CN114836073A - Residue-free glass transfer printing ink and preparation method thereof - Google Patents
Residue-free glass transfer printing ink and preparation method thereof Download PDFInfo
- Publication number
- CN114836073A CN114836073A CN202110624442.3A CN202110624442A CN114836073A CN 114836073 A CN114836073 A CN 114836073A CN 202110624442 A CN202110624442 A CN 202110624442A CN 114836073 A CN114836073 A CN 114836073A
- Authority
- CN
- China
- Prior art keywords
- residue
- free glass
- parts
- glass transfer
- transfer printing
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000011521 glass Substances 0.000 title claims abstract description 36
- 238000010023 transfer printing Methods 0.000 title claims abstract description 21
- 238000002360 preparation method Methods 0.000 title claims abstract description 13
- 239000002131 composite material Substances 0.000 claims abstract description 19
- 239000011159 matrix material Substances 0.000 claims abstract description 19
- 239000000919 ceramic Substances 0.000 claims abstract description 13
- 239000002994 raw material Substances 0.000 claims abstract description 13
- 239000000945 filler Substances 0.000 claims abstract description 11
- 239000002904 solvent Substances 0.000 claims abstract description 9
- 238000012546 transfer Methods 0.000 claims description 23
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 claims description 15
- 239000002216 antistatic agent Substances 0.000 claims description 14
- 239000003822 epoxy resin Substances 0.000 claims description 14
- 229920000647 polyepoxide Polymers 0.000 claims description 14
- 239000004925 Acrylic resin Substances 0.000 claims description 12
- 229920000178 Acrylic resin Polymers 0.000 claims description 12
- 229920001971 elastomer Polymers 0.000 claims description 11
- 239000005060 rubber Substances 0.000 claims description 11
- 229910000019 calcium carbonate Inorganic materials 0.000 claims description 7
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims description 6
- -1 alcohol ethers Chemical class 0.000 claims description 4
- 239000003795 chemical substances by application Substances 0.000 claims description 4
- 239000002270 dispersing agent Substances 0.000 claims description 4
- 150000002148 esters Chemical class 0.000 claims description 4
- 239000002245 particle Substances 0.000 claims description 4
- KXGFMDJXCMQABM-UHFFFAOYSA-N 2-methoxy-6-methylphenol Chemical compound [CH]OC1=CC=CC([CH])=C1O KXGFMDJXCMQABM-UHFFFAOYSA-N 0.000 claims description 3
- 239000005995 Aluminium silicate Substances 0.000 claims description 3
- 235000012211 aluminium silicate Nutrition 0.000 claims description 3
- 150000003863 ammonium salts Chemical class 0.000 claims description 3
- 150000001555 benzenes Chemical class 0.000 claims description 3
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 claims description 3
- 150000002576 ketones Chemical class 0.000 claims description 3
- 229910003002 lithium salt Inorganic materials 0.000 claims description 3
- 159000000002 lithium salts Chemical class 0.000 claims description 3
- 229920001568 phenolic resin Polymers 0.000 claims description 3
- 239000005011 phenolic resin Substances 0.000 claims description 3
- 239000000843 powder Substances 0.000 claims description 3
- 239000004408 titanium dioxide Substances 0.000 claims description 3
- 238000000034 method Methods 0.000 claims description 2
- 239000000454 talc Substances 0.000 claims 1
- 229910052623 talc Inorganic materials 0.000 claims 1
- 238000007639 printing Methods 0.000 abstract description 5
- 238000005299 abrasion Methods 0.000 abstract description 2
- 239000006185 dispersion Substances 0.000 abstract description 2
- 230000005611 electricity Effects 0.000 abstract description 2
- 230000007774 longterm Effects 0.000 abstract description 2
- 230000003068 static effect Effects 0.000 abstract description 2
- 239000000758 substrate Substances 0.000 abstract description 2
- 239000000976 ink Substances 0.000 description 24
- 230000000052 comparative effect Effects 0.000 description 17
- LVGFPWDANALGOY-UHFFFAOYSA-N 8-methylnonyl prop-2-enoate Chemical compound CC(C)CCCCCCCOC(=O)C=C LVGFPWDANALGOY-UHFFFAOYSA-N 0.000 description 9
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 9
- 229920005549 butyl rubber Polymers 0.000 description 7
- 239000000853 adhesive Substances 0.000 description 6
- 230000001070 adhesive effect Effects 0.000 description 6
- MHCFAGZWMAWTNR-UHFFFAOYSA-M lithium perchlorate Chemical compound [Li+].[O-]Cl(=O)(=O)=O MHCFAGZWMAWTNR-UHFFFAOYSA-M 0.000 description 6
- 229910001486 lithium perchlorate Inorganic materials 0.000 description 5
- 239000004593 Epoxy Substances 0.000 description 4
- 239000004721 Polyphenylene oxide Substances 0.000 description 4
- CJZGTCYPCWQAJB-UHFFFAOYSA-L calcium stearate Chemical compound [Ca+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O CJZGTCYPCWQAJB-UHFFFAOYSA-L 0.000 description 4
- 238000013329 compounding Methods 0.000 description 4
- 229920001577 copolymer Polymers 0.000 description 4
- 238000004519 manufacturing process Methods 0.000 description 4
- 229920000570 polyether Polymers 0.000 description 4
- ZWEHNKRNPOVVGH-UHFFFAOYSA-N 2-Butanone Chemical compound CCC(C)=O ZWEHNKRNPOVVGH-UHFFFAOYSA-N 0.000 description 3
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 3
- XEKOWRVHYACXOJ-UHFFFAOYSA-N Ethyl acetate Chemical compound CCOC(C)=O XEKOWRVHYACXOJ-UHFFFAOYSA-N 0.000 description 3
- 239000004841 bisphenol A epoxy resin Substances 0.000 description 3
- 235000013539 calcium stearate Nutrition 0.000 description 3
- 239000008116 calcium stearate Substances 0.000 description 3
- GYZLOYUZLJXAJU-UHFFFAOYSA-N diglycidyl ether Chemical compound C1OC1COCC1CO1 GYZLOYUZLJXAJU-UHFFFAOYSA-N 0.000 description 3
- FPAFDBFIGPHWGO-UHFFFAOYSA-N dioxosilane;oxomagnesium;hydrate Chemical compound O.[Mg]=O.[Mg]=O.[Mg]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O FPAFDBFIGPHWGO-UHFFFAOYSA-N 0.000 description 3
- 230000001788 irregular Effects 0.000 description 3
- 238000012986 modification Methods 0.000 description 3
- 230000004048 modification Effects 0.000 description 3
- 238000012360 testing method Methods 0.000 description 3
- FYGHSUNMUKGBRK-UHFFFAOYSA-N 1,2,3-trimethylbenzene Chemical compound CC1=CC=CC(C)=C1C FYGHSUNMUKGBRK-UHFFFAOYSA-N 0.000 description 2
- ARXJGSRGQADJSQ-UHFFFAOYSA-N 1-methoxypropan-2-ol Chemical compound COCC(C)O ARXJGSRGQADJSQ-UHFFFAOYSA-N 0.000 description 2
- DLFVBJFMPXGRIB-UHFFFAOYSA-N Acetamide Chemical compound CC(N)=O DLFVBJFMPXGRIB-UHFFFAOYSA-N 0.000 description 2
- IISBACLAFKSPIT-UHFFFAOYSA-N bisphenol A Chemical compound C=1C=C(O)C=CC=1C(C)(C)C1=CC=C(O)C=C1 IISBACLAFKSPIT-UHFFFAOYSA-N 0.000 description 2
- DKPFZGUDAPQIHT-UHFFFAOYSA-N butyl acetate Chemical compound CCCCOC(C)=O DKPFZGUDAPQIHT-UHFFFAOYSA-N 0.000 description 2
- JHIVVAPYMSGYDF-UHFFFAOYSA-N cyclohexanone Chemical compound O=C1CCCCC1 JHIVVAPYMSGYDF-UHFFFAOYSA-N 0.000 description 2
- 238000011161 development Methods 0.000 description 2
- GVGUFUZHNYFZLC-UHFFFAOYSA-N dodecyl benzenesulfonate;sodium Chemical compound [Na].CCCCCCCCCCCCOS(=O)(=O)C1=CC=CC=C1 GVGUFUZHNYFZLC-UHFFFAOYSA-N 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- HJOVHMDZYOCNQW-UHFFFAOYSA-N isophorone Chemical compound CC1=CC(=O)CC(C)(C)C1 HJOVHMDZYOCNQW-UHFFFAOYSA-N 0.000 description 2
- 239000000203 mixture Substances 0.000 description 2
- 229940080264 sodium dodecylbenzenesulfonate Drugs 0.000 description 2
- 238000003756 stirring Methods 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- PSGCQDPCAWOCSH-UHFFFAOYSA-N (4,7,7-trimethyl-3-bicyclo[2.2.1]heptanyl) prop-2-enoate Chemical compound C1CC2(C)C(OC(=O)C=C)CC1C2(C)C PSGCQDPCAWOCSH-UHFFFAOYSA-N 0.000 description 1
- DSSYKIVIOFKYAU-XCBNKYQSSA-N (R)-camphor Chemical compound C1C[C@@]2(C)C(=O)C[C@@H]1C2(C)C DSSYKIVIOFKYAU-XCBNKYQSSA-N 0.000 description 1
- RWNUSVWFHDHRCJ-UHFFFAOYSA-N 1-butoxypropan-2-ol Chemical compound CCCCOCC(C)O RWNUSVWFHDHRCJ-UHFFFAOYSA-N 0.000 description 1
- JOLQKTGDSGKSKJ-UHFFFAOYSA-N 1-ethoxypropan-2-ol Chemical compound CCOCC(C)O JOLQKTGDSGKSKJ-UHFFFAOYSA-N 0.000 description 1
- JDSQBDGCMUXRBM-UHFFFAOYSA-N 2-[2-(2-butoxypropoxy)propoxy]propan-1-ol Chemical compound CCCCOC(C)COC(C)COC(C)CO JDSQBDGCMUXRBM-UHFFFAOYSA-N 0.000 description 1
- RZVINYQDSSQUKO-UHFFFAOYSA-N 2-phenoxyethyl prop-2-enoate Chemical compound C=CC(=O)OCCOC1=CC=CC=C1 RZVINYQDSSQUKO-UHFFFAOYSA-N 0.000 description 1
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 description 1
- QSLJCEYMKUNKJF-UHFFFAOYSA-N C(C=C)(=O)O.C(C=C)(=O)O.C(C=C)(=O)O.C(C)OCCC(CO)(CO)CO Chemical compound C(C=C)(=O)O.C(C=C)(=O)O.C(C=C)(=O)O.C(C)OCCC(CO)(CO)CO QSLJCEYMKUNKJF-UHFFFAOYSA-N 0.000 description 1
- 241000036318 Callitris preissii Species 0.000 description 1
- 241000196324 Embryophyta Species 0.000 description 1
- 229920000181 Ethylene propylene rubber Polymers 0.000 description 1
- 244000043261 Hevea brasiliensis Species 0.000 description 1
- 241000249820 Lipotes vexillifer Species 0.000 description 1
- 229920000459 Nitrile rubber Polymers 0.000 description 1
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 description 1
- 239000005062 Polybutadiene Substances 0.000 description 1
- 235000005701 Tarchonanthus camphoratus Nutrition 0.000 description 1
- DAKWPKUUDNSNPN-UHFFFAOYSA-N Trimethylolpropane triacrylate Chemical compound C=CC(=O)OCC(CC)(COC(=O)C=C)COC(=O)C=C DAKWPKUUDNSNPN-UHFFFAOYSA-N 0.000 description 1
- 229920006311 Urethane elastomer Polymers 0.000 description 1
- IAXXETNIOYFMLW-COPLHBTASA-N [(1s,3s,4s)-4,7,7-trimethyl-3-bicyclo[2.2.1]heptanyl] 2-methylprop-2-enoate Chemical compound C1C[C@]2(C)[C@@H](OC(=O)C(=C)C)C[C@H]1C2(C)C IAXXETNIOYFMLW-COPLHBTASA-N 0.000 description 1
- HVVWZTWDBSEWIH-UHFFFAOYSA-N [2-(hydroxymethyl)-3-prop-2-enoyloxy-2-(prop-2-enoyloxymethyl)propyl] prop-2-enoate Chemical compound C=CC(=O)OCC(CO)(COC(=O)C=C)COC(=O)C=C HVVWZTWDBSEWIH-UHFFFAOYSA-N 0.000 description 1
- 230000006978 adaptation Effects 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- KQUVYHRORKUYQZ-UHFFFAOYSA-N bis(trifluoromethylsulfonyl)methylsulfonyl-trifluoromethane;lithium Chemical compound [Li].FC(F)(F)S(=O)(=O)C(S(=O)(=O)C(F)(F)F)S(=O)(=O)C(F)(F)F KQUVYHRORKUYQZ-UHFFFAOYSA-N 0.000 description 1
- 238000005034 decoration Methods 0.000 description 1
- 238000009826 distribution Methods 0.000 description 1
- JRBPAEWTRLWTQC-UHFFFAOYSA-N dodecylamine Chemical class CCCCCCCCCCCCN JRBPAEWTRLWTQC-UHFFFAOYSA-N 0.000 description 1
- 239000004845 glycidylamine epoxy resin Substances 0.000 description 1
- 229920002681 hypalon Polymers 0.000 description 1
- 229940119545 isobornyl methacrylate Drugs 0.000 description 1
- 229920003049 isoprene rubber Polymers 0.000 description 1
- 229910003473 lithium bis(trifluoromethanesulfonyl)imide Inorganic materials 0.000 description 1
- QSZMZKBZAYQGRS-UHFFFAOYSA-N lithium;bis(trifluoromethylsulfonyl)azanide Chemical compound [Li+].FC(F)(F)S(=O)(=O)[N-]S(=O)(=O)C(F)(F)F QSZMZKBZAYQGRS-UHFFFAOYSA-N 0.000 description 1
- MCVFFRWZNYZUIJ-UHFFFAOYSA-M lithium;trifluoromethanesulfonate Chemical compound [Li+].[O-]S(=O)(=O)C(F)(F)F MCVFFRWZNYZUIJ-UHFFFAOYSA-M 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 229920003052 natural elastomer Polymers 0.000 description 1
- 229920001194 natural rubber Polymers 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 229920003023 plastic Polymers 0.000 description 1
- 229920002857 polybutadiene Polymers 0.000 description 1
- 229920006146 polyetheresteramide block copolymer Polymers 0.000 description 1
- 125000002572 propoxy group Chemical group [*]OC([H])([H])C(C([H])([H])[H])([H])[H] 0.000 description 1
- 230000033764 rhythmic process Effects 0.000 description 1
- 239000007858 starting material Substances 0.000 description 1
- 238000010998 test method Methods 0.000 description 1
- 238000005491 wire drawing Methods 0.000 description 1
- 239000008096 xylene Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/02—Printing inks
- C09D11/10—Printing inks based on artificial resins
- C09D11/106—Printing inks based on artificial resins containing macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- C09D11/107—Printing inks based on artificial resins containing macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds from unsaturated acids or derivatives thereof
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/02—Printing inks
- C09D11/03—Printing inks characterised by features other than the chemical nature of the binder
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/02—Printing inks
- C09D11/03—Printing inks characterised by features other than the chemical nature of the binder
- C09D11/033—Printing inks characterised by features other than the chemical nature of the binder characterised by the solvent
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/02—Printing inks
- C09D11/10—Printing inks based on artificial resins
- C09D11/102—Printing inks based on artificial resins containing macromolecular compounds obtained by reactions other than those only involving unsaturated carbon-to-carbon bonds
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/02—Printing inks
- C09D11/10—Printing inks based on artificial resins
- C09D11/102—Printing inks based on artificial resins containing macromolecular compounds obtained by reactions other than those only involving unsaturated carbon-to-carbon bonds
- C09D11/103—Printing inks based on artificial resins containing macromolecular compounds obtained by reactions other than those only involving unsaturated carbon-to-carbon bonds of aldehydes, e.g. phenol-formaldehyde resins
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Printing Methods (AREA)
- Inks, Pencil-Leads, Or Crayons (AREA)
Abstract
The invention relates to the field of printing, in particular to a residue-free glass transfer printing ink and a preparation method thereof, wherein the preparation raw materials comprise: 20-30 parts of composite viscous matrix, 20-30 parts of solvent and 3-8 parts of rigid filler. The high-transfer-degree transfer printing ink disclosed by the invention has no electrostatic resistance during transfer printing, further has no pattern dispersion caused by static electricity, is firm in transferred pattern, good in adhesion to a substrate, small in abrasion after long-term use, and especially suitable for transfer printing on the surfaces of glass and ceramics. In addition, the ink disclosed by the invention is moderate in viscosity and high in transfer printing degree, and can not cause ink residue in transfer printing, can not cause the problems of unclear transfer printing patterns and the like.
Description
Technical Field
The invention relates to the field of printing, in particular to a residue-free glass transfer printing ink and a preparation method thereof.
Background
Along with the increasing improvement of aesthetic level of people, glass, ceramics and other products with irregular shapes in indoor and outdoor decorations and artworks are more and more, but the printing ink for printing patterns on the surfaces of the products with irregular surfaces cannot follow the rapid development rhythm, and because the surfaces of the glass and the ceramics are smooth, the adhesion force is poor, dead angles caused by the irregular shapes and other problems, a series of problems of uneven thickness, easy falling, non-wear resistance and the like are caused in the printing of ink clusters, so that the development of the high-transfer-degree transfer printing ink suitable for the fields of the glass and the ceramics is necessary.
Disclosure of Invention
The invention provides a residue-free glass transfer printing ink, which is prepared from the following raw materials in parts by weight: 20-30 parts of composite viscous matrix, 20-30 parts of solvent and 3-8 parts of rigid filler.
In a preferred embodiment, the composite adhesive matrix includes at least one of a monofunctional acrylic resin, a polyfunctional acrylic resin, an epoxy resin, and a phenolic resin.
As a preferred embodiment, the composite adhesive matrix further comprises rubber.
As a preferred embodiment, the rubber is added to the composite adhesive matrix in a proportion of no greater than 10% by weight.
In a preferred embodiment, the solvent includes at least one of benzenes, ketones, alcohol ethers, and esters.
As a preferred embodiment, the rigid filler is at least one selected from titanium dioxide, ceramic powder, calcium carbonate, talc powder and kaolin.
As a preferred embodiment, the rigid filler has a particle size of 1 to 50 nm.
As a preferred embodiment, the preparation raw materials comprise the following components in parts by weight: 2-5 parts of antistatic agent, 0.1-1 part of dispersant and 0.1-1 part of flatting agent.
In a preferred embodiment, the antistatic agent is at least one selected from the group consisting of organic lithium salt type antistatic agents and organic ammonium salt type antistatic agents. .
The second aspect of the invention provides a preparation method of the residue-free glass transfer printing ink, which is to mix and stir the preparation raw materials and coat the mixture on the surface of a ceramic or glass product.
Compared with the prior art, the invention has the following beneficial effects: the high-transferability transfer printing ink has no electrostatic resistance during transfer printing, further has no pattern dispersion caused by static electricity, has firm transferred pattern, good adhesion to a substrate and small abrasion after long-term use, and is particularly suitable for transfer printing on the surfaces of glass and ceramics. In addition, the ink disclosed by the invention is moderate in viscosity and high in transfer printing degree, and can not cause ink residue in transfer printing, can not cause the problems of unclear transfer printing patterns and the like.
Detailed Description
In order to solve the above technical problems, a first aspect of the present invention provides a residue-free glass transfer ink, which is prepared from the following raw materials in parts by weight: 20-30 parts of composite viscous matrix, 20-30 parts of solvent and 3-8 parts of rigid filler.
In a preferred embodiment, the composite adhesive matrix includes at least one of a monofunctional acrylic resin, a polyfunctional acrylic resin, an epoxy resin, and a phenolic resin.
Preferably, the composite viscous matrix comprises monofunctional acrylic resin, multifunctional acrylic resin and epoxy resin.
Preferably, the monofunctional acrylic resin is at least one selected from isodecyl acrylate, 2-phenoxyethyl acrylate, isobornyl methacrylate and isobornyl acrylate.
Preferably, the monofunctional acrylic resin is selected from isodecyl acrylates.
Preferably, the polyfunctional acrylic resin is at least one selected from the group consisting of 9-ethoxy-trimethylolpropane triacrylate, propoxy-containing trimethylolpropane triacrylate, 3-ethoxy-trimethylolpropane triacrylate, and pentaerythritol triacrylate.
Preferably, the polyfunctional acrylic resin is selected from 9-ethoxy-trimethylolpropane triacrylate.
Preferably, the epoxy resin includes at least one of glycidyl ether epoxy resin, glycidyl ester epoxy resin, and glycidyl amine epoxy resin.
Preferably, the epoxy resin includes glycidyl ether type epoxy resin.
Preferably, the glycidyl ether type epoxy resin includes a bisphenol a type epoxy resin.
Preferably, the bisphenol A type epoxy resin has an epoxy equivalent of (210) -250 equivalent/100 g.
Preferably, the mass ratio of the isodecyl acrylate, the 9-ethoxy-trimethylolpropane triacrylate and the bisphenol A epoxy resin is (1-3): (2-4): (0.5-1.5).
As a preferred embodiment, the composite adhesive matrix further comprises rubber.
As a preferred embodiment, the rubber is added to the composite adhesive matrix in a proportion of no greater than 10% by weight.
Preferably, the rubber is at least one selected from nitrile rubber, urethane rubber, ethylene propylene rubber, acrylate rubber, chlorosulfonated polyethylene rubber, butyl rubber, butadiene rubber, isoprene rubber and natural rubber.
Preferably, the rubber is selected from butyl rubber.
Preferably, the viscosity of the butyl rubber is 540-560mPa · s.
In a preferred embodiment, the solvent includes at least one of benzenes, ketones, alcohol ethers, and esters.
Preferably, the solvent comprises at least one of toluene, xylene, trimethylbenzene, acetone, methyl ethyl ketone, cyclohexanone, isophorone, propylene glycol methyl ether, propylene glycol ethyl ether, propylene glycol butyl ether, propylene glycol ether, ethyl acetate and n-butyl acetate.
Preferably, the solvent comprises toluene.
As a preferred embodiment, the rigid filler is at least one selected from titanium dioxide, ceramic powder, calcium carbonate, talc powder and kaolin.
As a preferred embodiment, the rigid filler has a particle size of 1 to 50 nm.
Preferably, the rigid filler is calcium carbonate.
Preferably, the calcium carbonate is ground calcium carbonate.
As a preferred embodiment, the preparation raw materials comprise the following components in parts by weight: 2-5 parts of antistatic agent, 0.1-1 part of dispersant and 0.1-1 part of flatting agent.
In a preferred embodiment, the antistatic agent is at least one selected from the group consisting of organic lithium salt type antistatic agents and organic ammonium salt type antistatic agents.
Preferably, the antistatic agent is at least one selected from lithium perchlorate, lithium trifluoromethanesulfonate, lithium bis (trifluoromethanesulfonyl) imide, lithium tris (trifluoromethanesulfonyl) methane, calcium stearate, ethoxylated lauryl amine, polyether ester amide, polyether ester acetamide and propylene oxide copolymer.
Preferably, the antistatic agent is selected from lithium perchlorate.
The dispersant is not particularly limited in the present invention, and any substance capable of achieving a dispersing effect in the system may be used, for example, sodium dodecylbenzenesulfonate.
The leveling agent is not particularly limited in the present invention, and any substance capable of providing a regular leveling effect on the surface of the transfer ink in the system may be used, for example, a polyether siloxane copolymer.
The second aspect of the invention provides a preparation method of the residue-free glass transfer printing ink, which is to mix and stir the preparation raw materials and coat the mixture on the surface of a ceramic or glass product.
The present invention will be specifically described below by way of examples. It should be noted that the following examples are only for illustrating the present invention and should not be construed as limiting the scope of the present invention, and that the insubstantial modifications and adaptations of the present invention by those skilled in the art based on the above disclosure are still within the scope of the present invention.
Bisphenol A epoxy resin purchased from Gallery Nojin anticorrosive materials Co Ltd
Butyl rubber was purchased from Camphor wood Hengtai Plastic rubber raw materials Ministry of China
Ground limestone purchased from Yongfengda superfine Talc powder plant in Penglai City
7791-03-9 CAS # of lithium perchlorate
Polyether siloxane copolymer purchased from Nanjing Baiji scientific Co
CAS # (1330-61-6) of isodecyl acrylate
CAS # for 9-ethoxy-trimethylolpropane triacrylate 28961-43-5
CAS # 1592-23-0 of calcium stearate
In addition, the starting materials used are all commercially available, unless otherwise specified.
Examples
Example 1
In a first aspect of this embodiment, a residue-free glass transfer ink is provided, which is prepared from the following raw materials in parts by weight: 25 parts of composite viscous matrix, 28 parts of toluene, 6 parts of heavy calcium carbonate (with the particle size of 15nm), 3 parts of lithium perchlorate, 0.7 part of sodium dodecyl benzene sulfonate and 0.5 part of polyether siloxane copolymer.
The composite viscous matrix is prepared from isodecyl acrylate, 9-ethoxy-trimethylolpropane triacrylate, bisphenol A epoxy resin (the epoxy equivalent is 230 equivalent/100 g), butyl rubber (the viscosity is 550mPa & s) in a mass ratio of 2: 3: 1: 0.3 compounding.
In a second aspect of this embodiment, a method for preparing a residue-free glass transfer ink is provided, wherein the preparation raw materials are mixed and stirred, and are applied to the surface of a ceramic or glass product.
Comparative example 1
This comparative example provides, in a first aspect, a residue-free glass transfer ink, the specific embodiment being the same as example 1, except that the composite viscous matrix is isodecyl acrylate, 9-ethoxy-trimethylolpropane triacrylate, bisphenol a type epoxy resin (epoxy equivalent of 230 equivalents/100 g), butyl rubber (viscosity of 550mPa · s) in a mass ratio of 5: 1: 3: 3, compounding.
In a second aspect of this comparative example, a method of making a residue-free glass transfer ink is provided, as described in example 1.
Comparative example 2
This comparative example provides, in a first aspect, a residue-free glass transfer ink, the same as example 1, except that the composite viscous matrix is isodecyl acrylate, 9-ethoxy-trimethylolpropane triacrylate, butyl rubber (viscosity 550mPa · s) in a mass ratio of 2: 3: 0.3 compounding.
In a second aspect of this comparative example, a method of making a residue-free glass transfer ink is provided, as described in example 1.
Comparative example 3
This comparative example provides, in a first aspect, a residue-free glass transfer ink, the specific embodiment being the same as example 1, except that the composite viscous matrix is isodecyl acrylate, 9-ethoxy-trimethylolpropane triacrylate, bisphenol a type epoxy resin (epoxy equivalent 230 equivalents/100 g) in a mass ratio of 2: 3: 1, compounding.
In a second aspect of this comparative example, a method of making a residue-free glass transfer ink is provided, as described in example 1.
Comparative example 4
This comparative example provides, in a first aspect, a residue-free glass transfer ink, and is similar to example 1, except that calcium stearate is used in place of lithium perchlorate.
In a second aspect of this comparative example, a method of making a residue-free glass transfer ink is provided, as described in example 1.
Performance testing
The transfer inks of examples and comparative examples were applied to the ceramic surface in the same amount, and dried to perform the following tests.
The transfer degree test method comprises the following steps: and (3) after the pattern is transferred, observing whether the edge line has the phenomena of wire drawing and scattering distribution by using a magnifying lens of 10 times.
Adhesion test standard reference: GB/T13217.7-2009.
| Changes to India | Adhesion force | |
| Example 1 | Is free of | 5B |
| Comparative example 1 | Is provided with | 2B |
| Comparative example 2 | Is provided with | 2B |
| Comparative example 3 | Is provided with | 2B |
| Comparative example 4 | Is provided with | 3B |
The above description is only a preferred embodiment of the present invention, and is not intended to limit the present invention in other forms, and any person skilled in the art may modify or change the technical content of the above disclosure into equivalent embodiments with equivalent changes, but all those simple modifications, equivalent changes and modifications made to the above embodiments according to the technical spirit of the present invention still belong to the protection scope of the present invention.
Claims (10)
1. The residue-free glass transfer printing ink is characterized by comprising the following raw materials in parts by weight: 20-30 parts of composite viscous matrix, 20-30 parts of solvent and 3-8 parts of rigid filler.
2. The residue-free glass transfer ink of claim 1, wherein the composite viscous matrix comprises at least one of a monofunctional acrylic resin, a multifunctional acrylic resin, an epoxy resin, and a phenolic resin.
3. The residue-free glass transfer ink of any one of claims 1-2, wherein the composite viscous matrix further comprises rubber.
4. The residue-free glass transfer ink of claim 3, wherein the rubber is added to the composite viscous matrix in a proportion of no greater than 10 wt%.
5. The residue-free glass transfer ink of any one of claims 1-4, wherein the solvent comprises at least one of benzenes, ketones, alcohol ethers, esters.
6. The residue-free glass transfer ink of any one of claims 1-5, wherein the rigid filler is at least one selected from titanium dioxide, ceramic powder, calcium carbonate, talc, and kaolin.
7. The residue-free glass transfer ink of any one of claims 1 to 6, wherein the rigid filler has a particle size of 1 to 50 nm.
8. The residue-free glass transfer ink of any one of claims 1-7, wherein the raw materials further comprise, in parts by weight: 2-5 parts of antistatic agent, 0.1-1 part of dispersant and 0.1-1 part of flatting agent.
9. The residue-free glass transfer ink of claim 8, wherein the antistatic agent is at least one selected from the group consisting of organic lithium salt type antistatic agents and organic ammonium salt type antistatic agents. .
10. The method for preparing the residue-free high-transfer-degree transfer ink according to any one of claims 1 to 9, wherein the preparation raw materials are mixed and stirred and are coated on the surface of a ceramic or glass product.
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Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN111253799A (en) * | 2020-03-31 | 2020-06-09 | 东莞市瑞辉新材料技术有限公司 | Pad printing ink for 3D glass surface decoration of mobile phone |
| CN111621194A (en) * | 2020-06-15 | 2020-09-04 | 昆山博益鑫成高分子材料有限公司 | Transfer printing ink formula |
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2021
- 2021-06-04 CN CN202110624442.3A patent/CN114836073A/en active Pending
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN111253799A (en) * | 2020-03-31 | 2020-06-09 | 东莞市瑞辉新材料技术有限公司 | Pad printing ink for 3D glass surface decoration of mobile phone |
| CN111621194A (en) * | 2020-06-15 | 2020-09-04 | 昆山博益鑫成高分子材料有限公司 | Transfer printing ink formula |
Non-Patent Citations (1)
| Title |
|---|
| 楚高利: "《特种印刷技术》", 30 September 2009, 印刷工业出版社 * |
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