CN114497650B - Power control method for methanol reforming fuel cell power generation system - Google Patents

Power control method for methanol reforming fuel cell power generation system Download PDF

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CN114497650B
CN114497650B CN202210018261.0A CN202210018261A CN114497650B CN 114497650 B CN114497650 B CN 114497650B CN 202210018261 A CN202210018261 A CN 202210018261A CN 114497650 B CN114497650 B CN 114497650B
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fuel cell
power
preset
soc
generation system
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CN114497650A (en
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王戈
樊军
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Moh Technology Co ltd
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    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00Fuel cells; Manufacture thereof
    • H01M8/04Auxiliary arrangements, e.g. for control of pressure or for circulation of fluids
    • H01M8/04298Processes for controlling fuel cells or fuel cell systems
    • H01M8/04313Processes for controlling fuel cells or fuel cell systems characterised by the detection or assessment of variables; characterised by the detection or assessment of failure or abnormal function
    • H01M8/04537Electric variables
    • H01M8/04604Power, energy, capacity or load
    • H01M8/04626Power, energy, capacity or load of auxiliary devices, e.g. batteries, capacitors
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00Fuel cells; Manufacture thereof
    • H01M8/04Auxiliary arrangements, e.g. for control of pressure or for circulation of fluids
    • H01M8/04298Processes for controlling fuel cells or fuel cell systems
    • H01M8/04694Processes for controlling fuel cells or fuel cell systems characterised by variables to be controlled
    • H01M8/04858Electric variables
    • H01M8/04925Power, energy, capacity or load
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00Fuel cells; Manufacture thereof
    • H01M8/04Auxiliary arrangements, e.g. for control of pressure or for circulation of fluids
    • H01M8/04298Processes for controlling fuel cells or fuel cell systems
    • H01M8/04694Processes for controlling fuel cells or fuel cell systems characterised by variables to be controlled
    • H01M8/04858Electric variables
    • H01M8/04925Power, energy, capacity or load
    • H01M8/0494Power, energy, capacity or load of fuel cell stacks
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/30Hydrogen technology
    • Y02E60/50Fuel cells

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  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Manufacturing & Machinery (AREA)
  • Sustainable Development (AREA)
  • Sustainable Energy (AREA)
  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Electrochemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Fuel Cell (AREA)

Abstract

The invention discloses a power control method of a methanol reforming fuel cell power generation system, which comprises the following steps: monitoring the working state of the storage battery and obtaining the SOC of the storage battery; judging whether the SOC meets a first preset condition or not; and when the SOC does not meet the first preset condition, performing nonlinear regulation on the preset power of the fuel cell and performing smooth regulation on the fuel. According to the power control method of the methanol reforming fuel cell power generation system, provided by the invention, the load power and the state of the storage battery are tracked, and then the preset concept is introduced, so that the linear regulation calculation of the timely response of the fuel cell power and the smooth regulation control of the system fuel are increased, the storage battery is prevented from being in a floating charge state, the change of the load power can be responded, and the stability of the system is ensured.

Description

Power control method for methanol reforming fuel cell power generation system
Technical Field
The invention relates to the technical field of fuel cells, in particular to a power control method of a methanol reforming fuel cell power generation system.
Background
In the application of the methanol reforming fuel cell, the methanol reforming reaction and the fuel cell reaction have certain hysteresis due to the chemical reaction mechanism, and meanwhile, the defects of softer output characteristic, slow dynamic response, long system stability time and the like exist, so that the continuous change of the user load cannot be responded in time. Therefore, the methanol reforming fuel cell power generation system generally needs to work together with a storage battery to form a system, in the stage of changing the power of the fuel cell, the storage battery is used for ensuring that the power of the fuel cell can respond to the change of the load power in time, and the fuel cell applies a power control strategy according to the load and the charge and discharge states of the battery.
However, the method only aims at the problems of lag of the methanol reforming reaction, lag of temperature and the like, provides a strategy for controlling the power of the fuel cell, but can not timely track and control the stability and timeliness of the methanol reforming reaction during the power control of the fuel cell; in addition, when the storage battery is in a floating charge state, the storage battery BMS can cause irregular fluctuation of power of the fuel cell from tens of watts to hundreds of watts when the charge/discharge switch is turned on, so that the stability of the system is seriously affected, and a certain risk is brought to the safe operation of the system. Therefore, a new control method is needed to track the power stability of the methanol reforming fuel cell power generation system to improve the system stability and safety.
Disclosure of Invention
The invention aims to provide a power control method of a methanol reforming fuel cell power generation system, which aims to solve the problem that the power control strategy of the existing methanol reforming fuel cell power generation system cannot track and control the control process timely and effectively, thereby influencing the stability of the system.
In order to achieve the above object, the present invention provides a power control method of a methanol reforming fuel cell power generation system, comprising:
monitoring the working state of the storage battery and obtaining the SOC of the storage battery;
judging whether the SOC meets a first preset condition or not;
the first preset condition is as follows:
SOCmin<SOC<SOCmax;
wherein, SOC is the charge state of the fuel cell and represents the percentage of the remaining available electric quantity of the cell to the total capacity; SOCmin, SOCmax represents the minimum and maximum values of the remaining usable power of the fuel cell as a percentage of the total capacity, respectively;
when the SOC does not meet the first preset condition, nonlinear adjustment is performed on preset power of the fuel cell and smooth adjustment is performed on fuel, specifically:
when SOC is<SOCmin, and I<I float When the fuel cell is started, the preset power of the fuel cell is gradually increased, and the fuel is smoothly increased and regulated; wherein I represents the charge/discharge current of the storage battery, I float Representing the current ground floating set value;
when SOC > SOCmax, and I > -I float And gradually reducing the preset power of the fuel cell, and performing smooth reduction adjustment on the fuel.
Further, preferably, the power control method of the methanol reforming fuel cell power generation system further includes:
when the SOC meets a first preset condition, acquiring the working current of the storage battery;
judging whether the working current meets a second preset condition or not; and when the working current does not meet the second preset condition, utilizing a linear regulation meter to carry out linear regulation on the preset power of the fuel cell and smooth regulation on the fuel.
Further, preferably, the power control method of the methanol reforming fuel cell power generation system further includes:
when the working current meets a second preset condition, keeping the preset power of the fuel cell unchanged;
the second preset condition is:
I f_set <I<I c_set
wherein I represents the charge/discharge current of the storage battery, I f_set Indicating the set value of discharge current, I c_set Indicating the charging current set point.
Further, preferably, when the operating current does not meet the second preset condition, the linear adjustment of the preset power of the fuel cell and the smooth adjustment of the fuel using the linear adjustment table include:
when I > I c_set And T is c >T c_set Gradually increasing the preset power of the fuel cell according to the linear regulation table and smoothly increasing and regulating the fuel, wherein T is c Indicating the charging time T c_set Indicating the charging time set point.
Further, preferably, when the operating current does not meet the second preset condition, the linear adjustment of the preset power of the fuel cell and the smooth adjustment of the fuel are performed by using a linear adjustment table, and the method further includes:
when I<I f_set And T is f >T f_set Gradually increasing the preset power of the fuel cell according to the linear regulation table and smoothly increasing and regulating the fuel, wherein T is f Indicating discharge time, T f_set Indicating the discharge time set point.
Further, preferably, the power control method of the methanol reforming fuel cell power generation system further includes:
when I > I c_set And T is c ≤T c_set When or when I<I f_set And T is f ≤T f_set And when the preset power of the fuel cell is kept unchanged.
Compared with the prior art, the invention has the beneficial effects that:
the invention discloses a power control method of a methanol reforming fuel cell power generation system, which comprises the following steps: monitoring the working state of the storage battery and obtaining the SOC of the storage battery; judging whether the SOC meets a first preset condition or not; and when the SOC does not meet the first preset condition, performing nonlinear regulation on the preset power of the fuel cell and performing smooth regulation on the fuel.
The invention introduces a preset concept by tracking the load power and the state of the storage battery and taking the instability caused by the reaction lag of the reforming part in the power adjustment into consideration. The change of the load power and the state of the storage battery can influence the change of the preset value, but the preset value cannot directly act on the power of the fuel cell, and the preset power is gradually reached through smooth adjustment of the fuel of the reactor, so that the storage battery is prevented from being in a floating charge state, the change of the load power can be responded, and the stability of the system is ensured. Meanwhile, the invention can be simultaneously applied to a direct current system and an alternating current system, and has wide application range.
Drawings
In order to more clearly illustrate the technical solutions of the present invention, the drawings that are needed in the embodiments will be briefly described below, and it is obvious that the drawings in the following description are only some embodiments of the present invention, and that other drawings can be obtained according to these drawings without inventive effort for a person skilled in the art.
FIG. 1 is a flow chart of a method for controlling power in a methanol reforming fuel cell power generation system according to an embodiment of the present invention;
FIG. 2 is a flow chart of a method for controlling power in a methanol reforming fuel cell power generation system according to yet another embodiment of the present invention;
FIG. 3 is a schematic diagram of a power control method of a methanol reforming fuel cell power generation system according to an embodiment of the present invention applied to a DC power generation system;
fig. 4 is a schematic diagram of a power control method of a methanol reforming fuel cell power generation system according to an embodiment of the present invention applied to an ac power generation system.
Detailed Description
The following description of the embodiments of the present invention will be made clearly and completely with reference to the accompanying drawings, in which it is apparent that the embodiments described are only some embodiments of the present invention, but not all embodiments. All other embodiments, which can be made by those skilled in the art based on the embodiments of the invention without making any inventive effort, are intended to be within the scope of the invention.
It should be understood that the step numbers used herein are for convenience of description only and are not limiting as to the order in which the steps are performed.
It is to be understood that the terminology used in the description of the invention is for the purpose of describing particular embodiments only and is not intended to be limiting of the invention. As used in this specification and the appended claims, the singular forms "a," "an," and "the" are intended to include the plural forms as well, unless the context clearly indicates otherwise.
The terms "comprises" and "comprising" indicate the presence of stated features, integers, steps, operations, elements, and/or components, but do not preclude the presence or addition of one or more other features, integers, steps, operations, elements, components, and/or groups thereof.
The term "and/or" refers to any and all possible combinations of one or more of the associated listed items, and includes such combinations.
Referring to fig. 1, a power control method of a power generation system of a methanol reforming fuel cell according to an embodiment of the invention is provided. As shown in fig. 1, the power control method of the methanol reforming fuel cell power generation system includes steps S10 to S20. The method comprises the following steps:
s10, monitoring the working state of the storage battery, and acquiring the SOC of the storage battery;
s20, judging whether the SOC meets a first preset condition or not; and when the SOC does not meet the first preset condition, performing nonlinear regulation on the preset power of the fuel cell and performing smooth regulation on the fuel.
In this embodiment, the first preset condition is:
SOCmin<SOC<SOCmax;
wherein, SOC is the charge state of the fuel cell and represents the percentage of the remaining available electric quantity of the cell to the total capacity; SOCmin, SOCmax represent the minimum and maximum values of the remaining usable power of the fuel cell as a percentage of the total capacity, respectively.
After the SOC of the storage battery is obtained, judging whether the storage battery meets SOCmin < SOC < SOCmax, and when the storage battery does not meet SOCmin < SOC < SOCmax, linear adjustment of preset power of the fuel cell is needed, and smooth adjustment of fuel is needed to keep stability of the system.
Referring to fig. 2, fig. 2 provides an overall flow of a method for controlling power in a methanol reforming fuel cell power generation system. In one embodiment, the linear adjustment of the preset power of the fuel cell and the smooth adjustment of the fuel involve 2 cases, as shown in fig. 2:
1) When SOC is<SOCmin, and I<I float When the fuel cell is started, the preset power of the fuel cell is gradually increased, and the fuel is smoothly increased and regulated; wherein I represents the charge/discharge current of the storage battery, I float Representing the current ground floating set value;
2) When SOC > SOCmax, and I > -I float And gradually reducing the preset power of the fuel cell, and performing smooth reduction adjustment on the fuel.
When the charge/discharge current exceeds the set threshold and reaches the set duration, the power control in the normal SOC stage adjusts the preset power of the fuel cell according to the power linear adjustment table. Specifically, preset power = current power + battery charge/discharge current × battery voltage:
P set =P now +I*V out
further, the power control in the SOCmin < SOC < SOCmax period is performed by gradually increasing/decreasing the power of the fuel cell to a preset power until the battery approaches the float state. Specifically, preset power = current power + power preset step value:
P set =P now +P step
it should be emphasized that here approaching the float state is to avoid the battery being in the float state, i.e. the current I during charging>Float charging set value I float The method comprises the steps of carrying out a first treatment on the surface of the Current I during discharge<Negative float setting-I float . According to the embodiment, the storage battery can be prevented from being in a floating charge state through accurate control of charge/discharge current, so that the stability of the power of the fuel cell is enhanced, and the stability of a system is improved.
As shown in fig. 2, in one embodiment, the power control method of the power generation system of the methanol reforming fuel cell further includes:
when the SOC meets a first preset condition, acquiring the working current of the storage battery;
judging whether the working current meets a second preset condition or not; and when the working current does not meet the second preset condition, utilizing a linear regulation meter to carry out linear regulation on the preset power of the fuel cell and smooth regulation on the fuel.
In this embodiment, when the SOC of the storage battery satisfies the first preset condition, the working current of the storage battery is obtained to determine the relationship between the working current and the second preset condition, where the working current of the storage battery mainly refers to the charging current or the discharging current, and when the working current satisfies the second preset condition, the stable operation of the system can be ensured by keeping the preset power of the fuel cell unchanged. When the working current does not meet the second preset condition, the preset power of the fuel cell is linearly regulated and the fuel is smoothly regulated by utilizing a linear regulation meter so as to ensure the stability of the system.
Specifically, the second preset condition in the present embodiment is:
I f_set <I<I c_set
wherein I represents the charge/discharge current of the storage battery, I f_set Indicating the set value of discharge current, I c_set Indicating the charging current set point.
In an exemplary embodiment, when the operating current does not meet the second preset condition, the preset power of the fuel cell is linearly adjusted and the fuel is smoothly adjusted by using the linear adjustment table, including 2 cases, as shown in fig. 2:
3) When I > I c_set And T is c >T c_set Gradually increasing the preset power of the fuel cell according to the linear regulation table and smoothly increasing and regulating the fuel, wherein T is c Indicating the charging time T c_set Indicating the charging time set point.
4) When I<I f_set And T is f >T f_set Gradually increasing the preset power of the fuel cell according to the linear regulation table and smoothly increasing and regulating the fuel, wherein T is f Indicating discharge time, T f_set Indicating the discharge time set point.
5) When I > I c_set And T is c ≤T c_set When or when I<I f_set And T is f ≤T f_set And when the preset power of the fuel cell is kept unchanged.
Unlike the cases 1) and 2) of the above embodiment, in this embodiment, whether the charging current of the storage battery is greater than the charging current set value and the charging time reaches the corresponding set value, or whether the charging current of the storage battery is smaller than the discharging current set value and the discharging time reaches the corresponding set value, the preset power of the fuel cell is gradually increased according to the linear adjustment table, and then the fuel is smoothly increased and adjusted, and in operation, the charging/discharging current of the storage battery is monitored in real time until the second preset condition is satisfied, the adjustment is ended, and the preset power of the fuel cell is kept unchanged.
In summary, the embodiment of the invention introduces a preset concept by tracking the load power and the state of the storage battery and considering the instability caused by the reaction lag of the reforming part when the power adjustment is performed. Since the change in load power and battery state affects the change in preset value, but the preset value does not directly affect the fuel cell power, the preset power can be gradually reached by smoothly adjusting the reactor fuel. In the embodiment, the SOC and the charge/discharge current of the storage battery are monitored, the relation between the SOC and the charge/discharge current of the storage battery and the preset condition is judged, and when the preset condition is not met, the fuel is smoothly regulated, so that the preset power is finally achieved. Therefore, the embodiment can respond to the change of the load power and ensure the stability of the system.
The power control method of the methanol reforming fuel cell power generation system provided by the embodiment can be used for both a direct current power generation system and an alternating current power generation system. Fig. 3-4 are schematic diagrams of the method applied to a direct current power generation system and an alternating current power generation system respectively. As can be seen from fig. 3, when the control method is applied, the monitoring unit is controlled to control the hydrogen output by controlling the fuel supply module and the methanol reforming hydrogen production system, the hydrogen output enters the fuel cell power generation module 4 to generate electric energy through electrochemical reaction, the DC/DC converter 5 converts the voltage of the fuel cell to meet the direct-current voltage requirement of the user, and the DC/DC converter 5 controls the voltage and the current to control the power of the fuel cell. The output contactor controls the DC/DC output, i.e., whether the fuel cell power generation system is providing power to the consumer load. As can be seen from fig. 4, when the control method is applied, the monitoring unit is controlled to control the hydrogen output by controlling the fuel supply module and the methanol reforming hydrogen production system, the hydrogen output enters the fuel cell power generation module 4 to generate electric energy through electrochemical reaction, the DC/DC converter 5 converts the voltage of the fuel cell to meet the direct-current voltage requirement of the user, and the DC/DC converter 5 controls the voltage and the current to control the power of the fuel cell. The output contactor 1 controls the connection between the DC/DC converter and the DC/AC, and the output contactor 2 controls the connection between the DC/AC converter and the load of the user, i.e. controls whether the AC power is supplied to the user.
Therefore, the method provided by the embodiment can be used for a direct current power generation system and is also suitable for an alternating current power generation system, and the application range is wide.
While the foregoing is directed to the preferred embodiments of the present invention, it will be appreciated by those skilled in the art that changes and modifications may be made without departing from the principles of the invention, such changes and modifications are also intended to be within the scope of the invention.

Claims (6)

1. A power control method of a methanol reforming fuel cell power generation system, comprising:
monitoring the working state of the storage battery and obtaining the SOC of the storage battery;
judging whether the SOC meets a first preset condition or not;
the first preset condition is as follows:
SOCmin<SOC<SOCmax;
wherein, SOC is the charge state of the fuel cell and represents the percentage of the remaining available electric quantity of the cell to the total capacity; SOCmin, SOCmax represents the minimum and maximum values of the remaining usable power of the fuel cell as a percentage of the total capacity, respectively;
when the SOC does not meet the first preset condition, nonlinear adjustment is performed on preset power of the fuel cell and smooth adjustment is performed on fuel, specifically:
when SOC is<SOCmin, and I<I float When the fuel cell is started, the preset power of the fuel cell is gradually increased, and the fuel is smoothly increased and regulated; wherein I represents the charge/discharge current of the storage battery, I float Representing the current ground floating set value;
when SOC > SOCmax, and I > -I float And gradually reducing the preset power of the fuel cell, and performing smooth reduction adjustment on the fuel.
2. The methanol reforming fuel cell power generation system power control method as claimed in claim 1, further comprising:
when the SOC meets a first preset condition, acquiring the working current of the storage battery;
judging whether the working current meets a second preset condition or not; and when the working current does not meet the second preset condition, utilizing a linear regulation meter to carry out linear regulation on the preset power of the fuel cell and smooth regulation on the fuel.
3. The methanol reforming fuel cell power generation system power control method as claimed in claim 2, further comprising:
when the working current meets a second preset condition, keeping the preset power of the fuel cell unchanged;
the second preset condition is:
I f_set <I<I c_set
wherein I represents the charge/discharge current of the storage battery, I f_set Indicating the set value of discharge current, I c_set Indicating the charging current set point.
4. The power control method of a methanol reforming fuel cell power generation system according to claim 3, wherein when the operating current does not satisfy a second preset condition, then performing linear adjustment on the preset power of the fuel cell and smooth adjustment on the fuel using a linear adjustment table, comprising:
when I > I c_set And T is c >T c_set Gradually increasing the preset power of the fuel cell according to the linear regulation table and smoothly increasing and regulating the fuel, wherein T is c Indicating the charging time T c_set Indicating the charging time set point.
5. The power control method of a methanol reforming fuel cell power generation system as recited in claim 4, further comprising:
when I<I f_set And T is f >T f_set Gradually increasing the preset power of the fuel cell according to the linear regulation table and smoothly increasing and regulating the fuel, wherein T is f Indicating discharge time, T f_set Indicating the discharge time set point.
6. The methanol reforming fuel cell power generation system power control method as defined in claim 5, further comprising:
when I > I c_set And T is c ≤T c_set When or when I<I f_set And T is f ≤T f_set And when the preset power of the fuel cell is kept unchanged.
CN202210018261.0A 2022-01-07 2022-01-07 Power control method for methanol reforming fuel cell power generation system Active CN114497650B (en)

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CN111063918A (en) * 2019-12-26 2020-04-24 潍柴动力股份有限公司 Control method and device for fuel cell
CN112820913A (en) * 2020-12-31 2021-05-18 宁波申江科技股份有限公司 Control system under variable load working condition of methanol reforming fuel cell power generation system
CN113844429A (en) * 2020-06-28 2021-12-28 杭州氢途科技有限公司 Control method of fuel cell engine energy management system

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Publication number Priority date Publication date Assignee Title
EP2858157B1 (en) * 2012-06-01 2017-03-15 Panasonic Intellectual Property Management Co., Ltd. Fuel-cell system, method for controlling same, and storage-cell system

Patent Citations (3)

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Publication number Priority date Publication date Assignee Title
CN111063918A (en) * 2019-12-26 2020-04-24 潍柴动力股份有限公司 Control method and device for fuel cell
CN113844429A (en) * 2020-06-28 2021-12-28 杭州氢途科技有限公司 Control method of fuel cell engine energy management system
CN112820913A (en) * 2020-12-31 2021-05-18 宁波申江科技股份有限公司 Control system under variable load working condition of methanol reforming fuel cell power generation system

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