CN114901374A - 使用分隔壁塔和/或传统塔制备用于针对烯烃生产的催化裂化单元的进料的方法 - Google Patents

使用分隔壁塔和/或传统塔制备用于针对烯烃生产的催化裂化单元的进料的方法 Download PDF

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CN114901374A
CN114901374A CN202080089899.2A CN202080089899A CN114901374A CN 114901374 A CN114901374 A CN 114901374A CN 202080089899 A CN202080089899 A CN 202080089899A CN 114901374 A CN114901374 A CN 114901374A
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B·B·辛格
I·C·埃尔吉
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Kellogg Brown and Root LLC
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Abstract

分隔壁塔或一对常规塔可用于分离未稳定化石脑油物流,以产生不含芳烃的轻石脑油物流作为用于烯烃生产的催化裂化单元的进料。

Description

使用分隔壁塔和/或传统塔制备用于针对烯烃生产的催化裂 化单元的进料的方法
技术领域
本发明涉及使用催化裂化单元制备烯烃的系统,更具体地涉及在系统内产生轻石脑油进料的这种系统。
背景
流化催化裂化(FCC)是石油炼制厂中使用的重要的且众所周知的商业转化方法。它被广泛用于将石油原油的高沸点、高分子量的烃馏分转化为更有价值的汽油、烯烃和其他产品。石油烃的裂化现在主要通过催化裂化完成,因为催化裂化比热裂化产生更多具有较高辛烷值的汽油。催化裂化还产生具有更多碳-碳双键,即更多烯烃的副产品气体,因此比通过热裂化产生的那些气体更有经济价值。
将大的烃分子分解成较小的分子在技术上被有机化学家称为碳-碳键的“裂解”。一些较小的烷烃随后被分解并转化为甚至更小的烯烃和支链烯烃如乙烯(CH2=CH2或C2=)、丙烯(CH3-CH=CH2或C3=)、丁烯和异丁烯(统称C4=)气体。那些烯烃气体具有用作石油化工原料的价值。丙烯、丁烯和异丁烯也是某些石油精炼工艺的有价值的原料,这些石油精炼工艺可以将它们转化为高辛烷值汽油共混组分。它们也可被用作用于较高分子产品如聚合物的有价值的化学结构单元。
人们总是期望通过提高可靠性、在设备区边界(battery limit)内控制分馏质量、稳定地制备轻烯烃、提高分馏效率、减少设施要求、减少总体能量要求、减少CO2/NOX排放、减少设备占地面积要求和/或提高产品的价值来改进催化裂化系统。
概述
在一个非限制性实施方案中,提供了一种被配置用于烯烃生产的催化裂化系统,其中所述系统包括反应器/再生器、主分馏器和蒸气回收单元(VR U)。所述反应器/再生器适于接收包含第一提升管中的粗柴油和/或脱沥青油(DAO)和/或常压渣油的进料以及第二提升管中的不含芳烃的富含C5/C6的轻石脑油进料,所述反应器/再生器产生包含轻石蜡烃和重石蜡烃、环烷烃、芳烃和烯烃的高价值产品物流。主分馏器被配置为接收和分馏高价值产品物流,其中所述主分馏器包含含有燃料气、C3/C4和轻石脑油的分馏器蒸气产品物流;粗石脑油产品物流;以及包含任选的重石脑油、轻循环油(LCO)和油浆的分馏器液体产品物流。所述VRU包括初级吸收器,其中所述VRU接收分馏器蒸气产品物流和粗石脑油产品物流,并将它们分离以得到不含芳烃的富含C5/C6的产品物流,其中不含芳烃的富含C5/C6的产品物流作为不含芳烃的富含C5/C6的轻石脑油进料被引导回至所述反应器/再生器。所述VRU进一步包括两个实施方案。在第一个非限制性实施方案中,所述VRU包括脱丁烷塔和石脑油分离器塔的组合,以及脱丁烷器塔底产品,其被分离为至石脑油分离器塔的进料和至初级吸收器的循环物,并且其中所述石脑油分离器塔分离出不含芳烃的富含C5/C6的产品物流。在第二个非限制性实施方案中,所述VRU包括分隔壁塔(DWC),该分隔壁塔包括预分馏器部分和主分馏器部分,其中所述DWC包含侧馏分,所述侧馏分是所述不含芳烃的富含C5/C6的产品物流,并且所述DWC包含塔底产品,所述塔底产品被分离为汽油产品和至所述初级吸收器的循环物。
另外提供了用于在催化裂化系统中生产烯烃的方法,其中该方法包括将进料引导至反应器/再生器,其中所述进料包含选自粗柴油、脱沥青油(DA O)、常压渣油和不含芳烃的富含C5/C6的轻石脑油进料的至少一种组分。该方法还包括所述反应器/再生器产生包含轻石蜡烃和重石蜡烃、环烷烃、芳烃和烯烃的高价值产品物流。该方法另外包括将所述高价值产品物流引导至主分馏器,其中主分馏器分馏所述高价值产品物流,并产生包含燃料气、C3/C4和轻石脑油的分馏器蒸气产品物流、粗石脑油产品物流和包含选自重石脑油、轻循环油(LCO)和油浆的至少一种组分的分馏器液体产品物流。该方法还包括将分馏器蒸气产品物流和粗石脑油产品物流引导至包括初级吸收器的蒸气回收单元(VRU),其中所述VRU分离所述分馏器蒸气产品物流和粗石脑油产品物流,以得到不含芳烃的富含C5/C6的产品物流。所述不含芳烃的富含C5/C6的产品物流作为不含芳烃的富含C5/C6的轻石脑油进料循环物被引导至所述反应器/再生器。所述VRU进一步包括上文所述的两个实施方案中的任一个的单元。
附图简述
图1是典型的FCC和气体装置(gas plant)的方框流程图的非限制性示意图,其示出了如本文所述的用于烯烃生产的输入石脑油进料;
图2是FCC和气体装置的方框流程图的非限制性示意图,其示出了使用如本文所述的两个塔的用于烯烃生产的内部石脑油进料产生;
图3是FCC和气体装置的方框流程图的非限制性示意图,其示出了使用如本文所述的分隔壁塔(DWC)的烯烃生产的内部石脑油进料产生;和
图4是图3系统的石脑油稳定器DWC的更详细视图的非限制性示意图。
详述
现有的FCC单元可以进行改造,或者可以使用改进的技术设计新的基层FCC单元,改进的技术包括但不必限于可得自KBR的MAXOFINTM技术,以由轻石脑油物流制备轻烯烃如乙烯和丙烯。MAXOFINTM技术是一种能够使炼油厂丙烯生产最大化20%或更多的方法,其比传统的蒸气裂化具有显著更少的乙烯,并且其能够根据变化的市场需求,灵活地作为传统的FCC系统运行以生产汽油。
KBR MAXOFINTM技术采用双提升管。第一提升管处理传统的FCC原料(粗柴油、DAO和常压渣油),而在第二提升管中裂解轻石蜡烃、环烷烃或烯烃以得到期望的高产量轻烯烃。来自MAXOFINTM单元中两个提升管的反应器流出物在主分馏器塔中被分馏。
适合通过在第二提升管中裂解制备轻烯烃的轻石脑油进料通常从设备区边界外(OSBL)输入。已发现,轻石脑油进料可在MAXOFINTM单元内部生产。
FCC单元由三个主要部分组成:反应器/再生器10、主分馏器18和不饱和气体装置部分(也称为蒸气回收单元(VRU)或气体浓缩单元(GCU))。图1显示了所有三个部分。VRU包括湿气体压缩机24、高压(HP)冷却器/高压接收器26、初级吸收器58、海绵吸收器66、汽提器30、脱丁烷器(稳定器)40、脱丙烷器44和C3=分离器50。
当轻石脑油物流12作为第二提升管进料从设备区边界外输入到反应器/再生器10时的典型MAXOFINTM单元方块流程图示于图1中。还有从OSBL到反应器/再生器10的第一提升管的粗柴油、DAO和渣油进料14。第一提升管和第二提升管是催化裂化单元10的常规部件,在图中没有单独示出,但可以理解为存在。
FCC进料(重质常压粗柴油、减压粗柴油、DAO和/或渣油)14在反应器/再生器10中被裂解成高价值产品16,并被输送到主分馏器部分18。来自主分馏器18的液体产品20包括重石脑油、轻循环油(LCO)和油浆。仅油浆是塔底产品;重石脑油和轻循环油是塔侧产品。
来自主分馏器18的塔顶产品22主要包含燃料气(C2-和惰性的)、液化石油气(LPG;C3/C4),并且催化裂化石脑油在气体装置部分(VRU)中被进一步分离。来自主分馏器18的湿气体22在塔顶流至湿气体压缩机24;这通常是两级离心机。来自第一级排放的蒸气在级间冷却器中被部分冷凝,并在级间筒中闪蒸。来自湿气体压缩机24的第二级的蒸气排出物与来自压缩机级间筒的液体、初级吸收器底部液体62和汽提器塔顶蒸气36合并。该合并物流流过高压(HP)冷却器进入高压(HP)接收器,统称为26。
来自高压分离器筒的蒸气32流至初级吸收器塔58。来自主分馏器18塔顶筒的烃液体(粗石脑油)34作为贫油被泵送至初级吸收器58。脱丁烷器40的塔底液体56也被泵送至初级吸收器58,以增加贫油流量,且因此提高丙烯回收率。脱丁烷器塔底液体56在比粗石脑油34更高的位置进入初级吸收器58。在初级吸收器58底部回收的LPG(C3/C4)62被引导至HP冷却器/HP接收器26。初级吸收器塔顶气体64流至二级吸收器或海绵吸收器66,以通过吸收变成贫海绵油68来回收LPG范围的物质。富海绵油70被输送到主分馏器18。海绵吸收器塔顶物流72(C2-)流向处理,然后被输送到炼油厂燃料气体系统。
来自HP分离器筒26的液体28被泵送至汽提器塔30的顶部。汽提器塔30的目的是达到至脱丁烷器(稳定器)40的进料38中的C2含量规格。含有大部分C2-和一些LPG的汽提蒸气36离开汽提器塔30的顶部,并返回到HP冷却器/HP接收器26。汽提器塔底液体38通过与脱丁烷器塔底液体的热交换被预热,并被进料至脱丁烷器塔40。
脱丁烷器塔40将进料分离成LPG 42和催化裂化石脑油(合并物流56和60)。来自脱丁烷器40的塔顶产品42是LPG(C3/C4)。来自脱丁烷器40的塔底液体(合并物流56和60)被塔进料冷却,然后被空气和/或水冷却器(未显示)冷却。一部分被冷却的脱丁烷器塔底液体56作为超贫油被返回至初级吸收器58,剩余物60则作为催化裂化石脑油汽油共混原料产生。来自脱丁烷器的塔顶的LPG 42在胺和硫醇脱除处理后流至脱丙烷器44,在那里其被分离成C3产品和C4产品。C3产品48可在脱丙烷器塔44下游的丙烯分离器50中进一步被分离为丙烯(C3=)54产品和丙烷(C3)产品52。来自脱丙烷器44的C4塔底产品46被送至OSBL。
已经发现,轻石脑油物流74可以在设备区边界内作为至反应器/再生器10的第二提升管进料产生,这是增加烯烃LPG产量的配置。图2展示了反应器/再生器10、主分馏器18和气体装置的非限制性示意图。本文的系统和方法涉及不饱和气体装置部分,也称为VRU或GCU。在一个非限制性实施方案中,所述VRU包括两个传统塔,但为一个独特的系列,即脱丁烷器40和石脑油分离器76。脱丁烷器40和石脑油分离器76可用于将汽提器塔底液体38分馏成三个产品物流:LPG C3/C4产品取自脱丁烷器塔顶78,来自脱丁烷器塔底的稳定化石脑油物流作为物流80被部分循环回至初级吸收器58,其余物82在石脑油分离器76中进一步被分馏,以从分离器塔顶产生不含芳烃的轻石脑油(C5/C6)产品74,和从分离器塔底产生汽油范围物质84。来自石脑油分离器76的塔顶产品是不含芳烃的富含C5/C6的物流74,其适合作为第二提升管进料被循环至反应器/再生器10。来自石脑油分离器76的塔底产品84被输送进行进一步处理,以使其适用于汽油共混。在该非限制性实施方案中,来自脱丙烷器44的一部分C4塔底产品85可以作为任选的循环物流86被引导至送入反应器/再生器10的不含芳烃的轻石脑油(C5/C6)产品74进料。与图1的现有技术配置所共有的其他单元和物流有相同的附图标记。
在不同的非限制性实施方案中,VRU包括分隔壁塔(DWC)技术,该技术可用于进一步改进和简化通过催化裂化单元生产烯烃的工艺流程方案(如图3所示)。分隔壁塔技术在单个塔中提供两个传统的串联塔的性能,减少了能源和资本需求。分隔壁塔技术可用于设计单个塔来代替如图2的实施方案所示的两个串联塔系统。如图3和图4所示,分隔壁塔(DWC)88用来将来自汽提器30的汽提器塔底液体38分馏成三种产品:
-LPG C3/C4产品90取自DWC塔顶。
-从DWC 88的主分馏器侧部得到的不含芳烃的轻石脑油物流96与C5/C6组分96一起被浓缩,并被输送到反应器/再生器10的第二提升管,用于烯烃生产。
-来自DWC 88的塔底产品被分为石脑油循环物92,其返回至初级吸收器58,在那里其余物94被输送进行进一步处理,以使其适用于汽油共混。
同样,相同的单元和物流有相同的附图标记,如在前面的图的讨论中使用的。
图4是图3系统中所示的石脑油稳定器DWC 88的更详细的视图。DWC 88包括被分隔壁100分开的预分馏器部分98和主分馏器部分99。
将理解的是,DWC可以是板式塔、填料塔或两者的组合。
还将理解的是,本文描述的系统和方法将具有许多技术和商业优势。
对于在图2中示意性地示出的将两个常规塔用于脱丁烷器和石脑油分离器的非限制性实施方案,技术优势包括但不必限于:
-与从设备区边界外输入的轻石脑油相比,可靠性提高;以及
-对设备区边界内的分馏质量的控制。
该非限制性实施方案的商业优势包括但不必限于轻烯烃的稳定制备。
对于如图3和图4所示意性示出的使用DWC的非限制性实施方案,技术优势包括但必限于:
-提高分馏效率;
-改进初级吸收器性能;
-减少设施需求;
-减少总体能源需求;
-减少CO2/NOX排放;
-有机会改造现有的塔,以获得适用于轻烯烃生产的附加产品;以及
-由于较少的烃库存,增强装置安全性。
使用DWC的非限制性实施方案的商业优势包括但不必限于上述使用两个传统塔时的商业优势,此外还有:
-与传统塔方案相比,资本需求减少20-30%。
-改善分馏经济性;
-更少的布局空间(占地面积)需求;
-为工厂升级/脱瓶颈提供优势;
-全面提高产品的价值;以及
-对现有资产的替代使用,以提高装置的整体经济效益。
换句话说,图2实施方案比图1传统塔系统的非限制性改进涉及在脱丁烷塔的下游引入二产品石脑油分离器塔,以生产不含芳烃的轻石脑油作为被循环回去用于轻烯烃生产的馏出物,,以及作为塔底产品的汽油物流。
图3和图4的非限制性实施方案比图2实施方案的改进包括使用DWC来匹配脱丁烷器塔和二产品传统石脑油分离器塔的分离要求。DWC生产LPG作为塔顶产品,轻石脑油作为塔侧产品,汽油物流作为塔底产品。与图2所示的路线相比,DWC的应用提供了资本支出(CAPEX)益处(更少的设备数量和布局空间益处)和运营支出(OPEX)益处(更低的能源需求)。
此外,在诸如Honeywell UOP的美国专利申请公开2008/0081937 A1的分馏方法和本文所述提出的系统之间有许多明显的差异,这些差异包括但不必限于以下表I中所列的那些差异:
表I
所提出的系统和‘937申请之间的差异
Figure BDA0003700516020000081
在上述说明中,本发明已经参照其具体实施方案进行了描述。然而,本说明书应被视为说明性的,而非限制性的意义。例如,设备、塔、DWC、方法、反应物、烯烃、产品、反应器、再生器、分离器、稳定器、吸收器、压缩器、冷却器、以及落入要求保护的或公开的参数范围内,但没有具体指出或在具体实施例中试用的操作条件预期都在本发明的范围内。
本发明可以在不存在未公开的要素的情况下实施。此外,本发明可以适当地包括所公开的要素,由或基本上由所公开的要素组成。例如,可以提供一种被配置用于烯烃生产的催化裂化系统,其中该系统基本上由或由反应器/再生器、主分馏器和VRU组成,其中,所述反应器/再生器适于接收包含粗柴油和/或DAO和/或常压渣油的进料以及不含芳烃的富含C5/C6的轻石脑油进料,所述反应器/再生器包含包括轻石蜡烃和重石蜡烃、环烷烃、芳烃和烯烃的高价值产品物流;所述主分馏器被配置为接收和分馏高价值产品物流,其中,主分馏器包含包括燃料气、C3/C4和轻石脑油的分馏器蒸气产品物流、粗石脑油物流和包括重石脑油、LCO和油浆的分馏器液体产品物流;并且所述VRU包括初级吸收器,所述VRU接收分馏器蒸气产品物流和粗石脑油产品物流,并将它们分离以得到不含芳烃的富含C5/C6的产品物流,其中所述不含芳烃的富含C5/C6的产品物流作为不含芳烃的富含C5/C6的轻石脑油进料循环物被引导至所述反应器/再生器;其中所述VRU进一步包括选自以下的单元:1)脱丁烷器塔和石脑油分离器塔的组合,或2)DWC,其中脱丁烷器塔底产品被分离为至石脑油分离器塔的进料和至初级吸收器的进料,并且石脑油分离器塔分离出不含芳烃的富含C5/C6的产品物流;并且其中如果使用DWC,其包括预分馏器部分和主分馏器部分,其中DWC包含作为不含芳烃的富含C5/C6的产品物流的侧馏分,并且DWC包含至初级吸收器的塔底产品进料。
在整个权利要求中使用的词“包括(comprising)”和“包括(comprises)”应分别解释为指代“包括(including)但不限于”和“包括(includes)但不限于”。
如本文所用,“大体上”一词应指“大体上是但不完全是所指定的”。
如本文所使用的,单数形式“一(a)”、“一(an)”和“所述(the)”意在也包括复数形式,除非上下文明确以其他方式指出。
如本文所使用的,术语“大约”在提及给定参数时包括所述值,并具有由上下文决定的含义(例如,它包括与给定参数的测量相关的误差程度)。
如本文所用,术语“和/或”包括一个或多个相关列出的项目的任何和所有组合。

Claims (14)

1.被配置用于烯烃生产的催化裂化系统,其中所述系统包括:
反应器/再生器(10),其适于接收包含选自粗柴油、脱沥青油(DAO)、常压渣油和不含芳烃的富含C5/C6的轻石脑油进料的至少一种组分的进料(14),所述反应器/再生器(10)包含含有轻石蜡烃和重石蜡烃、环烷烃、芳烃和烯烃的高价值产品物流(16);
主分馏器(18),其被配置用于接收和分馏所述高价值产品物流(16),所述主分馏器(18)包含:
分馏器蒸气产品物流(22),其包含燃料气、C3/C4和轻石脑油;
粗石脑油产品物流(34);和
分馏器液体产品物流(20),其包含选自重石脑油、轻循环油(LCO)和油浆的至少一种组分;和
蒸气回收单元(VRU),其包括初级吸收器(58),所述VRU接收分馏器蒸气产品物流和粗石脑油产品物流(22,34),并将它们分离以得到不含芳烃的富含C5/C6的产品物流(96),其中所述不含芳烃的富含C5/C6的产品物流(74)作为不含芳烃的富含C5/C6的轻石脑油进料循环物被引导至所述反应器/再生器(10);
其中,所述VRU进一步包括选自以下的单元:
1)脱丁烷器塔(40)和石脑油分离器塔(76)的组合,其中:
脱丁烷器的塔底产品(82)被分离为至所述石脑油分离器塔(76)的进料和至所述初级吸收器(58)的进料,并且
石脑油分离器塔(76)分离出不含芳烃的富含C5/C6的产品物流(74);和
2)分隔壁塔(DWC)(88),其包括预分馏器部分(98)和主分馏器部分(99),其中:
所述DWC(88)包含侧馏分,其是所述不含芳烃的富含C5/C6的产品物流(96);并且
所述DWC包含至初级吸收器(58)的塔底产品进料(92)。
2.权利要求1所述的催化裂化系统,其中所述VRU包括脱丁烷器塔(40)和石脑油分离器塔(76)的组合,并且其中所述石脑油分离器塔(76)进一步包含被引导至加氢处理器的塔底产品物流(84)。
3.权利要求2所述的催化裂化系统,其中所述塔底产品物流(84)是催化裂化石脑油汽油共混原料。
4.权利要求2所述的催化裂化系统,其中所述脱丁烷器塔(40)包括至脱丙烷器(44)的塔顶C3/C4产品物流(42),并且其中所述脱丙烷器(44)包含C3产品物流(48)。
5.权利要求1所述的催化裂化系统,其中所述VRU包括DWC(88),并且所述DWC(88)包含塔顶C3/C4产品物流(90);主分馏器侧物流,其为所述不含芳烃的富含C5/C6的产品物流(96);和被引导至加氢处理器的塔底产品(94)。
6.权利要求5所述的催化裂化系统,其中所述塔底产品(94)是催化裂化石脑油汽油共混原料。
7.权利要求5所述的催化裂化系统,其中所述DWC(88)包含至脱丙烷器(44)的塔顶C3/C4产品物流(90),并且其中所述脱丙烷器(44)包含C3产品物流(48)。
8.一种用于在催化裂化系统中生产烯烃的方法,其中所述方法包括:
将进料(14)引导至反应器/再生器(10),其中所述进料(14)包含选自粗柴油、脱沥青油(DAO)、常压渣油和不含芳烃的富含C5/C6的轻石脑油进料的至少一种组分;
所述反应器/再生器(10)产生包含轻石蜡烃和重石蜡烃、环烷烃、芳烃和烯烃的高价值产品物流(16);
将所述高价值产品物流(16)引导至主分馏器(18);
主分馏器(18)分馏并产生:
分馏器蒸气产品物流(22),其包含燃料气、C3/C4和轻石脑油;
粗石脑油产品物流(34);和
分馏器液体产品物流(20),其包含选自重石脑油、轻循环油(LCO)和油浆的至少一种组分;并且
将分馏器蒸气产品物流和粗石脑油产品物流(22,34)引导至包括初级吸收器(58)的蒸气回收单元(VRU);
所述VRU分离分馏器蒸气产品物流和粗石脑油产品物流(22,34),以得到不含芳烃的富含C5/C6的产品物流(74);
将所述不含芳烃的富含C5/C6的产品物流(74)作为不含芳烃的富含C5/C6的轻石脑油进料循环物引导至所述反应器/再生器(10);
其中所述VRU进一步包括选自以下的单元:
1)脱丁烷器塔(40)和石脑油分离器塔(76)的组合,其中:
脱丁烷器的塔底产品(82)被分离为至所述石脑油分离器塔(76)的进料和至所述初级吸收器(58)的进料,并且
石脑油分离器塔(76)分离出不含芳烃的富含C5/C6的产品物流(74);和
2)分隔壁塔(DWC)(88),其包括预分馏器部分和主分馏器部分(99),其中:
所述DWC(88)包含侧馏分,其是所述不含芳烃的富含C5/C6的产品物流(96);和
所述DWC包含至初级吸收器(58)的塔底产品进料(92)。
9.权利要求8所述的方法,其中所述VRU包括脱丁烷器塔(40)和石脑油分离器塔(76)的组合,并且其中,所述方法进一步包括将来自石脑油分离器塔(76)的塔底产品物流(84)引导至加氢处理器。
10.权利要求9所述的方法,其中所述塔底产品物流(84)是催化裂化石脑油汽油共混原料。
11.权利要求9所述的催化裂化系统,其中所述脱丁烷器塔(40)产生至脱丙烷器的塔顶C3/C4产品物流(42),并且其中所述脱丙烷器(44)产生C3产品物流(48)。
12.权利要求8所述的催化裂化系统,其中所述VRU包括DWC(88),并且所述DWC(88)产生塔顶C3/C4产品物流(90);主分馏器侧物流,其为不含芳烃的富含C5/C6的产品物流(96);并且所述方法进一步包括引导塔底产品(94)至加氢处理器。
13.权利要求12所述的方法,其中所述塔底产品(94)是催化裂化石脑油汽油共混原料。
14.权利要求12所述的方法,其中所述DWC(88)包含至脱丙烷器(44)的塔顶C3/C4产品物流(90),并且其中所述脱丙烷器(44)包含C3产品物流(48)。
CN202080089899.2A 2019-12-19 2020-12-18 使用分隔壁塔和/或传统塔制备用于针对烯烃生产的催化裂化单元的进料的方法 Pending CN114901374A (zh)

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