CN114686320A - 一种气雾型清洁凝胶及其制备方法 - Google Patents
一种气雾型清洁凝胶及其制备方法 Download PDFInfo
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- CN114686320A CN114686320A CN202011575890.0A CN202011575890A CN114686320A CN 114686320 A CN114686320 A CN 114686320A CN 202011575890 A CN202011575890 A CN 202011575890A CN 114686320 A CN114686320 A CN 114686320A
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- aerosol
- parts
- cleaning
- gel
- cleaning gel
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- LCGLNKUTAGEVQW-UHFFFAOYSA-N Dimethyl ether Chemical compound COC LCGLNKUTAGEVQW-UHFFFAOYSA-N 0.000 claims description 4
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- PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 description 1
- 230000000844 anti-bacterial effect Effects 0.000 description 1
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Classifications
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/83—Mixtures of non-ionic with anionic compounds
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/86—Mixtures of anionic, cationic, and non-ionic compounds
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D17/00—Detergent materials or soaps characterised by their shape or physical properties
- C11D17/0008—Detergent materials or soaps characterised by their shape or physical properties aqueous liquid non soap compositions
- C11D17/003—Colloidal solutions, e.g. gels; Thixotropic solutions or pastes
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D17/00—Detergent materials or soaps characterised by their shape or physical properties
- C11D17/0043—For use with aerosol devices
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
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- C11D3/02—Inorganic compounds ; Elemental compounds
- C11D3/04—Water-soluble compounds
- C11D3/044—Hydroxides or bases
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/02—Inorganic compounds ; Elemental compounds
- C11D3/12—Water-insoluble compounds
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
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- C11D3/16—Organic compounds
- C11D3/18—Hydrocarbons
- C11D3/181—Hydrocarbons linear
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2068—Ethers
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- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
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- C11D3/20—Organic compounds containing oxygen
- C11D3/2075—Carboxylic acids-salts thereof
- C11D3/2079—Monocarboxylic acids-salts thereof
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
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- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/22—Carbohydrates or derivatives thereof
- C11D3/222—Natural or synthetic polysaccharides, e.g. cellulose, starch, gum, alginic acid or cyclodextrin
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
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- C11D3/245—Organic compounds containing halogen containing fluorine
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- C—CHEMISTRY; METALLURGY
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- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
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- C11D3/30—Amines; Substituted amines ; Quaternized amines
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/38—Products with no well-defined composition, e.g. natural products
- C11D3/382—Vegetable products, e.g. soya meal, wood flour, sawdust
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
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- C11D3/48—Medical, disinfecting agents, disinfecting, antibacterial, germicidal or antimicrobial compositions
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/008—Polymeric surface-active agents
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/04—Carboxylic acids or salts thereof
- C11D1/06—Ether- or thioether carboxylic acids
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
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- C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
- C11D1/14—Sulfonic acids or sulfuric acid esters; Salts thereof derived from aliphatic hydrocarbons or mono-alcohols
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Abstract
本发明提供了一种气雾型清洁凝胶及其制备方法，气雾型清洁凝胶其配方按重量份配比包括：重油污清洁剂1.0～10.0份，表面活性剂1.0～10.0份，稠化剂0.1～5.0份，添加剂0.1～0.5份，增溶剂0.1～1.0份，防腐剂0.1～1.0份，酸碱调节剂0.1～3.0份，精油0.1～1.0份、水60～90.0份、推进剂3.0～20.0份。该气雾型清洁凝胶具有如下有益效果：1.本发明的气雾型清洁凝胶，使用方便、储存性能佳；2.产品弱碱性，不含挥发性溶剂，环保，安全；3.产品具有良好的剪切变稀效果，能有针对性的靶向喷雾，显著增加挂壁时间，提升除油效果；4.本发明的气雾型清洁凝胶产品采用独特的硬表面亲水改性技术，清洗后在硬表面形成保护膜，利于再次清洁。本发明还公开了该气雾型清洁凝胶的制备方法。
Description
技术领域
本发明涉及清洁剂技术领域，尤其涉及一种气雾型清洁凝胶及其制备方法。
背景技术
我国的清洁剂工业起步于1958年，经过多年年的发展，我国已进入世界清洁用品生产大国行列，产品形态及产品品种日益丰富，专业化、功能化、个性化产品不断涌现，形成个人清洁护理用品、家庭清洁护理用品、工业和公共设施清洁用品三大品类体系。现已具有一定的规模，成为我国轻工行业的支柱产业之一，清洁产品的发展也带动了相关原料的发展，目前大部分国内自主生产的助剂、表面活性剂品种均能满足清洁用品行业的需求。随着我国经济的稳步发展，城市化进程不断加快，清洁用品必然会继续保持稳定增长。目前，我国清洁用品行业的合成洗涤剂生产厂商较多，年生产能力也超百万吨，但市面上主要以液体和固体清洁剂为主，液体清洁剂除油能力不佳，且附着力不足，易流挂，固体清洁剂去污效果强，但无法有效地铺展使用，因此开发一种操作灵活、简便，同时具有良好的剪切变稀效果，能有针对性的靶向喷雾，且具有高附着力、能显著增加清洗剂在垂直表面的挂壁时间，提升除油效果，清洗后在硬表面形成保护膜，利于再次清洁等特点的气雾型清洁凝胶势在必行。
发明内容
本发明的一个目的是提供一种气雾型清洁凝胶，常温时具有凝胶（啫喱）状，喷涂在瓷砖、灶具、抽油烟机等物件表面不滴漏、飞溅，当抹布、百洁布、刷子等在物件表面洗刷过程中使凝胶软化变稀并附着在其表面，起到长时间浸润和清洁作用等特点的气雾型清洁凝胶，以克服上面所述的技术缺陷。本发明的另一个目的是提供上述气雾型清洁凝胶的制备方法。
根据本发明的一个方面，提供了气雾型清洁凝胶及其制备方法，其重量份配比包括：
重油污清洁剂 1.0～10.0份,
表面活性剂 1.0～10.0份,
稠化剂 0.1～5.0份,
添加剂 0.1～0.5份,
增溶剂 0.1～1.0份,
防腐剂 0.1～1.0份,
酸碱调节剂 0.1～3.0份,
精油 0.1～1.0份，
水 60.0～90.0份，
推进剂 10.0～30.0份。
所述的重油污清洁剂为十二烷基苯磺酸异丙醇胺盐LAS-IPA、Crodaquat _DGR重油垢清洗剂、椰油酰胺聚氧乙烯醚POEA-15、仲烷基磺酸钠60 SAS60、D-柠檬烯、Prifer6813中的至少一种。
所述表面活性剂为脂肪醇聚氧乙烯醚（AEO）、非离子型氟碳表面活性剂、TRIOTECSOE低泡表活、十二烷基苯磺酸钠LAS、脂肪醇聚氧乙烯醚硫酸钠AES中的至少一种。优选低泡类的表面活性剂有益于剂料喷出的状态，增强附着力。
所述的稠化剂为羧甲基纤维素钠、聚乙烯醇、聚丙烯酸钠、汉生胶、CrystaSense_Sapphire碱性稠化剂中的至少一种。
所述的添加剂为1227杀菌剂、MODISUFR硬表面清洁保持添加剂、季铵盐中的至少一种。
所述的增溶剂为巴斯夫CO40、二甲苯磺酸钠、CRODURET 40LV中的至少一种。
所述的防腐剂为卡松、苯氧乙醇、尼泊金甲酯、苯甲酸钠中的至少一种；所述的酸碱调节剂为液碱、三乙醇胺、氨水中的至少一种；所述的精油为柑橘精油、薰衣草精油、茉莉精油中的至少一种。
所述的推进剂为LPG、二甲醚、CO2、N2、HFC-134a、HFO-1234ze中的至少一种。
本发明提供的气雾型清洁凝胶与市场液体、固体清洁剂对比，具有如下有益效果：
1.产品使用方便，储存性能佳；
2.产品性能优异，弱碱性，不含挥发性溶剂，环保，安全；
3.产品具有良好的剪切变稀效果，能有针对性的靶向喷雾，显著增加挂壁时间，提升除油效果；
4. 独特的硬表面亲水改性技术，清洗后在硬表面形成保护膜，利于再次清洁。
根据本发明的另一个方面，提供了一种提供了气雾型清洁凝胶及其制备方法，包括以下步骤：
1) 剂料的制备：按重量份配比，将增溶剂和精油加入到容器中，搅拌均匀，再加入水搅拌15min，缓慢加入稠化剂，搅拌30min至完全溶解后，加入重油污清洁剂、表面活性剂、添加剂、防腐剂，搅拌50min，最后用酸碱调节剂调节酸碱值至10即可过滤备用。
2) 灌装：按一定充填率将剂料灌装至气雾罐中，加入阀门后进行封口、充填抛射剂，装按头、盖子，即制得气雾型清洁凝胶。
具体实施方式
以下通过具体实施例说明气雾型清洁凝胶的组成、制备方法及使用气雾型清洁凝胶进行清洁效果等测试，以便更好的理解本发明。
实施例1
十二烷基苯磺酸异丙醇胺盐LAS-IPA 1.0份
脂肪醇聚氧乙烯醚（AEO） 1.0份
羧甲基纤维素钠 0.1份
1227杀菌剂 0.1份
巴斯夫CO40 0.1份
卡松 0.1份
三乙醇胺 0.1份
薰衣草精油 0.1份
水 87.4份
LPG 10.0份
实施例2
Crodaquat DGR重油垢清洗剂 3.0份
TRIOTEC SOE低泡表活 5.0份
CrystaSense_Sapphire碱性稠化剂 2.5份
MODISUFR硬表面清洁保持添加剂 0.5份
CRODURET 40LV 0.5份
苯氧乙醇 0.5份
液碱 0.5份
柑橘精油 0.5份
水 71.9份
N2 15.0份
实施例3
仲烷基磺酸钠60 SAS60 10.0份
非离子型氟碳表面活性剂 10.0份
汉生胶 5.0份
季铵盐 0.5份
二甲苯磺酸钠 1.0份
苯甲酸钠 1.0份
氨水 3.0份
茉莉精油 1.0份
水 38.5份
HFO-1234ze 30.0份
比较例4
山梨醇/甘油 10.0份
羧甲基纤维素 0.1份
月桂醇聚氧乙烯醚 0.5份
1,2-丙二醇 0.18份
次氮基三乙酸钠 0.015份
苯并三氮唑 0.008份
氯化钠 0.4份
滑石粉 70.0份
香精 0.007份
水 18.79份
比较例5
异构十三醇聚氧乙烯醚 7.5份
癸基葡萄糖苷 2.0份
≥99%脱臭乙醇 6.0份
香茅油 0.25份
EDTA-4钠 0.25份
羟基二氯二苯醚 0.05份
季铵盐-15 0.25份
柠檬酸 0.05份
水 83.65份
实施例1～3，比较例4为清洁膏、比较例5为市售清洗剂，其相关性能测试方法如下：
1. 使用情况：观察清洗剂外观状态。
2. 去污率：按照标准《JB/T4323.1-1999水基金属清洗剂》中的测试方法，使用通用的硬表面摆洗机进行去污力的定量测定，记录摆洗前与摆洗后污垢量，计算去污效率。
由表1的测试效果表明，本发明一种气雾型清洁凝胶和比较例4清洁膏、比较例5清洗剂相比，其使用简单方便，呈凝胶（啫喱）状，有针对性的靶向喷雾且不易流挂，可较长时间附着在污渍表面并起到清洁剂作用，而且清洗力效果优异。
本发明一种气雾型清洁凝胶及其制备方法，使用便捷安全，不含挥发性溶剂，具有温和、安全、无气味等特点。
Claims (9)
1.一种气雾型清洁凝胶，其特征在于，各组分按重量份配比包括：
重油污清洁剂 1.0～10.0份,
表面活性剂 1.0～10.0份,
稠化剂 0.1～5.0份,
添加剂 0.1～0.5份,
增溶剂 0.1～1.0份,
防腐剂 0.1～1.0份,
酸碱调节剂 0.1～3.0份,
精油 0.1～1.0份，
水 60.0～90.0份，
推进剂 10.0～30.0份。
2.如权利要求1所述的一种气雾型清洁凝胶，其特征在于，所述的重油污清洁剂为十二烷基苯磺酸异丙醇胺盐LAS-IPA、Crodaquat_DGR_重油垢清洗剂、椰油酰胺聚氧乙烯醚POEA-15、仲烷基磺酸钠60 SAS60、D-柠檬烯、Prifer 6813中的至少一种。
3.如权利要求1所述的一种气雾型清洁凝胶，其特征在于，所述的表面活性剂为脂肪醇聚氧乙烯醚（AEO）、非离子型氟碳表面活性剂、TRIOTEC SOE低泡表活、十二烷基苯磺酸钠LAS、脂肪醇聚氧乙烯醚硫酸钠AES中的至少一种。
4.如权利要求1所述的一种气雾型清洁凝胶，其特征在于，所述的稠化剂为羧甲基纤维素钠、聚乙烯醇、聚丙烯酸钠、汉生胶、CrystaSense_Sapphire碱性稠化剂中的至少一种。
5.如权利要求1所述的一种气雾型清洁凝胶，其特征在于，所述的添加剂为1227杀菌剂、MODISUFR硬表面清洁保持添加剂、季铵盐中的至少一种。
6.如权利要求1所述的一种气雾型清洁凝胶，其特征在于，所述的增溶剂为巴斯夫CO40、二甲苯磺酸钠、CRODURET 40LV中的至少一种。
7.如权利要求1所述的一种气雾型清洁凝胶，其特征在于，所述的防腐剂为卡松、苯氧乙醇、尼泊金甲酯、苯甲酸钠中的至少一种；所述的酸碱调节剂为液碱、三乙醇胺、氨水中的至少一种；所述的精油为柑橘精油、薰衣草精油、茉莉精油中的至少一种。
8.如权利要求1所述的一种气雾型清洁凝胶，其特征在于，所述的推进剂为LPG、二甲醚、CO2、N2、HFC-134a、HFO-1234ze中的至少一种。
9.如权利要求1所述的一种气雾型清洁凝胶的制备方法，其特征在于，包括以下步骤：
1) 剂料的制备：按重量份配比，将增溶剂和精油加入到容器中，搅拌均匀，再加入水以搅拌15min，缓慢加入稠化剂，搅拌30min至完全溶解后，加入重油污清洁剂、表面活性剂、添加剂、防腐剂，搅拌50min，最后用酸碱调节剂调节酸碱值至10即可过滤备用；
2) 灌装：按一定充填率将剂料灌装至气雾罐中，加入阀门后进行封口、充填抛射剂，装按头、盖子，即制得气雾型清洁凝胶。
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