CN105755870A - Alkali-resistant chlorine-resistant type aldehyde-free active dye color fixing agent and preparation method thereof - Google Patents
Alkali-resistant chlorine-resistant type aldehyde-free active dye color fixing agent and preparation method thereof Download PDFInfo
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- CN105755870A CN105755870A CN201610105035.0A CN201610105035A CN105755870A CN 105755870 A CN105755870 A CN 105755870A CN 201610105035 A CN201610105035 A CN 201610105035A CN 105755870 A CN105755870 A CN 105755870A
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P5/00—Other features in dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form
- D06P5/02—After-treatment
- D06P5/04—After-treatment with organic compounds
- D06P5/08—After-treatment with organic compounds macromolecular
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
- C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
- C08F220/04—Acids; Metal salts or ammonium salts thereof
- C08F220/06—Acrylic acid; Methacrylic acid; Metal salts or ammonium salts thereof
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
- D06M11/73—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with carbon or compounds thereof
- D06M11/74—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with carbon or compounds thereof with carbon or graphite; with carbides; with graphitic acids or their salts
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/38—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using reactive dyes
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P5/00—Other features in dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form
- D06P5/02—After-treatment
- D06P5/10—After-treatment with compounds containing metal
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Abstract
The invention discloses an alkali-resistant chlorine-resistant type aldehyde-free active dye color fixing agent which comprises the following components in parts by weight: 5-10 parts of an organic silicon monomer, 12-15 parts of acrylic acid, 8-13 parts of butyl acrylate, 6-10 parts of butyl diphenyl ether sodium disulfonate, 1-4 parts of cardanol polyoxyethylene ether, 7-10 parts of polyethylene glycol, 1.5-2 parts of carbon nanotubes, 2-3 parts of calcium silicate, 0.5-1 part of an initiator and 10-20 parts of deionized water. The invention further discloses a preparation method of the alkali-resistant chlorine-resistant type aldehyde-free active dye color fixing agent. The alkali-resistant chlorine-resistant type aldehyde-free active dye color fixing agent is good in alkali resistance, high in chlorine solidness and good in water scrubbing resistance, free of influence to appearance and property of a textile, free of toxic substance release in the preparation and use process, and beneficial to environment protection.
Description
Technical field:
The present invention relates to technical field of textile auxiliary agent, be specifically related to a kind of alkaline-resisting resistance to chlorine type without aldehyde reactive dye
Color fixing agent.
Background technology:
Reactive dye are the Dyestuffs Used for Cellulose Fibres that a class is received by the market most, and it is not only replacement disabling dye
One of optimal selection of material and other types of fibers cellulose fiber dyestuff, and process economics, simple to operate, can
Obtain high-caliber every fastness, the wettest fastness.Reactive dye chromatogram is broad, bright in colour, property
The features such as energy is excellent, applicability is strong.Double-active radical dye, particular with two xenovitalism base (vinyl sulfone(RemzaolHuo Xingranliaohuoxingjituan)s
With a chloro-s-triazine active group) dyestuff, be the important kind being widely used at present.It addition, Vinyl-Sulfone Type
Reactive dye are currently used the most more, are particularly suited for contaminating turquoise blue, or green based on turquoise blue,
Cobalt blue and black etc..
Although forming functional group's covalent bonding between reactive dye dyestuff and fiber, if but hydrolyzed in dyeing
Dyestuff or soap insufficient to the dyestuff of non-key sum, also can make its color fastness reduce.Dyestuff is from dyed wet
Fall down on fiber, not only make the color and luster of fabric own shoal light, and white can be stain or dyed other look
The fiber in pool, produces staining and the phenomenon that cuts marks.It addition, the effect such as acid, alkali, ultraviolet and chlorine can cause dye
Material scission of link decomposes, and causes the problems such as the acid and alkali resistance of dyed fabric, Exposure to Sunlight and chlorine fastness difference, affects fabric
Outward appearance.
Color fixing agent is contemplated to make dyed fabric reach the color fastness being satisfied with as the use of dyeing and finishing auxiliaries, keeps
Outward appearance.After fabric uses color fixing agent to process, then can form insoluble color lake, life on fabric by making dyestuff
Reticulate film, make to produce chemical bonds between dyestuff and fiber and increase dyestuff to draw with the intermolecular of fiber
The mode of power improves the washing fastness of dyed fabric and utilizes the buffer capacity of color fixing agent, makes acidity or alkaline matter
It is neutralized, prevents dyestuff and fibroplastic breaking of covalent bonds, improve acid and alkali resistance fastness and utilize in color fixing agent
The effect of smooth agent, reduces the coefficient of friction of fiber surface, thus improves the crock fastness of dyed fabric by purple
Ultraviolet absorbers grafting introduces in color fixing agent molecule, utilizes the ultraviolet-absorbing group suction to daylight middle-ultraviolet lamp
Receive, prevent the ultraviolet destruction to dye structure, thus improve light fastness utilize color fixing agent chlorine resistance or
Chlorine absorptive property, prevents the Active Chlorine degraded to dyestuff, thus improves the chlorine fastness of dyed fabric.
Chinese patent (200810032830.7) discloses a kind of alkali-fast aldehyde-free colour stabilizer, is by acryloyl
The cationic polymer of the aggregated reaction of amine, butyl acrylate, epoxychloropropane, including acrylamide
10-35%, butyl acrylate 15-45%, epoxychloropropane 10-40%, the hydrochloric acid 5-13% of 36.5% and initiator
0.1-1.5%.This color fixing agent resistance to elevated temperatures is extremely strong, and process fabric, without discoloration, does not affect the chlorine-resistant jail of dye thing
Degree, light fastness and sweat light fastness.Chinese patent (201310712869.4) discloses a kind of fabric and lives
Property chlorine-resistant color fixing agent, by weight percentage, including activity color fixing agent 40-60%, polyethylene polyamine 15-30%
With deionized water 25-40%；Wherein activity color fixing agent be dimethyl-dipropenyl ammonium chloride, diallylamine and
Water is polymerized under certain condition.This color fixing agent can resist the ammoniacal liquor of variable concentrations, reduces fabric discoloration,
Chlorine fastness is high, and wash durability is good.But the above color fixing agent can produce poisonous in building-up process
Material, is harmful to environment and human body.
Summary of the invention:
It is an object of the invention to provide a kind of alkaline-resisting resistance to chlorine type without aldehyde active dye fixing agent, this color fixing agent is alkaline-resisting,
Chlorine fastness is high, and wash durability is good, and on appearance of fabrics and performance without impact, it is in preparation and the process of use
Middle without noxious material release, beneficially environmental protection.
It is a further object to provide this alkaline-resisting resistance to chlorine type preparation side without aldehyde active dye fixing agent
Method.
For achieving the above object, the present invention is by the following technical solutions:
A kind of alkaline-resisting resistance to chlorine type is without aldehyde active dye fixing agent, in parts by weight, including following components:
Organic silicon monomer 5-10 part,
Acrylic acid 12-15 part,
Butyl acrylate 8-13 part,
Butyl diphenyl ether sodium disulfonate 6-10 part,
Cardanol polyoxyethylene ether 1-4 part,
Polyethylene glycol 7-10 part,
CNT 1.5-2 part,
Calcium silicates 2-3 part,
Initiator 0.5-1 part,
Deionized water 10-20 part.
Preferred as technique scheme, a kind of alkaline-resisting resistance to chlorine type is without aldehyde active dye fixing agent, with weight
Part meter, including following components:
Organic silicon monomer 7 parts,
13 parts of acrylic acid,
Butyl acrylate 10 parts,
Butyl diphenyl ether sodium disulfonate 8 parts,
Cardanol polyoxyethylene ether 3 parts,
Polyethylene glycol 10 parts,
CNT 1.6 parts,
Calcium silicates 2 parts,
Initiator 1 part,
Deionized water 18 parts.
Preferred as technique scheme, described organic silicon monomer is VTES, ethene
Base triacetoxysilane, vinyl three ('beta '-methoxy ethyoxyl) silane, methacryloxypropyl
One or more mixing in trimethoxy silane, t etram-ethyltetravinylcyclotetrasiloxane.
Preferred as technique scheme, a diameter of 20-50nm of described CNT, a length of
70-90nm。
Preferred as technique scheme, described initiator is the one in ammonium persulfate, potassium peroxydisulfate.
A kind of alkaline-resisting resistance to chlorine type, without the preparation method of aldehyde active dye fixing agent, comprises the following steps:
(1) by acrylic acid, butyl acrylate and deionized water mixing and stirring, it is warming up to 50-60 DEG C,
Add organic silicon monomer, initiator, isothermal reaction 1.5-3h, obtain mixed liquor 1；
(2) in the mixed liquor 1 that step (1) obtains, add CNT and initiator, be warming up to 70-90 DEG C,
Isothermal reaction 2-5h, obtains mixed liquor 2；
(3) by butyl diphenyl ether sodium disulfonate, cardanol polyoxyethylene ether, polyethylene glycol, calcium silicates and
Deionized water mixing and stirring, ultrasonic 1-2h under the power of 1000W, obtain mixed liquor 3；
(4) mixed liquor 3 that the mixed liquor 2 step (2) obtained and step (3) obtain mixes,
Obtain alkaline-resisting resistance to chlorine type without aldehyde active dye fixing agent.
Preferred as technique scheme, in step (1), the condition of described reaction is 60 DEG C, 2h.
Preferred as technique scheme, in step (2), the condition of described reaction is 90 DEG C, 3.5h.
Preferred as technique scheme, in step (3), described ultrasonic condition is 1000W, 1.5h.
The method have the advantages that
Color fixing agent prepared by the present invention has many active groups, can send out with the active group of fabric surface
Raw bonding, forms stable network structure, thus by the fabric face that anchors at of dye molecule fastness, thus
Substantially increasing the wet colour fastness of dyestuff fabric, colour fixation, alkaline-resisting chlorine-resistant property is good；
The addition of CNT makes the fabric after processing have the antistatic property of excellence；And CNT
Bigger draw ratio, its surface active groups is sent out with the active group of fiber surface and other long chain macromolecules
The raw network structure being cross-linked to form is more firm；Color fixing agent prepared by the present invention does not contains formaldehyde, environmental protection.
Detailed description of the invention:
In order to be better understood from the present invention, below by embodiment, the present invention is further described, and embodiment is only
For explaining the present invention, the present invention will not be constituted any restriction.
Embodiment 1
A kind of alkaline-resisting resistance to chlorine type is without aldehyde active dye fixing agent, in parts by weight, including following components:
Organic silicon monomer 5 parts, 12 parts of acrylic acid,
Butyl acrylate 8 parts,
Butyl diphenyl ether sodium disulfonate 6 parts,
Cardanol polyoxyethylene ether 1 part,
Polyethylene glycol 7 parts, CNT 1.5 parts,
Calcium silicates 2 parts, initiator 0.5 part, deionized water 10 parts.
Its preparation method comprises the following steps:
(1) by acrylic acid, butyl acrylate and deionized water mixing and stirring, it is warming up to 50-60 DEG C,
Add organic silicon monomer, initiator, isothermal reaction 1.5h, obtain mixed liquor 1；
(2) in the mixed liquor 1 that step (1) obtains, add CNT and initiator, be warming up to 70 DEG C,
Isothermal reaction 2h, obtains mixed liquor 2；
(3) by butyl diphenyl ether sodium disulfonate, cardanol polyoxyethylene ether, polyethylene glycol calcium silicates with go
Ionized water mixing and stirring, ultrasonic 1h under the power of 1000W, obtain mixed liquor 3；
(4) mixed liquor 3 that the mixed liquor 2 step (2) obtained and step (3) obtain mixes,
Obtain alkaline-resisting resistance to chlorine type without aldehyde active dye fixing agent.
Embodiment 2
A kind of alkaline-resisting resistance to chlorine type is without aldehyde active dye fixing agent, in parts by weight, including following components:
Organic silicon monomer 10 parts, 15 parts of acrylic acid,
Butyl acrylate 13 parts,
Butyl diphenyl ether sodium disulfonate 10 parts,
Cardanol polyoxyethylene ether 4 parts,
Polyethylene glycol 10 parts, CNT 2 parts,
Calcium silicates 3 parts, initiator 1 part, deionized water 20 parts.
Its preparation method comprises the following steps:
(1) by acrylic acid, butyl acrylate and deionized water mixing and stirring, it is warming up to 50-60 DEG C,
Add organic silicon monomer, initiator, isothermal reaction 3h, obtain mixed liquor 1；
(2) in the mixed liquor 1 that step (1) obtains, add CNT and initiator, be warming up to 90 DEG C,
Isothermal reaction 5h, obtains mixed liquor 2；
(3) by butyl diphenyl ether sodium disulfonate, cardanol polyoxyethylene ether, polyethylene glycol calcium silicates with go
Ionized water mixing and stirring, ultrasonic 2h under the power of 1000W, obtain mixed liquor 3；
(4) mixed liquor 3 that the mixed liquor 2 step (2) obtained and step (3) obtain mixes,
Obtain alkaline-resisting resistance to chlorine type without aldehyde active dye fixing agent.
Embodiment 3
A kind of alkaline-resisting resistance to chlorine type is without aldehyde active dye fixing agent, in parts by weight, including following components:
Organic silicon monomer 7 parts, 13 parts of acrylic acid,
Butyl acrylate 10 parts,
Butyl diphenyl ether sodium disulfonate 8 parts,
Cardanol polyoxyethylene ether 3 parts,
Polyethylene glycol 10 parts, CNT 1.6 parts,
Calcium silicates 2 parts, initiator 1 part, deionized water 18 parts.
Its preparation method comprises the following steps:
(1) by acrylic acid, butyl acrylate and deionized water mixing and stirring, it is warming up to 50-60 DEG C,
Add organic silicon monomer, initiator, isothermal reaction 2h, obtain mixed liquor 1；
(2) in the mixed liquor 1 that step (1) obtains, add CNT and initiator, be warming up to 70 DEG C,
Isothermal reaction 3h, obtains mixed liquor 2；
(3) by butyl diphenyl ether sodium disulfonate, cardanol polyoxyethylene ether, polyethylene glycol calcium silicates with go
Ionized water mixing and stirring, ultrasonic 1.2h under the power of 1000W, obtain mixed liquor 3；
(4) mixed liquor 3 that the mixed liquor 2 step (2) obtained and step (3) obtain mixes,
Obtain alkaline-resisting resistance to chlorine type without aldehyde active dye fixing agent.
Embodiment 4
A kind of alkaline-resisting resistance to chlorine type is without aldehyde active dye fixing agent, in parts by weight, including following components:
Organic silicon monomer 6 parts, 13 parts of acrylic acid,
Butyl acrylate 9 parts,
Butyl diphenyl ether sodium disulfonate 7 parts,
Cardanol polyoxyethylene ether 2 parts,
Polyethylene glycol 8 parts, CNT 1.6 parts,
Calcium silicates 2.2 parts, initiator 0.6 part, deionized water 12 parts.
Its preparation method comprises the following steps:
(1) by acrylic acid, butyl acrylate and deionized water mixing and stirring, it is warming up to 50-60 DEG C,
Add organic silicon monomer, initiator, isothermal reaction 2.5h, obtain mixed liquor 1；
(2) in the mixed liquor 1 that step (1) obtains, add CNT and initiator, be warming up to 90 DEG C,
Isothermal reaction 3.5h, obtains mixed liquor 2；
(3) by butyl diphenyl ether sodium disulfonate, cardanol polyoxyethylene ether, polyethylene glycol calcium silicates with go
Ionized water mixing and stirring, ultrasonic 1.4h under the power of 1000W, obtain mixed liquor 3；
(4) mixed liquor 3 that the mixed liquor 2 step (2) obtained and step (3) obtain mixes,
Obtain alkaline-resisting resistance to chlorine type without aldehyde active dye fixing agent.
Embodiment 5
A kind of alkaline-resisting resistance to chlorine type is without aldehyde active dye fixing agent, in parts by weight, including following components:
Organic silicon monomer 7 parts, 14 parts of acrylic acid,
Butyl acrylate 10 parts,
Butyl diphenyl ether sodium disulfonate 8 parts,
Cardanol polyoxyethylene ether 3 parts,
Polyethylene glycol 9 parts, CNT 1.7 parts,
Calcium silicates 2.6 parts, initiator 0.8 part, deionized water 16 parts.
Its preparation method comprises the following steps:
(1) by acrylic acid, butyl acrylate and deionized water mixing and stirring, it is warming up to 50-60 DEG C,
Add organic silicon monomer, initiator, isothermal reaction 2.5h, obtain mixed liquor 1；
(2) in the mixed liquor 1 that step (1) obtains, add CNT and initiator, be warming up to 90 DEG C,
Isothermal reaction 4h, obtains mixed liquor 2；
(3) by butyl diphenyl ether sodium disulfonate, cardanol polyoxyethylene ether, polyethylene glycol calcium silicates with go
Ionized water mixing and stirring, ultrasonic 1.6h under the power of 1000W, obtain mixed liquor 3；
(4) mixed liquor 3 that the mixed liquor 2 step (2) obtained and step (3) obtain mixes,
Obtain alkaline-resisting resistance to chlorine type without aldehyde active dye fixing agent.
Embodiment 6
A kind of alkaline-resisting resistance to chlorine type is without aldehyde active dye fixing agent, in parts by weight, including following components:
Organic silicon monomer 9 parts, 14 parts of acrylic acid,
Butyl acrylate 12 parts,
Butyl diphenyl ether sodium disulfonate 9 parts,
Cardanol polyoxyethylene ether 3.5 parts,
Polyethylene glycol 9.5 parts, CNT 1.9 parts,
Calcium silicates 2.8 parts, initiator 0.9 part, deionized water 18 parts.
Its preparation method comprises the following steps:
(1) by acrylic acid, butyl acrylate and deionized water mixing and stirring, it is warming up to 50-60 DEG C,
Add organic silicon monomer, initiator, isothermal reaction 3h, obtain mixed liquor 1；
(2) in the mixed liquor 1 that step (1) obtains, add CNT and initiator, be warming up to 70-90 DEG C,
Isothermal reaction 4.5h, obtains mixed liquor 2；
(3) by butyl diphenyl ether sodium disulfonate, cardanol polyoxyethylene ether, polyethylene glycol calcium silicates with go
Ionized water mixing and stirring, ultrasonic 1.8h under the power of 1000W, obtain mixed liquor 3；
(4) mixed liquor 3 that the mixed liquor 2 step (2) obtained and step (3) obtain mixes,
Obtain alkaline-resisting resistance to chlorine type without aldehyde active dye fixing agent.
The color fixing agent prepared the present invention below carries out performance test, and wherein comparative example is common commercially available color fixing agent.
Color fixing condition:
1, cloth used: navy and large red Nylon Taffeta；
2, color fixing process: color fixing agent consumption 3.0% (o.w.f), bath raio 1:40, working liquid ph 4.5,
Color fixing temperature 75 DEG C, fixation time 20min, dry.
3, method of testing:
(1) content of formaldehyde test: test according to GB/T 2912.1-2912.2-1998 standard, work as first
< 20ppm thinks and does not detects aldehyde；
(2) soaping fastness: test according to GB/T 3921-1997；Water: according to GB/T
5713-1997 tests；Crock fastness: test according to GB/T 3920-1997；
(3) chlorine fastness: carry out according to ISO105-E03-1994；
Test result is as shown in table 1:
Table 1
From the point of view of table 1, color fixing agent prepared by the present invention can be greatly improved color fastness and the chlorine-resistant of dyed fabric
Fastness, and the formaldehydeless content of fabric processed, to human body and environmentally friendly.
Although the present invention is open as above with embodiment, but it is not limited to protection scope of the present invention,
Any technical staff being familiar with this technology, the change made without departing from the spirit and scope of the invention with
Retouching, all should belong to protection scope of the present invention.
Claims (9)
1. an alkaline-resisting resistance to chlorine type is without aldehyde active dye fixing agent, it is characterised in that in parts by weight,
Including following components:
Organic silicon monomer 5-10 part,
Acrylic acid 12-15 part,
Butyl acrylate 8-13 part,
Butyl diphenyl ether sodium disulfonate 6-10 part,
Cardanol polyoxyethylene ether 1-4 part,
Polyethylene glycol 7-10 part,
CNT 1.5-2 part,
Calcium silicates 2-3 part,
Initiator 0.5-1 part,
Deionized water 10-20 part.
2. a kind of alkaline-resisting resistance to chlorine type as claimed in claim 1 is without aldehyde active dye fixing agent, its feature
It is, in parts by weight, including following components:
Organic silicon monomer 7 parts,
13 parts of acrylic acid,
Butyl acrylate 10 parts,
Butyl diphenyl ether sodium disulfonate 8 parts,
Cardanol polyoxyethylene ether 3 parts,
Polyethylene glycol 10 parts,
CNT 1.6 parts,
Calcium silicates 2 parts,
Initiator 1 part,
Deionized water 18 parts.
3. a kind of alkaline-resisting resistance to chlorine type as claimed in claim 1 is without aldehyde active dye fixing agent, its feature
Be, described organic silicon monomer be VTES, vinyltriacetoxy silane,
Vinyl three ('beta '-methoxy ethyoxyl) silane, methacryloxypropyl trimethoxy silane,
One or more mixing in t etram-ethyltetravinylcyclotetrasiloxane.
4. a kind of alkaline-resisting resistance to chlorine type as claimed in claim 1 is without aldehyde active dye fixing agent, its feature
It is, a diameter of 20-50nm of described CNT, a length of 70-90nm.
5. a kind of alkaline-resisting resistance to chlorine type as claimed in claim 1 is without aldehyde active dye fixing agent, its feature
Being, described initiator is the one in ammonium persulfate, potassium peroxydisulfate.
6. the alkaline-resisting resistance to chlorine type of one as described in claim 1 to 5 is arbitrary is without aldehyde active dye fixing agent
Preparation method, it is characterised in that comprise the following steps:
(1) by acrylic acid, butyl acrylate and deionized water mixing and stirring, it is warming up to 50-60 DEG C,
Add organic silicon monomer, initiator, isothermal reaction 1.5-3h, obtain mixed liquor 1；
(2) in the mixed liquor 1 that step (1) obtains, add CNT and initiator, be warming up to
70-90 DEG C, isothermal reaction 2-5h, obtain mixed liquor 2；
(3) by butyl diphenyl ether sodium disulfonate, cardanol polyoxyethylene ether, polyethylene glycol, silicic acid
Calcium and deionized water mixing and stirring, ultrasonic 1-2h under the power of 1000W, obtain mixed liquor 3；
(4) mixed liquor 3 that the mixed liquor 2 step (2) obtained and step (3) obtain mixes all
Even, obtain alkaline-resisting resistance to chlorine type without aldehyde active dye fixing agent.
A kind of alkaline-resisting resistance to chlorine type the most as claimed in claim 6 is without the preparation side of aldehyde active dye fixing agent
Method, it is characterised in that in step (1), the condition of described reaction is 60 DEG C, 2h.
A kind of alkaline-resisting resistance to chlorine type the most as claimed in claim 6 is without the preparation side of aldehyde active dye fixing agent
Method, it is characterised in that in step (2), the condition of described reaction is 90 DEG C, 3.5h.
A kind of alkaline-resisting resistance to chlorine type the most as claimed in claim 6 is without the preparation side of aldehyde active dye fixing agent
Method, it is characterised in that in step (3), described ultrasonic condition is 1000W, 1.5h.
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Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
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| CN106498785A (en) * | 2016-12-07 | 2017-03-15 | 郑州源冉生物技术有限公司 | A kind of active alkaline-resisting aldehyde-free colour stabilizer and preparation method thereof |
| CN107383389A (en) * | 2017-08-21 | 2017-11-24 | 广东彩虹德记塑胶颜料股份有限公司 | A kind of diffusing oil and preparation method thereof |
| CN107700254A (en) * | 2017-09-06 | 2018-02-16 | 江苏新瑞贝科技股份有限公司 | A kind of preparation method of active dye fixing agent |
| CN110344267A (en) * | 2019-06-28 | 2019-10-18 | 苏州经贸职业技术学院 | A kind of preparation method of the resistance to fabric of soaping of easy dyeing fixation based on reactive dyeing |
| CN112521561A (en) * | 2020-12-15 | 2021-03-19 | 太仓宝霓实业有限公司 | Water-based organic silicon color fixing agent polymer and preparation method thereof |
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| CN112521561A (en) * | 2020-12-15 | 2021-03-19 | 太仓宝霓实业有限公司 | Water-based organic silicon color fixing agent polymer and preparation method thereof |
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