CN106218164A - A kind of manufacture method of the PVC artificial leather of high resistance against wear - Google Patents

A kind of manufacture method of the PVC artificial leather of high resistance against wear Download PDF

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Publication number
CN106218164A
CN106218164A CN201610786124.6A CN201610786124A CN106218164A CN 106218164 A CN106218164 A CN 106218164A CN 201610786124 A CN201610786124 A CN 201610786124A CN 106218164 A CN106218164 A CN 106218164A
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parts
artificial leather
manufacture method
high resistance
resistance against
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贺炳红
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Foshan Gaoming District Productivity Promotion Center
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Foshan Gaoming District Productivity Promotion Center
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Priority to CN201610786124.6A priority Critical patent/CN106218164A/en
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    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00—Layered products comprising a layer of synthetic resin
    • B32B27/12—Layered products comprising a layer of synthetic resin next to a fibrous or filamentary layer
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00—Layered products comprising a layer of synthetic resin
    • B32B27/18—Layered products comprising a layer of synthetic resin characterised by the use of special additives
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00—Layered products comprising a layer of synthetic resin
    • B32B27/18—Layered products comprising a layer of synthetic resin characterised by the use of special additives
    • B32B27/22—Layered products comprising a layer of synthetic resin characterised by the use of special additives using plasticisers
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00—Layered products comprising a layer of synthetic resin
    • B32B27/30—Layered products comprising a layer of synthetic resin comprising vinyl (co)polymers; comprising acrylic (co)polymers
    • B32B27/304—Layered products comprising a layer of synthetic resin comprising vinyl (co)polymers; comprising acrylic (co)polymers comprising vinyl halide (co)polymers, e.g. PVC, PVDC, PVF, PVDF
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B37/00—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding
    • B32B37/10—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding characterised by the pressing technique, e.g. using action of vacuum or fluid pressure
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
    • C08J9/04—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent
    • C08J9/06—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent by a chemical blowing agent
    • C08J9/10—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent by a chemical blowing agent developing nitrogen, the blowing agent being a compound containing a nitrogen-to-nitrogen bond
    • C08J9/102—Azo-compounds
    • C08J9/103—Azodicarbonamide
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L27/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers
    • C08L27/02—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L27/04—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment containing chlorine atoms
    • C08L27/06—Homopolymers or copolymers of vinyl chloride
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
    • D06M15/21—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M15/263—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of unsaturated carboxylic acids; Salts or esters thereof
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
    • D06M15/37—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M15/55—Epoxy resins
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/693—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with natural or synthetic rubber, or derivatives thereof
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2270/00—Resin or rubber layer containing a blend of at least two different polymers
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00—Properties of the layers or laminate
    • B32B2307/50—Properties of the layers or laminate having particular mechanical properties
    • B32B2307/536—Hardness
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00—Properties of the layers or laminate
    • B32B2307/50—Properties of the layers or laminate having particular mechanical properties
    • B32B2307/554—Wear resistance
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2315/00—Other materials containing non-metallic inorganic compounds not provided for in groups B32B2311/00 - B32B2313/04
    • B32B2315/02—Ceramics
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2315/00—Other materials containing non-metallic inorganic compounds not provided for in groups B32B2311/00 - B32B2313/04
    • B32B2315/08—Glass
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2327/00—Polyvinylhalogenides
    • B32B2327/06—PVC, i.e. polyvinylchloride
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2329/00—Polyvinylalcohols, polyvinylethers, polyvinylaldehydes, polyvinylketones or polyvinylketals
    • B32B2329/04—Polyvinylalcohol
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2375/00—Polyureas; Polyurethanes
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2203/00—Foams characterized by the expanding agent
    • C08J2203/04—N2 releasing, ex azodicarbonamide or nitroso compound
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2327/00—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Derivatives of such polymers
    • C08J2327/02—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Derivatives of such polymers not modified by chemical after-treatment
    • C08J2327/04—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Derivatives of such polymers not modified by chemical after-treatment containing chlorine atoms
    • C08J2327/06—Homopolymers or copolymers of vinyl chloride
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2491/00—Characterised by the use of oils, fats or waxes; Derivatives thereof
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K2201/00—Specific properties of additives
    • C08K2201/014—Additives containing two or more different additives of the same subgroup in C08K
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2203/00—Applications
    • C08L2203/14—Applications used for foams
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00—Polymer mixtures characterised by other features
    • C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Textile Engineering (AREA)
  • Polymers & Plastics (AREA)
  • Medicinal Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Organic Chemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Materials Engineering (AREA)
  • Physics & Mathematics (AREA)
  • Fluid Mechanics (AREA)
  • Synthetic Leather, Interior Materials Or Flexible Sheet Materials (AREA)

Abstract

The present invention provides the manufacture method of the PVC artificial leather of a kind of high resistance against wear, relate to artificial leather manufacture technology field, comprise the following steps: the making of top layer slurry, base pastes making, compound, base fabric selection and pretreatment and laminating and embossing, described base fabric selects and pretreatment refers to choose non-woven fabrics, non-woven fabrics is placed on immersion 40～50min in mixed liquor form with 3:1:1:4 with thickening agent, styrene-butadiene latex, acrylic acid ester emulsion and water-dispersible epoxy resins, then non-woven fabrics is drained, be positioned in drying plant and dry 25～32min with the temperature of 75～85 DEG C.Usefulness of the present invention is, method is simple, is easily mastered, and uses the wear resistance high-amplitude of PVC artificial leather that the method manufactures to strengthen, and improves ruggedness, increases the service life.

Description

A kind of manufacture method of the PVC artificial leather of high resistance against wear
Technical field
The present invention relates to artificial leather manufacture technology field, the manufacture method of the PVC artificial leather of a kind of high resistance against wear.
Background technology
Artificial leather is a kind of outward appearance, feel is like leather and can replace its plastic used, generally with fabric as base, Coating synthetic resin and various plastics add to be made.Last century the eighties, expensive fur clothing skin material common people consumes not rise, and answer The market demand, the artificial leather of counterfeit leather once came into vogue, and was widely used in the middle of clothing, system bag.In China, people practise Being used to be referred to as PVC artificial leather with the artificial leather of polrvinyl chloride (PVC) production of resins, PVC artificial leather is widely used in making life In the middle of article of everyday use and industrial goods, become the indispensable a kind of material of current social development.But along with going deep into of PVC artificial leather Application, people are more and more higher for the quality of PVC artificial leather and the requirement of comfort level, in particular for making footwear or dress ornament The PVC artificial leather of class, not only pursues fashionable appearance, soft, also requires that to possess certain toughness, antiwear characteristic, extends In service life, strengthen practicality, this not monoenergetic reduce family daily expenditure, also can alleviate environmental pollution, meet environmental protection Theory, and the most do not find the manufacture method of a kind of PVC artificial leather that can really be effective against abrasion.
Summary of the invention
Instant invention overcomes shortcoming of the prior art, it is provided that the manufacture method of the PVC artificial leather of a kind of high resistance against wear, side Method is simple, is easily mastered, and uses the wear resistance high-amplitude of PVC artificial leather that the method manufactures to strengthen, and improves Ruggedness, increases the service life.
In order to solve above-mentioned technical problem, the present invention is achieved by the following technical solutions:
The manufacture method of the PVC artificial leather of a kind of high resistance against wear, comprises the following steps:
(1) top layer slurry makes: weigh Corvic 50～60 parts, epoxy soybean oil 20～30 parts, O-phthalic Dioctyl phthalate 18～22 parts, dibutyl phthalate 3～8 parts, dibutyl tin laurate 3～5 parts, azodicarbonamide 3～7 Part, calcium carbonate 6～9 parts, antistatic additive 0.3～0.8 part, politef 1～1.3 parts, antioxidant 1.2～1.5 parts, PVC color Starch 5～8 parts, ultraviolet-resistant absorbent 1.2～1.5 parts and abrasion-resistant powder 1.2～1.5 parts, first, above-mentioned raw materials is put into kneading In machine with 430～460r/min speed stir 40～50min, then, material is poured in mill, regulation mill with Mill 30～40min under the parameter of " with drum rotation speed 40～60r/min, mixing temperature 120～130 DEG C "；Finally, material is sent Rolling to four-roll calender, control roller temperature is at 150～170 DEG C, and roller speed will under the parameter of 70～80m/min It is the A thin film of 0.5～0.7mm that material is pressed into thickness, standby；
(2) base pastes makes: weigh Corvic 70～90 parts, epoxy soybean oil 15～18 parts, O-phthalic Dioctyl phthalate 10～14 parts, dibutyl phthalate 5～10 parts, dibutyl tin laurate 1～3 parts, azodicarbonamide 2～ 4 parts, calcium carbonate 5～8 parts, politef 1～1.3 parts, mof material 2～2.2 parts, petroleum ether 2.2～2.6 parts, β-propenyl benzene Acid 0.2～0.4 part, face amino benzoic Acid 0.5～0.8 part, Graphene 0.6～1 part, first, above-mentioned raw materials is put into kneading In machine with 480～540r/min speed stir 30～40min, then, material is poured in mill, regulation mill with Mill 25～35min under the parameter of " with drum rotation speed 70～80r/min, mixing temperature 110～120 DEG C "；Finally, material is sent Rolling to four-roll calender, control roller temperature is at 120～140 DEG C, and roller speed is under the parameter of 90～100m/min It is the B thin film of 0.8～1.2mm that material is pressed into thickness, standby；
(3) compound: put layer by A thin film, B thin film is sent in four-roll calender after stacking in the way of putting down layer, controls pressure Roll temperature is at 90～110 DEG C, and it is 0.6～0.9mm that material is pressed into thickness under the parameter of 80～90m/min by roller speed C thin film；
(4) base fabric selects and pretreatment: described base fabric chooses non-woven fabrics, and described pretreatment mode refers to place non-woven fabrics The mixed liquor formed with 3:1:1:4 with thickening agent, styrene-butadiene latex, acrylic acid ester emulsion and water-dispersible epoxy resins soaks 40～50min, then non-woven fabrics is drained, be positioned in drying plant and dry 25～32min with the temperature of 75～85 DEG C；
(5) fit and emboss: with hydraulic press by after composite for base fabric, solidification after C thin film and described pretreatment, then delivering to Vacuum tattoo machine makes lines effect,.
Further, the manufacture method of step (1) described abrasion-resistant powder is: by glass, pottery, quartz, corundum and dark fund Sand stirs after mixing by the mass ratio of 3:7:2:6:1, put into concentration be 10% saline in soak 2～3 hours, drain After moisture, then with infrared ray with the temperature sterilizing 3 of 120～140 DEG C～5 hours, after stopping sterilizing, treat that temperature of charge is down to 40 ～when 60 DEG C, material is delivered to be ground in pulverizer the granule of 1600～17,000,000 mesh numbers the most again.
Further, step (1) described antistatic additive is anionic antistatic agents.
Further, step (1) described ultraviolet-resistant absorbent is the ultraviolet-resistant absorbent of a kind of salicylic acid esters.
Further, step (2) described mof material contains tri-kinds of elements of Cu, Zn and Co.
Further, step (4) described thickening agent refers to polyvinyl alcohol, polyurethane, sodium dodecyl benzenylsulfonate, carboxylic first Base sodium cellulosate and nonyl phenolic group polyoxyethylene ether are stirred by the mass ratio of 2:5:2:3:1 and mix.
Further, described in step (4), the soaking temperature of pin non-woven fabrics is 40～50 DEG C.
Further, drying plant described in step (4) is a kind of revolving cylinder dehydrator.
Compared with prior art, the invention has the beneficial effects as follows:
(1) mar proof greatly strengthens: compared with tradition PVC artificial leather, the PVC artificial leather of high resistance against wear of the present invention is not It is to increase top layer and the wear resistence of bottom with part simultaneously, is mixed into by several hard such as glass, pottery, quartz in the slurry of top layer The abrasion-resistant powder that material is fabricated by, adds mof material and grapheme material simultaneously in base pastes, makes PVC of the present invention artificial Remove from office whole body hardness to have strengthened；(2) cost of manufacture is low: PVC artificial leather of the present invention make equipment needed thereby to purchase the amount of money little, And making low in raw material price, without high price raw material, raw material all can easily buy acquisition, and supply is sufficient, can be full simultaneously Foot large-scale production.
Detailed description of the invention
Hereinafter the preferred embodiments of the present invention are illustrated, it will be appreciated that preferred embodiment described herein is only used In the description and interpretation present invention, it is not intended to limit the present invention.
Embodiment 1
Choose non-woven fabrics as base fabric, non-woven fabrics is placed on thickening agent, styrene-butadiene latex, acrylic acid ester emulsion and moisture Dissipating immersion 40min in the mixed liquor that property epoxy resin form with 3:1:1:4, soaking temperature is 40 DEG C, is then drained by non-woven fabrics, It is positioned in revolving cylinder dehydrator and dries 25min with the temperature of 75 DEG C, standby.
Thickening agent refers to polyvinyl alcohol, polyurethane, sodium dodecyl benzenylsulfonate, sodium carboxymethyl cellulose and nonyl phenolic group Polyoxyethylene ether is stirred by the mass ratio of 2:5:2:3:1 and mixes.
Make abrasion-resistant powder: stir after glass, pottery, quartz, corundum and dark fund sand being mixed by the mass ratio of 3:7:2:6:1 Mix uniformly, put into concentration be 10% saline in soak 2 hours, after draining away the water, then go out with the temperature of 120 DEG C with infrared ray Bacterium 3 hours, after stopping sterilizing, when temperature of charge is down to 40 DEG C, delivers to be ground in pulverizer 1600 the most again by material The granule of ten thousand mesh numbers, standby.
Top layer slurry makes: weigh Corvic 50 parts, epoxy soybean oil 20 parts, dioctyl phthalate 18 Part, dibutyl phthalate 3 parts, dibutyl tin laurate 3 parts, azodicarbonamide 3 parts, calcium carbonate 6 parts, antistatic additive 0.3 part, politef 1 part, 1.2 parts of antioxidant, PVC mill base 5 parts, ultraviolet-resistant absorbent 1.2 parts and abrasion-resistant powder 1.2 parts, First, above-mentioned raw materials is put into the speed stirring 40min with 430r/min in kneader, then, pours material into mill In, regulation mill is with mill 30min under the parameter of " with drum rotation speed 40r/min, mixing temperature 120 DEG C "；Finally, by material Deliver to four-roll calender roll, control roller temperature at 150 DEG C, roller speed under the parameter of 70m/min by material pressure Make the A thin film that thickness is 0.5mm, standby；
Base pastes makes: weigh Corvic 70 parts, epoxy soybean oil 15 parts, dioctyl phthalate 10 Part, dibutyl phthalate 5 parts, dibutyl tin laurate 1 part, azodicarbonamide 2 parts, calcium carbonate 5 parts, politef 1 part, mof material 2 parts, petroleum ether 2.2 parts, β-cinnamic acid 0.2 part, face amino benzoic Acid 0.5 part, Graphene 0.6 part, first First, above-mentioned raw materials is put into the speed stirring 30min with 480r/min in kneader, then, material is poured in mill, Regulation mill is with mill 25min under the parameter of " with drum rotation speed 70r/min, mixing temperature 110 DEG C "；Finally, material is sent Rolling to four-roll calender, control roller temperature is at 120 DEG C, and material is suppressed under the parameter of 90m/min by roller speed One-tenth thickness is the B thin film of 0.8mm, standby；
Compound: put layer by A thin film, B thin film is sent in four-roll calender after stacking in the way of putting down layer, controls pressure roller temperature Degree is at 90 DEG C, and material is pressed into the C thin film that thickness is 0.6mm under the parameter of 80m/min by roller speed；
Laminating and embossing: with hydraulic press by after composite for base fabric, solidification after C thin film and pretreatment, then deliver to vacuum and inhale Stricture of vagina machine makes lines effect,.
Preferably, antistatic additive is anionic antistatic agents.
Preferably, ultraviolet-resistant absorbent is the ultraviolet-resistant absorbent of a kind of salicylic acid esters.
Preferably, mof material contains tri-kinds of elements of Cu, Zn and Co.
Embodiment 2
Choose non-woven fabrics as base fabric, non-woven fabrics is placed on thickening agent, styrene-butadiene latex, acrylic acid ester emulsion and moisture Dissipating immersion 50min in the mixed liquor that property epoxy resin form with 3:1:1:4, soaking temperature is 50 DEG C, is then drained by non-woven fabrics, It is positioned in revolving cylinder dehydrator and dries 32min with the temperature of 85 DEG C, standby.
Thickening agent refers to polyvinyl alcohol, polyurethane, sodium dodecyl benzenylsulfonate, sodium carboxymethyl cellulose and nonyl phenolic group Polyoxyethylene ether is stirred by the mass ratio of 2:5:2:3:1 and mixes.
Make abrasion-resistant powder: stir after glass, pottery, quartz, corundum and dark fund sand being mixed by the mass ratio of 3:7:2:6:1 Mix uniformly, put into concentration be 10% saline in soak 3 hours, after draining away the water, then go out with the temperature of 140 DEG C with infrared ray Bacterium 5 hours, after stopping sterilizing, when temperature of charge is down to 60 DEG C, delivers to be ground in pulverizer 1700 the most again by material The granule of ten thousand mesh numbers, standby.
Top layer slurry makes: weigh Corvic 60 parts, epoxy soybean oil 30 parts, dioctyl phthalate 22 Part, dibutyl phthalate 8 parts, dibutyl tin laurate 5 parts, azodicarbonamide 7 parts, calcium carbonate 9 parts, antistatic additive 0.8 part, politef 1.3 parts, 1.5 parts of antioxidant, PVC mill base 8 parts, ultraviolet-resistant absorbent 1.5 parts and abrasion-resistant powder 1.5 Part, first, above-mentioned raw materials is put into the speed stirring 50min with 460r/min in kneader, then, pours material into mill In machine, regulation mill is with mill 40min under the parameter of " with drum rotation speed 60r/min, mixing temperature 130 DEG C "；Finally, by thing Material is delivered to four-roll calender and is rolled, and controls roller temperature at 170 DEG C, roller speed under the parameter of 80m/min by material It is pressed into the A thin film that thickness is 0.7mm, standby；
Base pastes makes: weigh Corvic 90 parts, epoxy soybean oil 18 parts, dioctyl phthalate 14 Part, dibutyl phthalate 10 parts, dibutyl tin laurate 3 parts, azodicarbonamide 4 parts, calcium carbonate 8 parts, polytetrafluoroethyl-ne 1.3 parts of alkene, mof material 2.2 parts, petroleum ether 2.6 parts, β-cinnamic acid 0.4 part, face amino benzoic Acid 0.8 part, Graphene 1 part, First, above-mentioned raw materials is put into the speed stirring 40min with 540r/min in kneader, then, pours material into mill In, regulation mill is with mill 35min under the parameter of " with drum rotation speed 80r/min, mixing temperature 120 DEG C "；Finally, by material Deliver to four-roll calender roll, control roller temperature at 140 DEG C, roller speed under the parameter of 100m/min by material pressure Make the B thin film that thickness is 1.2mm, standby；
Compound: put layer by A thin film, B thin film is sent in four-roll calender after stacking in the way of putting down layer, controls pressure roller temperature Degree is at 110 DEG C, and material is pressed into the C thin film that thickness is 0.9mm under the parameter of 90m/min by roller speed；
Laminating and embossing: with hydraulic press by after composite for base fabric, solidification after C thin film and pretreatment, then deliver to vacuum and inhale Stricture of vagina machine makes lines effect,.
Preferably, antistatic additive is anionic antistatic agents.
Preferably, ultraviolet-resistant absorbent is the ultraviolet-resistant absorbent of a kind of salicylic acid esters.
Preferably, mof material contains tri-kinds of elements of Cu, Zn and Co.
Embodiment 3
Choose non-woven fabrics as base fabric, non-woven fabrics is placed on thickening agent, styrene-butadiene latex, acrylic acid ester emulsion and moisture Dissipating immersion 45min in the mixed liquor that property epoxy resin form with 3:1:1:4, soaking temperature is 45 DEG C, is then drained by non-woven fabrics, It is positioned in revolving cylinder dehydrator and dries 28min with the temperature of 80 DEG C, standby.
Thickening agent refers to polyvinyl alcohol, polyurethane, sodium dodecyl benzenylsulfonate, sodium carboxymethyl cellulose and nonyl phenolic group Polyoxyethylene ether is stirred by the mass ratio of 2:5:2:3:1 and mixes.
Make abrasion-resistant powder: stir after glass, pottery, quartz, corundum and dark fund sand being mixed by the mass ratio of 3:7:2:6:1 Mix uniformly, put into concentration be 10% saline in soak 2.5 hours, after draining away the water, then with infrared ray with the temperature of 130 DEG C Sterilizing 4 hours, after stopping sterilizing, when temperature of charge is down to 50 DEG C, delivers to material be ground in pulverizer the most again The granule of 17000000 mesh numbers, standby.
Top layer slurry makes: weigh Corvic 55 parts, epoxy soybean oil 25 parts, dioctyl phthalate 20 Part, dibutyl phthalate 5 parts, dibutyl tin laurate 4 parts, azodicarbonamide 5 parts, calcium carbonate 7 parts, antistatic additive 0.5 part, politef 1.1 parts, 1.3 parts of antioxidant, PVC mill base 7 parts, ultraviolet-resistant absorbent 1.3 parts and abrasion-resistant powder 1.4 Part, first, above-mentioned raw materials is put into the speed stirring 45min with 450r/min in kneader, then, pours material into mill In machine, regulation mill is with mill 35min under the parameter of " with drum rotation speed 50r/min, mixing temperature 125 DEG C "；Finally, by thing Material is delivered to four-roll calender and is rolled, and controls roller temperature at 160 DEG C, roller speed under the parameter of 75m/min by material It is pressed into the A thin film that thickness is 0.6mm, standby；
Base pastes makes: weigh Corvic 80 parts, epoxy soybean oil 17 parts, dioctyl phthalate 12 Part, dibutyl phthalate 8 parts, dibutyl tin laurate 2 parts, azodicarbonamide 3 parts, calcium carbonate 7 parts, politef 1.2 parts, mof material 2.1 parts, petroleum ether 2.4 parts, β-cinnamic acid 0.3 part, face amino benzoic Acid 0.7 part, Graphene 0.8 part, First, above-mentioned raw materials is put into the speed stirring 35min with 500r/min in kneader, then, pours material into mill In, regulation mill is with mill 30min under the parameter of " with drum rotation speed 75r/min, mixing temperature 115 DEG C "；Finally, by material Deliver to four-roll calender roll, control roller temperature at 130 DEG C, roller speed under the parameter of 95m/min by material pressure Make the B thin film that thickness is 1mm, standby；
Compound: put layer by A thin film, B thin film is sent in four-roll calender after stacking in the way of putting down layer, controls pressure roller temperature Degree is at 100 DEG C, and material is pressed into the C thin film that thickness is 0.8mm under the parameter of 85m/min by roller speed；
Laminating and embossing: with hydraulic press by after composite for base fabric, solidification after C thin film and pretreatment, then deliver to vacuum and inhale Stricture of vagina machine makes lines effect,.
Preferably, antistatic additive is anionic antistatic agents.
Preferably, ultraviolet-resistant absorbent is the ultraviolet-resistant absorbent of a kind of salicylic acid esters.
Preferably, mof material contains tri-kinds of elements of Cu, Zn and Co.
Finally it is noted that these are only the preferred embodiments of the present invention, it is not limited to the present invention, although Being described in detail the present invention with reference to embodiment, for a person skilled in the art, it still can be to aforementioned Technical scheme described in each embodiment is modified, or wherein portion of techniques feature carries out equivalent, but all Within the spirit and principles in the present invention, any modification, equivalent substitution and improvement etc. made, should be included in the protection of the present invention Within the scope of.

Claims (8)

1. the manufacture method of the PVC artificial leather of a high resistance against wear, it is characterised in that comprise the following steps:
(1) top layer slurry makes: weigh Corvic 50～60 parts, epoxy soybean oil 20～30 parts, phthalic acid two Monooctyl ester 18～22 parts, dibutyl phthalate 3～8 parts, dibutyl tin laurate 3～5 parts, azodicarbonamide 3～7 parts, Calcium carbonate 6～9 parts, antistatic additive 0.3～0.8 part, politef 1～1.3 parts, antioxidant 1.2～1.5 parts, PVC mill base 5 ～8 parts, ultraviolet-resistant absorbent 1.2～1.5 parts and abrasion-resistant powder 1.2～1.5 parts, first, above-mentioned raw materials is put into kneader In with 430～460r/min speed stir 40～50min, then, material is poured in mill, regulation mill with " with Drum rotation speed 40～60r/min, mixing temperature 120～130 DEG C " parameter under mill 30～40min；Finally, material is delivered to Four-roll calender rolls, control roller temperature at 150～170 DEG C, roller speed under the parameter of 70～80m/min by thing It is the A thin film of 0.5～0.7mm that material is pressed into thickness, standby；
(2) base pastes makes: weigh Corvic 70～90 parts, epoxy soybean oil 15～18 parts, phthalic acid two Monooctyl ester 10～14 parts, dibutyl phthalate 5～10 parts, dibutyl tin laurate 1～3 parts, azodicarbonamide 2～4 parts, Calcium carbonate 5～8 parts, politef 1～1.3 parts, mof material 2～2.2 parts, petroleum ether 2.2～2.6 parts, β-cinnamic acid 0.2～0.4 part, face amino benzoic Acid 0.5～0.8 part, Graphene 0.6～1 part, first, above-mentioned raw materials is put into kneader In with 480～540r/min speed stir 30～40min, then, material is poured in mill, regulation mill with " with Drum rotation speed 70～80r/min, mixing temperature 110～120 DEG C " parameter under mill 25～35min；Finally, material is delivered to Four-roll calender rolls, and control roller temperature is at 120～140 DEG C, and roller speed will under the parameter of 90～100m/min It is the B thin film of 0.8～1.2mm that material is pressed into thickness, standby；
(3) compound: put layer by A thin film, B thin film is sent in four-roll calender after stacking in the way of putting down layer, controls pressure roller temperature Degree at 90～110 DEG C, roller speed under the parameter of 80～90m/min, material is pressed into thickness be 0.6～0.9mm C thin Film；
(4) base fabric selects and pretreatment: described base fabric chooses non-woven fabrics, and described pretreatment mode refers to non-woven fabrics is placed on use The mixed liquor that thickening agent, styrene-butadiene latex, acrylic acid ester emulsion and water-dispersible epoxy resins form with 3:1:1:4 soaks 40～ 50min, then drains non-woven fabrics, is positioned in drying plant and dries 25～32min with the temperature of 75～85 DEG C；
(5) fit and emboss: with hydraulic press by after composite for base fabric, solidification after C thin film and described pretreatment, then delivering to vacuum Inhale and stricture of vagina machine make lines effect,.
The manufacture method of the PVC artificial leather of a kind of high resistance against wear the most according to claim 1, it is characterised in that step (1) The manufacture method of described abrasion-resistant powder is: glass, pottery, quartz, corundum and dark fund sand are mixed by the mass ratio of 3:7:2:6:1 After stir, put into concentration be 10% saline in soak 2～3 hours, after draining away the water, then with infrared ray with 120～ The temperature sterilizing 3 of 140 DEG C～5 hours, after stopping sterilizing, when temperature of charge is down to 40～60 DEG C, send material the most again The granule of 1600～17,000,000 mesh numbers it is ground into pulverizer.
The manufacture method of the PVC artificial leather of a kind of high resistance against wear the most according to claim 1, it is characterised in that step (1) Described antistatic additive is anionic antistatic agents.
The manufacture method of the PVC artificial leather of a kind of high resistance against wear the most according to claim 1, it is characterised in that step (1) Described ultraviolet-resistant absorbent is the ultraviolet-resistant absorbent of a kind of salicylic acid esters.
The manufacture method of the PVC artificial leather of a kind of high resistance against wear the most according to claim 1, it is characterised in that step (2) Described mof material contains tri-kinds of elements of Cu, Zn and Co.
The manufacture method of the PVC artificial leather of a kind of high resistance against wear the most according to claim 1, it is characterised in that step (4) Described thickening agent refers to polyvinyl alcohol, polyurethane, sodium dodecyl benzenylsulfonate, sodium carboxymethyl cellulose and nonyl phenolic group polyoxy Vinyl Ether is stirred by the mass ratio of 2:5:2:3:1 and mixes.
The manufacture method of the PVC artificial leather of a kind of high resistance against wear the most according to claim 1, it is characterised in that step (4) Described in the soaking temperature of pin non-woven fabrics be 40～50 DEG C.
The manufacture method of the PVC artificial leather of a kind of high resistance against wear the most according to claim 1, it is characterised in that step (4) Described in drying plant be a kind of revolving cylinder dehydrator.
CN201610786124.6A 2016-08-31 2016-08-31 A kind of manufacture method of the PVC artificial leather of high resistance against wear Pending CN106218164A (en)

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CN106436346A (en) * 2016-12-19 2017-02-22 福建宝利特科技股份有限公司 Uvioresistant artificial leather
CN106967258A (en) * 2017-02-24 2017-07-21 佛山市宏尔塑胶制品有限公司 A kind of environment-friendly PVC film and preparation method thereof
CN107724099A (en) * 2017-10-27 2018-02-23 佛山威明塑胶有限公司 A kind of antistatic PVC artificial leather and its production method
CN107747233A (en) * 2017-10-27 2018-03-02 佛山威明塑胶有限公司 A kind of PVC artificial leather of low smell and preparation method thereof
CN108016102A (en) * 2017-12-19 2018-05-11 雄进塑料制品（东莞）有限公司 A kind of automotive trim PVC synthetic leather
CN112080942A (en) * 2020-09-08 2020-12-15 清远市腾翔皮革有限公司 Anti-cracking leather and production method thereof
CN112322202A (en) * 2020-11-04 2021-02-05 江苏兴广包装科技有限公司 Preparation method of corrosion-resistant and friction-resistant holographic laser hot stamping film
CN114161780A (en) * 2021-12-15 2022-03-11 苏州市广得利橡塑有限公司 High-strength wear-resistant coated artificial leather and preparation method thereof

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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106436346A (en) * 2016-12-19 2017-02-22 福建宝利特科技股份有限公司 Uvioresistant artificial leather
CN106967258A (en) * 2017-02-24 2017-07-21 佛山市宏尔塑胶制品有限公司 A kind of environment-friendly PVC film and preparation method thereof
CN107724099A (en) * 2017-10-27 2018-02-23 佛山威明塑胶有限公司 A kind of antistatic PVC artificial leather and its production method
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CN108016102A (en) * 2017-12-19 2018-05-11 雄进塑料制品（东莞）有限公司 A kind of automotive trim PVC synthetic leather
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CN114161780A (en) * 2021-12-15 2022-03-11 苏州市广得利橡塑有限公司 High-strength wear-resistant coated artificial leather and preparation method thereof

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