CN114622443A - Cigarette tipping paper based on water-based touch oil and processing technology thereof - Google Patents

Cigarette tipping paper based on water-based touch oil and processing technology thereof Download PDF

Info

Publication number
CN114622443A
CN114622443A CN202210261052.9A CN202210261052A CN114622443A CN 114622443 A CN114622443 A CN 114622443A CN 202210261052 A CN202210261052 A CN 202210261052A CN 114622443 A CN114622443 A CN 114622443A
Authority
CN
China
Prior art keywords
water
parts
touch oil
based touch
tipping
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN202210261052.9A
Other languages
Chinese (zh)
Inventor
陆靖杰
王明忠
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Longyou Tarn Paper Co ltd
Original Assignee
Longyou Tarn Paper Co ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Longyou Tarn Paper Co ltd filed Critical Longyou Tarn Paper Co ltd
Priority to CN202210261052.9A priority Critical patent/CN114622443A/en
Publication of CN114622443A publication Critical patent/CN114622443A/en
Pending legal-status Critical Current

Links

Classifications

    • DTEXTILES; PAPER
    • D21PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21HPULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H27/00Special paper not otherwise provided for, e.g. made by multi-step processes
    • D21H27/18Paper- or board-based structures for surface covering
    • D21H27/22Structures being applied on the surface by special manufacturing processes, e.g. in presses
    • D21H27/26Structures being applied on the surface by special manufacturing processes, e.g. in presses characterised by the overlay sheet or the top layers of the structures
    • D21H27/28Structures being applied on the surface by special manufacturing processes, e.g. in presses characterised by the overlay sheet or the top layers of the structures treated to obtain specific resistance properties, e.g. against wear or weather
    • DTEXTILES; PAPER
    • D21PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21HPULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H11/00Pulp or paper, comprising cellulose or lignocellulose fibres of natural origin only
    • DTEXTILES; PAPER
    • D21PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21HPULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H17/00Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
    • D21H17/03Non-macromolecular organic compounds
    • D21H17/05Non-macromolecular organic compounds containing elements other than carbon and hydrogen only
    • D21H17/17Ketenes, e.g. ketene dimers
    • DTEXTILES; PAPER
    • D21PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21HPULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H17/00Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
    • D21H17/20Macromolecular organic compounds
    • D21H17/21Macromolecular organic compounds of natural origin; Derivatives thereof
    • D21H17/24Polysaccharides
    • D21H17/25Cellulose
    • D21H17/26Ethers thereof
    • DTEXTILES; PAPER
    • D21PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21HPULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H17/00Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
    • D21H17/20Macromolecular organic compounds
    • D21H17/21Macromolecular organic compounds of natural origin; Derivatives thereof
    • D21H17/24Polysaccharides
    • D21H17/28Starch
    • D21H17/29Starch cationic
    • DTEXTILES; PAPER
    • D21PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21HPULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H17/00Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
    • D21H17/20Macromolecular organic compounds
    • D21H17/21Macromolecular organic compounds of natural origin; Derivatives thereof
    • D21H17/24Polysaccharides
    • D21H17/30Alginic acid or alginates
    • DTEXTILES; PAPER
    • D21PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21HPULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H17/00Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
    • D21H17/63Inorganic compounds
    • D21H17/66Salts, e.g. alums
    • DTEXTILES; PAPER
    • D21PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21HPULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H19/00Coated paper; Coating material
    • D21H19/36Coatings with pigments
    • D21H19/38Coatings with pigments characterised by the pigments
    • D21H19/385Oxides, hydroxides or carbonates
    • DTEXTILES; PAPER
    • D21PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21HPULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H19/00Coated paper; Coating material
    • D21H19/36Coatings with pigments
    • D21H19/38Coatings with pigments characterised by the pigments
    • D21H19/40Coatings with pigments characterised by the pigments siliceous, e.g. clays
    • DTEXTILES; PAPER
    • D21PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21HPULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H19/00Coated paper; Coating material
    • D21H19/36Coatings with pigments
    • D21H19/44Coatings with pigments characterised by the other ingredients, e.g. the binder or dispersing agent
    • DTEXTILES; PAPER
    • D21PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21HPULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H19/00Coated paper; Coating material
    • D21H19/36Coatings with pigments
    • D21H19/44Coatings with pigments characterised by the other ingredients, e.g. the binder or dispersing agent
    • D21H19/46Non-macromolecular organic compounds
    • DTEXTILES; PAPER
    • D21PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21HPULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H19/00Coated paper; Coating material
    • D21H19/36Coatings with pigments
    • D21H19/44Coatings with pigments characterised by the other ingredients, e.g. the binder or dispersing agent
    • D21H19/56Macromolecular organic compounds or oligomers thereof obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • D21H19/58Polymers or oligomers of diolefins, aromatic vinyl monomers or unsaturated acids or derivatives thereof
    • DTEXTILES; PAPER
    • D21PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21HPULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H19/00Coated paper; Coating material
    • D21H19/36Coatings with pigments
    • D21H19/44Coatings with pigments characterised by the other ingredients, e.g. the binder or dispersing agent
    • D21H19/62Macromolecular organic compounds or oligomers thereof obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • DTEXTILES; PAPER
    • D21PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21HPULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H21/00Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties
    • D21H21/14Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties characterised by function or properties in or on the paper
    • DTEXTILES; PAPER
    • D21PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21HPULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H21/00Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties
    • D21H21/14Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties characterised by function or properties in or on the paper
    • D21H21/16Sizing or water-repelling agents
    • DTEXTILES; PAPER
    • D21PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21HPULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H21/00Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties
    • D21H21/14Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties characterised by function or properties in or on the paper
    • D21H21/36Biocidal agents, e.g. fungicidal, bactericidal, insecticidal agents
    • DTEXTILES; PAPER
    • D21PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21HPULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H21/00Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties
    • D21H21/50Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties characterised by form
    • D21H21/52Additives of definite length or shape

Landscapes

  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Inorganic Chemistry (AREA)
  • Dispersion Chemistry (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Pest Control & Pesticides (AREA)
  • Paper (AREA)

Abstract

The invention relates to the technical field of cigarette auxiliary material processing, in particular to tipping paper for cigarettes based on water-based touch oil and a processing technology thereof; the tipping paper comprises tipping base paper and water-based touch oil coated on the surface of the tipping base paper, wherein the water-based touch oil is prepared from the following raw materials in parts by weight: 70-80 parts of aqueous polyurethane emulsion, 10-16 parts of aqueous styrene-acrylic emulsion, 1.5-2.8 parts of nano silicon dioxide, 1.5-3.0 parts of flatting agent, 3.5-5 parts of organic silicon modifier, 4-5.5 parts of touch modifier, 3.2-4.0 parts of antibacterial agent, 1.2-3.2 parts of nano titanium dioxide, 0.3-0.8 part of defoaming agent and 2-5 parts of deionized water; the tipping paper for the cigarette processed by the invention has good touch, and the comfortable experience of consumers is effectively increased; in addition, the tipping paper for the cigarette processed by the invention also has the advantages of good yellowing resistance, excellent scratch resistance, excellent antibacterial performance and the like, and effectively improves the quality of the tipping paper for the cigarette.

Description

Cigarette tipping paper based on water-based touch oil and processing technology thereof
Technical Field
The invention relates to the technical field of cigarette auxiliary material processing, in particular to tipping paper for cigarettes based on water-based touch oil and a processing technology thereof.
Background
The cigarette is prepared by baking tobacco, shredding, and rolling into cylindrical strip with a length of about 120mm and a diameter of 10 mm. When smoking, one end of the cigarette is ignited, and smoke generated by incomplete combustion is sucked hoots by the mouth at the other end. At present, the cigarette often needs to use tipping paper in the production process, the tipping paper is wrapping paper for connecting the cigarette with a filter tip, and the initial tipping paper is also called tipping paper because the appearance of the tipping paper is similar to pine wood grain. Tipping paper is produced with the advent of filter cigarettes, the specifications of which depend on the cigarette requirements.
Although the continuous tipping paper processed by the prior art can well wrap the cigarette and the filter rod, the touch feeling of the continuous tipping paper is relatively poor, and the yellowing resistance, the scraping resistance and the antibacterial performance of the continuous tipping paper are also relatively poor, so that the grade and the grade of the tipping paper for the cigarette are reduced to a certain extent. Therefore, the invention provides a tipping paper for cigarettes based on water-based touch oil and a processing technology thereof, which are used for solving the technical problems.
Disclosure of Invention
The invention aims to provide the tipping paper for the cigarettes based on the water-based touch oil and the processing technology thereof, and the processed tipping paper for the cigarettes has good touch and effectively increases the comfortable experience of consumers. In addition, the tipping paper for the cigarette processed by the invention also has the advantages of good yellowing resistance, excellent scratch resistance, excellent antibacterial performance and the like, and effectively improves the quality of the tipping paper for the cigarette.
In order to achieve the purpose, the invention provides the following technical scheme:
the cigarette tipping paper based on the water-based touch oil comprises tipping base paper and the water-based touch oil coated on the surface of the tipping base paper, wherein the water-based touch oil is prepared from the following raw materials in parts by weight: 70-80 parts of aqueous polyurethane emulsion, 10-16 parts of aqueous styrene-acrylic emulsion, 1.5-2.8 parts of nano silicon dioxide, 1.5-3.0 parts of flatting agent, 3.5-5 parts of organic silicon modifier, 4-5.5 parts of touch modifier, 3.2-4.0 parts of antibacterial agent, 1.2-3.2 parts of nano titanium dioxide, 0.3-0.8 part of defoaming agent and 2-5 parts of deionized water.
Furthermore, the pH value of the aqueous polyurethane emulsion is 8, and the solid content of the aqueous polyurethane emulsion is 33-37%.
Furthermore, the leveling agent is any one of BYK345, BYK347 and BYK 348.
Furthermore, the organic silicon modifier is selected from any one of gamma-aminopropyl triethoxysilane and gamma-methacryloxypropyl trimethoxysilane.
Further, the feel improver is wax powder, and the wax powder is Lanco GLIDD 5518 type wax powder.
Furthermore, the antibacterial agent is any one of didodecyl dimethyl ammonium chloride and dioctadecyl dimethyl ammonium bromide.
Furthermore, the defoaming agent is any one of a siloxane defoaming agent and a polyacrylate defoaming agent.
A processing technology of cigarette tipping paper based on water-based touch oil comprises the following steps:
firstly, preparing tipping base paper;
adding 1-1.5% by mass of carboxymethyl cellulose into a proper amount of water, mixing and stirring to fully dissolve the carboxymethyl cellulose, then dropwise adding a ferrous sulfate solution with the volume of 20-30% and the concentration of 2.5-3.5 wt% into the obtained mixed solution, stirring and reacting for 30-50 min under the condition of nitrogen protection, and after the reaction is finished, marking as a mixed component;
II, dropwise adding a sodium alginate solution with the volume of 8-12% and the concentration of 2-2.5 wt% into the obtained mixed component, uniformly mixing and stirring, adjusting the pH value to 9.5-10.5, and simultaneously carrying out heat preservation stirring reaction at the temperature of 30-40 ℃ for 40-60 min; after the reaction is finished, adjusting the pH value of the solution to be neutral, then sequentially carrying out freeze drying and grinding treatment to obtain solid particles with the particle size of 80-150 meshes, putting the obtained solid particles into a proper amount of reaction liquid for reaction, and washing the solid particles for 2-3 times by using deionized water after the reaction is finished; the obtained functional materials are stored for later use;
III, mixing the components in a volume ratio of 1.2-1.5: 1, mixing bleached softwood pulp with the pulping concentration of 2-4% and bleached hardwood pulp with the concentration of 1.8-2.5%, then respectively adding 0.4-0.8% of AKD sizing agent, 0.2-0.5% of cationic starch and 3-7% of filler into the obtained mixed wood pulp, mixing and stirring uniformly, supplementing 5-8% of functional material into the obtained mixed pulp, and after mixing and stirring uniformly, sequentially performing the procedures of net surfing, pressing, drying, press polishing, curling, slitting and finishing to obtain a finished tipping base paper product;
secondly, preparing water-based touch oil;
accurately weighing each raw material for preparing the water-based touch oil according to the formula amount, then adding nano silicon dioxide and half amount of defoaming agent into the water-based polyurethane emulsion at room temperature, and stirring and dispersing for 30-40 min; after the dispersion is finished, adding the water-based styrene-acrylic emulsion into the mixture, uniformly stirring and dispersing the mixture, adding the rest raw materials into the mixture, uniformly stirring and dispersing the mixture, sequentially checking hue, solid content, fineness and viscosity parameters, and filtering the mixture after the mixture is qualified to obtain a water-based touch oil finished product;
thirdly, preparing a finished tipping paper product for cigarettes;
and (3) coating the water-based touch oil prepared in the step two on the tipping base paper prepared in the step one, and drying to obtain the finished tipping paper for the cigarettes containing the water-based touch oil.
Furthermore, the reaction solution used in the step II is a calcium chloride solution with the concentration of 3-6 wt%, and the reaction time is 30-50 min.
Furthermore, the filler used in the step III is selected from any one of calcium carbonate and talcum powder.
Compared with the prior art, the invention has the beneficial effects that:
1. according to the invention, the aqueous polyurethane emulsion, the aqueous styrene-acrylic emulsion, the nano silicon dioxide, the organic silicon modifier, the touch modifier, the antibacterial agent, the nano titanium dioxide and the like are used as raw materials for preparing the aqueous touch oil, wherein the organic silicon modifier can effectively improve the smoothness of the aqueous touch oil, the touch modifier can effectively improve the touch of the aqueous touch oil, and the smooth performance and the touch of the aqueous touch oil are effectively improved by mixing the organic silicon modifier and the touch modifier, so that the comfortable experience of consumers is well increased. Meanwhile, the waterborne polyurethane emulsion and the waterborne styrene-acrylic emulsion have excellent weather resistance. In addition, the nano titanium dioxide can absorb ultraviolet rays and reflect and scatter the ultraviolet rays; the nano silicon dioxide has a good ultraviolet shielding function, so that the nano silicon dioxide and the waterborne polyurethane emulsion can be mixed with the waterborne styrene-acrylic emulsion for use, and the yellowing resistance of the waterborne touch oil can be effectively improved.
2. Due to the small size effect and the excellent antibacterial effect of the nano titanium dioxide and the nano silicon dioxide, the scratch resistance of the water-based touch oil can be improved to a certain degree, and the antibacterial performance of the water-based touch oil can be effectively improved. The prepared water-based touch oil is coated on the surface of the tipping base paper, so that the quality and quality of the tipping paper for the cigarettes are effectively improved, the service life of the tipping paper is prolonged to a certain extent, and the grade and grade of cigarette products produced by taking the tipping paper for the cigarettes processed by the invention as a raw material are improved.
Detailed Description
The technical solutions in the embodiments of the present invention will be clearly and completely described below with reference to the embodiments of the present invention, and it is obvious that the described embodiments are only a part of the embodiments of the present invention, and not all of the embodiments. All other embodiments, which can be derived by a person skilled in the art from the embodiments given herein without making any creative effort, shall fall within the protection scope of the present invention.
Example 1
The cigarette tipping paper based on the water-based touch oil comprises tipping base paper and the water-based touch oil coated on the surface of the tipping base paper, wherein the water-based touch oil is prepared from the following raw materials in parts by weight: 70 parts of aqueous polyurethane emulsion, 10 parts of aqueous styrene-acrylic emulsion, 1.5 parts of nano silicon dioxide, 1.5 parts of BYK345 leveling agent, 3.5 parts of gamma-aminopropyltriethoxysilane, 4 parts of Lanco GLIDD 5518 type wax lubricant powder, 3.2 parts of didecyl dimethyl ammonium chloride, 1.2 parts of nano titanium dioxide, 0.3 part of siloxane type defoaming agent and 2 parts of deionized water; wherein the pH value of the aqueous polyurethane emulsion is 8, and the solid content of the aqueous polyurethane emulsion is 33%.
A processing technology of cigarette tipping paper based on water-based touch oil comprises the following steps:
firstly, preparing tipping base paper;
adding 1% by mass of carboxymethyl cellulose into a proper amount of water, mixing and stirring to fully dissolve the carboxymethyl cellulose, then dropwise adding a ferrous sulfate solution with the volume of 20% and the concentration of 2.5 wt% into the obtained mixed solution, stirring and reacting for 30min under the protection of nitrogen, and after the reaction is finished, obtaining mixed components;
II, dropwise adding a sodium alginate solution with the volume of 8% and the concentration of 2 wt% into the obtained mixed component, uniformly mixing and stirring, adjusting the pH value to 9.5, and simultaneously carrying out heat preservation and stirring reaction at the temperature of 30 ℃ for 40 min; after the reaction is finished, adjusting the pH value of the solution to be neutral, then sequentially carrying out freeze drying and grinding treatment to obtain solid particles with the particle size of 80 meshes, putting the obtained solid particles into a proper amount of reaction solution for reaction, and washing the solid particles for 2 times by using deionized water after the reaction is finished; storing the obtained functional material for later use; wherein the reaction solution is a calcium chloride solution with the concentration of 3 wt%, and the reaction time is 30 min;
III, mixing the components in a volume ratio of 1.2: 1, mixing bleached softwood pulp with the pulping concentration of 2% and bleached hardwood pulp with the pulping concentration of 1.8%, then respectively adding 0.4% of AKD sizing agent, 0.2% of cationic starch and 3% of calcium carbonate into the obtained mixed wood pulp, mixing and stirring uniformly, supplementing 5% of functional material into the obtained mixed pulp, and after mixing and stirring uniformly, sequentially performing the processes of net surfing, papermaking, squeezing, drying, calendaring, curling, slitting and finishing to obtain a finished tipping base paper product;
secondly, preparing water-based touch oil;
accurately weighing each raw material for preparing the water-based touch oil according to the formula amount, then adding nano silicon dioxide and half amount of defoaming agent into the water-based polyurethane emulsion at room temperature, and stirring and dispersing for 30 min; after the dispersion is finished, adding the water-based styrene-acrylic emulsion into the mixture, uniformly stirring and dispersing the mixture, adding the rest raw materials into the mixture, uniformly stirring and dispersing the mixture, sequentially checking hue, solid content, fineness and viscosity parameters, and filtering the mixture after the mixture is qualified to obtain a water-based touch oil finished product;
thirdly, preparing a finished tipping paper product for cigarettes;
and (3) coating the water-based touch oil prepared in the step two on the tipping base paper prepared in the step one, and drying to obtain the finished tipping paper for the cigarettes containing the water-based touch oil.
Example 2
The cigarette tipping paper based on the water-based touch oil comprises tipping base paper and the water-based touch oil coated on the surface of the tipping base paper, wherein the water-based touch oil is prepared from the following raw materials in parts by weight: 75 parts of aqueous polyurethane emulsion, 13 parts of aqueous styrene-acrylic emulsion, 2.0 parts of nano silicon dioxide, 2.5 parts of BYK347 flatting agent, 4.5 parts of gamma-methacryloxypropyltrimethoxysilane, 5.0 parts of Lanco GLIDD 5518 type wax lubricant powder, 3.6 parts of dioctadecyl dimethyl ammonium bromide, 2.5 parts of nano titanium dioxide, 0.5 part of polyacrylate type defoaming agent and 3 parts of deionized water; wherein the pH value of the aqueous polyurethane emulsion is 8, and the solid content of the aqueous polyurethane emulsion is 35%.
A processing technology of cigarette tipping paper based on water-based touch oil comprises the following steps:
firstly, preparing tipping base paper;
i, adding 1.3 mass percent of carboxymethyl cellulose into a proper amount of water, mixing and stirring to fully dissolve the carboxymethyl cellulose, dropwise adding 25 volume percent of ferrous sulfate solution with the concentration of 3.0wt percent into the obtained mixed solution, stirring and reacting for 40min under the protection of nitrogen, and after the reaction is finished, obtaining mixed components;
II, dropwise adding a sodium alginate solution with the volume of 10% and the concentration of 2.3 wt% into the obtained mixed component, uniformly mixing and stirring, adjusting the pH value to 10, and simultaneously carrying out heat preservation stirring reaction at the temperature of 35 ℃ for 50 min; after the reaction is finished, adjusting the pH value of the solution to be neutral, then sequentially carrying out freeze drying and grinding treatment to obtain solid particles with the particle size of 100 meshes, putting the obtained solid particles into a proper amount of reaction solution for reaction, and washing the solid particles for 3 times by using deionized water after the reaction is finished; the obtained functional materials are stored for later use; wherein the reaction solution is a calcium chloride solution with the concentration of 5 wt%, and the reaction time is 40 min;
III, mixing the components in a volume ratio of 1.3: 1, mixing bleached softwood pulp with the pulping concentration of 3% and bleached hardwood pulp with the pulping concentration of 2.0%, then respectively adding 0.6% of AKD sizing agent, 0.3% of cationic starch and 5% of talcum powder into the mixed wood pulp, mixing and stirring uniformly, supplementing 6% of functional material into the mixed pulp, and sequentially performing the processes of net feeding papermaking, squeezing, drying, calendaring, curling, slitting and trimming after mixing and stirring uniformly to obtain a finished tipping base paper product;
secondly, preparing water-based touch oil;
accurately weighing each raw material for preparing the water-based touch oil according to the formula amount, then adding nano silicon dioxide and half amount of defoaming agent into the water-based polyurethane emulsion at room temperature, and stirring and dispersing for 35 min; after the dispersion is finished, adding the water-based styrene-acrylic emulsion into the mixture, uniformly stirring and dispersing the mixture, adding the rest raw materials into the mixture, uniformly stirring and dispersing the mixture, sequentially checking hue, solid content, fineness and viscosity parameters, and filtering the mixture after the mixture is qualified to obtain a water-based touch oil finished product;
thirdly, preparing a finished tipping paper product for cigarettes;
and (3) coating the water-based touch oil prepared in the step two on the tipping base paper prepared in the step one, and drying to obtain the finished tipping paper for the cigarettes containing the water-based touch oil.
Example 3
The cigarette tipping paper based on the water-based touch oil comprises tipping base paper and the water-based touch oil coated on the surface of the tipping base paper, wherein the water-based touch oil is prepared from the following raw materials in parts by weight: 80 parts of aqueous polyurethane emulsion, 16 parts of aqueous styrene-acrylic emulsion, 2.8 parts of nano silicon dioxide, 3.0 parts of BYK348 flatting agent, 5 parts of gamma-aminopropyltriethoxysilane, 5.5 parts of Lanco GLIDD 5518 type wax lubricant powder, 4.0 parts of didecyl dimethyl ammonium chloride, 3.2 parts of nano titanium dioxide, 0.8 part of siloxane type defoaming agent and 5 parts of deionized water; wherein the pH value of the aqueous polyurethane emulsion is 8, and the solid content of the aqueous polyurethane emulsion is 37%.
A processing technology of cigarette tipping paper based on water-based touch oil comprises the following steps:
firstly, preparing tipping base paper;
adding 1.5% by mass of carboxymethyl cellulose into a proper amount of water, mixing and stirring to fully dissolve the carboxymethyl cellulose, dropwise adding a 30% by volume ferrous sulfate solution with the concentration of 3.5 wt% into the obtained mixed solution, stirring and reacting for 50min under the protection of nitrogen, and after the reaction is finished, obtaining mixed components;
II, dropwise adding a sodium alginate solution with the volume of 12% and the concentration of 2.5 wt% into the obtained mixed component, uniformly mixing and stirring, adjusting the pH value to 10.5, and simultaneously carrying out heat preservation and stirring reaction at the temperature of 40 ℃ for 60 min; after the reaction is finished, adjusting the pH value of the solution to be neutral, then sequentially carrying out freeze drying and grinding treatment to obtain solid particles with the particle size of 150 meshes, putting the obtained solid particles into a proper amount of reaction solution for reaction, and washing the solid particles for 3 times by using deionized water after the reaction is finished; the obtained functional materials are stored for later use; wherein the reaction solution is a calcium chloride solution with the concentration of 6 wt%, and the reaction time is 50 min;
III, mixing the components in a volume ratio of 1.2-1.5: 1, mixing bleached softwood pulp with the beating concentration of 4% and bleached hardwood pulp with the concentration of 2.5%, then respectively adding 0.8% of AKD sizing agent, 0.5% of cationic starch and 7% of calcium carbonate into the obtained mixed wood pulp, mixing and stirring uniformly, supplementing 8% of functional material into the obtained mixed pulp, and after mixing and stirring uniformly, sequentially performing the processes of net surfing, papermaking, squeezing, drying, press polishing, curling, slitting and finishing to obtain a finished tipping base paper product;
secondly, preparing water-based touch oil;
accurately weighing each raw material for preparing the water-based touch oil according to the formula amount, then adding nano silicon dioxide and half amount of defoaming agent into the water-based polyurethane emulsion at room temperature, and stirring and dispersing for 40 min; after the dispersion is finished, adding the water-based styrene-acrylic emulsion into the mixture, uniformly stirring and dispersing the mixture, adding the rest raw materials into the mixture, sequentially inspecting hue, solid content, fineness and viscosity parameters after uniform stirring and dispersion, and filtering the mixture after the mixture is qualified to obtain a water-based touch oil finished product;
thirdly, preparing a finished tipping paper product for cigarettes;
and (3) coating the water-based touch oil prepared in the step two on the tipping base paper prepared in the step one, and drying to obtain the finished tipping paper for the cigarettes containing the water-based touch oil.
Comparative example: the main differences between this embodiment and embodiment 1 are: the aqueous touch feeling oil does not contain a touch feeling improver.
Performance testing
The tipping paper products for cigarettes processed in examples 1 to 3 and the comparative example are subjected to the following performance tests:
1. and (3) detecting the wear resistance: sutherland 2000 abrasion resistance apparatus, 2 pound pressure, Speed4, 200 to and fro
2. And (3) detecting the scratch resistance: the dried surface sample was scraped with a fingernail and gentle force.
3. And (3) detecting yellowing resistance: the coated sample was placed in an oven at 50 ℃ and observed for yellowing after one week.
4. And (3) detecting the antibacterial performance: detecting according to GB15979-2002 standard for 2 min.
The resulting test data are reported in the following table:
Figure BDA0003550131630000101
Figure BDA0003550131630000111
by comparing and analyzing relevant data in the table, the tipping paper for the cigarette processed by the invention has good touch feeling, and the comfortable experience of consumers is effectively increased. In addition, the tipping paper for the cigarette processed by the invention also has the advantages of good yellowing resistance, excellent scratch resistance, excellent antibacterial performance and the like, and effectively improves the quality of the tipping paper for the cigarette. Therefore, the tipping paper product for the temperature-change anti-counterfeiting cigarette processed by the invention has wider market prospect and is more suitable for popularization.
In the description herein, references to the description of "one embodiment," "an example," "a specific example" or the like are intended to mean that a particular feature, structure, material, or characteristic described in connection with the embodiment or example is included in at least one embodiment or example of the invention. In this specification, the schematic representations of the terms used above do not necessarily refer to the same embodiment or example. Furthermore, the particular features, structures, materials, or characteristics described may be combined in any suitable manner in any one or more embodiments or examples.
The preferred embodiments of the invention disclosed above are intended to be illustrative only. The preferred embodiments are not intended to be exhaustive or to limit the invention to the precise embodiments disclosed. Obviously, many modifications and variations are possible in light of the above teaching. The embodiments were chosen and described in order to best explain the principles of the invention and the practical application, to thereby enable others skilled in the art to best utilize the invention. The invention is limited only by the claims and their full scope and equivalents.

Claims (10)

1. The cigarette tipping paper based on the water-based touch oil comprises tipping base paper and the water-based touch oil coated on the surface of the tipping base paper, and is characterized in that the water-based touch oil is prepared from the following raw materials in parts by weight: 70-80 parts of aqueous polyurethane emulsion, 10-16 parts of aqueous styrene-acrylic emulsion, 1.5-2.8 parts of nano silicon dioxide, 1.5-3.0 parts of flatting agent, 3.5-5 parts of organic silicon modifier, 4-5.5 parts of touch modifier, 3.2-4.0 parts of antibacterial agent, 1.2-3.2 parts of nano titanium dioxide, 0.3-0.8 part of defoaming agent and 2-5 parts of deionized water.
2. The tobacco plug wrap based on the water-based touch oil of claim 1, characterized in that: the pH value of the aqueous polyurethane emulsion is 8, and the solid content of the aqueous polyurethane emulsion is 33-37%.
3. The tobacco plug wrap based on the water-based touch oil of claim 1, characterized in that: the leveling agent is any one of BYK345, BYK347 and BYK 348.
4. The tobacco plug wrap based on the water-based touch oil of claim 1, characterized in that: the organic silicon modifier is any one of gamma-aminopropyl triethoxysilane and gamma-methacryloxypropyl trimethoxysilane.
5. The tobacco plug wrap based on the water-based touch oil of claim 1, characterized in that: the touch feeling improver adopts wax lubricant powder, and the wax lubricant powder adopts Lanco GLIDD 5518 type wax lubricant powder.
6. The tobacco plug wrap based on the water-based touch oil of claim 1, characterized in that: the antibacterial agent is any one of didecyl dimethyl ammonium chloride and dioctadecyl dimethyl ammonium bromide.
7. The tobacco plug wrap based on the water-based touch oil of claim 1, characterized in that: the defoaming agent is any one of a siloxane defoaming agent and a polyacrylate defoaming agent.
8. The processing technology of the tipping paper for the cigarette based on the water-based touch oil according to any one of claims 1 to 7, characterized by comprising the following steps:
firstly, preparing tipping base paper;
adding 1-1.5% by mass of carboxymethyl cellulose into a proper amount of water, mixing and stirring to fully dissolve the carboxymethyl cellulose, then dropwise adding a ferrous sulfate solution with the volume of 20-30% and the concentration of 2.5-3.5 wt% into the obtained mixed solution, stirring and reacting for 30-50 min under the condition of nitrogen protection, and after the reaction is finished, marking as a mixed component;
II, dropwise adding a sodium alginate solution with the volume of 8-12% and the concentration of 2-2.5 wt% into the obtained mixed component, uniformly mixing and stirring, adjusting the pH value to 9.5-10.5, and simultaneously carrying out heat preservation stirring reaction at the temperature of 30-40 ℃ for 40-60 min; after the reaction is finished, adjusting the pH value of the solution to be neutral, then sequentially carrying out freeze drying and grinding treatment to obtain solid particles with the particle size of 80-150 meshes, putting the obtained solid particles into a proper amount of reaction liquid for reaction, and washing the solid particles for 2-3 times by using deionized water after the reaction is finished; the obtained functional materials are stored for later use;
III, mixing the components in a volume ratio of 1.2-1.5: 1, mixing bleached softwood pulp with the pulping concentration of 2-4% and bleached hardwood pulp with the concentration of 1.8-2.5%, then respectively adding 0.4-0.8% of AKD sizing agent, 0.2-0.5% of cationic starch and 3-7% of filler into the obtained mixed wood pulp, mixing and stirring uniformly, supplementing 5-8% of functional material into the obtained mixed pulp, and after mixing and stirring uniformly, sequentially performing the procedures of net surfing, pressing, drying, press polishing, curling, slitting and finishing to obtain a finished tipping base paper product;
secondly, preparing water-based touch oil;
accurately weighing each raw material for preparing the water-based touch oil according to the formula amount, then adding nano silicon dioxide and half amount of defoaming agent into the water-based polyurethane emulsion at room temperature, and stirring and dispersing for 30-40 min; after the dispersion is finished, adding the water-based styrene-acrylic emulsion into the mixture, uniformly stirring and dispersing the mixture, adding the rest raw materials into the mixture, uniformly stirring and dispersing the mixture, sequentially checking hue, solid content, fineness and viscosity parameters, and filtering the mixture after the mixture is qualified to obtain a water-based touch oil finished product;
thirdly, preparing a finished tipping paper product for cigarettes;
and (3) coating the water-based touch oil prepared in the second step on the tipping base paper prepared in the first step, and drying to obtain a finished tipping paper product for the cigarettes containing the water-based touch oil.
9. The processing technology of the tipping paper for the cigarettes based on the water-based touch oil as claimed in claim 8, wherein the processing technology comprises the following steps: and the reaction solution used in the step II is a calcium chloride solution with the concentration of 3-6 wt%, and the reaction time is 30-50 min.
10. The processing technology of the tipping paper for the cigarettes based on the water-based touch oil as claimed in claim 8, is characterized in that: and the filling agent used in the step III is any one of calcium carbonate and talcum powder.
CN202210261052.9A 2022-03-16 2022-03-16 Cigarette tipping paper based on water-based touch oil and processing technology thereof Pending CN114622443A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN202210261052.9A CN114622443A (en) 2022-03-16 2022-03-16 Cigarette tipping paper based on water-based touch oil and processing technology thereof

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN202210261052.9A CN114622443A (en) 2022-03-16 2022-03-16 Cigarette tipping paper based on water-based touch oil and processing technology thereof

Publications (1)

Publication Number Publication Date
CN114622443A true CN114622443A (en) 2022-06-14

Family

ID=81901974

Family Applications (1)

Application Number Title Priority Date Filing Date
CN202210261052.9A Pending CN114622443A (en) 2022-03-16 2022-03-16 Cigarette tipping paper based on water-based touch oil and processing technology thereof

Country Status (1)

Country Link
CN (1) CN114622443A (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN116163159A (en) * 2023-04-03 2023-05-26 湖南和锐镭射科技有限公司 Touch frame paper for cigarettes and method for manufacturing same

Citations (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101429364A (en) * 2008-12-18 2009-05-13 楚雄市华丽包装实业有限责任公司 Environment friendly bacteriostatic water color ink for tipping paper
CN102676036A (en) * 2012-05-22 2012-09-19 东莞市英科水墨有限公司 Water-based matte touch gloss oil and preparation method thereof
WO2013008938A1 (en) * 2011-07-14 2013-01-17 大阪印刷インキ製造株式会社 Food packaging paper
CN103666171A (en) * 2013-12-05 2014-03-26 襄阳金飞环彩色包装有限公司 Environmental protection type nanometer silica/polyacrylate composite-base aqueous varnish and preparation method thereof
CN104725955A (en) * 2015-02-11 2015-06-24 长兴艾飞特塑料科技有限公司 Preparation method of water-soluble varnish compounded with Ag-carrying chitosan
CN104725966A (en) * 2015-02-11 2015-06-24 长兴艾飞特塑料科技有限公司 Water-based polishing oil with antibacterial function
CN107268328A (en) * 2017-06-29 2017-10-20 滁州卷烟材料厂 A kind of preparation method of cigarette body paper
CN112852274A (en) * 2021-01-05 2021-05-28 广东轻工职业技术学院 Water-based gloss oil and preparation method thereof
CN113831775A (en) * 2021-11-11 2021-12-24 广东百适涂无机材料有限公司 Water-based inorganic mineral composite bright scratch-resistant varnish and preparation method thereof

Patent Citations (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101429364A (en) * 2008-12-18 2009-05-13 楚雄市华丽包装实业有限责任公司 Environment friendly bacteriostatic water color ink for tipping paper
WO2013008938A1 (en) * 2011-07-14 2013-01-17 大阪印刷インキ製造株式会社 Food packaging paper
CN102676036A (en) * 2012-05-22 2012-09-19 东莞市英科水墨有限公司 Water-based matte touch gloss oil and preparation method thereof
CN103666171A (en) * 2013-12-05 2014-03-26 襄阳金飞环彩色包装有限公司 Environmental protection type nanometer silica/polyacrylate composite-base aqueous varnish and preparation method thereof
CN104725955A (en) * 2015-02-11 2015-06-24 长兴艾飞特塑料科技有限公司 Preparation method of water-soluble varnish compounded with Ag-carrying chitosan
CN104725966A (en) * 2015-02-11 2015-06-24 长兴艾飞特塑料科技有限公司 Water-based polishing oil with antibacterial function
CN107268328A (en) * 2017-06-29 2017-10-20 滁州卷烟材料厂 A kind of preparation method of cigarette body paper
CN112852274A (en) * 2021-01-05 2021-05-28 广东轻工职业技术学院 Water-based gloss oil and preparation method thereof
CN113831775A (en) * 2021-11-11 2021-12-24 广东百适涂无机材料有限公司 Water-based inorganic mineral composite bright scratch-resistant varnish and preparation method thereof

Non-Patent Citations (2)

* Cited by examiner, † Cited by third party
Title
李建军: "《塑料配方设计》", 30 September 2019, 中国轻工业出版社 *
王云龙等: "水性触感油在烟用接装纸上的应用研究", 《涂料工业》 *

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN116163159A (en) * 2023-04-03 2023-05-26 湖南和锐镭射科技有限公司 Touch frame paper for cigarettes and method for manufacturing same

Similar Documents

Publication Publication Date Title
JP2883298B2 (en) Water dispersible sheet for tobacco and tobacco using the same
JP2947735B2 (en) Water dispersible sheet and tobacco using the same
CN107438370B (en) Cigarette paper with high staple fraction
CN114622443A (en) Cigarette tipping paper based on water-based touch oil and processing technology thereof
CN104594128B (en) Tobacco Product Wrapping Material, producing method and use thereof, and tobacco product
CN101218394A (en) Process for the production of a paper and a paper produced according to the process
CN104790264A (en) Functional low-gram-weight cigarette paper and preparation method thereof
CN102808358A (en) Method for preparing cigar wrapping paper
CN106436447B (en) A kind of superelevation air permeability forming paper and preparation method thereof
CN110537721A (en) Reconstituted tobacco for heating cigarettes and improved dry preparation method thereof
CN114790666A (en) High-stiffness straw base paper and preparation method thereof
CN112779818A (en) Heating tobacco cigarette paper and preparation method thereof
CN111021144B (en) Composite combustion regulator, flame retardant additive and cigarette paper and fine cigarette prepared from composite combustion regulator and flame retardant additive
CN101985819B (en) Process for producing low-basis-weight waxed base paper
CN105220559A (en) The thin cigarette paper of the tight light black circle of grey of ash is wrapped in a kind of burning smoke less
CN108077996B (en) Preparation method and application of tobacco cationic hemicellulose
CN111364289A (en) Cigarette paper with low air permeability variation coefficient and preparation method thereof
CN113439867B (en) Method for preparing reconstituted tobacco for heating non-combustible cigarettes by combining dry method and rolling method
CN114134758B (en) Production method of gray white smokeless moxibustion paper after combustion
CN105220560A (en) The preparation method of the thin cigarette paper of the tight light black circle of grey of ash is wrapped in a kind of burning smoke less
CN112813734B (en) Hydrophobic paper, preparation method thereof and application of hydrophobic paper to tipping paper for cigarettes
Fatehi et al. Impact of cationic polyvinyl alcohol on properties of papers made from two different pulps
CN116695486A (en) Method for improving dispersion uniformity of pigment in decorative base paper
CN117684410A (en) Strong ash-wrapping cigarette paper
CN107090742B (en) One kind having moisture-keeping functions cigarette paper and preparation method thereof

Legal Events

Date Code Title Description
PB01 Publication
PB01 Publication
SE01 Entry into force of request for substantive examination
SE01 Entry into force of request for substantive examination
RJ01 Rejection of invention patent application after publication
RJ01 Rejection of invention patent application after publication

Application publication date: 20220614