CN114589971B - 一种抑菌洗水拖把海绵 - Google Patents
一种抑菌洗水拖把海绵 Download PDFInfo
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- CN114589971B CN114589971B CN202210221523.3A CN202210221523A CN114589971B CN 114589971 B CN114589971 B CN 114589971B CN 202210221523 A CN202210221523 A CN 202210221523A CN 114589971 B CN114589971 B CN 114589971B
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- layer
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- antibacterial
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Abstract
本发明属于海绵技术领域，尤其是一种抑菌洗水拖把海绵，包括内芯，多个所述内芯呈环形阵列分布，所述海绵芯的外表面包裹有透气层，四个所述透气层以轴心连接的焦点为圆心四等分排列分布，所述透气层的外表面包裹有速干层。该抑菌洗水拖把海绵，通过设置抑菌层和除臭层达到了抑菌灭菌的同时起到除臭的效果，使得拖把海绵能够自消毒的同时对使用的地面起到消毒杀菌的效果，能够在有异味的环境使用能够进行吸附异味，通过耐磨细网能够增加拖把海绵使用的寿命，从而能够使得拖把海绵具有杀菌抑菌的效果的同时对地面起到消毒的作用，解决了现有的拖把海绵容易滋生细菌，产生臭味，无法对地面进行杀菌的技术问题。
Description
技术领域
本发明涉及海绵技术领域，尤其涉及一种抑菌洗水拖把海绵。
背景技术
海绵，是一种多孔材料，具有良好的吸水性，能够用于清洁物品。
现有的拖把海绵在实际使用时，存在较多缺点，拖把海绵使用完后水分无法快速蒸发，容易滋生细菌，同时长时间容易产生臭味，在下一次使用时将臭味与细菌带到使用的地面，造成细菌与臭味扩散，同时拖把海绵只能起到清洁作用，无法对地面进行杀菌，而且长时间使用后，与地面摩擦造成脱屑，影响拖地的效果。
发明内容
基于现有的拖把海绵容易滋生细菌，产生臭味，无法对地面进行杀菌，与地面摩擦造成脱屑，影响拖地的效果的技术问题，本发明提出了一种抑菌洗水拖把海绵。
本发明提出的一种抑菌洗水拖把海绵，包括内芯，多个所述内芯呈环形阵列分布，所述海绵芯的外表面包裹有透气层，四个所述透气层以轴心连接的焦点为圆心四等分排列分布，所述透气层的外表面包裹有速干层；
所述速干层的外表面包裹有抑菌层，所述抑菌层的外表面包裹有除臭层；
所述除臭层的外表面包裹有内层吸水层，所述内层吸水层的外表面包裹有外层吸水层，所述外层吸水层的外表面固定连接有弧形阵列分布的筋凸，所述外层吸水层和所述筋凸的外表面均包裹有耐磨细网。
优选地，所述内芯的材质选用高回弹海绵，以及依次包覆于所述内芯以外的各组分的材质分布为：所述透气层的材质为慢回弹海绵，所述透气层的横截面为花环形状；所述速干层的材质为大孔径海绵；所述抑菌层是由无机抗菌层和有机抗菌层构成；所述除臭层是由竹炭纤维层和吸臭层构成；所述内层吸水层的材质为PU亲水海绵；所述外层吸水层的材质为聚酯海绵构成；所述筋凸的材质为聚酯海绵；筋凸与外层吸水层采用发泡机模具发泡一体成型，所述耐磨细网是由聚酯纤维和棉纤维交错编织形成；
通过上述技术方案，高回弹海绵具有超强的回弹性与透气性,低的邂后损失,较高的压缩负荷比值，亦具有较好的耐燃性,其热老化,湿老化及动力疲劳性比较好，能够在变形后快速复原，透气层中的慢回弹海绵具有独特的感温特性，受热时会变软、受冷时会变硬，在接触热水时能够变软便于进行清洁，在不使用时，慢回弹海绵变硬后保持其花环形的形状，与内层之间形成空隙，便于进行透气，加快水分蒸发的速度，内层吸水层和外层吸水层能够快速吸水，对地面起到清洁作用，同时不会在干燥后发硬。
优选地，所述抑菌层和除臭层的外表面均开设有呈环形阵列分布的透气孔，所述透气孔的孔径为3mm-5mm；
通过上述技术方案，能够加快内芯和速干层的水分蒸发。
优选地，所述无机抗菌层的材质为经过纳米氧化锌水溶液涂覆后干燥的聚酯海绵，所述有机抗菌层的材质为有机硅树脂、载银二氧化硅、活性杀菌剂、润滑剂、成膜助剂、增稠剂、消泡剂和去离子水的混合物，所述有机抗菌层涂接在所述无机抗菌层的外表面；
通过上述技术方案，无机抗菌层通过将聚酯海绵涂覆纳米氧化锌水溶液使其具有杀菌消毒的作用，纳米氧化锌在吸收太阳光或照明光源中的紫外线后，在紫外线能量的激发下，从表面电子被激励起来而飞出，会产生具有超强氧化能力的正穴，这种空穴与吸附在材料表面的氧气、羟基和水等反应产生氢氧根、氧负离子和过氧化氢等具有还原作用的羟基自由基及活性氧离子，与空气中的水气反应后会制造出氧离子和氢氧自由基(O,HO),具有极强氧化作用的活性氧、氢氧自由基能将有害有机物、污染物臭气、细菌等氧化分解成无害物质的二氧化碳和水，而电子同时起到还原反应，还原空气中的氧，从而实现拖把海绵自消毒和对工作地面进行消毒的工作。
优选地，所述有机抗菌层的各组分的质量百分比含量分别为有机硅树脂30-40份、载银二氧化硅10-15份、活性杀菌剂15-20份、润滑剂4-5份、成膜助剂3-4份、增稠剂2份、消泡剂3份、去离子水15-30份；
优选地，所述活性杀菌剂的活性成份是经过微胶囊化处理的艾蒿、桧柏和姜黄素，所述成膜助剂选用三丙二醇甲醚；
通过上述技术方案，通过有机抗菌层的涂接，能够增强杀菌抑菌的效果，通过活性杀菌剂中经过微胶囊化能够减缓艾蒿、桧柏和姜黄素释放程度，使得抗菌更加长久，通过天然的植物进行杀菌与抑菌，其抗菌面广，尤其对真菌有较强的杀灭效果，成膜助剂中的三丙二醇甲醚其独特的亲水和亲油平衡使醇醚能对不同的树脂发挥不同的成膜效果。
优选地，所述增稠剂选用聚丙烯酰胺，所述消泡剂选用聚二甲基硅氧烷。
优选地，所述竹炭纤维层的材质为银纤维和竹炭纤维，所述竹炭纤维层的各组分的质量百分比含量分别为银纤维20-60份和竹炭纤维50-80份，将所述银纤维与所述竹炭纤维交错编织成网状；
通过上述技术方案，通过银纤维与竹炭纤维的编织配合，能够增加抑菌抗菌的效果，同时能够起到除臭的作用。
优选地，所述吸臭层的材质为复合消臭纤维，所述复合消臭纤维是利用化学中和的反应和光触媒的复合作用原理,采用除臭剂混入聚合物内进行纺丝形成的纤维，所述吸臭层包裹在所述竹炭纤维层的外表面；
通过上述技术方案，复合消臭纤维中的纤维有皮芯结构，一般皮层选用聚酰胺,芯层选用聚酯除臭剂分散混入皮层部分,其纤维既能除臭除臭抗菌,又能保持原有纤维的性能，并且通过多次洗涤后,除臭性能几乎不变。
优选地，步骤一：在多个内芯的外表面进行固定粘接透气层，固定完成后将包裹有透气层的内芯垂直水平排列插接进入大孔径海绵内部开设的通孔内，四个内芯的相交点为圆心，大孔径海绵形成包裹在透气层外表面的速干层；
步骤二：在速干层的外表面包裹粘接通过纳米氧化锌水溶液涂覆后干燥的聚酯海绵，形成无机抗菌层；
步骤三：将有机硅树脂、载银二氧化硅、润滑剂、成膜助剂、消泡剂和去离子水分别按照对应的质量分依次投入到球磨机中以300r/min高速球磨12小时并充分分散，使其混合均匀，加入增稠剂和活性杀菌剂，以70r/min低速搅拌5小时，过筛并稠化制得，然后将混合物挤出包裹在所述步骤三中的无机抗菌层外表面表面，使之形成有机抗菌层；
步骤四：在有机抗菌层的表面包裹由银纤维和竹炭限位编织形成的竹炭纤维层后，在继续将有复合消臭纤维编织的织物粘接在竹炭纤维层的外表面形成吸臭层，吸臭层与竹炭纤维层粘接形成除臭层，在除臭层的外表面包裹粘接上PU亲水海绵形成内层吸水层后，在其外表面继续包裹聚酯海绵形成的外层吸水层，外层吸水层上具有一体成型的筋凸，最后在外层吸水层的外表面包裹聚酯纤维与棉纤维编织的编织物，形成耐磨细网，从而得到抑菌洗水拖把海绵。
本发明中的有益效果为：
通过设置抑菌层和除臭层达到了抑菌灭菌的同时起到除臭的效果，使得拖把海绵能够自消毒的同时对使用的地面起到消毒杀菌的效果，能够在有异味的环境使用能够进行吸附异味，通过耐磨细网能够增加拖把海绵使用的寿命，从而能够使得拖把海绵具有杀菌抑菌的效果的同时对地面起到消毒的作用，解决了现有的拖把海绵容易滋生细菌，产生臭味，无法对地面进行杀菌，与地面摩擦造成脱屑，影响拖地的效果的技术问题。
附图说明
图1为本发明提出的一种抑菌洗水拖把海绵的示意图；
图2为本发明提出的一种抑菌洗水拖把海绵的内芯结构的立体图；
图3为本发明提出的一种抑菌洗水拖把海绵的透气层结构的立体图。
图中：1、内芯；2、透气层；3、速干层；4、抑菌层；41、无机抗菌层；42、有机抗菌层；5、除臭层；51、竹炭纤维层；52、吸臭层；6、透气孔；7、内层吸水层；8、外层吸水层；9、筋凸；10、耐磨细网。
具体实施方式
下面将结合本发明实施例中的附图，对本发明实施例中的技术方案进行清楚、完整地描述，显然，所描述的实施例仅仅是本发明一部分实施例，而不是全部的实施例。
实施例一
参照图1-3，一种抑菌洗水拖把海绵，包括内芯1，多个内芯1呈环形阵列分布，海绵芯的外表面包裹有透气层2，四个透气层3以轴心连接的焦点为圆心四等分排列分布，透气层2的外表面包裹有速干层3；
进一步地，内芯1的材质选用高回弹海绵，以及依次包覆于内芯1以外的各组分的材质分布为：透气层2的材质为慢回弹海绵，透气层2的横截面为花环形状；速干层3的材质为大孔径海绵；高回弹海绵具有超强的回弹性与透气性,较高的压缩负荷比值，亦具有较好的耐燃性,其热老化,湿老化及动力疲劳性比较好，能够在变形后快速复原，透气层2中的慢回弹海绵具有独特的感温特性，受热时会变软、受冷时会变硬，在接触热水时能够变软便于进行清洁，在不使用时，慢回弹海绵变硬后保持其花环形的形状，与内层之间形成空隙，便于进行透气，加快水分蒸发的速度，速干层3上的大孔径的海绵孔能够加快水分的流逝。
速干层3的外表面包裹有抑菌层4，抑菌层4的外表面包裹有除臭层5；
进一步地，抑菌层4是由无机抗菌层41和有机抗菌层42构成；除臭层5是由竹炭纤维层51和吸臭层52构成；
进一步地，抑菌层4和除臭层5的外表面均开设有呈环形阵列分布的透气孔6，透气孔6的孔径为3mm；能够加快内芯1和速干层3的水分蒸发。
进一步地，无机抗菌层41的材质为经过纳米氧化锌水溶液涂覆后干燥的聚酯海绵，有机抗菌层42的材质为有机硅树脂、载银二氧化硅、活性杀菌剂、润滑剂、成膜助剂、增稠剂、消泡剂和去离子水的混合物，有机抗菌层42涂接在无机抗菌层41的外表面；无机抗菌层41通过将聚酯海绵涂覆纳米氧化锌水溶液使其具有杀菌消毒的作用，纳米氧化锌在吸收太阳光或照明光源中的紫外线后，在紫外线能量的激发下，从表面电子被激励起来而飞出，会产生具有超强氧化能力的正穴，这种空穴与吸附在材料表面的氧气、羟基和水等反应产生氢氧根、氧负离子和过氧化氢等具有还原作用的羟基自由基及活性氧离子，与空气中的水气反应后会制造出氧离子和氢氧自由基(O,HO,)具有极强氧化作用的活性氧、氢氧自由基能将有害有机物、污染物臭气、细菌等氧化分解成无害物质的二氧化碳和水，而电子同时起到还原反应，还原空气中的氧，从而实现拖把海绵自消毒和对工作地面进行消毒的工作。
进一步地，有机抗菌层42的各组分的质量百分比含量分别为有机硅树脂30份、载银二氧化硅13份、活性杀菌剂15份、润滑剂4份、成膜助剂3份、增稠剂2份、消泡剂3份、去离子水30份。
进一步地，活性杀菌剂的活性成份是经过微胶囊化处理的艾蒿、桧柏和姜黄素，成膜助剂选用三丙二醇甲醚；通过有机抗菌层42的涂接，能够增强杀菌抑菌的效果，通过活性杀菌剂中经过微胶囊化能够减缓艾蒿、桧柏和姜黄素释放程度，使得抗菌更加长久，通过天然的植物进行杀菌与抑菌，其抗菌面广，尤其对真菌有较强的杀灭效果，成膜助剂中的三丙二醇甲醚其独特的亲水和亲油平衡使醇醚能对不同的树脂发挥不同的成膜效果。
进一步地，增稠剂选用聚丙烯酰胺，消泡剂选用聚二甲基硅氧烷。
进一步地，竹炭纤维层51的材质为银纤维和竹炭纤维，竹炭纤维层51的各组分的质量百分比含量分别为银纤维30份和竹炭纤维70份，将银纤维与竹炭纤维交错编织形状网状；通过银纤维与竹炭纤维的编织配合，能够增加抑菌抗菌的效果，同时能够起到除臭的作用。
进一步地，吸臭层52的材质为复合消臭纤维，复合消臭纤维是利用化学中和的反应和光触媒的复合作用原理,采用除臭剂混入聚合物内进行纺丝形成的纤维，吸臭层52包裹在竹炭纤维层51的外表面；复合消臭纤维中的纤维有皮芯结构，一般皮层选用聚酰胺,芯层选用聚酯除臭剂分散混入皮层部分,其纤维既能除臭除臭抗菌,又能保持原有纤维的性能，并且通过多次洗涤后,除臭性能几乎不变。
除臭层5的外表面包裹有内层吸水层7，内层吸水层7的外表面包裹有外层吸水层8，外层吸水层8的外表面固定连接有弧形阵列分布的筋凸9，外层吸水层8和筋凸9的外表面均包裹有耐磨细网10；
进一步地，内层吸水层7的材质为PU亲水海绵；外层吸水层8的材质为聚酯海绵构成；筋凸9的材质为聚酯海绵；筋凸9与外层吸水层8采用发泡机模具发泡一体成型，耐磨细网10是由聚酯纤维和棉纤维交错编织形成；内层吸水层7和外层吸水层8能够快速吸水，对地面起到清洁作用，同时不会在干燥后发硬，耐磨细网10增加了拖把海绵的耐磨性。
通过设置抑菌层4和除臭层5达到了抑菌灭菌的同时起到除臭的效果，使得拖把海绵能够自消毒的同时对使用的地面起到消毒杀菌的效果，能够在有异味的环境使用能够进行吸附异味，通过耐磨细网10能够增加拖把海绵使用的寿命，从而能够使得拖把海绵具有杀菌抑菌的效果的同时对地面起到消毒的作用，解决了现有的拖把海绵容易滋生细菌，产生臭味，无法对地面进行杀菌，与地面摩擦造成脱屑，影响拖地的效果的技术问题。
实施例二
参照图1-3，一种抑菌洗水拖把海绵，包括内芯1，多个内芯1呈环形阵列分布，海绵芯的外表面包裹有透气层2，四个透气层3以轴心连接的焦点为圆心四等分排列分布，透气层2的外表面包裹有速干层3；
进一步地，内芯1的材质选用高回弹海绵，以及依次包覆于内芯1以外的各组分的材质分布为：透气层2的材质为慢回弹海绵，透气层2的横截面为花环形状；速干层3的材质为大孔径海绵；高回弹海绵具有超强的回弹性与透气性,低的邂后损失,较高的压缩负荷比值，亦具有较好的耐燃性,其热老化,湿老化及动力疲劳性比较好，能够在变形后快速复原，透气层2中的慢回弹海绵具有独特的感温特性，受热时会变软、受冷时会变硬，在接触热水时能够变软便于进行清洁，在不使用时，慢回弹海绵变硬后保持其花环形的形状，与内层之间形成空隙，便于进行透气，加快水分蒸发的速度，速干层3上的大孔径的海绵孔能够加快水分的流逝。
速干层3的外表面包裹有抑菌层4，抑菌层4的外表面包裹有除臭层5；
抑菌层4是由无机抗菌层41和有机抗菌层42构成；除臭层5是由竹炭纤维层51和吸臭层52构成；
进一步地，抑菌层4和除臭层5的外表面均开设有呈环形阵列分布的透气孔6，透气孔6的孔径为4mm；能够加快内芯1和速干层3的水分蒸发。
进一步地，无机抗菌层41的材质为经过纳米氧化锌水溶液涂覆后干燥的聚酯海绵，有机抗菌层42的材质为有机硅树脂、载银二氧化硅、活性杀菌剂、润滑剂、成膜助剂、增稠剂、消泡剂和去离子水的混合物，有机抗菌层42涂接在无机抗菌层41的外表面；无机抗菌层41通过将聚酯海绵涂覆纳米氧化锌水溶液使其具有杀菌消毒的作用，纳米氧化锌在吸收太阳光或照明光源中的紫外线后，在紫外线能量的激发下，从表面电子被激励起来而飞出，会产生具有超强氧化能力的正穴，这种空穴与吸附在材料表面的氧气、羟基和水等反应产生氢氧根、氧负离子和过氧化氢等具有还原作用的羟基自由基及活性氧离子，与空气中的水气反应后会制造出氧离子和氢氧自由基O,HO,具有极强氧化作用的活性氧、氢氧自由基能将有害有机物、污染物臭气、细菌等氧化分解成无害物质的二氧化碳和水，而电子同时起到还原反应，还原空气中的氧，从而实现拖把海绵自消毒和对工作地面进行消毒的工作。
进一步地，有机抗菌层42的各组分的质量百分比含量分别为有机硅树脂35份、载银二氧化硅15份、活性杀菌剂15份、润滑剂4份、成膜助剂3份、增稠剂2份、消泡剂3份、去离子水23份。
进一步地，活性杀菌剂的活性成份是经过微胶囊化处理的艾蒿、桧柏和姜黄素，成膜助剂选用三丙二醇甲醚；通过有机抗菌层42的涂接，能够增强杀菌抑菌的效果，通过活性杀菌剂中经过微胶囊化能够减缓艾蒿、桧柏和姜黄素释放程度，使得抗菌更加长久，通过天然的植物进行杀菌与抑菌，其抗菌面广，尤其对真菌有较强的杀灭效果，成膜助剂中的三丙二醇甲醚其独特的亲水和亲油平衡使醇醚能对不同的树脂发挥不同的成膜效果。
进一步地，增稠剂选用聚丙烯酰胺，消泡剂选用聚二甲基硅氧烷。
进一步地，竹炭纤维层51的材质为银纤维和竹炭纤维，竹炭纤维层51的各组分的质量百分比含量分别为银纤维40份和竹炭纤维60份，将银纤维与竹炭纤维交错编织形状网状；通过银纤维与竹炭纤维的编织配合，能够增加抑菌抗菌的效果，同时能够起到除臭的作用。
进一步地，吸臭层52的材质为复合消臭纤维，复合消臭纤维是利用化学中和的反应和光触媒的复合作用原理,采用除臭剂混入聚合物内进行纺丝形成的纤维，吸臭层52包裹在竹炭纤维层51的外表面；复合消臭纤维中的纤维有皮芯结构，一般皮层选用聚酰胺,芯层选用聚酯除臭剂分散混入皮层部分,其纤维既能除臭除臭抗菌,又能保持原有纤维的性能，并且通过多次洗涤后,除臭性能几乎不变。
除臭层5的外表面包裹有内层吸水层7，内层吸水层7的外表面包裹有外层吸水层8，外层吸水层8的外表面固定连接有弧形阵列分布的筋凸9，外层吸水层8和筋凸9的外表面均包裹有耐磨细网10；
进一步地，内层吸水层7的材质为PU亲水海绵；外层吸水层8的材质为聚酯海绵构成；筋凸9的材质为聚酯海绵；筋凸9与外层吸水层8采用发泡机模具发泡一体成型，耐磨细网10是由聚酯纤维和棉纤维交错编织形成；内层吸水层7和外层吸水层8能够快速吸水，对地面起到清洁作用，同时不会在干燥后发硬，耐磨细网10增加了拖把海绵的耐磨性。
通过设置抑菌层4和除臭层5达到了抑菌灭菌的同时起到除臭的效果，使得拖把海绵能够自消毒的同时对使用的地面起到消毒杀菌的效果，能够在有异味的环境使用能够进行吸附异味，通过耐磨细网10能够增加拖把海绵使用的寿命，从而能够使得拖把海绵具有杀菌抑菌的效果的同时对地面起到消毒的作用，解决了现有的拖把海绵容易滋生细菌，产生臭味，无法对地面进行杀菌，与地面摩擦造成脱屑，影响拖地的效果的技术问题。
实施例三
参照图1-3，一种抑菌洗水拖把海绵，包括内芯1，多个内芯1呈环形阵列分布，海绵芯的外表面包裹有透气层2，四个透气层3以轴心连接的焦点为圆心四等分排列分布，透气层2的外表面包裹有速干层3；
进一步地，内芯1的材质选用高回弹海绵，以及依次包覆于内芯1以外的各组分的材质分布为：透气层2的材质为慢回弹海绵，透气层2的横截面为花环形状；速干层3的材质为大孔径海绵；高回弹海绵具有超强的回弹性与透气性,低的邂后损失,较高的压缩负荷比值，亦具有较好的耐燃性,其热老化,湿老化及动力疲劳性比较好，能够在变形后快速复原，透气层2中的慢回弹海绵具有独特的感温特性，受热时会变软、受冷时会变硬，在接触热水时能够变软便于进行清洁，在不使用时，慢回弹海绵变硬后保持其花环形的形状，与内层之间形成空隙，便于进行透气，加快水分蒸发的速度，速干层3上的大孔径的海绵孔能够加快水分的流逝。
速干层3的外表面包裹有抑菌层4，抑菌层4的外表面包裹有除臭层5；
抑菌层4是由无机抗菌层41和有机抗菌层42构成；除臭层5是由竹炭纤维层51和吸臭层52构成；
进一步地，抑菌层4和除臭层5的外表面均开设有呈环形阵列分布的透气孔6，透气孔6的孔径为5mm；能够加快内芯1和速干层3的水分蒸发。
进一步地，无机抗菌层41的材质为经过纳米氧化锌水溶液涂覆后干燥的聚酯海绵，有机抗菌层42的材质为有机硅树脂、载银二氧化硅、活性杀菌剂、润滑剂、成膜助剂、增稠剂、消泡剂和去离子水的混合物，有机抗菌层42涂接在无机抗菌层41的外表面；无机抗菌层41通过将聚酯海绵涂覆纳米氧化锌水溶液使其具有杀菌消毒的作用，纳米氧化锌在吸收太阳光或照明光源中的紫外线后，在紫外线能量的激发下，从表面电子被激励起来而飞出，会产生具有超强氧化能力的正穴，这种空穴与吸附在材料表面的氧气、羟基和水等反应产生氢氧根、氧负离子和过氧化氢等具有还原作用的羟基自由基及活性氧离子，与空气中的水气反应后会制造出氧离子和氢氧自由基O,HO,具有极强氧化作用的活性氧、氢氧自由基能将有害有机物、污染物臭气、细菌等氧化分解成无害物质的二氧化碳和水，而电子同时起到还原反应，还原空气中的氧，从而实现拖把海绵自消毒和对工作地面进行消毒的工作。
进一步地，有机抗菌层42的各组分的质量百分比含量分别为有机硅树脂40份、载银二氧化硅10份、活性杀菌剂10份、润滑剂5份、成膜助剂4份、增稠剂2份、消泡剂3份、去离子水26份。
进一步地，活性杀菌剂的活性成份是经过微胶囊化处理的艾蒿、桧柏和姜黄素，成膜助剂选用三丙二醇甲醚；通过有机抗菌层42的涂接，能够增强杀菌抑菌的效果，通过活性杀菌剂中经过微胶囊化能够减缓艾蒿、桧柏和姜黄素释放程度，使得抗菌更加长久，通过天然的植物进行杀菌与抑菌，其抗菌面广，尤其对真菌有较强的杀灭效果，成膜助剂中的三丙二醇甲醚其独特的亲水和亲油平衡使醇醚能对不同的树脂发挥不同的成膜效果。
进一步地，增稠剂选用聚丙烯酰胺，消泡剂选用聚二甲基硅氧烷。
进一步地，竹炭纤维层51的材质为银纤维和竹炭纤维，竹炭纤维层51的各组分的质量百分比含量分别为银纤维20份和竹炭纤维80份，将银纤维与竹炭纤维交错编织形状网状；通过银纤维与竹炭纤维的编织配合，能够增加抑菌抗菌的效果，同时能够起到除臭的作用。
进一步地，吸臭层52的材质为复合消臭纤维，复合消臭纤维是利用化学中和的反应和光触媒的复合作用原理,采用除臭剂混入聚合物内进行纺丝形成的纤维，吸臭层52包裹在竹炭纤维层51的外表面；复合消臭纤维中的纤维有皮芯结构，一般皮层选用聚酰胺,芯层选用聚酯除臭剂分散混入皮层部分,其纤维既能除臭除臭抗菌,又能保持原有纤维的性能，并且通过多次洗涤后,除臭性能几乎不变。
除臭层5的外表面包裹有内层吸水层7，内层吸水层7的外表面包裹有外层吸水层8，外层吸水层8的外表面固定连接有弧形阵列分布的筋凸9，外层吸水层8和筋凸9的外表面均包裹有耐磨细网10。
进一步地，内层吸水层7的材质为PU亲水海绵；外层吸水层8的材质为聚酯海绵构成；筋凸9的材质为聚酯海绵；筋凸9与外层吸水层8采用发泡机模具发泡一体成型，耐磨细网10是由聚酯纤维和棉纤维交错编织形成；内层吸水层7和外层吸水层8能够快速吸水，对地面起到清洁作用，同时不会在干燥后发硬，耐磨细网10增加了拖把海绵的耐磨性。
通过设置抑菌层4和除臭层5达到了抑菌灭菌的同时起到除臭的效果，使得拖把海绵能够自消毒的同时对使用的地面起到消毒杀菌的效果，能够在有异味的环境使用能够进行吸附异味，通过耐磨细网10能够增加拖把海绵使用的寿命，从而能够使得拖把海绵具有杀菌抑菌的效果的同时对地面起到消毒的作用，解决了现有的拖把海绵容易滋生细菌，产生臭味，无法对地面进行杀菌，与地面摩擦造成脱屑，影响拖地的效果的技术问题。
工作原理：在多个内芯1的外表面进行固定粘接透气层2，固定完成后将包裹有透气层2的内芯1垂直水平排列插接进入大孔径海绵内部开设的通孔内，四个内芯1的相交点为圆心，大孔径海绵形成包裹在透气层2外表面的速干层3；
在速干层3的外表面包裹粘接通过纳米氧化锌水溶液涂覆后干燥的聚酯海绵，形成无机抗菌层41；
将有机硅树脂、载银二氧化硅、润滑剂、成膜助剂、消泡剂和去离子水分别按照对应的质量分依次投入到球磨机中以300r/min高速球磨12小时并充分分散，使其混合均匀，加入增稠剂和活性杀菌剂，以70r/min低速搅拌5小时，过筛并稠化制得，然后将混合物挤出包裹在步骤三中的无机抗菌层41外表面表面，使之形成有机抗菌层42；
在有机抗菌层42的表面包裹由银纤维和竹炭限位编织形成的竹炭纤维层51后，在继续将有复合消臭纤维编织的织物粘接在竹炭纤维层51的外表面形成吸臭层52，吸臭层52与竹炭纤维层51粘接形成除臭层5，在除臭层5的外表面包裹粘接上PU亲水海绵形成内层吸水层7后，在其外表面继续包裹聚酯海绵形成外层吸水层8，外层吸水层8上具有一体成型的筋凸9，最后在外层吸水层8的外表面包裹聚酯纤维与棉纤维编织的编织物，形成耐磨细网10，从而得到抑菌洗水拖把海绵。
以上所述，仅为本发明较佳的具体实施方式，但本发明的保护范围并不局限于此，任何熟悉本技术领域的技术人员在本发明揭露的技术范围内，根据本发明的技术方案及其发明构思加以等同替换或改变，都应涵盖在本发明的保护范围之内。
Claims (5)
1.一种抑菌洗水拖把海绵，其特征在于：包括内芯（1），多个所述内芯（1）呈环形阵列分布，所述内芯（1）的外表面包裹有透气层（2），四个所述透气层（2）以轴心连接的焦点为圆心四等分排列分布，所述透气层（2）的外表面包裹有速干层（3）；
所述速干层（3）的外表面包裹有抑菌层（4），所述抑菌层（4）的外表面包裹有除臭层（5）；
所述除臭层（5）的外表面包裹有内层吸水层（7），所述内层吸水层（7）的外表面包裹有外层吸水层（8），所述外层吸水层（8）的外表面固定连接有弧形阵列分布的筋凸（9），所述外层吸水层（8）和所述筋凸（9）的外表面均包裹有耐磨细网（10）；
所述内芯（1）的材质选用高回弹海绵，以及依次包覆于所述内芯（1）以外的各组分的材质分布为：所述透气层（2）的材质为慢回弹海绵，所述透气层（2）的横截面为花环形状；所述速干层（3）的材质为大孔径海绵；所述抑菌层（4）是由无机抗菌层（41）和有机抗菌层（42）构成；所述除臭层（5）是由竹炭纤维层（51）和吸臭层（52）构成；所述内层吸水层（7）的材质为PU亲水海绵；所述外层吸水层（8）的材质为聚酯海绵构成；所述筋凸（9）的材质为聚酯海绵；筋凸（9）与外层吸水层（8）采用发泡机模具发泡一体成型，所述耐磨细网（10）是由聚酯纤维和棉纤维交错编织形成；
所述无机抗菌层（41）的材质为经过纳米氧化锌水溶液涂覆后干燥的聚酯海绵，所述有机抗菌层（42）的材质为有机硅树脂、载银二氧化硅、活性杀菌剂、润滑剂、成膜助剂、增稠剂、消泡剂和去离子水的混合物，所述有机抗菌层（42）涂接在所述无机抗菌层（41）的外表面；
所述有机抗菌层（42）的各组分的质量百分比含量分别为有机硅树脂30-40份、载银二氧化硅10-15份、活性杀菌剂15-20份、润滑剂4-5份、成膜助剂3-4份、增稠剂2份、消泡剂3份、去离子水15-30份；
所述活性杀菌剂的活性成份是经过微胶囊化处理的艾蒿、桧柏和姜黄素，所述成膜助剂选用三丙二醇甲醚；
所述增稠剂选用聚丙烯酰胺，所述消泡剂选用聚二甲基硅氧烷。
2.根据权利要求1所述的一种抑菌洗水拖把海绵，其特征在于：所述抑菌层（4）和除臭层（5）的外表面均开设有呈环形阵列分布的透气孔（6），所述透气孔（6）的孔径为3mm-5mm。
3.根据权利要求1所述的一种抑菌洗水拖把海绵，其特征在于：所述竹炭纤维层（51）的材质为银纤维和竹炭纤维，所述竹炭纤维层的各组分的质量百分比含量分别为银纤维20-60份和竹炭纤维50-80份，将所述银纤维与所述竹炭纤维交错编织成网状。
4.根据权利要求1所述的一种抑菌洗水拖把海绵，其特征在于：所述吸臭层（52）的材质为复合消臭纤维，所述复合消臭纤维是利用化学中和的反应和光触媒的复合作用原理,采用除臭剂混入聚合物内进行纺丝形成的纤维，所述吸臭层（52）包裹在所述竹炭纤维层（51）的外表面。
5.基于权利要求1-4任意一项所述一种抑菌洗水拖把海绵的制备工艺，包括如下步骤：
步骤一：在多个内芯（1）的外表面进行固定粘接透气层（2），固定完成后将包裹有透气层（2）的内芯（1）垂直水平排列插接进入大孔径海绵内部开设的通孔内，四个内芯（1）的相交点为圆心，大孔径海绵形成包裹在透气层（2）外表面的速干层（3）；
步骤二：在速干层（3）的外表面包裹粘接通过纳米氧化锌水溶液涂覆后干燥的聚酯海绵，形成无机抗菌层（41）；
步骤三：将有机硅树脂、载银二氧化硅、润滑剂、成膜助剂、消泡剂和去离子水分别按照对应的质量分依次投入到球磨机中以300r/min高速球磨12小时并充分分散，使其混合均匀，加入增稠剂和活性杀菌剂，以70r/min低速搅拌5小时，过筛并稠化制得，然后将混合物挤出包裹在所述步骤三中的无机抗菌层（41）外表面表面，使之形成有机抗菌层（42）；
步骤四：在有机抗菌层（42）的表面包裹由银纤维和竹炭限位编织形成的竹炭纤维层（51）后，在继续将有复合消臭纤维编织的织物粘接在竹炭纤维层（51）的外表面形成吸臭层（52），吸臭层（52）与竹炭纤维层（51）粘接形成除臭层（5），在除臭层（5）的外表面包裹粘接上PU亲水海绵形成内层吸水层（7）后，在其外表面继续包裹聚酯海绵形成的外层吸水层（8），外层吸水层（8）上具有一体成型的筋凸（9），最后在外层吸水层（8）的外表面包裹聚酯纤维与棉纤维编织的编织物，形成耐磨细网（10），从而得到抑菌洗水拖把海绵。
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