CN106436346A - Uvioresistant artificial leather - Google Patents
Uvioresistant artificial leather Download PDFInfo
- Publication number
- CN106436346A CN106436346A CN201611177150.5A CN201611177150A CN106436346A CN 106436346 A CN106436346 A CN 106436346A CN 201611177150 A CN201611177150 A CN 201611177150A CN 106436346 A CN106436346 A CN 106436346A
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- CN
- China
- Prior art keywords
- raw material
- artificial leather
- ultraviolet
- material layer
- parts
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- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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Classifications
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
- D06N3/00—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
- D06N3/04—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof with macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- D06N3/06—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof with macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds with polyvinylchloride or its copolymerisation products
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
- D06N3/00—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
- D06N3/0056—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof characterised by the compounding ingredients of the macro-molecular coating
- D06N3/0061—Organic fillers or organic fibrous fillers, e.g. ground leather waste, wood bark, cork powder, vegetable flour; Other organic compounding ingredients; Post-treatment with organic compounds
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
- D06N2209/00—Properties of the materials
- D06N2209/16—Properties of the materials having other properties
- D06N2209/1678—Resistive to light or to UV
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
- D06N2211/00—Specially adapted uses
- D06N2211/12—Decorative or sun protection articles
- D06N2211/28—Artificial leather
Landscapes
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Life Sciences & Earth Sciences (AREA)
- Wood Science & Technology (AREA)
- Synthetic Leather, Interior Materials Or Flexible Sheet Materials (AREA)
Abstract
The invention relates to uvioresistant artificial leather. The uvioresistant artificial leather comprises a bottom layer and a raw material layer, wherein the raw material layer is arranged on the bottom layer, the raw material layer is prepared from the following raw materials in parts by weight: 95-105 parts of polyvinyl chloride, 60-70 parts of dioctyl phthalate, 1-3 parts of an antioxidant and 1-3 parts of an ultraviolet absorber. The uvioresistant artificial leather provided by the invention has the advantage that surface colour of the leather is not changed after the leather resists ultraviolet for 720 hours.
Description
Technical field
The present invention relates to artificial leather technology, more particularly to a kind of anti-ultraviolet artificial leather.
Background technology
Artificial leather is more and more extensive in the application of the fields such as clothing, sport shoess, sofa, case and bag, compensate for a great extent
The animal skins impact for bringing to manufacturing industry in short supply, people are desirable to carry out ultraviolet protection when taking action under the sun, for
Typically do not possess the ability of anti-ultraviolet in the artificial leather of clothing.
The patent of invention of Patent No. 201410464267.6 discloses a kind of artificial leather of anti-ultraviolet, and lower floor is substrate
Layer, upper strata is that surface layer, the hypothalluses are made by fabric fibre, the material being spilled in fabric fibre with anti-ultraviolet function
Grain, the surface layer is made for PU.Foregoing invention is due to the material granule in hypothalluses with anti-ultraviolet, such as zinc oxide and dioxy
Change titanium so that effective protective action when dress ornament made by the artificial leather, can be played to ultraviolet.By adding with UV resistance
The mode of the material granule of line, although the protective action to ultraviolet can be obtained, but its anti-ultraviolet property is not perfect enough,
Still need to improve.
Content of the invention
The technical problem to be solved is：There is provided a kind of anti-ultraviolet property good anti-ultraviolet artificial leather.
In order to solve above-mentioned technical problem, the technical solution used in the present invention is：
A kind of anti-ultraviolet artificial leather, including bottom and raw material layer, the raw material layer is arranged on the bottom, described
Raw material layer includes that following raw material is prepared from：Polrvinyl chloride 95-105 part, dioctyl phthalate 60-70 part, anti-
Oxidant 1-3 part and UV absorbent 1-3 part.
The beneficial effects of the present invention is：
(1) the anti-ultraviolet artificial leather of the present invention, while add above-mentioned antioxidant and ultraviolet suction in raw material layer
Agent is received, antioxidant and UV absorbent are jointly sufficiently compatible with dioctyl phthalate, and then expand molecular structure,
Other the less molecular weight in artificial leather raw material are wrapped, makes ultraviolet not allow other less molecular weight of destructible；So as to
With good anti-ultraviolet property；
(2) antioxidant and UV absorbent are added jointly, for being compared to single interpolation UV absorbent, permissible
Obtain the longer UV resistant time, it is not easy to so that leather surface is changed colour, make leather more robust.
Specific embodiment
By describing the technology contents of the present invention in detail, realizing purpose and effect, it is explained below in conjunction with embodiment.
The design of most critical of the present invention is：While adding above-mentioned antioxidant and UV absorbent in raw material layer,
To expand molecular structure, so as to other less molecular weight are wrapped, anti-ultraviolet property is obtained.
The present invention provides a kind of anti-ultraviolet artificial leather, and including bottom and raw material layer, the raw material layer is arranged at described
On bottom, the raw material layer includes that following raw material is prepared from：Polrvinyl chloride 95-105 part, dioctyl phthalate
60-70 part, antioxidant 1-3 part and UV absorbent 1-3 part.
Knowable to foregoing description, the beneficial effects of the present invention is：
(1) the anti-ultraviolet artificial leather of the present invention, while add above-mentioned antioxidant and ultraviolet suction in raw material layer
Agent is received, antioxidant and UV absorbent are jointly sufficiently compatible with dioctyl phthalate, and then expand molecular structure,
Other the less molecular weight in artificial leather raw material are wrapped, makes ultraviolet not allow other less molecular weight of destructible；So as to
With good anti-ultraviolet property；
(2) antioxidant and UV absorbent are added jointly, for being compared to single interpolation UV absorbent, permissible
Obtain the longer UV resistant time, it is not easy to so that leather surface is changed colour, make leather more robust.
Further, the weight portion of the polrvinyl chloride is 100 parts.
Seen from the above description, the weight portion of example, polrvinyl chloride is selected to be 100 parts as a specific weight portion.
Further, the raw material of the raw material layer also includes the stabilizer of 1-3 weight portion.
Further, the stabilizer is KZn stabilizer.
Seen from the above description, as a specific example, the raw material of raw material layer also includes aforementioned stable agent, specifically
, stabilizer can be KZn stabilizer, and certainly, the stabilizer of the present invention can also be selected for artificial leather in prior art
Other stabilizers.
Further, the raw material layer is prepared from by following raw material：Polrvinyl chloride 95-105 part, O-phthalic
Dioctyl phthalate 60-70 part, stabilizer 1-3 part, antioxidant 1-3 part and UV absorbent 1-3 part.
Seen from the above description, as a specific selection example, raw material layer is only prepared by the raw material of above-mentioned weight portion
Form.
Further, the bottom is artificial leather base fabric.
Seen from the above description, as a specific selection example, bottom is common artificial leather base fabric, during preparation,
Directly raw material layer can be arranged on artificial leather base fabric by release paper.
Further, the antioxidant is AD12S antioxidant.
Further, the UV absorbent is AD12T UV absorbent.
Seen from the above description, as a specific selection example, antioxidant can select AD12S antioxidant,
UV absorbent can select AD12T UV absorbent；Above-mentioned specifically chosen with more excellent anti-ultraviolet property.
Embodiments of the invention one are：
A kind of anti-ultraviolet artificial leather, including bottom and raw material layer, the bottom is artificial leather base fabric.The raw material layer
It is arranged on the bottom, the raw material layer includes that following raw material is prepared from：95 parts of polrvinyl chloride, phthalic acid
60 parts of dioctyl ester, 1 part of KZn stabilizer, 1 part of AD12S antioxidation and 1 part of AD12T UV absorbent.
Embodiments of the invention two are：
A kind of anti-ultraviolet artificial leather, including bottom and raw material layer, the bottom is artificial leather base fabric.The raw material layer
It is arranged on the bottom, the raw material layer includes that following raw material is prepared from：105 parts of polrvinyl chloride, O-phthalic
70 parts of dioctyl phthalate, 3 parts of KZn stabilizer, 3 parts of AD12S antioxidation and 3 parts of AD12T UV absorbent.
Embodiments of the invention three are：
A kind of anti-ultraviolet artificial leather, including bottom and raw material layer, the bottom is artificial leather base fabric.The raw material layer
It is arranged on the bottom, the raw material layer includes that following raw material is prepared from：100 parts of polrvinyl chloride, O-phthalic
65 parts of dioctyl phthalate, 2 parts of KZn stabilizer, 2 parts of AD12S antioxidation and 2 parts of AD12T UV absorbent.
Performance test
The anti-ultraviolet artificial leather of above-described embodiment one to embodiment three is carried out anti-ultraviolet property test respectively；With
When, with reference to the proportioning raw materials of the raw material layer of the anti-ultraviolet artificial leather of above-described embodiment one to embodiment three, uniquely different
It is the AD12S antioxidation and AD12T ultra-violet absorption being not added with the raw material of above-described embodiment one to the raw material layer of embodiment three
Agent, using as reference examples 1-3.
Specifically anti-ultraviolet property test condition is：
By the anti-ultraviolet artificial leather of embodiment one to embodiment three be cut into respectively 20CM*20CM with tin-foil plate by skin
Leather surface half covers placement under the bulb of vitalight lamp 50CM, and temperature 50 C is tested 720 hours, and is tested with color inhibition
Instrument.
Test result shows：When the testing time being 720 hours, embodiment one is anti-ultraviolet to embodiment three
The still invariant color of the surface color of artificial leather, that is, have the non-discoloring advantage of 720 hours leather surface colors of uvioresistant.
With tin-foil plate, leather surface half is covered placement by what the artificial leather of reference examples 1-3 was cut into 20CM*20CM respectively
Under the bulb of vitalight lamp 50CM, temperature 50 C is tested 72 hours, and uses color inhibition tester.
Test result shows：When the testing time being 72 hours, the surface color of the artificial leather of reference examples 1-3 starts
Discoloration, i.e., its anti-ultraviolet property is poor.
In sum, the anti-ultraviolet artificial leather that the present invention is provided has 720 hours leather surface colors of uvioresistant
Non-discoloring advantage.
Embodiments of the invention are the foregoing is only, the scope of the claims of the present invention is not thereby limited, every using this
The equivalents made by bright description, or the technical field of correlation is directly or indirectly used in, all include at this in the same manner
In bright scope of patent protection.
Claims (8)
1. a kind of anti-ultraviolet artificial leather, including bottom and raw material layer, the raw material layer is arranged on the bottom, its feature
It is, the raw material layer includes that following raw material is prepared from：Polrvinyl chloride 95-105 part, dioctyl phthalate
60-70 part, antioxidant 1-3 part and UV absorbent 1-3 part.
2. anti-ultraviolet artificial leather according to claim 1, it is characterised in that the weight portion of the polrvinyl chloride is
100 parts.
3. anti-ultraviolet artificial leather according to claim 1, it is characterised in that the raw material of the raw material layer also includes 1-
The stabilizer of 3 weight portions.
4. anti-ultraviolet artificial leather according to claim 3, it is characterised in that the stabilizer be.
5. anti-ultraviolet artificial leather according to claim 1, it is characterised in that the raw material layer is by following weight portion original
Material is prepared from：Polrvinyl chloride 95-105 part, dioctyl phthalate 60-70 part, stabilizer 1-3 part, antioxidant 1-3 part
With UV absorbent 1-3 part.
6. anti-ultraviolet artificial leather according to claim 1, it is characterised in that the bottom be.
7. anti-ultraviolet artificial leather according to claim 1, it is characterised in that the antioxidant be
Agent.
8. anti-ultraviolet artificial leather according to claim 1, it is characterised in that the UV absorbent be
UV absorbent.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201611177150.5A CN106436346A (en) | 2016-12-19 | 2016-12-19 | Uvioresistant artificial leather |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201611177150.5A CN106436346A (en) | 2016-12-19 | 2016-12-19 | Uvioresistant artificial leather |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN106436346A true CN106436346A (en) | 2017-02-22 |
Family
ID=58215078
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201611177150.5A Pending CN106436346A (en) | 2016-12-19 | 2016-12-19 | Uvioresistant artificial leather |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN106436346A (en) |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107119466A (en) * | 2017-05-11 | 2017-09-01 | 佛山高明骏腾塑胶有限公司 | A kind of uvioresistant PVC artificial leather and preparation method thereof |
| CN108034168A (en) * | 2017-03-07 | 2018-05-15 | 广东菲安妮皮具股份有限公司 | Artificial polyvinyl chloride leather of luggage color inhibition and preparation method thereof |
| CN114892416A (en) * | 2022-04-25 | 2022-08-12 | 广东菲安妮皮具股份有限公司 | Ultraviolet-resistant polyvinyl chloride artificial leather |
| CN115595799A (en) * | 2021-07-08 | 2023-01-13 | 上海海优威新材料股份有限公司（Cn） | Polyolefin artificial leather base material containing rubber component and having excellent light aging resistance, and artificial leather |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1888299A (en) * | 2005-06-28 | 2007-01-03 | 上海广丽工贸有限公司 | Formula and process of antimagnetic face layer artificial leather |
| CN101121869A (en) * | 2007-09-21 | 2008-02-13 | 北京市化学工业研究院 | Method for preparing water polyurethane binder for shoe |
| CN102199882A (en) * | 2011-04-02 | 2011-09-28 | 江苏国信合成革有限公司 | TPU modified high performance PVC ball leather and its preparation method |
| CN106218164A (en) * | 2016-08-31 | 2016-12-14 | 佛山市高明区生产力促进中心 | A kind of manufacture method of the PVC artificial leather of high resistance against wear |
-
2016
- 2016-12-19 CN CN201611177150.5A patent/CN106436346A/en active Pending
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1888299A (en) * | 2005-06-28 | 2007-01-03 | 上海广丽工贸有限公司 | Formula and process of antimagnetic face layer artificial leather |
| CN101121869A (en) * | 2007-09-21 | 2008-02-13 | 北京市化学工业研究院 | Method for preparing water polyurethane binder for shoe |
| CN102199882A (en) * | 2011-04-02 | 2011-09-28 | 江苏国信合成革有限公司 | TPU modified high performance PVC ball leather and its preparation method |
| CN106218164A (en) * | 2016-08-31 | 2016-12-14 | 佛山市高明区生产力促进中心 | A kind of manufacture method of the PVC artificial leather of high resistance against wear |
Non-Patent Citations (1)
| Title |
|---|
| 丁振华等: "《紫外辐射生物学与医学》", 30 November 2000 * |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108034168A (en) * | 2017-03-07 | 2018-05-15 | 广东菲安妮皮具股份有限公司 | Artificial polyvinyl chloride leather of luggage color inhibition and preparation method thereof |
| CN107119466A (en) * | 2017-05-11 | 2017-09-01 | 佛山高明骏腾塑胶有限公司 | A kind of uvioresistant PVC artificial leather and preparation method thereof |
| CN115595799A (en) * | 2021-07-08 | 2023-01-13 | 上海海优威新材料股份有限公司（Cn） | Polyolefin artificial leather base material containing rubber component and having excellent light aging resistance, and artificial leather |
| CN114892416A (en) * | 2022-04-25 | 2022-08-12 | 广东菲安妮皮具股份有限公司 | Ultraviolet-resistant polyvinyl chloride artificial leather |
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| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20170222 |
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| RJ01 | Rejection of invention patent application after publication |