CN114736638A - Ultra-bright bi-component epoxy seam beautifying agent - Google Patents
Ultra-bright bi-component epoxy seam beautifying agent Download PDFInfo
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- CN114736638A CN114736638A CN202210284971.8A CN202210284971A CN114736638A CN 114736638 A CN114736638 A CN 114736638A CN 202210284971 A CN202210284971 A CN 202210284971A CN 114736638 A CN114736638 A CN 114736638A
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- 239000003795 chemical substances by application Substances 0.000 title claims abstract description 26
- 239000004593 Epoxy Substances 0.000 title claims abstract description 15
- 239000002994 raw material Substances 0.000 claims abstract description 20
- -1 modified alicyclic amine Chemical class 0.000 claims abstract description 19
- 239000003085 diluting agent Substances 0.000 claims abstract description 18
- 239000003822 epoxy resin Substances 0.000 claims abstract description 17
- 229920000647 polyepoxide Polymers 0.000 claims abstract description 17
- 239000013008 thixotropic agent Substances 0.000 claims abstract description 13
- ZBCBWPMODOFKDW-UHFFFAOYSA-N diethanolamine Chemical compound OCCNCCO ZBCBWPMODOFKDW-UHFFFAOYSA-N 0.000 claims abstract description 10
- 239000002518 antifoaming agent Substances 0.000 claims abstract description 8
- 238000002156 mixing Methods 0.000 claims description 13
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 claims description 9
- 238000002360 preparation method Methods 0.000 claims description 9
- LRHPLDYGYMQRHN-UHFFFAOYSA-N N-Butanol Chemical compound CCCCO LRHPLDYGYMQRHN-UHFFFAOYSA-N 0.000 claims description 6
- IISBACLAFKSPIT-UHFFFAOYSA-N bisphenol A Chemical compound C=1C=C(O)C=CC=1C(C)(C)C1=CC=C(O)C=C1 IISBACLAFKSPIT-UHFFFAOYSA-N 0.000 claims description 6
- PXKLMJQFEQBVLD-UHFFFAOYSA-N bisphenol F Chemical compound C1=CC(O)=CC=C1CC1=CC=C(O)C=C1 PXKLMJQFEQBVLD-UHFFFAOYSA-N 0.000 claims description 6
- 238000007789 sealing Methods 0.000 claims description 6
- 238000005303 weighing Methods 0.000 claims description 6
- 150000001412 amines Chemical class 0.000 claims description 4
- 235000010290 biphenyl Nutrition 0.000 claims description 4
- 239000004305 biphenyl Substances 0.000 claims description 4
- ZUOUZKKEUPVFJK-UHFFFAOYSA-N phenylbenzene Natural products C1=CC=CC=C1C1=CC=CC=C1 ZUOUZKKEUPVFJK-UHFFFAOYSA-N 0.000 claims description 4
- VILCJCGEZXAXTO-UHFFFAOYSA-N 2,2,2-tetramine Chemical compound NCCNCCNCCN VILCJCGEZXAXTO-UHFFFAOYSA-N 0.000 claims description 3
- DLYLVPHSKJVGLG-UHFFFAOYSA-N 4-(cyclohexylmethyl)cyclohexane-1,1-diamine Chemical compound C1CC(N)(N)CCC1CC1CCCCC1 DLYLVPHSKJVGLG-UHFFFAOYSA-N 0.000 claims description 3
- RPNUMPOLZDHAAY-UHFFFAOYSA-N Diethylenetriamine Chemical compound NCCNCCN RPNUMPOLZDHAAY-UHFFFAOYSA-N 0.000 claims description 3
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 claims description 3
- 239000004721 Polyphenylene oxide Substances 0.000 claims description 3
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 3
- 229910021485 fumed silica Inorganic materials 0.000 claims description 3
- NAQMVNRVTILPCV-UHFFFAOYSA-N hexane-1,6-diamine Chemical compound NCCCCCCN NAQMVNRVTILPCV-UHFFFAOYSA-N 0.000 claims description 3
- 229910002011 hydrophilic fumed silica Inorganic materials 0.000 claims description 3
- 230000002209 hydrophobic effect Effects 0.000 claims description 3
- 239000000155 melt Substances 0.000 claims description 3
- WVDDGKGOMKODPV-ZQBYOMGUSA-N phenyl(114C)methanol Chemical compound O[14CH2]C1=CC=CC=C1 WVDDGKGOMKODPV-ZQBYOMGUSA-N 0.000 claims description 3
- 229920000768 polyamine Polymers 0.000 claims description 3
- 229920000570 polyether Polymers 0.000 claims description 3
- 238000004321 preservation Methods 0.000 claims description 3
- 230000035484 reaction time Effects 0.000 claims description 3
- 229960001124 trientine Drugs 0.000 claims description 3
- 239000008096 xylene Substances 0.000 claims description 3
- 238000004519 manufacturing process Methods 0.000 abstract description 2
- 239000003292 glue Substances 0.000 description 21
- 239000000919 ceramic Substances 0.000 description 8
- 238000007599 discharging Methods 0.000 description 8
- 239000000945 filler Substances 0.000 description 3
- 230000005540 biological transmission Effects 0.000 description 2
- 239000004568 cement Substances 0.000 description 2
- 238000010276 construction Methods 0.000 description 2
- 239000000203 mixture Substances 0.000 description 2
- 238000012856 packing Methods 0.000 description 2
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 description 1
- 239000003086 colorant Substances 0.000 description 1
- 238000005034 decoration Methods 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 239000012530 fluid Substances 0.000 description 1
- 239000002932 luster Substances 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 239000011159 matrix material Substances 0.000 description 1
- 238000004806 packaging method and process Methods 0.000 description 1
- 229910052573 porcelain Inorganic materials 0.000 description 1
- 238000003825 pressing Methods 0.000 description 1
- 229910052709 silver Inorganic materials 0.000 description 1
- 239000004332 silver Substances 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
Images
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J163/00—Adhesives based on epoxy resins; Adhesives based on derivatives of epoxy resins
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G59/00—Polycondensates containing more than one epoxy group per molecule; Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups
- C08G59/18—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing
- C08G59/40—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing characterised by the curing agents used
- C08G59/50—Amines
- C08G59/5006—Amines aliphatic
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G59/00—Polycondensates containing more than one epoxy group per molecule; Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups
- C08G59/18—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing
- C08G59/40—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing characterised by the curing agents used
- C08G59/50—Amines
- C08G59/5026—Amines cycloaliphatic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
- C09J11/02—Non-macromolecular additives
- C09J11/04—Non-macromolecular additives inorganic
Abstract
The invention provides an ultra-bright bi-component epoxy seam beautifying agent, which comprises a component A and a component B; the component A comprises the following raw materials in parts by mass: 90-95 parts of epoxy resin, 5-9 parts of diluent, 0.01-0.03 part of defoaming agent and 3-8 parts of thixotropic agent; the component B comprises the following raw materials in parts by mass: 10-15 parts of modified alicyclic amine curing agent, 10-12 parts of aliphatic amine, 30-50 parts of diluent, 0.01-0.03 part of defoaming agent, 3-6 parts of thixotropic agent and 10-25 parts of accelerator; the mass ratio of the component A to the component B is 1: 1-1.15. After the invention is adopted, the secondary pollution which possibly occurs in the production process is effectively reduced.
Description
Technical Field
The invention relates to the technical field of glue, in particular to an ultra-bright bi-component epoxy seam beautifying agent.
Background
The crack sealer is an upgraded product of the crack sealer, the decorative practicability of the crack sealer is obviously superior to that of a color crack sealer, and the problems of unattractive gaps, dirty and black gaps and the like of the ceramic tiles are solved. The crack beautifying agent can be directly added into the gaps of the ceramic tiles after the ceramic tiles are bonded. The filling agent is suitable for filling gaps with the thickness of more than 2mm, is more convenient than the common filling agent in construction, and is an upgrading and updating product of the filling agent. The joint beautifying agent has luster after construction, rich, natural and fine colors, such as golden color, silver color, pearly color and the like, and the white and black chromaticities are obviously higher than those of white cement and a color joint mixture, so that the joint beautifying agent brings better integral effect to the wall surface, and the decoration property is greatly stronger than that of the white cement and the color joint mixture. And after the ceramic tile is solidified, the surface is smooth like porcelain, the ceramic tile can be scrubbed together with the ceramic tile, and the ceramic tile has the characteristics of permeation resistance and water resistance, so that the real ceramic tile gap can never become black. Traditional beautiful seam agent is arranged by gluey bottle conveyer trough and is carried backward after the filling, picks up the bottle lid through the manipulator and detains on the bottle, and the workman stands in the conveyer trough both sides, and handheld electric drill screws the bottle lid through the spiral cover head, and this kind of mode intensity of labour is big, and is efficient, and the elasticity degree of bottle lid is inconsistent simultaneously.
Disclosure of Invention
The invention aims to overcome the defects of the prior art and provide the ultra-bright bi-component epoxy seam beautifying agent which has high brightness and good weather resistance and effectively reduces the possible secondary pollution in the production process.
In order to achieve the purpose, the technical scheme provided by the invention is as follows: an ultra-bright bi-component epoxy seam beautifying agent comprises a component A and a component B;
the component A comprises the following raw materials in parts by mass: 90-95 parts of epoxy resin, 5-9 parts of diluent, 0.01-0.03 part of defoaming agent and 3-8 parts of thixotropic agent;
the component B comprises the following raw materials in parts by mass: 10-15 parts of modified alicyclic amine curing agent, 10-12 parts of aliphatic amine, 30-50 parts of diluent, 0.01-0.03 part of defoaming agent, 3-6 parts of thixotropic agent and 10-25 parts of accelerator;
the mass ratio of the component A to the component B is 1: 1-1.15.
The preparation method of the modified alicyclic amine comprises the following steps:
controlling the vacuum degree to be-0.1 MPa, and mixing 3, 3-dimethyl-4, 4-diaminodicyclohexyl methane and biphenyl dichlorobenzyl according to a molar ratio of 1: 1.2-1.5, the reaction temperature is 105 ℃, the reaction time is 5-8h, and the heat preservation is carried out for 1h, so as to obtain the modified alicyclic amine.
The epoxy resin is bisphenol A type epoxy resin, bisphenol F type epoxy resin or a combination thereof.
The diluent is at least one of benzyl alcohol, toluene, xylene and n-butanol.
The alicyclic amine curing agent is at least one of 3, 3-dimethyl-4, 4-diaminodicyclohexyl methane, 4' -diaminodicyclohexyl methane and 1, 6-diaminohexane.
The aliphatic amine curing agent is at least one of polyether amine, diethylenetriamine, triethylene tetramine and polyamine.
The thixotropic agent is at least one of hydrophilic fumed silica and hydrophobic fumed silica.
The preparation method comprises the following steps:
1) and preparation of the component A: weighing the raw materials according to the mass parts, fully mixing the epoxy resin and the diluent for 2 hours, adding the rest raw materials, and uniformly mixing to obtain a component A:
2) and preparing a component B: weighing raw materials according to the mass parts, fully mixing the modified alicyclic amine curing agent, the aliphatic amine and the diluent, and then adding other raw materials to be uniformly mixed to obtain a component B;
3) respectively pouring the component A and the component B into corresponding filling machines, and respectively filling the component A and the component B into corresponding rubber cylinders of rubber bottles through filling heads;
4) sealing the filled rubber cylinder by a melt mouth machine;
5) after sealing, the rubber bottle is conveyed to a bottle guide rotary disc through a conveying belt bearing, and the rubber bottle to be capped is driven to travel through the bottle guide rotary disc to enter a cap screwing system;
6) and grabbing by a manipulator to buckle the bottle cap on the rubber bottle, screwing the bottle cap by a cap screwing unit, and finally leading out by a bottle arranging unit to obtain the rubber bottle cap.
After the scheme is adopted, the epoxy resin, the thixotropic agent and the diluent are matched to form a fluid base material of a component A of the seam beautifying agent, the modified alicyclic amine is formed through the reaction of 3, 3-dimethyl-4, 4-diaminodicyclohexylmethane and biphenyl dichlorobenzyl, the super-bright matrix of a component B is formed through the reaction of the modified alicyclic amine, the fatty amine and the thixotropic agent, and the super-bright seam beautifying agent is formed through the mixing of the component AB during use.
Drawings
Fig. 1 is a schematic view of the overall structure of the present invention.
Fig. 2 is a schematic structural view of the cap screwing unit of the present invention.
Fig. 3 is a schematic structural diagram of the bottle arranging unit of the invention.
FIG. 4 is a schematic view of a check plate structure of the present invention.
Detailed Description
The invention will be further described with reference to the accompanying drawings, in which preferred embodiments of the invention are: referring to fig. 1 to 4, the ultra-bright two-component epoxy crack sealer of the embodiment comprises a component a and a component B;
the component A comprises the following raw materials in parts by mass: 90-95 parts of epoxy resin, 5-9 parts of diluent, 0.01-0.03 part of defoaming agent and 3-8 parts of thixotropic agent;
the component B comprises the following raw materials in parts by mass: 10-15 parts of modified alicyclic amine curing agent, 10-12 parts of aliphatic amine, 30-50 parts of diluent, 0.01-0.03 part of defoaming agent, 3-6 parts of thixotropic agent and 10-25 parts of accelerator;
the mass ratio of the component A to the component B is 1: 1-1.15.
The preparation method of the modified alicyclic amine comprises the following steps:
controlling the vacuum degree to be-0.1 MPa, and mixing 3, 3-dimethyl-4, 4-diaminodicyclohexyl methane and biphenyl dichlorobenzyl according to a molar ratio of 1: 1.2-1.5, the reaction temperature is 105 ℃, the reaction time is 5-8h, and the heat preservation is carried out for 1h, so as to obtain the modified alicyclic amine.
The epoxy resin is bisphenol A type epoxy resin, bisphenol F type epoxy resin or a combination thereof.
The diluent is at least one of benzyl alcohol, toluene, xylene and n-butanol.
The alicyclic amine curing agent is at least one of 3, 3-dimethyl-4, 4-diaminodicyclohexyl methane, 4' -diaminodicyclohexyl methane and 1, 6-diaminohexane.
The aliphatic amine curing agent is at least one of polyether amine, diethylenetriamine, triethylene tetramine and polyamine.
The thixotropic agent is at least one of hydrophilic fumed silica and hydrophobic fumed silica.
The preparation method comprises the following steps:
1) and preparation of the component A: weighing the raw materials according to the mass parts, fully mixing the epoxy resin and the diluent for 2 hours, adding the rest raw materials, and uniformly mixing to obtain a component A:
2) and preparing a component B: weighing raw materials according to the mass parts, fully mixing the modified alicyclic amine curing agent, the aliphatic amine and the diluent, and then adding other raw materials to be uniformly mixed to obtain a component B;
3) respectively pouring the component A and the component B into corresponding filling machines, and respectively filling the component A and the component B into corresponding rubber cylinders of rubber bottles through filling heads;
4) sealing the filled rubber cylinder by a melt mouth machine;
5) after sealing, the rubber bottle is conveyed to a bottle guide turntable through a conveyer belt bearing, and the rubber bottle to be capped is driven by the bottle guide turntable to travel into a cap screwing system;
6) and the bottle cap is buckled on the rubber bottle by grabbing through the manipulator, the bottle cap is screwed through the cap screwing unit, and finally the bottle cap is led out through the bottle arranging unit, so that the rubber bottle is formed.
The cap screwing system comprises a bottle guiding rotary disc 202 and a limiting ring 205, wherein the bottle guiding rotary disc 202 is arranged on a workbench 203, a rotary disc motor is arranged in the workbench 203, a transmission shaft of the rotary disc motor is upwards connected with the bottom of the bottle guiding rotary disc 202, bottle guiding grooves 204 with the number larger than 4 are uniformly distributed at the edge of the bottle guiding rotary disc 202, the workbench 203 at the outer side of the bottle guiding rotary disc 202 is provided with the annular limiting ring 205, and the limiting ring 205 surrounds the outer side of the bottle guiding rotary disc 202; a bottle inlet is formed in one side of the limiting ring 205, a glue bottle conveying groove 206 is formed in the workbench 203 on the outer side of the bottle inlet, an outlet of the glue bottle conveying groove 206 is connected with the bottle inlet, a cap screwing unit is installed above the output direction of the glue bottle conveying groove 206, an inclined bottle outlet guide groove 207 is formed in the workbench 203 on the output direction of the cap screwing unit, one end of the bottle outlet guide groove 207 is located below the glue bottle conveying groove 206, the other end of the bottle outlet guide groove obliquely extends downwards out of the workbench to form a bottle outlet, and a bottle discharging unit is arranged on the outer side of the bottle outlet;
the bottle arranging unit comprises a bottle arranging box 215 and a bottle guide plate 216, wherein the bottle arranging box 215 is arranged on the ground outside a bottle outlet, the upper part of one side of the bottle arranging box 215 is connected with the bottle outlet, two bottle plate support rails are arranged in the bottle arranging box 215 below the bottle outlet, the length direction of each bottle plate support rail and the output direction of the bottle outlet guide groove 207 are in a cross shape, the bottle guide plate 216 is obliquely arranged on each bottle plate support rail, the oblique direction of the bottle guide plate 216 is consistent with the oblique direction of the bottle outlet guide groove 207, a push plate cylinder 217 is arranged in the bottle arranging box 215 at one end of each bottle plate support rail, a piston rod of the push plate cylinder 217 is connected with one end of the bottle guide plate 216, a bottle arranging outlet is arranged on the bottle arranging box 215 at the other end of the bottle guide plate 216, and a return stop plate 218 is movably hinged on the outer side wall of the bottle arranging box 215 above the bottle arranging outlet.
The cap screwing unit comprises a cap screwing lifting cylinder 208 arranged above the rubber bottle conveying groove 206, a cap screwing seat 209 is arranged at the bottom of the cap screwing lifting cylinder 208, a cap screwing motor 210 is arranged in the cap screwing seat 209, a transmission shaft of the cap screwing motor 210 is downwards connected with a cap screwing head 211, a bottle guide pressure plate 212 is arranged below the cap screwing head 211, a vertically upward limiting guide pillar 213 is arranged at the top of the bottle guide pressure plate 212, the top of the limiting guide pillar 213 upwards penetrates through the cap screwing seat 209 to be meshed with a guide pillar limiting nut, a guide pillar spring 214 is sleeved on the limiting guide pillar 213, the bottom of the guide pillar spring 214 is abutted against the top of the bottle guide pressure plate 212, and the top of the guide pillar spring 214 is abutted against the bottom of the cap screwing seat 209; a bottle body positioning groove which penetrates through the bottle body positioning groove from top to bottom is formed in the bottle guide pressing plate 212 which is arranged right below the cap screwing head 211, and a centering ring 219 which is small in top and large in bottom is arranged at the bottom of the cap screwing head 211 which is arranged on the outer side of the bottle body positioning groove.
When the device is used, the glue bottles are arranged and conveyed to the bottle guide rotating disc through the glue bottle conveying grooves and are blocked by the disc edge of the bottle guide rotating disc, the bottle guide rotating disc moves under the driving of the rotating disc motor (one station is formed when the bottle guide rotating disc moves every time), when the bottle guide groove is over against the glue bottles, the disc edge of the bottle guide rotating disc is not blocked, the glue bottles enter the bottle guide groove, the rotating disc motor drives the bottle guide rotating disc to move for one station, the bottle caps are buckled on the glue bottles through the mechanical arm, and the bottle guide rotating disc continues to move for one station to the position below the cap screwing unit after the bottle caps are buckled;
the cap screwing lifting cylinder drives the cap screwing base to descend, the cap screwing base synchronously drives the bottle guide pressure plate to descend, the bottle guide pressure plate is gradually contacted with the upper part of the rubber bottle, when the rubber bottle deviates, automatic centering is carried out under the action of a centering ring, finally the bottle guide pressure plate is pressed on the outer side of a bottle opening at the top of the rubber bottle (a guide pillar spring is stressed and compressed), the cap screwing base continuously descends and the cap screwing head starts to be contacted with the bottle cap, the cap screwing motor rotates to drive the cap screwing head to lock the bottle cap, and the cap screwing lifting cylinder drives the cap screwing base to ascend after locking is finished;
the packing box is placed outside the outlet of the bottle arrangement, after the glue bottles enter the bottle guide plate, the end part of the bottle guide plate in the direction of the push plate cylinder is bent upwards to form an anti-skidding limiting edge, the horizontal plane of the top of the anti-skidding limiting edge is lower than the horizontal plane of the bottom of the check plate, and the horizontal plane of the bottom of the check plate is lower than the horizontal plane of the top of the glue bottles;
the bottle guiding rotary table continuously travels a station to the position above the bottle discharging guide groove, the glue bottles fall into the bottle discharging guide groove under the self weight, the glue bottles fall onto the bottle guiding plate in the bottle discharging box under the guide of the bottle discharging guide groove, a piston rod of the push plate cylinder extends out to drive the bottle guiding plate to travel towards the direction of a bottle discharging outlet, when the bottle guiding plate penetrates through the bottle discharging outlet, the glue bottles push the check plate outwards and upwards, the check plate rotates outwards and upwards, the bottle guiding plate drives the glue bottles to penetrate through the bottle discharging outlet and enter the packaging box, and after the glue bottles penetrate through, the lower part of the check plate falls under the self weight;
the glue bottle is located the non return board outside, and the piston rod of push pedal cylinder contracts and drives and leads the bottle board, and the glue bottle is stopped by the non return board when following the bottle board and going back (non return board upper portion is spacing by row bottle case lateral wall above row bottle export), and the glue bottle no longer returns to row bottle incasement along with leading the bottle board, but gets into the packing box, accomplishes the vanning of glue bottle.
The above-mentioned embodiments are merely preferred embodiments of the present invention, and the scope of the present invention is not limited thereto, so that the changes in the shape and principle of the present invention should be covered within the protection scope of the present invention.
Claims (8)
1. An ultra-bright bi-component epoxy seam beautifying agent is characterized in that: it comprises a component A and a component B;
the component A comprises the following raw materials in parts by mass: 90-95 parts of epoxy resin, 5-9 parts of diluent, 0.01-0.03 part of defoaming agent and 3-8 parts of thixotropic agent;
the component B comprises the following raw materials in parts by mass: 10-15 parts of modified alicyclic amine curing agent, 10-12 parts of aliphatic amine, 30-50 parts of diluent, 0.01-0.03 part of defoaming agent, 3-6 parts of thixotropic agent and 10-25 parts of accelerator;
the mass ratio of the component A to the component B is 1: 1-1.15.
2. The ultra-bright two-component epoxy crack sealer as claimed in claim 1, wherein: the preparation method of the modified alicyclic amine comprises the following steps:
controlling the vacuum degree to be-0.1 MPa, and mixing 3, 3-dimethyl-4, 4-diaminodicyclohexyl methane and biphenyl dichlorobenzyl according to a molar ratio of 1: 1.2-1.5, the reaction temperature is 105 ℃, the reaction time is 5-8h, and the heat preservation is carried out for 1h, so as to obtain the modified alicyclic amine.
3. The ultra-bright two-component epoxy crack sealer according to claim 1, wherein: the epoxy resin is bisphenol A type epoxy resin, bisphenol F type epoxy resin or a combination thereof.
4. The ultra-bright two-component epoxy crack sealer according to claim 1, wherein: the diluent is at least one of benzyl alcohol, toluene, xylene and n-butanol.
5. The ultra-bright two-component epoxy crack sealer according to claim 1, wherein: the alicyclic amine curing agent is at least one of 3, 3-dimethyl-4, 4-diaminodicyclohexyl methane, 4' -diaminodicyclohexyl methane and 1, 6-diaminohexane.
6. The ultra-bright two-component epoxy crack sealer as claimed in claim 1, wherein: the aliphatic amine curing agent is at least one of polyether amine, diethylenetriamine, triethylene tetramine and polyamine.
7. The ultra-bright two-component epoxy crack sealer according to claim 1, wherein: the thixotropic agent is at least one of hydrophilic fumed silica and hydrophobic fumed silica.
8. The ultra-bright two-component epoxy crack sealer according to claim 1, wherein: the preparation method comprises the following steps:
1) and preparation of the component A: weighing the raw materials according to the mass parts, fully mixing the epoxy resin and the diluent for 2 hours, adding the rest raw materials, and uniformly mixing to obtain a component A:
2) and preparing a component B: weighing raw materials according to the mass parts, fully mixing the modified alicyclic amine curing agent, the aliphatic amine and the diluent, and then adding other raw materials to be uniformly mixed to obtain a component B;
3) respectively pouring the component A and the component B into corresponding filling machines, and respectively filling the component A and the component B into corresponding rubber cylinders of rubber bottles through filling heads;
4) sealing the filled rubber cylinder by a melt mouth machine;
5) after sealing, the rubber bottle is conveyed to a bottle guide turntable through a conveyer belt bearing, and the rubber bottle to be capped is driven by the bottle guide turntable to travel into a cap screwing system;
6) and grabbing by a manipulator to buckle the bottle cap on the rubber bottle, screwing the bottle cap by a cap screwing unit, and finally leading out by a bottle arranging unit to obtain the rubber bottle cap.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN202210284971.8A CN114736638A (en) | 2022-03-22 | 2022-03-22 | Ultra-bright bi-component epoxy seam beautifying agent |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN202210284971.8A CN114736638A (en) | 2022-03-22 | 2022-03-22 | Ultra-bright bi-component epoxy seam beautifying agent |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN114736638A true CN114736638A (en) | 2022-07-12 |
Family
ID=82276448
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN202210284971.8A Pending CN114736638A (en) | 2022-03-22 | 2022-03-22 | Ultra-bright bi-component epoxy seam beautifying agent |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN114736638A (en) |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105802451A (en) * | 2016-06-02 | 2016-07-27 | 湖南柯盛新材料有限公司 | Two-component epoxy decorating sealant and preparation method thereof |
| CN108018012A (en) * | 2017-12-05 | 2018-05-11 | 万华化学集团股份有限公司 | Joint trimming agent is with amine curing agent and preparation method thereof and the joint trimming agent composition epoxy resin including the curing agent |
| CN109486460A (en) * | 2018-10-30 | 2019-03-19 | 湖南柯盛新材料有限公司 | A kind of two-component sealant joint trimming agent and preparation method thereof |
| CN112724901A (en) * | 2020-12-30 | 2021-04-30 | 湖南柯盛新材料有限公司 | Double-component home decoration seam beautifying agent and preparation method thereof |
| CN114163334A (en) * | 2021-11-18 | 2022-03-11 | 万华化学集团股份有限公司 | Modified alicyclic amine curing agent and preparation method thereof |
-
2022
- 2022-03-22 CN CN202210284971.8A patent/CN114736638A/en active Pending
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105802451A (en) * | 2016-06-02 | 2016-07-27 | 湖南柯盛新材料有限公司 | Two-component epoxy decorating sealant and preparation method thereof |
| CN108018012A (en) * | 2017-12-05 | 2018-05-11 | 万华化学集团股份有限公司 | Joint trimming agent is with amine curing agent and preparation method thereof and the joint trimming agent composition epoxy resin including the curing agent |
| CN109486460A (en) * | 2018-10-30 | 2019-03-19 | 湖南柯盛新材料有限公司 | A kind of two-component sealant joint trimming agent and preparation method thereof |
| CN112724901A (en) * | 2020-12-30 | 2021-04-30 | 湖南柯盛新材料有限公司 | Double-component home decoration seam beautifying agent and preparation method thereof |
| CN114163334A (en) * | 2021-11-18 | 2022-03-11 | 万华化学集团股份有限公司 | Modified alicyclic amine curing agent and preparation method thereof |
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Application publication date: 20220712 |