CN114686062A - Environment-friendly luminous aerosol paint and preparation method thereof - Google Patents
Environment-friendly luminous aerosol paint and preparation method thereof Download PDFInfo
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- CN114686062A CN114686062A CN202011573800.4A CN202011573800A CN114686062A CN 114686062 A CN114686062 A CN 114686062A CN 202011573800 A CN202011573800 A CN 202011573800A CN 114686062 A CN114686062 A CN 114686062A
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D133/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
- C09D133/04—Homopolymers or copolymers of esters
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/22—Luminous paints
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/20—Diluents or solvents
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/61—Additives non-macromolecular inorganic
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2217—Oxides; Hydroxides of metals of magnesium
- C08K2003/2224—Magnesium hydroxide
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2227—Oxides; Hydroxides of metals of aluminium
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/011—Nanostructured additives
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
- C08L2205/025—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
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- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
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- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Paints Or Removers (AREA)
Abstract
The invention discloses an environment-friendly luminous aerosol paint which comprises, by weight, 16-35 parts of mixed modified acrylic resin, 5-10 parts of chemical silicon acrylic resin, 10-20 parts of an environment-friendly solvent, 4-11 parts of bentonite, 4-11 parts of a wear-resisting agent, 25-40 parts of luminous powder, 2-4 parts of carbon nanotubes, 0.6-1 part of a coupling agent, 0.2-0.8 part of a flatting agent, 0.3-1 part of a defoaming agent and 5-23 parts of an environment-friendly propellant; the product has the advantages of improving the viscosity of the feed liquid and the fluidity of a wet film by preferentially selecting the thixotropic acrylic resin, but has less solid content per se and has good bearing effect on powder materials such as noctilucent powder and the like; the formula is preferred, the luminous brightness is good, and the time is long; aerosol packaging storage stability; the environment-friendly propellant has the advantages of good environmental protection, low GWP, environmental protection, low VOC, safety, environmental protection, aerosol packaging and high construction efficiency. The invention also discloses a preparation method of the noctilucent aerosol paint.
Description
Technical Field
The invention belongs to the technical field of aerosol products, and particularly relates to environment-friendly luminous aerosol paint and a preparation method thereof.
Background
Aerosol Paint (Spray Paint), also known as automatic Spray Paint or hand-operated automatic Spray Paint. The aerosol paint is a self-pressurized packaged product which is prepared by filling resin, solvent, pigment and filler, propellant and the like into an aerosol can and controlling the mixture by a valve release device to spray the mixture in the form of aerosol.
The aerosol paint has the characteristics of flexible and simple construction operation, convenient carrying, good spraying atomization effect, high spraying rate and the like, breaks through the construction method of the traditional paint, and easily solves the difficult problem that the traditional paint is difficult to construct indoors and outdoors. The aerosol paint gains the favor of consumers with convenience, reliability and economy, has greatly increased market demand in recent years, and is widely applied to coating and repairing of objects such as wood furniture, hardware workpieces, building decoration materials, vehicles, mechanical equipment, plastic products and the like.
The luminous paint is mainly formed by dispersing synthetic resin or emulsion, energy-storing luminescent material and other substances, and the paint can emit certain light by means of its energy-storing substance, and can absorb light energy under the irradiation of sunlight, lamp light and visible light, and can emit the absorbed energy in the form of low-frequency visible light under the dark condition. The method can be widely applied to various aspects such as buildings, decorations, advertisements, traffic signs, artificial landscapes and the like, and has wide applicable population and development prospect.
The luminescent material used in the luminescent coating is mainly a rare earth metal material, while China is a large rare earth resource country, and the reserve accounts for more than 80% of the world reserve. This provides convenient conditions for the development of luminescent paint products in China. The luminous paint has wide application range, and can be used in fields of military affairs, traffic, fire fighting and the like. Luminescent coatings have also been developed for various uses in foreign countries, such as in different areas of automobile wheels, bicycle spokes, automobile steering wheels, tunnels, lamp covers, in usa, japan, and also in europe, such as the uk and the netherlands. The luminescent materials in China have advanced technical level in the world, but the application level of the luminescent materials and the luminescent coatings is still different from that of the countries in the United kingdom, the Netherlands, the United states, Japan and the like.
The existing noctilucent paint in the market is mainly sold directly in a barreled form, has more construction steps, higher requirements on constructors and higher construction difficulty; the luminous aerosol type luminous paint has the advantages of convenient construction, portability and extremely superior market prospect, but a luminous aerosol paint product is not found in the domestic market, a smaller amount of luminous aerosol paint products are provided abroad, but the problems of short luminous time, easy precipitation and nozzle blockage are basically solved, the construction effect and the construction mood are influenced, and the popularization and the development of the luminous aerosol paint are seriously influenced.
Therefore, there is a great need for developing a luminous aerosol paint with high suspension, high storage stability and long-lasting luminescence.
Disclosure of Invention
One purpose of the invention is to provide an environment-friendly luminous aerosol paint, and the other purpose is to provide a preparation method thereof; the prescription comprises
16-35 parts of mixed modified acrylic resin
5-10 parts of chemical silicone-acrylate resin
10-20 parts of environment-friendly solvent
4-11 parts of bentonite
4-11 parts of wear-resisting agent
25-40 parts of noctilucent powder
2-4 parts of carbon nanotubes
0.6-1 part of coupling agent
0.2-0.8 part of flatting agent
0.3-1 part of defoaming agent
5-23 parts of an environment-friendly propellant;
the mixed modified acrylic resin is at least one of hydroxyl modified acrylic resin, styrene modified acrylic resin and styrene butadiene modified acrylic resin;
the environment-friendly solvent is at least one of propylene glycol, propanol, isopropanol and ethylene glycol monobutyl ether;
the bentonite is at least one of DeuRheo 211P, DeuRheo 211F and ThiXATROL P220X;
the wear-resisting agent is nano-scale magnesium hydroxide, nano-scale aluminum hydroxide and nano-scale SiO2、At least one of nano-scale graphite powder;
the noctilucent powder is at least one of 100-250-mesh bright MHG-4C, MHG-4D;
the coupling agent is at least one of silane coupling agents CG-C322, CG-A111, CG-A210 and CG-N1213;
the leveling agent is at least one of EFKA FL3740, EFKA FL3741, EFKA FL3745, EFKA FL3939, Borchi GOL LA200 and Borchi GOL LA 2;
the dispersing defoaming agent is at least one of EFKA-3034, EFKA SI 2741, Borchi GEN1252 and Borchi GEN 1015;
the environment-friendly propellant is prepared from carbon dioxide, R134a, LPG =0.1-0.5, 0-10, 1-10 by weight.
The preparation method of the environment-friendly aerosol type noctilucent coating comprises the following steps of dehydrating and cooling the wear-resistant agent, the carbon nanotubes and the noctilucent powder according to the weight part ratio, adding the coupling agent, and stirring uniformly; mixing modified acrylic resin, chemical silicone-acrylate resin, environment-friendly solvent, bentonite, flatting agent and defoaming agent, and stirring uniformly to prepare feed liquid; and (3) subpackaging the feed liquid into an aerosol can according to the specified weight part ratio, then installing a female valve and sealing, filling the corresponding environment-friendly propellant into the aerosol can according to the specified weight part ratio by using an aerosol filling and sealing machine, and packaging to obtain the finished product.
The noctilucent aerosol paint adopting the technical scheme has the following advantages
1. Thixotropic acrylic resin is preferably selected, so that the viscosity of feed liquid and the flowability of a wet film are improved, but the solid content of the thixotropic acrylic resin is low, and the thixotropic acrylic resin has a good bearing effect on powder materials such as noctilucent powder;
2. the formula is optimized, and the comprehensive paint film has good weather resistance, excellent performance, good brightness and long time;
3. aerosol packaging storage stability;
4. the environment-friendly propellant has the advantages of good environmental protection, low GWP, environmental protection, safety, environmental protection, aerosol packaging, combination with a universal female valve, and high construction efficiency.
Detailed description of the invention
The present invention is illustrated by the following examples, but the present invention is not limited to these examples. Modifications to the embodiments of the invention or equivalent substitutions of parts of technical features without departing from the spirit of the invention are intended to be covered by the scope of the claims of the invention.
Example 1
8 parts of nano-scale magnesium hydroxide, 3 parts of carbon nano-tube and 25 parts of bright MHG-4C are mixed according to the weight parts, dehydrated, cooled, added with CG-C3220.3 parts of silane coupling agent and CG-A1110.3 parts and stirred evenly; 25 parts of hydroxyl modified acrylic resin, 10 parts of chemical silicone-acrylic resin, 10 parts of propylene glycol, 0.1 part of DeuRheo 211P, 0.1 part of DeuRheo 211F, 0.1 part of THIXATROL P220X 0.1, 37400.2 parts of EFKA FL, 37410.1 parts of EFKA FL 37450.1 parts, EFKA FL 39390.1 parts, Borchi GOL LA2000.1 parts, Borchi GOL LA 20.1 parts, EFKA-30340.1 parts, EFKA SI 27410.1 parts, Borchi GEN 12520.1 parts and Borchi GEN 10150.1 uniformly mixed parts to prepare feed liquid; subpackaging the feed liquid into aerosol canister according to the specified weight part ratio, then installing universal female valve and sealing, filling 17 parts of corresponding environment-friendly propellant by aerosol filling and sealing machine according to the specified weight part ratio,
the environment-friendly propellant is prepared from carbon dioxide, R134a, LPG = 0.1: 0: 2 according to the specified weight portion, and the finished product is obtained after packaging.
Example 2
1 part of nano-scale magnesium hydroxide, 1 part of nano-scale aluminum hydroxide and nano-scale SiO in parts by weight20.5 portion、1.5 parts of nano-graphite powder, 2 parts of nano-graphite carbon tube, and 2 parts of bright MHG-4D35 parts, dehydrating, cooling, adding a silane coupling agent CG-A2100.1 parts and CG-N12130.5 parts, and stirring uniformly; 8 parts of hydroxyl modified acrylic resin, 1 part of styrene modified acrylic resin, 15 parts of styrene butadiene modified acrylic resin, 7.7 parts of chemical silicon propylene trilobate resin, 1 part of propylene glycol, 3 parts of propanol, 3 parts of isopropanol, 3 parts of ethylene glycol monobutyl ether, 0.2 part of DeuRheo 211P, 0.1 part of DeuRheo 211F, 0.4 part of THIXATROL P220X 0.4, EFKA FL 37400.1 parts, EFKA FL 37410.2 parts, Borchi GOL LA 2000.2 parts, Borchi GOL LA 20.1 parts, EFKA-30340.2 parts, Borchi GEN 12520.1 parts and Borchi GEN 10150.1 parts are uniformly stirred to prepare feed liquid; the feed liquid is subpackaged into an aerosol can according to the specified weight part ratio, then a universal female valve is arranged and sealed, 15 parts of corresponding environment-friendly propellant are filled by an aerosol filling and sealing machine according to the specified weight part ratio, the environment-friendly propellant is carbon dioxide, R134a, LPG = 0.5: 10: 1 according to the specified weight part ratio, and the finished product is obtained after packaging.
Example 3
Nano SiO in certain weight proportion24 portions of、7 parts of nano-scale graphite powder, 4 parts of nano-graphite carbon tubes, 15 parts of bright MHG-4C and 15 parts of bright MHG-4D are dehydrated, cooled, added with 1111 parts of silane coupling agent and stirred evenly; 6 parts of hydroxyl modified acrylic resin, 20 parts of styrene modified acrylic resin, 5.4 parts of chemical silicon acrylic resin, 5 parts of propanol, 5 parts of isopropanol, 3 parts of DeuRheo 211F, 220X 1 parts of THIXATROL P, 37410.3 parts of EFKA FL, 37450.1 parts of EFKA FL, 39390.1 parts of EFKA FL, 2000.1 parts of Borchi GOL LA, EFKA-30340.1 parts of Borchi GEN 10150.9 parts, and uniformly stirring to prepare a feed liquid; the feed liquid is subpackaged into an aerosol can according to the specified weight part ratio, then a universal female valve is arranged and sealed, 7 parts of corresponding environment-friendly propellant are filled by an aerosol filling and sealing machine according to the specified weight part ratio, the environment-friendly propellant is carbon dioxide, R134a, LPG = 0.1: 1 according to the specified weight part ratio, and the finished product is obtained after packaging.
Example 4
2 portions of nano-level aluminum hydroxide and nano-level SiO22 portions of、2 parts of nano-scale graphite powder, 4 parts of carbon nano-tubes, 16 parts of bright MHG-4C and 24 parts of bright MHG-4D are dehydrated and cooled, and silane coupling agents CG-C3220.1 parts, CG-A1110.3 parts and CG-N12130.3 parts are added and stirred evenly; hydroxyl modified acrylic resin, 10 parts of styrene butadiene modified acrylic resin, 9.3 parts of chemical silicon acrylic resin, 3 parts of propylene glycol, 3 parts of propanol, 3 parts of isopropanol, 1 part of ethylene glycol monobutyl ether, 1 part of DeuRheo 211P, 0.5 part of DeuRheo 211F, 220X 3 parts of THIXATROL P, 37400.05 parts of EFKA FL, 37410.05 parts of EFKA FL, 2000.1 parts of Borchi GOL LA, 20.1 parts of Borchi GOL LA, 25 parts of EFKA-30340.1 parts, EFKA SI 27410.1 parts of Borchi GEN 10150.1 parts, and uniformly stirring to prepare feed liquid; the feed liquid is subpackaged into an aerosol can according to the specified weight part ratio, then a universal female valve is arranged and sealed, 5 parts of corresponding environment-friendly propellant are filled by an aerosol filling and sealing machine according to the specified weight part ratio, the environment-friendly propellant is carbon dioxide, R134a, LPG =0.3, LPG = 1, and the finished product is obtained after packaging.
Example 5
4 parts of nano-scale graphite powder, 2 parts of nano-graphite carbon tubes, 10 parts of bright MHG-4C and 15 parts of bright MHG-4D are mixed according to the weight parts, dehydrated, cooled, added with silane coupling agent CG-A2100.1 parts and CG-N12130.5 parts and stirred evenly; 16 parts of styrene modified acrylic resin, 5 parts of chemical silicone-acrylate resin, 11.6 parts of isopropanol, 2 parts of DeuRheo 211P, 220 parts of THIXATROL P220X 9, 37400.1 parts of EFKA FL, 20.7 parts of Borchi GOL LA, 12520.5 parts of Borchi GEN and 10150.5 parts of Borchi GEN, and uniformly stirring to prepare a feed liquid; the feed liquid is subpackaged into an aerosol can according to the specified weight part ratio, then a universal female valve is arranged and sealed, 23 parts of corresponding environment-friendly propellant are filled by an aerosol filling and sealing machine according to the specified weight part ratio, the environment-friendly propellant is carbon dioxide, R134a, LPG = 0.1: 0: 10 according to the specified weight part ratio, and the finished product is obtained after packaging.
Performance testing
1. Drying time is tested according to GB/T1728 1989 paint film and putty film drying time determination method.
2. Paint film hardness is tested according to GB/T6739 & 2006 paint film hardness determination by color paint and varnish pencil method.
3. An adhesion tester was used as specified in GB/T1720-. The needle points mark a circle rolling line pattern with a certain length and overlapped in sequence on the paint film, so that the paint film is divided into 7 parts with different areas.
4. The impact height was 50cm and the weight was (1000. + -.1) g using an HJ13-QCJ coating impact tester, according to the regulations of GB/T1732-1993 [ determination of impact resistance of paint film ].
5. The storage stability is that the noctilucent paint is respectively packed in 15 aerosol cans and 15 small iron cans, the aerosol cans are vacuumized and then sealed and filled with propellant, and the small iron cans are sealed by pressing covers; respectively placing 5 cans in a 50 +/-2 ℃ blast oven, placing 5 cans in a-10 +/-2 ℃ refrigerator, placing 5 cans in a room temperature (blank comparison), sequentially storing for 15d, 30d, 60d and 90d, taking out, shaking uniformly, observing whether thickening, oxidation discoloration, thickening and the like exist or not, and judging whether spraying construction is normal or not.
6. Luminescence time was measured in accordance with GB/T1727-92 general paint film preparation method, which comprises preparing the paint spray samples obtained in the examples, irradiating the paint films after they were dried for 2 hours in natural light, and recording the luminescence time of the samples in the dark.
The results of the performance tests on the environment-friendly luminous aerosol paint and the preparation method thereof obtained in the examples are shown in the following table
Through tests, the finished product of the invention has the advantages of excellent paint film performance, good material liquid stability, stable and long-acting luminescence time, environment-friendly material liquid, convenient use and great development and application prospects.
Claims (10)
1. The environment-friendly luminous aerosol paint is characterized by comprising the following components in parts by weight
16-35 parts of mixed modified acrylic resin
5-10 parts of chemical silicone-acrylate resin
10-20 parts of environment-friendly solvent
4-11 parts of bentonite
4-11 parts of wear-resisting agent
25-40 parts of noctilucent powder
2-4 parts of carbon nanotubes
0.6-1 part of coupling agent
0.2-0.8 part of flatting agent
0.3-1 part of defoaming agent
5-23 parts of an environment-friendly propellant.
2. The environment-friendly luminous aerosol paint as claimed in claim 1, wherein the mixed modified acrylic resin is at least one of hydroxyl modified acrylic resin, styrene modified acrylic resin and styrene butadiene modified acrylic resin.
3. The environment-friendly luminous aerosol paint as claimed in claim 1, wherein the environment-friendly solvent is at least one of propylene glycol, propanol, isopropanol and ethylene glycol monobutyl ether.
4. The environment-friendly luminous aerosol paint as claimed in claim 1, wherein the bentonite is at least one of DeuRheo 211P, DeuRheo 211F and ThiXATROL P220X.
5. The environment-friendly luminous aerosol paint as claimed in claim 1, wherein the wear-resisting agent is at least one of nano magnesium hydroxide, nano aluminum hydroxide, nano SiO2 and nano graphite powder.
6. The environment-friendly luminous aerosol paint as claimed in claim 1, wherein the luminous powder is at least one of bright MHG-4C, MHG-4D with the particle size of 100-250 meshes.
7. The environment-friendly luminous aerosol paint as claimed in claim 1, wherein the coupling agent is at least one of silane coupling agents CG-C322, CG-A111, CG-A210 and CG-N1213.
8. The environment-friendly luminous aerosol paint as claimed in claim 1, wherein the leveling agent is at least one of EFKA FL3740, EFKA FL3741, EFKA FL3745, EFKA FL3939, Borchi GOL LA200 and Borchi GOL LA 2.
9. The environment-friendly luminous aerosol paint as claimed in claim 1, wherein the dispersing defoaming agent is at least one of EFKA-3034, EFKA SI 2741, Borchi GEN1252 and Borchi GEN 1015; the environment-friendly propellant is prepared from carbon dioxide, R134a, LPG =0.1-0.5, 0-10, 1-10 by weight.
10. The environment-friendly luminous aerosol paint as claimed in claim 1, wherein the preparation method comprises the steps of dehydrating and cooling the wear-resistant agent, the carbon nanotubes and the luminous powder in parts by weight, adding the coupling agent, and stirring; mixing modified acrylic resin, chemical silicone-acrylate resin, environment-friendly solvent, bentonite, flatting agent and defoaming agent, and stirring uniformly to prepare feed liquid; and (3) subpackaging the feed liquid into an aerosol can according to the specified weight part ratio, then installing a universal female valve and sealing, filling the corresponding environment-friendly propellant according to the specified weight part ratio by using an aerosol filling and sealing machine, and packaging to obtain the finished product.
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| Application Number | Priority Date | Filing Date | Title |
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| CN202011573800.4A CN114686062A (en) | 2020-12-28 | 2020-12-28 | Environment-friendly luminous aerosol paint and preparation method thereof |
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| Application Number | Priority Date | Filing Date | Title |
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| CN202011573800.4A CN114686062A (en) | 2020-12-28 | 2020-12-28 | Environment-friendly luminous aerosol paint and preparation method thereof |
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| CN114686062A true CN114686062A (en) | 2022-07-01 |
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN116082899A (en) * | 2022-10-18 | 2023-05-09 | 广东自由能科技股份有限公司 | Aerosol paint suitable for tile pavement marking and preparation method thereof |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20160002475A1 (en) * | 2013-03-05 | 2016-01-07 | Peter Kwasny Gmbh | Water-based paint composition for aerosol cans |
| CN109810590A (en) * | 2019-01-31 | 2019-05-28 | 中山市大田汽车护理用品有限公司 | A kind of indoor wall repairs aerosol and preparation method thereof |
-
2020
- 2020-12-28 CN CN202011573800.4A patent/CN114686062A/en active Pending
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20160002475A1 (en) * | 2013-03-05 | 2016-01-07 | Peter Kwasny Gmbh | Water-based paint composition for aerosol cans |
| CN109810590A (en) * | 2019-01-31 | 2019-05-28 | 中山市大田汽车护理用品有限公司 | A kind of indoor wall repairs aerosol and preparation method thereof |
Non-Patent Citations (1)
| Title |
|---|
| 侯瑞祥等: "一种低毒快干型镀锌喷漆", 《涂层与防护》 * |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN116082899A (en) * | 2022-10-18 | 2023-05-09 | 广东自由能科技股份有限公司 | Aerosol paint suitable for tile pavement marking and preparation method thereof |
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