CN114891410A - Pervious concrete high-weather-resistance protective agent and preparation method thereof - Google Patents
Pervious concrete high-weather-resistance protective agent and preparation method thereof Download PDFInfo
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D143/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and containing boron, silicon, phosphorus, selenium, tellurium, or a metal; Coating compositions based on derivatives of such polymers
- C09D143/04—Homopolymers or copolymers of monomers containing silicon
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/20—Diluents or solvents
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/45—Anti-settling agents
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/47—Levelling agents
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/61—Additives non-macromolecular inorganic
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/63—Additives non-macromolecular organic
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/65—Additives macromolecular
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/30—Sulfur-, selenium- or tellurium-containing compounds
- C08K2003/3045—Sulfates
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/08—Stabilised against heat, light or radiation or oxydation
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02A—TECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE
- Y02A30/00—Adapting or protecting infrastructure or their operation
- Y02A30/60—Planning or developing urban green infrastructure
Abstract
The invention discloses a pervious concrete high-weather-resistance protective agent and a preparation method thereof, wherein the pervious concrete high-weather-resistance protective agent is formed by mixing A, B components. The component A consists of fluorine-silicon modified acrylic resin, a diluent, a dispersing agent, a filler, a pigment, an auxiliary agent and an anti-ultraviolet agent. The component B is an isocyanate curing agent. According to the invention, the main resin is fluorine-silicon modified acrylic resin, fluorine-containing silicon groups are introduced into the side chain of the acrylic resin and are simultaneously introduced into the acrylic polymer, and the organosilicon polymer with double bonds and the fluorine monomer with double bonds are used as modified copolymer resin, so that the weather resistance of the modified copolymer resin is greatly improved, the weather resistance of the modified copolymer resin is improved, and the service life of the modified copolymer resin is prolonged. The component B is trimer aliphatic polyisocyanate curing agent, which has the greatest advantages that no active hydrogen atom exists on the molecular structure, no intramolecular or intermolecular hydrogen bond is formed, the viscosity of the product is lower, and the product has good corrosion resistance and yellowing resistance, and the comprehensive performance is enhanced.
Description
Technical Field
The invention relates to the field of building materials, in particular to a pervious concrete high-weather-resistance protective agent and a preparation method thereof.
Background
The urbanization process of china has advanced dramatically since the 21 st century. More and more urban ground surfaces adopt ecological and environment-friendly permeable pavements to solve the urban heat island effect, the permeable pavements are paved by permeable concrete,
the excellent characteristics of ventilation, water permeability, cooling, noise reduction and comfortable walking make the permeable concrete an indispensable auxiliary material in the garden landscape road. However, most of the existing water permeable paint protective agents are solvent type acrylic resins, and although the water permeable paint protective agents have good film-forming properties, the structural characteristics of the acrylic resins cause the weather resistance, water resistance and ultraviolet resistance to be unsatisfactory, and the light and color retention effects are poor, so that the problems of texture gliding, color loss and the like can occur after the water permeable paint protective agents are sprayed on the surface of concrete for a certain time, and the protective effect on the surface of the water permeable concrete can also be reduced, so that a water permeable concrete protective agent with stronger weather resistance is urgently needed to solve the problems.
Disclosure of Invention
The invention aims to solve the technical problem of providing a high-weather-resistant protective agent for pervious concrete, which not only has good film-forming property, but also has excellent weather resistance, water resistance and ultraviolet light resistance, has good light and color retention effects, and can prolong the protection time of the surface of the pervious concrete.
In order to achieve the purpose, the invention adopts the technical scheme that: a pervious concrete high-weatherability protective agent is prepared by mixing A, B components. The component A comprises fluorine-silicon modified acrylic resin, a diluent, a dispersing agent, a filler, a pigment, an auxiliary agent and an anti-ultraviolet agent. The component B is an isocyanate curing agent. The A, B component has the weight ratio of 5-7: 1.
furthermore, the component A comprises 55-75 wt% of fluorine-silicon modified acrylic resin, 8-20 wt% of diluent, 1-2 wt% of dispersant, 0.5-5 wt% of filler, 0.7-1.3 wt% of assistant, 0.5-5 wt% of anti-ultraviolet agent and 3-13 wt% of pigment.
Furthermore, the diluent is xylene, butyl acetate and propylene glycol monomethyl ether acetate, and the weight percentage of each component in the permeable concrete organic protective agent is 9.5-10.5% of xylene, 3.5-4.5% of butyl acetate and 3.5-4.5% of propylene glycol monomethyl ether acetate.
Furthermore, the auxiliary agent is an acrylate leveling agent and polyamide wax anti-settling wax slurry, and the weight percentage of each component of the auxiliary agent in the permeable concrete organic protective agent is 0.4-0.6% of the acrylate leveling agent and 0.4-0.6% of the polyamide wax anti-settling wax slurry.
Preferably, the filler is barium sulfate.
Preferably, the dispersing agent is a mixture of a high-molecular polycarboxylic acid solution and a polysiloxane solution.
Preferably, the anti-uv agent is bis (1,2,2,6, 6-pentamethyl-4-piperidinyl) sebacate.
Preferably, the component B is a trimer aliphatic polyisocyanate curing agent.
A preparation method of a pervious concrete high-weather-resistance protective agent comprises the following steps:
1) under the condition of stirring, sequentially adding a diluent xylene, butyl acetate and propylene glycol monomethyl ether acetate into a mixing kettle, stirring and mixing, and then sequentially adding a dispersing agent, an acrylate leveling agent and an anti-ultraviolet agent for mixing;
2) stirring and dispersing for 10-15 minutes at 800r/min for 600-;
3) according to the weight ratio of the component A to the component B, the component A and the component B are uniformly mixed under the stirring condition to obtain the pervious concrete high-weather-resistant protective agent.
Compared with the prior art, the invention has the following beneficial effects:
according to the invention, the fluorine-containing silicon group is introduced into the acrylic polymer through introducing the fluorine-containing silicon group into the side chain of the acrylic resin, and the organosilicon polymer with double bonds and the fluorine monomer with double bonds are used as modified copolymer resin, so that the water resistance, cold resistance, heat resistance and ultraviolet resistance of the acrylic resin are greatly improved, and the weather resistance and the service life of the acrylic resin are improved.
In the invention, the component B curing agent is trimer aliphatic polyisocyanate curing agent, and the aliphatic isocyanate has the greatest advantage over aromatic isocyanate that no active hydrogen atom exists on the structure of the synthesized aliphatic isocyanate trimer, and no intramolecular or intermolecular hydrogen bond is formed, so that the product has low viscosity, good corrosion resistance and yellowing resistance, and enhanced comprehensive performance.
In the invention, the dispersing agent is a mixture of a macromolecular polycarboxylic acid solution and a polysiloxane solution, is a controlled flocculation dispersing agent, has wide universality, improves wetting, has stronger floating color and floating color prevention capability on a multicolor system, and has excellent comprehensive performance.
In the invention, the ultraviolet resistant agent is bis (1,2,2,6, 6-pentamethyl-4-piperidyl) sebacate, and the ultraviolet resistant agent is used for the coating and can effectively prolong the service life of the coating and prevent cracks and loss of luster.
In the invention, the diluent is a mixture of xylene, butyl acetate and propylene glycol monomethyl ether acetate, and the mixture of the three components can meet various requirements of the paint, such as good solubility to non-volatile paint components, increased intersolubility among the paint components, moderate volatilization rate of the mixed diluent, stronger capability of reducing the viscosity of the paint, good leveling property of a paint film and avoidance of wrinkles in the drying process of the paint film.
The assistant is an acrylate leveling agent and a polyamide wax anti-settling wax slurry, wherein the acrylate leveling agent can improve the wettability of a base material, promote the leveling of a paint film, prevent shrinkage cavities and has a defoaming effect, and the polyamide wax anti-settling wax slurry is a slurry thixotropic agent consisting of modified polyamide wax, forms a strong network structure in the paint, has excellent thixotropic performance and good dispersibility, and provides excellent sagging prevention, settling prevention and thickening effects. And the barium sulfate filler plays a role in enhancing the hardness and plumpness of the paint film.
Detailed Description
The brand and model of the fluorosilicone modified acrylic resin in examples 1-3 was Dismann NEOCRYL B-851.
Example 1
A high-weather-resistant protective agent for pervious concrete is prepared by the following steps of: 1, wherein the component A comprises 67 percent of fluorine-silicon modified acrylic resin, 10.5 percent of dimethylbenzene, 4 percent of butyl acetate, 3.5 percent of propylene glycol methyl ether acetate, 1 percent of dispersant, 10 percent of pigment, 0.5 percent of acrylate leveling agent, 0.6 percent of polyamide wax anti-settling slurry, 1.9 percent of barium sulfate and 1 percent of ultraviolet resistant agent, wherein the dispersant is a mixture of a high molecular polycarboxylic acid solution and a polysiloxane solution, and the ultraviolet resistant agent is bis (1,2,2,6, 6-pentamethyl-4-piperidyl) sebacate. The component B is an aliphatic isocyanate curing agent.
The preparation method of the pervious concrete high-weather-resistance protective agent comprises the following steps:
1) at room temperature (the room temperature is 25 +/-10 ℃), sequentially adding a diluent xylene, butyl acetate and propylene glycol monomethyl ether acetate into a mixing kettle, stirring and mixing, and then sequentially adding a dispersing agent, an acrylate leveling agent and an anti-ultraviolet agent for mixing;
2) stirring and dispersing for 10-15 minutes at 800r/min for 600-;
3) and (3) under the stirring condition, uniformly mixing the component A and the component B to obtain the pervious concrete high-weather-resistance protective agent.
Example 2
A high weather-resistant protective agent for pervious concrete is prepared by the following steps: a, B double components are mixed according to the weight proportion of 1, wherein the component A comprises 59.3 percent of fluorine-silicon modified acrylic resin, 10.5 percent of dimethylbenzene, 4.5 percent of butyl acetate, 4.5 percent of propylene glycol methyl ether acetate, 2 percent of dispersant, 10 percent of pigment, 0.6 percent of acrylate leveling agent, 0.6 percent of polyamide wax anti-settling wax slurry, 3 percent of barium sulfate and 5 percent of ultraviolet resistant agent according to the weight proportion, wherein the dispersant is a mixture of a high molecular polycarboxylic acid solution and a polysiloxane solution, and the ultraviolet resistant agent is bis (1,2,2,6, 6-pentamethyl-4-piperidyl) sebacate. The component B is an aliphatic isocyanate curing agent.
The rest of the examples are as in example 1
Example 3
A high-weather-resistant protective agent for pervious concrete is prepared by the following steps: 1, wherein the component A comprises 75 percent of fluorine-silicon modified acrylic resin, 9.5 percent of dimethylbenzene, 3.5 percent of butyl acetate, 3.5 percent of propylene glycol methyl ether acetate, 1 percent of dispersant, 3 percent of pigment, 0.4 percent of acrylate leveling agent, 0.4 percent of polyamide wax anti-settling slurry, 1.6 percent of barium sulfate and 2.1 percent of ultraviolet resistant agent, wherein the dispersant is a mixture of a high molecular polycarboxylic acid solution and a polysiloxane solution, and the ultraviolet resistant agent is bis (1,2,2,6, 6-pentamethyl-4-piperidyl) sebacate. The component B is an aliphatic isocyanate curing agent.
The rest of the example was as in example 1.
Comparative example 1
The organic protecting agent for pervious concrete consists of solvent type acrylic resin 60 wt%, xylene 8 wt%, butyl acetate 3 wt%, propylene glycol methyl ether acetate 3 wt%, dispersant 1 wt%, pigment 8 wt%, acrylate leveling agent 0.5 wt%, polyamide wax deposition preventing slurry 1 wt%, organic bentonite 1.0 wt%, deposited barium sulfate 13 wt% and chlorinated paraffin 1.5 wt%.
The pervious concrete high weather-resistant protective agent obtained in example 1 was subjected to performance testing, and the results are shown in table 1:
TABLE 1
As can be seen from Table 1, the pervious concrete high-weatherability protective agent prepared by the embodiment has higher indexes than the ordinary acrylic acid protective agent, and has more excellent durability, water resistance and weather resistance.
The pervious concrete high-weatherability protective agent prepared in example 1 is sprayed on the surface of pervious concrete, and the sprayed surface is naturally exposed for 24 months, and through comparison experiments with the existing protective agent at home and abroad, the obtained results are shown in table 2:
TABLE 2
As can be seen from Table 2, the pervious concrete high-weatherability protective agent prepared by the embodiment has stronger weatherability in gloss and color, obviously enhanced ultraviolet resistance and superior gloss and color retention effects compared with similar samples.
The foregoing shows and describes the general principles and broad features of the present invention and advantages thereof. It will be understood by those skilled in the art that the present invention is not limited to the embodiments described above, which are described in the specification and illustrated only to illustrate the principle of the present invention, but that various changes and modifications may be made therein without departing from the spirit and scope of the present invention, which fall within the scope of the invention as claimed. The scope of the invention is to be construed by the appended claims and equivalents thereof.
Claims (9)
1. The high-weather-resistance protective agent for the pervious concrete is characterized in that: is prepared by mixing A, B components; the component A comprises fluorine-silicon modified acrylic resin, a diluent, a dispersing agent, barium sulfate, a pigment, an auxiliary agent and an anti-ultraviolet agent; the component B is an isocyanate curing agent; the A, B component has the weight ratio of 5-7: 1.
2. the pervious concrete high-weather-resistant protective agent as claimed in claim 1, wherein: the component A comprises 55-75 wt% of fluorine-silicon modified acrylic resin, 8-20 wt% of diluent, 1-2 wt% of dispersant, 0.5-5 wt% of barium sulfate, 0.7-1.3 wt% of assistant, 0.5-5 wt% of anti-ultraviolet agent and 3-13 wt% of pigment.
3. The pervious concrete high-weather-resistant protective agent as claimed in claim 2, characterized in that: the diluent is xylene, butyl acetate and propylene glycol methyl ether acetate, and the weight percentage of each component in the permeable concrete organic protective agent is 9.5-10.5% of xylene, 3.5-4.5% of butyl acetate and 3.5-4.5% of propylene glycol methyl ether acetate.
4. The pervious concrete high-weather-resistant protective agent as claimed in claim 2, characterized in that: the auxiliary agent is an acrylate leveling agent and polyamide wax anti-settling wax slurry, and the weight percentage of each component of the auxiliary agent in the permeable concrete organic protective agent is 0.4-0.6% of the acrylate leveling agent and 0.4-0.6% of the polyamide wax anti-settling wax slurry.
5. The pervious concrete high-weather-resistant protective agent as claimed in claim 2, characterized in that: the filler is barium sulfate.
6. The pervious concrete high-weather-resistant protective agent as claimed in claim 2, characterized in that: the dispersing agent is a mixture of a high-molecular polycarboxylic acid solution and a polysiloxane solution.
7. The pervious concrete high-weather-resistant protective agent as claimed in claim 2, characterized in that: the anti-ultraviolet agent is bis (1,2,2,6, 6-pentamethyl-4-piperidyl) sebacate.
8. The pervious concrete high-weather-resistant protective agent as claimed in claim 2, characterized in that: the component B is trimer aliphatic polyisocyanate curing agent.
9. The preparation method of the pervious concrete high-weather-resistance protective agent is characterized by comprising the following steps: the component A as claimed in claim 2, wherein the component A comprises the following components by weight percent, 1) under the stirring condition, sequentially adding the diluents xylene, butyl acetate and propylene glycol monomethyl ether acetate into a mixing kettle, stirring and mixing, and then sequentially adding the dispersing agent, the acrylate leveling agent and the anti-ultraviolet agent for mixing; 2) stirring and dispersing for 10-15 minutes at 800r/min for 600-; 3) according to the weight ratio of the component A to the component B, the component A and the component B are uniformly mixed under the stirring condition to obtain the pervious concrete high-weather-resistant protective agent.
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Citations (15)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2004137761A (en) * | 2002-10-17 | 2004-05-13 | Hachiya Kenzai Kogyo Kk | Surface treatment construction method of permeable concrete, and surface treated object of the permeable concrete |
| CN1772777A (en) * | 2005-11-16 | 2006-05-17 | 广州市化学工业研究所 | Fluorosilicone modified acrylic emulsion for weather resistant antifouling paint |
| CN101544868A (en) * | 2009-05-08 | 2009-09-30 | 厦门大学 | Fluoro-silicone self-cleaning paint and preparation method thereof |
| CN101613562A (en) * | 2009-07-21 | 2009-12-30 | 三棵树涂料股份有限公司 | A kind of anti-xanthochromia, zero triphen, zero TDI environment-friendly double-component polyurethane paint |
| CN101928498A (en) * | 2010-08-24 | 2010-12-29 | 中国电力科学研究院 | Fluorosilicone-modified acrylic resin hydrophobic anti-corrosion paint |
| CN102010651A (en) * | 2010-12-16 | 2011-04-13 | 广东美涂士建材股份有限公司 | Acid rain-resistant polyurethane outer wall paint |
| CN103214628A (en) * | 2013-05-10 | 2013-07-24 | 东南大学 | Modified acrylic resin for weather-resistant coating and preparation method for same |
| CN104673039A (en) * | 2015-02-04 | 2015-06-03 | 浙江天女集团制漆有限公司 | Organic-silicon organic-fluorine modified acrylic heavy anti-corrosion coating and preparation method thereof |
| CN105254235A (en) * | 2015-11-07 | 2016-01-20 | 盘锦斯比瑞涂装有限公司 | Colorful pervious concrete terrace material and manufacturing method thereof |
| CN106010186A (en) * | 2016-06-28 | 2016-10-12 | 上海砼仁环保技术发展有限公司 | Permeable concrete pavement protection agent and preparation method thereof |
| CN106928802A (en) * | 2017-03-15 | 2017-07-07 | 广东中星科技股份有限公司 | A kind of anticorrosive paint and its preparation based on fluorinated silicone modified acrylic resin |
| CN108178812A (en) * | 2017-12-30 | 2018-06-19 | 浙江工业大学 | A kind of fluorinated silicone modified acrylic resin and its preparation and application |
| CN109369862A (en) * | 2018-09-28 | 2019-02-22 | 合众（佛山）化工有限公司 | A kind of fluorine-silicon polyurethane modified acroleic acid water-base resin and preparation method thereof |
| CN111393071A (en) * | 2020-04-13 | 2020-07-10 | 上海砼仁环保技术发展有限公司 | Antiskid layer material composition for permeable pavement and preparation method thereof |
| CN114436566A (en) * | 2022-03-17 | 2022-05-06 | 广东悦谷道路材料有限公司 | Antiskid mat surface protective agent and preparation method thereof |
-
2022
- 2022-05-24 CN CN202210567910.2A patent/CN114891410A/en active Pending
Patent Citations (15)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2004137761A (en) * | 2002-10-17 | 2004-05-13 | Hachiya Kenzai Kogyo Kk | Surface treatment construction method of permeable concrete, and surface treated object of the permeable concrete |
| CN1772777A (en) * | 2005-11-16 | 2006-05-17 | 广州市化学工业研究所 | Fluorosilicone modified acrylic emulsion for weather resistant antifouling paint |
| CN101544868A (en) * | 2009-05-08 | 2009-09-30 | 厦门大学 | Fluoro-silicone self-cleaning paint and preparation method thereof |
| CN101613562A (en) * | 2009-07-21 | 2009-12-30 | 三棵树涂料股份有限公司 | A kind of anti-xanthochromia, zero triphen, zero TDI environment-friendly double-component polyurethane paint |
| CN101928498A (en) * | 2010-08-24 | 2010-12-29 | 中国电力科学研究院 | Fluorosilicone-modified acrylic resin hydrophobic anti-corrosion paint |
| CN102010651A (en) * | 2010-12-16 | 2011-04-13 | 广东美涂士建材股份有限公司 | Acid rain-resistant polyurethane outer wall paint |
| CN103214628A (en) * | 2013-05-10 | 2013-07-24 | 东南大学 | Modified acrylic resin for weather-resistant coating and preparation method for same |
| CN104673039A (en) * | 2015-02-04 | 2015-06-03 | 浙江天女集团制漆有限公司 | Organic-silicon organic-fluorine modified acrylic heavy anti-corrosion coating and preparation method thereof |
| CN105254235A (en) * | 2015-11-07 | 2016-01-20 | 盘锦斯比瑞涂装有限公司 | Colorful pervious concrete terrace material and manufacturing method thereof |
| CN106010186A (en) * | 2016-06-28 | 2016-10-12 | 上海砼仁环保技术发展有限公司 | Permeable concrete pavement protection agent and preparation method thereof |
| CN106928802A (en) * | 2017-03-15 | 2017-07-07 | 广东中星科技股份有限公司 | A kind of anticorrosive paint and its preparation based on fluorinated silicone modified acrylic resin |
| CN108178812A (en) * | 2017-12-30 | 2018-06-19 | 浙江工业大学 | A kind of fluorinated silicone modified acrylic resin and its preparation and application |
| CN109369862A (en) * | 2018-09-28 | 2019-02-22 | 合众（佛山）化工有限公司 | A kind of fluorine-silicon polyurethane modified acroleic acid water-base resin and preparation method thereof |
| CN111393071A (en) * | 2020-04-13 | 2020-07-10 | 上海砼仁环保技术发展有限公司 | Antiskid layer material composition for permeable pavement and preparation method thereof |
| CN114436566A (en) * | 2022-03-17 | 2022-05-06 | 广东悦谷道路材料有限公司 | Antiskid mat surface protective agent and preparation method thereof |
Non-Patent Citations (2)
| Title |
|---|
| 李永军等: "《表面处理技术 涂装技术基础》", 31 August 2020 * |
| 武德涛等: "水性涂料在混凝土防腐中的应用", 《上海涂料》 * |
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