CN113355009A - Marine coating for preventing marine organisms from attaching and processing technology - Google Patents

Marine coating for preventing marine organisms from attaching and processing technology Download PDF

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Publication number
CN113355009A
CN113355009A CN202110743410.5A CN202110743410A CN113355009A CN 113355009 A CN113355009 A CN 113355009A CN 202110743410 A CN202110743410 A CN 202110743410A CN 113355009 A CN113355009 A CN 113355009A
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sector
plate
shaped
fixedly connected
parts
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CN202110743410.5A
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徐晓飞
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Guangzhou Xiumide Technology Co ltd
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Guangzhou Xiumide Technology Co ltd
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Priority to CN202110743410.5A priority Critical patent/CN113355009A/en
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    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D163/00Coating compositions based on epoxy resins; Coating compositions based on derivatives of epoxy resins
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B67OPENING, CLOSING OR CLEANING BOTTLES, JARS OR SIMILAR CONTAINERS; LIQUID HANDLING
    • B67CCLEANING, FILLING WITH LIQUIDS OR SEMILIQUIDS, OR EMPTYING, OF BOTTLES, JARS, CANS, CASKS, BARRELS, OR SIMILAR CONTAINERS, NOT OTHERWISE PROVIDED FOR; FUNNELS
    • B67C3/00Bottling liquids or semiliquids; Filling jars or cans with liquids or semiliquids using bottling or like apparatus; Filling casks or barrels with liquids or semiliquids
    • B67C3/30Filling of barrels or casks
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/08Anti-corrosive paints
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/16Antifouling paints; Underwater paints
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/16Antifouling paints; Underwater paints
    • C09D5/1656Antifouling paints; Underwater paints characterised by the film-forming substance
    • C09D5/1662Synthetic film-forming substance
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/60Additives non-macromolecular
    • C09D7/61Additives non-macromolecular inorganic
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/70Additives characterised by shape, e.g. fibres, flakes or microspheres
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/03Polymer mixtures characterised by other features containing three or more polymers in a blend
    • C08L2205/035Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Agricultural Chemicals And Associated Chemicals (AREA)

Abstract

The invention discloses marine paint for preventing marine organisms from attaching and a processing technology thereof, and relates to the technical field of paint, wherein the marine paint for preventing marine organisms from attaching comprises the following raw materials in parts: 9-12 parts of nano silicon dioxide, 4.5-7.5 parts of castor oil modified waterborne polyurethane, 2.3-4.5 parts of vinyl polydimethylsiloxane, 10-12 parts of hollow glass microsphere, 13-18 parts of epoxy resin, 8.3-11.8 parts of polychlorotrifluoroethylene, 1.5-1.8 parts of titanate coupling agent, 4.5-5.8 parts of polyacrylamide and 12-24 parts of defoaming agent; the marine coating for preventing marine organisms from attaching has good hydrophobicity and oleophobicity, antifouling property and corrosion resistance, can effectively avoid marine organisms from attaching, is suitable for the use environment of the surface of a ship, ensures the actual use of the coating, and is convenient for quantitative filling during filling of the coating.

Description

Marine coating for preventing marine organisms from attaching and processing technology
Technical Field
The invention relates to the technical field of coatings, in particular to a marine coating for preventing marine organisms from attaching and a processing technology thereof.
Background
More than 18000 organisms in various sea areas of the world are attached animals, and more than 600 organisms are attached plants. After marine organisms are attached to the bottom of the ship, resistance is increased, the speed is reduced, the fuel consumption is increased, and the mechanical abrasion is increased. The adhesion of marine organisms also damages a paint film, the corrosion of the steel plate is accelerated, the maintenance times and time of the ship are increased, and the sailing rate of the ship is reduced.
At present, in order to better promote the use of ships, need evenly paint coating at the boats and ships outer wall and protect the processing, but present coating prevents that the marine organism from adhering to the effect unsatisfactory, is unfavorable for boats and ships long-term use, simultaneously, inconvenient quantitative filling that carries on during the coating filling.
Thus, marine paints and processes for preventing marine adhesion have been proposed to solve the above problems.
Disclosure of Invention
The invention aims to provide a marine coating for preventing marine organisms from attaching and a processing technology thereof, so as to solve the problems in the background technology.
In order to achieve the purpose, the invention provides the following technical scheme: the marine coating for preventing marine organisms from attaching comprises the following raw materials in parts: 9-12 parts of nano silicon dioxide, 4.5-7.5 parts of castor oil modified waterborne polyurethane, 2.3-4.5 parts of vinyl polydimethylsiloxane, 10-12 parts of hollow glass microsphere, 13-18 parts of epoxy resin, 8.3-11.8 parts of polychlorotrifluoroethylene, 1.5-1.8 parts of titanate coupling agent, 4.5-5.8 parts of polyacrylamide and 12-24 parts of defoaming agent.
A processing technology of marine coating for preventing marine organisms from attaching comprises the following specific steps:
s1, pouring the nano silicon dioxide, the castor oil modified waterborne polyurethane, the vinyl polydimethylsiloxane, the epoxy resin and the polychlorotrifluoroethylene into a four-port double-layer glass cylindrical reaction kettle in sequence, controlling the stirring temperature at 75-90 ℃, and uniformly stirring to obtain a mixed solution;
s2, adding the hollow glass beads, the titanate coupling agent and the polyacrylamide into the mixed solution for continuous mixing and dispersion, controlling the mixing and dispersion temperature at 65-70 ℃, the mixing speed at 1000-3000rpm, and the rotating speed for dispersion for 3-5h to obtain an intermediate solution;
s3, adding the defoaming agent into the intermediate liquid, reacting at normal temperature, standing for 10-20h, adding distilled water, adjusting the solid content to 45-55%, stirring at 800rpm for 13-25min, and then quantitatively filling by a quantitative filling machine to obtain the marine coating for preventing marine organisms from attaching.
A device for preventing marine organism-attached ship coating, a quantitative filling machine with a preparation device as a step, comprises a first support frame, a second support frame and a charging basket, wherein the first support frame is connected with an intermittent driving structure for intermittent movement of the charging basket, the intermittent driving structure comprises a driving roller, a conveying belt, a first gear ring, a second gear ring, a support plate, an air cylinder, a square frame, a second rotating shaft, a first rotating shaft, a push rod and a transverse rod, the top of the support plate is fixedly provided with the air cylinder, the output end of the air cylinder is fixedly connected with the transverse rod, the end part of the transverse rod is fixedly connected with the square frame, the side wall of the first support frame is rotatably connected with the second rotating shaft and the first rotating shaft through a fixedly connected bearing, the outer wall of the first rotating shaft is fixedly connected with the first gear ring, the outer wall of the first gear ring is fixedly connected with the push rod, the outer wall of the push rod is in laminating contact with the inner wall of the square frame, the outer end of the second rotating shaft is fixedly connected with a second gear ring, the first gear ring is meshed with the second gear ring, the inner wall of the first support frame is rotatably connected with driving rollers through bearings which are uniformly and fixedly connected, one group of driving rollers are fixedly connected with the inner end of the second rotating shaft, and the outer wall of each driving roller is movably connected with a conveying belt;
the outer wall of the conveying belt is uniformly provided with mounting structures, each mounting structure comprises a supporting seat, an arc-shaped supporting plate, a supporting round rod, an inserting sleeve and a supporting block, the top of each supporting seat is fixedly connected with the corresponding inserting sleeve, the front side wall and the rear side wall of each inserting sleeve are fixedly connected with the corresponding supporting round rods, the upper end of the inner wall of each first supporting frame is uniformly and fixedly connected with the corresponding supporting block, the top of each supporting block is fixedly connected with the corresponding arc-shaped supporting plate, the two ends of each arc-shaped supporting plate are uniformly arc-shaped, and the bottom of each supporting round rod is in fit contact with the top of the corresponding arc-shaped supporting plate;
the charging bucket is inserted into the inserting sleeve;
the top of the second support frame is fixedly connected with a raw material box, the bottom of the raw material box is fixedly provided with a quantitative blanking structure for quantitative blanking, the quantitative blanking structure comprises a quantitative cylinder, a driving motor, a first sector plate, a third rotating shaft, a first bevel gear, a second bevel gear, an L-shaped support plate, a first sector hole, a second sector plate, a fourth sector plate, a second sector hole, a fourth rotating shaft, a third sector plate, a third sector hole and a fourth sector hole, the inner wall of the quantitative cylinder is fixedly connected with the L-shaped support plate, the second sector plate and the fourth sector plate from top to bottom, the second sector hole is formed in the second sector plate, the fourth sector plate is formed in the fourth sector hole, the opposite hole of the second sector hole and the opposite hole of the fourth sector hole are formed in the inner wall of the quantitative cylinder, the transverse part of the L-shaped support plate is rotatably connected with the fourth rotating shaft through a bearing which is fixedly connected with the L-shaped support plate, the outer wall of the fourth rotating shaft is fixedly connected with a second bevel gear, a first sector plate and a third sector plate from top to bottom in sequence, the first sector plate is attached to the second sector plate in a sliding connection mode, the third sector plate is attached to the fourth sector plate in a sliding connection mode, the first sector plate is provided with a first sector hole, the third sector plate is provided with a third sector hole, the first sector hole and the third sector hole are arranged at the same position, the first sector hole, the second sector hole, the third sector hole and the fourth sector hole are right-angle grooves, the output end of the driving motor is fixedly connected with a third rotating shaft, the output end of the third rotating shaft is fixedly connected with a first bevel gear, and the bottom of the first bevel gear is meshed with the second bevel gear;
the bottom of a quantitative section of thick bamboo is connected with extending structure, extending structure includes slide pipe, straight tube, electric putter and diaphragm, straight tube fixed mounting is in the bottom of a quantitative section of thick bamboo, the lateral wall fixedly connected with electric putter of straight tube, electric putter's output fixedly connected with diaphragm, diaphragm fixed mounting is at the outer wall top of slide pipe.
Furthermore, the supporting plate is fixedly arranged on the side wall of the first supporting frame.
Furthermore, the flexible end of cylinder drives the horizontal pole round trip movement round, and the horizontal pole passes through catch bar and square frame and drives first ring gear rotation round, and first ring gear rotation round drive second ring gear rotates four rings, and the second ring gear passes through drive roller and conveyer belt drive mounting structure and removes fixed distance, realizes that mounting structure removes in order.
Furthermore, the left end arc position contact that the plug bush drove support round bar and arc backup pad when upwards moving moves to the arc backup pad on, and supports the round bar and break away from the right-hand member arc position of arc backup pad, and the arc backup pad supports mounting structure with supporting the cooperation of round bar.
Furthermore, the bottom of the supporting seat is fixedly arranged on the outer wall of the driving roller.
Furthermore, the quantitative cylinder is fixedly arranged at the bottom of the raw material box.
Furthermore, when the third sector hole and the fourth sector hole are overlapped, materials between the second sector plate and the fourth sector plate are discharged from the fourth sector hole, and at the moment, the solid part of the first sector plate blocks the second sector hole; when the first sector hole and the second sector hole are coincided, the material above the first sector plate moves to a position between the second sector plate and the fourth sector plate, and at the moment, the solid part of the third sector plate blocks the fourth sector hole.
Furthermore, when the telescopic end of the transverse plate extends, the electric push rod drives the sliding pipe to be inserted into the charging basket.
The invention has the beneficial effects that:
according to the invention, the cylinder of the intermittent driving structure drives the cross rod to move back and forth, the cross rod drives the square frame to move back and forth, the square frame drives the first gear ring to rotate through the pushing rod, the first gear ring rotates for one circle to drive the second gear ring to rotate for four circles, the second gear ring drives the mounting structure to move for a fixed distance through the driving roller and the conveying belt, the mounting structure is moved in sequence, and the charging barrel is moved to the position under the raw material box in sequence to be filled;
according to the quantitative blanking structure, a driving motor drives a third rotating shaft to rotate, the third rotating shaft drives a first bevel gear to rotate, the first bevel gear drives a second bevel gear to rotate, the second bevel gear drives a fourth rotating shaft to rotate, the fourth rotating shaft drives a first sector plate and a third sector plate to rotate, the first sector plate drives a first sector hole to rotate right above a second sector hole, when the first sector hole and the second sector hole are overlapped, a material above the first sector plate moves to a position between the second sector plate and the fourth sector plate, a solid part of the third sector plate blocks the fourth sector hole, and a quantitative material enters a position between the second sector plate and the fourth sector plate; the driving motor drives the third rotating shaft to continue rotating, the first sector plate drives the first sector hole to rotate to the solid part of the second sector plate, when the third sector hole and the fourth sector hole are overlapped, materials between the second sector plate and the fourth sector plate are discharged from the fourth sector hole, the solid part of the first sector plate blocks the second sector hole, quantitative materials are conveniently discharged, and quantitative filling is conveniently carried out when the coating is filled;
according to the invention, the charging bucket is inserted into the insertion sleeve of the mounting structure, then the insertion sleeve is driven to move, so that the charging bucket can be conveniently inserted, and meanwhile, the supporting round rod is contacted with the arc-shaped supporting plate to support the insertion sleeve, so that the pressure on the driving roller is reduced;
the marine coating for preventing marine organisms from attaching is prepared by matching nano silicon dioxide, castor oil modified waterborne polyurethane, vinyl polydimethylsiloxane, hollow glass beads, epoxy resin, polychlorotrifluoroethylene, titanate coupling agent, polyacrylamide and defoaming agent, has good hydrophobicity and oleophobicity, antifouling property and corrosion resistance, can effectively avoid marine organisms from attaching, is suitable for the use environment of the surface of a ship, and ensures the actual use of the coating.
Drawings
In order to more clearly illustrate the technical solutions of the embodiments of the present invention, the drawings used in the description of the embodiments will be briefly introduced below, and it is obvious that the drawings in the following description are only some embodiments of the present invention, and it is obvious for those skilled in the art that other drawings can be obtained according to the drawings without creative efforts.
FIG. 1 is a flow chart of the process of the present invention;
FIG. 2 is a schematic structural view of the present invention;
FIG. 3 is a left side view of the structure of the present invention;
FIG. 4 is a right side view of the structure of the present invention;
FIG. 5 is a top view of the structure of the present invention;
FIG. 6 is a partial cross-sectional view of a structure of the present invention;
FIG. 7 is a sectional view of a driving motor and its connection structure according to the present invention;
FIG. 8 is a sectional bottom view of a driving motor and a connection structure thereof according to the present invention;
FIG. 9 is an enlarged view of the structure at A of FIG. 2 according to the present invention;
FIG. 10 is a schematic view of the telescopic structure of the present invention;
FIG. 11 is a cross-sectional view of an arcuate support plate and its attachment structure in accordance with the present invention;
in the drawings, the components represented by the respective reference numerals are listed below:
1. the first support frame 2, the second support frame 3, the intermittent drive structure 301, the drive roller 302, the conveyor belt 303, the first gear ring 304, the second gear ring 305, the support plate 306, the cylinder 307, the square frame 308, the second rotating shaft 309, the first rotating shaft 310, the push rod 311, the cross rod 4, the charging basket 5, the raw material box 6, the quantitative blanking structure 601, the quantitative cylinder 602, the drive motor 603, the first sector plate 604, the third rotating shaft 605, the first bevel gear 606, the second bevel gear 607, the L-shaped support plate 608, the first sector hole 609, the second sector plate 610, the fourth sector plate 611, the second sector hole 612, the fourth rotating shaft 613, the third sector plate 614, the third sector hole 615, the fourth sector hole 7, the telescopic structure 701, the sliding pipe 702, the electric push rod 704, the transverse plate 8, the mounting structure 801, the support seat 802, the arc-shaped support plate 803 and the support circular rod 804 Insert sleeve 805, support block.
Detailed Description
The technical solutions in the embodiments of the present invention will be clearly and completely described below with reference to the drawings in the embodiments of the present invention, and it is obvious that the described embodiments are only a part of the embodiments of the present invention, and not all of the embodiments. All other embodiments, which can be derived by a person skilled in the art from the embodiments given herein without making any creative effort, shall fall within the protection scope of the present invention.
The present invention will be further described with reference to the following examples.
Example 1
As shown in fig. 1, the marine coating for preventing marine organisms from attaching comprises the following raw materials in parts: 9 parts of nano silicon dioxide, 7.5 parts of castor oil modified waterborne polyurethane, 2.3 parts of vinyl polydimethylsiloxane, 12 parts of hollow glass beads, 18 parts of epoxy resin, 8.3 parts of polychlorotrifluoroethylene, 1.8 parts of titanate coupling agent, 4.5 parts of polyacrylamide and 12 parts of defoaming agent.
A processing technology of marine coating for preventing marine organisms from attaching comprises the following specific steps:
s1, pouring the nano-silica, the castor oil modified waterborne polyurethane, the vinyl polydimethylsiloxane, the epoxy resin and the polychlorotrifluoroethylene into a four-port double-layer glass cylindrical reaction kettle in sequence, controlling the stirring temperature at 90 ℃, and uniformly stirring to obtain a mixed solution;
s2, adding the hollow glass beads, the titanate coupling agent and the polyacrylamide into the mixed solution for continuous mixing and dispersion, controlling the mixing and dispersion temperature at 65 ℃, the mixing speed at 3000rpm, and dispersing for 3 hours at the rotating speed to obtain an intermediate solution;
and S3, adding the defoaming agent into the intermediate liquid, reacting at normal temperature, standing for 20h, adding distilled water, adjusting the solid content to 45%, stirring at 600rpm for 25min, and then quantitatively filling through a quantitative filling machine to obtain the marine coating for preventing marine organisms from attaching.
Example 2
As shown in fig. 1, the embodiment 2 is a marine coating for preventing marine organisms from attaching, which is a further improvement of the embodiment 1, and comprises the following raw materials in parts: 12 parts of nano silicon dioxide, 4.5 parts of castor oil modified waterborne polyurethane, 4.5 parts of vinyl polydimethylsiloxane, 10 parts of hollow glass beads, 13 parts of epoxy resin, 11.8 parts of polychlorotrifluoroethylene, 1.5 parts of titanate coupling agent, 5.8 parts of polyacrylamide and 24 parts of defoaming agent.
A processing technology of marine coating for preventing marine organisms from attaching comprises the following specific steps:
s1, pouring the nano silicon dioxide, the castor oil modified waterborne polyurethane, the vinyl polydimethylsiloxane, the epoxy resin and the polychlorotrifluoroethylene into a four-port double-layer glass cylindrical reaction kettle in sequence, controlling the stirring temperature at 75 ℃, and uniformly stirring to obtain a mixed solution;
s2, adding the hollow glass beads, the titanate coupling agent and the polyacrylamide into the mixed solution for continuous mixing and dispersion, controlling the mixing and dispersion temperature at 70 ℃, the mixing speed at 1000rpm, and dispersing for 5 hours at the rotating speed to obtain an intermediate solution;
and S3, adding the defoaming agent into the intermediate liquid, reacting at normal temperature, standing for 10h, adding distilled water, adjusting the solid content to 55%, stirring at 800rpm for 13min, and then quantitatively filling through a quantitative filling machine to obtain the marine coating for preventing marine organisms from attaching.
The marine coating for preventing marine organisms from attaching is prepared by matching nano silicon dioxide, castor oil modified waterborne polyurethane, vinyl polydimethylsiloxane, hollow glass beads, epoxy resin, polytrifluorochloroethylene, titanate coupling agent, polyacrylamide and defoaming agent, has good hydrophobicity and oleophobicity, antifouling property and corrosion resistance, can effectively avoid marine organisms from attaching, is suitable for the use environment of the surface of a ship, and ensures the actual use of the coating.
Example 3
Example 3 is a further modification to example 1.
As shown in fig. 2, 3, 4, 5, 6, 7, 8, 9, 10, 11, a device for preventing marine organism from attaching marine coating, the preparation device is a quantitative filling machine of a step intermittent drive structure 3, and comprises a first support frame 1, a second support frame 2 and a charging basket 4, the first support frame 1 is connected with the intermittent drive structure 3 for the intermittent movement of the charging basket 4, the intermittent drive structure 3 comprises a driving roller 301, a conveyor belt 302, a first gear ring 303, a second gear ring 304, a support plate 305, a cylinder 306, a square frame 307, a second rotating shaft 308, a first rotating shaft 309, a push rod 310 and a cross rod 311, the top of the support plate 305 is fixedly provided with the cylinder 306, the output end of the cylinder 306 is fixedly connected with the cross rod 311, the end of the cross rod 311 is fixedly connected with the square frame 307, the side wall of the first support frame 1 is rotatably connected with the second rotating shaft 308 and the first rotating shaft 309 through a bearing which is fixedly connected, the outer wall of the first rotating shaft 309 is fixedly connected with a first gear ring 303, the outer wall of the first gear ring 303 is fixedly connected with a push rod 310, the outer wall of the push rod 310 is in contact with the inner wall of a square frame 307 in a fitting manner, the outer end of a second rotating shaft 308 is fixedly connected with a second gear ring 304, the first gear ring 303 is in meshed connection with the second gear ring 304, the inner wall of the first support frame 1 is rotatably connected with a driving roller 301 through a bearing which is uniformly and fixedly connected, one group of driving rollers 301 are fixedly connected with the inner end of the second rotating shaft 308, the outer wall of the driving roller 301 is movably connected with a conveyor belt 302, a support plate 305 is fixedly arranged on the side wall of the first support frame 1, the telescopic end of the air cylinder 306 drives a cross rod 311 to move back and forth for one circle, the cross rod 311 drives the first gear ring to rotate for one circle through the push rod 310 and the square frame 307, the first gear ring 303 rotates for one circle to drive the second gear ring 304 to rotate for four circles, the second gear ring 304 drives the mounting structure 8 to move for a fixed distance through the driving roller 301 and the conveyor belt 302, the mounting structure 8 is enabled to move in sequence, the air cylinder 306 of the intermittent driving structure 3 drives the cross rod 311 to move back and forth, the cross rod 311 drives the square frame 307 to move back and forth, the square frame 307 drives the first gear ring 303 to rotate through the push rod 310, the first gear ring 303 rotates for one circle to drive the second gear ring 304 to rotate for four circles, the second gear ring 304 drives the mounting structure 8 to move for a fixed distance through the driving roller 301 and the conveyor belt 302, the mounting structure 8 is enabled to move in sequence, and the charging basket 4 is enabled to move to the position under the raw material box 5 in sequence for filling;
the outer wall of the conveyor belt 302 is uniformly provided with a mounting structure 8, the mounting structure 8 comprises a supporting seat 801, an arc-shaped supporting plate 802, a supporting round rod 803, an inserting sleeve 804 and a supporting block 805, the top of the supporting seat 801 is fixedly connected with the inserting sleeve 804, the front side wall and the rear side wall of the inserting sleeve 804 are fixedly connected with the supporting round rod 803, the upper end of the inner wall of the first supporting frame 1 is uniformly and fixedly connected with the supporting block 805, the top of the supporting block 805 is fixedly connected with the arc-shaped supporting plate 802, the two ends of the arc-shaped supporting plate 802 are uniformly arc-shaped, the bottom of the supporting round rod 803 is in contact with the top of the arc-shaped supporting plate 802, when the inserting sleeve 804 moves upwards, the supporting round rod 803 is driven to contact with the arc-shaped part at the left end of the arc-shaped supporting plate 802 and move onto the arc-shaped supporting plate 802, the supporting round rod 803 is separated from the arc-shaped part at the right end of the arc-shaped supporting plate 802, and the arc-shaped supporting plate 802 and the mounting structure 8 is supported by the cooperation of the arc-shaped supporting round rod 803, the bottom of the supporting seat 801 is fixedly mounted on the outer wall of the driving roller 301, the charging bucket 4 is inserted into the inserting sleeve 804 of the mounting structure 8, then the inserting sleeve 804 is driven by the driving rod 401 to move, the charging bucket 4 is convenient to insert, meanwhile, the supporting round rod 803 and the arc-shaped supporting plate 802 are in contact with each other to support the inserting sleeve 804, and pressure on the driving roller 301 is reduced;
the top of the second support frame 2 is fixedly connected with a raw material box 5, the bottom of the raw material box 5 is fixedly provided with a quantitative blanking structure 6 for quantitative blanking, the quantitative blanking structure 6 comprises a quantitative cylinder 601, a driving motor 602, a first sector plate 603, a third rotating shaft 604, a first bevel gear 605, a second bevel gear 606, an L-shaped support plate 607, a first sector hole 608, a second sector plate 609, a fourth sector plate 610, a second sector hole 611, a fourth rotating shaft 612, a third sector plate 613, a third sector hole 614 and a fourth sector hole 615, the inner wall of the quantitative cylinder 601 is fixedly connected with an L-shaped support plate 607, a second sector plate 609 and a fourth sector plate 610 from top to bottom, the second sector plate 609 is provided with the second sector hole 611, the fourth sector plate 610 is provided with the fourth sector hole 615, the second sector hole 611 and the fourth sector hole 615 are opposite, the transverse part of the L-shaped support plate 607 is rotatably connected with the fourth rotating shaft 612 through a bearing fixedly connected, a second bevel gear 606, a first sector plate 603 and a third sector plate 613 are fixedly connected to the outer wall of the fourth rotating shaft 612 from top to bottom in sequence, the first sector plate 603 is in fit sliding connection with a second sector plate 609, the third sector plate 613 is in fit sliding connection with a fourth sector plate 610, a first sector hole 608 is formed in the first sector plate 603, a third sector hole 614 is formed in the third sector plate 613, the positions of the first sector hole 608 and the third sector hole 614 are the same, the first sector hole 608, the second sector hole 611, the third sector hole 614 and the fourth sector hole 615 are all right-angle grooves, a third rotating shaft 604 is fixedly connected to the output end of the driving motor 602, a first bevel gear 605 is fixedly connected to the output end of the third rotating shaft 604, the bottom of the first bevel gear 605 is in mesh connection with the second sector plate 606, the third sector hole 601 is fixedly mounted to the bottom of the raw material box 5, and when the third sector hole 614 and the fourth sector hole 615 are overlapped, materials between the second sector plate 609 and the fourth sector plate 610 are arranged from the fourth sector hole 615 Discharging, at this time, the solid portion of the first sector plate 603 blocks the second sector hole 611; when the first sector hole 608 and the second sector hole 611 coincide, the material above the first sector plate 603 moves to between the second sector plate 609 and the fourth sector plate 610, at this time, the solid portion of the third sector plate 613 blocks the fourth sector hole 615, the driving motor 602 of the quantitative discharging structure 6 drives the third rotating shaft 604 to rotate, the third rotating shaft 604 drives the first bevel gear 605 to rotate, the first bevel gear 605 drives the second bevel gear 606 to rotate, the second bevel gear 606 drives the fourth rotating shaft 612 to rotate, the fourth rotating shaft 612 drives the first sector plate 603 and the third sector plate 613 to rotate, the first sector plate 603 drives the first sector hole 608 to rotate right above the second sector hole 611, when the first sector hole 608 and the second sector hole 611 coincide, the material above the first sector plate 603 moves to between the second sector plate 609 and the fourth sector plate 610, the solid portion of the third sector plate 613 blocks the fourth sector hole 615, feeding a metered quantity of material between the second sector 609 and the fourth sector 610; the driving motor 602 drives the third rotating shaft 604 to continue rotating, the first sector plate 603 drives the first sector hole 608 to rotate to a solid part of the second sector plate 609, when the third sector hole 614 and the fourth sector hole 615 are overlapped, materials between the second sector plate 609 and the fourth sector plate 610 are discharged from the fourth sector hole 615, the solid part of the first sector plate 603 blocks the second sector hole 611, quantitative materials are conveniently discharged, and quantitative filling is conveniently carried out when the coating is filled;
the bottom of a quantitative section of thick bamboo 601 is connected with extending structure 7, extending structure 7 includes slide pipe 701, straight tube 702, electric putter 703 and diaphragm 704, straight tube 702 fixed mounting is in the bottom of a quantitative section of thick bamboo 601, the lateral wall fixedly connected with electric putter 703 of straight tube 702, the output fixedly connected with diaphragm 704 of electric putter 703, diaphragm 704 fixed mounting is at the outer wall top of slide pipe 701, diaphragm 704 drives slide pipe 701 and inserts in storage bucket 4 when electric putter 703's flexible end extends, make things convenient for slide pipe 701 to insert in storage bucket 4, avoid appearing the excessive phenomenon.
When the device is used, the charging basket 4 is inserted into the inserting sleeve 804 of the mounting structure 8, then the inserting sleeve 804 is driven by the cylinder 401 to move, so that the charging basket 4 can be conveniently inserted, meanwhile, the supporting round rod 803 and the arc-shaped supporting plate 802 are contacted to support the inserting sleeve 804, so that the pressure on the driving roller 301 is reduced, the cylinder 306 of the intermittent driving structure 3 drives the cross rod 311 to move back and forth, the cross rod 311 drives the square frame 307 to move back and forth, the square frame 307 drives the first gear ring 303 to rotate through the pushing rod 310, the first gear ring 303 rotates for one circle to drive the second gear ring 304 to rotate for four circles, the second gear ring 304 drives the mounting structure 8 to move for a fixed distance through the driving roller 301 and the conveying belt 302, the sequential movement of the mounting structure 8 is realized, the charging basket 4 sequentially moves to the position under the raw material box 5 to be filled, the charging basket 4 moves to the position under the sliding pipe 701, the electric push rod 703 drives the transverse plate 704 to move downwards, the transverse plate 704 drives the sliding pipe 701 to move downwards, the sliding pipe 701 is inserted into the charging basket 4, so that the sliding pipe 701 is conveniently inserted into the charging basket 4, the overflow phenomenon is avoided, then the driving motor 602 of the quantitative blanking structure 6 drives the third rotating shaft 604 to rotate, the third rotating shaft 604 drives the first bevel gear 605 to rotate, the first bevel gear 605 drives the second bevel gear 606 to rotate, the second bevel gear 606 drives the fourth rotating shaft 612 to rotate, the fourth rotating shaft 612 drives the first sector plate 603 and the third sector plate 613 to rotate, the first sector plate 603 drives the first sector hole 608 to rotate right above the second sector hole 611, when the first sector hole 608 and the second sector hole 611 are overlapped, the material above the first sector plate 603 moves to a position between the second sector plate 609 and the fourth sector plate 610, the solid part of the third sector plate 613 blocks the fourth sector hole 615, and the quantitative material enters a position between the second sector plate 609 and the fourth sector plate 610; the driving motor 602 drives the third rotating shaft 604 to continue rotating, the first sector plate 603 drives the first sector hole 608 to rotate to the solid part of the second sector plate 609, when the third sector hole 614 and the fourth sector hole 615 are overlapped, materials between the second sector plate 609 and the fourth sector plate 610 are discharged from the fourth sector hole 615, the solid part of the first sector plate 603 blocks the second sector hole 611, so that quantitative materials are conveniently discharged, quantitative filling is conveniently performed during filling of the coating, the sliding pipe 701 is separated from the material barrel 4 after filling, and the intermittent driving structure 3 drives another group of material barrels 4 to move to the position under the raw material box 5 for continuous quantitative filling.
The rotation angle of the fourth rotation shaft 612 is 270 °, the fourth rotation shaft 612 rotates from 0 to 90 °, the first sector-shaped plate 603 drives the first sector-shaped hole 608 to rotate to a position right above the second sector-shaped hole 611, when the first sector-shaped hole 608 and the second sector-shaped hole 611 are overlapped, the material above the first sector-shaped plate 603 moves to a position between the second sector-shaped plate 609 and the fourth sector-shaped plate 610, and the solid part of the third sector-shaped plate 613 blocks the fourth sector-shaped hole 615; when the fourth rotating shaft 612 rotates from 90 degrees to 180 degrees, the solid part of the first sector plate plugs the second sector hole, and simultaneously, the solid part of the third sector plate plugs the fourth sector hole; when the fourth rotating shaft rotates from 180 degrees to 270 degrees, the driving motor 602 drives the third rotating shaft 604 to continue rotating, the first sector-shaped plate 603 drives the first sector-shaped hole 608 to rotate to the solid part of the second sector-shaped plate 609, when the third sector-shaped hole 614 and the fourth sector-shaped hole 615 are overlapped, materials between the second sector-shaped plate 609 and the fourth sector-shaped plate 610 are discharged from the fourth sector-shaped hole 615, and the solid part of the first sector-shaped plate 603 blocks the second sector-shaped hole 611.
In the description herein, references to the description of "one embodiment," "an example," "a specific example" or the like are intended to mean that a particular feature, structure, material, or characteristic described in connection with the embodiment or example is included in at least one embodiment or example of the invention. In this specification, the schematic representations of the terms used above do not necessarily refer to the same embodiment or example. Furthermore, the particular features, structures, materials, or characteristics described may be combined in any suitable manner in any one or more embodiments or examples.
The preferred embodiments of the invention disclosed above are intended to be illustrative only. The preferred embodiments are not intended to be exhaustive or to limit the invention to the precise forms disclosed. Obviously, many modifications and variations are possible in light of the above teaching. The embodiments were chosen and described in order to best explain the principles of the invention and the practical application, to thereby enable others skilled in the art to best utilize the invention. The invention is limited only by the claims and their full scope and equivalents.

Claims (10)

1. Marine coating for preventing marine organisms from attaching, which is characterized in that: the marine coating for preventing marine organisms from attaching comprises the following raw materials in parts: 9-12 parts of nano silicon dioxide, 4.5-7.5 parts of castor oil modified waterborne polyurethane, 2.3-4.5 parts of vinyl polydimethylsiloxane, 10-12 parts of hollow glass microsphere, 13-18 parts of epoxy resin, 8.3-11.8 parts of polychlorotrifluoroethylene, 1.5-1.8 parts of titanate coupling agent, 4.5-5.8 parts of polyacrylamide and 12-24 parts of defoaming agent.
2. The process for preparing marine coating for preventing marine organism adhesion according to claim 1, wherein the process comprises the following steps: the method comprises the following specific steps:
s1, pouring the nano silicon dioxide, the castor oil modified waterborne polyurethane, the vinyl polydimethylsiloxane, the epoxy resin and the polychlorotrifluoroethylene into a four-port double-layer glass cylindrical reaction kettle in sequence, controlling the stirring temperature at 75-90 ℃, and uniformly stirring to obtain a mixed solution;
s2, adding the hollow glass beads, the titanate coupling agent and the polyacrylamide into the mixed solution for continuous mixing and dispersion, controlling the mixing and dispersion temperature at 65-70 ℃, the mixing speed at 1000-3000rpm, and the rotating speed for dispersion for 3-5h to obtain an intermediate solution;
s3, adding the defoaming agent into the intermediate liquid, reacting at normal temperature, standing for 10-20h, adding distilled water, adjusting the solid content to 45-55%, stirring at 800rpm for 13-25min, and then quantitatively filling by a quantitative filling machine to obtain the marine coating for preventing marine organisms from attaching.
3. A marine coating material device for preventing marine organisms from attaching is characterized in that: the preparation device is a quantitative filling machine of step 3, and comprises a first support frame (1), a second support frame (2) and a charging basket (4), wherein the first support frame (1) is connected with an intermittent driving structure (3) for intermittent movement of the charging basket (4), the intermittent driving structure (3) comprises a driving roller (301), a conveying belt (302), a first gear ring (303), a second gear ring (304), a support plate (305), an air cylinder (306), a square frame (307), a second rotating shaft (308), a first rotating shaft (309), a push rod (310) and a cross rod (311), the top of the support plate (305) is fixedly provided with the air cylinder (306), the output end of the air cylinder (306) is fixedly connected with the cross rod (311), the end part of the cross rod (311) is fixedly connected with the square rotating shaft (307), the side wall of the first support frame (1) is rotatably connected with the second rotating shaft (308) and the first rotating shaft (309) through a bearing which is fixedly connected, the outer wall of the first rotating shaft (309) is fixedly connected with a first gear ring (303), the outer wall of the first gear ring (303) is fixedly connected with a push rod (310), the outer wall of the push rod (310) is in contact with the inner wall of a square frame (307) in a fitting manner, the outer end of the second rotating shaft (308) is fixedly connected with a second gear ring (304), the first gear ring (303) is in meshed connection with the second gear ring (304), the inner wall of the first support frame (1) is rotatably connected with a driving roller (301) through a bearing which is uniformly and fixedly connected, one group of driving rollers (301) are fixedly connected with the inner end of the second rotating shaft (308), and the outer wall of each driving roller (301) is movably connected with a conveying belt (302);
the outer wall of the conveyor belt (302) is uniformly provided with mounting structures (8), each mounting structure (8) comprises a supporting seat (801), an arc-shaped supporting plate (802), a supporting round rod (803), an inserting sleeve (804) and a supporting block (805), the top of each supporting seat (801) is fixedly connected with the inserting sleeve (804), the front side wall and the rear side wall of each inserting sleeve (804) are fixedly connected with the supporting round rods (803), the upper end of the inner wall of the first supporting frame (1) is uniformly and fixedly connected with the supporting block (805), the top of each supporting block (805) is fixedly connected with the arc-shaped supporting plate (802), the two ends of each arc-shaped supporting plate (802) are uniformly arc-shaped, and the bottom of each supporting round rod (803) is in fit contact with the top of each arc-shaped supporting plate (802);
the charging bucket (4) is inserted into the inserting sleeve (804);
the top of the second support frame (2) is fixedly connected with a raw material box (5), the bottom of the raw material box (5) is fixedly provided with a quantitative blanking structure (6) for quantitative blanking, the quantitative blanking structure (6) comprises a quantitative cylinder (601), a driving motor (602), a first sector plate (603), a third rotating shaft (604), a first bevel gear (605), a second bevel gear (606), an L-shaped support plate (607), a first sector hole (608), a second sector plate (609), a fourth sector plate (610), a second sector hole (611), a fourth rotating shaft (612), a third sector plate (613), a third sector hole (614) and a fourth sector hole (615), the inner wall of the quantitative cylinder (601) is fixedly connected with the L-shaped support plate (607), the second sector plate (609) and the fourth sector plate (610) from top to bottom, the second sector hole (611) is formed in the second sector plate (609), fourth sector hole (615) has been seted up to fourth sector plate (610), and second sector hole (611) and fourth sector hole (615) are seted up in opposition, the horizontal position of L shape backup pad (607) is rotated through fixed connection's bearing and is connected with fourth axis of rotation (612), the outer wall from the top down of fourth axis of rotation (612) fixedly connected with second bevel gear (606), first sector plate (603), and third sector plate (613) in proper order, first sector plate (603) and second sector plate (609) laminating sliding connection, third sector plate (613) and fourth sector plate (610) laminating sliding connection, first sector hole (608) has been seted up to first sector plate (603), third sector hole (614) has been seted up to third sector plate (613), first sector hole (608) and third sector hole (614) set up the position the same, the first fan-shaped hole (608), the second fan-shaped hole (611), the third fan-shaped hole (614) and the fourth fan-shaped hole (615) are all right-angle grooves, the output end of the driving motor (602) is fixedly connected with a third rotating shaft (604), the output end of the third rotating shaft (604) is fixedly connected with a first bevel gear (605), and the bottom of the first bevel gear (605) is in meshed connection with a second bevel gear (606);
the bottom of ration section of thick bamboo (601) is connected with extending structure (7), extending structure (7) are including slide pipe (701), straight tube (702), electric putter (703) and diaphragm (704), straight tube (702) fixed mounting is in the bottom of ration section of thick bamboo (601), the lateral wall fixedly connected with electric putter (703) of straight tube (702), the output fixedly connected with diaphragm (704) of electric putter (703), diaphragm (704) fixed mounting is at the outer wall top of slide pipe (701).
4. The marine coating material apparatus for preventing marine organism adhesion according to claim 3, wherein: the supporting plate (305) is fixedly arranged on the side wall of the first supporting frame (1).
5. The marine coating material apparatus for preventing marine organism adhesion according to claim 4, wherein: the telescopic end of the air cylinder (306) drives the cross rod (311) to move back and forth for one circle, the cross rod (311) drives the first gear ring (303) to rotate for one circle through the push rod (310) and the square frame (307), the first gear ring (303) rotates for one circle to drive the second gear ring (304) to rotate for four circles, the second gear ring (304) drives the mounting structure (8) to move for a fixed distance through the driving roller (301) and the conveyor belt (302), and the mounting structure (8) is sequentially moved.
6. The marine coating material apparatus for preventing marine organism adhesion according to claim 3, wherein: the plug bush (804) drives the supporting round rod (803) to contact with the arc-shaped part at the left end of the arc-shaped supporting plate (802) when moving upwards, the supporting round rod (803) is separated from the arc-shaped part at the right end of the arc-shaped supporting plate (802), and the arc-shaped supporting plate (802) and the supporting round rod (803) are matched to support the mounting structure (8).
7. The marine coating material apparatus for preventing marine organism adhesion according to claim 6, wherein: the bottom of the supporting seat (801) is fixedly arranged on the outer wall of the driving roller (301).
8. The marine coating material apparatus for preventing marine organism adhesion according to claim 3, wherein: the quantitative cylinder (601) is fixedly arranged at the bottom of the raw material box (5).
9. The marine coating material preventing marine organism adhesion device according to claim 8, wherein: when the third fan-shaped hole (614) and the fourth fan-shaped hole (615) are overlapped, materials between the second fan-shaped plate (609) and the fourth fan-shaped plate (610) are discharged from the fourth fan-shaped hole (615), and at the moment, the solid part of the first fan-shaped plate (603) blocks the second fan-shaped hole (611); when the first fan-shaped hole (608) and the second fan-shaped hole (611) are overlapped, the material above the first fan-shaped plate (603) moves to a position between the second fan-shaped plate (609) and the fourth fan-shaped plate (610), and at the moment, the solid part of the third fan-shaped plate (613) blocks the fourth fan-shaped hole (615).
10. The marine coating material preventing marine organism adhesion device according to claim 9, wherein: when the telescopic end of the transverse plate (704) extends, the electric push rod (703) drives the sliding pipe (701) to be inserted into the charging basket (4).
CN202110743410.5A 2021-07-01 2021-07-01 Marine coating for preventing marine organisms from attaching and processing technology Withdrawn CN113355009A (en)

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Publication number Priority date Publication date Assignee Title
CN114537723A (en) * 2022-02-10 2022-05-27 中山市晟美打印科技有限公司 Intelligent automatic carbon powder filling equipment
CN114573753A (en) * 2022-03-04 2022-06-03 东营勤和工贸有限公司 High molecular resin adhesive for profile control and water plugging of oil well and water well
CN118831366A (en) * 2024-08-06 2024-10-25 吉安巨联环保科技有限公司 NMP wastewater treatment equipment and treatment method thereof

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CN107011794A (en) * 2017-04-13 2017-08-04 江苏大使同丰涂料有限公司 A kind of coating for preventing marine organisms from adhering to and preparation method thereof
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CN112280463A (en) * 2020-11-24 2021-01-29 湖南连心科技有限公司 Marine organism adhesion-preventing powder coating for ship coating
CN212863227U (en) * 2020-07-27 2021-04-02 蔡金荣 Pharmacy department is with device of getting it filled
CN112960151A (en) * 2021-01-29 2021-06-15 福州三合元生物科技有限公司 Production method and production equipment of nerve-soothing and sleep-promoting solid beverage

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CN104356921A (en) * 2014-10-23 2015-02-18 安徽省金盾涂料有限责任公司 Powder coating for ship surface
CN107011794A (en) * 2017-04-13 2017-08-04 江苏大使同丰涂料有限公司 A kind of coating for preventing marine organisms from adhering to and preparation method thereof
CN110330823A (en) * 2019-04-19 2019-10-15 福建科华中盈新材料有限公司 It is a kind of to apply the coating and preparation method that can inhibit fouling organism growth attachment on ocean
CN212863227U (en) * 2020-07-27 2021-04-02 蔡金荣 Pharmacy department is with device of getting it filled
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Publication number Priority date Publication date Assignee Title
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CN114573753A (en) * 2022-03-04 2022-06-03 东营勤和工贸有限公司 High molecular resin adhesive for profile control and water plugging of oil well and water well
CN118831366A (en) * 2024-08-06 2024-10-25 吉安巨联环保科技有限公司 NMP wastewater treatment equipment and treatment method thereof

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Application publication date: 20210907