CN114892416A - Ultraviolet-resistant polyvinyl chloride artificial leather - Google Patents
Ultraviolet-resistant polyvinyl chloride artificial leather Download PDFInfo
- Publication number
- CN114892416A CN114892416A CN202210442071.1A CN202210442071A CN114892416A CN 114892416 A CN114892416 A CN 114892416A CN 202210442071 A CN202210442071 A CN 202210442071A CN 114892416 A CN114892416 A CN 114892416A
- Authority
- CN
- China
- Prior art keywords
- parts
- polyvinyl chloride
- ultraviolet
- artificial leather
- chloride artificial
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Classifications
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
- D06N3/00—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
- D06N3/04—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof with macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- D06N3/06—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof with macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds with polyvinylchloride or its copolymerisation products
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
- D06N3/00—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
- D06N3/0056—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof characterised by the compounding ingredients of the macro-molecular coating
- D06N3/0059—Organic ingredients with special effects, e.g. oil- or water-repellent, antimicrobial, flame-resistant, magnetic, bactericidal, odour-influencing agents; perfumes
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
- D06N3/00—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
- D06N3/0056—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof characterised by the compounding ingredients of the macro-molecular coating
- D06N3/0063—Inorganic compounding ingredients, e.g. metals, carbon fibres, Na2CO3, metal layers; Post-treatment with inorganic compounds
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
- D06N2209/00—Properties of the materials
- D06N2209/16—Properties of the materials having other properties
- D06N2209/1678—Resistive to light or to UV
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
- D06N2211/00—Specially adapted uses
- D06N2211/12—Decorative or sun protection articles
- D06N2211/28—Artificial leather
Abstract
The invention discloses ultraviolet-resistant polyvinyl chloride artificial leather which comprises the following components in parts by weight: 80-100 parts of polyvinyl chloride resin, 20-30 parts of castor oil, 10-15 parts of di-n-octyl phthalate, 5-8 parts of diisononyl phthalate, 1-2 parts of foaming agent, 5-8 parts of filler, 0.5-2 parts of anti-ultraviolet agent, 1-3 parts of antioxidant, 5-12 parts of color paste, 1-2 parts of methyl anthranilate and 1-2 parts of stabilizer. The anti-ultraviolet agent is added into the leather, so that the prepared polyvinyl chloride artificial leather not only has excellent physical properties such as oxidation resistance, aging resistance and the like, but also has an anti-ultraviolet effect, the artificial leather is further prevented from deteriorating, the service life of the polyvinyl chloride artificial leather can be prolonged, and meanwhile, the selected materials are easy to obtain and low in price, the production cost of enterprises is effectively reduced, and the polyvinyl chloride artificial leather is suitable for mass production.
Description
Technical Field
The invention relates to the technical field of production of polyvinyl chloride artificial leather, in particular to ultraviolet-resistant polyvinyl chloride artificial leather.
Background
Artificial leather is a plastic product that looks and feels like leather and can replace it. Usually, the fabric is used as a substrate and coated with synthetic resin and various plastic additives. Mainly comprises PVC artificial leather and PU synthetic leather.
The PVC artificial leather is a material-proofing product made up by using the mixture formed from PVC resin, plasticizer and other compounding agent and coating or sticking them on the fabric through a certain preparation process. In addition, there is also double-sided polyvinyl chloride artificial leather in which both sides of the base material are plastic layers.
The polyvinyl chloride artificial leather product has high strength, easy processing and low cost, and can be used for making various bags, seat covers, linings, sundries and the like, so that the polyvinyl chloride artificial leather product is widely used for making various backpacks, bags and the like by people.
The damage of light to leather, mainly referred to as ultraviolet rays, is most obviously the damage caused by ultraviolet rays, namely, fading, which is more serious for vegetable tanning and aniline leather. The higher intensity of uv light not only accelerates the degradation of the dye but also causes the degradation of collagen within the leather fibres, which has the meaning of being a little muscular if the leather fibres are bones, and also helps the leather to be stronger. Its degradation will make the leather more brittle and more easily broken.
Therefore, in order to prolong the service life of the leather, the leather must have a certain ultraviolet resistance, and the invention aims to research and develop the ultraviolet-resistant polyvinyl chloride artificial leather.
Disclosure of Invention
The invention aims to provide polyvinyl chloride artificial leather with good ultraviolet resistance.
In order to solve the technical problems, the invention provides ultraviolet-resistant polyvinyl chloride artificial leather which comprises the following components in parts by weight: 80-100 parts of polyvinyl chloride resin, 20-30 parts of castor oil, 10-15 parts of di-n-octyl phthalate, 5-8 parts of diisononyl phthalate, 1-2 parts of foaming agent, 5-8 parts of filler, 0.5-2 parts of anti-ultraviolet agent, 1-3 parts of antioxidant, 5-12 parts of color paste, 1-2 parts of methyl anthranilate and 1-2 parts of stabilizer.
Preferably, the paint comprises the following components in parts by weight: 100 parts of polyvinyl chloride resin, 25 parts of castor oil, 10 parts of di-n-octyl phthalate, 5 parts of diisononyl phthalate, 2 parts of foaming agent, 5 parts of filler, 2 parts of anti-ultraviolet agent, 1 part of antioxidant, 12 parts of color paste and 2 parts of methyl anthranilate.
Preferably, the uvioresistant agent is 2-hydroxy-4-n-octoxy benzophenone.
Preferably, the filler is magnesium carbonate.
Preferably, the antioxidant is 2, 6-tertiary butyl-4-methylphenol.
Preferably, the blowing agent is azodicarbonamide.
Preferably, the stabilizer is an organotin stabilizer.
Through reasonable formula optimization, the prepared polyvinyl chloride artificial leather not only has excellent physical properties such as oxidation resistance, aging resistance and the like, but also has an anti-ultraviolet effect, further prevents the polyvinyl chloride artificial leather from deteriorating, can prolong the service life of the polyvinyl chloride artificial leather, is easy to obtain and low in price, effectively reduces the production cost of enterprises, and is suitable for mass production.
Detailed Description
The technical solutions in the embodiments of the present invention will be clearly and completely described below with reference to specific embodiments.
Example 1
The ultraviolet-resistant polyvinyl chloride artificial leather comprises the following components in parts by weight: 80 parts of polyvinyl chloride resin, 20 parts of castor oil, 10 parts of di-n-octyl phthalate, 5 parts of diisononyl phthalate, 1 part of azodicarbonamide, 5 parts of magnesium carbonate, 0.5 part of 2-hydroxy-4-n-octyloxy benzophenone, 1 part of 2, 6-tertiary butyl-4-methylphenol, 5 parts of color paste, 1 part of methyl anthranilate and 1 part of organic tin stabilizer.
Mixing the raw materials according to the proportion, reacting for 2.5h at 120 ℃, then preserving heat for 2h at 90 ℃ to obtain a material, then extruding and molding, cooling, and cutting into a required shape.
Example 2
The ultraviolet-resistant polyvinyl chloride artificial leather comprises the following components in parts by weight: 100 parts of polyvinyl chloride resin, 30 parts of castor oil, 15 parts of di-n-octyl phthalate, 8 parts of diisononyl phthalate, 2 parts of azodicarbonamide, 8 parts of magnesium carbonate, 2 parts of 2-hydroxy-4-n-octyloxy benzophenone, 3 parts of 2, 6-tertiary butyl-4-methylphenol, 12 parts of color paste, 2 parts of methyl anthranilate and 2 parts of organic tin stabilizer.
The preparation method is the same as example 1.
Example 3
The ultraviolet-resistant polyvinyl chloride artificial leather comprises the following components in parts by weight: 85 parts of polyvinyl chloride resin, 25 parts of castor oil, 12 parts of di-n-octyl phthalate, 8 parts of diisononyl phthalate, 1 part of azodicarbonamide, 5 parts of magnesium carbonate, 1 part of 2-hydroxy-4-n-octyloxy benzophenone, 2 parts of 2, 6-tertiary butyl-4-methylphenol, 8 parts of color paste, 1 part of methyl anthranilate and 2 parts of organic tin stabilizer.
The preparation method is the same as example 1.
Example 4
The ultraviolet-resistant polyvinyl chloride artificial leather comprises the following components in parts by weight: 90 parts of polyvinyl chloride resin, 25 parts of castor oil, 12 parts of di-n-octyl phthalate, 6 parts of diisononyl phthalate, 1 part of azodicarbonamide, 6 parts of magnesium carbonate, 1 part of 2-hydroxy-4-n-octyloxy benzophenone, 2 parts of 2, 6-tertiary butyl-4-methylphenol, 3 parts of color paste, 1 part of methyl anthranilate and 2 parts of organic tin stabilizer.
The preparation method is the same as example 1.
According to the invention, the uvioresistant agent is added into the leather, so that the prepared leather not only has excellent physical properties such as oxidation resistance, aging resistance and the like, but also has an uvioresistant effect, the leather is further prevented from deteriorating, the service life of the leather can be prolonged, and meanwhile, the selected material is easy to obtain and low in price, the production cost of enterprises is effectively reduced, and the leather is suitable for mass production.
While the foregoing is directed to the preferred embodiment of the present invention, it will be understood by those skilled in the art that various changes and modifications may be made without departing from the spirit and scope of the invention.
Claims (7)
1. The ultraviolet-resistant polyvinyl chloride artificial leather is characterized by comprising the following components in parts by weight: 80-100 parts of polyvinyl chloride resin, 20-30 parts of castor oil, 10-15 parts of di-n-octyl phthalate, 5-8 parts of diisononyl phthalate, 1-2 parts of foaming agent, 5-8 parts of filler, 0.5-2 parts of anti-ultraviolet agent, 1-3 parts of antioxidant, 5-12 parts of color paste, 1-2 parts of methyl anthranilate and 1-2 parts of stabilizer.
2. An ultraviolet-resistant polyvinyl chloride artificial leather is characterized in that: the paint comprises the following components in parts by weight: 100 parts of polyvinyl chloride resin, 25 parts of castor oil, 10 parts of di-n-octyl phthalate, 5 parts of diisononyl phthalate, 2 parts of foaming agent, 5 parts of filler, 2 parts of anti-ultraviolet agent, 1 part of antioxidant, 12 parts of color paste and 2 parts of methyl anthranilate.
3. An ultraviolet-resistant polyvinyl chloride artificial leather is characterized in that: the uvioresistant agent is 2-hydroxy-4-n-octoxy benzophenone.
4. An ultraviolet-resistant polyvinyl chloride artificial leather is characterized in that: the filler is magnesium carbonate.
5. An ultraviolet-resistant polyvinyl chloride artificial leather is characterized in that: the antioxidant is 2, 6-tertiary butyl-4-methylphenol.
6. An ultraviolet-resistant polyvinyl chloride artificial leather is characterized in that: the foaming agent is azodicarbonamide.
7. An ultraviolet-resistant polyvinyl chloride artificial leather is characterized in that: the stabilizer is an organic tin stabilizer.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN202210442071.1A CN114892416A (en) | 2022-04-25 | 2022-04-25 | Ultraviolet-resistant polyvinyl chloride artificial leather |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN202210442071.1A CN114892416A (en) | 2022-04-25 | 2022-04-25 | Ultraviolet-resistant polyvinyl chloride artificial leather |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN114892416A true CN114892416A (en) | 2022-08-12 |
Family
ID=82717325
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN202210442071.1A Pending CN114892416A (en) | 2022-04-25 | 2022-04-25 | Ultraviolet-resistant polyvinyl chloride artificial leather |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN114892416A (en) |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102046186A (en) * | 2008-05-06 | 2011-05-04 | 马拉德克里科聚合物公司 | Antimicrobial and antistatic polymers and methods of using such polymers on various substrates |
| CN106436346A (en) * | 2016-12-19 | 2017-02-22 | 福建宝利特科技股份有限公司 | Uvioresistant artificial leather |
| CN107119466A (en) * | 2017-05-11 | 2017-09-01 | 佛山高明骏腾塑胶有限公司 | A kind of uvioresistant PVC artificial leather and preparation method thereof |
| CN111040329A (en) * | 2018-10-12 | 2020-04-21 | 现代自动车株式会社 | Surface layer for artificial leather and method for manufacturing artificial leather |
-
2022
- 2022-04-25 CN CN202210442071.1A patent/CN114892416A/en active Pending
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102046186A (en) * | 2008-05-06 | 2011-05-04 | 马拉德克里科聚合物公司 | Antimicrobial and antistatic polymers and methods of using such polymers on various substrates |
| CN106436346A (en) * | 2016-12-19 | 2017-02-22 | 福建宝利特科技股份有限公司 | Uvioresistant artificial leather |
| CN107119466A (en) * | 2017-05-11 | 2017-09-01 | 佛山高明骏腾塑胶有限公司 | A kind of uvioresistant PVC artificial leather and preparation method thereof |
| CN111040329A (en) * | 2018-10-12 | 2020-04-21 | 现代自动车株式会社 | Surface layer for artificial leather and method for manufacturing artificial leather |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN105440505A (en) | PVC (polyvinyl chloride) foam material for sole and preparation method of PVC foam material | |
| CN109627636B (en) | Frosted PVC material for automobile internal and external decoration strips and manufacturing method thereof | |
| CN105670145B (en) | A kind of preparation method of ageing-resistant tire curing bladder | |
| CN102532747A (en) | Polyvinyl chloride decoration material and preparation method thereof | |
| CN106947187A (en) | A kind of sunlight fabric is material modified and preparation method thereof with PVC | |
| CN104130528A (en) | Transparent and environment-friendly PVC modified material and preparation method thereof | |
| CN113710857B (en) | Novel polyvinyl chloride plastic alloy tile and preparation method thereof | |
| CN106496856A (en) | Micro-foaming material and preparation method thereof and refrigeration plant | |
| CN112321915A (en) | Nitrile rubber sealing ring | |
| CN104277289A (en) | High temperature-resistant and light aging-resistant PE (polyethylene) film and preparation method thereof | |
| CN106947139A (en) | A kind of antistatic film and preparation method thereof | |
| CN110498985A (en) | A kind of high durable waterproof roll PVC material for building and preparation method thereof | |
| CN114892416A (en) | Ultraviolet-resistant polyvinyl chloride artificial leather | |
| CN1244628C (en) | Improved polyvinyl chloride-butadiene-acrylonitrile rubber as cable material | |
| US4393022A (en) | Eraser and process for its manufacture | |
| CN113121851A (en) | Carrier-free master batch composition and preparation method of carrier-free master batch | |
| CN109438859A (en) | A kind of plastic cement race track thermoplastic elastomer (TPE) and preparation method thereof | |
| CN108530786A (en) | A kind of ageing-resistant HIPS foamed plastics and preparation method thereof | |
| CN108641227B (en) | Decomposition-resistant weather-resistant colored polyvinyl chloride and preparation method thereof | |
| CN109006052B (en) | Agricultural greenhouse plastic composite film and preparation method thereof | |
| CN110387070A (en) | Rubber composition and its mixing method with fluorescent effect | |
| CN110951182A (en) | PVC film for automotive interior night warning and preparation method | |
| CN111154220A (en) | High-frequency welding ABS composite material for automobile sun shield and preparation method thereof | |
| CN108752646A (en) | A kind of preparation method of water-fast degradable plastic toy | |
| CN108752780A (en) | The preparation method of anti-oxidant heat-resistant PVC modified material |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination |