CN114656133B - An anti-viscosity and wear-reducing ultra-precision mold, processing system and method - Google Patents
An anti-viscosity and wear-reducing ultra-precision mold, processing system and method Download PDFInfo
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- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03B—MANUFACTURE, SHAPING, OR SUPPLEMENTARY PROCESSES
- C03B11/00—Pressing molten glass or performed glass reheated to equivalent low viscosity without blowing
- C03B11/06—Construction of plunger or mould
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B23—MACHINE TOOLS; METAL-WORKING NOT OTHERWISE PROVIDED FOR
- B23K—SOLDERING OR UNSOLDERING; WELDING; CLADDING OR PLATING BY SOLDERING OR WELDING; CUTTING BY APPLYING HEAT LOCALLY, e.g. FLAME CUTTING; WORKING BY LASER BEAM
- B23K26/00—Working by laser beam, e.g. welding, cutting or boring
- B23K26/02—Positioning or observing the workpiece, e.g. with respect to the point of impact; Aligning, aiming or focusing the laser beam
- B23K26/06—Shaping the laser beam, e.g. by masks or multi-focusing
- B23K26/064—Shaping the laser beam, e.g. by masks or multi-focusing by means of optical elements, e.g. lenses, mirrors or prisms
- B23K26/0643—Shaping the laser beam, e.g. by masks or multi-focusing by means of optical elements, e.g. lenses, mirrors or prisms comprising mirrors
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B23—MACHINE TOOLS; METAL-WORKING NOT OTHERWISE PROVIDED FOR
- B23K—SOLDERING OR UNSOLDERING; WELDING; CLADDING OR PLATING BY SOLDERING OR WELDING; CUTTING BY APPLYING HEAT LOCALLY, e.g. FLAME CUTTING; WORKING BY LASER BEAM
- B23K26/00—Working by laser beam, e.g. welding, cutting or boring
- B23K26/352—Working by laser beam, e.g. welding, cutting or boring for surface treatment
- B23K26/355—Texturing
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B23—MACHINE TOOLS; METAL-WORKING NOT OTHERWISE PROVIDED FOR
- B23K—SOLDERING OR UNSOLDERING; WELDING; CLADDING OR PLATING BY SOLDERING OR WELDING; CUTTING BY APPLYING HEAT LOCALLY, e.g. FLAME CUTTING; WORKING BY LASER BEAM
- B23K26/00—Working by laser beam, e.g. welding, cutting or boring
- B23K26/70—Auxiliary operations or equipment
- B23K26/702—Auxiliary equipment
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
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- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P40/00—Technologies relating to the processing of minerals
- Y02P40/50—Glass production, e.g. reusing waste heat during processing or shaping
- Y02P40/57—Improving the yield, e-g- reduction of reject rates
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Abstract
本发明属于超精密加工领域,具体提出了一种抗粘减磨超精密模具、加工系统及方法,具体的,本发明提出的超光滑表面和纳米织构复合的光学模具,通过超精密磨削和抛光技术获得超光滑表面的模具后,采用飞秒激光加工技术在模具表面制备纳米织构,在不影响模具的性能以及模压后光学元件表面质量和面型精度的前提下,利用纳米织构降低高温下模具与光学元件的粘接以及模具的磨损。
The invention belongs to the field of ultra-precision machining, and specifically proposes an anti-viscosity and wear-reducing ultra-precision mold, a processing system and a method. After obtaining a mold with an ultra-smooth surface using femtosecond laser processing technology, nano-texture is prepared on the surface of the mold by using femtosecond laser processing technology. Reduces mold-to-optical bonding and mold wear at high temperatures.
Description
技术领域technical field
本发明属于超精密加工领域,具体涉及一种抗粘减磨超精密模具、加工系统及方法。The invention belongs to the field of ultra-precision machining, and in particular relates to an anti-viscosity and wear-reducing ultra-precision mold, a processing system and a method.
背景技术Background technique
模具是制造业的重要基础工艺装备,主要用于高效大批量生产工业产品中的有关零部件和制件,是装备制造业的重要组成部分。模具批量生产的制件具有高效率、高一致性、低耗能耗材、精度和复杂程度较高等优点,因而被广泛的运用于机械、电子、汽车、航空、航天、军工、医疗、生物、能源等行业。目前,模具制造水平已经成为衡量一个国家制造业水平高低的重要标志,也是一个国家的工业产品保持国际竞争力的重要保证之一。Mold is an important basic process equipment in the manufacturing industry. It is mainly used for efficient mass production of related parts and components in industrial products, and is an important part of the equipment manufacturing industry. The mass-produced parts of the mold have the advantages of high efficiency, high consistency, low energy consumption, high precision and complexity, so they are widely used in machinery, electronics, automobiles, aviation, aerospace, military, medical, biological, energy, etc. and other industries. At present, the level of mold manufacturing has become an important symbol to measure the level of a country's manufacturing industry, and it is also one of the important guarantees for a country's industrial products to maintain international competitiveness.
微型复杂结构器件,如微型复杂结构光学元件,因其特殊的几何特征,而具有多种光学功能,可以实现传统光学元件难以完成的功能,在现代光学技术发展中具有重要应用价值。目前,微型复杂结构光学元件的制造方法主要以单点金刚石切削加工、光刻技术和LIGA 技术为主。单点金刚石切削具有较高的加工精度,但是由于玻璃材料在常温下属于脆性材料,因此一次切削进给量非常小,且加工一致性难以保证,不适合批量生产; 光刻技术和LIGA 技术虽然能够完成特征尺寸很小、表面质量很高的微纳结构加工,但该工艺受到生产效率及工艺稳定性的限制,不能很好的满足行业需求。Micro-complex structure devices, such as micro-complex structure optical elements, have a variety of optical functions due to their special geometric characteristics, which can realize functions that are difficult to be accomplished by traditional optical elements, and have important application value in the development of modern optical technology. At present, the manufacturing methods of micro-complex optical components are mainly based on single-point diamond cutting, photolithography and LIGA technology. Single-point diamond cutting has high machining accuracy, but because glass materials are brittle materials at room temperature, the feed rate of one cutting is very small, and the machining consistency is difficult to guarantee, which is not suitable for mass production; although lithography technology and LIGA technology It can complete micro-nano structure processing with small feature size and high surface quality, but this process is limited by production efficiency and process stability, and cannot well meet the needs of the industry.
光学元件模压成形技术在近年来逐渐得到了重视,该技术是指在高温下对模具施加一定的压力从而将模具表面特定的结构复制到受热软化的光学元件表面上,再经退火冷却固化,得到理想的微型复杂结构光学元件。该技术可以实现光学元件的大批量、高效率制造,由于加工过程中不涉及材料的去除,因此能够大幅度减少原材料消耗,降低制造成本,被认为是光学元件制造最有效方法之一。The optical component molding technology has gradually gained attention in recent years. This technology refers to applying a certain pressure to the mold at high temperature to copy the specific structure of the mold surface to the surface of the optical component that is softened by heat, and then annealing, cooling and solidifying to obtain Ideal for miniature and complex optical components. This technology can realize high-volume and high-efficiency manufacturing of optical components. Since the removal of materials is not involved in the processing process, it can greatly reduce the consumption of raw materials and reduce manufacturing costs. It is considered to be one of the most effective methods for manufacturing optical components.
其中,模压成形技术通常在高温下(500-1500℃)进行。目前,由于光学元件的面形精度和表面质量由模具决定,因此现有的模压成形过程中对模具的表面质量要求较高,需要满足模具表面无划痕、破碎、裂纹等缺陷,并且为无任何结构的光滑或超光滑表面。然而,模具表面在高温下易与熔化的光学元件发生粘连,从而降低了模具表面质量和使用寿命,增加了生产成本。此外,在加热-冷却的温度循环和合模-脱模的压力循环作用下,模具会出现热疲劳和应力疲劳,而模具材料的疲劳容易造成模具的磨损与失效。所谓模具磨损,是指在成形过程中,模具工作部分由于高温、高压作用下产生的正常变钝现象。模具破损是指模具发生大的变形或表面有脱落现象产生,导致模具不能正常使用的现象,模具破损一般是由于高温高压作用使微结构产生了塑性流动而丧失成形能力。Among them, the compression molding technology is usually carried out at high temperature (500-1500 ℃). At present, since the surface shape accuracy and surface quality of optical components are determined by the mold, the existing molding process has high requirements on the surface quality of the mold. Smooth or ultra-smooth surface of any structure. However, the mold surface is prone to stick to the melted optical components at high temperature, thereby reducing the mold surface quality and service life, and increasing the production cost. In addition, under the action of heating-cooling temperature cycle and mold-clamping-release pressure cycle, the mold will experience thermal fatigue and stress fatigue, and the fatigue of mold material will easily cause mold wear and failure. The so-called mold wear refers to the normal dulling phenomenon of the working part of the mold due to high temperature and high pressure during the forming process. Mold breakage refers to the phenomenon that the mold is greatly deformed or the surface falls off, resulting in the phenomenon that the mold cannot be used normally. The mold damage is generally caused by the plastic flow of the microstructure caused by high temperature and high pressure, and the loss of forming ability.
同时,近些年来,耐高温超硬材料碳化钨、碳化硅等已经而成为模压成形技术所用模具的主要材料,但是对该超硬材料模具的加工中依然面临许多难题。首先,使用机械去除的方法在这些硬材料表面加工结构阵列效率非常低,有些结构甚至不能加工;其次,由于微细结构阵列尺寸极小化的特点,一旦加工过程中出现瑕疵就无法修复,间接增加了微型复杂结构光学元件的制造成本。At the same time, in recent years, high-temperature superhard materials such as tungsten carbide and silicon carbide have become the main materials for molds used in compression molding technology, but there are still many difficulties in the processing of superhard material molds. First, the efficiency of machining structure arrays on the surface of these hard materials by mechanical removal is very inefficient, and some structures cannot even be machined; secondly, due to the miniaturized size of microstructure arrays, once defects occur during the machining process, they cannot be repaired, and indirectly increase It reduces the manufacturing cost of micro-complex optical components.
发明内容SUMMARY OF THE INVENTION
针对现有技术存在的不足,本发明的目的是提供一种抗粘减磨超精密模具、加工系统及方法。Aiming at the deficiencies of the prior art, the purpose of the present invention is to provide an anti-viscosity and wear-reducing ultra-precision mold, a processing system and a method.
为了实现上述目的,本发明采用的技术方案如下:In order to achieve the above object, the technical scheme adopted in the present invention is as follows:
第一方面,本发明提出了一种抗粘减磨超精密模具,模具的工作面为超光滑表面,所述的超光滑表面上具有纳米织构。In the first aspect, the present invention provides an anti-viscosity and wear-reducing ultra-precision mold, the working surface of the mold is an ultra-smooth surface, and the ultra-smooth surface has nano-texture.
相比于常规的表面无缺陷或无任何织构的光滑或超光滑模具,本发明在超光滑模具表面加工了周期性或规则排布的纳米织构,本发明提出的纳米织构可以提高模具表面硬度,降低模具表面压强,从而改善模具的抗沾减磨性能。本发明提出的织构尺寸为纳米量级,在高温下融化的光学元件由于尺寸效应无法流入纳米织构中,因此超光滑模具表面的纳米织构不会转移到光学元件表面,光学元件的表面质量和面型精度不会受到纳米织构的影响。Compared with the conventional smooth or ultra-smooth mold with no defects or any texture on the surface, the present invention processes periodic or regularly arranged nano-textures on the surface of the ultra-smooth mold. Surface hardness, reducing the surface pressure of the mold, thereby improving the anti-sticking and anti-wear performance of the mold. The texture size proposed by the present invention is in nanometer order, and the optical element melted at high temperature cannot flow into the nanotexture due to the size effect, so the nanotexture on the surface of the ultra-smooth mold will not be transferred to the surface of the optical element, and the surface of the optical element cannot flow into the nanotexture due to the size effect. Quality and surface accuracy are not affected by nanotexturing.
作为进一步的技术方案,当模具的工作面为平面时,位于同一面上的纳米织构的间距相等。As a further technical solution, when the working surface of the mold is a plane, the spacing of the nano-textures on the same surface is equal.
作为进一步的技术方案,当模具的工作面为弧形时,位于同一工作面上的纳米织构的弧度相等。As a further technical solution, when the working surface of the mold is arc-shaped, the arcs of the nano-textures on the same working surface are equal.
作为进一步的技术方案,抗粘减磨超精密模具,包括上模和下模,上模工作面的纳米织构与下模工作面上的纳米织构的间距相等。As a further technical solution, the anti-viscosity and wear-reducing ultra-precision mold includes an upper mold and a lower mold, and the distance between the nano-textures on the working surface of the upper mold and the nano-textures on the working surface of the lower mold is equal.
作为进一步的技术方案,在抗粘减磨超精密模具的工作面表面还镀有一层膜。As a further technical solution, a layer of film is also plated on the working surface of the anti-stick and wear-reducing ultra-precision mold.
第二方面,本发明还提供了一种抗粘减磨超精密模具的加工方法,如下:In the second aspect, the present invention also provides a processing method of an anti-viscosity and wear-reducing ultra-precision mold, as follows:
步骤1获得超光滑表面的模具;Step 1 to obtain a mold with an ultra-smooth surface;
步骤2在模具表面制备纳米织构。
第三方面,本发明还提供了一种用于加工光学元件的超精密模具,包括上模、下模;所述的上模、下模的工作面为超光滑表面,所述的超光滑表面上具有纳米织构;所述的下模固定在加热腔上或者加热腔内;所述模具熔点大于光学元件的熔点;加热腔内的温度大于光学元件的熔点且小于模具的熔点。In a third aspect, the present invention also provides an ultra-precision mold for processing optical components, including an upper mold and a lower mold; the working surfaces of the upper mold and the lower mold are ultra-smooth surfaces, and the ultra-smooth surfaces The upper part has nano-texture; the lower mold is fixed on the heating cavity or in the heating cavity; the melting point of the mold is greater than the melting point of the optical element; the temperature in the heating cavity is greater than the melting point of the optical element and lower than the melting point of the mold.
第四方面,本发明还提供了一种利用所述的抗粘减磨超精密模具加工光学元件的方法,如下:In a fourth aspect, the present invention also provides a method for processing an optical element using the anti-viscosity and wear-reducing ultra-precision mold, as follows:
将抗粘减磨超精密模具的下模固定在加热腔内;Fix the lower mold of the anti-viscosity and wear-reducing ultra-precision mold in the heating cavity;
在下模上方放置待加工光学元件;Place the optical element to be processed above the lower mold;
将抗粘减磨超精密模具的上模固定在光学元件上方;Fix the upper mold of the anti-viscosity and wear-reducing ultra-precision mold above the optical element;
对加热腔进行加热、保温、冷却,获得光学元件。The heating chamber is heated, kept warm, and cooled to obtain an optical element.
第五方面,本发明还提供了一种抗粘减磨超精密模具的加工系统,包括飞秒激光器、空间光调制器、反射镜、二向色镜和物镜;所述的飞秒激光器产生用于加工的激光;所述的空间光调制器对所述的光场进行调整,调整后的激光依次经过反射镜、二向色镜以及物镜后,作用到被加工模具的表面,在被加工模具的表面形成纳米织构。In a fifth aspect, the present invention also provides a processing system for an anti-viscosity and wear-reducing ultra-precision mold, including a femtosecond laser, a spatial light modulator, a mirror, a dichroic mirror and an objective lens; the femtosecond laser is used for generating laser for processing; the spatial light modulator adjusts the light field, and the adjusted laser passes through the reflector, the dichroic mirror and the objective lens in sequence, and then acts on the surface of the processed mold, and the adjusted laser is applied to the surface of the processed mold. The surface forms nanotextures.
作为进一步的技术方案,抗粘减磨超精密模具的加工系统还包括相机,其设置在二向色镜一侧,用于观察工件表面形貌。As a further technical solution, the processing system of the anti-viscosity and wear-reducing ultra-precision mold further includes a camera, which is arranged on one side of the dichroic mirror and is used to observe the surface morphology of the workpiece.
第六方面,利用所述的抗粘减磨超精密模具的加工系统加工周期性等弧长纳米织构模具的方法,其特征在于;建立复杂曲面的参数方程和相应的坐标系;确定单次激光加工织构的数量以及纳米织构间的弧长;计算两两织构之间弧长的水平投影长度,将投影长度代入空间光调制器,并对飞秒激光光场进行调整;利用调整后的激光加工曲面模具,即可获得周期性等弧长纳米织构。In the sixth aspect, a method for processing a periodic equal-arc-length nano-textured mold using the anti-viscosity and wear-reducing ultra-precision mold processing system is characterized in that: establishing a parametric equation of a complex curved surface and a corresponding coordinate system; determining a single The number of laser processing textures and the arc length between nano-textures; calculate the horizontal projection length of the arc length between two textures, substitute the projection length into the spatial light modulator, and adjust the femtosecond laser light field; use the adjustment After laser processing the curved mold, the periodic equal arc length nanotexture can be obtained.
上述本发明的实施例的有益效果如下:The beneficial effects of the above embodiments of the present invention are as follows:
1.本发明打破了常规的模具设计思路,本发明在模具的超光滑表面上加工纳米织构,由于纳米织构的尺寸极小,因此可以保证高温条件下融化的被加工元件无法流进尺寸较小的纳米织构中,因此超精密模具表面的纳米织构不会转移到元件表面,使得模压后的元件拥有较高的表面质量和面型精度。1. The present invention breaks the conventional mold design thinking. The present invention processes nano-texture on the ultra-smooth surface of the mold. Because the size of the nano-texture is extremely small, it can ensure that the processed element melted under high temperature conditions cannot flow into the size. In the smaller nano-texture, the nano-texture on the surface of the ultra-precision mold will not be transferred to the surface of the component, so that the molded component has high surface quality and surface accuracy.
2. 本发明的模具织构区域会出现硬度增加的现象,因此加工纳米织构会提高模具的硬度,改善其耐磨性能;同时,纳米织构增加了模具受力面积,降低了模具表面压强,可以提高模具抗粘接能力,并进一步改善其耐磨性能。2. The phenomenon of increased hardness will occur in the mold texture area of the present invention, so processing the nano texture will increase the hardness of the mold and improve its wear resistance; at the same time, the nano texture increases the force area of the mold and reduces the surface pressure of the mold. , which can improve the anti-adhesion ability of the mold and further improve its wear resistance.
3.本发明提出的超光滑表面和纳米织构复合的光学模具加工方法,通过超精密磨削和抛光技术获得超光滑表面的模具后,采用飞秒激光加工方法或者聚焦离子束或电子束在模具表面制备纳米织构,在不影响模具的性能以及模压后光学元件表面质量和面型精度的前提下,利用纳米织构降低高温下模具与光学元件的粘接以及模具的磨损。3. The ultra-smooth surface and nano-texture composite optical mold processing method proposed by the present invention, after obtaining the mold with ultra-smooth surface through ultra-precision grinding and polishing technology, adopt femtosecond laser processing method or focus ion beam or electron beam in The nano-texture is prepared on the surface of the mold. On the premise of not affecting the performance of the mold and the surface quality and surface accuracy of the optical element after molding, the nano-texture is used to reduce the adhesion between the mold and the optical element and the wear of the mold under high temperature.
4.本发明提出的等弧长加工方法,可以实现曲面模具表面一次性多个具有统一间距阵列结构的加工,大大提高织构的加工效率,并进一步改善模具表面抗沾减磨性能,延长模具使用寿命。4. The equal arc length processing method proposed by the present invention can realize the processing of multiple array structures with uniform spacing on the surface of the curved mold at one time, greatly improve the processing efficiency of the texture, further improve the anti-sticking and wear-reducing performance of the mold surface, and extend the mold surface. service life.
5.本发明提出了一种模具表面纳米织构的加工系统,通过空间光调制器对飞秒激光光斑的定向调制,可以在模具表面获得多种形状结构的纳米结构,从而实现模具表面极小化结构的高效加工,降低生产成本。5. The present invention proposes a nano-texture processing system on the surface of the mold. Through the directional modulation of the femtosecond laser spot by the spatial light modulator, nano-structures of various shapes and structures can be obtained on the surface of the mold, thereby realizing the extremely small surface of the mold. The efficient processing of the chemical structure reduces the production cost.
附图说明Description of drawings
构成本发明的一部分的说明书附图用来提供对本发明的进一步理解,其中,附图中模具的尺寸为毫米量级以上,模具表面的纳米织构仅为纳米量级,为了表示纳米织构的形状以及结构特点,对纳米织构均进行了放大处理,实际的纳米结构面积(尺寸)在模具表面所占的比例非常小。本发明的示意性实施例及其说明用于解释本发明,并不构成对本发明的不当限定。The accompanying drawings, which form a part of the present invention, are used to provide a further understanding of the present invention, wherein the dimensions of the mold in the drawings are on the order of millimeters or more, and the nanotexture on the surface of the mold is only on the order of nanometers. The shape and structural characteristics of the nano-texture have been enlarged, and the actual nano-structure area (size) accounts for a very small proportion of the mold surface. The exemplary embodiments of the present invention and their descriptions are used to explain the present invention, and do not constitute an improper limitation of the present invention.
图1是实施例1中公开的梯形截面的抗粘减磨超精密模具示意图;1 is a schematic diagram of the anti-viscosity and wear-reducing ultra-precision mold of the trapezoidal cross-section disclosed in Example 1;
图2是实施例1中公开的三角形锯齿截面的抗粘减磨超精密模具示意图;2 is a schematic diagram of an anti-viscosity and wear-reducing ultra-precision mold of triangular sawtooth cross-section disclosed in Example 1;
图3是实施例1中公开的抗粘减磨超精密曲面模具示意图;3 is a schematic diagram of the anti-viscosity and wear-reducing ultra-precision curved mold disclosed in Example 1;
图4是实施例1中公开的镀膜后的抗粘减磨超精密模具;Fig. 4 is the anti-stick and wear-reducing ultra-precision mold after coating disclosed in embodiment 1;
图5是实施例2中公开的抗粘减磨超精密模具加工示意图;5 is a schematic diagram of the processing of the anti-viscosity and wear-reducing ultra-precision mold disclosed in Example 2;
图6是实施例3中公开的纳米织构曲面模具模压过程示意图;6 is a schematic diagram of the molding process of the nano-textured curved surface mold disclosed in Example 3;
图7是实施例3中公开的纳米织构梯形截面模具模压过程示意图;7 is a schematic diagram of the molding process of the nano-textured trapezoidal cross-section mold disclosed in Example 3;
图8 是实施例3中公开的纳米织构三角形截面模具模压过程示意图;8 is a schematic diagram of the molding process of the nano-textured triangular section mold disclosed in Example 3;
图9 是实施例3中公开的纳米织构模具表面镀膜示意图;9 is a schematic diagram of the surface coating of the nano-textured mold disclosed in Example 3;
图中:1 CCD相机、2 反射镜、3飞秒激光器、4 空间光调制器、5 反射镜、6 二向色镜、7 物镜、8 纳米织构、9 模具、10 上模、11 光学元件、12 下模、13 镀膜。In the picture: 1 CCD camera, 2 mirrors, 3 femtosecond lasers, 4 spatial light modulators, 5 mirrors, 6 dichroic mirrors, 7 objective lenses, 8 nanostructures, 9 molds, 10 upper molds, 11 optical elements , 12 lower die, 13 coating.
具体实施方式Detailed ways
应该指出,以下详细说明都是例示性的,旨在对本发明提供进一步的说明。除非另有指明,本发明使用的所有技术和科学术语具有与本发明所属技术领域的普通技术人员通常理解的相同含义。It should be noted that the following detailed description is exemplary and intended to provide further explanation of the invention. Unless otherwise defined, all technical and scientific terms used herein have the same meaning as commonly understood by one of ordinary skill in the art to which this invention belongs.
需要注意的是,这里所使用的术语仅是为了描述具体实施方式,而非意图限制根据本发明的示例性实施方式。如在这里所使用的,除非本发明另外明确指出,否则单数形式也意图包括复数形式,此外,还应当理解的是,当在本说明书中使用术语“包含”和/或“包括”时,其指明存在特征、步骤、操作、器件、组件和/或它们的组合;It should be noted that the terminology used herein is for the purpose of describing specific embodiments only, and is not intended to limit the exemplary embodiments according to the present invention. As used herein, unless the invention clearly dictates otherwise, the singular is intended to include the plural as well, and it is also to be understood that when the terms "comprising" and/or "including" are used in this specification, Indicate the presence of features, steps, operations, devices, components and/or combinations thereof;
名词解释:本发明中“超精密模具”的形状精度为亚微米级,表面粗糙度≤10nm;“超光滑表面”的表面粗糙度≤1nm;“纳米织构”是指织构的尺寸在纳米级。Explanation of terms: in the present invention, the shape accuracy of the "ultra-precision mold" is sub-micron, and the surface roughness is ≤10 nm; the surface roughness of the "ultra-smooth surface" is ≤1 nm; class.
本发明中的纳米织构,也可以被称为周期性纳米结构。The nanotextures in the present invention can also be referred to as periodic nanostructures.
实施例1Example 1
本发明的一种典型的实施方式中,如图1-图3所示,本实施例提供了多种抗粘减磨超精密模具,模具的工作面为超光滑表面,超光滑表面上具有纳米织构,其中工作面的形状可以是平面也可以是曲面,如图1所示,为梯形截面的抗粘减磨超精密模具示意图,在梯形截面的抗粘减磨超精密模具工作面上加工有若干圆坑式的纳米织构;如图2所示,为三角形锯齿截面的抗粘减磨超精密模具示意图;在三角形截面的抗粘减磨超精密模具工作面上加工有若干如水滴状的纳米织构;如图3所示,图3为抗粘减磨超精密曲面模具示意图;在曲面的抗粘减磨超精密模具工作面上加工有若干圆坑式的纳米织构。In a typical embodiment of the present invention, as shown in FIG. 1 to FIG. 3 , this embodiment provides a variety of anti-viscosity and wear-reducing ultra-precision molds, the working surface of the mold is an ultra-smooth surface, and the ultra-smooth surface has nano Texture, in which the shape of the working surface can be either a plane or a curved surface. As shown in Figure 1, it is a schematic diagram of the anti-viscosity and wear-reducing ultra-precision mold with trapezoidal cross-section. There are several nano-textures in the form of circular pits; as shown in Figure 2, it is a schematic diagram of the anti-viscosity and wear-reducing ultra-precision mold with triangular sawtooth cross-section; on the working surface of the anti-viscosity and wear-reducing ultra-precision mold with triangular cross-section, there are a number of water droplets. As shown in Figure 3, Figure 3 is a schematic diagram of the anti-viscosity and wear-reducing ultra-precision curved mold; on the working surface of the anti-viscosity and wear-reducing ultra-precision ultra-precision mold, a number of nano-textures are processed.
本实施例提出的抗粘减磨超精密模具打破了常规的模具设计思路,在超精密加工领域,为了保证加工件的精度,一般要求模具表面越光滑越好,而本申请则打破了常规的思路,提出在模具的超光滑表面上加工纳米织构,由于纳米织构的尺寸极小,因此可以保证高温条件下融化的被加工元件无法流进尺寸较小的纳米织构中,因此超精密模具表面的纳米织构不会转移到元件表面,使得模压后的元件拥有较高的表面质量和面型精度。The anti-stick and wear-reducing ultra-precision mold proposed in this embodiment breaks the conventional mold design idea. In the field of ultra-precision machining, in order to ensure the accuracy of the workpiece, the smoother the mold surface is generally required, and the present application breaks the conventional mold. The idea is to process the nano-texture on the ultra-smooth surface of the mold. Since the size of the nano-texture is extremely small, it can ensure that the processed components melted under high temperature conditions cannot flow into the smaller-sized nano-texture, so the ultra-precision The nano-texture of the mold surface will not be transferred to the component surface, so that the molded component has high surface quality and surface accuracy.
本实施例中模具的纳米织构区域会出现硬度增加的现象,因此加工纳米织构会提高模具的硬度,改善其耐磨性能;同时,纳米织构增加了模具受力面积,降低了模具表面压强,可以提高模具抗粘接能力,并进一步改善其耐磨性能。In this embodiment, the nano-texture area of the mold will increase the hardness, so processing the nano-texture will increase the hardness of the mold and improve its wear resistance; at the same time, the nano-texture increases the force-bearing area of the mold and reduces the surface of the mold. The pressure can improve the anti-adhesion ability of the mold and further improve its wear resistance.
为了进一步发挥纳米织构减粘抗磨的性能,工件表面上的纳米织构需保持统一的间距;即当模具的工作面为平面时,位于同一面上的纳米织构的间距相等,如图1所示,其工作面为多个高低设置的平面,位于同一平面上的纳米织构的间距相等,位于不同平面上的纳米织构的间距可以相等,也可以不相等,具体根据实际加工要求进行设置。如图2所示,其工作面为多个斜面,位于同一个斜面上的纳米织构的间距相等,位于不同斜面上的纳米织构的间距可以相等,也可以不相等;当模具的工作面为曲面时,位于整个工作面上的纳米织构的弧度相等,具体的如图3所示,模具的工作面为一个连续的曲面,位于整个工作面上的纳米织构的弧度相等。In order to further exert the viscosity-reducing and anti-wear properties of nano-textures, the nano-textures on the workpiece surface need to maintain a uniform spacing; that is, when the working surface of the mold is flat, the nano-textures on the same surface have the same spacing, as shown in the figure As shown in Figure 1, the working surface is a plurality of planes with high and low settings. The spacing of nano-textures on the same plane is equal, and the spacing of nano-textures on different planes can be equal or unequal, depending on the actual processing requirements. Make settings. As shown in Figure 2, the working surface is a plurality of inclined planes, and the spacing of nanotextures on the same inclined plane is equal, and the spacing of nanotextures on different inclined planes can be equal or unequal; when the working surface of the mold is When it is a curved surface, the radians of the nano-textures on the entire working surface are equal. Specifically, as shown in Figure 3, the working surface of the mold is a continuous curved surface, and the radians of the nano-textures on the entire working surface are equal.
更为具体的,抗粘减磨超精密模具,包括上模和下模,上模工作面的纳米织构与下模工作面上的纳米织构的间距相等,或者不等,具体根据实际需要进行设置即可。More specifically, the anti-viscosity and wear-reducing ultra-precision mold includes an upper mold and a lower mold. The distance between the nano-textures on the working surface of the upper mold and the nano-textures on the working surface of the lower mold is equal or different, depending on the actual needs. Just set it up.
进一步的,抗粘减磨超精密模具的材料主要包括镍磷合金,玻璃碳,碳化硅,碳化钨,单晶硅,模具钢,石英玻璃,铜镍合金,聚甲基丙烯酸甲酯等,其中,经超精密磨削和抛光后的模具表面粗糙度≤1nm。Further, the materials of anti-sticking and anti-wear ultra-precision molds mainly include nickel-phosphorus alloy, glass carbon, silicon carbide, tungsten carbide, single crystal silicon, mold steel, quartz glass, copper-nickel alloy, polymethyl methacrylate, etc., among which , the surface roughness of the mold after ultra-precision grinding and polishing is less than or equal to 1nm.
更进一步的,本实施例中的模具表面的纳米织构可以是直线沟槽、交叉沟槽和周期性圆坑等;在图6所示的模具中,模具表面加工的就是直线沟槽,交叉沟槽是由两个不同方向的直线沟槽交叉形成,周期性圆坑是指在模具表面形成多个独立的坑,坑的形状为半圆形、或者半球形、弧形等;至于各种沟槽的具体尺寸,一般要求如下:Further, the nano-texture of the mold surface in this embodiment can be straight grooves, intersecting grooves, periodic circular pits, etc.; in the mold shown in FIG. The groove is formed by the intersection of two straight grooves in different directions. The periodic circular pit refers to the formation of multiple independent pits on the surface of the mold. The shape of the pit is semicircle, or hemisphere, arc, etc.; The specific dimensions of the groove, the general requirements are as follows:
直线沟槽或者交叉沟槽形的纳米织构,其沟槽的宽度≤100nm,深度≤50nm;周期性圆坑形的纳米织构,圆坑的直径≤100nm,深度≤50nm;同时,在直线沟槽和周期性圆坑纳米织构中,沟槽和圆坑间距可以为100-500nm。Linear groove or cross groove-shaped nano-texture, the width of the groove is ≤ 100nm, the depth is ≤ 50 nm; the nano-texture of periodic circular pit shape, the diameter of the circular pit is ≤ 100 nm, and the depth is ≤ 50 nm; at the same time, in the straight line In the groove and periodic circular pit nanotexture, the distance between the groove and the circular pit can be 100-500 nm.
进一步的,纳米织构的模具工作面表面还可以进行镀膜,如图4所示,通过镀膜可以进一步提升模具抗沾减磨性能,同时,织构化的表面能够提升模具表面与镀膜材料的结合强度,改善镀膜效果。具体的,镀膜的厚度可以为10-20nm;镀膜的材料一般包括三种,三种材料任选其一即可,具体的包括:(1)金属或贵金属合金膜,如 Pt-Ir、Ir-Re合金;(2)陶瓷膜,如TaN、TiAIN和CrWN;(3)碳基膜,如类金刚石(DLC)。Further, the surface of the nano-textured mold working surface can also be coated, as shown in Figure 4, the coating can further improve the anti-sticking and wear-reducing performance of the mold, and at the same time, the textured surface can improve the mold surface and the coating material. strength, improve the coating effect. Specifically, the thickness of the coating can be 10-20 nm; the coating materials generally include three kinds, and one of the three materials can be selected, specifically including: (1) metal or precious metal alloy films, such as Pt-Ir, Ir- Re alloys; (2) ceramic films such as TaN, TiAIN and CrWN; (3) carbon-based films such as diamond-like carbon (DLC).
实施例2Example 2
本实施例还提供了一种抗粘减磨超精密模具的加工方法,步骤1获得超光滑表面的模具;步骤2在模具表面制备纳米织构;具体的,先通过超精密磨削和抛光方法获得超光滑表面的模具后,再采用飞秒激光加工方法或者聚焦离子束或电子束在模具表面制备纳米织构。The present embodiment also provides a method for processing an anti-viscosity and wear-reducing ultra-precision mold. In step 1, a mold with an ultra-smooth surface is obtained; in
进一步的,由于超精密磨削和抛光方法是采用现有加工方法进行的,因此在此不进行赘述了。Further, since the ultra-precision grinding and polishing methods are performed by using the existing processing methods, they will not be described in detail here.
进一步的,上述的飞秒激光技术可以加工平面和曲面的模具;聚焦离子束或电子束主要加工平面模具。Further, the above-mentioned femtosecond laser technology can process flat and curved molds; focused ion beam or electron beam mainly processes flat molds.
本实施例中重点描述一下飞秒激光加工方法,其中飞秒激光加工方法采用的加工系统如图5所示,其包括飞秒激光器3、空间光调制器4、反射镜2、反射镜5、二向色镜6、物镜7和CCD相机1组成。飞秒激光器3产生用于加工的激光,进入空间光调制器4,其可对激光光场进行调整,而后激光经过反射镜2、反射镜5二向色镜6以及物镜7,作用到物体表面,从而实现工件的加工。通过利用空间光调制器4对激光振幅、相位、偏振态和相干性等的调制,可以获得平行直线阵列、交叉直线阵列和圆环阵列等多种形状的光场分布。采用调制后的激光对曲面模具进行加工时,相比于传统激光加工中的单点或逐条直线沟槽加工,本系统一次性可以加工多个圆形凹坑、直线沟槽或者交叉沟槽等不同形状的纳米织构,大大增加了加工面积,提升了激光加工效率。In this embodiment, the femtosecond laser processing method is mainly described. The processing system used in the femtosecond laser processing method is shown in FIG. 5, which includes a
二向色镜6用于光谱分光,可以选择性的透过或反射一定波长的激光。本系统用的飞秒激光波长为800纳米,为了实现激光透过、可见光反射的功能,选择800nm及以上波长可透过、800nm以下波长不可透过的二向色镜6。The
CCD相机1用于观察工件表面形貌。物体表面的可见光经过二向色镜6后反射到CCD相机1,可以实现工件加工前后以及加工过程中表面形貌的观察,便于激光对焦以及工件表面形貌分析。The CCD camera 1 is used to observe the surface topography of the workpiece. The visible light on the surface of the object is reflected to the CCD camera 1 after passing through the
采用飞秒激光在模具表面加工纳米织构,从而改善模具的抗粘接以及抗磨损性能。空间光调制器可以改变激光光场的分布,从而一次性加工多个圆形凹坑、直线沟槽或者交叉沟槽等不同形状的纳米织构。Femtosecond laser is used to process nano-texture on the surface of the mold, thereby improving the anti-adhesion and anti-wear properties of the mold. The spatial light modulator can change the distribution of the laser light field, so as to process multiple nano-textures of different shapes such as circular pits, straight grooves or cross grooves at one time.
为了进一步发挥纳米织构减粘抗磨的性能,工件表面上的织构需保持统一的间距。通过空间光调制器生成周期性激光光场,可以在梯形截面模具以及三角形截面模具表面进行统一间距纳米织构的加工。由于圆弧截面模具具有一定的曲率,因此空间光调制器生成的周期性光场无法在其表面加工出统一间距的纳米织构。In order to further exert the viscosity-reducing and anti-wear properties of nanotextures, the textures on the workpiece surface need to maintain a uniform spacing. By generating a periodic laser light field with a spatial light modulator, nanotextures with uniform pitch can be processed on the surfaces of trapezoidal cross-section molds and triangular cross-section molds. Due to the curvature of the circular-arc cross-section mold, the periodic light field generated by the spatial light modulator cannot process nanotextures with uniform spacing on its surface.
下面针对曲面模具表面等弧长周期性纳米织构的加工方法,进行详细说明,包括以下步骤:The following is a detailed description of the processing method of the arc-length periodic nanotexture on the surface of the curved mold, including the following steps:
首先,建立复杂曲面的参数方程,建立相应的坐标系,复杂曲面截面的方程一般如下所示:First, establish the parametric equation of the complex surface and establish the corresponding coordinate system. The equation of the complex surface section is generally as follows:
(1) (1)
式(1)中,R表示顶点半径,K表示圆锥系数,均为曲面模具的本征参数。In formula (1), R represents the vertex radius, and K represents the cone coefficient, both of which are intrinsic parameters of the surface mold.
其次,确定单次激光加工织构的数量以及织构间的距离(即弧长),如图4所示,使得弧长l1=l2。在已知l1的情况下,求出弦ab的长度lab,如下所示:Second, determine the number of textures processed by a single laser and the distance between the textures (ie arc length), as shown in Figure 4, so that the arc length l 1 =l 2 . Given l 1 , find the length of the string ab, ab , as follows:
(2) (2)
(3) (3)
式(2)和(3)中,θ3为弧ab对应的圆心角,r为a、b两点对应的半径,由于弧长的距离在纳米量级,因此在计算过程中使得两点对应的半径近似相等。直线ef为曲面在b点的切线,b点的斜率即对(1)式求导,θ2为直线bd和直线be的夹角,通过下式求出:In formulas (2) and (3), θ 3 is the central angle corresponding to the arc ab, and r is the radius corresponding to the two points a and b. Since the distance between the arc lengths is in the order of nanometers, the two points correspond to each other in the calculation process. radii are approximately equal. The straight line ef is the tangent of the curved surface at point b, the slope of point b is derived from the formula (1), and θ 2 is the angle between the straight line bd and the straight line be, which can be obtained by the following formula:
(4) (4)
因此可以求出直线bd的长度,即弧ab在y方向的投影,如下式所示:Therefore, the length of the straight line bd can be obtained, that is, the projection of the arc ab in the y direction, as shown in the following formula:
(5) (5)
同理,可求得弧bc在y方面的投影长度d2。Similarly, the projection length d 2 of arc bc in y can be obtained.
在曲面模具表面完成纳米织构的种类、数量以及间隔的设计后,采用该方法计算两两织构之间的弧长在y方向上的投影长度,将该长度代入空间光调制器,并对飞秒激光光场进行调整。利用调整后的激光加工曲面模具,即可获得周期性等弧长纳米织构。After completing the design of the type, quantity and interval of nanotextures on the surface of the curved mold, this method is used to calculate the projection length of the arc length between the two textures in the y direction, and the length is substituted into the spatial light modulator, and the The femtosecond laser light field is adjusted. Using the adjusted laser to process the curved mold, the periodic equal arc length nanotexture can be obtained.
实施例3Example 3
本实施例提供了一种用于加工光学元件的加工系统及方法,采用高温模压成形的系统及方法进行批量制造光学元件,其中,系统包括实施例1中公开的抗粘减磨超精密模具;更为具体的,用于加工光学元件的加工系统包括上模、下模;上模、下模的工作面为超光滑表面,超光滑表面上具有纳米织构;下模固定在加热腔上或者加热腔内;模具熔点大于光学元件的熔点;加热腔内的温度大于光学元件的熔点且小于模具的熔点。其中上模和下模的具体结构与实施例1基本相同,在此不进行赘述了。This embodiment provides a processing system and method for processing optical elements, and adopts the system and method for high-temperature compression molding to manufacture optical elements in batches, wherein the system includes the anti-viscosity and wear-reducing ultra-precision mold disclosed in Embodiment 1; More specifically, the processing system for processing optical elements includes an upper mold and a lower mold; the working surfaces of the upper mold and the lower mold are ultra-smooth surfaces, and the ultra-smooth surfaces have nano-textures; the lower mold is fixed on the heating cavity or In the heating cavity; the melting point of the mold is greater than the melting point of the optical element; the temperature in the heating cavity is greater than the melting point of the optical element and lower than the melting point of the mold. The specific structures of the upper mold and the lower mold are basically the same as those in Embodiment 1, and will not be repeated here.
具体的加工方法如下:The specific processing method is as follows:
首先,将带有纳米织构的模具下模12固定在高温加热腔内或者加热腔上,而后在其上方放置待加工光学元件11,最后将同样带有纳米织构的模具上模10固定在光学元件上方,对加热腔进行加热、保温、冷却等一系列操作后,即可获得一定形状尺寸的光学元件。First, fix the
其中,光学元件11与模具的熔点不同,在模压成形加工过程中,加热腔内的温度需要大于光学元件的熔点,小于模具的熔点。模压过程中,光学元件受热软化,材料发生流动,从而填充到模具特定的结构内。填充时,材料与模具表面发生接触,在高温、往复以及表面相互作用下,模具表面会出现粘接破损以及摩擦磨损现象,从而进一步影响模具以及成形后光学元件的面形精度。通过在模具表面加工纳米织构,包括直线沟槽、交叉沟槽和周期性圆坑等,可以有效的增加材料与模具的接触面积,使得接触面上的压强减小,从而降低了模压过程中的粘接作用以及模具的磨损。同时,模具表面加工纳米织构的区域会出现硬度增加的现象,从而提升了模具表面硬度,可以进一步降低模具的磨损,延长模具寿命,提高生产效率。The melting point of the
本实施例中,因高温融化的光学元件无法填充(流入)到尺寸较小的纳米织构中,因此光学元件仅会通过模压成形技术获得特定截面(梯形、三角形或其他复杂形状截面)的结构,而超光滑模具表面的纳米织构不会转移到光学元件表面,因此纳米织构不会影响模压后光学元件的表面质量和面型精度。In this embodiment, the optical element melted at high temperature cannot be filled (flowed into) into the nano-texture of smaller size, so the optical element can only obtain a structure with a specific cross-section (trapezoid, triangular or other complex shape cross-section) through the molding technology , and the nanotexture of the ultra-smooth mold surface will not be transferred to the surface of the optical element, so the nanotexture will not affect the surface quality and surface accuracy of the optical element after molding.
本实施例中,模具上模10和模具下模具12的材料主要包括镍磷合金,玻璃碳,碳化硅,碳化钨,单晶硅,模具钢,石英玻璃,铜镍合金,聚甲基丙烯酸甲酯等,其中,经超精密磨削和抛光后的模具表面粗糙度≤1nm。In this embodiment, the materials of the
本实施例中,模具上模10和模具下模具12表面的纳米织构主要包括直线沟槽、交叉沟槽和周期性圆坑等。其中,对于沟槽纳米织构,沟槽的宽度沟槽的宽度≤100nm,深度≤50nm;对于圆坑纳米织构,圆坑的直径≤100nm,深度≤50nm。同时,在直线沟槽和周期性圆坑纳米织构中,沟槽和圆坑间距可以为100-500nm。In this embodiment, the nano-textures on the surfaces of the
本实施例中,采用离子溅射法在加工完纳米织构的模具表面进行镀膜13,如图9所示;通过镀膜可以进一步提升模具抗沾减磨性能,同时,织构化的表面能够提升模具表面与镀膜材料的结合强度,改善镀膜效果。其中,镀膜的厚度为10-20nm;镀膜的材料主要包括三种:(1)金属或贵金属合金膜,如 Pt-Ir、Ir-Re合金;(2)陶瓷膜,如TaN、TiAIN和CrWN;(3)碳基膜,如类金刚石(DLC),三种材料选着其中一种即可。In this embodiment, the ion sputtering method is used to coat the surface of the nano-textured
上述加工方法,在不影响模具的性能以及模压后光学元件表面质量和面型精度的前提下,利用纳米织构降低高温下模具与光学元件的粘接以及模具的磨损。The above processing method uses nano-texture to reduce the adhesion between the mold and the optical element and the wear of the mold under the premise of not affecting the performance of the mold and the surface quality and surface accuracy of the optical element after molding.
以上所述仅为本发明的优选实施例而已,并不用于限制本发明,对于本领域的技术人员来说,本发明可以有各种更改和变化。凡在本发明的精神和原则之内,所作的任何修改、等同替换、改进等,均应包含在本发明的保护范围之内。The above descriptions are only preferred embodiments of the present invention, and are not intended to limit the present invention. For those skilled in the art, the present invention may have various modifications and changes. Any modification, equivalent replacement, improvement, etc. made within the spirit and principle of the present invention shall be included within the protection scope of the present invention.
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