CN114561685B - Stainless steel welding seam and surface treatment method and device, terminal equipment and storage medium - Google Patents

Stainless steel welding seam and surface treatment method and device, terminal equipment and storage medium Download PDF

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Publication number
CN114561685B
CN114561685B CN202210143494.3A CN202210143494A CN114561685B CN 114561685 B CN114561685 B CN 114561685B CN 202210143494 A CN202210143494 A CN 202210143494A CN 114561685 B CN114561685 B CN 114561685B
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stainless steel
treated
welding seam
steel welding
brush head
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CN114561685A (en
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王康
王雄
王建廷
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China Construction Second Engineering Bureau Co Ltd
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China Construction Second Engineering Bureau Co Ltd
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    • CCHEMISTRY; METALLURGY
    • C25ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25FPROCESSES FOR THE ELECTROLYTIC REMOVAL OF MATERIALS FROM OBJECTS; APPARATUS THEREFOR
    • C25F7/00Constructional parts, or assemblies thereof, of cells for electrolytic removal of material from objects; Servicing or operating
    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23GCLEANING OR DE-GREASING OF METALLIC MATERIAL BY CHEMICAL METHODS OTHER THAN ELECTROLYSIS
    • C23G1/00Cleaning or pickling metallic material with solutions or molten salts
    • C23G1/02Cleaning or pickling metallic material with solutions or molten salts with acid solutions
    • C23G1/08Iron or steel
    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23GCLEANING OR DE-GREASING OF METALLIC MATERIAL BY CHEMICAL METHODS OTHER THAN ELECTROLYSIS
    • C23G3/00Apparatus for cleaning or pickling metallic material
    • CCHEMISTRY; METALLURGY
    • C25ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25DPROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
    • C25D11/00Electrolytic coating by surface reaction, i.e. forming conversion layers
    • CCHEMISTRY; METALLURGY
    • C25ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25DPROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
    • C25D11/00Electrolytic coating by surface reaction, i.e. forming conversion layers
    • C25D11/005Apparatus specially adapted for electrolytic conversion coating
    • CCHEMISTRY; METALLURGY
    • C25ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25DPROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
    • C25D21/00Processes for servicing or operating cells for electrolytic coating
    • C25D21/12Process control or regulation
    • CCHEMISTRY; METALLURGY
    • C25ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25FPROCESSES FOR THE ELECTROLYTIC REMOVAL OF MATERIALS FROM OBJECTS; APPARATUS THEREFOR
    • C25F1/00Electrolytic cleaning, degreasing, pickling or descaling
    • C25F1/02Pickling; Descaling
    • C25F1/04Pickling; Descaling in solution
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E30/00Energy generation of nuclear origin

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Materials Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Electrochemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Mechanical Engineering (AREA)
  • Automation & Control Theory (AREA)
  • Cleaning And De-Greasing Of Metallic Materials By Chemical Methods (AREA)
  • Arc Welding In General (AREA)

Abstract

The invention discloses a stainless steel welding seam and surface treatment method, a device, terminal equipment and a storage medium, wherein the on-site information of the stainless steel welding seam and the surface to be treated is obtained; gear adjustment is carried out on processing equipment according to the field information, wherein the processing equipment comprises a grounding wire clamp, an operation brush head and an inverter; connecting the grounding wire clamp with the stainless steel welding seam and the surface to be treated, and switching on an operation power supply of the treatment equipment so as to enable the operation brush head to alternately change with the electrode of the stainless steel welding seam and the surface to be treated through an inverter in the treatment equipment; and brushing the pre-configured electrolyte on the welding seam and the surface of the stainless steel to be treated through the operation brush head so as to remove the oxides on the welding seam and the surface of the stainless steel to be treated and generate a passivation film. The invention improves the treatment efficiency of the stainless steel welding seam and the surface.

Description

Stainless steel welding seam and surface treatment method and device, terminal equipment and storage medium
Technical Field
The invention relates to the field of metal surface treatment, in particular to a stainless steel welding seam and surface treatment method, a device, terminal equipment and a storage medium.
Background
In the welding process of the stainless steel pool of the nuclear power plant, free iron exists on the surface of a welding line, a passivation film affecting the surface of the stainless steel is formed, corrosion of the stainless steel can be caused by long-term exposure, so that the stainless steel pool can be subjected to surface treatment after the welding is finished, namely acid washing passivation, free iron on the surface of the stainless steel is removed, the passivation film is formed, and the corrosion resistance of the stainless steel is improved.
The traditional pickling passivation technology mainly adopts nitric acid with strong oxidability such as pickling passivation solution or pickling passivation paste as a main agent for chemical treatment, has strong corrosiveness, can generate a large amount of acid mist in the pickling process, has strong irritation and corrosiveness, is easy to cause injury to staff, and can influence the speed of pickling passivation reaction if weak acid with low safety risk is adopted as electrolyte, so that the working efficiency is reduced.
Therefore, there is a need for a solution that improves the efficiency of the treatment of stainless steel welds and surfaces.
Disclosure of Invention
The invention mainly aims to provide a stainless steel welding seam and surface treatment method, a device, terminal equipment and a storage medium, aiming at improving the treatment efficiency of the stainless steel welding seam and the surface.
In order to achieve the above object, the present invention provides a stainless steel weld and a surface treatment method, comprising:
Acquiring field information of a stainless steel welding line and the surface to be treated;
Gear adjustment is carried out on processing equipment according to the field information, wherein the processing equipment comprises a grounding wire clamp, an operation brush head and an inverter;
Connecting the grounding wire clamp with the stainless steel welding seam and the surface to be treated, and switching on an operation power supply of the treatment equipment so as to enable the operation brush head to alternately change with the electrode of the stainless steel welding seam and the surface to be treated through an inverter in the treatment equipment;
And brushing the pre-configured electrolyte on the welding seam and the surface of the stainless steel to be treated through the operation brush head so as to remove the oxides on the welding seam and the surface of the stainless steel to be treated and generate a passivation film.
Optionally, before the step of obtaining the field information of the weld joint and the surface of the stainless steel to be treated, the method further comprises:
And pre-treating the stainless steel welding seam and the surface to be treated to remove impurities of the stainless steel welding seam and the surface to be treated, wherein the impurities comprise one or more of oxide scale, water stain, rust and oil stain.
Optionally, the step of performing gear adjustment on the processing device according to the site information includes:
Adjusting a gear mode of the treatment equipment according to the stainless steel welding line to be treated and the flatness of the surface in the field information, wherein the gear mode comprises a brush pickling mode and a liner pickling mode;
And adjusting gear parameters of the processing equipment according to the area of the stainless steel weld joint to be processed and the surface in the field information.
Optionally, the step of connecting the ground clip with the stainless steel weld joint and the surface to be treated and switching on an operation power supply of the treatment device so as to enable the operation brush head to be alternately changed with the electrode of the stainless steel weld joint and the surface to be treated through an inverter in the treatment device includes:
Connecting the grounding wire clamp with the stainless steel welding seam to be treated and the surface;
switching on a power supply of the processing equipment to generate current between the stainless steel welding seam and the surface to be processed, which are connected with the grounding wire clamp, and the operation brush head;
And controlling the current through an inverter in the processing equipment so as to enable the cathode and the anode between the operation brush head and the stainless steel welding line to be processed and between the operation brush head and the surface to be processed to be alternately changed.
Optionally, the step of brushing the pre-configured electrolyte on the stainless steel welding seam and the surface to be treated through the operation brush head comprises the following steps:
Dipping the electrolyte through the operation brush head, wherein the operation brush head comprises a liner and a brush, and the electrolyte comprises citric acid and phosphoric acid;
and the operation brush head dipped with the electrolyte is contacted with the stainless steel welding seam and the surface to be treated, and the operation brush head is pushed according to a preset speed so as to coat the stainless steel welding seam and the surface to be treated to obtain an electrolyte layer.
Optionally, the step of contacting the operation brush head dipped with the electrolyte with the stainless steel welding seam and the surface to be treated and pushing the operation brush head according to a preset speed to obtain the electrolyte layer after the step of brushing the stainless steel welding seam and the surface to be treated further comprises:
judging whether the height of the electrolyte layer is lower than a preset height;
And if the height of the electrolyte layer is lower than the preset height, supplementing the electrolyte through the operation brush head so that the height of the electrolyte layer reaches the preset height.
Optionally, the step of brushing the pre-configured electrolyte on the stainless steel welding seam and the surface to be treated through the operation brush head further comprises the following steps:
Washing the stainless steel welding seam and the surface to be treated by adopting desalted water to obtain a washed stainless steel welding seam and the surface;
testing the washed stainless steel welding seam and the surface by test paper to obtain a test result;
judging whether the test result is in a preset range or not;
And if the test result is not in the preset range, returning to the execution step, and flushing the stainless steel welding seam and the surface to be treated by adopting desalted water and the subsequent steps until the test result is in the preset range.
In addition, in order to achieve the above object, the present invention also provides a stainless steel weld and a surface treatment apparatus, comprising:
The acquisition module is used for acquiring the stainless steel welding line to be processed and the field information of the surface;
The adjusting module is used for adjusting the gear of the processing equipment according to the field information, and the processing equipment comprises a grounding wire clamp, an operation brush head and an inverter;
the connecting module is used for connecting the grounding wire clamp with the stainless steel welding seam and the surface to be treated and connecting an operating power supply of the treatment equipment so as to enable the operating brush head to be alternately changed with the electrode of the stainless steel welding seam and the surface to be treated through an inverter in the treatment equipment;
And the brushing module is used for brushing the pre-configured electrolyte on the welding seam and the surface of the stainless steel to be treated through the operation brush head so as to remove the oxides on the welding seam and the surface of the stainless steel to be treated and generate a passivation film.
In addition, in order to achieve the above object, the present invention also provides a terminal device including a memory, a processor, and a stainless steel weld and a surface treatment program stored on the memory and operable on the processor, which when executed by the processor, implements the steps of the stainless steel weld and surface treatment method as described above.
In addition, in order to achieve the above object, the present invention also provides a computer-readable storage medium having stored thereon a stainless steel weld and a surface treatment program which, when executed by a processor, implements the steps of the stainless steel weld and surface treatment method as described above.
The embodiment of the invention provides a stainless steel welding seam and surface treatment method, a device, terminal equipment and a storage medium, wherein the on-site information of the stainless steel welding seam and the surface to be treated is obtained; gear adjustment is carried out on processing equipment according to the field information, wherein the processing equipment comprises a grounding wire clamp, an operation brush head and an inverter; connecting the grounding wire clamp with the stainless steel welding seam and the surface to be treated, and switching on an operation power supply of the treatment equipment so as to enable the operation brush head to alternately change with the electrode of the stainless steel welding seam and the surface to be treated through an inverter in the treatment equipment; and brushing the pre-configured electrolyte on the welding seam and the surface of the stainless steel to be treated through the operation brush head so as to remove the oxides on the welding seam and the surface of the stainless steel to be treated and generate a passivation film. The electrolyte is coated on the stainless steel welding seam and the surface through the operation brush head of the treatment equipment, and electrodes between the treatment equipment and the stainless steel welding seam and the surface are alternately changed under the control of the inverter, so that the electrolyte decomposes oxides on the stainless steel welding seam and the surface, thereby having the deoxidization effect, and simultaneously, the passivation film is rapidly generated through the electrochemical reaction, so that the treatment efficiency of the stainless steel welding seam and the surface is improved.
Drawings
FIG. 1 is a schematic diagram of functional modules of a terminal device to which a stainless steel weld and surface treatment apparatus of the present invention pertains;
FIG. 2 is a schematic flow chart of an exemplary embodiment of a method for welding and surface treatment of stainless steel according to the present invention;
FIG. 3 is a schematic diagram illustrating a specific flow of step S40 in the embodiment of FIG. 2;
FIG. 4 is a schematic view showing an operation mode of dipping an electrolyte by using a gasket according to an embodiment of the present invention;
FIG. 5 is a schematic view showing an operation mode of dipping an electrolyte by using a brush according to an embodiment of the present invention;
FIG. 6 is a schematic diagram of an operation process of applying an electrolyte to a stainless steel weld to be treated and a surface by using an operation brush head in an embodiment of the present invention;
Fig. 7 is a schematic power diagram of a processing device according to an embodiment of the present invention.
The achievement of the objects, functional features and advantages of the present invention will be further described with reference to the accompanying drawings, in conjunction with the embodiments.
Detailed Description
It should be understood that the specific embodiments described herein are for purposes of illustration only and are not intended to limit the scope of the invention.
The main solutions of the embodiments of the present invention are: acquiring field information of a stainless steel weld joint and the surface to be treated; gear adjustment is carried out on processing equipment according to the field information, wherein the processing equipment comprises a grounding wire clamp, an operation brush head and an inverter; connecting the grounding wire clamp with the stainless steel welding seam and the surface to be treated, and switching on an operation power supply of the treatment equipment so as to enable the operation brush head to alternately change with the electrode of the stainless steel welding seam and the surface to be treated through an inverter in the treatment equipment; and brushing the pre-configured electrolyte on the welding seam and the surface of the stainless steel to be treated through the operation brush head so as to remove the oxides on the welding seam and the surface of the stainless steel to be treated and generate a passivation film. The electrolyte is coated on the stainless steel welding seam and the surface through the operation brush head of the treatment equipment, and electrodes between the treatment equipment and the stainless steel welding seam and the surface are alternately changed under the control of the inverter, so that the electrolyte decomposes oxides on the stainless steel welding seam and the surface, thereby having the deoxidization effect, and simultaneously, the passivation film is rapidly generated through the electrochemical reaction, so that the treatment efficiency of the stainless steel welding seam and the surface is improved.
The traditional pickling passivation process mainly adopts nitric acid with strong oxidizing property such as pickling passivation solution or pickling passivation paste as a main agent for chemical treatment, has strong corrosiveness, can generate a large amount of acid mist in the pickling process, has strong irritation and corrosiveness, and operators must wear safety protection tools. Because the stainless steel pool is the restricted space, in order to prevent the acid mist from gathering and causing injury to personnel, the operating personnel adopts alternate system, but can lead to operation interval time to be long, work efficiency reduces.
Taking pickling passivation paste as an example, the main components of the pickling passivation paste are as follows: hf+hno 3; weld surface oxide: fe/Fe 2O3 + NiO. The high acid in the pickling paste plays a role in cleaning dirt, rust, high-temperature oxide and the like on the surface of stainless steel, and the reaction is as follows:
(1) Acid washing process
FeO/Fe2O3+HF+HNO3→Fe3++F-+NOX↑+H2O
Ni/NiO+HF+HNO3→Ni2++F-+NOX↑+H2O
Wherein NOX gas is harmful gas in the pickling passivation process.
(2) Passivation process
The pickling passivation paste can oxidize Cr element in the stainless steel (Cr is preferentially oxidized compared with Fe with the chemical property), and a Cr 2O3 compact protective film is generated on the surface of the stainless steel to isolate the stainless steel from air.
Cr+HF+HNO3→Cr2O3+F-+NOX↑+H2O
(3) Cleaning process
After the pickling passivation paste is brushed for 1 hour, the cleaning water is used for repeatedly flushing and wiping clean, and if the pickling paste is not flushed clean, the stainless steel is continuously oxidized, and the following chemical reaction occurs:
Fe+HF+HNO3→Fe3++F-+NOX↑+H2O
The solution containing iron ions forms a "rust return" when dried.
In order to ensure the safety of stainless steel pickling and passivation operators and improve the working efficiency of pickling and passivation, the invention provides a solution, and the reaction process of oxide on the surface of stainless steel and electrolyte is quickened through electrolytic reaction, so that the deoxidization effect is achieved and the working efficiency can be improved. Because the main components of the electrolyte are weak acids (citric acid and phosphoric acid), compared with strong acids (hydrofluoric acid and nitric acid), the electrolyte reduces the risks of personnel operation health and safety, and can be cleaned by only a small amount of neutralization liquid and B-stage desalted water after use, thereby reducing the wastewater discharge and the pollution discharge cost.
Specifically, referring to fig. 1, fig. 1 is a schematic diagram of functional modules of a terminal device to which a stainless steel weld and surface treatment apparatus of the present invention belongs. The stainless steel welding seam and surface treatment device can be a device which is independent of the terminal equipment and can carry out stainless steel welding seam and surface treatment, and the device can be carried on the terminal equipment in a form of hardware or software. The terminal equipment can be an intelligent mobile terminal with a data processing function such as a mobile phone and a tablet personal computer, and can also be a fixed terminal equipment or a server with a data processing function.
In this embodiment, the terminal device of the stainless steel welding seam and the surface treatment device at least includes an output module 110, a processor 120, a memory 130, and a communication module 140.
The memory 130 stores an operating system and a stainless steel welding seam and surface treatment program, and the stainless steel welding seam and surface treatment device can store the acquired information such as the field information of the stainless steel welding seam and the surface to be treated in the memory 130; the output module 110 may be a display screen or the like. The communication module 140 may include a WIFI module, a mobile communication module, a bluetooth module, and the like, and communicates with an external device or a server through the communication module 140.
Wherein the stainless steel weld and surface treatment program in the memory 130 when executed by the processor performs the steps of:
Acquiring field information of a stainless steel welding line and the surface to be treated;
Gear adjustment is carried out on processing equipment according to the field information, wherein the processing equipment comprises a grounding wire clamp, an operation brush head and an inverter;
Connecting the grounding wire clamp with the stainless steel welding seam and the surface to be treated, and switching on an operation power supply of the treatment equipment so as to enable the operation brush head to alternately change with the electrode of the stainless steel welding seam and the surface to be treated through an inverter in the treatment equipment;
And brushing the pre-configured electrolyte on the welding seam and the surface of the stainless steel to be treated through the operation brush head so as to remove the oxides on the welding seam and the surface of the stainless steel to be treated and generate a passivation film.
Further, the stainless steel weld and surface treatment program in the memory 130 when executed by the processor also performs the steps of:
And pre-treating the stainless steel welding seam and the surface to be treated to remove impurities of the stainless steel welding seam and the surface to be treated, wherein the impurities comprise one or more of oxide scale, water stain, rust and oil stain.
Further, the stainless steel weld and surface treatment program in the memory 130 when executed by the processor also performs the steps of:
Adjusting a gear mode of the treatment equipment according to the stainless steel welding line to be treated and the flatness of the surface in the field information, wherein the gear mode comprises a brush pickling mode and a liner pickling mode;
And adjusting gear parameters of the processing equipment according to the area of the stainless steel weld joint to be processed and the surface in the field information.
Further, the stainless steel weld and surface treatment program in the memory 130 when executed by the processor also performs the steps of:
Connecting the grounding wire clamp with the stainless steel welding seam to be treated and the surface;
switching on a power supply of the processing equipment to generate current between the stainless steel welding seam and the surface to be processed, which are connected with the grounding wire clamp, and the operation brush head;
And controlling the current through an inverter in the processing equipment so as to enable the cathode and the anode between the operation brush head and the stainless steel welding line to be processed and between the operation brush head and the surface to be processed to be alternately changed.
Further, the stainless steel weld and surface treatment program in the memory 130 when executed by the processor also performs the steps of:
Dipping the electrolyte through the operation brush head, wherein the operation brush head comprises a liner and a brush, and the electrolyte comprises citric acid and phosphoric acid;
and the operation brush head dipped with the electrolyte is contacted with the stainless steel welding seam and the surface to be treated, and the operation brush head is pushed according to a preset speed so as to coat the stainless steel welding seam and the surface to be treated to obtain an electrolyte layer.
Further, the stainless steel weld and surface treatment program in the memory 130 when executed by the processor also performs the steps of:
judging whether the height of the electrolyte layer is lower than a preset height;
And if the height of the electrolyte layer is lower than the preset height, supplementing the electrolyte through the operation brush head so that the height of the electrolyte layer reaches the preset height.
Further, the stainless steel weld and surface treatment program in the memory 130 when executed by the processor also performs the steps of:
Washing the stainless steel welding seam and the surface to be treated by adopting desalted water to obtain a washed stainless steel welding seam and the surface;
testing the washed stainless steel welding seam and the surface by test paper to obtain a test result;
judging whether the test result is in a preset range or not;
And if the test result is not in the preset range, returning to the execution step, and flushing the stainless steel welding seam and the surface to be treated by adopting desalted water and the subsequent steps until the test result is in the preset range.
According to the technical scheme, the method comprises the steps of obtaining field information of a stainless steel welding line to be processed and the surface; gear adjustment is carried out on processing equipment according to the field information, wherein the processing equipment comprises a grounding wire clamp, an operation brush head and an inverter; connecting the grounding wire clamp with the stainless steel welding seam and the surface to be treated, and switching on an operation power supply of the treatment equipment so as to enable the operation brush head to alternately change with the electrode of the stainless steel welding seam and the surface to be treated through an inverter in the treatment equipment; and brushing the pre-configured electrolyte on the welding seam and the surface of the stainless steel to be treated through the operation brush head so as to remove the oxides on the welding seam and the surface of the stainless steel to be treated and generate a passivation film. The electrolyte is coated on the stainless steel welding seam and the surface through the operation brush head of the treatment equipment, and electrodes between the treatment equipment and the stainless steel welding seam and the surface are alternately changed under the control of the inverter, so that the electrolyte decomposes oxides on the stainless steel welding seam and the surface, thereby having the deoxidization effect, and simultaneously, the passivation film is rapidly generated through the electrochemical reaction, so that the treatment efficiency of the stainless steel welding seam and the surface is improved.
The method embodiment of the invention is proposed based on the above-mentioned terminal equipment architecture but not limited to the above-mentioned architecture.
The main execution body of the method of the embodiment may be a stainless steel welding seam and surface treatment device or terminal equipment, and the embodiment uses the stainless steel welding seam and the surface treatment device as an example.
Referring to fig. 2, fig. 2 is a schematic flow chart of an exemplary embodiment of a method for welding and surface treatment of stainless steel according to the present invention. The stainless steel welding seam and surface treatment method comprises the following steps:
s10, acquiring field information of a stainless steel welding line to be processed and the surface;
The stainless steel weld and the surface are pretreated before being treated:
And pre-treating the stainless steel welding seam and the surface to be treated to remove impurities of the stainless steel welding seam and the surface to be treated, wherein the impurities comprise one or more of oxide scale, water stain, rust and oil stain.
After the welding of the stainless steel pool is finished, a stainless steel wire brush is adopted to brush a bright weld joint, oxide scales are removed, when marks such as water marks, rust and the like exist on the surface of a component, a stainless steel special wire wheel or a gauze grinding wheel is adopted to polish the surface, the marks are removed, and degreasing treatment is carried out on the part with the oil marks.
And further acquiring field information of the stainless steel welding seam and the surface to be treated, wherein the field information mainly comprises the area and the flatness of the stainless steel welding seam and the surface to be treated so as to be convenient for adjusting the gear of the treatment equipment.
Step S20, gear adjustment is carried out on processing equipment according to the field information, wherein the processing equipment comprises a grounding wire clamp, an operation brush head and an inverter;
after the information such as the area and the flatness of the welding seam and the surface of the stainless steel to be processed is obtained, the power supply of the equipment is connected, and then the gear adjustment is carried out on the processing equipment:
Adjusting a gear mode of the treatment equipment according to the stainless steel welding line to be treated and the flatness of the surface in the field information, wherein the gear mode comprises a brush pickling mode and a liner pickling mode;
And adjusting gear parameters of the processing equipment according to the area of the stainless steel weld joint to be processed and the surface in the field information.
For a smoother stainless steel weld joint and surface to be treated, the gear can be adjusted to a 'hairbrush pickling' gear, namely, the gear is selected to be PICKLING BRUSH in a panel through MODE, the machine parameters are preset for 10, and the gear can be properly adjusted through a '+/-' gear according to the field condition; the 'lining pickling' gear can be used when the back heat affected zone with a slightly larger stainless steel area is treated, namely, the gear is selected to be PICKLING PAD on the panel through MODE, the machine parameters are preset 18, and the machine parameters can be properly adjusted through the '+/-' gear according to the field condition.
Step S30, connecting the grounding wire clamp with the stainless steel welding seam and the surface to be treated, and switching on an operation power supply of the treatment equipment so as to enable the operation brush head to be alternately changed with the electrode of the stainless steel welding seam and the surface to be treated through an inverter in the treatment equipment;
Connecting the grounding wire clamp with the stainless steel welding seam to be treated and the surface;
switching on a power supply of the processing equipment to generate current between the stainless steel welding seam and the surface to be processed, which are connected with the grounding wire clamp, and the operation brush head;
And controlling the current through an inverter in the processing equipment so as to enable the cathode and the anode between the operation brush head and the stainless steel welding line to be processed and between the operation brush head and the surface to be processed to be alternately changed.
Specifically, when the gear of the processing equipment is adjusted, an operating power supply can be switched on, and after the indicator lamp is on, the operation can be performed by dipping in electrolyte. During operation, the grounding wire clamp is connected to the stainless steel welding seam and the proper position of the surface, so that under the control of the inverter, the cathode and the anode between the treatment equipment and the stainless steel welding seam and between the treatment equipment and the surface are alternately changed, and the electrolyte is subjected to electrolytic reaction and electrochemical reaction.
And S40, brushing the pre-configured electrolyte on the welding seam and the surface of the stainless steel to be treated through the operation brush head so as to remove the oxides on the welding seam and the surface of the stainless steel to be treated and generate a passivation film.
In the operation process, the operation brush head is dipped with the pre-configured electrolyte and then contacts the stainless steel welding seam and the surface to be treated, the stainless steel welding seam and the surface are painted back and forth at a uniform speed, the electrolyte decomposes oxides on the stainless steel welding seam and the surface, thereby playing a role in deoxidization, and meanwhile, the passivation film is rapidly generated through the electrochemical reaction.
In addition, the carbon fiber of the brush head has loss in the use process, and the brush head is preferably kept at the length of 1 cm when the welding line is cleaned. The length of the carbon fiber brush head can be controlled by the extension and retraction of the outer insulating sleeve. After the treatment is completed, the stainless steel weld joint and the surface are also required to be washed:
Washing the stainless steel welding seam and the surface to be treated by adopting desalted water to obtain a washed stainless steel welding seam and the surface;
testing the washed stainless steel welding seam and the surface by test paper to obtain a test result;
judging whether the test result is in a preset range or not;
And if the test result is not in the preset range, returning to the execution step, and flushing the stainless steel welding seam and the surface to be treated by adopting desalted water and the subsequent steps until the test result is in the preset range.
The stainless steel welding seam and the surface after the B-stage desalted water flushing treatment are adopted, and then the flushing surface is tested by using pH test paper, so that the pH value is ensured to be more than or equal to 6 and less than or equal to 8.
In the embodiment, the on-site information of the stainless steel welding line and the surface to be treated is obtained; gear adjustment is carried out on processing equipment according to the field information, wherein the processing equipment comprises a grounding wire clamp, an operation brush head and an inverter; connecting the grounding wire clamp with the stainless steel welding seam and the surface to be treated, and switching on an operation power supply of the treatment equipment so as to enable the operation brush head to alternately change with the electrode of the stainless steel welding seam and the surface to be treated through an inverter in the treatment equipment; and brushing the pre-configured electrolyte on the welding seam and the surface of the stainless steel to be treated through the operation brush head so as to remove the oxides on the welding seam and the surface of the stainless steel to be treated and generate a passivation film. The electrolyte is coated on the stainless steel welding seam and the surface through the operation brush head of the treatment equipment, and electrodes between the treatment equipment and the stainless steel welding seam and the surface are alternately changed under the control of the inverter, so that the electrolyte decomposes oxides on the stainless steel welding seam and the surface, thereby having the deoxidization effect, and simultaneously, the passivation film is rapidly generated through the electrochemical reaction, so that the treatment efficiency of the stainless steel welding seam and the surface is improved.
Referring to fig. 3, fig. 3 is a specific flowchart of step S40 in the embodiment of fig. 2. In this embodiment, the step S40 of brushing the pre-configured electrolyte on the stainless steel weld and the surface to be treated by the operation brush head to remove the oxide on the stainless steel weld and the surface to be treated and generate the passivation film includes:
Step S401, dipping the electrolyte through the operation brush head, wherein the operation brush head comprises a liner and a brush, and the electrolyte comprises citric acid and phosphoric acid;
In the operation process, the operation brush head is adopted to dip the pre-configured electrolyte, the operation brush head comprises a liner and a brush, the main components in the electrolyte are citric acid and phosphoric acid, referring to fig. 4 and 5, fig. 4 is a schematic diagram of the operation mode of dipping the electrolyte by the liner in the embodiment of the invention, and fig. 5 is a schematic diagram of the operation mode of dipping the electrolyte by the brush in the embodiment of the invention, the operation brush head is mainly weak acid, compared with strong acid (hydrofluoric acid and nitric acid), the risk of personnel operation health and safety is reduced, and after the operation brush head is used, only a small amount of neutralization solution and B-stage desalted water are needed to be cleaned, so that the waste water discharge is reduced, and the pollution discharge cost is reduced.
Step S402, the operation brush head dipped with the electrolyte is contacted with the stainless steel welding seam and the surface to be treated, and the operation brush head is pushed in according to a preset speed so as to coat the stainless steel welding seam and the surface to be treated to obtain an electrolyte layer.
Referring to fig. 6, fig. 6 is a schematic diagram of an operation process of brushing an electrolyte on a stainless steel welding seam and a surface to be treated by using an operation brush head in an embodiment of the present invention, as shown in fig. 6, after the operation brush head dips in the electrolyte, the operation brush head contacts the stainless steel welding seam and the surface to be treated, and brushes back and forth at a uniform speed, and a propulsion speed is kept about 1m to 2m per minute, so that the stainless steel welding seam and the surface to be treated are coated with the electrolyte layer, and in addition, the treatment process further includes:
judging whether the height of the electrolyte layer is lower than a preset height;
And if the height of the electrolyte layer is lower than the preset height, supplementing the electrolyte through the operation brush head so that the height of the electrolyte layer reaches the preset height.
During cleaning, the amount of the cleaning liquid is observed, and a layer of liquid with the same height as the welding line is preferably reserved on the surface of the welding line. If the liquid amount is reduced, the operation brush head is used for dipping the electrolyte for supplementing the liquid.
In the process, when the stainless steel welding line and the surface are subjected to cathode reaction, hydrogen ions are accumulated on the surface to generate hydrogen gas to accelerate the mechanical stripping reaction of oxide:
2H++e-→H2
when the surface of the stainless steel weld is subjected to anodic reaction, the electrochemically acting part starts anodic dissolution reaction, and dissolves away from the surface of the stainless steel:
Fe/Fe2O3→Fe3+e-+O2↑;Ni/NiO→Ni2+e-+O2↑;
After the oxide on the surface of the stainless steel weld joint is cleaned, the oxidant component in the electrolyte simultaneously starts to help the Cr element in the stainless steel to be oxidized preferentially, so that a passivation film is formed:
Cr→Cr3++e-;Cr3++e-+O2→Cr2O3
According to the scheme, the electrolyte is dipped through the operation brush head, wherein the operation brush head comprises a liner and a brush, and the electrolyte comprises citric acid and phosphoric acid; and the operation brush head dipped with the electrolyte is contacted with the stainless steel welding seam and the surface to be treated, and the operation brush head is pushed according to a preset speed so as to coat the stainless steel welding seam and the surface to be treated to obtain an electrolyte layer. By adopting the operation brush head to dip the electrolyte with weak acid as the main component, compared with strong acid (hydrofluoric acid and nitric acid), the operation health and safety risk of personnel are reduced, and after the operation, the operation brush head can be cleaned by only needing a small amount of neutralization liquid and B-stage desalted water, so that the wastewater discharge is reduced, and the pollution discharge cost is reduced. Under the control of the inverter, the cathode and the anode between the stainless steel welding seam and the surface and the equipment electrode are quickly alternated, and the electrolyte decomposes the oxide on the stainless steel welding seam and the surface, thereby playing a role in deoxidization, and simultaneously, the electrochemical reaction quickly generates a passivation film. The treatment efficiency of the stainless steel welding seam and the surface is improved.
In addition, the embodiment of the invention also provides a stainless steel welding seam and surface treatment device, which comprises:
The acquisition module is used for acquiring the stainless steel welding line to be processed and the field information of the surface;
The adjusting module is used for adjusting the gear of the processing equipment according to the field information, and the processing equipment comprises a grounding wire clamp, an operation brush head and an inverter;
the connecting module is used for connecting the grounding wire clamp with the stainless steel welding seam and the surface to be treated and connecting an operating power supply of the treatment equipment so as to enable the operating brush head to be alternately changed with the electrode of the stainless steel welding seam and the surface to be treated through an inverter in the treatment equipment;
And the brushing module is used for brushing the pre-configured electrolyte on the welding seam and the surface of the stainless steel to be treated through the operation brush head so as to remove the oxides on the welding seam and the surface of the stainless steel to be treated and generate a passivation film.
After the welding of the stainless steel pool is finished, a stainless steel wire brush is adopted to brush a bright weld joint, oxide scales are removed, when marks such as water marks, rust and the like exist on the surface of a component, a stainless steel special wire wheel or a gauze grinding wheel is adopted to polish the surface, the marks are removed, and degreasing treatment is carried out on the part with the oil marks.
Further, turning on the power supply of the processing device, referring to fig. 7, fig. 7 is a schematic power supply diagram of the processing device in the embodiment of the present invention, after the power supply is turned on, the gear of the processing device is adjusted by the control panel, and during the processing operation, the adjusting position is adjusted to the "brush pickling" gear, that is, the gear is selected to the PICKLING BRUSH icon gear by MODE in the panel, and the machine parameters are preset to 10, so that the gear can be properly adjusted by the "+/-" gear according to the on-site situation; the 'lining pickling' gear can be used when the back heat affected zone with a slightly larger stainless steel area is treated, namely, the gear is selected to be PICKLING PAD on the panel through MODE, the machine parameters are preset 18, and the machine parameters can be properly adjusted through the '+/-' gear according to the field condition. After the mode is adjusted, the operation power supply is switched on, and the indicator lamp can dip in electrolyte for operation after being lightened.
During operation, the grounding wire is clamped at a proper position, the brush head is contacted with the stainless steel welding seam and the surface to be treated after being dipped with electrolyte, the stainless steel welding seam and the surface to be treated are painted back and forth at a uniform speed, and the propelling speed is kept to be about 1-2 m per minute. During cleaning, the amount of the cleaning liquid is observed, and a layer of liquid with the same height as the welding line is preferably reserved on the surface of the welding line. If the liquid amount is reduced, the brush head is used for dipping liquid and supplementing liquid. The carbon fiber of the brush head has loss in the use process, and the brush head is preferably kept at the length of 1 cm when the welding line is cleaned. The length of the carbon fiber brush head can be controlled by the extension and retraction of the outer insulating sleeve. After the treatment is finished, the stainless steel welding seam and the surface after the treatment are washed by using B-stage desalted water, and the washing surface is tested by using PH test paper, so that the PH value is ensured to be more than or equal to 6 and less than or equal to 8.
In the embodiment, through an electrochemical pickling passivation process, electrolyte is subjected to electrolytic reaction under the action of current, and under the control of an inverter, a cathode and an anode between a stainless steel welding seam and a surface and an equipment electrode are rapidly alternated, so that the electrolyte decomposes oxides on the stainless steel welding seam and the surface, thereby playing a role in deoxidization, and meanwhile, a passivation film is rapidly generated through the electrochemical reaction. The defects caused by the traditional pickling passivation technology for treating the welding seam and the surface of the stainless steel pool of the nuclear power station are successfully overcome, and the method comprises the steps of reducing the safety risk of operators, reducing the damage to the environment, improving the efficiency of pickling passivation operation and the like.
In addition, the embodiment of the invention also provides a terminal device, which comprises a memory, a processor and a stainless steel welding seam and surface treatment program stored on the memory and capable of running on the processor, wherein the steps of the stainless steel welding seam and surface treatment method are realized when the stainless steel welding seam and surface treatment program is executed by the processor.
Because all the technical schemes of all the embodiments are adopted when the stainless steel welding seam and the surface treatment program are executed by the processor, the stainless steel welding seam and the surface treatment program at least have all the beneficial effects brought by all the technical schemes of all the embodiments, and are not described in detail herein.
In addition, the embodiment of the invention also provides a computer readable storage medium, wherein the computer readable storage medium is stored with a stainless steel welding seam and a surface treatment program, and the stainless steel welding seam and the surface treatment program realize the steps of the stainless steel welding seam and the surface treatment method when being executed by a processor.
Because all the technical schemes of all the embodiments are adopted when the stainless steel welding seam and the surface treatment program are executed by the processor, the stainless steel welding seam and the surface treatment program at least have all the beneficial effects brought by all the technical schemes of all the embodiments, and are not described in detail herein.
Compared with the prior art, the stainless steel welding seam and surface treatment method, the device, the terminal equipment and the storage medium provided by the embodiment of the invention are used for acquiring the field information of the stainless steel welding seam and the surface to be treated; gear adjustment is carried out on processing equipment according to the field information, wherein the processing equipment comprises a grounding wire clamp, an operation brush head and an inverter; connecting the grounding wire clamp with the stainless steel welding seam and the surface to be treated, and switching on an operation power supply of the treatment equipment so as to enable the operation brush head to alternately change with the electrode of the stainless steel welding seam and the surface to be treated through an inverter in the treatment equipment; and brushing the pre-configured electrolyte on the welding seam and the surface of the stainless steel to be treated through the operation brush head so as to remove the oxides on the welding seam and the surface of the stainless steel to be treated and generate a passivation film. The electrolyte is coated on the stainless steel welding seam and the surface through the operation brush head of the treatment equipment, and electrodes between the treatment equipment and the stainless steel welding seam and the surface are alternately changed under the control of the inverter, so that the electrolyte decomposes oxides on the stainless steel welding seam and the surface, thereby having the deoxidization effect, and simultaneously, the passivation film is rapidly generated through the electrochemical reaction, so that the treatment efficiency of the stainless steel welding seam and the surface is improved.
It should be noted that, in this document, the terms "comprises," "comprising," or any other variation thereof, are intended to cover a non-exclusive inclusion, such that a process, method, article, or system that comprises a list of elements does not include only those elements but may include other elements not expressly listed or inherent to such process, method, article, or system. Without further limitation, an element defined by the phrase "comprising one … …" does not exclude the presence of other like elements in a process, method, article, or system that comprises the element.
The foregoing embodiment numbers of the present application are merely for the purpose of description, and do not represent the advantages or disadvantages of the embodiments.
From the above description of the embodiments, it will be clear to those skilled in the art that the above-described embodiment method may be implemented by means of software plus a necessary general hardware platform, but of course may also be implemented by means of hardware, but in many cases the former is a preferred embodiment. Based on such understanding, the technical solution of the present application may be embodied essentially or in a part contributing to the prior art in the form of a software product stored in a storage medium (e.g. ROM/RAM, magnetic disk, optical disk) as above, comprising instructions for causing a terminal device (which may be a mobile phone, a computer, a server, a controlled terminal, or a network device, etc.) to perform the method of each embodiment of the present application.
The foregoing description is only of the preferred embodiments of the present invention, and is not intended to limit the scope of the invention, but rather is intended to cover any equivalents of the structures or equivalent processes disclosed herein or in the alternative, which may be employed directly or indirectly in other related arts.

Claims (9)

1. The method for treating the stainless steel welding seam and the surface is characterized by comprising the following steps of:
Acquiring field information of a stainless steel welding line and the surface to be treated;
Gear adjustment is carried out on processing equipment according to the field information, wherein the processing equipment comprises a grounding wire clamp, an operation brush head and an inverter;
Connecting the grounding wire clamp with the stainless steel welding seam and the surface to be treated, and switching on an operation power supply of the treatment equipment so as to enable the polarities of the operation brush head and the electrode of the stainless steel welding seam and the surface to be treated to be alternately changed through an inverter in the treatment equipment;
Coating the pre-configured electrolyte on the stainless steel welding seam and the surface to be treated through the operation brush head so as to remove the oxides on the stainless steel welding seam and the surface to be treated and generate a passivation film;
the step of adjusting the gear of the processing equipment according to the site information comprises the following steps:
Adjusting a gear mode of the treatment equipment according to the stainless steel welding line to be treated and the flatness of the surface in the field information, wherein the gear mode comprises a brush pickling mode and a liner pickling mode;
And adjusting gear parameters of the processing equipment according to the area of the stainless steel weld joint to be processed and the surface in the field information.
2. The method for processing a stainless steel weld and a surface according to claim 1, wherein the step of obtaining field information of the stainless steel weld and the surface to be processed further comprises, before:
And pre-treating the stainless steel welding seam and the surface to be treated to remove impurities of the stainless steel welding seam and the surface to be treated, wherein the impurities comprise one or more of oxide scale, water stain, rust and oil stain.
3. The method of treating a stainless steel weld and a surface according to claim 1, wherein the step of connecting the ground clip to the stainless steel weld and the surface to be treated and turning on an operating power supply of the treating apparatus to alternately change polarities of the operating brush head and the electrode of the stainless steel weld and the surface to be treated by an inverter in the treating apparatus comprises:
Connecting the grounding wire clamp with the stainless steel welding seam to be treated and the surface;
switching on a power supply of the processing equipment to generate current between the stainless steel welding seam and the surface to be processed, which are connected with the grounding wire clamp, and the operation brush head;
And controlling the current through an inverter in the processing equipment so as to enable the cathode and the anode between the operation brush head and the stainless steel welding line to be processed and between the operation brush head and the surface to be processed to be alternately changed.
4. The method of claim 1, wherein the step of applying a pre-configured electrolyte to the stainless steel weld and surface to be treated by the operating brush head comprises:
Dipping the electrolyte through the operation brush head, wherein the operation brush head comprises a liner and a brush, and the electrolyte comprises citric acid and phosphoric acid;
and the operation brush head dipped with the electrolyte is contacted with the stainless steel welding seam and the surface to be treated, and the operation brush head is pushed according to a preset speed so as to coat the stainless steel welding seam and the surface to be treated to obtain an electrolyte layer.
5. The method for treating a stainless steel weld and a surface according to claim 4, wherein the step of contacting the operation brush head dipped with the electrolyte with the stainless steel weld and the surface to be treated and advancing the operation brush head according to a predetermined speed to obtain an electrolyte layer after the step of coating the stainless steel weld and the surface to be treated further comprises:
judging whether the height of the electrolyte layer is lower than a preset height;
And if the height of the electrolyte layer is lower than the preset height, supplementing the electrolyte through the operation brush head so that the height of the electrolyte layer reaches the preset height.
6. The method of claim 1, wherein the step of applying a pre-configured electrolyte to the stainless steel weld and surface to be treated by the operating brush head further comprises:
Washing the stainless steel welding seam and the surface to be treated by adopting desalted water to obtain a washed stainless steel welding seam and the surface;
testing the washed stainless steel welding seam and the surface by test paper to obtain a test result;
judging whether the test result is in a preset range or not;
And if the test result is not in the preset range, returning to the execution step, and flushing the stainless steel welding seam and the surface to be treated by adopting desalted water and the subsequent steps until the test result is in the preset range.
7. A stainless steel weld and surface treatment apparatus, comprising:
The acquisition module is used for acquiring the stainless steel welding line to be processed and the field information of the surface;
The adjusting module is used for adjusting the gear of the processing equipment according to the field information, and the processing equipment comprises a grounding wire clamp, an operation brush head and an inverter;
The connecting module is used for connecting the grounding wire clamp with the stainless steel welding seam and the surface to be treated and connecting an operating power supply of the treatment equipment so as to enable the polarities of the operating brush head and the electrode of the stainless steel welding seam and the surface to be treated to be alternately changed through an inverter in the treatment equipment;
The brushing module is used for brushing the pre-configured electrolyte on the stainless steel welding seam and the surface to be treated through the operation brush head so as to remove the oxides on the stainless steel welding seam and the surface to be treated and generate a passivation film;
The adjustment module is also for: adjusting a gear mode of the treatment equipment according to the stainless steel welding line to be treated and the flatness of the surface in the field information, wherein the gear mode comprises a brush pickling mode and a liner pickling mode; and adjusting gear parameters of the processing equipment according to the area of the stainless steel weld joint to be processed and the surface in the field information.
8. A terminal device, characterized in that it comprises a memory, a processor and a stainless steel weld and surface treatment program stored on the memory and executable on the processor, which when executed by the processor realizes the steps of the stainless steel weld and surface treatment method according to any one of claims 1-6.
9. A computer-readable storage medium, characterized in that the computer-readable storage medium has stored thereon a stainless steel weld and surface treatment program, which when executed by a processor, implements the steps of the stainless steel weld and surface treatment method according to any one of claims 1-6.
CN202210143494.3A 2022-02-16 2022-02-16 Stainless steel welding seam and surface treatment method and device, terminal equipment and storage medium Active CN114561685B (en)

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