CN1145402A - Aqueous detergent compositions - Google Patents
Aqueous detergent compositions Download PDFInfo
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- CN1145402A CN1145402A CN 96110286 CN96110286A CN1145402A CN 1145402 A CN1145402 A CN 1145402A CN 96110286 CN96110286 CN 96110286 CN 96110286 A CN96110286 A CN 96110286A CN 1145402 A CN1145402 A CN 1145402A
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Abstract
Disclosed is a water-based washing agent compound containing the following ingredients: (A) 1- 50 percent (by weight) nonionic surfactant in the following formula of RCOO - (CH 2 CH2) n - H, wherein RCO stands for C 4 - C 30 carboxylic acid acyl, n stands for an integral between 1 and 50; (B) 20 - 70 percent (by weight) polyatomic alcohol or glycol monobutyl ether; and (C) 0.5 - 5 percent (by weight) powder. The compound has excellent washing effect on cosmetic residues, sebum and attle, is mild for the skin, brings no sense of oiliness in the washing course, provides good operation sense and has stable property to ensure the use under high temperature and high humidity.
Description
The present invention relates to aqueous detergent compositions, they have fabulous washing effect to cosmetics residue and sebum scrap; To skin is soft; Fabulous operation feeling is arranged; The aftersensation of washing that makes us salubrious is arranged; In cleaning process, there is not tedious oiliness sensation; And because its fabulous stability is applicable to high temperature and super-humid conditions.
Cosmetics such as lipstick, end powder, eye shadow and cosmetic cream (mascaras) contain a large amount of oily components or solid oils.So common washing one's face removed old makeup unsatisfactorily with washing composition such as solid or paste soap, because such washing composition does not have enough dissolving poweies and emulsifying capacity.So far, in order to remove old makeup, in other words,, use the oil base detergent that comprises clean gel, cleans cream frost or wash oil in order to remove the makeup residue.
But these traditional oil base detergents can not be removed the sebum scrap fully as stopping up the solid scrap of skin pore.And these traditional oil base detergents stay the oiliness sensation after they are used for cleaning, and need to use the washing step that adds of the facial washing composition of class paste etc.In addition, if the oil base detergent uses under high temperature and super-humid conditions, they can absorb moisture, damage its stability, cause to separate or the washing effect variation.Another shortcoming relevant with the use of traditional detergent oil is that if use low viscous wash oil, they can drip the user's that makes dirty clothes etc. from face.
The detergent composition of removing oiliness scrap such as makeup and sebum must be soft to skin.Usually, not necessarily soft to skin with common fats acid soap or aniorfic surfactant as the detergent composition of its base-material preparation.If as base-material, the detergent composition of generation is soft to skin not only, and also has fabulous washing effect with nonionic surface active agent.But, the problem that adds nonionic surface active agent is, the composition that generates has the butyrous sensation in cleaning process, and when attempting that the viscosity of detergent composition brought up to the degree of easy handling, the washing effect of nonionic surface active agent significantly descends.
Therefore, an object of the present invention is to provide a kind of like this detergent composition: it has fabulous washing effect to makeup residue or sebum scrap; It is soft to skin; It has fabulous operation feeling and makes us the salubrious aftersensation of washing, and does not have tedious oiliness sensation in cleaning process, therefore can use under high temperature and super-humid conditions.
In view of the foregoing, the present inventor has carried out research widely, and find when specific nonionic surface active agent, polyvalent alcohol or glycol ethers and powder are pressed specific mixed, can make such aqueous detergent compositions, they have fabulous washing effect to the oiliness residue and the sebum scrap of makeup; To skin is soft; Be easy to coat to the hands or face; Fabulous operation feeling is arranged; The aftersensation of washing that makes us salubrious is arranged; In cleaning process, there is not tedious oiliness sensation; And because its fabulous stability is applicable to high temperature and super-humid conditions.
Therefore, the invention provides a kind of water quality detergent composition that contains following component:
(A) nonionic surface active agent of 1-50% (weight) following formula (1) expression:
RCOO-(CH
2CH
2O)
nIn-H (1) formula, RCO represents C
4-C
30Saturated or unsaturated carboxylic acyl radical, n are represented an integer between the 1-50.
(B) 20-70% (weight) polyvalent alcohol or glycol ethers.
(C) 0.5-5% (weight) powder.
Aqueous detergent compositions of the present invention has fabulous washing effect to makeup oiliness residue and sebum scrap, and is soft to skin.And it has makes us salubrious aftersensation and the good washing effect of washing, and does not have tedious oiliness sensation in cleaning process.Because it has fabulous shape-holding property, it can remain in the hand, and is easy to be coated in face.It also has fabulous operation feeling.In addition, it is very stable, can use under high temperature and super-humid conditions, can not reduce quality.
Being used for nonionic surface active agent of the present invention (component (A)) represents with above-mentioned formula (1).It is the higher fatty acid fat of polyoxyethylene glycol.In formula (1), RCO represents C
4-C
30Saturated or unsaturated carboxylic acyl radical, preferably, RCO is C
4-C
30Alkyloyl or alkenoic acid acyl group, wherein carbonatoms does not comprise carbonyl carbon.Preferably, RCO is C
10-C
22Saturated or unsaturated carboxylic acyl radical is as decanoyl, lauroyl, myristoyl, brown paulownia acyl group and stearyl-.N represents an integer among the 1-50.In order to ensure the dissolving power that improves the makeup residue, n is preferably an integer among the 10-30.
The ester class nonionic surface active agent of formula (1) is compared cellular toxicity and is descended with corresponding ethers tensio-active agent, be soft to skin therefore.In addition, they have improved the washability to the oiliness scrap.
Component (A) (being nonionic surface active agent of the present invention) can use separately or two or more are used in combination.Press total restatement of composition, their consumption is 1-50% (weight), preferred 5-30% (weight), more preferably 10-20% (weight).When they when these amount ranges are used, can obtain gratifying washing effect, can not cause tedious stickiness feeling in the time of on being coated in skin.And, obtain fabulous operation feeling, and this detergent composition can be easy to flush away.
Being used for component of the present invention (B) is polyvalent alcohol or glycol ethers.The example of polyvalent alcohol includes but not limited to ethylene glycol, propylene glycol, isoamyl glycol, dipropylene glycol, 1,3 butylene glycol, Diethylene Glycol, dipropylene glycol, glycerine, tetramethylolmethane and sorbyl alcohol.The example of glycol ethers includes but not limited to ethylene glycol monomethyl ether, ethylene glycol monoethyl ether, ethylene glycol ether, ethylene glycol monobutyl ether, diethylene glycol monomethyl ether, diethylene glycol monoethyl ether, Diethylene glycol monopropyl ether, diethylene glycol monobutyl ether, propylene glycol monomethyl ether, dihydroxypropane single-ether and ethyleneglycol monophenylether.
In these compounds of component (B) category, especially preferably ethylene glycol, propylene glycol, isoamyl glycol, dipropylene glycol, glycerine, 1,3 butylene glycol, sorbyl alcohol and diethylene glycol monoethyl ether.
As component (B), can be used singly or in combination one or more these polyvalent alcohols or glycol ethers.Preferred two or more are used in combination especially.Press total restatement of composition, the consumption of component (B) is 20-70% (weight), preferred 20-50% (weight), preferred especially 20-40% (weight).When the consumption of component (B) is in these scopes, can obtain sufficient washing effect, the composition of generation is stable, can not produce separation.
Component (C) (powder that the present invention uses) has no particular limits.The concrete example of component (C) powder comprises inorganic powder such as talcum, titanium dioxide, mica, zinc oxide, kaolin, zirconium white, chromic oxide, cobalt oxide, red iron oxide, Yellow iron oxides, Black Rouge, barium sulfate, pearl white, manganese, Prussian orchid, ultramarine, chromium hydroxide, aluminium hydroxide, pure aluminium silicate, silicic anhydride, aluminium, copper, gold, mica titanium, wilkinite and polynite; And toner such as polyester, polyethylene, polystyrene, methyl-methacrylate resin, Mierocrystalline cellulose, nylon 12, nylon 6, vinylbenzene and acrylic copolymer, polypropylene, vinylchlorid and tetrafluoroethylene such as Teflon
Wherein inorganic powder is preferred, and zinc oxide is particularly preferred.
The mean diameter of component (C) powder has no particular limits.For example, diameter is that 0.01-60 μ m is preferred.Considering has good sensation in operating process, mean particle size is that 0.1-10 μ m is particularly preferred.
The shape of component (C) powder is without particular limitation.More the spheric particle is preferred.
As component (C), can be used singly or in combination one or more powder.The consumption of component (C) is counted 0.5-5% (weight) by the gross weight of composition, preferred 0.8-3% (weight), preferred especially 1.0-2.0% (weight).When the consumption of component (C) was in these scopes, that uses in operation felt it is good, and no oiliness sensation in cleaning process can have salubrious sensation in that drying is later.
The preferred batching like this of aqueous detergent compositions of the present invention, thus rest part is a water.
So far, various scouring washing composition are known, and wherein seed hulls and the solid fat of aniorfic surfactant, organic polymer powder, plant are used in combination.The abrasive material of removing scrap as just physics from skin at traditional like this powder of cleaning in the washing composition adds.On the contrary, in the present invention, use powder, particularly inorganic powder, feel so that prevent the oiliness of using nonionic surface active agent to cause, and in use with after using produce salubrious sensation.Therefore, water quality detergent composition of the present invention is a kind of composition of aniorfic surfactant as its detergent component that do not need basically on feature.
Water quality detergent composition of the present invention also can contain component (D), i.e. water-soluble polymers.Any natural or synthetic water-soluble polymers all can use, as long as it is water-soluble.The example of preferred water-soluble polymers comprises pectin, carrageenin, guar gum, perverse locust bean gum, gelatin, xanthan gum, carboxy vinyl polymer, carboxymethyl hydroxyethyl cellulose, Natvosol, alginate, starch, polyvinyl alcohol, polyacrylic ester, polymethyl acrylate and polyoxyethylene glycol.Wherein, particularly preferably be carrageenin, guar gum, carboxy vinyl polymer, Natvosol and xanthan gum.
These water-soluble polymerss can be used singly or in combination.Press total restatement of composition, the consumption of water-soluble polymers is that 0.1-5% (weight) is preferred, more preferably 0.1-3% (weight), most preferably 0.3-1% (weight).When they use in these scopes, there is not drip to occur in operation, the danger of the clothes of having avoided making dirty etc.And, can obtain good feel and high washing effect.
Aqueous detergent compositions of the present invention also can contain and the different nonionic surface active agent of component (A), to improve washing effect and stability.Examples of nonionic surfactants except that component (A) includes but not limited to the epoxyethane derivative of Vykamol Sorbitol 8B or glycerol fatty acid ester, epoxyethane derivative, Voranol EP 2001, polyoxypropylene alkyl oxide, polyoxyethylene alkyl phenyl ether and the polyoxyethylene hydrogenated castor oil of propylene glycol fatty acid ester.In these nonionic surface active agent, hydrophilic-lipophilic balance (HLB) is not less than 10, particularly be not less than 12 be preferred.The preferred such consumption of these nonionic surface active agent outside component (A) definition, so that the weight ratio of the such nonionic surface active agent and the nonionic surface active agent of component (A) is 1/10 to 10/1, preferred 1/4 to 4/1, more preferably 1/2 to 2/1, thus improve washing effect and clean stability better.
Aqueous detergent compositions of the present invention can contain the various oils of 55% (weight) at the most by total restatement of composition.And except said components, said composition also can contain the various components that are added in the common detergent composition.Such optional components comprises wetting agent, sterilant, sanitas, sequestrant, ionogen, medicine, tinting material, spices, antioxidant and pH value improving agent.Its consumption should not have detrimentally affect to effect of the present invention.
Aqueous detergent compositions of the present invention prepares by above-mentioned each component and water are mixed.Aqueous detergent can have any suitable form, comprises liquid, solid and powder.Preferably, aqueous detergent can be processed into liquid, pasty state or paste.By controlling the quantity of each component, can reach preferably bonding.From easy-to-handle viewpoint, the viscosity between the 10000-60000cps is preferred.
The aqueous detergent compositions that so makes is used to clean etc., is particularly suitable for removing the facial washing composition of makeup.
Embodiment
To describe the present invention in detail with embodiment subsequently, this embodiment is not as limitation of the present invention.
Embodiment 1
Various aqueous detergent compositions shown in the table 1 prepare with ordinary method, and have estimated about removing the character of the sensation in makeup effect, operation feeling and the cleaning.The result also lists table 1 in.
Evaluation method
(1) removes the effect of makeup
The lipstick of pre-determined quantity is coated on the skin of human body forearm inboard.After being coated to the lipstick residue, each detergent composition is with a certain pressure and the operation of a certain coating number of times, with after scouring.For all subject composition, coating pressure and number of times are constant.By measuring color distortion, calculate washing effect with percentage ratio, by following standard evaluation.
A: be not less than 70%
B: more than or equal to 50%, but less than 70%
C: less than 50%
(2) operation feeling
Every kind of detergent composition is coated onto the member's of expert group face.After a certain pressure and the operation of a certain number of times, on the basis of following standard, estimate extensibility and sensation in the operating process:
A: fabulous extensibility
B: medium extensibility
C: poor expandability
(3) sensation in the cleaning process
Every kind of detergent composition is coated in the member's of expert group face.Operate after 20 seconds, with some amount water cleaning detergent composition.On the basis of following standard, estimate the sensation in the cleaning process:
A: very fast cleaning has the salubrious aftersensation of washing
B: medium
C: it is poor to clean, and leaves the oiliness sensation
(4) shape hold facility
The member of expert group gets every kind of detergent composition with hand, and is coated in face.On the basis of following standard, estimate the shape hold facility of every kind of detergent composition:
A: be easy to maintain and be coated in face, fabulous extensibility is arranged with hand.
B: medium
C: drip has sense of heaviness aspect expansion
Table 1
Embodiment 2
| Component (% (weight)) | Embodiments of the invention | Comparative Examples |
| ?1????2????3????4????5????6????7 | ??1????2????3 | |
| Polyoxyethylene lauric acid ester (10E.O.) | 12.0?12.0?12.0?12.0?12.0?12.0?12.0 | ?12.0?12.0?12.0 |
| Polyoxyethylene list isostearate (20E.O.) | 12.0?12.0?12.0?12.0?12.0?12.0?12.0 | ?12.0?12.0?12.0 |
| Sorbyl alcohol | 25.0?25.0?25.0?25.0?25.0?25.0?25.0 | ?25.0?25.0?25.0 |
| Carboxy vinyl polymer | ?-????0.4??0.4??0.4??0.4??0.4??0.4 | ??0.4??0.4??0.4 |
| The 48%KOH aqueous solution | ?0.2??0.2??0.2??0.2??0.2??0.2??0.2 | ??0.2??0.2??0.2 |
| Titanium dioxide (mean diameter: 0.2 μ m) | ?1.5??1.5???-???1.0??2.0??3.0??0.75 | ??-????0.3??6.0 |
| Zinc oxide (mean diameter: pure water 1.0 μ m) | --1.5---0.75 rest parts | ??-?????-????- |
| (1) the makeup residue removes sensation (4) shape-holding property in (2) operation feeling (3) cleaning process | ?A?????A????A????A????A????A????A ?A?????A????A????A????A????A????A ?A?????A????A????A????A????A????A ?B?????A????A????A????A????A????A | ??A?????A????A ??A?????A????C ??C?????B????A ??A?????A????A |
Prepare the water quality detergent composition shown in table 2 and 3 with traditional method.
The detergent composition that generates has the fabulous ability of removing the makeup residue, does not have the oiliness sensation in cleaning process, salubrious sensation is arranged and fabulous operation feeling is arranged.
Table 2
Component % (weight)
Polyoxyethylene (10E.O) laurate 11.00
The single isostearate 11.00 of anhydro sorbitol polyoxyethylene (20E.O)
Anhydro sorbitol coco-nut oil fatty acid polyoxyethylene (6E.O) 3.50
Diethylene glycol ether 8.00
Sorbyl alcohol (70%) 20.00
Carboxy vinyl polymer 0.34
Potassium hydroxide (48%) 0.17
To oxybenzoic acid ethyl ester 0.20
Butylated hydroxytoluene 0.10
Titanium dioxide 1.30
Liquid Macrogol 0.70
Spices 0.10
The pure water rest part
100
Table 3
Component % (weight)
Polyoxyethylene (10E.O.) laurate 12.00
The single isostearate 12.00 of anhydro sorbitol polyoxyethylene (20E.O.)
Anhydro sorbitol coco-nut oil fatty acid polyoxyethylene (6E.O.) 4.00
Diethylene glycol ether 16.00
Sorbyl alcohol (70%) 20.00
Carrageenin 0.50
To oxybenzoic acid ethyl ester 0.20
Butylated hydroxytoluene 0.10
Titanium dioxide 3.00
Spices 0.10
The pure water rest part
100
The application's book is based on the Japanese patent application book NO7-192903 that submits Japan Office July 28 nineteen ninety-five to, and its full content is incorporated the present invention here as a reference into.
Claims (22)
1. aqueous detergent compositions that contains following component:
(A) nonionic surface active agent of 1-50% (weight) following formula (1) expression:
RCOO-(CH
2CH
2O) in n-H (1) formula, RCO represents C
4-C
30Saturated or unsaturated carboxylic acyl radical, n are an integer among the 1-50.
(B) 20-70% (weight) polyvalent alcohol or glycol ethers, and
(C) 0.5-5% (weight) powder,
Wherein % (weight) is the total restatement by composition.
2. according to the aqueous detergent compositions of claim 1, also contain 0.1-5% (weight) water-soluble polymers as component (D), wherein % (weight) is the total restatement by composition.
3. according to the aqueous detergent compositions of claim 1, wherein component (B) is selected from ethylene glycol, propylene glycol, Isopropanediol, dipropylene glycol, glycerine, 1,3 butylene glycol, sorbyl alcohol, diethylene glycol monoethyl ether and mixture.
4. according to the aqueous detergent compositions of claim 1, wherein component (D) is selected from pectin, carrageenin, guar gum, perverse locust bean gum, gelatin, is total to virgin rubber, carboxy vinyl polymer, carboxymethyl hydroxyethyl cellulose, Natvosol, alginate, starch, polyvinyl alcohol, polyacrylic ester, polymethyl acrylate, polyoxyethylene glycol and composition thereof.
5. according to the aqueous detergent compositions of claim 1, wherein component (C) is an inorganic powder.
6. according to the aqueous detergent compositions of claim 1, wherein component (C) is that mean particle size is the inorganic powder of 0.01-60 μ m.
7. according to the aqueous detergent compositions of claim 1, also contain and the different nonionic surface active agent of component (A).
8. according to the aqueous detergent compositions of claim 1, contain 5-30% (weight) component (A).
9. according to the aqueous detergent compositions of claim 1, contain 10-20% (weight) component (A).
10. according to the aqueous detergent compositions of claim 1, contain 20-50% (weight) component (B).
11., contain 20-40% (weight) component (B) according to the aqueous detergent compositions of claim 1.
12., contain 0.8-3.0% (weight) component (C) according to the aqueous detergent compositions of claim 1.
13., contain 1.0-2.0% (weight) component (C) according to the aqueous detergent compositions of claim 1.
14. according to the aqueous detergent compositions of claim 1, wherein said powder is selected from talcum, titanium dioxide, mica, zinc oxide, kaolin, zirconium white, chromic oxide, cobalt oxide, red iron oxide, Yellow iron oxides, Black Rouge, barium sulfate, pearl white, manganese, the Prussian orchid, ultramarine, chromium hydroxide, aluminium hydroxide, pure aluminium silicate, silicic anhydride, aluminium, copper, gold, mica titanium, wilkinite and polynite, the vibrin powder, the polyvinyl resin powder, the polystyrene resin powder, the methyl-methacrylate resin powder, the celluosic resin powder, nylon 12 resin-oatmeals, the Nylon 6 powder, vinylbenzene and acrylic copolymer resin powder, the acrylic resin powder, vinyl chloride resin powder and teflon resin powder.
15. according to the aqueous detergent compositions of claim 2, wherein component (D) is selected from pectin, carrageenin, guar gum, perverse locust bean gum, gelatin, xanthan gum, carboxy vinyl polymer, carboxymethyl hydroxyethyl cellulose, Natvosol, alginate, starch, polyvinyl alcohol, polyacrylic ester, polymethacrylate and polyoxyethylene glycol.
16., contain 0.1-3% (weight) component (D) according to the aqueous detergent compositions of claim 2.
17., contain 0.3-1% (weight) component (D) according to the aqueous detergent compositions of claim 1.
18. according to the aqueous detergent compositions of claim 7, the wherein said nonionic surface active agent different with component (A) is selected from the oxyethylene derivative of Vykamol Sorbitol 8B or glycerol fatty acid ester, oxyethylene derivative, Voranol EP 2001, polyoxypropylene alkyl oxide, polyxyethylated phenylate and the polyoxyethylene hydrogenated castor oil of propylene glycol fatty acid ester.
19. according to the aqueous detergent compositions of claim 7, the weight ratio of the nonionic surface active agent of wherein above-mentioned nonionic surface active agent and component (A) is 1/10 to 10/1.
20. according to the aqueous detergent compositions of claim 1, wherein rest part is a water.
21. according to the aqueous detergent compositions of claim 7, the hydrophilic-lipophilic balance of the wherein said nonionic surface active agent different with component (A) is not less than 10.
22. according to the aqueous detergent compositions of claim 7, the hydrophilic-lipophilic balance of the wherein said nonionic surface active agent different with component (A) is not less than 12.
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP19290395A JP3526352B2 (en) | 1995-07-28 | 1995-07-28 | Aqueous detergent composition |
| JP192903/95 | 1995-07-28 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN1145402A true CN1145402A (en) | 1997-03-19 |
| CN1089579C CN1089579C (en) | 2002-08-28 |
Family
ID=16298903
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN96110286A Expired - Fee Related CN1089579C (en) | 1995-07-28 | 1996-07-25 | Aqueous detergent compositions |
Country Status (2)
| Country | Link |
|---|---|
| JP (1) | JP3526352B2 (en) |
| CN (1) | CN1089579C (en) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103550993A (en) * | 2013-10-30 | 2014-02-05 | 王维玲 | Atmospheric pollution purificant and preparation method, application of purificant and application method thereof |
| CN104694272A (en) * | 2013-12-04 | 2015-06-10 | 日油株式会社 | Liquid decontaminant composition |
| CN106281820A (en) * | 2016-08-16 | 2017-01-04 | 张�杰 | Facial soap that a kind of moisturizing is anti-ageing and preparation method thereof |
Families Citing this family (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US6174533B1 (en) * | 1997-05-23 | 2001-01-16 | The Procter & Gamble Company | Skin care compositions and method of improving skin appearance |
| JP4792648B2 (en) * | 2001-03-26 | 2011-10-12 | 日油株式会社 | Hot cleansing fee |
| JP4529402B2 (en) * | 2003-09-30 | 2010-08-25 | 日油株式会社 | Skin cosmetics |
| JP2009275010A (en) * | 2008-05-16 | 2009-11-26 | Kao Corp | Skin cleanser composition |
| JP5604058B2 (en) * | 2009-06-03 | 2014-10-08 | 花王株式会社 | Skin cleanser |
| JP5946422B2 (en) * | 2013-03-19 | 2016-07-06 | 株式会社マンダム | Aqueous cleansing cosmetics |
Family Cites Families (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5157837A (en) * | 1974-11-12 | 1976-05-20 | Shiseido Co Ltd | HIFUHIFUKU SEIIKESHORYONO SEIZOHO |
| JP2963285B2 (en) * | 1992-10-05 | 1999-10-18 | サンスター株式会社 | Gel cosmetics |
-
1995
- 1995-07-28 JP JP19290395A patent/JP3526352B2/en not_active Expired - Fee Related
-
1996
- 1996-07-25 CN CN96110286A patent/CN1089579C/en not_active Expired - Fee Related
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103550993A (en) * | 2013-10-30 | 2014-02-05 | 王维玲 | Atmospheric pollution purificant and preparation method, application of purificant and application method thereof |
| CN103550993B (en) * | 2013-10-30 | 2015-07-08 | 王维玲 | Atmospheric pollution purificant and preparation method, application of purificant and application method thereof |
| CN104694272A (en) * | 2013-12-04 | 2015-06-10 | 日油株式会社 | Liquid decontaminant composition |
| CN104694272B (en) * | 2013-12-04 | 2018-12-28 | 日油株式会社 | liquid detergent composition |
| CN106281820A (en) * | 2016-08-16 | 2017-01-04 | 张�杰 | Facial soap that a kind of moisturizing is anti-ageing and preparation method thereof |
Also Published As
| Publication number | Publication date |
|---|---|
| JP3526352B2 (en) | 2004-05-10 |
| CN1089579C (en) | 2002-08-28 |
| JPH0940525A (en) | 1997-02-10 |
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Granted publication date: 20020828 Termination date: 20100725 |