CN114573753A - High molecular resin adhesive for profile control and water plugging of oil well and water well - Google Patents
High molecular resin adhesive for profile control and water plugging of oil well and water well Download PDFInfo
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Abstract
本发明公开了一种油、水井调剖堵水用高分子树脂胶,涉及油气开采技术领域,该油、水井调剖堵水用高分子树脂胶由以下成分组成:高分子树脂3‑4%、水溶性单体3‑4%、交联剂0.05‑0.1%、引发剂0.005‑0.01%、除氧剂0.1‑0.2%,抗酸稳定剂0.1‑0.2%,余量为水;本发明通过高分子树脂与水溶性树脂由引发剂引发成树脂自由基,自由基与单体起连锁反应聚合,交联为大分子网络结构,形成整体强度较高的树脂胶,油水井调剖堵水用高分子树脂胶能对油水井裂缝、溶洞型水淹、水窜进行有效封堵,可以实现油藏深部调剖,封堵效果理想,利于实际使用。
The invention discloses a polymer resin glue for profile control and water plugging of oil and water wells, and relates to the technical field of oil and gas exploitation. The polymer resin glue for profile control and water plugging of oil and water wells is composed of the following components: 3-4% of polymer resin , 3-4% of water-soluble monomer, 0.05-0.1% of crosslinking agent, 0.005-0.01% of initiator, 0.1-0.2% of oxygen scavenger, 0.1-0.2% of antacid stabilizer, and the balance is water; Polymer resin and water-soluble resin are initiated by initiator to form resin free radicals, free radicals and monomers undergo chain reaction polymerization, cross-linking into macromolecular network structure, forming resin glue with high overall strength, used for profile control and water plugging of oil and water wells Polymer resin glue can effectively seal oil-water well fractures, water flooding in karst caves, and water channeling, and can realize profile control in deep reservoirs.
Description
技术领域technical field
本发明涉及油气开采技术领域,具体为一种油、水井调剖堵水用高分子树脂胶。The invention relates to the technical field of oil and gas exploitation, in particular to a polymer resin glue for profile control and water shutoff of oil and water wells.
背景技术Background technique
当前,我国陆地石油基本都是采用注水开发的方式。在油井开采之下,出水现象越发普遍,加上注水开发力度不断提升,含水量也随之提高。根据以往调查结果可知,我国当前油田中的含水量已达到80%,尤其是东部地区,含水率已经达到90%。在此背景下,石油中含水比例不断增加,导致开采能耗提高、产率降低,堵水工作显得更加重要。At present, my country's onshore oil is basically developed by water injection. Under the development of oil wells, the phenomenon of water production is becoming more and more common. With the continuous improvement of water injection development, the water content also increases. According to the previous survey results, the water content of the current oil fields in my country has reached 80%, especially in the eastern region, the water content has reached 90%. Under this background, the proportion of water in oil is increasing, which leads to higher energy consumption and lower production rate. Water plugging becomes more important.
随着油田开发逐渐进入中后期,由于水层窜槽、底水锥进或注入水、边水突进,使一些油井过早见水或水淹;油井出水导致注入剖面均匀性受到影响,一些区块注入水顺着高渗透层快速突破,导致大量油井出水,极大的影响了原油产率,油田出水问题越发普遍,急需采用堵水剂进行控制和解决。As oilfield development gradually enters the middle and late stages, due to channeling of water layers, bottom water coning or injection water, and edge water inrush, some oil wells have premature water breakthrough or water flooding; The block injection water quickly breaks through the high-permeability layer, resulting in a large number of oil wells producing water, which greatly affects the crude oil production rate.
目前主要使用的堵水剂是以水基类水解聚丙烯酰胺为主的堵水剂,这种化学调剖剂在调配形成堵水材料的过程中所应用到的材料成本低,且效用高,现场使用过程简便,对现场的操作要求亦不高,但此类堵剂在高温下易发生降解,长期稳定性差,且通过多孔介质封堵实验表明,水基类水解聚丙烯酰胺类凝胶在多孔介质的动态运移剪切过程中是不易形成胶体;在高矿化度盐水中,对水的稠化性不足等。The water-blocking agent mainly used at present is water-based hydrolyzed polyacrylamide-based water-blocking agent. This chemical profile control agent has low material cost and high utility in the process of preparing the water-blocking material. The on-site use process is simple, and the requirements for on-site operations are not high, but such plugging agents are prone to degradation at high temperatures and have poor long-term stability. In the dynamic migration and shearing process of porous media, it is not easy to form colloids; in high salinity brine, the thickening of water is insufficient.
因此提出一种油、水井调剖堵水用高分子树脂胶以解决上述问题。Therefore, a polymer resin glue for profile control and water plugging of oil and water wells is proposed to solve the above problems.
发明内容SUMMARY OF THE INVENTION
本发明的目的在于提供一种油、水井调剖堵水用高分子树脂胶,以解决上述背景技术中提出问题。The purpose of the present invention is to provide a polymer resin glue for profile control and water plugging of oil and water wells, so as to solve the problems raised in the above-mentioned background technology.
为实现上述目的,本发明提供如下技术方案:To achieve the above object, the present invention provides the following technical solutions:
一种油、水井调剖堵水用高分子树脂胶,该油水井调剖堵水用高分子树脂胶由以下成分组成:高分子树脂3-4%、水溶性单体3-4%、交联剂0.05-0.1%、引发剂0.005-0.01%、除氧剂0.1-0.2%,抗酸稳定剂0.1-0.2%,余量为水。A polymer resin glue for profile control and water plugging of oil and water wells. The joint agent is 0.05-0.1%, the initiator is 0.005-0.01%, the oxygen scavenger is 0.1-0.2%, the antacid stabilizer is 0.1-0.2%, and the balance is water.
更进一步的,所述高分子树脂为羧甲基淀粉。Further, the polymer resin is carboxymethyl starch.
更进一步的,所述水溶性单体为2-丙烯酰胺-2-甲基丙磺酸。Further, the water-soluble monomer is 2-acrylamide-2-methylpropanesulfonic acid.
更进一步的,所述交联剂为N-甲基甲酰胺。Further, the crosslinking agent is N-methylformamide.
更进一步的,所述引发剂为过氧焦磷酸钾。Further, the initiator is potassium peroxypyrophosphate.
更进一步的,所述除氧剂为亚硫酸氢钠。Further, the oxygen scavenger is sodium bisulfite.
更进一步的,所述抗酸稳定剂为硬葡聚糖。Further, the antacid stabilizer is scleroglucan.
一种油、水井调剖堵水用高分子树脂胶的制备工艺,制备工艺步骤如下:A preparation process of a polymer resin glue for profile control and water plugging of oil and water wells, the preparation process steps are as follows:
步骤1,将烧杯放置数显机械搅拌器搅拌杆下方平台,在烧杯加入水,调节搅拌杆高度至其完全没过水面,打开调节转速旋钮,调节转速至700-800rpm;
步骤2,在步骤1基础上加入抗酸稳定剂,持续剪切28-32min,直至硬葡聚糖溶解;
步骤3,在步骤2基础上将高分子树脂缓慢引流加入正在剪切的水面,降低搅拌器转速至300-400rpm,得到均质溶液,高分子树脂全部溶解入水后继续搅拌25-30min;
步骤4,在步骤3基础上将水溶性单体加入,剪切5-10min至其均匀溶解;
步骤5,在步骤4基础上依次加入交联剂、除氧剂和引发剂,搅拌剪切5-10min,至此,高分子树脂胶溶液制作完毕;
步骤6,在步骤5基础上将制作完成的高分子树脂胶溶液倒入耐高温密封试管内,随后对试管封口,放入120℃恒温老化箱中静置约2-4h,静置后通过定量结构进行灌装处理,灌装后得到油水井调剖堵水用高分子树脂胶。
一种油、水井调剖堵水用高分子树脂胶的装置,装置为步骤5中的定量结构,包括第一支撑架,所述第一支撑架之间通过固定连接的轴承转动连接有传送带,所述第一支撑架的后侧壁固定安装有第一驱动电机,所述第一驱动电机与传送带的转轴一端固定连接;A device for high-molecular resin glue for profile control and water blocking of oil and water wells, the device is the quantitative structure in
所述第一支撑架的顶部用于油桶导向的扶正结构,所述扶正结构包括插销、定位孔、滑动横板、拉簧、凸形块、直限位板、斜导向板和滑动孔,所述凸形块的顶部固定连接有拉簧,所述拉簧的顶部固定连接有插销,所述凸形块开设有滑动孔,所述滑动孔内贴合滑动连接有滑动横板,所述滑动横板均匀开设有定位孔,所述拉簧的恢复力带动插销的底部插在定位孔内,所述滑动横板的里端固定连接有直限位板,所述直限位板的右端固定连接有斜导向板;The top of the first support frame is used for a centralizing structure for guiding the oil drum, and the centralizing structure includes a latch, a positioning hole, a sliding transverse plate, a tension spring, a convex block, a straight limit plate, an inclined guide plate and a sliding hole, The top of the convex block is fixedly connected with a tension spring, the top of the tension spring is fixedly connected with a latch, the convex block is provided with a sliding hole, and a sliding horizontal plate is fitted and slidably connected in the sliding hole. The sliding horizontal plate is evenly provided with positioning holes, the bottom of the latch is driven by the restoring force of the tension spring to be inserted into the positioning holes, the inner end of the sliding horizontal plate is fixedly connected with a straight limit plate, and the right end of the straight limit plate is Fixed connection with inclined guide plate;
所述第一支撑架在扶正结构的左端设有第二支撑架,所述第二支撑架的顶部固定连接有料筒,所述料筒的顶部连接有定量下料结构,所述定量下料结构包括第三支撑架、气管、气缸、外罩、n形板、挡板、下料孔、Z形架、旋转电磁铁、盖板和转动轴,所述第三支撑架的顶部固定连接有气缸,所述气缸的底部固定连接有n形板,所述n形板的底部固定连接有Z形架,所述Z形架的底部固定连接有挡板,且挡板的外壁与料筒的内部贴合滑动连接,所述挡板的一端开设有用于下料的下料孔,所述Z形架的顶部固定连接有外罩和旋转电磁铁,所述外罩设置在旋转电磁铁外侧,所述旋转电磁铁的输出端固定连接有转动轴,所述转动轴的底部固定连接有盖板,且盖板的底板与挡板的顶部贴合滑动连接,所述盖板的顶部直孔处固定连接有用于平衡挡板下方压力的气管;The first support frame is provided with a second support frame at the left end of the centralizing structure, the top of the second support frame is fixedly connected with a material barrel, and the top of the material barrel is connected with a quantitative blanking structure. It includes a third support frame, a gas pipe, a cylinder, an outer cover, an n-shaped plate, a baffle plate, a blanking hole, a Z-shaped frame, a rotating electromagnet, a cover plate and a rotating shaft, and a cylinder is fixedly connected to the top of the third support frame. The bottom of the cylinder is fixedly connected with an n-shaped plate, the bottom of the n-shaped plate is fixedly connected with a Z-shaped frame, the bottom of the Z-shaped frame is fixedly connected with a baffle, and the outer wall of the baffle is attached to the interior of the barrel. A blanking hole for blanking is opened at one end of the baffle, a cover and a rotating electromagnet are fixedly connected to the top of the Z-shaped frame, the cover is arranged outside the rotating electromagnet, and the rotating electromagnetic The output end of the iron is fixedly connected with a rotating shaft, the bottom of the rotating shaft is fixedly connected with a cover plate, and the bottom plate of the cover plate is connected with the top of the baffle plate in a fit and sliding connection, and a straight hole on the top of the cover plate is fixedly connected with a Air pipe to balance the pressure below the baffle;
所述料筒的底部固定连接有下料管,所述下料管固定安装有控制阀;A feeding tube is fixedly connected to the bottom of the barrel, and a control valve is fixedly installed on the feeding tube;
所述第一支撑架在下料管的下方处设有用于油桶限位的定位结构,所述定位结构包括第一C形板、第二C形板、滑动槽、螺纹杆、转动杆、螺纹槽、U形板、连接直块、第二驱动电机、第三驱动电机和滑动板,所述第三驱动电机的输出端固定连接有螺纹杆,所述螺纹杆螺纹连接有连接直块,所述连接直块的顶部固定连接有U形板,所述U形板的一端固定连接有第二驱动电机,所述第二驱动电机的输出端固定连接有转动杆,所述转动杆对称开设有螺纹槽,所述转动杆通过螺纹槽螺纹连接有滑动板,所述滑动板的侧壁分别固定连接有第二C形板和第一C形板,所述第一支撑架的侧壁开设有与第二C形板和第一C形板配合使用的滑动槽。The first support frame is provided with a positioning structure for limiting the position of the oil drum at the lower part of the feeding pipe, and the positioning structure includes a first C-shaped plate, a second C-shaped plate, a sliding groove, a threaded rod, a rotating rod, a thread The groove, the U-shaped plate, the connecting straight block, the second driving motor, the third driving motor and the sliding plate, the output end of the third driving motor is fixedly connected with a threaded rod, and the threaded rod is threadedly connected with the connecting straight block, so The top of the connecting straight block is fixedly connected with a U-shaped plate, one end of the U-shaped plate is fixedly connected with a second drive motor, the output end of the second drive motor is fixedly connected with a rotating rod, and the rotating rod is symmetrically opened with A threaded groove, through which the rotating rod is threadedly connected with a sliding plate, the side walls of the sliding plate are respectively fixedly connected with a second C-shaped plate and a first C-shaped plate, and the side walls of the first support frame are provided with Sliding slot for use with the second C-shaped plate and the first C-shaped plate.
更进一步的,所述凸形块固定安装在第一支撑架的顶部,且凸形块设置在第二支撑架的右端。Further, the convex block is fixedly installed on the top of the first support frame, and the convex block is arranged on the right end of the second support frame.
更进一步的,上料时所述旋转电磁铁带动转动轴转动,转动轴带动盖板转动至下料孔外侧,上料结束后旋转电磁铁进行复位,旋转电磁铁带动盖板转动下料孔的正上方将下料孔堵住。Furthermore, when feeding, the rotating electromagnet drives the rotating shaft to rotate, and the rotating shaft drives the cover plate to rotate to the outside of the feeding hole. Block the feeding hole just above.
更进一步的,所述第三支撑架固定安装在料筒的顶部。Further, the third support frame is fixedly installed on the top of the barrel.
更进一步的,下料时所述气管将空气导向至挡板内,保证了挡板下方的物料排出。Furthermore, the air pipe guides the air into the baffle when the material is unloaded, so as to ensure the discharge of the material under the baffle.
更进一步的,所述第三驱动电机固定安装在第一支撑架的侧壁,所述第一支撑架的侧壁通过固定连接的轴承与螺纹杆转动连接。Further, the third drive motor is fixedly mounted on the side wall of the first support frame, and the side wall of the first support frame is rotatably connected to the threaded rod through a fixedly connected bearing.
更进一步的,所述U形板的直立部位通过固定连接的轴承转动连接有转动杆。Furthermore, the upright part of the U-shaped plate is rotatably connected with a rotating rod through a fixedly connected bearing.
更进一步的,所述第二C形板和第一C形板设置在下料管的两端。Further, the second C-shaped plate and the first C-shaped plate are arranged at both ends of the feeding pipe.
本发明的有益效果是:The beneficial effects of the present invention are:
本发明通过根据定量灌装的油桶尺寸选择扶正结构的定位孔,向上拉动插销,滑动滑动横板,滑动横板带动选择的定位孔移动至插销下方处,松开插销后拉簧的恢复力带动插销插在定位孔内,使得直限位板之间适合定量灌装的油桶,斜导向板方便将定量灌装的油桶引到至直限位板内,再通过直限位板移动至下料管下方;The invention selects the positioning hole of the centralizing structure according to the size of the oil drum to be filled quantitatively, pulls the latch upward, slides the horizontal plate, and the sliding horizontal plate drives the selected positioning hole to move to the lower part of the latch, and the restoring force of the tension spring after releasing the latch Drive the pin to be inserted into the positioning hole, so that the straight limit plates are suitable for quantitatively filled oil drums, and the inclined guide plate is convenient to guide the quantitatively filled oil drums to the straight limit plate, and then move through the straight limit plate. to the bottom of the feeding pipe;
本发明定位结构的第二驱动电机带动转动杆转动,转动杆通过螺纹槽驱动滑动板移动,滑动板带动第一C形板和第二C形板移动,使得第一C形板和第二C形板之间适合不同定量灌装的油桶尺寸,灌装前,第三驱动电机带动螺纹杆转动,螺纹杆驱动连接直块向后移动,连接直块带动U形板向后移动,U形板带动第二C形板和第一C形板向后移动,第二C形板和第一C形板移动至最后端,油桶通过第二C形板移动至第一C形板的右端,第一C形板将油桶限位住然后进行灌装,灌装后,第三驱动电机带动螺纹杆转动,螺纹杆驱动连接直块向前移动,连接直块带动U形板向前移动,U形板带动第二C形板和第一C形板向前移动,第二C形板和第一C形板移动至最前端,第二C形板将第二C形板右侧的油桶堵住,第一C形板右端的油桶从第一C形板排出,方便将油桶按顺序限位在下料管整下方;The second drive motor of the positioning structure of the present invention drives the rotating rod to rotate, the rotating rod drives the sliding plate to move through the threaded groove, and the sliding plate drives the first C-shaped plate and the second C-shaped plate to move, so that the first C-shaped plate and the second C-shaped plate move. The size of the oil barrels suitable for different quantitative filling is between the shaped plates. Before filling, the third drive motor drives the threaded rod to rotate, the threaded rod drives the connecting straight block to move backwards, and the connecting straight block drives the U-shaped plate to move backwards. The plate drives the second C-shaped plate and the first C-shaped plate to move backward, the second C-shaped plate and the first C-shaped plate move to the rearmost end, and the oil barrel moves to the right end of the first C-shaped plate through the second C-shaped plate , The first C-shaped plate stops the oil drum and then fills it. After filling, the third drive motor drives the threaded rod to rotate, the threaded rod drives the connecting straight block to move forward, and the connecting straight block drives the U-shaped plate to move forward. , the U-shaped plate drives the second C-shaped plate and the first C-shaped plate to move forward, the second C-shaped plate and the first C-shaped plate move to the front end, and the second C-shaped plate moves the right side of the second C-shaped plate. The oil drum is blocked, and the oil drum at the right end of the first C-shaped plate is discharged from the first C-shaped plate, which is convenient to limit the oil drum to the bottom of the feeding pipe in sequence;
本发明根据定量下料的定量启动定量下料结构的气缸,气缸通过n形板和Z形架带动挡板移动,挡板下方存放量符合定量要求时停止气缸,上料时旋转电磁铁带动转动轴转动,转动轴带动盖板转动至下料孔外侧,上料结束后旋转电磁铁进行复位,旋转电磁铁带动盖板转动下料孔的正上方将下料孔堵住,然后将挡板下方存放量通过下料管进行定量下料,使得装置方便进行定量下料;The invention starts the cylinder of the quantitative blanking structure according to the quantitative blanking. The cylinder drives the baffle to move through the n-shaped plate and the Z-shaped frame. When the storage volume under the baffle meets the quantitative requirements, the cylinder is stopped, and the rotating electromagnet drives the rotation during feeding. The shaft rotates, and the rotating shaft drives the cover plate to rotate to the outside of the blanking hole. After the feeding is completed, the rotating electromagnet resets. The rotating electromagnet drives the cover plate to rotate just above the blanking hole to block the blanking hole. The storage capacity is quantitatively fed through the feeding tube, which makes the device convenient for quantitative feeding;
本发明通过高分子树脂与水溶性树脂由引发剂引发成树脂自由基,自由基与单体起连锁反应聚合,交联为大分子网络结构,形成整体强度较高的树脂胶,油水井调剖堵水用高分子树脂胶能对油水井裂缝、溶洞型水淹、水窜进行有效封堵,可以实现油藏深部调剖,封堵效果理想,利于实际使用;油水井调剖堵水用高分子树脂胶耐温、抗盐,成胶前粘度低具有很好的注入性能,施工不需要动管柱,堵剂优先进入水窜高导流通道,选择性封堵,成胶后调整储层油水通道压差,增大绕流面积,达到控水增油的目的,纯粘流体均匀波及优势通道实现有效堵水。In the invention, the polymer resin and the water-soluble resin are initiated by the initiator to form resin free radicals, and the free radicals and the monomers undergo chain reaction polymerization, cross-linking into a macromolecular network structure, forming a resin glue with high overall strength, and profile control of oil and water wells. The polymer resin glue for water plugging can effectively plug the oil-water well cracks, karst cave-type flooding, and water channeling, and can realize the profile control in the deep reservoir. The sealing effect is ideal, which is beneficial to practical use; Molecular resin glue is temperature-resistant and salt-resistant. It has low viscosity before gel formation and has good injection performance. It does not require moving pipe strings during construction. The pressure difference of the oil-water channel increases the flow area to achieve the purpose of controlling water and increasing oil, and the pure viscous fluid spreads evenly to the dominant channel to achieve effective water blocking.
附图说明Description of drawings
为了更清楚地说明本发明实施例的技术方案,下面将对实施例描述所需要使用的附图作简单地介绍,显而易见地,下面描述中的附图仅仅是本发明的一些实施例,对于本领域普通技术人员来讲,在不付出创造性劳动的前提下,还可以根据这些附图获得其他的附图。In order to illustrate the technical solutions of the embodiments of the present invention more clearly, the following briefly introduces the accompanying drawings used in the description of the embodiments. Obviously, the drawings in the following description are only some embodiments of the present invention. For those of ordinary skill in the art, other drawings can also be obtained from these drawings without any creative effort.
图1为本发明的制备工艺流程图;Fig. 1 is the preparation process flow chart of the present invention;
图2为本发明的不同渗透率填砂管中注入速度与注入压力的关系图;Fig. 2 is the relation diagram of injection speed and injection pressure in the sand filling pipe of different permeability of the present invention;
图3为本发明的Sydansk瓶视法快速优选图;Fig. 3 is the quick optimization diagram of the Sydansk bottle view method of the present invention;
图4为本发明的30m长填砂管注入10m堵剂成胶后的水驱曲线图;Fig. 4 is the water flooding curve diagram of the 30m long sand filling pipe of the present invention after 10m plugging agent is injected into gel;
图5为本发明的树脂胶封堵率图;Fig. 5 is the resin glue blocking rate diagram of the present invention;
图6为本发明的封堵率与注入量的关系曲线图;6 is a graph showing the relationship between the plugging rate and the injection amount of the present invention;
图7为本发明的新疆油田H2410井注水井来水水窜封窜堵水采曲线;Fig. 7 is the water recovery curve of water channeling, channeling, channeling and plugging of the water injection well of the H2410 well in Xinjiang Oilfield of the present invention;
图8为本发明的冀东油田注水井G26-24井堵压力曲线图;Fig. 8 is the plugging pressure curve diagram of the water injection well G26-24 of Jidong Oilfield of the present invention;
图9为本发明的高分子树脂胶扫描电镜呈像;9 is a scanning electron microscope image of the polymer resin glue of the present invention;
图10为本发明具体案例中不同运移位置的阻力系数;Fig. 10 is the drag coefficient of different transport positions in the specific case of the present invention;
图11为本发明的冀东油田注水井G26-24吸水剖面图;Fig. 11 is the water absorption profile of Jidong Oilfield water injection well G26-24 of the present invention;
图12为本发明的冀东油田注水井G26-24井生产数据图;Fig. 12 is the production data diagram of the water injection well G26-24 of Jidong Oilfield of the present invention;
图13为本发明的结构示意图;Figure 13 is a schematic structural diagram of the present invention;
图14为本发明的结构后视图;Figure 14 is a rear view of the structure of the present invention;
图15为本发明的结构俯视图;Figure 15 is a top view of the structure of the present invention;
图16为本发明的结构剖视图;Figure 16 is a structural cross-sectional view of the present invention;
图17为本发明的结构剖视仰视图;Figure 17 is a bottom view of the structure of the present invention;
图18为本发明的结构右视剖视图;Figure 18 is a right side sectional view of the structure of the present invention;
图19为本发明的扶正结构示意图;Figure 19 is a schematic diagram of the righting structure of the present invention;
图20为本发明的图17的A处结构放大示意图;FIG. 20 is an enlarged schematic view of the structure at A of FIG. 17 of the present invention;
图21为本发明的图18的B处结构放大示意图;21 is an enlarged schematic view of the structure at B of FIG. 18 of the present invention;
图22为本发明的转动杆及其连接结构示意图;Figure 22 is a schematic diagram of the rotating rod and its connection structure of the present invention;
附图中,各标号所代表的部件列表如下:In the accompanying drawings, the list of components represented by each number is as follows:
1.第一支撑架 2.第一驱动电机 3.传送带 4.扶正结构 401.插销 402.定位孔403.滑动横板 404.拉簧 405.凸形块 406.直限位板 407.斜导向板 408.滑动孔 5.第二支撑架 6.定位结构 601.第一C形板 602.第二C形板 603.滑动槽 604.螺纹杆 605.转动杆 606.螺纹槽 607.U形板 608.连接直块 609.第二驱动电机 610.第三驱动电机 611.滑动板 7.控制阀 8.下料管 9.料筒 10.定量下料结构 1001.第三支撑架 1002.气管 1003.气缸 1004.外罩 1005.n形板 1006.挡板 1007.下料孔 1008.Z形架 1009.旋转电磁铁1010.盖板 1011.转动轴。1. The
具体实施方式Detailed ways
下面将结合本发明实施例中的附图,对本发明实施例中的技术方案进行清楚、完整地描述,显然,所描述的实施例仅仅是本发明一部分实施例,而不是全部的实施例。基于本发明中的实施例,本领域普通技术人员在没有作出创造性劳动前提下所获得的所有其它实施例,都属于本发明保护的范围。The technical solutions in the embodiments of the present invention will be clearly and completely described below with reference to the accompanying drawings in the embodiments of the present invention. Obviously, the described embodiments are only a part of the embodiments of the present invention, but not all of the embodiments. Based on the embodiments of the present invention, all other embodiments obtained by those of ordinary skill in the art without creative efforts shall fall within the protection scope of the present invention.
下面结合实施例对本发明作进一步的描述。The present invention will be further described below in conjunction with the examples.
实施例1Example 1
如图1-8所示,As shown in Figure 1-8,
一种油、水井调剖堵水用高分子树脂胶,该油水井调剖堵水用高分子树脂胶由以下成分组成:高分子树脂3%、水溶性单体4%、交联剂0.1%、引发剂0.01%、除氧剂0.2%,抗酸稳定剂0.1%,余量为水。A polymer resin glue for profile control and water plugging of oil and water wells. The polymer resin glue for profile control and water plugging of oil and water wells is composed of the following components: 3% of polymer resin, 4% of water-soluble monomer, and 0.1% of cross-linking agent , initiator 0.01%, oxygen scavenger 0.2%, antacid stabilizer 0.1%, and the balance is water.
所述高分子树脂为羧甲基淀粉。The polymer resin is carboxymethyl starch.
所述水溶性单体为2-丙烯酰胺-2-甲基丙磺酸。The water-soluble monomer is 2-acrylamide-2-methylpropanesulfonic acid.
所述交联剂为N-甲基甲酰胺。The crosslinking agent is N-methylformamide.
所述引发剂为过氧焦磷酸钾。The initiator is potassium peroxypyrophosphate.
所述除氧剂为亚硫酸氢钠。The oxygen scavenger is sodium bisulfite.
所述抗酸稳定剂为硬葡聚糖。The antacid stabilizer is scleroglucan.
一种油、水井调剖堵水用高分子树脂胶的制备工艺,制备工艺步骤如下:A preparation process of a polymer resin glue for profile control and water plugging of oil and water wells, the preparation process steps are as follows:
步骤1,将烧杯放置数显机械搅拌器搅拌杆下方平台,在烧杯加入水,再调节搅拌杆高度至其完全没过水面,打开调节转速旋钮,调节转速至700rpm;
步骤2,在步骤1基础上加入抗酸稳定剂,持续剪切32min,直至硬葡聚糖溶解;
步骤3,在步骤2基础上将高分子树脂缓慢引流加入正在剪切的水面,降低搅拌器转速至400rpm,得到均质溶液,高分子树脂全部溶解入水后继续搅拌25min;
步骤4,在步骤3基础上将水溶性单体加入,剪切10min至其均匀溶解;
步骤5,在步骤4基础上依次加入交联剂、除氧剂和引发剂,搅拌剪切10min,至此,高分子树脂胶溶液制作完毕;
步骤6,在步骤5基础上将制作完成的高分子树脂胶溶液倒入耐高温密封试管内,随后对试管封口,放入120℃恒温老化箱中静置约4h,静置后通过定量结构进行灌装处理,灌装后得到油水井调剖堵水用高分子树脂胶。
实施例2Example 2
实施例2是对实施例1的进一步改进。
如图1-8所示的,As shown in Figure 1-8,
一种油、水井调剖堵水用高分子树脂胶,该油水井调剖堵水用高分子树脂胶由以下成分组成:高分子树脂4%、水溶性单体3%、交联剂0.2%、引发剂0.05%、除氧剂0.2%,抗酸稳定剂0.2%,余量为水。A polymer resin glue for profile control and water plugging of oil and water wells. The polymer resin glue for profile control and water plugging of oil and water wells is composed of the following components: 4% of polymer resin, 3% of water-soluble monomer, and 0.2% of cross-linking agent , initiator 0.05%, oxygen scavenger 0.2%, antacid stabilizer 0.2%, and the balance is water.
所述高分子树脂为羧甲基淀粉。The polymer resin is carboxymethyl starch.
所述水溶性单体为2-丙烯酰胺-2-甲基丙磺酸。The water-soluble monomer is 2-acrylamide-2-methylpropanesulfonic acid.
所述交联剂为N-甲基甲酰胺。The crosslinking agent is N-methylformamide.
所述引发剂为过氧焦磷酸钾。The initiator is potassium peroxypyrophosphate.
所述除氧剂为亚硫酸氢钠。The oxygen scavenger is sodium bisulfite.
所述抗酸稳定剂为硬葡聚糖。The antacid stabilizer is scleroglucan.
一种油、水井调剖堵水用高分子树脂胶的制备工艺,制备工艺步骤如下:A preparation process of a polymer resin glue for profile control and water plugging of oil and water wells, the preparation process steps are as follows:
步骤1,将烧杯放置数显机械搅拌器搅拌杆下方平台,在烧杯加入水,再调节搅拌杆高度至其完全没过水面,打开调节转速旋钮,调节转速至800rpm;
步骤2,在步骤1基础上加入抗酸稳定剂,持续剪切28min,直至硬葡聚糖溶解;
步骤3,在步骤2基础上将高分子树脂缓慢引流加入正在剪切的水面,降低搅拌器转速至300rpm,得到均质溶液,高分子树脂全部溶解入水后继续搅拌30min;
步骤4,在步骤3基础上将水溶性单体加入,剪切5min至其均匀溶解;
步骤5,在步骤4基础上依次加入交联剂、除氧剂和引发剂,搅拌剪切5min,至此,高分子树脂胶溶液制作完毕;
步骤6,在步骤5基础上将制作完成的高分子树脂胶溶液倒入耐高温密封试管内,随后对试管封口,放入120℃恒温老化箱中静置约5h,静置后通过定量结构进行灌装处理,灌装后得到油水井调剖堵水用高分子树脂胶。
对实施例1和实施例2进行检测,检测标准为Q/SH1020 1493-2014/强冻胶
本发明通过高分子树脂与水溶性树脂由引发剂引发成树脂自由基,自由基与单体起连锁反应聚合,交联为大分子网络结构,形成整体强度较高的树脂胶,油水井调剖堵水用高分子树脂胶能对油水井裂缝、溶洞型水淹、水窜进行有效封堵,可以实现油藏深部调剖,封堵效果理想,利于实际使用。In the invention, the polymer resin and the water-soluble resin are initiated by an initiator to form resin free radicals, and the free radicals and the monomers undergo chain reaction polymerization, cross-linking into a macromolecular network structure, forming a resin glue with high overall strength, and profile control of oil and water wells. The polymer resin glue for water plugging can effectively plug the oil-water well cracks, karst cave water flooding and water channeling, and can realize the profile control in the deep part of the reservoir.
具体案例Specific case
如图9所示,高分子树脂胶注入后,扫描电镜呈像高分子树脂胶整体段塞式封堵水流优势通道,高分子树脂胶耐温、抗盐,成胶前粘度低具有很好的注入性能,施工不需要动管柱,堵剂优先进入水窜高导流通道,选择性封堵,成胶后调整储层油水通道压差,增大绕流面积,达到控水增油的目的,纯粘流体均匀波及优势通道实现有效堵水。As shown in Figure 9, after the polymer resin glue is injected, the scanning electron microscope shows that the polymer resin glue is integrally slug-type to block the dominant water flow channel. Injection performance, the construction does not need to move the pipe string, the blocking agent preferentially enters the water channeling high diversion channel, selectively plugs, adjusts the pressure difference of the oil-water channel in the reservoir after gelation, increases the bypass area, and achieves the purpose of controlling water and increasing oil. , the pure viscous fluid spreads evenly to the dominant channel to achieve effective water plugging.
具体操作如下:The specific operations are as follows:
在30m长填砂管注入10m堵剂过程中,堵剂在多孔介质中以段塞的方式运移,运移过程中阻力系数缓慢降低,即堵剂的视粘度随剪切而下降,从入口运移到8.16m处时,阻力系数由50降到约40,对应视粘度降低了约20%,该堵剂有一定的抗剪切能力,详见图10。长填砂管封堵实验结果表明树脂胶封堵孔道后,高分子树脂胶同时具有良好的抗冲刷性,详情见表1。During the process of injecting 10m plugging agent into the 30m long sand-filling pipe, the plugging agent migrated in the porous medium in the form of slug, and the resistance coefficient decreased slowly during the migration process, that is, the apparent viscosity of the plugging agent decreased with shearing, and the When it moved to 8.16m, the resistance coefficient decreased from 50 to about 40, corresponding to a decrease of about 20% in apparent viscosity. The plugging agent has a certain shear resistance, see Figure 10 for details. The results of the long sand-filled pipe plugging experiment show that after the resin glue blocks the pores, the polymer resin glue has good erosion resistance at the same time. See Table 1 for details.
表1Table 1
冀东油田G26-24为高深北区高5断块一口水井,2017年8月17日测吸水剖面,资料显示28#层吸水24.82%、29#层吸水75.18%,为主吸水层,对应油井均高含水,经研究决定对该井实施调剖,要求控制28、29#主吸水层。2018年5月10日进行了调剖施工,该井地层温度130℃左右,选用的高分子树脂凝胶,累注430方,关井3天后,恢复注水。Jidong Oilfield G26-24 is a water well in
如图11和12所示,该井调剖后,主吸水层29#层吸水量由施工前的75.18%降为31.77%;28#层由施工前的24.82%降为0,完全不吸水。而且重新启动了27b#层,吸水量50.52%,30#层吸水量17.71%,有效地改善了吸水剖面,浅调施工非常成功。As shown in Figures 11 and 12, after the profile control of the well, the water absorption of the 29# layer of the main water absorption layer decreased from 75.18% before construction to 31.77%; the 28# layer decreased from 24.82% before construction to 0, and did not absorb water at all. Moreover, the 27b# layer was restarted, the water absorption was 50.52%, and the 30# layer was 17.71%, which effectively improved the water absorption profile, and the shallow adjustment was very successful.
实施例3Example 3
实施例3是对实施例1的进一步改进。Example 3 is a further improvement to Example 1.
如图13至22所示,一种油、水井调剖堵水用高分子树脂胶的装置,装置为步骤三中的定量结构,包括第一支撑架1,第一支撑架1之间通过固定连接的轴承转动连接有传送带3,第一支撑架1的后侧壁固定安装有第一驱动电机2,第一驱动电机2与传送带3的转轴一端固定连接;As shown in Figures 13 to 22, a device for oil and water well profile control and water plugging with polymer resin glue, the device is the quantitative structure in
第一支撑架1的顶部用于油桶导向的扶正结构4,扶正结构4包括插销401、定位孔402、滑动横板403、拉簧404、凸形块405、直限位板406、斜导向板407和滑动孔408,凸形块405的顶部固定连接有拉簧404,拉簧404的顶部固定连接有插销401,凸形块405开设有滑动孔408,滑动孔408内贴合滑动连接有滑动横板403,滑动横板403均匀开设有定位孔402,拉簧404的恢复力带动插销401的底部插在定位孔402内,滑动横板403的里端固定连接有直限位板406,直限位板406的右端固定连接有斜导向板407,凸形块405固定安装在第一支撑架1的顶部,且凸形块405设置在第二支撑架5的右端,通过根据定量灌装的油桶尺寸选择扶正结构4的定位孔402,向上拉动插销401,滑动滑动横板403,滑动横板403带动选择的定位孔402移动至插销401下方处,松开插销401后拉簧404的恢复力带动插销401插在定位孔402内,使得直限位板406之间适合定量灌装的油桶,斜导向板407方便将定量灌装的油桶引到至直限位板406内,再通过直限位板406移动至下料管8下方;The top of the
第一支撑架1在扶正结构4的左端设有第二支撑架5,第二支撑架5的顶部固定连接有料筒9,料筒9的顶部连接有定量下料结构10,定量下料结构10包括第三支撑架1001、气管1002、气缸1003、外罩1004、n形板1005、挡板1006、下料孔1007、Z形架1008、旋转电磁铁1009、盖板1010和转动轴1011,第三支撑架1001的顶部固定连接有气缸1003,气缸1003的底部固定连接有n形板1005,n形板1005的底部固定连接有Z形架1008,Z形架1008的底部固定连接有挡板1006,且挡板1006的外壁与料筒9的内部贴合滑动连接,挡板1006的一端开设有用于下料的下料孔1007,Z形架1008的顶部固定连接有外罩1004和旋转电磁铁1009,外罩1004设置在旋转电磁铁1009外侧,旋转电磁铁1009的输出端固定连接有转动轴1011,转动轴1011的底部固定连接有盖板1010,且盖板1010的底板与挡板1006的顶部贴合滑动连接,盖板1010的顶部直孔处固定连接有用于平衡挡板1006下方压力的气管1002,上料时旋转电磁铁1009带动转动轴1011转动,转动轴1011带动盖板1010转动至下料孔1007外侧,上料结束后旋转电磁铁1009进行复位,旋转电磁铁1009带动盖板1010转动下料孔1007的正上方将下料孔1007堵住,第三支撑架1001固定安装在料筒9的顶部,下料时气管1002将空气导向至挡板1006内,保证了挡板1006下方的物料排出,根据定量下料的定量启动定量下料结构10的气缸1003,气缸1003通过n形板1005和Z形架1008带动挡板1006移动,挡板1006下方存放量符合定量要求时停止气缸1003,上料时旋转电磁铁1009带动转动轴1011转动,转动轴1011带动盖板1010转动至下料孔1007外侧,上料结束后旋转电磁铁1009进行复位,旋转电磁铁1009带动盖板1010转动下料孔1007的正上方将下料孔1007堵住,然后将挡板1006下方存放量通过下料管8进行定量下料,使得装置方便进行定量下料;The
料筒9的底部固定连接有下料管8,下料管8固定安装有控制阀7。The bottom of the
实施例4Example 4
实施例4是对实施例3的进一步改进。Example 4 is a further improvement to Example 3.
如图13至22所示,第一支撑架1在下料管8的下方处设有用于油桶限位的定位结构6,定位结构6包括第一C形板601、第二C形板602、滑动槽603、螺纹杆604、转动杆605、螺纹槽606、U形板607、连接直块608、第二驱动电机609、第三驱动电机610和滑动板611,第三驱动电机610的输出端固定连接有螺纹杆604,螺纹杆604螺纹连接有连接直块608,连接直块608的顶部固定连接有U形板607,U形板607的一端固定连接有第二驱动电机609,第二驱动电机609的输出端固定连接有转动杆605,转动杆605对称开设有螺纹槽606,转动杆605通过螺纹槽606螺纹连接有滑动板611,滑动板611的侧壁分别固定连接有第二C形板602和第一C形板601,第一支撑架1的侧壁开设有与第二C形板602和第一C形板601配合使用的滑动槽603,第三驱动电机610固定安装在第一支撑架1的侧壁,第一支撑架1的侧壁通过固定连接的轴承与螺纹杆604转动连接,U形板607的直立部位通过固定连接的轴承转动连接有转动杆605,第二C形板602和第一C形板601设置在下料管8的两端,定位结构6的第二驱动电机609带动转动杆605转动,转动杆605通过螺纹槽606驱动滑动板611移动,滑动板611带动第一C形板601和第二C形板602移动,使得第一C形板601和第二C形板602之间适合不同定量灌装的油桶尺寸,灌装前,第三驱动电机610带动螺纹杆604转动,螺纹杆604驱动连接直块608向后移动,连接直块608带动U形板607向后移动,U形板607带动第二C形板602和第一C形板601向后移动,第二C形板602和第一C形板601移动至最后端,油桶通过第二C形板602移动至第一C形板601的右端,第一C形板601将油桶限位住然后进行灌装,灌装后,第三驱动电机610带动螺纹杆604转动,螺纹杆604驱动连接直块608向前移动,连接直块608带动U形板607向前移动,U形板607带动第二C形板602和第一C形板601向前移动,第二C形板602和第一C形板601移动至最前端,第二C形板602将第二C形板602右侧的油桶堵住,第一C形板601右端的油桶从第一C形板601排出,方便将油桶按顺序限位在下料管8整下方。As shown in FIGS. 13 to 22 , the
使用时,根据定量灌装要求,启动定量下料结构10的气缸1003,气缸1003通过n形板1005和Z形架1008带动挡板1006移动,挡板1006下方存放量符合定量要求时停止气缸1003;When in use, according to the quantitative filling requirements, start the
根据定量灌装的油桶尺寸选择扶正结构4的定位孔402,向上拉动插销401,滑动滑动横板403,滑动横板403带动选择的定位孔402移动至插销401下方处,松开插销401后拉簧404的恢复力带动插销401插在定位孔402内,使得直限位板406之间适合定量灌装的油桶,定位结构6的第二驱动电机609带动转动杆605转动,转动杆605通过螺纹槽606驱动滑动板611移动,滑动板611带动第一C形板601和第二C形板602移动,使得第一C形板601和第二C形板602之间适合不同定量灌装的油桶尺寸;灌装前,第三驱动电机610带动螺纹杆604转动,螺纹杆604驱动连接直块608向后移动,连接直块608带动U形板607向后移动,U形板607带动第二C形板602和第一C形板601向后移动,第二C形板602和第一C形板601移动至最后端,将油桶放到传送带3,第一驱动电机2驱动传送带3移动,传送带3驱动油桶移动,斜导向板407方便将定量灌装的油桶引到至直限位板406内,再通过直限位板406移动至下料管8下方,油桶通过第二C形板602移动至第一C形板601的右端,第一C形板601将油桶限位住然后进行灌装,方便将油桶按顺序限位在下料管8整下方,然后对挡板1006进行上料,上料时旋转电磁铁1009带动转动轴1011转动,转动轴1011带动盖板1010转动至下料孔1007外侧,上料结束后旋转电磁铁1009进行复位,旋转电磁铁1009带动盖板1010转动下料孔1007的正上方将下料孔1007堵住,然后将挡板1006下方存放量通过下料管8进行定量下料,使得装置方便进行定量下料,定量灌装后,第三驱动电机610带动螺纹杆604转动,螺纹杆604驱动连接直块608向前移动,连接直块608带动U形板607向前移动,U形板607带动第二C形板602和第一C形板601向前移动,第二C形板602和第一C形板601移动至最前端,第二C形板602将第二C形板602右侧的油桶堵住,第一C形板601右端的油桶从第一C形板601排出,然后第三驱动电机610带动螺纹杆604转动,螺纹杆604驱动连接直块608向后移动,连接直块608带动U形板607向后移动,U形板607带动第二C形板602和第一C形板601向后移动,第二C形板602和第一C形板601移动至最后端。Select the
在本说明书的描述中,参考术语“一个实施例”、“示例”、“具体示例”等的描述意指结合该实施例或示例描述的具体特征、结构、材料或者特点包含于本发明的至少一个实施例或示例中。在本说明书中,对上述术语的示意性表述不一定指的是相同的实施例或示例。而且,描述的具体特征、结构、材料或者特点可以在任何的一个或多个实施例或示例中以合适的方式结合。In the description of this specification, description with reference to the terms "one embodiment," "example," "specific example," etc. means that a particular feature, structure, material, or characteristic described in connection with the embodiment or example is included in at least one aspect of the present invention. in one embodiment or example. In this specification, schematic representations of the above terms do not necessarily refer to the same embodiment or example. Furthermore, the particular features, structures, materials or characteristics described may be combined in any suitable manner in any one or more embodiments or examples.
以上公开的本发明优选实施例只是用于帮助阐述本发明。优选实施例并没有详尽叙述所有的细节,也不限制该发明仅为的具体实施方式。显然,根据本说明书的内容,可作很多的修改和变化。本说明书选取并具体描述这些实施例,是为了更好地解释本发明的原理和实际应用,从而使所属技术领域技术人员能很好地理解和利用本发明。本发明仅受权利要求书及其全部范围和等效物的限制。The above-disclosed preferred embodiments of the present invention are provided only to help illustrate the present invention. The preferred embodiments do not describe all the details and do not limit the invention to specific embodiments only. Obviously, many modifications and variations are possible in light of the contents of this specification. The present specification selects and specifically describes these embodiments in order to better explain the principles and practical applications of the present invention, so that those skilled in the art can well understand and utilize the present invention. The present invention is to be limited only by the claims and their full scope and equivalents.
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