CN1147547C - Color inner wall decorating material - Google Patents
Color inner wall decorating materialInfo
- Publication number
- CN1147547C CN1147547C CNB991240677A CN99124067A CN1147547C CN 1147547 C CN1147547 C CN 1147547C CN B991240677 A CNB991240677 A CN B991240677A CN 99124067 A CN99124067 A CN 99124067A CN 1147547 C CN1147547 C CN 1147547C
- Authority
- CN
- China
- Prior art keywords
- powder
- water
- coating
- concentration
- calcite
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 239000000463 material Substances 0.000 title claims abstract description 23
- 238000000576 coating method Methods 0.000 claims abstract description 32
- 239000011248 coating agent Substances 0.000 claims abstract description 29
- 239000000843 powder Substances 0.000 claims abstract description 25
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 18
- 229910021532 Calcite Inorganic materials 0.000 claims abstract description 13
- 229920002689 polyvinyl acetate Polymers 0.000 claims abstract description 13
- 229920002134 Carboxymethyl cellulose Polymers 0.000 claims abstract description 9
- GCLGEJMYGQKIIW-UHFFFAOYSA-H sodium hexametaphosphate Chemical compound [Na]OP1(=O)OP(=O)(O[Na])OP(=O)(O[Na])OP(=O)(O[Na])OP(=O)(O[Na])OP(=O)(O[Na])O1 GCLGEJMYGQKIIW-UHFFFAOYSA-H 0.000 claims abstract description 9
- 235000019982 sodium hexametaphosphate Nutrition 0.000 claims abstract description 9
- 239000001577 tetrasodium phosphonato phosphate Substances 0.000 claims abstract description 9
- 239000001768 carboxy methyl cellulose Substances 0.000 claims abstract description 8
- 235000010948 carboxy methyl cellulose Nutrition 0.000 claims abstract description 8
- 239000008112 carboxymethyl-cellulose Substances 0.000 claims abstract description 8
- 239000003795 chemical substances by application Substances 0.000 claims description 15
- 239000000243 solution Substances 0.000 claims description 14
- 239000004372 Polyvinyl alcohol Substances 0.000 claims description 12
- 239000006185 dispersion Substances 0.000 claims description 12
- 229920002451 polyvinyl alcohol Polymers 0.000 claims description 12
- 239000007864 aqueous solution Substances 0.000 claims description 10
- 239000005083 Zinc sulfide Substances 0.000 claims description 7
- 229910052984 zinc sulfide Inorganic materials 0.000 claims description 7
- DRDVZXDWVBGGMH-UHFFFAOYSA-N zinc;sulfide Chemical compound [S-2].[Zn+2] DRDVZXDWVBGGMH-UHFFFAOYSA-N 0.000 claims description 7
- 150000004649 carbonic acid derivatives Chemical class 0.000 claims description 6
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 claims description 5
- 239000011575 calcium Substances 0.000 claims description 5
- 229910052791 calcium Inorganic materials 0.000 claims description 5
- 239000000945 filler Substances 0.000 claims description 5
- 239000012752 auxiliary agent Substances 0.000 claims description 4
- 230000008719 thickening Effects 0.000 claims description 4
- 239000005995 Aluminium silicate Substances 0.000 claims description 3
- 235000012211 aluminium silicate Nutrition 0.000 claims description 3
- FPAFDBFIGPHWGO-UHFFFAOYSA-N dioxosilane;oxomagnesium;hydrate Chemical compound O.[Mg]=O.[Mg]=O.[Mg]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O FPAFDBFIGPHWGO-UHFFFAOYSA-N 0.000 claims description 3
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 claims description 3
- 239000010456 wollastonite Substances 0.000 claims description 3
- 229910052882 wollastonite Inorganic materials 0.000 claims description 3
- 230000004048 modification Effects 0.000 claims description 2
- 238000012986 modification Methods 0.000 claims description 2
- 238000010276 construction Methods 0.000 abstract description 7
- 230000008901 benefit Effects 0.000 abstract description 2
- 230000005587 bubbling Effects 0.000 abstract description 2
- 238000002360 preparation method Methods 0.000 abstract description 2
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 abstract 2
- 229910000019 calcium carbonate Inorganic materials 0.000 abstract 1
- 238000011109 contamination Methods 0.000 abstract 1
- 238000005336 cracking Methods 0.000 abstract 1
- 239000003431 cross linking reagent Substances 0.000 abstract 1
- 239000002270 dispersing agent Substances 0.000 abstract 1
- 229920000642 polymer Polymers 0.000 abstract 1
- 238000005201 scrubbing Methods 0.000 abstract 1
- 239000003973 paint Substances 0.000 description 9
- 238000005034 decoration Methods 0.000 description 6
- 239000000839 emulsion Substances 0.000 description 5
- 239000000203 mixture Substances 0.000 description 4
- 238000005299 abrasion Methods 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- 239000000126 substance Substances 0.000 description 3
- 229910000831 Steel Inorganic materials 0.000 description 2
- 230000008859 change Effects 0.000 description 2
- -1 polyethylene Polymers 0.000 description 2
- 239000010959 steel Substances 0.000 description 2
- BHPQYMZQTOCNFJ-UHFFFAOYSA-N Calcium cation Chemical compound [Ca+2] BHPQYMZQTOCNFJ-UHFFFAOYSA-N 0.000 description 1
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 1
- 239000004698 Polyethylene Substances 0.000 description 1
- 239000004743 Polypropylene Substances 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 239000004566 building material Substances 0.000 description 1
- 229910001424 calcium ion Inorganic materials 0.000 description 1
- 239000004568 cement Substances 0.000 description 1
- 239000003086 colorant Substances 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 238000004132 cross linking Methods 0.000 description 1
- 201000010099 disease Diseases 0.000 description 1
- 208000037265 diseases, disorders, signs and symptoms Diseases 0.000 description 1
- 239000003292 glue Substances 0.000 description 1
- 230000006872 improvement Effects 0.000 description 1
- 239000008235 industrial water Substances 0.000 description 1
- 239000004816 latex Substances 0.000 description 1
- 229920000126 latex Polymers 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- 229920000573 polyethylene Polymers 0.000 description 1
- 229920001155 polypropylene Polymers 0.000 description 1
- 229910052573 porcelain Inorganic materials 0.000 description 1
- 230000008569 process Effects 0.000 description 1
- 230000004044 response Effects 0.000 description 1
- 239000007921 spray Substances 0.000 description 1
- 239000007858 starting material Substances 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 230000000007 visual effect Effects 0.000 description 1
- 239000002699 waste material Substances 0.000 description 1
Abstract
The present invention relates to a colorful decorative coating for inner walls, which is prepared from the base materials of sierozem powder and waterproof PVA glue modified from a TS-604A polymer cross-linking agent, and a certain amount of water solution of sodium hexametaphosphate with the concentration of 10%, DA dispersant, active calcium carbonate, a water solution of carboxymethyl cellulose with the concentration of 1.5%, calcite powder, lithopone and a trace amount of color paste are added to the base materials. The colorful decorative coating has the functions of both putty and a coating and does not need preparation on site, and the construction can be finished by only one-time coating. A coat has the advantages of strong scrubbing resistance, strong water resistance and firm bonding. The colorful decorative coating does not have the phenomena of peeling, bubbling, mould development, color contamination or cracking, and has long service life.
Description
The invention relates to coating, particularly about having the interior wall coating of water resistance.
Room or indoor decoration are constantly to change with The development in society and economy.The continuous improvement of people's material life and economic condition then requires also to improve constantly to indoor decoration.Therefore finishing material is also brought in constant renewal in the replacement, to adapt to the demand in this house decoration market of expanding day by day.For example the finishing material of interior wall uses liming to whitewash or paint at first, is in fashion multicolor finish and wallpaper later on again.And generally use at present bright emulsion paint of all kinds.But emulsion paint must carry out the operation of putty bottoming to body of wall before smearing, so that the smooth flawless of surface of wall.Putty is generally preparations such as chemical paste, 107 glue, white cement, old powder.Because it is easy to polish flat, makes and smear emulsion paint acquisition good decoration effect.But this putty quality is loose, and intensity is low, and water tolerance is very poor, and therefore after meeting tide, coating will produce and flake, mouldy, phenomenon such as come off, and is repugnant to the eye, and destroyed the effect of whole decoration, brings many worries to the user.At present for various reasons, external wall seepage has become a kind of frequently-occurring disease of buildings; Nonstandard interior decoration simultaneously, the particularly construction wrong of toilet warterproof layer, or drain gully is handled error, often causes the hidden danger of interior wall percolating water.And the emulsion paint coating is stymied by to this.In addition, the expansion and the shrinkage coefficient of putty and emulsion paint differ, and cause local latex enamelled coating volume skin bubbling easily, so could paint after must waiting putty to parch, this just makes construction period prolong the increase expense.The early 1990s, domestic building materials industry has been developed several interior walls with water resistance in succession and has been criticized spread coated paint, as: spray of molten steel coating, brilliant steel porcelain powder coating, L-94 porcelain-imitated coating, waterproof constructional paint etc.Their common feature is with the base-material of modified polyethylene alcohol (PVA) aqueous solution as main film forming substance, adds a certain amount of filler that contains calcium ion and forms.These interior wall coatings all have good abrasion resistance and water tolerance, and high intensity and hardness.But they generally all need be smeared twice even be more, have also be divided into A material and prepare at B material needs scene.Because the rigidity and the hardness height of material, cause and batch scrape vestige and can't polish flat, therefore not only cause difficulty of construction big, and influence indoor whole coating visual effect.More seriously these coatings ftracture gradually with the passage meeting in years.In addition, the only suitable white coating of these coating serious grow diming phenomenon will occur if make coloured coating.Just because of above-mentioned some shortcomings part, this is multiple to be that the interior wall coating of base-material is difficult to promote the use of with the modified polyvinyl alcohol, disappeares in market at present.
The object of the present invention is to provide a kind of color inner wall decorating material, it not only has good abrasion resistance and water tolerance, and outside the high characteristics of cohesive strength, and collection putty and coating are one, only need once smear and to finish construction, and can not cause be full of cracks and color grow diming phenomenon.
The object of the present invention is achieved like this: a kind of color inner wall decorating material, it comprises water-fast PVA glue, dispersion agent, thickening material, auxiliary agent, filler and the mill base that polyvinyl alcohol modification is made, it is characterized in that described water-fast PVA glue is is 10% polyvinyl alcohol water solution through grey calcium powder and the crosslinked concentration of TS-604A superpolymer linking agent, the consumption of grey calcium powder and TS-604A respectively is: with concentration is that 10% polyvinyl alcohol water solution is counted 0.2-1%; Described dispersion agent is that concentration is 10% sodium hexametaphosphate solution and DA dispersion agent; Described auxiliary agent is a treated carbonates; Described thickening material is that concentration is 1.5% carboxymethyl cellulose aqueous solution; Described filler is calcite in powder and zinc sulfide white; The weight percent of described each component is as follows:
Water-fast PVA glue 15～23% treated carbonatess 8～15%
10% sodium hexametaphosphate solution 4～1 0% calcite in powder 38～45%
DA dispersion agent 0.5～1.5% moral powder 6～12%
1.5% carboxymethyl cellulose aqueous solution, 8～15% mill base trace
Above-mentioned color inner wall decorating material is characterized in that: described calcite in powder can substitute with talcum powder, water-ground limestone, wollastonite powder or the kaolin of equivalent.
The present invention compares with existing various interior wall coatings, has following advantage:
1. the present invention is a kind of thick coating, and it has the effect of putty concurrently.Therefore before smearing, needn't beat greasy operation to interior wall.And only need once smear and to finish construction.So easy construction, the duration is short.
2. not existing thick coating needs base-material and the now with the current trouble of auxiliary material two-pack, does not make the waste of toing many or too much for use and causing after also now not joining simultaneously.
3. abrasion resistance doubles, and reaches more than 2000 times.
4. water tolerance improves a lot, and sample is through water logging bubble no change still after half a year; And cohesive force is strong.The working life of coating is long.
5. as the water-fast PVA glue dry film of base-material intensity height not only, and softness has certain toughness, so coating can not ftracture.
6. mill base can be evenly dispersed in the whole coating, can make the coating of various colors, and needn't worry the grow diming phenomenon of coating.
7. starting material are easy to get, easily manufactured, low price, and price is 1/4～1/8 of general coating only at 5～5.5 yuan/kg.
As base-material of the present invention---the making processes of water-fast PVA glue is: earlier be that 1799 or 1899 polyvinyl alcohol (PVA) is dissolved in the hot water with model, make concentration and be 10% polyvinyl alcohol water solution.After treating that this polyvinyl alcohol water solution is cooled to 50 ℃, successively add weight more respectively and respectively be 0.2～1% grey calcium powder and TS-604A superpolymer linking agent (low-molecular-weight polypropylene acid, Tianjin Chemical Research ﹠ Desing Inst Treatment of Industrial Water Engineering Technical Research Centre is produced) and carry out crosslinking reaction.Question response is stirred to cooling after fully.Mill base in the batching is the aqueous solution of pigment of all kinds.
Below be several batching embodiment of the present invention.
Embodiment 1.
Water-fast PVA glue 23% treated carbonates 8%
10% sodium hexametaphosphate solution, 4% calcite in powder 38%
DA dispersion agent 0.5% zinc sulfide white 11.5%
The 1.5% carboxyl methylcellulose aqueous solution, 15% mill base trace
With above-mentioned each component mix product.
Embodiment 2.
Water-fast PVA glue 15% treated carbonates 13.5%
10% sodium hexametaphosphate solution, 10% calcite in powder 40%
DA dispersion agent 1.5% zinc sulfide white 12%
1.5% carboxymethyl cellulose aqueous solution, 8% mill base trace
With above-mentioned each component mix product.
Embodiment 3.
Water-fast PVA glue 15% treated carbonates 15%
10% sodium hexametaphosphate solution, 6% calcite in powder 45%
DA dispersion agent 1% zinc sulfide white 10%
1.5% carboxymethyl cellulose aqueous solution, 8% mill base trace
With above-mentioned each component stir mix product.
Water-fast PVA glue 20% treated carbonates 10%
10% sodium hexametaphosphate solution, 8% calcite in powder 44%
DA dispersion agent 1% zinc sulfide white 6%
1.5% carboxymethyl cellulose aqueous solution, 11% mill base trace
With above-mentioned each component mix product.
Calcite in powder in the various embodiments described above can be used the talcum powder of equivalent, and water-ground limestone, wollastonite powder or kaolin substitute, but is the best with the calcite in powder.
Claims (2)
1, a kind of color inner wall decorating coating, it comprises water-fast PVA glue, dispersion agent, auxiliary agent, thickening material, filler and the mill base that polyvinyl alcohol modification is made, it is characterized in that described water-fast PVA glue is is 10% polyvinyl alcohol water solution through grey calcium powder and the crosslinked concentration of TS-604A superpolymer linking agent, the consumption of grey calcium powder and TS-604A respectively is: with concentration is that 10% polyvinyl alcohol water solution is counted 0.2-1%; Described dispersion agent is that concentration is 10% sodium hexametaphosphate solution and DA dispersion agent; Described auxiliary agent is a treated carbonates; Described thickening material is that concentration is 1.5% carboxymethyl cellulose aqueous solution; Described filler is calcite in powder and zinc sulfide white; The weight percent of described each component is as follows:
Water-fast PVA glue 15～23% treated carbonatess 8～15%
10% sodium hexametaphosphate solution, 4～10% calcite in powder 38～45%
DA dispersion agent 0.5～1.5% zinc sulfide white 6～12%
1.5% carboxymethyl cellulose aqueous solution, 8～15% mill base trace
2, color inner wall decorating coating according to claim 1 is characterized in that: described calcite in powder can substitute with talcum powder, water-ground limestone, wollastonite powder or the kaolin of equivalent.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNB991240677A CN1147547C (en) | 1999-11-23 | 1999-11-23 | Color inner wall decorating material |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNB991240677A CN1147547C (en) | 1999-11-23 | 1999-11-23 | Color inner wall decorating material |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN1258704A CN1258704A (en) | 2000-07-05 |
| CN1147547C true CN1147547C (en) | 2004-04-28 |
Family
ID=5283163
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CNB991240677A Expired - Lifetime CN1147547C (en) | 1999-11-23 | 1999-11-23 | Color inner wall decorating material |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN1147547C (en) |
Families Citing this family (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| SE524117C2 (en) * | 2002-01-25 | 2004-06-29 | Pergo Ab | Procedure for sealing a joint |
| CN101628795B (en) * | 2008-07-18 | 2012-07-04 | 崔光宗 | Environment-friendly active carbon decorating material |
-
1999
- 1999-11-23 CN CNB991240677A patent/CN1147547C/en not_active Expired - Lifetime
Also Published As
| Publication number | Publication date |
|---|---|
| CN1258704A (en) | 2000-07-05 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C06 | Publication | ||
| PB01 | Publication | ||
| ASS | Succession or assignment of patent right |
Owner name: SHANGHAI QIAOMAO BUILDING WATERPROOF MATERIAL CO. Free format text: FORMER OWNER: JINSHAN QIAOMAO COMPREHENSIVE ENGINEERING CO., LTD., SHANGHAI Effective date: 20020726 |
|
| C41 | Transfer of patent application or patent right or utility model | ||
| TA01 | Transfer of patent application right |
Effective date of registration: 20020726 Address after: 201508 No. 985 Hongqi Road West, Shanyang Town, Shanghai, Jinshan District Applicant after: Qiaomao Building Waterproof Materials Co., Ltd., Shanghai Address before: 201508, 1208, 71 village, Hongqi Road, Shanyang Town, Shanghai, Jinshan District Applicant before: Jinshan Qiaomao Comprehensive Engineering Co., Ltd., Shanghai |
|
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| ASS | Succession or assignment of patent right |
Owner name: ZHONGDA CONSTRUCTION GROUP CO., LTD. Free format text: FORMER OWNER: SHANGHAI QIAOMAO WATERPROOF BUILDING MATERIALS CO., LTD. Effective date: 20090522 |
|
| C41 | Transfer of patent application or patent right or utility model | ||
| TR01 | Transfer of patent right |
Effective date of registration: 20090522 Address after: 8 floor, building A, Lianhua Plaza, Hongqiao, Wuzhong Road, Shanghai 1050, China Patentee after: Zhongda Construction Group Co.,Ltd. Address before: No. 985 Hongqi Road West, Shanyang Town, Shanghai, Jinshan District Patentee before: Qiaomao Building Waterproof Materials Co., Ltd., Shanghai |
|
| CX01 | Expiry of patent term |
Granted publication date: 20040428 |
|
| CX01 | Expiry of patent term | ||
| DD01 | Delivery of document by public notice | ||
| DD01 | Delivery of document by public notice |
Addressee: Zhongda Construction Group Co.,Ltd. Document name: Notification of Expiration of Patent Right Duration |