CN114574254A - Biomass power fuel and preparation method thereof - Google Patents

Biomass power fuel and preparation method thereof Download PDF

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Publication number
CN114574254A
CN114574254A CN202210309803.XA CN202210309803A CN114574254A CN 114574254 A CN114574254 A CN 114574254A CN 202210309803 A CN202210309803 A CN 202210309803A CN 114574254 A CN114574254 A CN 114574254A
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CN
China
Prior art keywords
parts
biomass power
power fuel
auxiliary agent
improver
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN202210309803.XA
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Chinese (zh)
Inventor
肖松良
张早贵
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Hunan Chuang'ou New Energy Technology Co ltd
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Hunan Chuang'ou New Energy Technology Co ltd
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Priority to CN202210309803.XA priority Critical patent/CN114574254A/en
Publication of CN114574254A publication Critical patent/CN114574254A/en
Pending legal-status Critical Current

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    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10LFUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00Liquid carbonaceous fuels
    • C10L1/02Liquid carbonaceous fuels essentially based on components consisting of carbon, hydrogen, and oxygen only
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10LFUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00Liquid carbonaceous fuels
    • C10L1/10Liquid carbonaceous fuels containing additives
    • C10L1/14Organic compounds
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10LFUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L10/00Use of additives to fuels or fires for particular purposes
    • C10L10/04Use of additives to fuels or fires for particular purposes for minimising corrosion or incrustation
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10LFUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L10/00Use of additives to fuels or fires for particular purposes
    • C10L10/12Use of additives to fuels or fires for particular purposes for improving the cetane number
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10LFUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00Liquid carbonaceous fuels
    • C10L1/10Liquid carbonaceous fuels containing additives
    • C10L1/14Organic compounds
    • C10L1/22Organic compounds containing nitrogen
    • C10L1/23Organic compounds containing nitrogen containing at least one nitrogen-to-oxygen bond, e.g. nitro-compounds, nitrates, nitrites
    • C10L1/231Organic compounds containing nitrogen containing at least one nitrogen-to-oxygen bond, e.g. nitro-compounds, nitrates, nitrites nitro compounds; nitrates; nitrites
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10LFUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00Liquid carbonaceous fuels
    • C10L1/10Liquid carbonaceous fuels containing additives
    • C10L1/14Organic compounds
    • C10L1/24Organic compounds containing sulfur, selenium and/or tellurium
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10LFUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00Liquid carbonaceous fuels
    • C10L1/10Liquid carbonaceous fuels containing additives
    • C10L1/14Organic compounds
    • C10L1/30Organic compounds compounds not mentioned before (complexes)
    • C10L1/305Organic compounds compounds not mentioned before (complexes) organo-metallic compounds (containing a metal to carbon bond)
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E50/00Technologies for the production of fuel of non-fossil origin
    • Y02E50/30Fuel from waste, e.g. synthetic alcohol or diesel

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  • Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Engineering & Computer Science (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Combustion & Propulsion (AREA)
  • Liquid Carbonaceous Fuels (AREA)

Abstract

The invention discloses a biomass power fuel and a preparation method thereof, wherein the biomass power fuel comprises the following components in percentage by mass: 40-50 parts of fatty acid methyl ester, 35-45 parts of liquid wax, 10-15 parts of ethylene propylene alcohol and 2-5 parts of an auxiliary agent; the auxiliary agent comprises the following components: combustion improver, cetane improver and anti-sulfidation corrosion agent. The biomass power fuel can completely replace the traditional petrochemical diesel oil, has various indexes reaching or being superior to 0# commercial diesel oil, is a novel environment-friendly energy source, has strong stability, extremely low sulfur content, good safety, higher efficiency and more environment protection compared with 0# diesel oil, more sufficient combustion, more superior power performance and lower emission, and is beneficial to saving energy and protecting environment; meanwhile, the raw materials of the invention have wide sources, low cost and simple preparation process.

Description

Biomass power fuel and preparation method thereof
Technical Field
The invention relates to a biomass liquid fuel, in particular to a biomass power fuel capable of completely replacing petroleum diesel.
Background
Along with the development of national economy, the increase of motor vehicles, the increment of the use amount of industrial and agricultural diesel engines and the rapid increase of the use amount of fuel boilers, the consumption amount of diesel oil is more and more large. However, petroleum resources are non-renewable resources, and the petroleum resources are quickly exhausted by using a large amount of petroleum resources. With the global shortage of petroleum resources, the research on new energy resources in various countries is more and more emphasized, and a large amount of capital and manpower are invested for research. Different technical means are adopted to overcome the difficulty and find substitutes. However, the actual situation is not optimistic so far, and the fuel produced by research has poor combustion performance, high corrosion to machinery, high requirement on raw materials, high production cost, unstable performance and problems in storage and circulation.
With the increasingly prominent energy crisis and the serious environmental pollution, the dependence of society on petrochemical fuels is indispensable. Therefore, the research and development of gasoline and diesel oil substitutes are urgent, and the production of a clean, efficient, low-emission and economical novel energy source is imperative.
Disclosure of Invention
The technical problem to be solved by the invention is to overcome the defects of the prior art and provide a biomass power fuel and a preparation method thereof.
The technical scheme adopted by the invention for solving the technical problems is as follows:
a biomass power fuel comprises the following components: fatty acid methyl ester, liquid wax, ethylene propylene alcohol and an auxiliary agent.
Further, the mass ratio of each component is as follows:
40-50 parts of fatty acid methyl ester;
35-45 parts of liquid wax;
10-15 parts of ethyl propanol;
and 2-5 parts of an auxiliary agent.
Further, the mass ratio of each component is as follows:
50 parts of fatty acid methyl ester;
35 parts of liquid wax;
13 parts of ethyl propanol;
and 2 parts of an auxiliary agent.
The auxiliary agent comprises the following components: combustion improver, cetane improver and anti-sulfidation corrosion agent.
Further, the mass ratio of each component of the auxiliary agent is as follows:
1-2 parts of a combustion improver;
2-6 parts of a cetane number improver;
and 1-2 parts of anti-sulfuration corrosion agent.
Further, the mass ratio of each component of the auxiliary agent is as follows:
1 part of combustion improver;
2 parts of cetane number improver;
and 1 part of anti-sulfuration corrosion agent.
The combustion improver comprises dicyclopentadienyl iron.
The cetane improver includes amyl nitrate.
The anti-sulfuration corrosion agent comprises T122 high base number sulfuration alkyl calcium phenate.
A preparation method of biomass power fuel comprises the following steps:
1) adding fatty acid methyl ester, liquid wax and ethyl propanol into a mixing tank according to a certain proportion, fully stirring and mixing;
2) adding the auxiliary agent, and fully stirring and mixing;
3) and finally standing for a moment to prepare the fuel.
Stirring and mixing for 10 minutes in the step 1; stirring and mixing for 10 minutes in the step 2; and standing for 30 minutes in the step 3.
All steps are carried out at normal temperature and pressure.
Compared with the prior art, the invention has the beneficial effects that:
the synthetic biomass power fuel provided by the invention can completely replace the traditional petrochemical diesel, and each index reaches or is superior to 0# commercial diesel, thus being a novel environment-friendly energy source.
The structure of the existing diesel engine is not required to be changed, and the diesel engine can be directly used for replacing 0# diesel oil and is completely universal with 0# diesel oil; the fuel has strong stability, extremely low sulfur content, high flash point of 70-100 ℃, good safety and high condensation point of-30 ℃, and is more suitable for high and cold areas; compared with 0# diesel oil, the diesel oil is more efficient and environment-friendly, can be combusted more fully, has more excellent dynamic property and lower emission, and is beneficial to energy conservation and environmental protection.
Meanwhile, the raw materials of the invention have wide sources, the cost is lower, the preparation process is simple, three wastes are not generated in the production process, and the market prospect is wide.
Detailed Description
The present invention will be further described with reference to specific embodiments.
Example 1
The preparation method of the biomass power fuel designed by the preferred embodiment of the invention comprises the following steps:
adding 50kg of fatty acid methyl ester, 35kg of liquid wax and 13kg of ethylene propylene alcohol into a mixing tank at normal temperature and normal pressure, and fully stirring and mixing for 10 minutes; then 0.5kg of dicyclopentadienyl iron, 1kg of amyl nitrate and 0.5kgT122 g of high-base-number sulfurized calcium alkyl are added, and the mixture is fully stirred and mixed for 10 minutes; standing for 30 minutes, and finally pumping into a finished oil tank through a filter pump.
Example 2
The preparation method of the biomass power fuel designed by the preferred embodiment of the invention comprises the following steps:
adding 50kg of fatty acid methyl ester, 40kg of liquid wax and 15kg of ethylene propylene alcohol into a mixing tank at normal temperature and normal pressure, and fully stirring and mixing for 10 minutes; then adding 1kg of dicyclopentadienyl iron, 2kg of amyl nitrate and 1kgT122 high-base-number sulfurized calcium alkyl phenate, and fully stirring and mixing for 10 minutes; standing for 30 minutes, and finally pumping into a finished oil tank through a filter pump.
Example 3
The preparation method of the biomass power fuel designed by the preferred embodiment of the invention comprises the following steps:
adding 400kg of fatty acid methyl ester, 450kg of liquid wax and 100kg of ethylene propylene alcohol into a mixing tank at normal temperature and normal pressure, and fully stirring and mixing for 10 minutes; then adding 10kg of dicyclopentadienyl iron, 30kg of amyl nitrate and 5kgT122 high-base-number sulfurized calcium alkyl phenate, and fully stirring and mixing for 10 minutes; standing for 30 minutes, and finally pumping into a finished oil tank through a filter pump.
Example 4
The preparation method of the biomass power fuel designed by the preferred embodiment of the invention comprises the following steps:
adding 500kg of fatty acid methyl ester, 350kg of liquid wax and 130kg of ethylene propylene alcohol into a mixing tank at normal temperature and normal pressure, and fully stirring and mixing for 10 minutes; then 5kg of dicyclopentadienyl iron, 10kg of amyl nitrate and 5kgT122 high-base-number sulfurized calcium alkyl phenolate are added, and fully stirred and mixed for 10 minutes; standing for 30 minutes, and finally pumping into a finished oil tank through a filter pump.
The above description is only a preferred embodiment of the present invention, and is not intended to limit the present invention in any way, and any indirect modifications, equivalent changes and modifications made to the above embodiment according to the technical spirit of the present invention by those skilled in the art are within the technical scope of the present invention.

Claims (10)

1. The biomass power fuel is characterized by comprising the following components in percentage by mass:
40-50 parts of fatty acid methyl ester;
35-45 parts of liquid wax;
10-15 parts of ethyl propanol;
and 2-5 parts of an auxiliary agent.
2. The biomass power fuel according to claim 1, wherein the mass ratio of each component is as follows:
50 parts of fatty acid methyl ester;
35 parts of liquid wax;
13 parts of ethyl propanol;
and 2 parts of an auxiliary agent.
3. The biomass power fuel according to claim 1 or 2, wherein the auxiliary agent comprises: combustion improver, cetane improver and anti-sulfidation corrosion agent.
4. The biomass power fuel according to claim 3, wherein the mass ratio of each component of the auxiliary agent is as follows:
1-2 parts of a combustion improver;
2-6 parts of a cetane number improver;
and 1-2 parts of anti-sulfuration corrosion agent.
5. The biomass power fuel according to claim 3, wherein the mass ratio of each component of the auxiliary agent is as follows:
1 part of combustion improver;
2 parts of cetane number improver;
and 1 part of anti-sulfuration corrosion agent.
6. The biomass power fuel of claim 3, wherein the combustion improver comprises iron dicyclopentadienyl.
7. The biomass power fuel of claim 3, wherein the cetane improver comprises amyl nitrate.
8. The biomass power fuel of claim 3, wherein the anti-sulfidation corrosion agent comprises a T122 overbased calcium sulfurized alkylphenol.
9. The preparation method of the biomass power fuel is characterized by comprising the following steps:
1) adding fatty acid methyl ester, liquid wax and ethyl propanol into a mixing tank in proportion, and fully stirring and mixing;
2) then adding the auxiliary agent, and fully stirring and mixing;
3) and finally standing for a moment to prepare the fuel.
10. The method of claim 9, wherein all steps are performed at ambient temperature and pressure.
CN202210309803.XA 2022-03-28 2022-03-28 Biomass power fuel and preparation method thereof Pending CN114574254A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN202210309803.XA CN114574254A (en) 2022-03-28 2022-03-28 Biomass power fuel and preparation method thereof

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Application Number Priority Date Filing Date Title
CN202210309803.XA CN114574254A (en) 2022-03-28 2022-03-28 Biomass power fuel and preparation method thereof

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Publication Number Publication Date
CN114574254A true CN114574254A (en) 2022-06-03

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Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101314720A (en) * 2008-07-17 2008-12-03 天津中荣源能源发展有限公司 Multicomponent combined biological diesel oil and preparation thereof
CN104449903A (en) * 2014-11-13 2015-03-25 山东华亚环保科技有限公司 Compound additive for biodiesel and preparation method thereof
CN104745242A (en) * 2015-03-13 2015-07-01 张东宁 Alcohol-hydrocarbon composite liquid fuel
CN106893613A (en) * 2015-12-17 2017-06-27 株洲中醇化新能源科技有限公司 A kind of combined diesel oil
CN109576018A (en) * 2018-12-20 2019-04-05 谢家传 A kind of B20 biology blending fuel and preparation method thereof
CN113621414A (en) * 2021-08-12 2021-11-09 安徽醇生新能源科技有限公司 Environment-friendly energy-saving diesel alcohol-based biofuel additive

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101314720A (en) * 2008-07-17 2008-12-03 天津中荣源能源发展有限公司 Multicomponent combined biological diesel oil and preparation thereof
CN104449903A (en) * 2014-11-13 2015-03-25 山东华亚环保科技有限公司 Compound additive for biodiesel and preparation method thereof
CN104745242A (en) * 2015-03-13 2015-07-01 张东宁 Alcohol-hydrocarbon composite liquid fuel
CN106893613A (en) * 2015-12-17 2017-06-27 株洲中醇化新能源科技有限公司 A kind of combined diesel oil
CN109576018A (en) * 2018-12-20 2019-04-05 谢家传 A kind of B20 biology blending fuel and preparation method thereof
CN113621414A (en) * 2021-08-12 2021-11-09 安徽醇生新能源科技有限公司 Environment-friendly energy-saving diesel alcohol-based biofuel additive

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