CN114736997B - Manufacturing process of beach sheep fur - Google Patents

Manufacturing process of beach sheep fur Download PDF

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Publication number
CN114736997B
CN114736997B CN202210296161.4A CN202210296161A CN114736997B CN 114736997 B CN114736997 B CN 114736997B CN 202210296161 A CN202210296161 A CN 202210296161A CN 114736997 B CN114736997 B CN 114736997B
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China
Prior art keywords
beach
skin
wool
manufacturing
fur
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CN114736997A (en
Inventor
马兴祥
马明军
马亮
马海楠
马芮
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Qingtongxia Xiangyun fur And Leather Co ltd
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Qingtongxia Xiangyun fur And Leather Co ltd
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    • CCHEMISTRY; METALLURGY
    • C14SKINS; HIDES; PELTS; LEATHER
    • C14CCHEMICAL TREATMENT OF HIDES, SKINS OR LEATHER, e.g. TANNING, IMPREGNATING, FINISHING; APPARATUS THEREFOR; COMPOSITIONS FOR TANNING
    • C14C1/00Chemical treatment prior to tanning
    • C14C1/08Deliming; Bating; Pickling; Degreasing
    • CCHEMISTRY; METALLURGY
    • C14SKINS; HIDES; PELTS; LEATHER
    • C14CCHEMICAL TREATMENT OF HIDES, SKINS OR LEATHER, e.g. TANNING, IMPREGNATING, FINISHING; APPARATUS THEREFOR; COMPOSITIONS FOR TANNING
    • C14C1/00Chemical treatment prior to tanning
    • C14C1/04Soaking
    • CCHEMISTRY; METALLURGY
    • C14SKINS; HIDES; PELTS; LEATHER
    • C14CCHEMICAL TREATMENT OF HIDES, SKINS OR LEATHER, e.g. TANNING, IMPREGNATING, FINISHING; APPARATUS THEREFOR; COMPOSITIONS FOR TANNING
    • C14C11/00Surface finishing of leather
    • C14C11/003Surface finishing of leather using macromolecular compounds
    • CCHEMISTRY; METALLURGY
    • C14SKINS; HIDES; PELTS; LEATHER
    • C14CCHEMICAL TREATMENT OF HIDES, SKINS OR LEATHER, e.g. TANNING, IMPREGNATING, FINISHING; APPARATUS THEREFOR; COMPOSITIONS FOR TANNING
    • C14C3/00Tanning; Compositions for tanning
    • C14C3/02Chemical tanning
    • C14C3/04Mineral tanning
    • C14C3/06Mineral tanning using chromium compounds
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P60/00Technologies relating to agriculture, livestock or agroalimentary industries
    • Y02P60/80Food processing, e.g. use of renewable energies or variable speed drives in handling, conveying or stacking
    • Y02P60/87Re-use of by-products of food processing for fodder production

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  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Treatment And Processing Of Natural Fur Or Leather (AREA)

Abstract

The invention relates to a manufacturing process of beach sheep fur, which comprises the following steps: (1) selecting materials; (2) pretreatment; (3) degreasing; (4) pickling; (5) tanning; and (6) finishing. Because the beach sheep fur is treated by the oxidant under the acidic condition, scales on wool can be removed, the wool is treated by the anti-felting resin, the difference between the forward friction coefficient and the reverse friction coefficient of the wool scales becomes small, and the migration from the tip to the root of the wool is stopped, so that the anti-felting effect is obtained.

Description

Manufacturing process of beach sheep fur
Technical Field
The invention relates to the technical field of leather processing, in particular to a manufacturing process of beach sheep fur.
Background
The tanning industry in China plays a role in underestimating the export foreign exchange, enriching the market of urban commodity and developing the economy of rural pasture areas. The Tan sheep skin is commonly called as 'Bai Bao' in Ningxia wubao, is well known as 'light, warm and beautiful', and the skin is plump Mao Sui and naturally stranded, has the bending degree as high as nine times, is deeply favored by domestic and foreign customers, and is an unique livestock production resource in Ningxia regions.
Wool of the beach sheep is similar to wool of other varieties, and scales are grown on the surface layer. The kurtosis of each scale points to the tip of the fiber. This is why beach wool rolls out the felt. Once the beach fur is rolled in the processing and wearing processes, the quality and the appearance of the product can be affected, and the warmth retention property of the fur garment can be reduced.
Disclosure of Invention
The invention aims to solve the technical problems and provide a manufacturing process of beach sheep fur, which can remove scales on wool by treating the wool with an oxidant under an acidic condition, and treat the wool with anti-felt resin, wherein the difference between forward and reverse friction coefficients of the scales becomes very small, and migration from a tip to a root of the wool is stopped, so that an anti-felt rolling effect is obtained.
In order to achieve the above purpose, the invention adopts the following technical scheme:
a manufacturing process of beach sheep fur is characterized in that: the method comprises the following steps:
(1) Selecting materials: selecting a beach sheepskin with beach wool, wherein the length of the beach sheepskin is 55-70 mm;
(2) Pretreatment: soaking the Tan sheep skin in 3% sodium chloride solution for 120 min, taking out, washing with clear water, and finally drying the Tan sheep skin at 20-30 ℃;
(3) Degreasing: placing the Chan sheep skin into warm water at 40-45 ℃, adding a degreasing agent into the warm water, stirring for 5 minutes in a rotating way, soaking for 3 hours, taking out, and cleaning with clear water;
(4) Pickling: putting the Chan sheep skin into a blended pickling solution, adding an oxidant, stirring for 5 minutes in a rotating way, soaking for 5 hours, keeping the blended pH value at 5.7-6.5, taking out, cleaning with clear water, and drying at a low temperature of 25-35 ℃;
(5) Tanning: putting the Chan sheep skin into a blending tanning solution, stirring for 5 minutes in a rotating way, soaking for 3 hours, taking out, cleaning with clear water, and drying at a low temperature of 23-28 ℃;
(6) And (3) finishing: and (3) treating wool on the Tan sheep skin by using anti-sticking resin, and then performing natural drying and then finishing and warehousing.
Further, the wool length of the Tan sheep skin selected in the step (1) is 62 mm.
Further, in the step (2), the Channa Argus skin is dried at a low temperature of 25 ℃.
Further, the degreasing agent AP-degreasing agent in the step (3).
Further, a bacitracin agent is added in the step (4).
Further, the prepared pickling solution in the step (4) is prepared by taking hydrochloric acid, industrial salt and water=2:3:5 according to the weight.
Further, the pH is adjusted to be kept at 6.1 in the step (4).
Further, in the step (4), the Channa Argus skin is dried at a low temperature of 30 ℃.
Further, the blending tanning solution in the step (5) is prepared by taking chromium-aluminum composite tanning agent, sodium carbonate and water according to the weight parts, wherein the ratio of the sodium carbonate to the water is 1:11:700.
Further, in the step (5), the Channa Argus skin is dried at a low temperature of 26 ℃.
Compared with the prior art, the invention has the following beneficial effects:
according to the invention, the beach sheep fur is treated by the oxidant under the acidic condition, scales on wool can be removed, the wool is treated by the anti-felt resin, the difference between forward and reverse friction coefficients of the scales becomes small, and the migration from the tip to the root of the wool can be stopped, so that the anti-felt rolling effect is obtained.
Detailed Description
The present invention will be described in further detail with reference to the following examples, for the purpose of making the objects, technical solutions and advantages of the present invention more apparent, and the description thereof is merely illustrative of the present invention and not intended to be limiting.
In the description of the present invention, it should also be noted that, unless explicitly specified and limited otherwise, the terms "disposed," "mounted," "connected," and "connected" are to be construed broadly, and may be, for example, fixedly connected, detachably connected, or integrally connected; can be mechanically or electrically connected; can be directly connected or indirectly connected through an intermediate medium, and can be communication between two elements. The specific meaning of the above terms in the present invention will be understood in specific cases by those of ordinary skill in the art.
The present invention will be described in detail below.
Example 1
A manufacturing process of beach sheep fur comprises the following steps:
(1) Selecting materials: selecting a beach sheepskin with beach wool, wherein the length of the wool of the beach sheepskin is 55 mm;
(2) Pretreatment: soaking the Chao sheep skin in 3% sodium chloride solution for 120 min, taking out, washing with clear water, and oven drying at 20deg.C;
(3) Degreasing: placing the Chan sheep skin into warm water at 40-45 ℃, adding a degreasing agent into the warm water, stirring for 5 minutes in a rotating way, soaking for 3 hours, taking out, and cleaning with clear water;
(4) Pickling: adding the Channa Argus skin into an pickling solution prepared by taking hydrochloric acid, industrial salt and water according to the weight ratio of 2:3:5, adding an oxidant, stirring for 5 minutes in a rotating way, soaking for 5 hours, regulating the pH value to be 5.7, taking out, cleaning with clear water, and drying at a low temperature of 25 ℃;
(5) Tanning: putting the Chan sheep skin into tanning solution prepared by taking chromium-aluminum compound tanning agent, sodium carbonate and water=1:11:700 according to parts by weight, stirring for 5 minutes in a rotating way, soaking for 3 hours, taking out, cleaning with clear water, and drying at a low temperature of 23 ℃;
(6) And (3) finishing: and (3) treating wool on the Tan sheep skin by using anti-sticking resin, and then performing natural drying and then finishing and warehousing.
According to the invention, the beach sheep fur is treated by the oxidant under the acidic condition, scales on wool can be removed, the wool is treated by the anti-felt resin, the difference between forward and reverse friction coefficients of the scales becomes small, and the migration from the tip to the root of the wool can be stopped, so that the anti-felt rolling effect is obtained.
Example 2
A manufacturing process of beach sheep fur comprises the following steps:
(1) Selecting materials: selecting a beach sheepskin with beach wool, wherein the length of the beach wool is 62 mm;
(2) Pretreatment: soaking the Chao sheep skin in 3% sodium chloride solution for 120 min, taking out, washing with clear water, and oven drying at 25deg.C;
(3) Degreasing: placing the Chan sheep skin into warm water at 40-45 ℃, adding a degreasing agent into the warm water, stirring for 5 minutes in a rotating way, soaking for 3 hours, taking out, and cleaning with clear water;
(4) Pickling: adding the Chan sheep skin into an pickling solution prepared by taking hydrochloric acid, industrial salt and water according to the weight ratio of 2:3:5, adding an oxidant, stirring for 5 minutes in a rotating way, soaking for 5 hours, regulating the pH value to be 6.1 all the time, taking out, cleaning with clear water, and drying at a low temperature of 30 ℃;
(5) Tanning: putting the Chan sheep skin into tanning solution prepared by taking chromium-aluminum compound tanning agent, sodium carbonate and water=1:11:700 according to parts by weight, stirring for 5 minutes in a rotating way, soaking for 3 hours, taking out, cleaning with clear water, and drying at a low temperature of 26 ℃;
(6) And (3) finishing: and (3) treating wool on the Tan sheep skin by using anti-sticking resin, and then performing natural drying and then finishing and warehousing.
Example 3
A manufacturing process of beach sheep fur comprises the following steps:
(1) Selecting materials: selecting a beach sheepskin with beach wool, wherein the length of the beach wool is 55-70 mm;
(2) Pretreatment: soaking the Chao sheep skin in 3% sodium chloride solution for 120 min, taking out, washing with clear water, and oven drying at 30deg.C;
(3) Degreasing: placing the Chan sheep skin into warm water at 40-45 ℃, adding a degreasing agent into the warm water, stirring for 5 minutes in a rotating way, soaking for 3 hours, taking out, and cleaning with clear water;
(4) Pickling: adding the Chan sheep skin into an pickling solution prepared by taking hydrochloric acid, industrial salt and water according to the weight ratio of 2:3:5, adding an oxidant, stirring for 5 minutes in a rotating way, soaking for 5 hours, regulating the pH value to be 6.5 all the time, taking out, cleaning with clear water, and drying at a low temperature of 35 ℃;
(5) Tanning: putting the Chan sheep skin into tanning solution prepared by taking chromium-aluminum compound tanning agent, sodium carbonate and water=1:11:700 according to parts by weight, stirring for 5 minutes in a rotating way, soaking for 3 hours, taking out, cleaning with clear water, and drying at a low temperature of 28 ℃;
(6) And (3) finishing: and (3) treating wool on the Tan sheep skin by using anti-sticking resin, and then performing natural drying and then finishing and warehousing.
Sequence number Inspection item Unit (B) Technical requirements Actual measurement value Determination of
1 Peculiar smell Without any means for Without any means for Qualified product
2 pH value of 3.8~6.4 5.7 Qualified product
3 Mao length of ≥9 13 Qualified product
4 Mao flower bend Personal (S) ≥6 10 Qualified product
5 Density of wool quilt Root/[ Y ], ≥1500 1937 qualified product
6 Formaldehyde content mg/㎏ ≤300 58 Qualified product
7 Elongation under load % ≥20 23 Qualified product
8 Tearing force N ≥9 35 Qualified product
9 Appearance quality Without any means for Without any means for Qualified product
According to the table above, the beach fur obtained in all the examples in the invention completely meets the national standard GB/T2033-2008.
There are, of course, many other embodiments of the invention that can be made by those skilled in the art in light of the above teachings without departing from the spirit or essential scope thereof and that such modifications and variations are intended to be included within the scope of the invention as defined in the following claims.

Claims (8)

1. A manufacturing process of beach sheep fur is characterized in that: the method comprises the following steps:
(1) Selecting materials: selecting a beach sheepskin with beach wool, wherein the length of the beach sheepskin is 55-70 mm;
(2) Pretreatment: soaking the Tan sheep skin in 3% sodium chloride solution for 120 min, taking out, washing with clear water, and finally drying the Tan sheep skin at 20-30 ℃;
(3) Degreasing: placing the Chan sheep skin into warm water at 40-45 ℃, adding a degreasing agent into the warm water, stirring for 5 minutes in a rotating way, soaking for 3 hours, taking out, and cleaning with clear water;
(4) Pickling: putting the Chan sheep skin into a blended pickling solution, adding an oxidant, stirring for 5 minutes in a rotating way, soaking for 5 hours, keeping the blended pH value at 5.7-6.5 all the time, taking out, cleaning with clear water, and drying at a low temperature of 25-35 ℃;
(5) Tanning: putting the Chan sheep skin into a blending tanning solution, stirring for 5 minutes in a rotating way, soaking for 3 hours, taking out, cleaning with clear water, and drying at a low temperature of 23-28 ℃;
(6) And (3) finishing: treating wool on the Tan sheep skin by using anti-sticking resin, and then naturally drying and then finishing and warehousing;
the prepared pickling solution in the step (4) is prepared by taking hydrochloric acid, industrial salt and water=2:3:5 according to the weight ratio;
the blending tanning solution in the step (5) is prepared by taking chromium-aluminum composite tanning agent, sodium carbonate and water=1:11:700 according to parts by weight.
2. The process for manufacturing beach fur according to claim 1, wherein: the wool length of the Tan sheep skin selected in the step (1) is 62 mm.
3. The process for manufacturing beach fur according to claim 1, wherein: and (3) in the step (2), the Channa Argus skin is dried at a low temperature of 25 ℃.
4. The process for manufacturing beach fur according to claim 1, wherein: the degreasing agent AP-degreasing agent in the step (3).
5. The process for manufacturing beach fur according to claim 1, wherein: the step (4) is added with a bacitracin reagent.
6. The process for manufacturing beach fur according to claim 1, wherein: the pH of the formulation in step (4) was kept at 6.1 at all times.
7. The process for manufacturing beach fur according to claim 1, wherein: and (3) in the step (4), the Channa Argus skin is dried at a low temperature of 30 ℃.
8. The process for manufacturing beach fur according to claim 1, wherein: and (3) in the step (5), the Channa Argus skin is dried at a low temperature of 26 ℃.
CN202210296161.4A 2022-03-24 2022-03-24 Manufacturing process of beach sheep fur Active CN114736997B (en)

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Application Number Priority Date Filing Date Title
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CN114736997B true CN114736997B (en) 2023-08-25

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Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107267693A (en) * 2017-08-15 2017-10-20 宁夏成丰农业科技开发股份有限公司 A kind of improved tibet lamp process for tanning
CN108774649A (en) * 2018-07-04 2018-11-09 宁夏吴忠市精艺裘皮制品有限公司 A kind of tibet lamp is without aldehyde chromium-free environment-friendly process for tanning
CN112941248A (en) * 2021-02-01 2021-06-11 辛集市梅花皮业有限公司 Sheep fur leather and processing technology of chrome-free tanning thereof

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107267693A (en) * 2017-08-15 2017-10-20 宁夏成丰农业科技开发股份有限公司 A kind of improved tibet lamp process for tanning
CN108774649A (en) * 2018-07-04 2018-11-09 宁夏吴忠市精艺裘皮制品有限公司 A kind of tibet lamp is without aldehyde chromium-free environment-friendly process for tanning
CN112941248A (en) * 2021-02-01 2021-06-11 辛集市梅花皮业有限公司 Sheep fur leather and processing technology of chrome-free tanning thereof

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