CN114621628A - Sweetener and preparation method thereof - Google Patents
Sweetener and preparation method thereof Download PDFInfo
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- CN114621628A CN114621628A CN202210241099.9A CN202210241099A CN114621628A CN 114621628 A CN114621628 A CN 114621628A CN 202210241099 A CN202210241099 A CN 202210241099A CN 114621628 A CN114621628 A CN 114621628A
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- sweetener
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/02—Printing inks
- C09D11/03—Printing inks characterised by features other than the chemical nature of the binder
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- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H27/00—Special paper not otherwise provided for, e.g. made by multi-step processes
- D21H27/18—Paper- or board-based structures for surface covering
- D21H27/22—Structures being applied on the surface by special manufacturing processes, e.g. in presses
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- General Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
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Abstract
The invention relates to a sweetener and a preparation method thereof, wherein the sweetener comprises the following components in percentage by weight: the sweet taste composition comprises, by weight, 5-50% of a sweet taste composition, 10-50% of a cosolvent, 0.01-0.1% of a mildew preventive, 0-0.1% of a preservative, and the balance of water, wherein the sweet taste composition is prepared by combining at least 2 of sodium o-benzoylsulfimide, potassium o-benzoylsulfimide, acesulfame potassium, sodium cyclamate, N- [ N- (3, 3-dimethylbutyl) -L-alpha-aspartyl-L-phenylalanine 1-methyl ester, stevioside, sucralose, and neohesperidin dihydrochalcone. The sweetener provided by the application is adjustable in taste, different in sweet taste can be obtained by reasonably combining and matching sweet substances and adding food-grade cosolvents such as ethanol and propylene glycol, food mildew preventive and preservative, and the sweetener is easily dispersed in solvent-based gloss oil, can be stored for a long time and has a good market application prospect.
Description
Technical Field
The invention relates to printing ink for cigarette tipping paper, in particular to a sweetening agent and a preparation method thereof.
Background
The cigarette filter is an upper surface portion of the cigarette, and it is necessary to print the outer package with ink for the sake of appearance. In recent years, cigarette filter tip ink has a plurality of popular tastes, and is prepared by adding additives with tastes of sweet taste, mint taste, sour taste and the like into paper ink of a filter tip, wherein the additives are the most sweet taste and are the most popular, such as Nanjing Bihmen, Liaoning people's meeting hall, Changbai mountain saint border, inner Mongolia aweto and the like.
The existing sweetening agent has a single composition, and mainly comprises sodium o-benzoylsulfonimide and N- [ N- (3, 3-dimethylbutyl) -L-alpha-aspartyl-L-phenylalanine 1-methyl ester. The sweetness of the sodium o-benzoylsulfonyl imide is 400-600, the price is low, the solubility in water at normal temperature is high, the defect is that the after taste is bitter, the sodium o-benzoylsulfonyl imide is easy to crystallize and separate out at low temperature, and the sodium o-benzoylsulfonyl imide is not suitable for people who are sensitive to sodium ions such as hypertension; the N- [ N- (3, 3-dimethylbutyl) -L-alpha-aspartyl-L-phenylalanine 1-methyl ester has the sweetness of 5000-7000, is higher in price, soluble in water and alcohol, and purer and more positive in taste, and has the defects that the melting point is only 82 ℃, and a cigarette feeding machine is easy to adhere; some water-soluble sweetening agents are added into solvent-based ink, and the water cannot dissolve resin, so that the sweetening agents are difficult to disperse and easy to mildew after being placed for a long time.
Patent application CN113430859A discloses cigarette that contains novel sweetener connects dress paper, cigarette is with connecing dress paper include the base stock material and the sweetener adhesive linkage on the base stock material, the sweetener adhesive linkage comprises thickener, sour agent, sweetener, cinnamon volatile oil, ginger volatile oil, deionized water, 50% edible ethanol. The sweetener comprises one or more of stevioside, mogroside, rebaudioside, acesulfame potassium, aspartame, sucralose, erythritol, and caramel. According to the scheme, various auxiliary agents are added, so that the pure mouthfeel is not facilitated, and the compatibility of the volatile oil and the printing ink is limited, so that the printing operation is not facilitated.
Disclosure of Invention
The invention aims to overcome the defects of the existing tipping paper for cigarettes, and provides a sweetening agent which solves the problem that the printing ink of the existing tipping paper for cigarettes is not easy to dissolve mutually and affects the printing effect through the matching of components; the printed tipping paper for the cigarettes tastes bitter and the sweet taste is kept for a short time; the cigarette feeding machine is easy to adhere, the formula with reasonable production cost is obtained, meanwhile, the taste is improved, and the cigarette feeding machine also has the advantage of high temperature resistance.
The specific scheme is as follows:
a sweetener is composed of the following components in percentage by weight: 5-50% of sweet composition, 10-50% of cosolvent, 0.01-0.1% of mildew preventive, 0-0.1% of preservative and the balance of water, wherein the sweet composition is prepared by at least 2 of sodium o-benzoylsulfonimide, potassium acesulfame, sodium cyclamate, N- [ N- (3, 3-dimethylbutyl) -L-alpha-aspartyl-L-phenylalanine 1-methyl ester, stevioside, sucralose and neohesperidin dihydrochalcone.
Further, the sweetness of the sweet taste composition is 10000 times that of sucrose in terms of solid, and preferably comprises the following components in percentage by weight:
10-20% of sodium o-benzoylsulfonyl imide, 3-10% of acesulfame potassium, 1-5% of sucralose and 1-5% of neohesperidin dihydrochalcone;
or 40-50% of o-benzoylsulfonyl imide potassium and 2-10% of N- [ N- (3, 3-dimethylbutyl) -L-alpha-aspartyl-L-phenylalanine 1-methyl ester;
or 10-30% of acesulfame potassium and 20-35% of stevioside;
or 20-30% of sodium cyclamate, 1-5% of sucralose and 5-10% of neohesperidin dihydrochalcone;
or 1-10% of acesulfame potassium, 5-15% of sodium cyclamate and 20-35% of N- [ N- (3, 3-dimethylbutyl) -L-alpha-aspartyl-L-phenylalanine 1-methyl ester.
Further, the cosolvent is ethanol or a combination of propylene glycol and ethanol, wherein when the propylene glycol and the ethanol are combined, the content of the propylene glycol in the sweetener is less than or equal to 2%.
Further, the mildew preventive is at least one of propyl 4-hydroxybenzoate, calcium propionate and monoethyl fumarate, and the preservative is at least one of clove, chitosan or tea polyphenol.
Further, the sweetener comprises the following components in percentage by weight: 16% of acesulfame potassium, 25% of stevioside, 23% of water, 35.95% of ethanol and 0.05% of propyl 4-hydroxybenzoate; or 15% of sodium o-benzoylsulfonyl imide, 5% of acesulfame potassium, 1% of sucralose, 2% of neomethyl hesperidin dihydrochalcone, 40% of water, 35.85% of ethanol, 1% of propylene glycol, 0.05% of 4-propyl hydroxybenzoate and 0.1% of clove; or 26% of sodium cyclamate, 2% of sucralose, 8% of neohesperidin dihydrochalcone, 50% of water, 12.95% of ethanol, 1% of propylene glycol and 0.05% of propyl 4-hydroxybenzoate; or 5% of acesulfame potassium, 10% of sodium cyclamate, 27% of N- [ N- (3, 3-dimethylbutyl) -L-alpha-aspartyl-L-phenylalanine 1-methyl ester, 10% of water, 47.94% of ethanol and 0.06% of 4-hydroxybenzoic acid propyl ester.
Furthermore, the solution is clear after the sweetening agent is mixed with the solvent type gloss oil, the temperature resistance index is 110-165 ℃, the taste is sweet, the sweet duration is 10-40s, and the aftertaste is not bitter.
The invention also provides a preparation method of the sweetener, which comprises the following steps:
(1) weighing the raw materials according to the weight percentage,
(2) heating water to 40-50 deg.C;
(3) adding cosolvent, mildew preventive and antiseptic in sequence, and dispersing uniformly;
(4) adding the sweet taste composition, stirring until the sweet taste composition is dissolved, and filtering to obtain the sweetener.
The invention also protects the application of the sweetening agent on the tipping paper for cigarettes.
The invention also protects an ink containing the sweetener.
The invention also protects the tipping paper for the cigarette, which is obtained by printing the printing ink on a paper substrate.
Has the advantages that:
the sweetener provided by the invention has adjustable taste and convenient preparation, can be prepared from o-benzoyl sulfonyl imide potassium with high solubility, can be prepared into high-concentration solution without precipitation at low temperature, can be suitable for people sensitive to sodium, can be prepared into sweeteners with different sweet tastes by reasonably combining and matching sweet substances, adding food-grade cosolvents such as ethanol and propylene glycol and food mildew preventives, and can be easily dispersed in solvent-based gloss oil and stored for a long time.
Detailed Description
The definitions of some of the terms used in the present invention are given below, and other non-mentioned terms have definitions and meanings known in the art:
polishing oil: the varnish is preferably solvent type varnish, can be divided into ester-soluble (the solvent is esters such as ethyl acetate and the like), alcohol-soluble (the solvent is usually ethanol and isopropanol), water-soluble (the solvent is water), UV (the solvent is usually esters containing an acrylic acid structure), offset printing (the solvent is mineral oil) and the like according to a solvent system, and generally comprises a solvent, resin and an auxiliary agent (a slipping agent, an anti-wear agent, a defoaming agent, a wetting agent, a leveling agent, a pH regulator and the like).
Temperature resistance indexes are as follows: the invention uses temperature resistance as a temperature resistance index, specifically, 40 g of solvent type gloss oil, 60 g of diluent and 10 g of sweetener are mixed and stirred for 10s, then a coating is prepared on tipping paper by a wire rod with the film thickness (the wet thickness of ink/paint or the thickness of a dried ink layer/coating), and the temperature when the coating is adhered is tested, namely the temperature corresponding to the temperature resistance index. The higher the temperature, the better the temperature resistance of the product, generally, the higher the temperature resistance index is than 120 ℃, the adhesion of the cigarette feeding machine can not occur.
The sweetener provided by the invention comprises the following components in percentage by weight: the sweet taste composition comprises, by weight, 5-50% of a sweet taste composition, 10-50% of a cosolvent, 0.01-0.1% of a mildew preventive, 0-0.1% of a preservative, and the balance of water, wherein the sweet taste composition is prepared by combining at least 2 of sodium o-benzoylsulfimide, potassium o-benzoylsulfimide, acesulfame potassium, sodium cyclamate, N- [ N- (3, 3-dimethylbutyl) -L-alpha-aspartyl-L-phenylalanine 1-methyl ester, stevioside, sucralose, and neohesperidin dihydrochalcone.
In order to ensure the mouthfeel and printing effect of the sweetener, the weight ratio of the sweet taste composition is 50% at most, the weight ratio of the cosolvent is 50%, the weight ratio of the mildew preventive is 0.1% at most, and the weight ratio of water is 50% at most.
The sweet taste composition has the effect of proper mouthfeel, and in order to avoid discomfort caused by overhigh sweetness, when the sweet taste components are combined, the maximum weight proportion of the sodium o-benzoylsulfonyl imide is 45%, the maximum weight proportion of the potassium o-benzoylsulfonyl imide is 50%, the maximum weight proportion of the potassium acetylsulfanilate is 30%, the maximum weight proportion of the sodium cyclamate is 30%, the maximum weight proportion of the N- [ N- (3, 3-dimethylbutyl) -L-alpha-aspartyl-L-phenylalanine 1-methyl ester is 40%, the maximum weight proportion of the stevioside is 35%, the maximum weight proportion of the sucralose is 4%, and the maximum weight proportion of the neohesperidin dihydrochalcone is 10%.
The combination of 2 sweet components can overcome the defects of a single sweet component, and in the case of sodium o-benzoylsulfimide, the sodium o-benzoylsulfimide has the defects of high bitter taste, short sweet taste retention period, metallic taste, sodium content and the like, so the sodium o-benzoylsulfimide is compounded with acesulfame potassium, sucralose and neohesperidin dihydrochalcone to realize the effects of bitter taste removal, pure sweet taste and long sweet taste retention period.
Preferably, the sweetening composition consists of, in weight percent: 10-20% of sodium o-benzoylsulfonyl imide, 3-10% of acesulfame potassium, 1-5% of sucralose and 1-5% of neohesperidin dihydrochalcone. More preferably, the sweetening composition consists of, in weight percent: 12-18% of sodium o-benzoylsulfonyl imide, 3-8% of acesulfame potassium, 1-3% of sucralose and 1-3% of neohesperidin dihydrochalcone.
In a particular embodiment, the sweetening composition may also employ: 40-50% of o-benzoyl sulfimide potassium and 2-10% of N- [ N- (3, 3-dimethylbutyl) -L-alpha-aspartyl-L-phenylalanine 1-methyl ester. Preferably, the compound comprises 42 to 47 percent of potassium o-benzoylsulfonyl imide and 2 to 5 percent of N- [ N- (3, 3-dimethylbutyl) -L-alpha-aspartyl-L-phenylalanine 1-methyl ester. The single use of the potassium o-benzoylsulfonimide can cause the sweet taste to have aftertaste, and after the potassium o-benzoylsulfonimide is compounded with the N- [ N- (3, 3-dimethylbutyl) -L-alpha-aspartyl-L-phenylalanine 1-methyl ester, the aftertaste can be obviously reduced, the sweet taste is more mellow, and the sweet taste retention period can be prolonged by 1 to 6 seconds.
In a particular embodiment, the sweetening composition may also employ: 10-30% of acesulfame potassium and 20-35% of stevioside; preferably, the content of acesulfame potassium is 10-20%, and the content of stevioside is 20-30%. The stevioside has unique taste similar to that of liquorice which is a Chinese herbal medicine, is easy to dissolve in ethanol, and can remarkably improve the dispersion stability of the sweetener in the solvent gloss oil.
In a particular embodiment, the sweetening composition may also employ: 20-30% of sodium cyclamate, 1-5% of sucralose and 5-10% of neohesperidin dihydrochalcone; preferably, 24-28% of sodium cyclamate, 1-3% of sucralose and 5-9% of neohesperidin dihydrochalcone. Sucralose is the sweet substance closest to sucrose, neohesperidin dihydrochalcone has very high sweetness, can obviously improve the sweetness of the mouthfeel of printed matters, sodium cyclamate is economic, the metal taste is obvious, and the two are matched with the sodium cyclamate, so that the sweetener with good comprehensive mouthfeel and reasonable cost can be obtained.
In a particular embodiment, the sweetening composition may also employ: 1-10% of acesulfame potassium, 5-15% of sodium cyclamate and 20-35% of N- [ N- (3, 3-dimethylbutyl) -L-alpha-aspartyl-L-phenylalanine 1-methyl ester. Preferably, 3-8% of acesulfame potassium, 8-13% of sodium cyclamate and 25-30% of N- [ N- (3, 3-dimethylbutyl) -L-alpha-aspartyl-L-phenylalanine 1-methyl ester. The acesulfame potassium has certain afterbitterness, the cyclohexyl amino sodium sulfonate has certain metal flavor, the two have higher melting points and are more economical, the N- [ N- (3, 3-dimethylbutyl) -L-alpha-aspartyl-L-phenylalanine 1-methyl ester has high solubility in water and ethanol, the sweet taste is kept for a long time, the sweet taste is purer, and the combination of the N- [ N- (3, 3-dimethylbutyl) -L-alpha-aspartyl-L-phenylalanine 1-methyl ester can obtain the sweetening agent which has moderate sodium content, no obvious bitterness and metal flavor in mouthfeel and is more economical.
The cosolvent is ethanol or a combination of propylene glycol and ethanol. When the propylene glycol and the ethanol are combined, the mass content of the propylene glycol in the sweetener is less than or equal to 2 percent, because the boiling point of the propylene glycol is 188 ℃, the propylene glycol has higher solubility on organic sodium and potassium salt, and can be used as a cosolvent of solvent type resin, which is easy to absorb water and slowly volatilize, and is over 2 percent, thus easily causing poor drying and fogging of an ink layer. For example, 0.1-2% of propylene glycol, 10-48% of ethanol, preferably, 1-2% of propylene glycol and 10-48% of ethanol.
The ink disclosed by the invention generally contains gloss oil, a diluent and a sweetening agent, wherein the sweetening agent is the sweetening agent disclosed by the invention, and the rest ingredients can be the same as those in the prior art. The gloss oil is preferably solvent-type gloss oil, and the diluent is generally ethanol, ethyl acetate or a mixture of the two. In a specific embodiment, the ink composition is as follows: 40-50 parts of gloss oil, 60-70 parts of diluent and 10-20 parts of sweetener.
The ink of the present invention can be used for printing on paper substrates, for example, by gravure printing, and the printing method can be the same as that of the prior art, which can be known by those skilled in the art and will not be described herein.
Preferred embodiments of the present invention will be described in more detail below. While the following describes preferred embodiments of the present invention, it should be understood that the present invention may be embodied in various forms and should not be limited by the embodiments set forth herein. The examples do not specify particular techniques or conditions, and are performed according to the techniques or conditions described in the literature in the art or according to the product specifications. The reagents or instruments used are not indicated by the manufacturer, and are all conventional products commercially available. In the following examples, "%" means weight percent, unless otherwise specified.
Example 1
A sweetening agent for cigarette tipping paper comprises the following components, by weight, 15% of sodium o-benzoylsulfimide, 5% of acesulfame potassium, 1% of sucralose, 2% of neomethyl hesperidin dihydrochalcone, 40% of water, 35.85% of ethanol, 1% of propylene glycol, 0.05% of propyl 4-hydroxybenzoate and 0.1% of clove.
The sweetener for cigarette tipping paper of example 1 was prepared by the following steps:
(1) weighing the raw materials according to the weight ratio;
(2) heating water to 45 deg.C;
(3) sequentially adding ethanol, propylene glycol, 4-hydroxy propyl benzoate and flos Caryophylli, and dispersing uniformly;
(4) adding sodium o-benzoylsulfonimide, acesulfame potassium, sucralose and neohesperidin dihydrochalcone, stirring until completely dissolved, and filtering.
Table 1 raw materials used in one wt% of the table
Example 2
A sweetening agent for cigarette tipping paper comprises 45% of potassium o-benzoylsulfonimide, 3% of N- [ N- (3, 3-dimethylbutyl) -L-alpha-aspartyl-L-phenylalanine 1-methyl ester, 36% of water, 13.85% of ethanol, 2% of propylene glycol, 0.1% of 4-hydroxybenzoic acid propyl ester and 0.05% of clove.
The sweetener for cigarette tipping paper of example 2 was prepared by the following steps:
(1) weighing the raw materials according to the weight ratio;
(2) heating water to 50 deg.C;
(3) sequentially adding ethanol, propylene glycol, 4-hydroxy propyl benzoate and flos Caryophylli, and dispersing uniformly;
(4) adding the potassium o-benzoylsulfonyl imide and the N- [ N- (3, 3-dimethylbutyl) -L-alpha-aspartyl-L-phenylalanine 1-methyl ester, stirring until the mixture is completely dissolved, and filtering.
Example 3
A sweetening agent for cigarette tipping paper comprises 16% of acesulfame potassium, 25% of stevioside, 23% of water, 35.95% of ethanol and 0.05% of 4-hydroxy propyl benzoate, and the dosage of each component is shown in Table 1.
The sweetener for tipping paper for cigarettes of example 3 was prepared by the following steps:
(1) weighing the raw materials according to the weight ratio;
(2) heating water to 43 deg.C;
(3) sequentially adding ethanol and 4-propyl hydroxybenzoate, and uniformly dispersing;
(4) adding acesulfame potassium and stevioside, stirring to dissolve completely, and filtering.
Example 4
A sweetening agent for cigarette tipping paper comprises 26% of sodium cyclamate, 2% of sucralose, 8% of neomethyl hesperidin dihydrochalcone, 50% of water, 12.95% of ethanol and 0.05% of propylene glycol 1 and 4-propyl hydroxybenzoate, wherein the dosage of each component is shown in Table 1.
The sweetener for cigarette tipping paper of example 4 was prepared by the following steps:
(1) weighing the raw materials according to the weight ratio;
(2) heating water to 48 deg.C;
(3) sequentially adding ethanol, propylene glycol and 4-hydroxy propyl benzoate, and uniformly dispersing;
(4) adding sodium cyclamate, sucralose and neohesperidin dihydrochalcone, stirring until completely dissolving, and filtering.
Example 5
A sweetening agent for cigarette tipping paper comprises the following components, by weight, 5% of acesulfame potassium, 10% of sodium cyclamate, 27% of N- [ N- (3, 3-dimethylbutyl) -L-alpha-aspartyl-L-phenylalanine 1-methyl ester, 10% of water, 47.94% of ethanol and 0.06% of 4-hydroxybenzoic acid propyl ester.
The sweetener for cigarette tipping paper of example 5 was prepared by the following steps:
(1) weighing the raw materials according to the weight ratio.
(2) Heating water to 40 deg.C;
(3) sequentially adding ethanol and 4-propyl hydroxybenzoate, and uniformly dispersing;
(4) adding acesulfame potassium, sodium cyclamate and N- [ N- (3, 3-dimethylbutyl) -L-alpha-aspartyl-L-phenylalanine 1-methyl ester, stirring until completely dissolved, and filtering.
Examples 6 to 15
A sweetening agent for tipping paper for cigarettes comprises the following components in amount shown in Table 2.
The preparation method comprises the following steps:
(1) weighing the raw materials according to the weight ratio;
(2) heating water to 45 deg.C;
(3) adding cosolvent, mildew preventive and antiseptic in sequence, and dispersing uniformly;
(4) adding the sweet taste composition, stirring to dissolve completely, and filtering.
TABLE 2 raw materials amounts table two wt%
Performance detection
The prepared sweetening agent is mixed with the solvent type gloss oil, and the formula is as follows: 40 g of solvent gloss oil, 60 g of diluent and 10 g of sweetener, manually mixing and stirring for 10s, and observing whether the solution is clear or not.
Temperature resistance: the solution mixed according to the proportion is used for preparing a coating on tipping paper by using a wire rod with the film thickness of 40 microns, and the temperature of the coating when the coating is adhered is tested and used as a temperature-resistant index.
The mouthfeel is as follows: the printed samples were tasted by 50 test persons and the test experience was recorded.
The test results are shown in Table 3.
Table 3 table of performance test results
Comparative example 1
Referring to example 1, a sweetener for tipping paper for cigarettes comprises, by weight, 17% of sodium benzoylsulfonimide, 5% of acesulfame potassium, 1% of sucralose, 40% of water, 35.85% of ethanol, 1% of propylene glycol, 0.05% of propyl 4-hydroxybenzoate, and 0.1% of clove.
A sweetener for tipping paper for cigarettes of the comparative example was prepared by the following steps:
(1) weighing the raw materials according to the weight ratio;
(2) heating water to 45 deg.C;
(3) sequentially adding ethanol, propylene glycol, 4-hydroxy propyl benzoate and flos Caryophylli, and dispersing uniformly;
(4) adding sodium o-benzoylsulfonimide, acesulfame potassium and sucralose, stirring until completely dissolved, and filtering.
The prepared sweetening agent is mixed with the solvent gloss oil and the diluent, the adding proportion of the sweetening agent is 8 wt%, the solvent gloss oil accounts for 35 wt%, and the rest is the diluent, the printing ink is prepared, the sweetness of a printed product is obviously reduced, the afterbitterness is reduced, the sweetness is kept for 7s, the sweetening agent is more crystallized at the temperature of 15 ℃ or below, and the prepared gloss oil also has precipitate, so that the normal operation of printing and the sweetness quality of the printed product are influenced.
Comparative example 2
Referring to example 2, the sweetener for tipping paper for cigarettes comprises the following components in percentage by weight: 45% of o-benzoylsulfonyl imide potassium, 39% of water, 13.85% of ethanol, 2% of propylene glycol, 0.1% of 4-hydroxybenzoic acid propyl ester and 0.05% of clove.
The preparation method is the same as example 2.
The prepared sweetening agent is mixed with the solvent type gloss oil and the diluent, the adding proportion of the sweetening agent is 8 wt%, the solvent type gloss oil accounts for 35 wt%, and the rest is the diluent, the printing ink is prepared, the sweetness of a printed product is weakened, the printed product has obvious afterbitterness, and the sweetness retention time is shortened by 1-3 seconds.
Comparative example 3
Referring to example 3, the sweetener for tipping paper for cigarettes comprises the following components in percentage by weight: 30% of acesulfame potassium, 34% of water, 35.95% of ethanol and 0.05% of 4-hydroxybenzoic acid propyl ester.
The preparation method is the same as example 3.
The prepared sweetening agent is mixed with the solvent type gloss oil and the diluent, the adding proportion of the sweetening agent is 8 wt%, the solvent type gloss oil accounts for 35 wt%, and the rest is the diluent, so that the printing ink is prepared, the sweetness of the printed matter is reduced, the unique sweet taste of the stevioside is lost, and the metal taste and the after-bitterness are obvious.
Comparative example 4
Referring to example 4, the sweetener for tipping paper for cigarettes comprises the following components in percentage by weight: 26% of sodium cyclamate, 2% of sucralose, 58% of water, 12.95% of ethanol, 1% of propylene glycol and 0.05% of 4-hydroxy propyl benzoate.
The preparation method is the same as example 4.
The prepared sweetening agent is mixed with the solvent type gloss oil and the diluent, the adding proportion of the sweetening agent is 8 wt%, the solvent type gloss oil accounts for 35 wt%, and the rest is the diluent, so that the printing ink is prepared, and the mouthfeel and sweetness of a printed product are obviously reduced, and the printed product has certain after-bitterness.
Comparative example 5
Referring to example 5, the sweetener for tipping paper for cigarettes comprises the following components in percentage by weight: 5% of acesulfame potassium, 10% of sodium cyclamate, 27% of stevioside, 10% of water, 47.94% of ethanol and 0.06% of 4-hydroxy propyl benzoate.
The preparation method is the same as example 5.
The prepared sweetening agent is mixed with the solvent gloss oil and the diluent, the adding proportion of the sweetening agent is 8 wt%, the adding proportion of the solvent gloss oil is 35 wt%, and the rest is the diluent, the printing ink is prepared, the sweetness of the printed matter is obviously increased, the sweet taste retention time is prolonged by 2-3 seconds, the liquorice is thick, and the later stage of the taste has obvious astringent taste.
The preferred embodiments of the present invention have been described in detail, however, the present invention is not limited to the specific details of the above embodiments, and various simple modifications may be made to the technical solution of the present invention within the technical idea of the present invention, and these simple modifications are within the protective scope of the present invention.
It should be noted that the various features described in the above embodiments may be combined in any suitable manner without departing from the scope of the invention. The invention is not described in detail in order to avoid unnecessary repetition.
In addition, any combination of the various embodiments of the present invention is also possible, and the same should be considered as the disclosure of the present invention as long as it does not depart from the spirit of the present invention.
Claims (10)
1. A sweetener characterized by: the sweetener comprises the following components in percentage by weight: 5-50% of sweet composition, 10-50% of cosolvent, 0.01-0.1% of mildew preventive, 0-0.1% of preservative and the balance of water, wherein the sweet composition is prepared by at least 2 of sodium o-benzoylsulfonimide, potassium acesulfame, sodium cyclamate, N- [ N- (3, 3-dimethylbutyl) -L-alpha-aspartyl-L-phenylalanine 1-methyl ester, stevioside, sucralose and neohesperidin dihydrochalcone.
2. A sweetener according to claim 1, wherein: the sweetness of the sweet taste composition is 10000 times that of sucrose in terms of solid, and preferably comprises the following components in percentage by weight:
10-20% of sodium o-benzoylsulfonyl imide, 3-10% of acesulfame potassium, 1-5% of sucralose and 1-5% of neohesperidin dihydrochalcone;
or 40-50% of potassium o-benzoylsulfonyl imide and 2-10% of N- [ N- (3, 3-dimethylbutyl) -L-alpha-aspartyl-L-phenylalanine 1-methyl ester;
or 10-30% of acesulfame potassium and 20-35% of stevioside;
or 20-30% of sodium cyclamate, 1-5% of sucralose and 5-10% of neohesperidin dihydrochalcone;
or 1-10% of acesulfame potassium, 5-15% of sodium cyclamate and 20-35% of N- [ N- (3, 3-dimethylbutyl) -L-alpha-aspartyl-L-phenylalanine 1-methyl ester.
3. A sweetener according to claim 1 or 2, characterized in that: the cosolvent is ethanol or a combination of propylene glycol and ethanol, wherein the content of propylene glycol in the sweetener is less than or equal to 2% when the propylene glycol and the ethanol are combined.
4. A sweetener according to claim 1 or 2, wherein: the mildew preventive is at least one of 4-hydroxy propyl benzoate, calcium propionate or monoethyl fumarate, and the preservative is at least one of clove, chitosan or tea polyphenol.
5. A sweetener according to claim 1 or 2, wherein: the sweetener comprises the following components in percentage by weight: 16% of acesulfame potassium, 25% of stevioside, 23% of water, 35.95% of ethanol and 0.05% of propyl 4-hydroxybenzoate; or 15% of sodium o-benzoylsulfonyl imide, 5% of acesulfame potassium, 1% of sucralose, 2% of neomethyl hesperidin dihydrochalcone, 40% of water, 35.85% of ethanol, 2% of propylene glycol, 0.05% of 4-propyl hydroxybenzoate and 0.1% of clove; or 26% of sodium cyclamate, 2% of sucralose, 8% of neohesperidin dihydrochalcone, 50% of water, 12.95% of ethanol, 1% of propylene glycol and 0.05% of propyl 4-hydroxybenzoate; or 5% of acesulfame potassium, 10% of sodium cyclamate, 27% of N- [ N- (3, 3-dimethylbutyl) -L-alpha-aspartyl-L-phenylalanine 1-methyl ester, 10% of water, 47.94% of ethanol and 0.06% of 4-hydroxybenzoic acid propyl ester.
6. A sweetener according to claim 5, wherein: the solution is clear after the sweetening agent and the solvent type gloss oil are mixed and dissolved, the temperature resistance index is 110-165 ℃, the taste is sweet, the duration time of the sweet taste is 10-40s, and the aftertaste is not bitter.
7. A method of making a sweetener according to any one of claims 1 to 6, wherein: the method comprises the following steps:
(1) weighing the raw materials according to the weight percentage,
(2) heating water to 40-50 deg.C;
(3) adding cosolvent, mildew preventive and antiseptic in sequence, and dispersing uniformly;
(4) adding the sweet taste composition, stirring until the sweet taste composition is dissolved, and filtering to obtain the sweetener.
8. Use of a sweetener according to any one of claims 1 to 6 on tipping paper for cigarettes.
9. An ink comprising the sweetener of claim 7.
10. A cigarette tipping paper printed on a paper substrate using the ink of claim 9.
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