CN114561116A - Marble and granite surface anti-skid treatment fluid and preparation method thereof - Google Patents

Marble and granite surface anti-skid treatment fluid and preparation method thereof Download PDF

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Publication number
CN114561116A
CN114561116A CN202210331117.2A CN202210331117A CN114561116A CN 114561116 A CN114561116 A CN 114561116A CN 202210331117 A CN202210331117 A CN 202210331117A CN 114561116 A CN114561116 A CN 114561116A
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China
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percent
marble
treatment fluid
granite
plastic container
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CN202210331117.2A
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Chinese (zh)
Inventor
张佳
张德田
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Shanghai Jiadeli Non Slip Protection Technology Co ltd
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Shanghai Jiadeli Non Slip Protection Technology Co ltd
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Priority to CN202210331117.2A priority Critical patent/CN114561116A/en
Publication of CN114561116A publication Critical patent/CN114561116A/en
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    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/60Additives non-macromolecular
    • C09D7/61Additives non-macromolecular inorganic
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/60Additives non-macromolecular
    • C09D7/63Additives non-macromolecular organic
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/65Additives macromolecular

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Paints Or Removers (AREA)

Abstract

The invention relates to the technical field of anti-skid treatment fluid, and discloses marble and granite surface anti-skid treatment fluid and a preparation method thereof in order to solve the problem that the existing floor tile anti-skid treatment fluid is poor in anti-skid effect when in use, wherein the marble and granite surface anti-skid treatment fluid comprises the following components in percentage by weight: 48.5 to 80.5 percent of deionized water, 18.3 to 37 percent of fruit acid, 0.35 to 3.5 percent of acetic acid, 0.31 to 3.5 percent of cationic surfactant, 0.24 to 3.5 percent of nonionic surfactant, 0.2 to 2.0 percent of inorganic corrosion inhibitor, 0.1 to 1.0 percent of cosolvent and 1.0 percent of defoaming agent. The anti-skid treatment fluid for the surfaces of the marble and the granite, prepared by the invention, can effectively play an anti-skid effect when applied to the marble and the granite, and improves the use safety of the marble and the granite.

Description

Marble and granite surface anti-skid treatment fluid and preparation method thereof
Technical Field
The invention relates to the technical field of anti-skid treatment fluid, in particular to marble and granite surface anti-skid treatment fluid and a preparation method thereof.
Background
The marble, granite and other stones are often applied to the floor tile manufacturing, and have excellent properties of hardness, pressure resistance, wear resistance, moisture resistance and the like. Some ceramic tiles are glazed, have decorative effects, are mostly used for the ground and floor of public buildings and civil buildings, and the surface of the ceramic tiles made of marble and granite needs to be coated with protective agents, anti-slip agents and the like when in use, so as to ensure the waterproof, antifouling and anti-slip effects of the ceramic tiles, but the anti-slip treatment liquid on the surfaces of the existing marble and granite has the problem of poor anti-slip effect when in use.
Disclosure of Invention
The invention aims to solve the defects in the prior art and provides a marble and granite surface anti-skid treatment fluid and a preparation method thereof.
In order to achieve the purpose, the invention adopts the following technical scheme:
the marble and granite surface antiskid treatment fluid comprises the following components in percentage by weight: 48.5 to 80.5 percent of deionized water, 18.3 to 37 percent of fruit acid, 0.35 to 3.5 percent of acetic acid, 0.31 to 3.5 percent of cationic surfactant, 0.24 to 3.5 percent of nonionic surfactant, 0.2 to 2.0 percent of inorganic corrosion inhibitor, 0.1 to 1.0 percent of cosolvent and 1.0 percent of defoaming agent.
Preferably, the paint comprises the following components in percentage by weight: 50-80% of deionized water, 20-35% of fruit acid, 0.5-3.0% of acetic acid, 0.5-3.0% of cationic surfactant, 0.5-3.0% of nonionic surfactant, 0.6-1.5% of inorganic corrosion inhibitor, 0.2-0.8% of cosolvent and 1.0% of defoaming agent.
Preferably, the paint comprises the following components in percentage by weight: 64% of deionized water, 27.5% of fruit acid, 2.0% of acetic acid, 2.0% of cationic surfactant, 2.2% of nonionic surfactant, 1.1% of inorganic corrosion inhibitor, 0.5% of cosolvent and 1.0% of defoaming agent.
Preferably, the paint comprises the following components in percentage by weight: 60 to 70 percent of deionized water, 25 to 30 percent of fruit acid, 1.5 to 2.5 percent of acetic acid, 1.5 to 2.5 percent of cationic surfactant, 2.0 to 2.5 percent of nonionic surfactant, 1.0 to 1.4 percent of inorganic corrosion inhibitor, 0.3 to 0.8 percent of cosolvent and 1.0 percent of defoaming agent.
Preferably, the surfactant is one of cetyl trimethyl quaternary ammonium bromide and stearyl dimethyl benzyl quaternary ammonium chloride.
Preferably, the nonionic surfactant is one of a polyoxyethylene type, a polyol type, an alkanolamide type, a polyether type, and an amine oxide type.
The preparation method of the marble and granite surface antiskid treatment fluid comprises the following steps:
step 1: heating deionized water and putting into a plastic container;
and 2, step: adding acetic acid into a plastic container and uniformly stirring;
and step 3: adding fruit acid into the plastic container and stirring uniformly;
and 4, step 4: and (3) sequentially adding a cationic surfactant, a nonionic surfactant, an inorganic corrosion inhibitor, a cosolvent and a defoaming agent into the plastic container, fully reacting, and filling into the plastic container to obtain the marble and granite surface anti-slip treatment solution.
Preferably, the deionized water is heated to 35 ℃.
Preferably, the stirring time in the step 2 and the step 3 is 5 min.
Preferably, the reaction time in step 4 is 30 min.
The invention has the beneficial effects that: the anti-skid treatment fluid for the surfaces of the marble and the granite, prepared by the invention, can effectively play an anti-skid effect when applied to the marble and the granite, and improves the use safety of the marble and the granite.
Detailed Description
The technical solutions in the embodiments of the present invention will be clearly and completely described below, and it is obvious that the described embodiments are only a part of the embodiments of the present invention, and not all embodiments.
Example 1
Weighing 48.5 g of deionized water, 18.3 g of fruit acid, 0.35 g of acetic acid, 0.31 g of cationic hexadecyl trimethyl quaternary ammonium bromide, 0.24 g of glycerol, 0.2 g of inorganic corrosion inhibitor, 0.1 g of cosolvent and 1.0 g of defoaming agent;
heating deionized water and putting into a plastic container; adding acetic acid into a plastic container, and uniformly stirring for 5 min; adding fruit acid into the plastic container, and stirring for 5 min; and (3) sequentially adding cationic cetyl trimethyl quaternary ammonium bromide, glycerol, an inorganic corrosion inhibitor, a cosolvent and a defoaming agent into a plastic container, fully reacting for 30min, and filling into the plastic container to obtain the marble and granite surface anti-slip treatment solution.
Example 2
Weighing 80.5 g of deionized water, 37 g of tartaric acid, 3.5 g of acetic acid, 3.5 g of cationic hexadecyl trimethyl quaternary ammonium bromide, 3.5 g of glycerol, 2.0 g of inorganic corrosion inhibitor, 1.0 g of cosolvent and 1.0 g of defoamer;
heating deionized water and putting into a plastic container; adding acetic acid into a plastic container, and uniformly stirring for 5 min; adding fruit acid into the plastic container, and stirring for 5 min; and (3) sequentially adding cationic cetyl trimethyl quaternary ammonium bromide, glycerol, an inorganic corrosion inhibitor, a cosolvent and a defoaming agent into a plastic container, fully reacting for 30min, and filling into the plastic container to obtain the marble and granite surface anti-slip treatment solution.
Example 3
Weighing 50 g of deionized water, 20 g of fruit acid, 0.5 g of acetic acid, 0.5 g of cationic hexadecyl trimethyl quaternary ammonium bromide, 0.5 g of glycerol, 0.6 g of inorganic corrosion inhibitor, 0.2 g of cosolvent and 1.0 g of defoaming agent;
heating deionized water and putting into a plastic container; adding acetic acid into a plastic container, and uniformly stirring for 5 min; adding fruit acid into the plastic container, and stirring for 5 min; and (3) sequentially adding cationic hexadecyl trimethyl quaternary ammonium bromide, glycerol, an inorganic corrosion inhibitor, a cosolvent and a defoaming agent into a plastic container, fully reacting for 30min, and then filling into the plastic container to obtain the marble and granite surface anti-skidding treatment liquid.
Example 4
Weighing 80 g of deionized water, 35 g of fruit acid, 3.0 g of acetic acid, 3.0 g of cationic hexadecyl trimethyl quaternary ammonium bromide, 3.0 g of glycerol, 1.5 g of inorganic corrosion inhibitor, 0.8 g of cosolvent and 1.0 g of defoaming agent;
heating deionized water and putting into a plastic container; adding acetic acid into a plastic container, and uniformly stirring for 5 min; adding fruit acid into the plastic container, and stirring for 5 min; and (3) sequentially adding cationic hexadecyl trimethyl quaternary ammonium bromide, glycerol, an inorganic corrosion inhibitor, a cosolvent and a defoaming agent into a plastic container, fully reacting for 30min, and then filling into the plastic container to obtain the marble and granite surface anti-skidding treatment liquid.
Example 5
Weighing 64 g of deionized water, 27.5 g of fruit acid, 2.0 g of acetic acid, 2.0 g of cationic octadecyl dimethyl benzyl quaternary ammonium chloride, 2.2 g of polyether type nonionic surfactant, 1.1 g of inorganic corrosion inhibitor, 0.5 g of cosolvent and 1.0 g of defoaming agent;
heating deionized water and putting into a plastic container; adding acetic acid into a plastic container, and uniformly stirring for 5 min; adding fruit acid into the plastic container, and stirring for 5 min; and (3) sequentially adding cationic octadecyl dimethyl benzyl quaternary ammonium chloride, polyether type nonionic surfactant, inorganic corrosion inhibitor, cosolvent and defoaming agent into a plastic container, fully reacting for 30min, and filling into the plastic container to obtain the marble and granite surface anti-slip treatment solution.
Example 6
Weighing 70 g of deionized water, 30 g of fruit acid, 2.5 g of acetic acid, 2.5 g of cation octadecyl dimethyl benzyl quaternary ammonium chloride, 2.5 g of polyether type nonionic surfactant, 1.4 g of inorganic corrosion inhibitor, 0.8 g of cosolvent and 1.0 g of defoaming agent;
heating deionized water and putting into a plastic container; adding acetic acid into a plastic container, and uniformly stirring for 5 min; adding fruit acid into the plastic container, and stirring for 5 min; and (3) sequentially adding cationic octadecyl dimethyl benzyl quaternary ammonium chloride, polyether type nonionic surfactant, inorganic corrosion inhibitor, cosolvent and defoaming agent into a plastic container, fully reacting for 30min, and filling into the plastic container to obtain the marble and granite surface anti-slip treatment solution.
Example 7
Weighing 60 g of deionized water, 25 g of fruit acid, 1.5 g of acetic acid, 1.5 g of cation octadecyl dimethyl benzyl quaternary ammonium chloride, 2.0 g of polyether type nonionic surfactant, 1.0 g of inorganic corrosion inhibitor, 0.3 g of cosolvent and 1.0 g of defoaming agent;
heating deionized water and putting into a plastic container; adding acetic acid into a plastic container, and uniformly stirring for 5 min; adding fruit acid into the plastic container, and stirring for 5 min; and (3) sequentially adding cationic octadecyl dimethyl benzyl quaternary ammonium chloride, polyether type nonionic surfactant, inorganic corrosion inhibitor, cosolvent and defoaming agent into a plastic container, fully reacting for 30min, and filling into the plastic container to obtain the marble and granite surface anti-slip treatment solution.
Experimental examples 1 to 5 were set to test the anti-slip effect of the anti-slip treatment liquid for marble and granite surfaces prepared in example 1 of the present invention on ceramic bricks in different scenes, samples of the experimental examples were selected from student restaurants, student public education buildings, teacher kitchens, student kitchens and administrative buildings in the special schools such as obedience medicine, and the experimental examples 1 to 5 were as follows:
experimental example 1
Selecting 3 student restaurant floor tiles with the sizes of 200mm multiplied by 200mm as samples, smearing the marble and granite surface anti-skid treatment liquid prepared in the embodiment 1 of the invention on the surfaces of the samples, and testing the friction coefficients of the 3 samples smeared with the surface anti-skid treatment liquid according to the test basis of GB/T4100-2015, wherein the dry friction coefficient test results of the 3 samples are 0.81, 0.81 and 0.80, and the wet friction coefficient test results are 0.81, 0.81 and 0.81.
Experimental example 2
3 pieces of student public education floor tiles with the sizes of 200mm multiplied by 200mm are selected as samples, the marble and granite surface antiskid treatment solution prepared in the embodiment 1 of the invention is smeared on the surfaces of the samples, and the friction coefficients of the 3 samples smeared with the surface antiskid treatment solution are tested according to the test basis of GB/T4100-2015, wherein the dry friction coefficient test results of the 3 samples are 0.84, 0.84 and 0.84, and the wet friction coefficient test results are 0.80, 0.81 and 0.80.
Experimental example 3
Selecting 3 teachers' kitchen floor tiles with the block size of 200mm multiplied by 200mm as samples, smearing the marble and granite surface anti-skid treatment liquid prepared in the embodiment 1 of the invention on the surfaces of the samples, and testing the friction coefficients of the 3 samples smeared with the surface anti-skid treatment liquid according to the test basis of GB/T4100-2015, wherein the dry friction coefficient test results of the 3 samples are 0.81, 0.81 and 0.80, and the wet friction coefficient test results are 0.80, 0.79 and 0.80.
Experimental example 4
Selecting 3 student kitchen floor tiles with the sizes of 200mm multiplied by 200mm as samples, smearing the marble and granite surface anti-skid treatment liquid prepared in the embodiment 1 of the invention on the surfaces of the samples, and testing the friction coefficients of the 3 samples smeared with the surface anti-skid treatment liquid according to the test basis of GB/T4100-2015, wherein the dry friction coefficient test results of the 3 samples are 0.82, 0.82 and 0.82, and the wet friction coefficient test results are 0.81, 0.82 and 0.82.
Experimental example 5
Selecting 3 administrative floor tiles with the size of 200mm multiplied by 200mm as a sample, smearing the marble and granite surface anti-skid treatment liquid prepared in the embodiment 1 of the invention on the surface of the sample, and testing the friction coefficients of the 3 samples smeared with the surface anti-skid treatment liquid according to the test basis of GB/T4100-2015, wherein the dry friction coefficient test results of the 3 samples are 0.81, 0.82 and 0.82, and the wet friction coefficient test results are 0.82, 0.83 and 0.82.
According to the test results of the experimental examples 1 to 5, the anti-skid effect of the anti-skid treatment liquid for the surfaces of the marble and the granite prepared by the embodiment of the invention on the floor tiles of the marble and the granite is obviously superior to the detection standard.
The anti-skid treatment fluid for the surfaces of the marble and the granite, prepared by the invention, can effectively play an anti-skid effect when applied to the marble and the granite, and improves the use safety of the marble and the granite.
The above description is only for the preferred embodiment of the present invention, but the scope of the present invention is not limited thereto, and any person skilled in the art should be considered to be within the technical scope of the present invention, and the technical solutions and the inventive concepts thereof according to the present invention should be equivalent or changed within the scope of the present invention.

Claims (10)

1. The marble and granite surface antiskid treatment fluid is characterized by comprising the following components in percentage by weight: 48.5 to 80.5 percent of deionized water, 18.3 to 37 percent of fruit acid, 0.35 to 3.5 percent of acetic acid, 0.31 to 3.5 percent of cationic surfactant, 0.24 to 3.5 percent of nonionic surfactant, 0.2 to 2.0 percent of inorganic corrosion inhibitor, 0.1 to 1.0 percent of cosolvent and 1.0 percent of defoaming agent.
2. The marble and granite surface antiskid treatment fluid according to claim 1, which comprises the following components in percentage by weight: 50-80% of deionized water, 20-35% of fruit acid, 0.5-3.0% of acetic acid, 0.5-3.0% of cationic surfactant, 0.5-3.0% of nonionic surfactant, 0.6-1.5% of inorganic corrosion inhibitor, 0.2-0.8% of cosolvent and 1.0% of defoaming agent.
3. The marble and granite surface antiskid treatment fluid according to claim 1, which comprises the following components in percentage by weight: 64% of deionized water, 27.5% of fruit acid, 2.0% of acetic acid, 2.0% of cationic surfactant, 2.2% of nonionic surfactant, 1.1% of inorganic corrosion inhibitor, 0.5% of cosolvent and 1.0% of defoaming agent.
4. The marble and granite surface antiskid treatment fluid according to claim 1, which comprises the following components in percentage by weight: 60 to 70 percent of deionized water, 25 to 30 percent of fruit acid, 1.5 to 2.5 percent of acetic acid, 1.5 to 2.5 percent of cationic surfactant, 2.0 to 2.5 percent of nonionic surfactant, 1.0 to 1.4 percent of inorganic corrosion inhibitor, 0.3 to 0.8 percent of cosolvent and 1.0 percent of defoaming agent.
5. The marble and granite surface antiskid treatment fluid of claim 1, wherein the surfactant is one of cetyl trimethyl quaternary ammonium bromide and stearyl dimethyl benzyl quaternary ammonium chloride.
6. The marble and granite surface antiskid treatment fluid according to claim 1, wherein the nonionic surfactant is one of polyoxyethylene type, polyol type, alkanolamide type, polyether type, and amine oxide type.
7. The process for preparing the marble and granite surface anti-slip treatment fluid according to any one of claims 1 to 6, characterized by comprising the following steps:
step 1: heating deionized water and putting into a plastic container;
and 2, step: adding acetic acid into a plastic container and uniformly stirring;
and 3, step 3: then adding the tartaric acid into the plastic container and stirring uniformly;
and 4, step 4: and (3) sequentially adding a cationic surfactant, a nonionic surfactant, an inorganic corrosion inhibitor, a cosolvent and a defoaming agent into the plastic container, fully reacting, and filling into the plastic container to obtain the marble and granite surface anti-slip treatment solution.
8. The method for preparing the marble and granite surface antiskid treatment fluid according to claim 7, characterized in that the deionized water is heated to 35 ℃.
9. The method for preparing the surface antiskid treatment solution for marble and granite according to claim 7, wherein the stirring time in the step 2 and the step 3 is 5 min.
10. The method for preparing the marble and granite surface antiskid treatment solution according to claim 7, wherein the reaction time in step 4 is 30 min.
CN202210331117.2A 2022-03-30 2022-03-30 Marble and granite surface anti-skid treatment fluid and preparation method thereof Pending CN114561116A (en)

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Citations (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR20080011255A (en) * 2006-07-29 2008-02-01 (주)브릿지바이오 Water-soluble anti-slip composition
CN105482778A (en) * 2015-12-17 2016-04-13 李志广 Environment-friendly floor anti-skid material and preparing method thereof
CN106811757A (en) * 2017-01-23 2017-06-09 江苏理工学院 Acid mist inhibitor for hydochloric acid pickling and its application that a kind of normal temperature is used
CN107117990A (en) * 2017-05-25 2017-09-01 广东青筑科技有限公司 A kind of antilubricant of ceramic tile surface and preparation method thereof
CN107325788A (en) * 2017-06-13 2017-11-07 上海世卿防滑防护科技有限公司 A kind of preparation method of floor tile antilubricant
CN108753254A (en) * 2018-06-24 2018-11-06 江苏浩翔防滑科技有限公司 A kind of ground antilubricant and preparation method thereof
CN110452665A (en) * 2019-05-30 2019-11-15 王铭 A kind of ground antiskid liquid and preparation method thereof
CN111040491A (en) * 2019-12-11 2020-04-21 佛山市善益科技有限公司 Safe and harmless tile anti-slip agent and preparation method thereof

Patent Citations (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR20080011255A (en) * 2006-07-29 2008-02-01 (주)브릿지바이오 Water-soluble anti-slip composition
CN105482778A (en) * 2015-12-17 2016-04-13 李志广 Environment-friendly floor anti-skid material and preparing method thereof
CN106811757A (en) * 2017-01-23 2017-06-09 江苏理工学院 Acid mist inhibitor for hydochloric acid pickling and its application that a kind of normal temperature is used
CN107117990A (en) * 2017-05-25 2017-09-01 广东青筑科技有限公司 A kind of antilubricant of ceramic tile surface and preparation method thereof
CN107325788A (en) * 2017-06-13 2017-11-07 上海世卿防滑防护科技有限公司 A kind of preparation method of floor tile antilubricant
CN108753254A (en) * 2018-06-24 2018-11-06 江苏浩翔防滑科技有限公司 A kind of ground antilubricant and preparation method thereof
CN110452665A (en) * 2019-05-30 2019-11-15 王铭 A kind of ground antiskid liquid and preparation method thereof
CN111040491A (en) * 2019-12-11 2020-04-21 佛山市善益科技有限公司 Safe and harmless tile anti-slip agent and preparation method thereof

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