CN114631530B - Surfactant compositions for controlling or preventing insects and methods of use thereof - Google Patents

Surfactant compositions for controlling or preventing insects and methods of use thereof Download PDF

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Publication number
CN114631530B
CN114631530B CN202111191614.9A CN202111191614A CN114631530B CN 114631530 B CN114631530 B CN 114631530B CN 202111191614 A CN202111191614 A CN 202111191614A CN 114631530 B CN114631530 B CN 114631530B
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surfactant composition
insects
present disclosure
insect
controlling
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CN114631530A (en
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江丰明
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Huajie Chemical Shanghai Co ltd
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Huajie Chemical Shanghai Co ltd
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    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N41/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a sulfur atom bound to a hetero atom
    • A01N41/02—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a sulfur atom bound to a hetero atom containing a sulfur-to-oxygen double bond
    • A01N41/04—Sulfonic acids; Derivatives thereof

Abstract

The present disclosure provides a surfactant composition for controlling or controlling insects and a method of using the same, wherein the surfactant composition is formed by combining alkyl sulfosuccinate with a specific humectant, and is applied to insects in proper dosages and embodiments to rapidly reduce or eliminate the motility of the insects, to alleviate the damage of the insects to agriculture, or to reduce the loss of crops and economy. In addition, the present disclosure may avoid abuse of chemical pesticides, use of unauthorized pesticides, contamination of certain toxins, or enhancement of insect resistance, and the surfactant compositions of the present disclosure are free of volatile chemicals, free of any fluorine, silicon, or phosphorus based compounds, or free of any aromatic compounds. It follows that the present disclosure may reduce environmental pollution and deterioration or adverse effects on human and animal health.

Description

Surfactant compositions for controlling or preventing insects and methods of use thereof
Technical Field
The present disclosure relates to a surfactant composition for controlling or controlling insects and methods of use thereof.
Background
Cockroaches are omnivorous insects with hundreds of millions of years of evolution history, which are highly productive and harbor bacteria on themselves, and are therefore widely recognized as a pest. Ants may harm crops and protect pests, for example, solenopsis invicta may bite with big jaws and secrete formic acid (formic acid) from the abdomen end to stimulate the bite wound, resulting in red swelling and pain of affected parts. Longicorn is a coleopteran insect whose larvae feed under the bark and, after the age increases, dig into and eat the wood, causing decay of the woods and wooden building, thus causing harm to the human living environment. The scarab beetles are the general name of insects of the family scarab beetle, and adults eat tender buds, new leaves and flowers of fruit trees, which cause economic losses of planted or recuperated flowers, fruit trees and crops.
In addition, mosquitoes transmit diseases (such as dengue fever, malaria, yellow fever, zkarst virus, filariasis, japanese encephalitis, west nile virus, chikungunya fever, etc.) from one host to another during ingestion, so about 7 million people are infected with the mosquitoes each year, and 1 person per 17 people die of the diseases transmitted by the mosquitoes, so mosquitoes are rated as one of the most dangerous animals worldwide. Wasps wake up from hibernation in spring, often bite people around their nest, and because their venom can trigger the nervous system of the person being bitten, skin allergic reactions such as swelling, pain and itching of affected parts are caused. Fleas are small, wing-free and jumping parasitic insects, and parasitic on the human body often cause allergic dermatitis and biting dermatitis, so that human skin generates pimples with different sizes and difficult itching. Spiders are of the amputation phylum, not strictly insects, but a large number of spiders have poison glands, which may affect the health of humans, and a small number of spiders have a more fatal risk.
Secondly, the locust is an insect with considerable harm, and the locust clusters fly fast to cause damage to large-area crops, so that crop resources and grains are affected. Recent research published in Nature journal 584, p.584-588, 2020, states that the factor triggering locust bunching is known as the pheromone (pheomone) of 4-vinyl anisole "4-vinylanisole" (4 VA), and that only 4-5 locust bunches are required to produce and release 4VA, which specifically causes an alkalinity sensory response on the locust antenna, attracting surrounding locust bunches. Recent research publications in journal of scientific Advances (Science Advances, jan.23, 2019) indicate that, by chemical analysis, benzyl cyanide (PAN) can be detected in all tissues and fluids of the group locust, but is not present in the solitary locust, so the group locust reduces predation of birds by PAN and serves as an olfactory characteristic signal in locust defense.
It is known that insects may have many effects on human life safety, food resources or living environment, but conventional chemical pesticides or pesticides and other harmful substances are widely applied to insects in various places for a long time, and some insects have been resistant to the harmful substances, so that the effects after application are greatly reduced. In addition, conventional chemical pesticides or insecticides often contain a large amount of volatile chemicals/organic solvents for rapid contact with insect surfaces, are prone to environmental pollution, and may also be hazardous to human and poultry health, and are therefore difficult and impossible to apply in large amounts to insects living or flying in groups.
Accordingly, in order to solve the above problems, there is a need to develop a surfactant composition for controlling or preventing insects and a method of using the same, so as to eliminate or alleviate the above problems.
Disclosure of Invention
In view of this, the present disclosure proposes a surfactant composition for controlling or controlling insects, which may be free of toxic substances, free of volatile chemical/organic solvents, free of any fluorine-, silicon-or phosphorus-based compounds or free of any aromatic compounds, or environmentally friendly and human and animal safe, and has a broad spectrum of properties against harmful insects.
To achieve the above object, according to one aspect of the present disclosure, there is provided a surfactant composition for controlling or preventing insects, comprising 0.01 to 5 weight percent of alkyl sulfosuccinate, 0.01 to 1 weight percent of humectant, and the balance being water. Here, the water used is not particularly limited, and is preferably purified water, distilled water, deionized water, or ultrapure water.
In the surfactant composition of the present disclosure, the alkyl sulfosuccinate may be a mono-alkyl sulfosuccinate, a di-alkyl sulfosuccinate, a poly-alkyl sulfosuccinate, or a combination thereof, wherein the mono-alkyl sulfosuccinate may have from 1 to 18 carbon chain alkyl groups, preferably from 4 to 18 carbon chain alkyl groups, more preferably from 4 to 12 carbon chain alkyl groups, most preferably from 6 to 8 carbon chain alkyl groups; the dialkyl sulfosuccinates may have two identical or different 1 to 18 carbon chain alkyl groups, preferably 4 to 18 carbon chain alkyl groups, more preferably 4 to 12 carbon chain alkyl groups, most preferably 6 to 8 carbon chain alkyl groups; and the polyalkylsulfosuccinate may have a plurality of identical or different 1 to 18 carbon chain alkyl groups, preferably 4 to 18 carbon chain alkyl groups, more preferably 4 to 12 carbon chain alkyl groups, and most preferably 6 to 8 carbon chain alkyl groups, but the disclosure is not limited thereto.
In the surfactant composition of the present disclosure, the alkyl sulfosuccinate may be an alkyl sulfosuccinate having the following chemical formula:
wherein R1 and R2 may be an alkyl group, respectively, but the disclosure is not limited thereto. Further, R1 and R2 may each be 1 to 18 carbon chain alkyl groups, preferably 4 to 18 carbon chain alkyl groups, more preferably 4 to 12 carbon chain alkyl groups, and most preferably 6 to 8 carbon chain alkyl groups, but the present disclosure is not limited thereto. Furthermore, R1 and R2 may be the same or different alkyl groups, and are preferably the same alkyl groups.
In the surfactant composition of the present disclosure, the humectant may be an alkyl monol, an alkyl diol, an alkyl polyol, or a combination thereof, wherein the alkyl group may be 1 to 18 carbon chain alkyl groups, preferably 4 to 18 carbon chain alkyl groups, more preferably 4 to 12 carbon chain alkyl groups, and most preferably 6 to 8 carbon chain alkyl groups, but the present disclosure is not limited thereto.
In the surfactant composition of the present disclosure, the surfactant composition may be free of any volatile compound organic solvent, free of any fluorine, silicon or phosphorus-based compound, free of any aromatic compound or free of conventional pesticides or insecticides, but the present disclosure is not limited thereto.
According to another aspect of the present disclosure, there is provided a method of using an insect surfactant composition for controlling or preventing, comprising the steps of: (a) formulating a surfactant composition as described above; and (b) applying the surfactant composition obtained in (a) to an insect. Through the excellent solvency of the surfactant compositions of the present disclosure, the transmission of volatile compounds pheromones of insects can be eliminated and blocked to reduce or prevent insect population or swarm flight.
In addition, since most insects breathe with the tracheal system in the body, the tracheal system is spread throughout the body and vented to the atmosphere by the air valve (air valve), through which air is diffused into the trachea (trachia), the bronchi and the micro-bronchi (trachele) branching stepwise, and finally into the tissue cells. Thus, if the opening and closing of the air valve on the insect body can be affected, the respiratory system of the insect can be affected. If the insect respiratory system can be affected, the insect's flight can be controlled and even its survival can be affected. Thus, insects may also be moistened by applying the surfactant composition of the present disclosure to the insects, causing the insects to breathe hard or increase in weight, to reduce their mobility or flying ability.
In the method of the present disclosure, the insect may be any insect having an air hole, an air pipe, an air bag, or a combination thereof forming a respiratory system, for example, may be a locust, a fly, a longhorn beetle, a spider, a wasp, a winged insect, a fly, a cockroach, or a pillworm (a tide), etc., but the present disclosure is not limited thereto.
In the methods of the present disclosure, the insects may be any crawling or flying insects, either static or dynamic, but the present disclosure is not limited thereto.
In the method of the present disclosure, the insects may be any insects that are scattered or colonised, but the present disclosure is not limited thereto.
In the methods of the present disclosure, wherein such methods may be applied to prevent or contain the aforementioned insect population or swarm fly, the present disclosure is not limited thereto.
In the methods of the present disclosure, wherein such methods are useful for controlling or controlling eggs, larvae, or adults of insects, the disclosure is not limited thereto.
In the methods of the present disclosure, the aforementioned surfactant compositions may be applied directly to the aforementioned insects using spray, foam, aerosol, spread, cover, pour-on, or combinations thereof, but the present disclosure is not limited thereto.
Other objects, advantages and novel features of the disclosure will become apparent from the following detailed description when considered in conjunction with the drawings.
Drawings
FIG. 1 schematically illustrates a flow chart of the formulation of the surfactant composition of the present disclosure;
FIG. 2 schematically illustrates a schematic of a method of using the surfactant compositions of the present disclosure;
in the drawing the view of the figure,
1-surfactant compositions
2-device
3-insect
S1, S2 and S3-.
Detailed Description
Different embodiments of the present disclosure are provided below. These examples are intended to illustrate the technical content of the present disclosure, and are not intended to limit the scope of the claims of the present disclosure. A feature of one embodiment may be applied to other embodiments by suitable modifications, substitutions, combinations, and separations.
In this context, unless otherwise indicated, the so-called feature A "or" and/or "feature B" means that the nail alone, the B alone, or both the A and the B are present; the feature A and or and feature B means that the nail and the B exist simultaneously; the terms "including", "comprising", "having", "containing" and "containing" are intended to be inclusive and mean the inclusion of, but not limited to.
Fig. 1 schematically illustrates a formulation flow diagram of the surfactant composition of the present disclosure.
As shown in fig. 1, the formulation flow of the surfactant composition of the present disclosure includes the following steps: (step S1) mixing an alkyl sulfosuccinate with a humectant to form a mixture; (step S2) adding purified water into the mixture; and (step S3) forming a surfactant composition.
Fig. 2 schematically illustrates a method of using the surfactant compositions of the present disclosure.
As shown in fig. 2, the surfactant composition 1 prepared as described above was filled in a suitable device 2, where the device 2 is a spray bottle, the surfactant composition 1 was applied to the insects 3 by spraying through the device 2, and was applied to different kinds of insects 3 to test the effect of the surfactant composition 1 of the present disclosure on controlling or controlling the insects 3, and examples 1 to 10 below were all tested in a similar manner as above, except for the ratio of each component of the surfactant composition 1, the number of spraying seconds, the amount of single spraying, and the application to different kinds of insects 3.
Specific examples of surfactant compositions provided by the present disclosure are as follows:
example 1 (Small locust, about 30mm in size)
The surfactant composition 1 of example 1 of table 1 below was stirred uniformly into an aqueous solution and applied to static locusts by spraying or sprinkling with a suitable device 2 (as shown in fig. 2).
Table 1 composition, embodiment and results of the surfactant composition of example 1
Example 2 (locust, size about 45 mm)
The surfactant composition 1 of example 2 of table 2 below was stirred uniformly into an aqueous solution and applied to the dynamic locust by spraying or sprinkling with a suitable device 2 (as shown in fig. 2).
Table 2 composition, embodiment and results of the surfactant composition of example 2
Example 3 (Formica Fusca, size about 10 mm)
The surfactant composition 1 of example 3 of table 3 below was uniformly stirred into an aqueous solution and applied to static termites in a spray or spray manner using a suitable device 2 (as shown in fig. 2).
TABLE 3 composition, embodiment and results of surfactant composition of example 3
Example 4 (longhorn beetle, size about 13 mm)
The surfactant composition 1 of example 4 of table 4 below was stirred uniformly into an aqueous solution and applied to static longicorn by spraying or sprinkling with a suitable device 2 (as shown in fig. 2).
Table 4 composition, embodiment and results of the surfactant composition of example 4
Example 5 (spider, size about 20 mm)
The surfactant composition 1 of example 5 of table 5 below was stirred uniformly into an aqueous solution and applied to a dynamic spider by spraying or sprinkling using a suitable device 2 (as shown in fig. 2).
TABLE 5 composition, embodiment and results of surfactant composition of example 5
Example 6 (wasp, about 30mm in size)
Surfactant composition 1 of example 6 of table 6 below was stirred uniformly into an aqueous solution and applied to static wasps in a spray or sprinkle using a suitable device 2 (as shown in fig. 2).
TABLE 6 composition, embodiment and results of surfactant composition of example 6
Example 7 (Small flying insect, size about 3 mm)
Surfactant composition 1 of example 7 of table 7 below was stirred uniformly into an aqueous solution and applied to static flying insects by spraying or sprinkling using a suitable device 2 (as shown in fig. 2).
TABLE 7 composition, embodiment and results of surfactant composition of example 7
Example 8 (fly, size about 12 mm)
The surfactant composition 1 of example 8 of table 8 below was stirred uniformly into an aqueous solution and applied to static flies by spraying or sprinkling with a suitable device 2 (as shown in fig. 2).
TABLE 8 composition, embodiment and results of surfactant composition of example 8
Example 9 (cockroach, size about 15 mm)
Surfactant composition 1 of example 9 of table 9 below was stirred uniformly into an aqueous solution and applied to static cockroaches by spraying or sprinkling with a suitable device 2 (as shown in fig. 2). The amount of spray must be sufficient because cockroaches are large in size.
TABLE 9 composition, embodiment and results of surfactant composition of example 9
Example 10 (Armadillidium, size about 40 mm)
The surfactant composition 1 of example 10 of table 10 below was stirred uniformly into an aqueous solution and applied to a dynamic pillworm (hygrophila) by spraying or sprinkling with a suitable device 2 (as shown in fig. 2). The surfactant compositions of the present disclosure may also be used for control or prevention, although Armadillidium is not an insect.
Table 10 composition, embodiment and results of the surfactant composition of example 10
From the results of examples 1 to 10, it is shown that the surfactant composition of the present disclosure has a synergistic effect, so that various insects can be quickly brought into a wet state, and a deep wet state is maintained, thereby achieving an immediate and effective insect control or prevention effect.
The surfactant composition disclosed by the invention is directly or indirectly applied to scattered or populated insects in a proper dosage and implementation mode in a mode of spraying, foaming, aerosol, smearing, pouring or a combination of the aqueous solution, so that the breathing system of the insects can be influenced, the propagation of the flying insect pheromone of the group is prevented, the flying of the flying insects of the group is restrained, the survival of the flying insects is even influenced, and the purpose of rapidly and effectively controlling or preventing the insects is achieved. The surfactant compositions for controlling or preventing insects and methods of use thereof of the present disclosure have the following advantages over existing techniques for controlling or preventing insects:
1. the organic solvent without any volatile compound can not harm the health of human and livestock. In addition, the air conditioner does not generate peculiar smell when in use, and can keep indoor fresh air.
2. Does not contain any aromatic compound and has excellent safety.
3. Does not contain any compound based on fluorine, silicon or phosphorus, has biodegradability and avoids causing environmental pollution. Fluorine compounds are intangible contaminants that may affect the ecological environment and animals, and phosphorus compounds have been identified as contaminating water resources. Methylcyclosiloxane has been reported to accumulate in aquatic animals and thus may be a contaminant affecting water resources.
4. Does not contain traditional pesticides or insecticides, and has excellent environmental protection.
5. The surfactant compositions of the present disclosure may be formulated with water to provide a specific concentration of aqueous solution that can be applied directly or indirectly to the insect population or population in a spray, foam, aerosol, spread, cover, pour-on, or combination thereof.
6. The surfactant composition of the present disclosure may be sprayed or poured to highly moisten the eggs of the subterranean insects, causing them to suffocate, decay or foam out, failing to hatch adults.
7. Can be applied to prevent or contain the growth of insect larvae or the population or swarm flight of adults.
8. The implementation mode and the dosage can be adjusted according to the type, the body type and the inhabitation type of insects, and the insect pest control device has high elasticity and convenience.
9. Can avoid the problem of drug resistance of insects to traditional pesticides or pesticides.
In summary, the surfactant composition of the present disclosure is characterized by small usage amount, fast effect, high implementation convenience, safety, no toxicity, no odor, environmental friendliness, no drug resistance, economy, etc.
While the present disclosure has been illustrated by a number of embodiments, it should be understood that many other possible modifications and variations may be made without departing from the spirit of the disclosure and as claimed.

Claims (9)

1. Use of a surfactant composition for controlling or controlling insects, characterized in that the surfactant composition comprises:
0.01 to 5 weight percent of an alkyl sulfosuccinate;
0.01 to 1 weight percent humectant; and
the balance being water;
wherein the surfactant composition is free of other pesticides;
the alkyl sulfosuccinate is an alkyl sulfosuccinate having the formula:
CH2—COOR1
︱
CH—COOR2
︱
SO3Na
wherein R1 and R2 are respectively an alkyl group, R1 and R2 are respectively 4-18 carbon chain alkyl groups, and the humectant is alkyl polyol;
the insect comprises at least one of locust, termite, longhorn beetle, spider, wasp, fly, cockroach or pillworm.
2. The use according to claim 1, wherein the alkyl sulfosuccinate is a mono-alkyl sulfosuccinate, a di-alkyl sulfosuccinate, a poly-alkyl sulfosuccinate or a combination thereof.
3. The use according to claim 1, wherein the surfactant composition is free of any volatile compound organic solvent.
4. The use according to claim 1, wherein the surfactant composition does not contain any fluorine, silicon or phosphorus compounds.
5. The use according to claim 1, wherein the surfactant composition is free of any aromatic compounds.
6. A method of controlling or combating insects, comprising the steps of:
formulating the surfactant composition of any one of claims 1 to 5; and
applying the surfactant composition of (a) to an insect;
wherein the insect comprises at least one of locust, termite, longicorn, spider, wasp, fly, cockroach or pillworm.
7. The method of claim 6, wherein the method is applied to prevent or contain insect population or mass fly.
8. The method of claim 6, wherein the method is used to control or control eggs, larvae or adults of insects.
9. The method of any one of claims 6 to 8, wherein the surfactant composition is applied directly to the insect using a spray, foam, aerosol, spread, cover, pour-on, or a combination thereof.
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