CN114886153A - Water capsule for cigarettes and preparation method and application thereof - Google Patents
Water capsule for cigarettes and preparation method and application thereof Download PDFInfo
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- CN114886153A CN114886153A CN202210388790.XA CN202210388790A CN114886153A CN 114886153 A CN114886153 A CN 114886153A CN 202210388790 A CN202210388790 A CN 202210388790A CN 114886153 A CN114886153 A CN 114886153A
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- A—HUMAN NECESSITIES
- A24—TOBACCO; CIGARS; CIGARETTES; SIMULATED SMOKING DEVICES; SMOKERS' REQUISITES
- A24D—CIGARS; CIGARETTES; TOBACCO SMOKE FILTERS; MOUTHPIECES FOR CIGARS OR CIGARETTES; MANUFACTURE OF TOBACCO SMOKE FILTERS OR MOUTHPIECES
- A24D3/00—Tobacco smoke filters, e.g. filter-tips, filtering inserts; Filters specially adapted for simulated smoking devices; Mouthpieces for cigars or cigarettes
- A24D3/02—Manufacture of tobacco smoke filters
- A24D3/0204—Preliminary operations before the filter rod forming process, e.g. crimping, blooming
- A24D3/0212—Applying additives to filter materials
- A24D3/0216—Applying additives to filter materials the additive being in the form of capsules, beads or the like
-
- A—HUMAN NECESSITIES
- A24—TOBACCO; CIGARS; CIGARETTES; SIMULATED SMOKING DEVICES; SMOKERS' REQUISITES
- A24D—CIGARS; CIGARETTES; TOBACCO SMOKE FILTERS; MOUTHPIECES FOR CIGARS OR CIGARETTES; MANUFACTURE OF TOBACCO SMOKE FILTERS OR MOUTHPIECES
- A24D3/00—Tobacco smoke filters, e.g. filter-tips, filtering inserts; Filters specially adapted for simulated smoking devices; Mouthpieces for cigars or cigarettes
- A24D3/06—Use of materials for tobacco smoke filters
- A24D3/061—Use of materials for tobacco smoke filters containing additives entrapped within capsules, sponge-like material or the like, for further release upon smoking
-
- A—HUMAN NECESSITIES
- A24—TOBACCO; CIGARS; CIGARETTES; SIMULATED SMOKING DEVICES; SMOKERS' REQUISITES
- A24D—CIGARS; CIGARETTES; TOBACCO SMOKE FILTERS; MOUTHPIECES FOR CIGARS OR CIGARETTES; MANUFACTURE OF TOBACCO SMOKE FILTERS OR MOUTHPIECES
- A24D3/00—Tobacco smoke filters, e.g. filter-tips, filtering inserts; Filters specially adapted for simulated smoking devices; Mouthpieces for cigars or cigarettes
- A24D3/06—Use of materials for tobacco smoke filters
- A24D3/08—Use of materials for tobacco smoke filters of organic materials as carrier or major constituent
- A24D3/10—Use of materials for tobacco smoke filters of organic materials as carrier or major constituent of cellulose or cellulose derivatives
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K36/00—Medicinal preparations of undetermined constitution containing material from algae, lichens, fungi or plants, or derivatives thereof, e.g. traditional herbal medicines
- A61K36/18—Magnoliophyta (angiosperms)
- A61K36/185—Magnoliopsida (dicotyledons)
- A61K36/28—Asteraceae or Compositae (Aster or Sunflower family), e.g. chamomile, feverfew, yarrow or echinacea
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K36/00—Medicinal preparations of undetermined constitution containing material from algae, lichens, fungi or plants, or derivatives thereof, e.g. traditional herbal medicines
- A61K36/18—Magnoliophyta (angiosperms)
- A61K36/185—Magnoliopsida (dicotyledons)
- A61K36/61—Myrtaceae (Myrtle family), e.g. teatree or eucalyptus
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K36/00—Medicinal preparations of undetermined constitution containing material from algae, lichens, fungi or plants, or derivatives thereof, e.g. traditional herbal medicines
- A61K36/18—Magnoliophyta (angiosperms)
- A61K36/185—Magnoliopsida (dicotyledons)
- A61K36/63—Oleaceae (Olive family), e.g. jasmine, lilac or ash tree
- A61K36/634—Forsythia
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K36/00—Medicinal preparations of undetermined constitution containing material from algae, lichens, fungi or plants, or derivatives thereof, e.g. traditional herbal medicines
- A61K36/18—Magnoliophyta (angiosperms)
- A61K36/185—Magnoliopsida (dicotyledons)
- A61K36/73—Rosaceae (Rose family), e.g. strawberry, chokeberry, blackberry, pear or firethorn
- A61K36/734—Crataegus (hawthorn)
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K36/00—Medicinal preparations of undetermined constitution containing material from algae, lichens, fungi or plants, or derivatives thereof, e.g. traditional herbal medicines
- A61K36/18—Magnoliophyta (angiosperms)
- A61K36/88—Liliopsida (monocotyledons)
- A61K36/888—Araceae (Arum family), e.g. caladium, calla lily or skunk cabbage
- A61K36/8888—Pinellia
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K36/00—Medicinal preparations of undetermined constitution containing material from algae, lichens, fungi or plants, or derivatives thereof, e.g. traditional herbal medicines
- A61K36/18—Magnoliophyta (angiosperms)
- A61K36/88—Liliopsida (monocotyledons)
- A61K36/896—Liliaceae (Lily family), e.g. daylily, plantain lily, Hyacinth or narcissus
- A61K36/8967—Lilium, e.g. tiger lily or Easter lily
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K36/00—Medicinal preparations of undetermined constitution containing material from algae, lichens, fungi or plants, or derivatives thereof, e.g. traditional herbal medicines
- A61K36/18—Magnoliophyta (angiosperms)
- A61K36/88—Liliopsida (monocotyledons)
- A61K36/898—Orchidaceae (Orchid family)
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61P—SPECIFIC THERAPEUTIC ACTIVITY OF CHEMICAL COMPOUNDS OR MEDICINAL PREPARATIONS
- A61P11/00—Drugs for disorders of the respiratory system
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61P—SPECIFIC THERAPEUTIC ACTIVITY OF CHEMICAL COMPOUNDS OR MEDICINAL PREPARATIONS
- A61P25/00—Drugs for disorders of the nervous system
- A61P25/20—Hypnotics; Sedatives
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02A—TECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE
- Y02A50/00—TECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE in human health protection, e.g. against extreme weather
- Y02A50/30—Against vector-borne diseases, e.g. mosquito-borne, fly-borne, tick-borne or waterborne diseases whose impact is exacerbated by climate change
Abstract
The invention provides a water capsule for cigarettes and a preparation method and application thereof, wherein the water capsule for cigarettes comprises a core liquid and a wall material, wherein the core liquid is a water-in-oil emulsion; the wall material comprises wax, cellulose and vegetable gum. The water capsule for the cigarettes provided by the invention releases water after being pinched and broken, can increase the humidity of smoke, soften the smoke, reduce the irritation and reduce the release of harmful components in the smoke; and has proper crushing strength and simple production process.
Description
Technical Field
The invention belongs to the technical field of cigarettes, and particularly relates to a water capsule for cigarettes as well as a preparation method and application thereof.
Background
In the traditional cigarette flavoring technology, the flavoring liquid is mainly added into tobacco shreds, the added flavoring liquid is partially lost in the cigarette combustion process, and meanwhile, as the reaction of a complex material system at high temperature is difficult to expect, part of the flavoring liquid can generate some undesirable sensory effects.
As a novel cigarette flavoring mode, the bead blasting flavoring can overcome the defects of the existing flavoring mode to a certain extent, and the main reasons are as follows: the exploded beads contain spices, before smoking cigarettes, consumers preferably crush the exploded beads contained in the filter rods and then smoke the cigarettes, and smoke gas passes through the filter tips and acts on the consumers together with the exploded bead feed liquid, so that the flavoring and fragrance supplementing process is completed; the mode can effectively avoid the loss of the spice liquid in the combustion process of the tobacco on one hand, and on the other hand, the spice is arranged in the sealed exploding bead, so that the loss can not occur during the storage of the cigarette, and the stability of the quality of the cigarette is ensured.
CN104305521A discloses a water bag with water and hydrophilic substances as core materials, and a preparation method thereof. The water bag is prepared by adopting a long-chain ester material and a coagulant aid as wall materials through a sharp hole-coagulation bath method, the preparation process is greatly influenced by the viscosity of the wall materials, the adding rate of the water bag in cigarettes is only 73-86%, and the subsequent processing of cigarette filter sticks is not facilitated.
CN105559139A discloses a hollow alginate capsule production system for tobacco, which adopts CaCl containing essential oil 2 The emulsion is dripped into the sodium alginate solution to generate bead blasting, the capsule for the cigarette prepared by the invention gradually consumes the sodium alginate in the forming solution, the pressure born by the finished capsule produced subsequently is gradually reduced, and the quality stability of the capsule for the cigarette is required to be improved.
Therefore, how to provide the water capsule for the cigarettes, which can have proper crushing resistance pressure and soft smoke, and the preparation method is simple, becomes a problem to be solved at present.
Disclosure of Invention
Aiming at the defects of the prior art, the invention aims to provide a water capsule for cigarettes and a preparation method and application thereof. The water capsule for the cigarettes provided by the invention has proper crushing pressure resistance and soft fragrance, and the preparation method is simple.
In order to achieve the purpose, the invention adopts the following technical scheme:
in a first aspect, the invention provides a water capsule for tobacco, which comprises a core liquid and a wall material, wherein the core liquid is a water-in-oil emulsion; the wall material comprises wax, cellulose and vegetable gum.
In the invention, the mass ratio of the core liquid to the wall material in the water capsule for cigarettes is (0.5-10) to 1;
wherein "0.5-10" may be 0.5, 1, 1.5, 2, 2.5, 3, 3.5, 4, 4.5, 5, 5.5, 6, 6.5, 7, 7.5, 8, 8.5, 9, 9.5, 10, etc.
Preferably, the raw materials for preparing the water-in-oil emulsion comprise a water phase and an oil phase.
Preferably, the mass ratio of the water phase to the oil phase is (0.2-5) to 1;
wherein "0.2 to 5" may be 0.2, 0.5, 1, 1.5, 2, 2.5, 3, 3.5, 4, 4.5, 5, etc.
In the invention, the raw materials for preparing the water phase comprise a traditional Chinese medicine extraction concentrated solution and water.
Preferably, the aqueous phase comprises 10-60% of the Chinese medicinal extract concentrate by mass, such as 10%, 15%, 20%, 25%, 30%, 35%, 40%, 45%, 50%, 55%, 60%, etc.
Preferably, the Chinese medicinal extract concentrated solution comprises Chinese medicinal alcohol extract concentrated solution and/or Chinese medicinal water extract concentrated solution.
In the invention, the preparation method of the traditional Chinese medicine extraction concentrated solution comprises the following steps:
(1) grinding the Chinese medicinal materials, and sieving with 40-50 mesh sieve (such as 40 mesh, 41 mesh, 42 mesh, 43 mesh, 44 mesh, 45 mesh, 46 mesh, 47 mesh, 48 mesh, 49 mesh, 50 mesh, etc.) to obtain Chinese medicinal powder;
(2) adding the extractive solution into the Chinese medicinal powder obtained in step (1), and soaking for 1-5 hr (such as 1 hr, 2 hr, 3 hr, 4 hr, 5 hr, etc.) at 40-80 deg.C (such as 40 deg.C, 50 deg.C, 60 deg.C, 70 deg.C, 80 deg.C, etc.) to obtain Chinese medicinal extractive solution;
wherein the extraction solution comprises 65-85% (e.g. 65%, 70%, 75%, 80%, 85%, etc.) volume fraction of an aqueous alcohol solution (wherein the alcohol may be ethanol) or water; the mass ratio of the extraction solvent to the Chinese medicinal composition is (1-10):1 (for example, 1:1, 2:1, 3:1, 4:1, 5:1, 6:1, 7:1, 8:1, 9:1, 10:1, etc.);
(3) and (3) concentrating the traditional Chinese medicine extract obtained in the step (2) under reduced pressure until the volume is unchanged to obtain the traditional Chinese medicine extract concentrated solution.
When the extraction solution is an alcohol-water solution, obtaining the traditional Chinese medicine alcohol extraction concentrated solution; when the extraction solution is water, the Chinese medicinal water extraction concentrated solution is obtained.
Preferably, the Chinese medicinal concentrated extract comprises one or a combination of at least two of clove extract concentrated solution, lily extract concentrated solution, hawthorn extract concentrated solution, eupatorium extract concentrated solution, pinellia ternate extract, forsythia suspensa extract and rhododendron extract.
Preferably, the traditional Chinese medicine extraction concentrated solution comprises a clove extraction concentrated solution, a lily extraction concentrated solution, a hawthorn extraction concentrated solution, a eupatorium extraction concentrated solution, a pinellia ternate extracting solution, a fructus forsythiae extracting solution and a rhododendron extracting solution according to the mass ratio of (2-20): (3-20): 4-15): (2-6): 1-10 (1-10);
in (2-20), (3-20), (4-15), (2-6), (1-10) and (1-10);
"2-20" can be 2, 4, 6, 8, 10, 12, 14, 16, 18, 20, etc.;
"3-20" can be 3, 5, 7, 8, 10, 12, 14, 16, 18, 20, etc.;
"4-15" can be 4, 6, 8, 10, 12, 14, 15, etc.;
"2-6" can be 2, 3, 4, 5, 6, etc.;
"1-10" can be 1, 3, 5, 7, 9, 10, etc.
In the invention, the clove extraction concentrated solution, the lily extraction concentrated solution, the hawthorn extraction concentrated solution, the eupatorium extraction concentrated solution, the pinellia ternate extract, the forsythia suspensa extract and the rhododendron extract are matched with each other, have synergistic interaction, can absorb harmful gases in neutralized smoke, release fragrance, improve and enrich cigarette fragrance, remarkably improve the fragrance richness, sensory quality and suction interest of cigarettes, and have certain efficacies of nourishing yin and moistening lung, clearing away the heart fire and soothing the nerves, reducing cigarette harm and the like.
In the invention, the raw material for preparing the water phase also comprises a preservative.
Preferably, the preservative comprises one or a combination of at least two of potassium sorbate, sodium benzoate, ethyl paraben, or propyl paraben.
Preferably, the raw material for preparing the aqueous phase comprises 0.01-0.5% of preservative by mass percentage, such as 0.01%, 0.05%, 0.1%, 0.15%, 0.2%, 0.25%, 0.3%, 0.35%, 0.4%, 0.45%, 0.5% and the like.
Preferably, the raw materials for preparing the aqueous phase also comprise a cosolvent.
Preferably, the co-solvent comprises any one of ethanol, propylene glycol or glycerol or a combination of at least two thereof.
Preferably, the mass ratio of the water to the cosolvent is (10-130) to 1;
wherein "10-130" may be 10, 30, 50, 70, 90, 110, 130, etc.
In the invention, the preparation raw materials of the oil phase comprise a water-in-oil emulsifier, oil phase essence and vegetable oil.
Preferably, the mass ratio of the water-in-oil emulsifier to the oil-phase essence to the vegetable oil is (1-10) to (5-20) to (30-90);
wherein "1-10" can be 1, 2, 3, 4, 5, 6, 7, 8, 9, 10, etc.;
"5-20" can be 5, 7, 9, 11, 13, 15, 17, 19, 20, etc.;
"30-90" can be 30, 40, 50, 60, 70, 80, 90, etc.
Preferably, the water-in-oil emulsifier comprises any one of or a combination of at least two of polyglyceryl fatty acid ester, diglyceryl monolaurate, sorbitol monolaurate, nonylphenoxy polyethoxyethanol, span 80, or PEG-10 polydimethylsiloxane.
Preferably, the oil phase essence comprises lemon essential oil, mint essential oil and orange peel oil.
According to the invention, the lemon essential oil, the mint essential oil and the orange peel oil are mutually matched, so that the synergistic effect is realized, the cigarette aroma is improved and enriched, and the aroma richness, the sensory quality and the smoking interestingness of the cigarette are remarkably improved; and can inhibit the release of harmful gases in the flue gas.
Preferably, the mass ratio of the lemon essential oil to the mint essential oil to the orange peel oil is (1-5) (1-5): 1;
wherein "1-5" can be 1, 2, 3, 4, 5, etc.
Preferably, the vegetable oil comprises any one of olive oil, soybean oil, corn oil or rapeseed oil or a combination of at least two thereof.
In the invention, the mass ratio of the wax, the cellulose and the vegetable gum is (1-5) to (1-3) to (1-10);
wherein "1-5" can be 1, 2, 3, 4, 5, etc.;
"1-3" can be 1, 1.5, 2, 2.5, 3, etc.;
"1-10" can be 1, 2, 3, 4, 5, 6, 7, 8, 9, 10, etc.
In the invention, the wax, the cellulose and the vegetable gum in the wall material are mutually matched, so that the water capsule has proper crushing pressure and is only suitable for processing, and the water capsule can be well crushed by a consumer to release the wrapped contents.
Preferably, the wax comprises any one of carnauba wax, candelilla wax, rice bran wax, sugar cane wax, bay wax, castor bean wax, jojoba wax, ouricury wax or douglas fir wax or a combination of at least two thereof.
Preferably, the cellulose comprises synthetic cellulose.
Preferably, the synthetic cellulose comprises any one of carboxyethyl cellulose, carboxypropyl methyl cellulose, carboxymethyl cellulose or ethylcarboxyethyl cellulose or a combination of at least two thereof.
Preferably, the vegetable gum comprises any one of or a combination of at least two of sesbania gum, guar gum, flax gum, fenugreek gum, arabinogelatin, tamarind polysaccharide gum or locust bean gum, preferably a combination of sesbania gum and arabinogelatin.
In the present invention, the vegetable gum is preferably a combination of sesbania gum and arabinogelatin, which cooperate with each other to block the release of smoke.
Preferably, the mass ratio of the sesbania gum to the arabinogelatin is (1-5): 1;
wherein "1 to 5" may be 1, 2, 3, 4, 5, etc.
In a second aspect, the invention provides a preparation method of the water capsule for tobacco according to the first aspect, which comprises the following steps:
and respectively placing the core liquid and the wall material in an inner core channel and an outer wall channel of the coaxial double-layer dripper, dripping the core liquid and the wall material into the protective liquid through the coaxial double-layer dripper, and separating and washing the core liquid and the wall material through a screen to obtain the water capsule for the cigarettes.
Preferably, the temperature of the coaxial double-layer dripper is 50 to 150 ℃, and may be, for example, 50 ℃, 60 ℃, 70 ℃, 80 ℃, 90 ℃, 100 ℃, 110 ℃, 120 ℃, 130 ℃, 140 ℃, 150 ℃ or the like.
Preferably, the temperature of the protective solution is 5 to 30 ℃, for example, 5 ℃, 10 ℃, 15 ℃, 20 ℃, 25 ℃, 30 ℃ and the like.
In the present invention, the protective solution comprises an aqueous ethanol solution and/or paraffin oil;
preferably, the volume percentage of ethanol in the ethanol aqueous solution is 90-98% (e.g., can be 90%, 91%, 92%, 93%, 94%, 95%, 96%, 97%, 98%, etc.);
preferably, the preparation method of the bore fluid comprises the following steps:
(a) mixing water and the concentrated solution of Chinese medicinal extract to obtain water phase; mixing the water-in-oil type emulsifier, the oil phase essence and the vegetable oil to obtain an oil phase;
(b) mixing the water phase and the oil phase obtained in the step (a), and homogenizing to obtain the core liquid.
Preferably, in step (a), the temperature for mixing the obtained aqueous phase is 2-30 ℃ (for example, 2 ℃, 4 ℃, 6 ℃, 8 ℃, 10 ℃, 12 ℃, 14 ℃, 16 ℃, 18 ℃, 20 ℃, 22 ℃, 24 ℃, 26 ℃, 28 ℃, 30 ℃ and the like can be used); the temperature of the oil phase is 50-150 deg.C (such as 50 deg.C, 60 deg.C, 70 deg.C, 80 deg.C, 90 deg.C, 100 deg.C, 110 deg.C, 120 deg.C, 130 deg.C, 140 deg.C, 150 deg.C).
Preferably, in step (a), the resulting aqueous phase mixture further comprises a preservative and/or a cosolvent.
Preferably, in step (b), the rotation speed of the homogenizing is 4000-6000rpm (for example, 4000rpm, 4300rpm, 4600rpm, 4900rpm, 5100rpm, 5400rpm, 5700rpm, 6000rpm and the like), and the time is 5-20min (for example, 5min, 7min, 9min, 11min, 13min, 15min, 17min, 19min, 20min and the like).
Preferably, the preparation method of the wall material comprises the following steps: and mixing and melting the wax, the cellulose and the vegetable gum to obtain the wall material.
Preferably, the temperature of the mixing and melting is 50-150 ℃ (for example, 50 ℃, 60 ℃, 70 ℃, 80 ℃, 90 ℃, 100 ℃, 110 ℃, 120 ℃, 130 ℃, 140 ℃, 150 ℃ and the like can be used).
As a preferable technical scheme, the preparation method of the water capsule for the cigarettes comprises the following steps:
(1) preparing core liquid:
(a) mixing water, Chinese medicinal extract concentrated solution, optional antiseptic and optional cosolvent at 2-30 deg.C to obtain water phase; mixing water-in-oil emulsifier, oil phase essence and vegetable oil at 50-150 deg.C to obtain oil phase;
(b) homogenizing the water phase and the oil phase obtained in the step (a) for 5-20min at the rotating speed of 4000-6000rpm to obtain core liquid;
(2) preparing wall materials: mixing and melting wax, cellulose and vegetable gum at 50-150 ℃ to obtain the wall material;
(3) preparing a water capsule for cigarettes: and respectively placing the core liquid and the wall material in an inner core channel and an outer wall channel of a coaxial double-layer dripper at the temperature of 50-150 ℃, dripping the core liquid and the wall material into a protective liquid at the temperature of 5-30 ℃ through the coaxial double-layer dripper, and separating and washing the core liquid and the wall material by using a screen to obtain the water capsule for the cigarettes.
In a third aspect, the invention provides the application of the water capsule for the cigarette according to the first aspect in preparing cigarette tobacco shreds, cigarette paper or filters.
Compared with the prior art, the invention has the following beneficial effects:
(1) the water capsule for the cigarettes provided by the invention releases water after being pinched and broken, can increase the humidity of smoke, soften the smoke, reduce the irritation and reduce the release of harmful components in the smoke; the cigarette aroma is improved and enriched, the aroma richness, the sensory quality and the smoking interestingness of the cigarette are remarkably improved, and the cigarette has the effects of nourishing yin, moistening the lung, clearing away the heart fire, soothing the nerves, reducing the harm of the cigarette and the like;
(2) the water capsule for the cigarette has proper crushing strength, so that the blasting beads have good processing resistance, the water in the capsule can be prevented from overflowing when the capsule is not used, and the storage and use period of the capsule is guaranteed;
(3) the water capsule for the cigarettes provided by the invention is simple in production process and good in quality stability, and can also meet the production requirements.
Detailed Description
The technical solution of the present invention is further explained by the following embodiments. It should be understood by those skilled in the art that the examples are only for the understanding of the present invention and should not be construed as the specific limitations of the present invention.
The temperatures stated in the examples below are the temperatures of the reaction medium.
The traditional Chinese medicine extract concentrated solutions related in the following examples are prepared by adopting the following method:
(1) grinding the traditional Chinese medicine, and sieving with a 45-mesh sieve to obtain traditional Chinese medicine powder;
(2) adding the extraction solution into the Chinese medicinal powder obtained in the step (1), and soaking at 60 ℃ for 3h to obtain a Chinese medicinal extract;
wherein the extraction solution comprises 70% by volume of an aqueous ethanol solution; the mass ratio of the extraction solvent to the traditional Chinese medicine composition is 5: 1;
(3) and (3) carrying out reduced pressure concentration on the traditional Chinese medicine extracting solution obtained in the step (2) until the volume is unchanged, so as to obtain the traditional Chinese medicine extracting concentrated solution.
Example 1
The embodiment provides a water capsule for cigarettes, which comprises the following raw materials in parts by weight:
the preparation method of the water capsule for the cigarettes comprises the following steps:
(1) preparing core liquid:
(a) mixing water, concentrated Chinese medicinal extract, antiseptic and cosolvent at 25 deg.C to obtain water phase; mixing water-in-oil emulsifier, oil phase essence and vegetable oil at 110 deg.C to obtain oil phase;
(b) homogenizing the water phase and the oil phase obtained in the step (a) at the rotating speed of 5000rpm for 15min to obtain core liquid;
(2) preparing wall materials: mixing and melting wax, cellulose and vegetable gum at 110 ℃ to obtain the wall material;
(3) preparing a water capsule for cigarettes: and respectively placing the core liquid and the wall material in an inner core channel and an outer wall channel of a coaxial double-layer dripper at the temperature of 110 ℃, dripping the core liquid and the wall material into a protective liquid at the temperature of 12 ℃ through the coaxial double-layer dripper, and separating and washing the core liquid and the wall material by using a screen to obtain the water capsule for the cigarettes.
Example 2
The embodiment provides a water capsule for cigarettes, which comprises the following raw materials in parts by weight:
the preparation method of the water capsule for the cigarette comprises the following steps:
(1) preparing core liquid:
(a) mixing water, concentrated Chinese medicinal extract, antiseptic and cosolvent at 26 deg.C to obtain water phase; mixing water-in-oil emulsifier, oil phase essence and vegetable oil at 105 deg.C to obtain oil phase;
(b) homogenizing the water phase and the oil phase obtained in the step (a) for 17min at the rotating speed of 4900rpm to obtain core liquid;
(2) preparing wall materials: mixing and melting wax, cellulose and vegetable gum at 105 ℃ to obtain the wall material;
(3) preparing a water capsule for cigarettes: and respectively placing the core liquid and the wall material in an inner core channel and an outer wall channel of a coaxial double-layer dripper at 105 ℃, dripping the core liquid and the wall material into a protective liquid at 11 ℃ through the coaxial double-layer dripper, and separating and washing the core liquid and the wall material by using a screen to obtain the water capsule for the cigarettes.
Example 3
The embodiment provides a water capsule for cigarettes, which comprises the following raw materials in parts by weight:
the preparation method of the water capsule for the cigarettes comprises the following steps:
(1) preparing core liquid:
(a) mixing water, concentrated Chinese medicinal extract, antiseptic and cosolvent at 27 deg.C to obtain water phase; mixing water-in-oil type emulsifier, oil phase essence and vegetable oil at 100 ℃ to obtain an oil phase;
(b) homogenizing the water phase and the oil phase obtained in the step (a) for 14min at the rotating speed of 5100rpm to obtain core liquid;
(2) preparing wall materials: mixing and melting wax, cellulose and vegetable gum at 100 ℃ to obtain the wall material;
(3) preparing a water capsule for cigarettes: and respectively placing the core liquid and the wall material in an inner core channel and an outer wall channel of a coaxial double-layer dripper at 100 ℃, dripping the core liquid and the wall material into a protective liquid at 13 ℃ through the coaxial double-layer dripper, and separating and washing the core liquid and the wall material by using a screen to obtain the water capsule for the cigarettes.
Examples 4 to 10
Embodiments 4 to 10 provide a water capsule for cigarettes, which is different from embodiment 1 only in that any one of a clove water extraction concentrated solution, a lily water extraction concentrated solution, a hawthorn water extraction concentrated solution, a eupatorium water extraction concentrated solution, a pinellia ternate water extraction concentrated solution, a forsythia water extraction concentrated solution, or a rhododendron water extraction concentrated solution is respectively absent from a traditional Chinese medicine extraction concentrated solution, and the total weight parts of the traditional Chinese medicine extraction concentrated solution and the weight ratios of other components in the traditional Chinese medicine extraction concentrated solution are kept unchanged.
Examples 11 to 13
Examples 11-13 each provide a water capsule for cigarettes, differing from example 1 only in that the oil phase essence lacks any one of lemon essential oil, peppermint essential oil or orange peel oil, respectively, and the total weight parts of the oil phase essence remains unchanged, and the weight ratio of the other components in the oil phase essence remains unchanged.
Examples 14 to 15
Examples 14-15 each provide a water capsule for tobacco, differing from example 1 only in that the vegetable gum lacks sesbania gum or arabinogelatin, respectively, and the total weight fraction of the vegetable gum remains unchanged.
Example 16
Example 16 provides a water capsule for cigarettes, which is different from example 1 only in that the vegetable gum is 30 parts by weight of guar gum, and other preparation raw materials and preparation methods are the same as those of example 1.
Comparative examples 1 to 3
Comparative examples 1 to 3 each provide a water capsule for cigarettes, which is different from example 1 only in that the wall material lacks any one of wax (carnauba wax), cellulose (sodium carboxymethyl cellulose), and vegetable gum (sesbania gum and arabinogelatin), respectively, and the total weight part of the wall material is kept constant and the weight ratio of the other components in the wall material is kept constant.
Comparative example 4
This comparative example provides a water capsule for tobacco, which does not contain a water-in-oil emulsifier (span 80) in the raw materials for preparation, as compared with example 1, and the other raw materials for preparation are the same as in example 1.
The preparation method of the water capsule for the cigarettes comprises the following steps:
(1) mixing water, concentrated Chinese medicinal extract, antiseptic and cosolvent at 25 deg.C to obtain water phase; mixing the oil-phase essence and the vegetable oil at 110 ℃ to obtain an oil phase;
(2) preparing wall materials: mixing and melting wax, cellulose and vegetable gum at 110 ℃ to obtain the wall material;
(3) preparing a water capsule for cigarettes: and respectively placing the water phase, the oil phase and the wall material in an inner core channel, a middle channel and an outer wall channel of a coaxial three-layer dripper at the temperature of 110 ℃, dripping the water phase, the oil phase and the wall material into a protective solution at the temperature of 12 ℃ through the coaxial three-layer dripper, and obtaining the water capsule for the cigarette through screen separation and washing.
Comparative example 5
The comparative example provides a water capsule for tobacco, compared with example 1, the raw materials for preparing the water capsule for tobacco do not contain oil phase, and other raw materials for preparing the water capsule for tobacco are the same as those in example 1.
The preparation method of the water capsule for the cigarette comprises the following steps:
(1) mixing water, concentrated Chinese medicinal extract, antiseptic and cosolvent at 25 deg.C to obtain water phase;
(2) preparing wall materials: mixing and melting wax, cellulose and vegetable gum at 110 ℃ to obtain the wall material;
(3) preparing a water capsule for cigarettes: and respectively placing the water phase and the wall material in an inner core channel and an outer wall channel of a coaxial double-layer dripper at the temperature of 110 ℃, dripping the water phase and the wall material into a protective solution at the temperature of 12 ℃ through the coaxial double-layer dripper, and separating and washing the water phase and the wall material by using a screen to obtain the water capsule for the cigarettes.
Comparative example 6
This comparative example provides a water capsule for tobacco, which contains no aqueous phase in the raw materials for preparation compared with example 1, and the other raw materials for preparation are the same as those in example 1.
The preparation method of the water capsule for the cigarette comprises the following steps:
(1) mixing water-in-oil emulsifier, oil phase essence and vegetable oil at 110 deg.C to obtain oil phase;
(2) preparing wall materials: mixing and melting wax, cellulose and vegetable gum at 110 ℃ to obtain the wall material;
(3) preparing a water capsule for cigarettes: and respectively placing the oil phase and the wall material in an inner core channel and an outer wall channel of a coaxial double-layer dripper at the temperature of 110 ℃, dripping the oil phase and the wall material into a protective solution at the temperature of 12 ℃ through the coaxial double-layer dripper, and separating and washing the water capsule for the cigarettes by using a screen.
Test example 1
Physical property evaluation of water capsule for cigarette
Testing a sample: water capsule for cigarette provided in examples 1 to 16 and comparative examples 1 to 6
The test method comprises the following steps:
(1) weighing 20 water capsules for cigarettes by a weighing method, and taking an average value;
(2) measuring the diameter of the water capsule for the cigarette by a vernier caliper, measuring 20 particles, and taking an average value;
(3) the crushing strength of the water capsule for the cigarette is measured by self-made equipment, the core of the equipment comprises an electronic balance connected with a pressure recorder and a pushing rod linked above the electronic balance, the pushing rod extrudes the popping beads arranged on a balance platform at a constant speed during measurement, and the crushing strength of the popping beads can be measured by recording the pressure change trend and the acting force of the popping beads at the moment through the recorder; measuring at least 10 particles, and taking an average value;
the test results are shown in table 1:
TABLE 1
| Sample (I) | Weight (mg) | Diameter (mm) | Crushing strength (N) |
| Example 1 | 22.91 | 3.65 | 10.82 |
| Example 2 | 22.87 | 3.66 | 10.73 |
| Example 3 | 22.89 | 3.64 | 10.61 |
| Example 4 | 23.12 | 3.61 | 10.51 |
| Example 5 | 23.05 | 3.58 | 10.32 |
| Example 6 | 22.94 | 3.59 | 10.24 |
| Example 7 | 22.97 | 3.55 | 10.52 |
| Example 8 | 22.89 | 3.61 | 10.67 |
| Example 9 | 23.14 | 3.62 | 10.74 |
| Example 10 | 23.09 | 3.62 | 10.55 |
| Example 11 | 22.98 | 3.58 | 10.63 |
| Example 12 | 22.21 | 3.61 | 10.61 |
| Example 13 | 23.12 | 3.59 | 10.57 |
| Example 14 | 23.00 | 3.62 | 8.21 |
| Example 15 | 23.05 | 3.55 | 8.05 |
| Example 16 | 22.87 | 3.59 | 7.55 |
| Comparative example 1 | 22.95 | 3.58 | 5.55 |
| Comparative example 2 | 23.15 | 3.57 | 5.42 |
| Comparative example 3 | 22.96 | 3.52 | 5.24 |
| Comparative example 4 | 23.04 | 3.70 | 7.14 |
| Comparative example 5 | 22.96 | 3.67 | 6.04 |
| Comparative example 6 | 23.08 | 3.61 | 6.05 |
As can be seen from the data in Table 1, the cigarette blasting beads provided by the invention (examples 1-16) have the mass of 22.21-23.14mg, the diameter of 3.55-3.66mm and the crushing strength of 7.55-10.82N. The 20N bead blasting for cigarettes provided by the invention is suitable in crushing strength, is suitable for processing, and can be well broken by consumers to release wrapped contents.
As can be seen from the comparison between example 1 and examples 14 to 16, when the vegetable gum is not in the preferred range of the present invention, the crushing strength of the water capsule for tobacco is affected and the water capsule is easily broken during the processing.
As can be seen from the comparison between example 1 and comparative examples 1 to 3, the absence of any of wax, cellulose and vegetable gum in the wall material affects the crushing strength of the water capsule for cigarettes.
As can be seen from the comparison between example 1 and comparative example 4, the processing technology of the water capsule for tobacco can affect the crushing strength of the water capsule for tobacco.
As can be seen from the comparison between example 1 and comparative examples 5 to 6, when the bore fluid is only an oil phase or the bore fluid is only a water phase, the crushing strength of the water capsule for cigarettes is affected.
Test example 2
Evaluation of harm reduction performance of bead blasting for cigarettes
Testing a sample: water capsule for cigarette provided in examples 1 to 16 and comparative examples 1 to 6
The test method comprises the following steps: adding the water capsule for cigarettes into cigarettes, pinching and breaking the bead, measuring the release amount of harmful ingredients in the main stream smoke by using a smoking machine, and calculating the reduction rate of the release amount of the harmful ingredients in the main stream smoke compared with a control cigarette (the capsule is not pinched and broken);
the test results are shown in table 2:
TABLE 2
As can be seen from the data in Table 2, the water capsules for cigarettes provided by the invention (examples 1-16) can reduce the release amount of harmful gas components in smoke, wherein the release amount of HCN is reduced by 27-43%, the release amount of phenol is reduced by 24-44%, the release amount of ammonia is reduced by 27-42%, the release amount of carbon monoxide is reduced by 18-33%, and the release amount of tar is reduced by 24-35%.
In the invention, the components of the aqueous phase traditional Chinese medicine extraction concentrated solution are matched with each other, the components of the oil phase essence are matched with each other, and the components of the wall material are matched with each other, so that the release amount of harmful gases in the neutralized smoke can be absorbed; in addition, the core liquid of the invention adopts water-in-oil emulsion, which can improve the absorption capacity of harmful smoke in water phase or oil phase.
As can be seen from the comparison between the embodiment 1 and the embodiments 4 to 10, the components in the concentrated solution of the traditional Chinese medicine extract are matched with each other, have synergistic effect and reduce the emission of harmful gases in smoke.
As can be seen from the comparison between example 1 and examples 11-13, the various components of the oil phase essence cooperate with each other to absorb and neutralize the harmful gases in the smoke.
As can be seen from the comparison between example 1 and examples 14-16, sesbania gum and arabic gelatin cooperate with each other to block the emission of harmful gases in the smoke.
As can be seen from the comparison between example 1 and comparative examples 1 to 3, the release of harmful smoke can be blocked by the mutual matching of the components in the wax, the cellulose and the vegetable gum in the wall material.
As is clear from comparison between example 1 and comparative examples 4 to 6, the use of a water-in-oil emulsion as a bore fluid can reduce the emission of harmful gases.
Test example 3
Sensory evaluation
Testing a sample: water capsule for cigarette provided in examples 1 to 16 and comparative examples 1 to 6
The test method comprises the following steps: adding the water capsule for cigarettes into cigarettes, collecting 220 volunteers, dividing into 22 groups, dividing each group into 10 persons, grading the gloss (full score of 5), the fragrance (full score of 32), the harmony (full score of 6), the miscellaneous gas (full score of 12), the irritation (full score of 20) and the aftertaste (full score of 25) of the cigarettes, and taking the average value of each group according to the test result;
the test results are shown in table 3:
TABLE 3
As can be seen from the data in Table 3, the sensory evaluation score of the water capsule for cigarettes provided by the invention is 64.20-93.80, the fragrance of the cigarettes is obviously improved, the aftertaste is improved, and the irritation and the offensive odor are also greatly reduced.
The applicant states that the invention is described by the above embodiments, but the invention is not limited to the above embodiments, that is, the invention is not limited to the above embodiments. It should be understood by those skilled in the art that any modification of the present invention, equivalent substitutions of the raw materials of the product of the present invention, addition of auxiliary components, selection of specific modes, etc., are within the scope and disclosure of the present invention.
Claims (10)
1. The water capsule for the cigarette is characterized by comprising a core liquid and a wall material, wherein the core liquid is a water-in-oil emulsion; the wall material comprises wax, cellulose and vegetable gum.
2. The water capsule for cigarettes as claimed in claim 1, wherein the mass ratio of the core liquid to the wall material in the water capsule for cigarettes is (0.5-10): 1;
preferably, the raw materials for preparing the water-in-oil emulsion comprise a water phase and an oil phase;
preferably, the mass ratio of the water phase to the oil phase is (0.2-5): 1.
3. The water capsule for tobacco as claimed in claim 2, wherein the water phase is prepared from concentrated Chinese medicinal extractive solution and water;
preferably, the water phase comprises 10-60% of traditional Chinese medicine extract concentrated solution by mass percent;
preferably, the traditional Chinese medicine extract concentrated solution comprises traditional Chinese medicine alcohol extract concentrated solution and/or traditional Chinese medicine water extract concentrated solution;
preferably, the Chinese medicinal concentrated extract comprises one or a combination of at least two of clove extract concentrated solution, lily extract concentrated solution, hawthorn extract concentrated solution, eupatorium extract concentrated solution, pinellia ternate extract, forsythia suspensa extract and rhododendron extract;
preferably, the traditional Chinese medicine extract concentrated solution comprises clove extract concentrated solution, lily extract concentrated solution, hawthorn extract concentrated solution, eupatorium extract concentrated solution, pinellia ternate extract, fructus forsythiae extract and rhododendron extract according to the mass ratio of (2-20): (3-20): (4-15): (2-6): (1-10): 1-10).
4. The water capsule for tobacco as claimed in claim 3, wherein the water phase is prepared from raw materials further comprising a preservative;
preferably, the preservative comprises any one or a combination of at least two of potassium sorbate, sodium benzoate, ethyl paraben, or propyl paraben;
preferably, the preparation raw material of the water phase comprises 0.01-0.5% of preservative by mass percentage;
preferably, the preparation raw material of the water phase also comprises a cosolvent;
preferably, the co-solvent comprises any one or a combination of at least two of ethanol, propylene glycol or glycerol;
preferably, the mass ratio of the water to the cosolvent is (10-130): 1.
5. The water capsule for cigarette as claimed in any one of claims 2 to 4, wherein the raw materials for preparing the oil phase comprise water-in-oil type emulsifier, oil phase essence and vegetable oil;
preferably, the mass ratio of the water-in-oil emulsifier to the oil-phase essence to the vegetable oil is (1-10) to (5-20) to (30-90);
preferably, the water-in-oil emulsifier comprises any one of or a combination of at least two of polyglyceryl fatty acid ester, diglyceryl monolaurate, sorbitol monolaurate, nonylphenoxy polyethoxyethanol, span 80, or PEG-10 polydimethylsiloxane;
preferably, the oil phase essence comprises lemon essential oil, mint essential oil and orange peel oil;
preferably, the mass ratio of the lemon essential oil to the mint essential oil to the orange peel oil is (1-5) (1-5): 1;
preferably, the vegetable oil comprises any one of olive oil, soybean oil, corn oil or rapeseed oil or a combination of at least two thereof.
6. The water capsule for cigarette as in any one of claims 1-5, wherein the mass ratio of the wax, cellulose and vegetable gum is (1-5) to (1-3) to (1-10);
preferably, the wax comprises any one of carnauba wax, candelilla wax, rice bran wax, sugar cane wax, bay wax, castor bean wax, jojoba wax, ouricury wax or douglas fir wax or a combination of at least two thereof;
preferably, the cellulose comprises synthetic cellulose;
preferably, the synthetic cellulose comprises any one of carboxyethyl cellulose, carboxypropyl methyl cellulose, carboxymethyl cellulose or ethylcarboxyethyl cellulose or a combination of at least two thereof;
preferably, the vegetable gum comprises any one or a combination of at least two of sesbania gum, guar gum, flax gum, fenugreek gum, arabinogelatin, tamarind polysaccharide gum or locust bean gum, preferably a combination of sesbania gum and arabinogelatin;
preferably, the mass ratio of the sesbania gum to the arabinogelatin is (1-5): 1.
7. A preparation method of the water capsule for the cigarette according to any one of claims 1 to 6, wherein the preparation method comprises the following steps:
respectively placing the core liquid and the wall material in an inner core channel and an outer wall channel of a coaxial double-layer dripper, dripping the core liquid and the wall material into the protective liquid through the coaxial double-layer dripper, and separating and washing the core liquid and the wall material through a screen to obtain the water capsule for the cigarettes;
preferably, the temperature of the coaxial double-layer dripper is 50-150 ℃;
preferably, the temperature of the protection solution is 5-30 ℃.
8. The method of claim 7, wherein the protective solution comprises an aqueous ethanol solution and/or paraffin oil;
preferably, the volume percentage of ethanol in the ethanol water solution is 90-98%;
preferably, the preparation method of the bore fluid comprises the following steps:
(a) mixing water and the concentrated solution of Chinese medicinal extract to obtain water phase; mixing the water-in-oil type emulsifier, the oil phase essence and the vegetable oil to obtain an oil phase;
(b) mixing the water phase and the oil phase obtained in the step (a), and homogenizing to obtain a core liquid;
preferably, in step (a), the temperature for mixing the obtained aqueous phase is 2-30 ℃; the temperature of the mixture in the obtained oil phase is 50-150 ℃;
preferably, in step (a), the obtained aqueous phase mixture further comprises a preservative and/or a cosolvent;
preferably, in the step (b), the rotation speed of the homogenizing is 4000-;
preferably, the preparation method of the wall material comprises the following steps: mixing and melting wax, cellulose and vegetable gum to obtain the wall material;
preferably, the temperature of the mixed melt is 50 to 150 ℃.
9. The method for preparing according to claim 7 or 8, characterized in that it comprises the following steps:
(1) preparing core liquid:
(a) mixing water, concentrated Chinese medicinal extract, optional antiseptic and optional cosolvent at 2-30 deg.C to obtain water phase; mixing water-in-oil emulsifier, oil phase essence and vegetable oil at 50-150 deg.C to obtain oil phase;
(b) homogenizing the water phase and the oil phase obtained in the step (a) for 5-20min at the rotating speed of 4000-6000rpm to obtain core liquid;
(2) preparing wall materials: mixing and melting wax, cellulose and vegetable gum at 50-150 ℃ to obtain the wall material;
(3) preparing a water capsule for cigarettes: and respectively placing the core liquid and the wall material in an inner core channel and an outer wall channel of a coaxial double-layer dripper at the temperature of 50-150 ℃, dripping the core liquid and the wall material into a protective liquid at the temperature of 5-30 ℃ through the coaxial double-layer dripper, and separating and washing the core liquid and the wall material by using a screen to obtain the water capsule for the cigarettes.
10. Use of the water capsule for cigarette according to any one of claims 1 to 6 for preparing cut tobacco, cigarette paper or filter tip of cigarette.
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| Application Number | Priority Date | Filing Date | Title |
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| CN202210388790.XA CN114886153A (en) | 2022-04-13 | 2022-04-13 | Water capsule for cigarettes and preparation method and application thereof |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN202210388790.XA CN114886153A (en) | 2022-04-13 | 2022-04-13 | Water capsule for cigarettes and preparation method and application thereof |
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| CN114886153A true CN114886153A (en) | 2022-08-12 |
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