following steps:
1) extracting sericin: cleaning the silkworm cocoon, placing the cleaned silkworm cocoon into a degumming solution, carrying out degumming treatment on the silkworm cocoon and the degumming solution at 80 ℃, and filtering the degumming solution;
2) mixing and dissolving sericin and alginate; adding nano silver into the degumming solution, heating to 42 ℃ at the speed of 1 ℃/min, and then cooling;
3) preparing a nano silver-alginate-sericin compound: adding the nano silver dispersion liquid into the solution obtained in the step 2), mixing and stirring.
The invention discloses a preparation method of an antibacterial wear-resistant fabric, which comprises the following steps:
1) preparing a wear-resistant layer: simultaneously spraying a polyester solution and an aramid polymer from spinneret orifices, wherein the spinneret orifices comprise a polyester solution spray orifice in the middle and four aramid resin polymer liquid spinneret orifices surrounding the polyester solution spray orifice; the spinning holes of the aramid fiber resin polymerization liquid are regulated to rotate by a regulating assembly, the rotating angle is 1 degree, and a wavy aramid fiber resin fiber layer is covered outside the polyester fiber; spraying nano silica gel on the outer layer of the fiber sprayed from the spinneret orifice; a nano silica gel nozzle is arranged at the spinning outlet and is used for spraying nano silica gel on the sprayed fiber;
2) preparation of the antibacterial layer: mixing the starch-alginate-sericin compound, the modified chitosan, the nano modified bamboo charcoal, the bamboo pulp and the polyester solution to prepare spinning fibers, and interweaving the prepared spinning fibers to form an antibacterial layer;
3) preparing a moisture absorption breathable layer: the warp yarns and the weft yarns are interwoven by the covering yarns I and the covering yarns II according to the arrangement ratio of 5:2 to prepare the moisture-absorbing and breathable layer.
Example 2
The invention relates to an antibacterial wear-resistant fabric which comprises a wear-resistant layer on the surface layer, an antibacterial layer on the middle layer and a moisture-absorbing breathable layer on the inner layer; the wear-resistant layer, the antibacterial layer and the moisture absorption breathable layer are connected through binding; the wear-resistant layer is formed by interweaving wear-resistant fibers; the wear-resistant fiber comprises the following components in parts by weight: 25 parts of nano silica gel, 80 parts of polyester solution and 100 parts of aramid resin polymerization solution; the antibacterial layer consists of the following components in parts by weight: 10 parts of nano silver-alginate-sericin compound, 10 parts of modified chitosan, 10 parts of nano modified bamboo charcoal, 90 parts of bamboo pulp and 40 parts of polyester solution.
Warp yarns and weft yarns of the moisture-absorbing and air-permeable layer are interwoven by the first core-spun yarns and the second core-spun yarns according to the arrangement ratio of 5: 2; the first core-spun yarn adopts superfine profiled acrylic fibers and alginate fibers as core yarns, the center of the core yarn is the alginate fibers, and 4 superfine profiled acrylic fibers surround the periphery of the core yarn; the outer wrapping fiber is Tai Chi viscose fiber; the core yarn of the second core-spun yarn is modal fiber, and the outer wrapping fiber is composite fiber consisting of hydrophilic antibacterial fiber, heating fiber and spectrum fiber.
The preparation method of the hydrophilic antibacterial fiber comprises the following steps: adding the copper nonyl phenolsulfonate and the silver-carrying antibacterial agent into a hydrophilic polymer, and carrying out melt spinning to obtain the antibacterial agent.
The preparation method of the nano silver-alginate-sericin compound comprises the following steps:
1) extracting sericin: cleaning the silkworm cocoon, placing the cleaned silkworm cocoon into a degumming solution, carrying out degumming treatment at 100 ℃, and filtering degumming solution;
2) mixing and dissolving sericin and alginate; adding nano silver into the degumming solution, heating to 42 ℃ at the speed of 3 ℃/min, and then cooling;
3) preparing a nano silver-alginate-sericin compound: adding the nano silver dispersion liquid into the solution obtained in the step 2), mixing and stirring.
Example 3
The invention relates to an antibacterial wear-resistant fabric which comprises a wear-resistant layer on the surface layer, an antibacterial layer on the middle layer and a moisture-absorbing breathable layer on the inner layer; the wear-resistant layer, the antibacterial layer and the moisture absorption breathable layer are connected through binding; the wear-resistant layer is formed by interweaving wear-resistant fibers; the wear-resistant fiber comprises the following components in parts by weight: 12 parts of nano-silica gel, 66 parts of polyester solution and 89 parts of aramid resin polymerization solution.
The antibacterial layer consists of the following components in parts by weight: 5 parts of nano silver-alginate-sericin compound, 5 parts of modified chitosan, 1 part of nano modified bamboo charcoal, 70 parts of bamboo pulp and 50 parts of polyester solution.
Warp yarns and weft yarns of the moisture-absorbing and air-permeable layer are interwoven by the first core-spun yarns and the second core-spun yarns according to the arrangement ratio of 5: 2; the first core-spun yarn adopts superfine profiled acrylic fibers and alginate fibers as core yarns, the center of the core yarn is the alginate fibers, and 5 superfine profiled acrylic fibers surround the periphery of the core yarn; the outer wrapping fiber is Tai Chi viscose fiber; the core yarn of the second core-spun yarn is modal fiber, and the outer wrapping fiber is composite fiber consisting of hydrophilic antibacterial fiber, heating fiber and spectrum fiber.
The preparation method of the hydrophilic antibacterial fiber comprises the following steps: adding the copper nonyl phenolsulfonate and the silver-carrying antibacterial agent into a hydrophilic polymer, and carrying out melt spinning to obtain the antibacterial agent.
The preparation method of the nano silver-alginate-sericin compound comprises the following steps:
1) extracting sericin: cleaning the silkworm cocoon, placing the cleaned silkworm cocoon into a degumming solution, carrying out degumming treatment on the silkworm cocoon and the degumming solution at 90 ℃, and filtering the degumming solution;
2) mixing and dissolving sericin and alginate; adding nano silver into the degumming solution, heating to 42 ℃ at the speed of 2 ℃/min, and then cooling;
3) preparing a nano silver-alginate-sericin compound: adding the nano silver dispersion liquid into the solution obtained in the step 2), mixing and stirring.
The invention discloses a preparation method of an antibacterial wear-resistant fabric, which comprises the following steps:
1) preparing a wear-resistant layer: simultaneously spraying a polyester solution and an aramid polymer from spinneret orifices, wherein the spinneret orifices comprise a polyester solution spray orifice in the middle and four aramid resin polymer liquid spinneret orifices surrounding the polyester solution spray orifice; the rotating angle of the spinneret orifice of the aramid fiber resin polymerization liquid is 1 degree, and a wavy aramid fiber resin fiber layer is covered outside the polyester fiber; spraying nano silica gel on the outer layer of the fiber sprayed from the spinneret orifice; and a nano silica gel nozzle is arranged at the spinning outlet and is used for spraying nano silica gel on the sprayed fiber yarns.
2) Preparation of the antibacterial layer: mixing the starch-alginate-sericin compound, the modified chitosan, the nano modified bamboo charcoal, the bamboo pulp and the polyester solution to prepare spinning fibers, and interweaving the prepared spinning fibers to form an antibacterial layer;
3) preparing a moisture absorption breathable layer: the warp yarns and the weft yarns are interwoven by the covering yarns I and the covering yarns II according to the arrangement ratio of 5:2 to prepare the moisture-absorbing and breathable layer.
Example 4
The invention relates to an antibacterial wear-resistant fabric which comprises a wear-resistant layer on the surface layer, an antibacterial layer on the middle layer and a moisture-absorbing breathable layer on the inner layer; the wear-resistant layer, the antibacterial layer and the moisture absorption breathable layer are connected through binding; the wear-resistant layer is formed by interweaving wear-resistant fibers; the wear-resistant fiber comprises the following components in parts by weight: 15 parts of nano-silica gel, 72 parts of polyester solution and 95 parts of aramid resin polymer solution.
The antibacterial layer consists of the following components in parts by weight: 1 part of nano silver-alginate-sericin compound, 1 part of modified chitosan, 1 part of nano modified bamboo charcoal, 80 parts of bamboo pulp and 60 parts of polyester solution.
Warp yarns and weft yarns of the moisture-absorbing and air-permeable layer are interwoven by the first core-spun yarns and the second core-spun yarns according to the arrangement ratio of 5: 2; the first core-spun yarn adopts superfine profiled acrylic fibers and alginate fibers as core yarns, the center of the core yarn is the alginate fibers, and 5 superfine profiled acrylic fibers surround the periphery of the core yarn; the outer wrapping fiber is Tai Chi viscose fiber; the core yarn of the second core-spun yarn is modal fiber, and the outer-wrapping fiber is composite fiber consisting of hydrophilic antibacterial fiber, heating fiber and spectrum fiber.
The preparation method of the hydrophilic antibacterial fiber comprises the following steps: adding the copper nonyl phenolsulfonate and the silver-carrying antibacterial agent into a hydrophilic polymer, and carrying out melt spinning to obtain the antibacterial agent.
The preparation method of the nano silver-alginate-sericin compound comprises the following steps:
1) extracting sericin: cleaning the silkworm cocoon, placing the cleaned silkworm cocoon into a degumming solution, carrying out degumming treatment on the silkworm cocoon and the degumming solution at 100 ℃, and filtering the degumming solution;
2) mixing and dissolving sericin and alginate; adding nano silver into the degumming solution, heating to 42 ℃ at the speed of 2 ℃/min, and then cooling;
3) preparing a nano silver-alginate-sericin compound: adding the nano silver dispersion liquid into the solution obtained in the step 2), mixing and stirring.
The invention discloses a preparation method of an antibacterial wear-resistant fabric, which is characterized by comprising the following steps of: the method comprises the following steps:
1) preparing a wear-resistant layer: simultaneously spraying a polyester solution and an aramid polymer from spinneret orifices, wherein the spinneret orifices comprise a polyester solution spray orifice in the middle and four aramid resin polymer liquid spinneret orifices surrounding the polyester solution spray orifice; the spinning holes of the aramid fiber resin polymerization liquid are regulated to rotate by a regulating assembly, the rotating angle is 1 degree, and a wavy aramid fiber resin fiber layer is covered outside the polyester fiber; spraying nano silica gel on the outer layer of the fiber sprayed from the spinneret orifice; a nano silica gel nozzle is arranged at the spinning outlet and is used for spraying nano silica gel on the sprayed fiber;
2) preparation of the antibacterial layer: mixing the starch-alginate-sericin compound, the modified chitosan, the nano modified bamboo charcoal, the bamboo pulp and the polyester solution to prepare spinning fibers, and interweaving the prepared spinning fibers to form an antibacterial layer;
3) preparing a moisture absorption breathable layer: the warp yarns and the weft yarns are interwoven by the covering yarns I and the covering yarns II according to the arrangement ratio of 5:2 to prepare the moisture-absorbing and breathable layer.
While the invention has been described with reference to a preferred embodiment, it will be understood by those skilled in the art that various changes may be made and equivalents may be substituted without departing from the spirit and scope of the invention.

Claims (8)

1. An antibacterial wear-resistant fabric is characterized in that: comprises a wear-resistant layer on the surface layer, an antibacterial layer on the middle layer and a moisture-absorbing and breathable layer on the inner layer; the wear-resistant layer, the antibacterial layer and the moisture absorption breathable layer are connected through binding;
the wear-resistant layer is formed by interweaving wear-resistant fibers; the wear-resistant fiber comprises the following components in parts by weight: 5-25 parts of nano silica gel, 60-80 parts of polyester solution and 80-100 parts of aramid resin polymer solution;
the antibacterial layer consists of the following components in parts by weight: 1-10 parts of nano silver-alginate-sericin compound, 1-10 parts of modified chitosan, 1-10 parts of nano modified bamboo charcoal, 70-90 parts of bamboo pulp and 40-60 parts of polyester solution.
2. The antibacterial wear-resistant fabric according to claim 1, characterized in that: the wear-resistant layer is formed by interweaving wear-resistant fibers; the wear-resistant fiber comprises the following components in parts by weight: 12-15 parts of nano silica gel, 66-72 parts of polyester solution and 89-95 parts of aramid resin polymerization solution.
3. The antibacterial wear-resistant fabric according to claim 1, characterized in that: the antibacterial layer consists of the following components in parts by weight: 1-5 parts of nano silver-alginate-sericin compound, 1-5 parts of modified chitosan, 1-5 parts of nano modified bamboo charcoal, 70-80 parts of bamboo pulp and 50-60 parts of polyester solution.
4. The antibacterial wear-resistant fabric according to claim 1, characterized in that: warp yarns and weft yarns of the moisture-absorbing and breathable layer are interwoven by the first core-spun yarns and the second core-spun yarns according to the arrangement ratio of 5: 2; the first core-spun yarn adopts superfine profiled acrylic fibers and alginate fibers as core yarns, the center of the core yarn is the alginate fibers, and 3-5 superfine profiled acrylic fibers surround the periphery of the core yarn; the outer wrapping fiber is Tai Chi viscose fiber; the core yarn of the second core-spun yarn is modal fiber, and the outer wrapping fiber is composite fiber consisting of hydrophilic antibacterial fiber, heating fiber and spectrum fiber.
5. The antibacterial wear-resistant fabric according to claim 4, characterized in that: the preparation method of the hydrophilic antibacterial fiber comprises the following steps: adding the copper nonyl phenolsulfonate and the silver-carrying antibacterial agent into a hydrophilic polymer, and carrying out melt spinning to obtain the antibacterial agent.
6. The antibacterial wear-resistant fabric according to claim 1, characterized in that: the preparation method of the nano silver-alginate-sericin compound comprises the following steps:
1) extracting sericin: cleaning silkworm cocoon, placing into degumming solution, degumming at 80-100 deg.C, and filtering to obtain degumming solution;
2) mixing sericin and alginate for dissolving; adding nano silver into the degumming solution, heating to 42 ℃ at the speed of 1-3 ℃/min, and then cooling;
3) preparing a nano silver-alginate-sericin compound: adding the nano silver dispersion liquid into the solution obtained in the step 2), mixing and stirring.
7. The preparation method of the antibacterial wear-resistant fabric according to claim 1, which is characterized by comprising the following steps: the method comprises the following steps:
1) preparing a wear-resistant layer: simultaneously spraying a polyester solution and an aramid polymer from spinneret orifices, wherein the spinneret orifices comprise a polyester solution spray orifice in the middle and four aramid resin polymer liquid spinneret orifices surrounding the polyester solution spray orifice; the spinning holes of the aramid fiber resin polymerization liquid are regulated to rotate by a regulating assembly, the rotating angle is 1 degree, and a wavy aramid fiber resin fiber layer is covered outside the polyester fiber; spraying nano silica gel on the outer layer of the fiber sprayed from the spinneret orifice;
2) preparation of the antibacterial layer: mixing the starch-alginate-sericin compound, the modified chitosan, the nano modified bamboo charcoal, the bamboo pulp and the polyester solution to prepare spinning fibers, and interweaving the prepared spinning fibers to form an antibacterial layer;
3) preparing a moisture absorption breathable layer: the warp yarns and the weft yarns are interwoven by the covering yarns I and the covering yarns II according to the arrangement ratio of 5:2 to prepare the moisture-absorbing and breathable layer.
8. The preparation method of the antibacterial wear-resistant fabric according to claim 7, characterized by comprising the following steps: in the step 1), a nano silica gel nozzle is arranged at the spinning outlet and is used for spraying nano silica gel on the spun fiber.
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