CN114622420A - Garment with strong hydrophobicity and preparation method thereof - Google Patents
Garment with strong hydrophobicity and preparation method thereof Download PDFInfo
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- CN114622420A CN114622420A CN202210383625.5A CN202210383625A CN114622420A CN 114622420 A CN114622420 A CN 114622420A CN 202210383625 A CN202210383625 A CN 202210383625A CN 114622420 A CN114622420 A CN 114622420A
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
- D06N3/00—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
- D06N3/04—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof with macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- D06N3/047—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof with macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds with fluoropolymers
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
- D06N3/00—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
- D06N3/0002—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof characterised by the substrate
- D06N3/0015—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof characterised by the substrate using fibres of specified chemical or physical nature, e.g. natural silk
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
- D06N3/00—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
- D06N3/0002—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof characterised by the substrate
- D06N3/0015—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof characterised by the substrate using fibres of specified chemical or physical nature, e.g. natural silk
- D06N3/0036—Polyester fibres
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
- D06N2209/00—Properties of the materials
- D06N2209/14—Properties of the materials having chemical properties
- D06N2209/142—Hydrophobic
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
- D06N2211/00—Specially adapted uses
- D06N2211/10—Clothing
Abstract
The invention relates to the technical field of clothes, in particular to clothes with strong hydrophobicity and a preparation method thereof. The polyester fiber-acetate fiber-polyester composite material comprises polyester fiber, acetate fiber and a hydrophobic reinforced coating, wherein the hydrophobic reinforced coating at least comprises the following raw materials: the preparation method comprises the following steps of (1) preparing a fluorine-containing monomer, a silicon-containing monomer, methyl methacrylate, an emulsion, an initiator, a catalyst and a grafting agent; according to the high-hydrophobicity clothes and the preparation method thereof, a fluorine-containing monomer, a silicon-containing monomer, methyl methacrylate and emulsion are polymerized under the action of an initiator to form a fluorine-silicon polymer solution with excellent hydrophobicity, the solution is modified by a grafting agent and a catalyst continuously to prepare a hydrophobic enhanced coating with higher hydrophobicity, cloth is soaked in the coating for matching, and the high-hydrophobicity clothes can be prepared after processing.
Description
Technical Field
The invention relates to the technical field of clothes, in particular to clothes with strong hydrophobicity and a preparation method thereof.
Background
Currently, in the field of garment fabrics, various blended fabrics are generally adopted as the fabric of the garment. The existing fabric for clothes does not have the hydrophobic characteristic, so that the fabric for clothes is difficult to dry quickly under the condition that the fabric for clothes is wetted by rainwater or splashed by water, the warm-keeping effect of the clothes and the normal use of the clothes are affected, and the defect of the prior art is overcome by the clothes with strong hydrophobic property.
Disclosure of Invention
The invention aims to provide clothes with strong hydrophobicity and a preparation method thereof, so as to solve the problems in the background technology.
In order to achieve the above purpose, in one aspect, the present invention provides a garment with strong hydrophobicity, which comprises polyester fibers, acetate fibers and a hydrophobic reinforced coating, wherein the hydrophobic reinforced coating at least comprises the following raw materials, by weight: 5-9 parts of fluorine-containing monomer, 5-9 parts of silicon-containing monomer, 1-5 parts of methyl methacrylate, 50-70 parts of emulsion, 1-3 parts of initiator, 1-3 parts of catalyst and 5-9 parts of grafting agent.
As a further improvement of the technical scheme, the fluorine-containing monomer is perfluoroalkyl ethyl methacrylate.
As a further improvement of the technical scheme, the silicon-containing monomer is vinyl triethoxysilane, and the vinyl triethoxysilane reacts with the fluorine-containing monomer to perform fluorine-silicon modification on the emulsion, so that the modified emulsion has excellent hydrophobicity.
As a further improvement of the technical scheme, the emulsion at least comprises butyl acrylate and acrylic acid, and the emulsion has good adhesive force and is convenient to be matched with cloth in the later period.
As a further improvement of the technical scheme, the initiator is ammonium sulfate, so that the reaction between materials is conveniently initiated.
As a further improvement of the technical scheme, the catalyst is at least one selected from aluminum trichloride, boron trifluoride, antimony pentachloride, ferric bromide, ferric chloride, stannic chloride, titanium tetrachloride and zinc chloride.
As a further improvement of the technical scheme, the grafting agent is polysiloxane, and grafting reaction can be carried out on a fluorosilicone polymer solution under the action of a catalyst, so that the prepared coating has stronger hydrophobic property.
In another aspect, the present invention provides a method for preparing a strongly hydrophobic garment as described in any one of the above, comprising the steps of:
s1, adding the emulsion into a reaction kettle, preheating for 10-15min, then sequentially adding a fluorine-containing monomer, a silicon-containing monomer and methyl methacrylate, and heating and stirring for 60-90 min;
s2, adding an initiator into the emulsion, mixing and stirring for 10-15min, cooling and standing for 6-8h to prepare a fluorosilicone polymer solution, sequentially adding a grafting agent and a catalyst into the fluorosilicone polymer solution, mixing and stirring to prepare the hydrophobic reinforced coating;
s3, preparing the polyester fiber and the acetate fiber into cloth through a textile machine;
s4, soaking the cloth in the hydrophobic reinforced coating, heating and standing for 30-60min, taking out the cloth, repeatedly pressing the cloth through a roller press, and finally drying the cloth for 30-60min through a dryer to obtain the hydrophobic cloth;
and S5, processing the hydrophobic cloth to obtain the hydrophobic clothes.
Preferably, in the step S1, the preheating temperature is 20-40 ℃, and the temperature rising temperature is 40-60 ℃.
Preferably, in the step S4, the soaking temperature is 50-70 ℃.
Compared with the prior art, the invention has the beneficial effects that:
according to the high-hydrophobicity clothes and the preparation method thereof, a fluorine-containing monomer, a silicon-containing monomer, methyl methacrylate and emulsion are polymerized under the action of an initiator to form a fluorine-silicon polymer solution with excellent hydrophobicity, the solution is modified by a grafting agent and a catalyst continuously to prepare a hydrophobic enhanced coating with higher hydrophobicity, cloth is soaked in the coating for matching, and the high-hydrophobicity clothes can be prepared after processing.
Drawings
FIG. 1 is an overall flow diagram of the present invention.
Detailed Description
The technical solutions in the embodiments of the present invention will be clearly and completely described below with reference to the drawings in the embodiments of the present invention, and it is obvious that the described embodiments are only a part of the embodiments of the present invention, and not all of the embodiments. All other embodiments, which can be derived by a person skilled in the art from the embodiments given herein without making any creative effort, shall fall within the protection scope of the present invention.
Example 1 a strongly hydrophobic garment and method of making, comprising:
preparation of hydrophobic reinforced paint
1. Adding 50 parts of emulsion into a reaction kettle, preheating for 10min at 20 ℃, then sequentially adding 5 parts of fluorine-containing monomer, 5 parts of silicon-containing monomer and 1 part of methyl methacrylate, heating to 40 ℃, and stirring for 60 min;
2. adding 1 part of initiator into the emulsion, mixing and stirring for 10min, cooling and standing for 6h to prepare a fluorosilicone polymer solution, sequentially adding 5 parts of grafting agent and 1 part of catalyst into the fluorosilicone polymer solution, mixing and stirring to prepare the hydrophobic reinforced coating;
preparation of hydrophobic clothes
1. Preparing polyester fiber and acetate fiber into cloth through a textile machine;
2. soaking the cloth in the hydrophobic reinforced coating, heating to 50 ℃, standing for 30min, taking out the cloth, repeatedly pressing by a roller press, and finally drying for 30min by a dryer to obtain the hydrophobic cloth;
3. and processing the hydrophobic cloth to obtain the hydrophobic clothes.
Example 2 a strongly hydrophobic garment and method of making, comprising:
preparation of hydrophobic reinforced paint
1. Adding 55 parts of emulsion into a reaction kettle, preheating for 12min at 25 ℃, then sequentially adding 6 parts of fluorine-containing monomer, 6 parts of silicon-containing monomer and 2 parts of methyl methacrylate, heating to 45 ℃, and stirring for 70 min;
2. adding 1 part of initiator into the emulsion, mixing and stirring for 12min, cooling and standing for 6h to prepare a fluorosilicone polymer solution, sequentially adding 6 parts of grafting agent and 1 part of catalyst into the fluorosilicone polymer solution, mixing and stirring to prepare the hydrophobic reinforced coating;
preparation of hydrophobic clothes
1. Preparing polyester fiber and acetate fiber into cloth through a textile machine;
2. soaking the cloth in the hydrophobic reinforced coating, heating to 55 ℃, standing for 40min, taking out the cloth, repeatedly pressing by a roller press, and finally drying for 40min by a dryer to obtain the hydrophobic cloth;
3. and processing the hydrophobic cloth to obtain the hydrophobic clothes.
Example 3 a strongly hydrophobic garment and method of making, comprising:
preparation of hydrophobic reinforced paint
1. Adding 60 parts of emulsion into a reaction kettle, preheating for 13min at 30 ℃, then sequentially adding 7 parts of fluorine-containing monomer, 7 parts of silicon-containing monomer and 3 parts of methyl methacrylate, heating to 50 ℃, and stirring for 80 min;
2. adding 2 parts of initiator into the emulsion, mixing and stirring for 13min, cooling and standing for 7h to prepare a fluorosilicone polymer solution, sequentially adding 7 parts of grafting agent and 2 parts of catalyst into the fluorosilicone polymer solution, mixing and stirring to prepare the hydrophobic reinforced coating;
preparation of hydrophobic clothes
1. Preparing polyester fiber and acetate fiber into cloth through a textile machine;
2. soaking the cloth in the hydrophobic reinforced coating, heating to 60 ℃, standing for 45min, taking out the cloth, repeatedly pressing by a roller press, and finally drying for 45min by a dryer to obtain the hydrophobic cloth;
3. and processing the hydrophobic cloth to obtain the hydrophobic clothes.
Example 4 a strongly hydrophobic garment and method of making, comprising:
preparation of hydrophobic reinforced paint
1. Adding 65 parts of emulsion into a reaction kettle, preheating for 14min at 35 ℃, then sequentially adding 8 parts of fluorine-containing monomer, 8 parts of silicon-containing monomer and 4 parts of methyl methacrylate, heating to 55 ℃, and stirring for 80 min;
2. adding 3 parts of initiator into the emulsion, mixing and stirring for 14min, cooling and standing for 8h to prepare a fluorosilicone polymer solution, sequentially adding 8 parts of grafting agent and 3 parts of catalyst into the fluorosilicone polymer solution, mixing and stirring to prepare the hydrophobic reinforced coating;
preparation of hydrophobic clothes
1. Preparing polyester fiber and acetate fiber into cloth through a textile machine;
2. soaking the cloth in the hydrophobic reinforced coating, heating to 65 ℃, standing for 50min, taking out the cloth, repeatedly pressing by a roller press, and finally drying for 50min by a dryer to obtain the hydrophobic cloth;
3. and processing the hydrophobic cloth to obtain the hydrophobic clothes.
Example 5 a strongly hydrophobic garment and method of making, comprising:
preparation of hydrophobic reinforced paint
1. Adding 70 parts of emulsion into a reaction kettle, preheating for 15min at 40 ℃, then sequentially adding 9 parts of fluorine-containing monomer, 9 parts of silicon-containing monomer and 5 parts of methyl methacrylate, heating to 60 ℃, and stirring for 90 min;
2. adding 3 parts of initiator into the emulsion, mixing and stirring for 15min, cooling and standing for 8h to prepare a fluorosilicone polymer solution, sequentially adding 9 parts of grafting agent and 3 parts of catalyst into the fluorosilicone polymer solution, mixing and stirring to prepare the hydrophobic reinforced coating;
preparation of hydrophobic clothes
1. Preparing polyester fiber and acetate fiber into cloth through a textile machine;
2. soaking the cloth in the hydrophobic reinforced coating, heating to 70 ℃, standing for 60min, taking out the cloth, repeatedly pressing by a roller press, and finally drying for 60min by a dryer to obtain the hydrophobic cloth;
3. and processing the hydrophobic cloth to obtain the hydrophobic clothes.
In the above examples 1 to 5, the fluorine-containing monomer is perfluoroalkyl ethyl methacrylate, the silicon-containing monomer is vinyl triethoxysilane, and the fluorine-containing monomer reacts with the fluorine-containing monomer to perform fluorine-silicon modification on the emulsion, so that the modified emulsion has excellent hydrophobicity;
the emulsion at least comprises butyl acrylate and acrylic acid, and the emulsion has good adhesive force and is convenient to be matched with cloth in the later period;
the initiator is ammonium sulfate, so that the reaction between materials is initiated conveniently;
the catalyst is at least one selected from aluminum trichloride, boron trifluoride, antimony pentachloride, ferric bromide, ferric chloride, stannic chloride, titanium tetrachloride and zinc chloride;
the grafting agent is polysiloxane, and grafting reaction can be carried out on the fluorosilicone polymer solution under the action of a catalyst, so that the prepared coating has stronger hydrophobic property;
fluorine-containing monomer, silicon-containing monomer, methyl methacrylate and emulsion are polymerized under the action of initiator to form fluorosilicone polymer solution with excellent hydrophobicity, the solution is modified by grafting agent and catalyst to prepare hydrophobic reinforced paint with stronger hydrophobic performance, and cloth is soaked in the paint for matching and the clothing with strong hydrophobic performance is prepared after processing.
The indexes related to the clothes with strong hydrophobicity prepared by the invention are shown in table 1:
TABLE 1
| Example 1 | Example 2 | Example 3 | Example 4 | Example 5 | |
| Contact angle (°) | 164 | 166 | 171 | 169 | 167 |
As shown in Table 1, in examples 1 to 5, the contact angles of the hydrophobic clothes are all above 160 degrees, which shows that the clothes have better hydrophobic performance.
Comparative example 1
1. Preparing polyester fiber and acetate fiber into cloth through a textile machine;
2. and processing the cloth to obtain the clothes.
Comparative example 2
Preparation of hydrophobic reinforced paint
Adding 60 parts of emulsion into a reaction kettle, preheating for 13min at 30 ℃, then sequentially adding 7 parts of fluorine-containing monomer, 7 parts of silicon-containing monomer and 3 parts of methyl methacrylate, heating to 50 ℃, and stirring for 80min to obtain a coating;
preparation of hydrophobic clothes
1. Preparing polyester fiber and acetate fiber into cloth through a textile machine;
2. soaking the cloth in the coating, heating to 60 ℃, standing for 45min, taking out the cloth, repeatedly pressing by a roller press, and finally drying for 45min by a dryer to obtain hydrophobic cloth;
3. and processing the hydrophobic cloth to obtain the hydrophobic clothes.
The hydrophobic clothes prepared by the invention have better hydrophobicity, have a larger relationship with the hydrophobic reinforced coating added in the hydrophobic clothes, and in order to verify the related technical scheme, the applicant performs the following tests:
comparative examples 1 to 2: by using the method of example 3, the indexes related to the prepared clothes were examined under the condition that the hydrophobic enhanced coating and the grafting agent and catalyst in the preparation of the hydrophobic enhanced coating were removed, and are specifically shown in table 2:
TABLE 2
| Comparative example 1 | Comparative example 2 | Example 3 | |
| Contact angle (°) | 117 | 145 | 171 |
As shown in Table 2, in comparative example 1, the contact angle of clothes was greatly decreased when the hydrophobic reinforcing coating was completely removed, indicating that the hydrophobicity was greatly decreased, compared to example 3, and in comparative example 2, the contact angle of clothes was significantly decreased when the grafting agent and the catalyst in the preparation of the hydrophobic reinforcing coating were removed, indicating that the hydrophobicity was decreased, compared to example 3, and thus it can be shown that the addition of the hydrophobic reinforcing coating in the present invention is an important factor for improving the hydrophobicity of clothes.
The foregoing shows and describes the general principles, essential features, and advantages of the invention. It will be understood by those skilled in the art that the present invention is not limited to the embodiments described above, and the preferred embodiments of the present invention are described in the above embodiments and the description, and are not intended to limit the present invention. The scope of the invention is defined by the appended claims and equivalents thereof.
Claims (10)
1. A strongly hydrophobic garment, characterized in that: the polyester fiber-acetate fiber-polyester composite material comprises polyester fiber, acetate fiber and a hydrophobic reinforced coating, wherein the hydrophobic reinforced coating at least comprises the following raw materials in parts by weight: 5-9 parts of fluorine-containing monomer, 5-9 parts of silicon-containing monomer, 1-5 parts of methyl methacrylate, 50-70 parts of emulsion, 1-3 parts of initiator, 1-3 parts of catalyst and 5-9 parts of grafting agent.
2. The strongly hydrophobic garment of claim 1, wherein: the fluorine-containing monomer is perfluoroalkyl ethyl methacrylate.
3. The strongly hydrophobic garment of claim 1, wherein: the silicon-containing monomer is vinyl triethoxysilane.
4. The strongly hydrophobic garment of claim 1, wherein: the emulsion includes at least butyl acrylate and acrylic acid.
5. The strongly hydrophobic garment of claim 1, wherein: the initiator is ammonium sulfate.
6. The strongly hydrophobic garment of claim 1, wherein: the catalyst is at least one selected from aluminum trichloride, boron trifluoride, antimony pentachloride, ferric bromide, ferric chloride, stannic chloride, titanium tetrachloride and zinc chloride.
7. The strongly hydrophobic garment according to claim 1, wherein: the grafting agent is polysiloxane.
8. A method for preparing a strongly hydrophobic garment according to any of claims 1-7, comprising the steps of:
s1, adding the emulsion into a reaction kettle, preheating for 10-15min, then sequentially adding the fluorine-containing monomer, the silicon-containing monomer and the methyl methacrylate, and heating and stirring for 60-90 min;
s2, adding an initiator into the emulsion, mixing and stirring for 10-15min, cooling and standing for 6-8h to prepare a fluorosilicone polymer solution, sequentially adding a grafting agent and a catalyst into the fluorosilicone polymer solution, mixing and stirring to prepare the hydrophobic reinforced coating;
s3, preparing the polyester fiber and the acetate fiber into cloth through a textile machine;
s4, soaking the cloth in the hydrophobic reinforced coating, heating and standing for 30-60min, taking out the cloth, repeatedly pressing the cloth through a roller press, and finally drying the cloth for 30-60min through a dryer to obtain the hydrophobic cloth;
and S5, processing the hydrophobic cloth to obtain the hydrophobic clothes.
9. The method of making a strongly hydrophobic garment according to claim 8, wherein: in the S1, the preheating temperature is 20-40 ℃, and the temperature rising temperature is 40-60 ℃.
10. The method of making a strongly hydrophobic garment according to claim 8, wherein: in the S4, the soaking temperature is 50-70 ℃.
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Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101544868A (en) * | 2009-05-08 | 2009-09-30 | 厦门大学 | Fluoro-silicone self-cleaning paint and preparation method thereof |
| CN102443099A (en) * | 2011-09-16 | 2012-05-09 | 陕西科技大学 | Preparation method of (sesqui) siloxane hybrid modified fluorinated polyacrylate emulsion |
| CN103666173A (en) * | 2012-09-04 | 2014-03-26 | 中国石油天然气股份有限公司 | Super hydrophobic anticorrosive paint and preparation method thereof |
| CN107501561A (en) * | 2017-09-24 | 2017-12-22 | 陈晨特 | A kind of cold curing super-hydrophobic automatic cleaning fluorine silicon resin and preparation method thereof |
| CN109824817A (en) * | 2019-01-30 | 2019-05-31 | 广西经正科技开发有限责任公司 | A kind of hydrophobic acrylic acid's aqueous dispersion and preparation method thereof |
| CN216139560U (en) * | 2021-08-12 | 2022-03-29 | 苏州市嘉元化纤有限公司 | Composite fabric with strong hydrophobicity |
-
2022
- 2022-04-12 CN CN202210383625.5A patent/CN114622420A/en active Pending
Patent Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101544868A (en) * | 2009-05-08 | 2009-09-30 | 厦门大学 | Fluoro-silicone self-cleaning paint and preparation method thereof |
| CN102443099A (en) * | 2011-09-16 | 2012-05-09 | 陕西科技大学 | Preparation method of (sesqui) siloxane hybrid modified fluorinated polyacrylate emulsion |
| CN103666173A (en) * | 2012-09-04 | 2014-03-26 | 中国石油天然气股份有限公司 | Super hydrophobic anticorrosive paint and preparation method thereof |
| CN107501561A (en) * | 2017-09-24 | 2017-12-22 | 陈晨特 | A kind of cold curing super-hydrophobic automatic cleaning fluorine silicon resin and preparation method thereof |
| CN109824817A (en) * | 2019-01-30 | 2019-05-31 | 广西经正科技开发有限责任公司 | A kind of hydrophobic acrylic acid's aqueous dispersion and preparation method thereof |
| CN216139560U (en) * | 2021-08-12 | 2022-03-29 | 苏州市嘉元化纤有限公司 | Composite fabric with strong hydrophobicity |
Non-Patent Citations (2)
| Title |
|---|
| 张永革;王慧玲;周彬;陈燕;: "自清洁高仿真貂绒面料的设计与生产", 毛纺科技, vol. 45, no. 01, pages 6 - 9 * |
| 杨秦欢;李正军;张廷有;: "含氟丙烯酸酯聚合物乳液研究新进展(Ⅱ)――新体系:FPUA, PTFE-PA, PFASi与PFA-Nano", 中国皮革, vol. 38, no. 11, pages 42 - 46 * |
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