CN114712252A - 一种与阳离子日化品兼容的水凝胶微胶囊 - Google Patents
一种与阳离子日化品兼容的水凝胶微胶囊 Download PDFInfo
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- CN114712252A CN114712252A CN202210474876.4A CN202210474876A CN114712252A CN 114712252 A CN114712252 A CN 114712252A CN 202210474876 A CN202210474876 A CN 202210474876A CN 114712252 A CN114712252 A CN 114712252A
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Abstract
本发明公开一种与阳离子日化品兼容的水凝胶微胶囊,由非离子性或者阳离子性的水凝胶作外壳包裹与水凝胶不相溶的油相形成稳定的微胶囊;该微胶囊为核‑壳结构,核心为单个或多个油滴,且核心被凝固的水凝胶包裹;或为非核‑壳结构,油滴颗粒悬浮在不凝固或半凝固的凝胶中,所述凝胶与阳离子体系兼容。非离子性的微胶囊可以和任何体系:阳离子、阴离子、两性离子以及非离子体系兼容没有配伍禁忌;阳离子的微胶囊和阳离子体系兼容,而且含有阳离子的调理剂,可以直接用在多种日化品中。
Description
技术领域
本发明涉及个人护理品及化妆品技术领域,具体涉及一种与阳离子日化品兼容的水凝胶微胶囊。
背景技术
日化品主要是指人们平日常用的科技化学制品,包括洗发水、沐浴露、护肤品、护发品、化妆品等等。其中,清洁用的香波、沐浴露、洁面膏等含有具有较强的去污去脂能力的阴离子表面活性剂。而护发素以及一些面霜和身体乳使用了阳离子乳化剂以及阳离子调理剂。
例如,一头干净、柔顺、茂密、光亮、健康的秀发是每个爱美人士的梦想,健康的头发表层由一组完整的毛鳞片和自然分泌的油脂构成头发的保护膜。然而,每天人们的头皮都会分泌大量的皮脂,并附着空气中大量的灰尘和细菌使蓬松的头发变得糟糕。因此,不得不使用洗发香波来清洗头发和头皮。
现有技术中,洗发香波中的表面活性剂通常是阴离子的表面活性剂,具有较强的去污去脂能力。头发带有负电荷,用洗发香波(主要是阴离子洗涤剂,肥皂也属于此类)洗发后,会使头发带有更多的负电荷,从而会产生静电,使头发容易打结致使梳理不便;另外,阳光中的紫外线,频繁的洗发、烫发和染发也给头发和头皮带来伤害,头发出现毛躁、分叉、脱发、断发的问题非常普遍。因此,人们通常在洗发以后会使用一些护发的产品,例如用护发素、焗油膏、免洗护发素、护发精油或发膜等,来护理头发的保护膜,使头发免受伤害和修复受损的毛鳞片。
而护发素、焗油膏、免洗护发素、护发精油或发膜等产品主要是由表面活性剂、辅助表面活性剂、阳离子调理剂、增脂的油脂精油、增脂剂、防腐剂、色素、香精及其他活性成分组成。表面活性剂主要起乳化、抗静电、抑菌作用;辅助表面活性剂可以辅助乳化;阳离子调理剂可以中和洗发产品残留在头发表面带阴离子的分子,并留下一层均匀的单分子膜,这层奇妙的东西会给头发带来一系列好处:使头发柔软、有光泽、易于梳理、抗静电,并使头发的机械损伤和化学烫、电烫、染发剂所带来的损伤受到一定程度的修复;阳离子表面活性剂可以乳化油脂以及香精等。但是,乳化剂的量太高会导致油脂被乳化很容易被水冲洗掉;其次,增脂的油脂精油以及活性物在阳离子表活体系里面不够稳定。增脂剂如羊毛脂、橄榄油、硅油等在护发素中可改善头发营养状况,使头发光亮,易梳理;其他活性成分去头皮屑、润湿、防晒、维生素、水解蛋白、植物提取液等赋予护发素各种功能。
由此可见,大部分护发产品都是阳离子体系的,并含有增脂的油脂。精油水凝胶类微胶囊可以达到增脂带来活性物的目的又含有乳化剂使油脂被冲洗掉。目前市场上有很多种水凝胶类微胶囊,但是没有特别针对阳离子体系兼容无配伍禁忌的微胶囊。当微胶囊含有负电荷与阳离子正电荷聚电荷交联反应,而使凝胶变性、变色和变硬等等,甚至出现微胶囊发生破裂或者坚硬不可涂开的情况。
发明内容
针对现有技术存在的上述不足,本发明的目的在于提供一种与阳离子日化品兼容的水凝胶微胶囊,解决现有技术中水凝胶类微胶囊与阳离子日化品存在配伍禁忌的问题。
为了解决上述技术问题,本发明采用如下技术方案:
本发明提供一种与阳离子日化品兼容的水凝胶微胶囊,由非离子性或者阳离子性的凝固水凝胶作外壳,包裹与水凝胶不相溶的油相形成稳定的核壳结构微胶囊;核心为单个或多个直径大于0.1毫米的油相球粒。
本发明还提供形态不同的另一种与阳离子日化品兼容的水凝胶微胶囊,该微胶囊为非核-壳结构,油相球粒悬浮在不凝固或半凝固的非离子性或者阳离子性水凝胶外相中,所述水凝胶与阳离子体系兼容。
进一步,所述非离子性或者阳离子性的水凝胶,包括如下非离子或阳离子胶体:琼脂、魔芋胶、壳聚糖、刺槐豆胶、瓜尔豆胶及其衍生物、甲基纤维素、羟乙基纤维素、羟丙基甲基纤维素、羟丙基纤维素、聚乙烯醇、聚乙烯吡咯烷酮、聚乙二醇-240/HDI共聚物双-癸基十四烷醇聚醚-2、甘油聚丙烯酸脂中的一种或多种。
进一步,所述非离子性或者阳离子性水凝胶中含有增塑剂或者润肤剂,包括甘油、丙二醇、丁二醇、戊二醇、山梨醇中的一种或多种。
进一步,所述水凝胶可以选择含有水溶性的阳离子调理剂;所述水溶性的阳离子调理剂包括聚季氨盐、瓜儿胶羟丙基三甲基氯化铵、季铵化羟乙基纤维素、丙烯酸/二甲基二丙烯基氯化铵共聚物、乙烯吡咯烷酮/二甲基乙基氨基丙烯酸-硫酸二乙酯季铵盐共聚物、丙烯酰胺/N,N-二甲基-2-丙烯基-1-氯化铵共聚物、季铵化二甲基硅氧烷、季铵化水解胶原、季铵化水解角蛋白、季铵化水解豆蛋白或季铵化丝氨酸。
进一步,所述水凝胶中含有水溶性色素、无机色淀或珠光粉,因此水凝胶皮可以是无色或彩色透明的,也可以是彩色带有珍珠光泽的。
进一步,所述水凝胶中含有水溶活性物例如透明质酸、水溶角蛋白、肽、氨基酸、水溶植物萃取物等等中的一种或多种。
进一步,所述油核结构中,含有油溶性色素或经过亲脂处理的色淀,油核可以是无色或彩色透明的,也可以是白色或彩色不透明的。
进一步,所述油相的油脂包括植物油、矿物油、硅油、合成油脂、脂肪酸脂、脂肪醇、蜡、硅油及其衍生物、蜡或羊毛脂,以及脂溶活性物中的一种或多种组成。
进一步,油相中可含有脂溶性活性物,包括:维生素A、维生素E、维生素K、神经酰胺、植物鞘氨醇、叶黄素、胡萝卜素、虾青素、精油、薄荷醇中的一种或多种。
进一步,油相中可包含防晒剂,包括超细钛白粉、超细氧化锌;还包含紫外吸收剂,包括对氨基苯甲酸及其酯类、水杨酸酯类及其衍生物、邻氨基苯甲酸酯类、二苯酮及其衍生物、对甲基肉桂酸类、二苯甲酰甲烷类、樟脑衍生物类、苯并三唑类、二甲氧基硅氧烷丙二酸酯类和三嗪酮类中的一种或多种。
进一步,所述油相中可以选择含有油溶高分子材料粘合剂,包括糊精棕榈酸脂、蓖麻油/IPDI共聚物、聚酰胺脂、硅弹体、氢化苯乙烯/丁二烯共聚物、二丁基乙基己酰基谷氨酰胺或二丁基月桂酰谷氨酰胺中的一种或多种。
进一步,所述核-壳球状结构的直径为0.3-10毫米;油核占微胶囊总的质量百分比为5-50%。
进一步,所述核-壳结构可以是在一个异形的模具中成型的凝固含有大量油滴的果冻块状。油核占总的质量百分比为5-50%。没有形状和尺寸的限制。
进一步,所述油相球粒的直径为0.1-10毫米;油相重量占整体水凝胶包油啫喱重量的百分比为5-70%。
进一步,所述的油相和水凝胶中不含有乳化剂或表面活性剂。
相比现有技术,本发明具有如下有益效果:
1、本发明提供的水凝胶微胶囊,由非离子性或者阳离子性的凝固水凝胶将油相包裹起来得到一个稳定的核壳结构微胶囊;或者为非核-壳结构,油相球粒悬浮在不凝固或半凝固的非离子性或者阳离子性水凝胶外相中;所述水凝胶不和阳离子基料发生聚合反应,稳定性高;对阳离子体系有高度的兼容性,不会因为长期的保存而出现凝胶阴阳离子聚电荷反应而变得坚韧或粘连,无法涂开释放精油;并且,非离子性的微胶囊可以和任何体系阳离子、阴离子、两性离子以及非离子体系兼容没有配伍禁忌;阳离子的微胶囊不仅和阳离子兼容,而且具有阳离子的调理性,可以直接用在不需要冲洗的日化品里面。有效中和含有阴离子清洁产品的残留的负电荷,同时达到增脂的目的
2、本发明提供的水凝胶微胶囊是一种非离子的,或者带有阳离子的水凝胶包裹的精油活性胶囊不含乳化剂,能够稳定精油等活性物,避免普通霜乳类产品中大量的乳化剂使精油容易被水冲洗掉。并且,核壳结构的微胶囊可以使用在精油中,改变油体系没有水相的缺点;同时凝胶壳中的阳离子调理剂有柔顺抗静电的作用。此外,非核壳结构的凝胶包精油微粒也可以作为无乳化剂的水包油精华应用,改变了全水的啫喱体系没有油脂的问题,使产品的功能更加全面。
3、本发明提供的水凝胶微胶囊,可以是核壳结构的微胶囊,油相核心外面有一个凝固的凝胶壳;也可以是一个油相的核心悬浮在没有凝固的或者半凝固的阳离子体系的凝胶中。不局限于护发产品中使用,也可以在护肤品中使用。本发明的水凝胶包油微胶囊是非离子性的可以和任何体系兼容包括阳离子体系,或者特别含有阳离子调理剂不仅和阳离子体系兼容而且本身具有调理性。
4、本发明采取现有的同心二流体或三流体装置,基于互不相容的水、油两相具有不同的界面张力,水凝胶包裹在油滴的外面,落入冷却的油相中,水凝胶凝固而将油滴包裹其中。因此通常滴头的最中心走的是被包裹油相流体,外面是水凝胶的流体。水的表面张力大于油,水凝胶包裹在油滴表面,当表面张力无法克服重力的时候整个包裹的微胶囊下落到冷却油中,水凝胶壳冷却凝固得到一个核壳结构的球形微胶囊。如果流体直接注入到一个特定形状的容器中凝固,就能得到一个该形状的果冻状凝胶,里面包裹有很多油滴。
当水凝胶包裹油滴直接下落到容器中,由于水凝胶不凝固而融合成连续的水相,油相球粒悬浮在水凝胶中。
通过控制滴头的孔径、水油流体的速度、以及对这个同心最外层的第三流体的冲击力切割而得到不同大小的微胶囊。
附图说明
图1是本发明水凝胶微胶囊单核-壳结构示意图;
图2是本发明水凝胶微胶囊多核-壳结构示意图;
图3是本发明水凝胶微胶囊非核壳结构的水包油(油珠)嗜喱示意图;
图4是图4中三流同心滴头的示意图。
具体实施方式
为了使本领域技术人员更好地理解本发明的技术方案,下面结合具体实施例对本发明作进一步的说明,但本发明的实施方式不仅限于此。
本发明提供一种与阳离子日化品兼容的水凝胶微胶囊,由非离子性或者阳离子性的凝固水凝胶作外壳,包裹与水凝胶不相溶的油相形成稳定的核壳结构微胶囊。
参见图1为单核-壳结构的水凝胶微胶囊,图2为多核-壳结构的水凝胶微胶囊,所述核心为单个或多个直径大于0.1毫米的油相球粒。所述水凝胶微胶囊采取的是水相、油相互不相溶,利用表面张力不同的相分离原理制备。
参见图3,本发明还提供形态不同的一种与阳离子日化品兼容的水凝胶微胶囊,该微胶囊为非核-壳结构,油相球粒悬浮在不凝固或半凝固的非离子性或者阳离子性水凝胶外相中,所述水凝胶与阳离子体系兼容。当水相凝胶是无法凝固的液态,且具有一定悬浮力的时候,水凝胶包油的滴点滴下来水凝胶堆积成连续的水相;而油相的核心被悬浮其中,就会形成水包油滴的混合物。油滴具有肉眼可见的直径。
参见图4,其生产方法采用现有技术,使用一个二流或三流的同心滴头,中心是核心油相的流体、中间一层是水凝胶的流体同心包裹在核心油流体的外面、最外面一层流体是气流或者冷却油的流体。
通常,当液滴的表面张力无法克服重力的时候,水凝胶包裹油自然滴下,或者在第三流体的冲力下落下,由于表面张力不同水凝胶包裹里面的油滴,滴落到冷却的油中。凝胶外壳冷却凝固得到凝胶包油的核壳结构微胶囊。或者落到容器中水凝胶不凝固得到非核壳结构的水凝胶包油珠结构的微胶囊。可以通过控制滴头的孔径、水油流体的速度、以及对这个同心第三流体的冲击力切割而得到不同大小的微胶囊。
实施例1
1、一种可以在含有阳离子日化品中添加的水凝胶精油胶囊。
成份 | 原料 | 百分比 |
精油 | 亚麻籽油 | 15 |
精油 | 阿甘油 | 15 |
水凝胶 | 琼脂 | 1 |
水凝胶 | 羟乙基纤维素 | 1 |
水凝胶 | 羟丙基甲基纤维素 | 0.5 |
水溶活性物 | 水解角蛋白 | 0.5 |
增塑剂 | 丁二醇 | 5 |
水凝胶溶解剂 | 水 | 62 |
合计100 |
2、一种可以在阳离子日化品中添加的水凝胶精油胶囊的制备方法,按上述配比取原料,具体制备包括如下步骤:
1)将水溶性胶体羟乙基纤维素、羟丙基甲基纤维素、水解角蛋白溶解于水中得到所需要的浓度,并在滴制前一直保温到50-70℃;浓度范围通常在1-5%;
2)将琼脂溶解到沸腾的水中,得到所需要的浓度,浓度范围通常在1-5%;
3)将步骤1)和步骤2)的水相混合得到均匀的水相,并加入丁二醇混合均匀;
4)将亚麻籽油和阿甘油混合均匀得到油相;
5)通过精确的泵将油相输送到同心滴头的中心,水相混合物输送到同心滴头的外层,将油包裹成一个个同心的液珠,自然滴落到1-5℃的冷却液体石蜡中即得到壳包油的凝胶微胶囊,参见图1所示;该凝胶微胶囊直径大约3-5毫米。
3、应用及效果
所述水凝胶微胶囊是非离子性的可以添加到任何体系的乳或者带有阳离子体的日化产品中。对阳离子体系有高度的兼容性,不会因为长期的保存而出现凝胶阴阳离子聚电荷反应而变得坚韧或粘连,或无法涂开释放精油。
实施例2
1、一种可以全硅油或矿物油基料中添加的植物油微胶囊
成份 | 原料 | 百分比 |
水凝胶 | 魔芋胶 | 0.5 |
阳离子调理剂 | 瓜儿胶羟丙基三甲基氯化铵 | 1 |
阳离子活性物 | 季铵化丝氨酸 | 1 |
水溶活性物 | 维生素B5 | 0.5 |
植物精油 | 阿甘油 | 25 |
油溶活性物 | 维生素E | 0.5 |
着色剂 | 金色珠光粉 | 0.5 |
水凝胶溶解剂 | 水 | 71 |
合计100 |
2、一种可以全硅油或矿物油基料中添加的植物油微胶囊制备方法,按上述配比取原料,具体制备包括如下步骤:
1)将瓜儿胶羟丙基三甲基氯化铵、季铵化丝氨酸、维生素B5溶解到适量的水中并在滴制前保温在50-70℃;
2)将魔芋胶用沸腾的水溶解到浓度1-2%,并加入到步骤1)的混合物中,再加入适量的金色珠光粉搅拌均匀得到水相,并保温在50-70℃;
3)将维生素E溶解到阿甘油中得到油相;
4)将二甲硅油冷却到1-5℃作为冷却油;
5)通过精确的注射泵将油相输送到三流同心滴头的中心,水相混合物输送到同心滴头的中层,将油包裹成一个个同心的液柱,外层吹出压缩空气迫使液柱吹断成小珠子;
并且,小珠子滴落到1-5℃的冷却二甲硅油中,即可得到壳包油的金色水凝胶包油微胶囊,直径大约1-3毫米。
3、应用及效果
过滤出微胶囊按加入到硅油或矿物油基料中,通常只含有二甲硅油或者矿物油的日化品很难和植物油混合。含水凝胶包植物油微胶囊丰富了产品的油脂种类和不同油脂的功效。同时含有阳离子的调理剂和活性物,水全油的基料中有了水相,并且可以提高调理的作用和产品的价值。
实施例3
1、一种无乳化剂的流动水凝胶包油珠微胶囊
2、一种无乳化剂的流动水凝胶包油珠微胶囊的制备方法
1)将季铵化羟乙基纤维素、瓜儿胶羟丙基三甲基氯化铵、聚乙二醇-240/HDI共聚物双-癸基十四烷醇聚醚-2、加适量的水溶解成均匀的溶液,保温在50-70℃;
2)用沸腾的水溶解琼脂,然后和步骤1)的溶液混合均匀得到水溶胶体,保温在50-70℃;
3)将水溶角蛋白和维生素B5溶解到步骤2)所得到的水溶胶体中,得到水相;
4)将氨基硅油和硅蜡加热到40℃混合溶解,得到油相;
5)通过精确的泵将油相输送到二流同心滴头的中心,水相混合物输送到同心滴头的外层,水凝胶将油包裹成一个个液滴,并滴落到收集容器中;由于琼脂的含量低、外相无法形成凝固的壳而是流动性的胶体溶液,得到一个在胶体溶液中悬浮油珠子的混合精华,参见图3
3、该水凝胶包油珠微胶囊含有调理性的氨基硅油以及水溶的阳离子调理剂。可以和其他非离子基料或者阳离子的基料混合得到所需要的产品。也可以直接当作带有阳离子调理性的产品使用。是一种不含乳化剂的水包油(油珠微胶囊)新颖产品。
实施例4
1、一种水凝胶包裹含有颜料精油的变色微胶囊
成份 | 原料 | 百分比 |
水凝胶 | 琼脂 | 0.5 |
水凝胶 | 甘油丙烯酸酯 | 0.5 |
水凝胶 | 聚乙烯醇 | 0.5 |
油脂 | 辛酸葵酸三甘油酯 | 20 |
油脂 | 肉豆蔻酸肉豆蔻脂 | 10 |
紫外吸收剂 | 甲基肉桂酸辛酯 | 10 |
油溶胶体 | 糊精棕榈酸脂 | 5 |
矿物色淀 | 钛白粉 | 2 |
矿物色淀 | 氧化铁棕 | 0.2 |
矿物色淀 | 白色云母粉 | 1.5 |
水凝胶溶解剂 | 水 | 39.8 |
合计100 |
2、一种水凝胶包裹含有颜料精油的变色微胶囊的制备方法,包括如下步骤:
1)将刺槐豆胶、聚乙烯醇和甘油聚丙烯酸脂混合溶解在水中,保温到50-70℃;然后加入白色云母粉得水相;
2)将辛酸葵酸三甘油酯和肉豆蔻酸肉豆蔻脂混合,并水浴加热到80℃;然后,加入糊精棕榈酸脂充分溶解。然后加入甲基肉桂酸辛酯并保温在80℃;得油相;
3)将钛白粉和氧化铁棕碾磨到200目左右混合均匀,混合加到步骤2)油相中均质;
4)通过精确的泵将油相输送到二流同心滴头的中心,水相混合物输送到同心滴头的外层,将油包裹成一个个同心液滴,通过重力自然下落滴入冷却到1-5度的液体石蜡中
水凝胶外相冷却凝固成壳将油相包裹其中,从而得到一个外观如珍珠的微胶囊,由于凝胶壳含有白色云母粉使凝胶壳呈现珍珠光泽,里面包裹的油相是钛白粉和氧化铁混合成的肤色油滴。胶囊在涂抹开的时候有一个从珍珠白色到肉色的变色效果。
3、所述含有颜料精油的变色微胶囊的应用
该产品水相为中性,稳定性高;并且不含有乳化剂、外观独特,肤感清爽,可以添加到任何体系例如啫喱,膏霜中得到具有一定的遮瑕和亮肤防止紫外线效果的产品例如妆前乳、BB霜等。
综上,通过与大多数阳离子调理剂的混合实验测试,本发明所得到的水凝胶微胶囊、含有精油微胶囊的发油和免洗护发素均不和阳离子基料发生聚合反应,稳定性高;并且,非离子性的微胶囊可以和任何体系阳离子、阴离子、两性离子以及非离子体系兼容没有配伍禁忌;阳离子的微胶囊不仅和阳离子兼容,而且具有阳离子的调理性。微胶囊中不含有乳化剂,避免普通乳内产品中大量的乳化剂使精油容易被水冲洗掉问题。并且,核壳结构的微胶囊可以使用在全油的发油中,改变发油体系没有水相的缺点;同时凝胶壳中的阳离子调理剂对头发也有柔顺抗静电的作用。此外,非核壳结构的凝胶包精油微粒也可以作为护发护肤啫喱应用,改变了全水的啫喱体系没有油脂的问题,使产品更加全面。
最后需要说明的是,以上实施例仅用以说明本发明的技术方案而非限制技术方案,本领域的普通技术人员应当理解,那些对本发明的技术方案进行修改或者等同替换,而不脱离本技术方案的宗旨和范围,均应涵盖在本发明的权利要求范围当中。
Claims (15)
1.一种与阳离子日化品兼容的水凝胶微胶囊,其特征在于,由非离子性或者阳离子性的凝固水凝胶作外壳,包裹与水凝胶不相溶的油相,形成稳定的核壳结构微胶囊;所述水凝胶与阳离子体系兼容;核心为单个或多个直径大于0.1毫米的油相球粒。
2.一种与阳离子日化品兼容的水凝胶微胶囊,其特征在于,该微胶囊为非核-壳结构,油相球粒悬浮在不凝固或半凝固的非离子性或者阳离子性水凝胶外相中,所述水凝胶与阳离子体系兼容。
3.根据权利要求1或2所述与阳离子日化品兼容的水凝胶微胶囊,其特征在于,所述非离子性或者阳离子性水凝胶包括:琼脂、魔芋胶、壳聚糖、刺槐豆胶、瓜尔豆胶及其衍生物、甲基纤维素、羟乙基纤维素、羟丙基甲基纤维素、羟丙基纤维素、聚乙烯醇、聚乙烯吡咯烷酮、聚乙二醇-240/HDI共聚物双-癸基十四烷醇聚醚-2、甘油聚丙烯酸脂中的一种或多种。
4.根据权利要求1或2所述与阳离子日化品兼容的水凝胶微胶囊,其特征在于,所述水凝胶中含有增塑剂或者润肤剂,包括甘油、丙二醇、丁二醇、戊二醇、山梨醇中的一种或多种。
5.根据权利要求1或2所述与阳离子日化品兼容的水凝胶微胶囊,其特征在于,所述水凝胶还含有水溶性的阳离子调理剂;所述水溶性的阳离子调理剂包括聚季氨盐、瓜儿胶羟丙基三甲基氯化铵、季铵化羟乙基纤维素、季铵化水解胶原、季铵化水解角蛋白、季铵化水解豆蛋白、季铵化丝氨酸、丙烯酸/二甲基二丙烯基氯化铵共聚物、乙烯吡咯烷酮/二甲基乙基氨基丙烯酸-硫酸二乙酯季铵盐共聚物、丙烯酰胺/N,N-二甲基-2-丙烯基-1-氯化铵共聚物或季铵化二甲基硅氧烷。
6.根据权利要求1或2所述与阳离子日化品兼容的水凝胶微胶囊,其特征在于,所述水凝胶中含有水溶性色素、无机色淀或珠光粉,因此水凝胶皮可以是无色或彩色透明的,也可以是彩色带有珍珠光泽的。
7.根据权利要求1或2所述与阳离子日化品兼容的水凝胶微胶囊,其特征在于,所述水凝胶中含有水溶活性物,包括但不限于透明质酸、水溶角蛋白、肽、氨基酸、水溶植物萃取物中的一种或多种。
8.根据权利要求1或2所述与阳离子日化品兼容的水凝胶微胶囊,其特征在于,所述油核中含有油溶性色素或经过亲脂处理的色淀,油核为无色或彩色透明的,或者是白色或彩色不透明的。
9.根据权利要求1或2所述与阳离子日化品兼容的水凝胶微胶囊,其特征在于,所述油相包括植物油、矿物油、硅油、合成油脂、脂肪酸脂、脂肪醇、蜡、硅油及其衍生物、表面活性剂、蜡或羊毛脂,以及脂溶活性物中的一种或多种组成。
10.根据权利要求1或2所述与阳离子日化品兼容的水凝胶微胶囊,其特征在于,油相中包括含有脂溶性活性物,但不限于:维生素A、维生素E、维生素K、神经酰胺、植物鞘氨醇、叶黄素、胡萝卜素、虾青素、精油、薄荷醇中的一种或多种。
11.根据权利要求1或2所述与阳离子日化品兼容的水凝胶微胶囊,其特征在于,油相中还含防晒剂,包括超细钛白粉、超细氧化锌;或还含有紫外吸收剂,包括对氨基苯甲酸及其酯类、水杨酸酯类及其衍生物、邻氨基苯甲酸酯类、二苯酮及其衍生物、对甲基肉桂酸类、二苯甲酰甲烷类、樟脑衍生物类、苯并三唑类、二甲氧基硅氧烷丙二酸酯类和三嗪酮类中的一种或多种。
12.根据权利要求1或2所述与阳离子日化品兼容的水凝胶微胶囊,其特征在于,所述油相中还含有油溶高分子材料粘合剂,包括糊精棕榈酸脂、蓖麻油IPDI共聚物、聚酰胺脂、硅弹体、氢化苯乙烯/丁二烯共聚物、二丁基乙基己酰基谷氨酰胺或二丁基月桂酰谷氨酰胺中的一种或多种。
13.根据权利要求1所述与阳离子日化品兼容的水凝胶微胶囊,其特征在于,所述核-壳结构的微胶囊直径为0.3-10毫米;油核和整个胶囊的质量百分比为5-50%。
14.权利要求2所述与阳离子日化品兼容的水凝胶微胶囊,其特征在于,所述油相球粒的直径为0.1-10毫米;油滴颗粒的重量和外相水凝胶重量的比例为5-50%。
15.根据权利要求1或2所述与阳离子日化品兼容的水凝胶微胶囊,其特征在于,所述的油相和水凝胶中不含有乳化剂或表面活性剂。
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Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
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CN104434548A (zh) * | 2014-12-16 | 2015-03-25 | 重庆小丸科贸有限公司 | 一种具有防晒功效的水凝胶微胶囊 |
CN104546514A (zh) * | 2014-12-16 | 2015-04-29 | 重庆小丸科贸有限公司 | 一种水凝胶微胶囊型护发精华 |
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US20180021241A1 (en) * | 2015-01-12 | 2018-01-25 | International Flavors & Fragrances Inc. | Hydrogel capsules and process for preparing the same |
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